CN103603003B - Environment-friendly metal decontamination liquid - Google Patents
Environment-friendly metal decontamination liquid Download PDFInfo
- Publication number
- CN103603003B CN103603003B CN201310508506.9A CN201310508506A CN103603003B CN 103603003 B CN103603003 B CN 103603003B CN 201310508506 A CN201310508506 A CN 201310508506A CN 103603003 B CN103603003 B CN 103603003B
- Authority
- CN
- China
- Prior art keywords
- decontamination liquid
- metal decontamination
- carboxylate
- mass percent
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention provides a kind of environment-friendly metal decontamination liquid with corrosion proof function, it comprises: defoamer 0.3%～5%, cationic surfactant 1%～15%, anion surfactant 1%～10%, non-ionic surface active agent 3%～15%, cleaning host 20%～40%, corrosion inhibiter 2%～5% and surplus deionized water, described corrosion inhibiter is by Shuangzi cation imidazoline quaternary ammonium salt and O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N-diethyl ammonium forms. Metal decontamination liquid provided by the invention provides a kind of low alkali, low bubble, environmental protection, has at a lower temperature the effect of deoiling very by force, and the low-down efficient metal scavenger of corrosivity.
Description
Technical field
The present invention relates to cleaning agent technical field, relate in particular to a kind of environmental protection typed gold with corrosion proof functionBelong to decontamination liquid.
Background technology
In the time of the maintenance and repair of machined and plant equipment, automobile etc., mostly adopt diesel oil, kerosene orGasoline carrys out cleaning components as cleaning fluid. This not only wastes energy, and exists potential unsafe factor,Careless slightly, may lead to fire. In recent years, a kind of novel metal cleaner has obtained extensively graduallyGeneral application, it well diesel oil substitute, kerosene and gasoline carry out cleaning components, and low price,Use safety, be well suited for mechanized cleaning operation. It can be metal washing, and does not have rust staining.
At present, metal cleaner on the market contains strong acid, highly basic, phosphate and aluminium salt etc. mostly hasEvil chemical composition, these chemical compositions not only can be brought certain infringement to metal surface, and can be rightEnvironment causes certain harm, and simultaneously due to complex process, cost is higher.
Summary of the invention
Object of the present invention is exactly for the problems referred to above, provides a kind of low alkali, low bubble, environmental protection, lowerAt temperature, there is the effect of deoiling very by force, and the low-down efficient metal decontamination liquid of corrosivity.
The invention provides a kind of metal decontamination liquid, it comprises: defoamer 0.3%～5%, cationic surfaceActivating agent 1%～15%, anion surfactant 1%～10%, non-ionic surface active agent 3%～15%, cleaning host 20%～40%, corrosion inhibiter 2%～5% and She measure deionized water.
Wherein, described cleaning host is made up of sodium phosphate and sodium metasilicate, the weight between sodium phosphate and sodium metasilicateAmount is than being 2～4: 1.
Wherein, described cationic surfactant can be chloro distearyl dimethyl ammonium, chlorination bayIn base trimethyl ammonium, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and Cetylpyridinium Chloride onePlant or several mixing.
Wherein, described anion surfactant can be alkyl carboxylate's (carboxylate) and poly-alkoxyl carboxylicHydrochlorate, alcohol b-oxide carboxylate, nonylphenol ethoxylate carboxylate, and analog; Sulfonate,For example alkylsulfonate, alkylbenzenesulfonate, alkylaryl sulfonates, sulfonated fatty acid ester, and similarThing; Sulfate, for example sulfated alcohols, sulfated alcohols b-oxide, sulphation alkylphenol, alkyl sulfideHydrochlorate, sulfosuccinate, alkyl ether sulfate, and analog; And phosphate, for example alkyl phosphoric acidEster, and analog. The anion surfactant exemplifying comprises sodium alklyarylsulfonate, alpha-alefinically sulfonic acidSalt and aliphatic alcohol sulfate.
Wherein, described non-ionic surface active agent can for for example chloro-, benzyl-, methyl-, ethyl-, thirdBase-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohols; Not containing polyalkylene oxidesNon-ionic surface active agent, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and ethoxyquinThing; Amine oxide, for example alkoxide ethylenediamine; Alcohol alkoxide, for example alcohol ethoxy propoxide, alcohol thirdOxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide, and analog; Nonyl phenol ethoxyCompound, polyoxyethylene glycol ether and analog; Carboxylate, for example glyceride, polyoxyethylene ester, fatEthoxyquin and the binary alcohol esters of acid, and analog; Carboxylic acid amide, for example diethanol amine condensation product, single alkaneHydramine condensation product, polyoxyethylene fatty acid amide, and analog; And polyalkylene oxide block copolymer, itsComprise ethylene oxide/propylene oxide block copolymer, for example, with trade nameBe purchasedThose (BASF-Wyandotte), and analog; With other similar non-ionic compound. Also can useOrganic silicon surfactant, for exampleB8852。
Described corrosion inhibiter is by Shuangzi cation imidazoline quaternary ammonium salt and O ', and O '-Diphenyl disulfide is for phosphoric acid-N, N-diethyl ammonium forms.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N-diethyl ammonium is as shown in Equation 1.
Described Shuangzi cation imidazoline quaternary ammonium salt as shown in Equation 2.
Described Shuangzi cation imidazoline quaternary ammonium salt and O ', O '-Diphenyl disulfide is for phosphoric acid-N, N-diethyl ammoniumMass ratio be 1: 2～1: 4.
The preparation method of described Shuangzi cation imidazoline quaternary ammonium salt is specially:
The first step, gets 34.8g oleic acid and 15.3g diethylenetriamine, 0.2g aluminum trioxide catalyst is put intoTo being equipped with in the there-necked flask of thermometer, reflux condensing tube and water knockout drum, add band aqua dimethylbenzene simultaneously40ml, adopts 140 DEG C, 170 DEG C, 220 DEG C ladder-elevating temperature methods, dewaters, until no longer include aquaticBecome, be down to 140 DEG C of decompression distillation, slough dimethylbenzene, generate acid amides cyclisation and obtain imidazoline intermediate;
Second step, joins imidazoline intermediate and benzyl chloride in there-necked flask in 1: 1 in molar ratio, dressUpper condenser pipe and thermometer, stir and be warming up to 90 DEG C～110 DEG C reaction 4h, then add epoxychloropropane 4ml,Holding temperature is constant, continues reaction 5h, is cooled to room temperature, obtains crude product, uses acetone/isopropanol weightCrystallization 5 times, 50 DEG C of vacuum drying 48h, obtain the Shuangzi cation imidazoline quaternary ammonium salt shown in formula 2.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and the preparation method of N-diethyl ammonium is specially:
By 22.2g phosphorus pentasulfide (0.1mol), 37.6g phenol (0.4mol) joins 250mL tri-In mouth flask, add 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to 100 DEG C of left sidesRight reaction 45min; Again heat up until reflux, backflow 3h, in course of reaction, solid fades away; SolutionSlightly cold, add a small amount of active carbon boiling decoloring, to filter while hot, filtrate is cooled to room temperature; By gained filtrateBe transferred in beaker, water-bath is cooling and under agitation dropwise drip 22mL diethyl ammonium (0.2mol),Reaction system is emitted a large amount of heat, and liquid color gradually becomes Chinese red, uses glass bar rapid stirring, hasPrecipitation produces, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is whiteLook acicular crystal; Toluene recrystallization, filtration under diminished pressure, vacuum drying, obtains white crystal, to obtain final product.
Wherein, described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
Beneficial effect of the present invention:
Metal decontamination liquid provided by the invention has the advantage of low alkali, low bubble, environmental protection, at a lower temperatureHave the effect of deoiling very by force, and corrosivity is very low.
Detailed description of the invention
The invention provides a kind of metal decontamination liquid, it comprises: defoamer 0.3%～5%, cationic surfaceActivating agent 1%～15%, anion surfactant 1%～10%, non-ionic surface active agent 3%～15%, cleaning host 20%～40%, corrosion inhibiter 2%～5% and She measure deionized water.
Described cleaning host is made up of sodium phosphate and sodium metasilicate, and the weight ratio between sodium phosphate and sodium metasilicate is2～4∶1。
Described cationic surfactant can be chloro distearyl dimethyl ammonium, chlorination lauryl front threeOne in base ammonium, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and Cetylpyridinium Chloride or severalPlant and mix.
Described anion surfactant can be alkyl carboxylate's (carboxylate) and poly-alkoxyl carboxylate,Alcohol b-oxide carboxylate, nonylphenol ethoxylate carboxylate, and analog; Sulfonate, for example alkaneBase sulfonate, alkylbenzenesulfonate, alkylaryl sulfonates, sulfonated fatty acid ester, and analog; SulphurHydrochlorate, for example sulfated alcohols, sulfated alcohols b-oxide, sulphation alkylphenol, alkyl sulfate,Sulfosuccinate, alkyl ether sulfate, and analog; And phosphate, for example alkyl phosphate, andAnalog. The anion surfactant exemplifying comprises sodium alklyarylsulfonate, alpha-alefinically sulfonate and fatFat alcohol sulfate.
Described non-ionic surface active agent can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-DingBase-and the polyglycol ether of other similar alkyl-blocked fatty alcohols; Containing polyalkylene oxides non-fromSub-surface activating agent, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; OxygenChange amine, for example alkoxide ethylenediamine; Alcohol alkoxide, for example alcohol ethoxy propoxide, alcohol propoxide,Alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide, and analog; Nonylphenol ethoxylate, poly-Oxyethylene glycol ether and analog; Carboxylate, for example glyceride, polyoxyethylene ester, the ethoxy of aliphatic acidChange and binary alcohol esters, and analog; Carboxylic acid amide, for example diethanol amine condensation product, monoalkanolamine condensationThing, polyoxyethylene fatty acid amide, and analog; And polyalkylene oxide block copolymer, comprising ringOxidative ethane/propylene oxide block copolymer, for example, with trade nameThose that are purchased, and analog (BASF-Wyandotte); With other similar non-ionic compound. Also can use organicSilicon surface active agent, for exampleB8852。
Described corrosion inhibiter is by Shuangzi cation imidazoline quaternary ammonium salt and O ', and O '-Diphenyl disulfide is for phosphoric acid-N, N-diethyl ammonium forms.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N-diethyl ammonium is as shown in Equation 1.
Described Shuangzi cation imidazoline quaternary ammonium salt as shown in Equation 2.
Described Shuangzi cation imidazoline quaternary ammonium salt and O ', O '-Diphenyl disulfide is for phosphoric acid-N, N-diethyl ammoniumMass ratio be 1: 2～1: 4.
The preparation method of described Shuangzi cation imidazoline quaternary ammonium salt is specially:
The first step, gets 34.8g oleic acid and 15.3g diethylenetriamine, 0.2g aluminum trioxide catalyst is put intoTo being equipped with in the there-necked flask of thermometer, reflux condensing tube and water knockout drum, add band aqua dimethylbenzene simultaneously40ml, adopts 140 DEG C, 170 DEG C, 220 DEG C ladder-elevating temperature methods, dewaters, until no longer include aquaticBecome, be down to 140 DEG C of decompression distillation, slough dimethylbenzene, generate acid amides cyclisation and obtain imidazoline intermediate;
Second step, joins imidazoline intermediate and benzyl chloride in there-necked flask in 1: 1 in molar ratio, dressUpper condenser pipe and thermometer, stir and be warming up to 90 DEG C～110 DEG C reaction 4h, then add epoxychloropropane 4ml,Holding temperature is constant, continues reaction 5h, is cooled to room temperature, obtains crude product, uses acetone/isopropanol weightCrystallization 5 times, 50 DEG C of vacuum drying 48h, obtain the Shuangzi cation imidazoline quaternary ammonium salt shown in formula 2.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and the preparation method of N-diethyl ammonium is specially:
By 22.2g phosphorus pentasulfide (0.1mol), 37.6g phenol (0.4mol) joins 250mL tri-In mouth flask, add 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to 100 DEG C of left sidesRight reaction 45min; Again heat up until reflux, backflow 3h, in course of reaction, solid fades away; SolutionSlightly cold, add a small amount of active carbon boiling decoloring, to filter while hot, filtrate is cooled to room temperature; By gained filtrateBe transferred in beaker, water-bath is cooling and under agitation dropwise drip 22mL diethyl ammonium (0.2mol),Reaction system is emitted a large amount of heat, and liquid color gradually becomes Chinese red, uses glass bar rapid stirring, hasPrecipitation produces, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is whiteLook acicular crystal; Toluene recrystallization, filtration under diminished pressure, vacuum drying, obtains white crystal, obtains sterling.
Described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
The present invention also provides the preparation method of above-mentioned metal decontamination liquid, in deionized water, adds in proportionDefoamer, cationic surfactant, anion surfactant, non-ionic surface active agent, cleaningHost and corrosion inhibiter, stir about 30 minutes, to obtain final product.
Below adopt embodiment to describe embodiments of the present invention in detail, whereby how the present invention is appliedTechnological means solves technical problem, and the implementation procedure of reaching technique effect can fully understand and real according to thisExecute.
The preparation of embodiment 1 Shuangzi cation imidazoline quaternary ammonium salt
Get 34.8g oleic acid and 15.3g diethylenetriamine, 0.2g aluminum trioxide catalyst is put into temperature is housedIn the there-necked flask of degree meter, reflux condensing tube and water knockout drum, add band aqua dimethylbenzene 40ml simultaneously, adoptBy 140 DEG C, 170 DEG C, 220 DEG C ladder-elevating temperature methods, dewater, generate until no longer include water, be down to140 DEG C of decompression distillation, slough dimethylbenzene, generate acid amides cyclisation and obtain imidazoline intermediate; By imidazolineIntermediate and benzyl chloride join in there-necked flask for 1: 1 in molar ratio, load onto condenser pipe and thermometer, stirMix and be warming up to 90 DEG C～110 DEG C reaction 4h, then add epoxychloropropane 4ml, holding temperature is constant, continuesContinuous reaction 5h, is cooled to room temperature, obtains crude product, and with acetone/isopropanol recrystallization 5 times, 50 DEG C trueEmpty dry 48h, obtains Shuangzi cation imidazoline quaternary ammonium salt.
Embodiment 2O ', O '-Diphenyl disulfide is for phosphoric acid-N, the preparation of N-diethyl ammonium
By 22.2g phosphorus pentasulfide (0.1mol), 37.6g phenol (0.4mol) joins 250mL tri-In mouth flask, add 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to 100 DEG C of left sidesRight reaction 45min; Again heat up until reflux, backflow 3h, in course of reaction, solid fades away; SolutionSlightly cold, add a small amount of active carbon boiling decoloring, to filter while hot, filtrate is cooled to room temperature; By gained filtrateBe transferred in beaker, water-bath is cooling and under agitation dropwise drip 22mL diethyl ammonium (0.2mol),Reaction system is emitted a large amount of heat, and liquid color gradually becomes Chinese red, uses glass bar rapid stirring, hasPrecipitation produces, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is whiteLook acicular crystal; Toluene recrystallization, filtration under diminished pressure, vacuum drying, obtains white crystal, obtains sterling.
Embodiment 3: metal decontamination liquid 1
By defoamer tributyl phosphate 2g, cationic surfactant chloro distearyl dimethyl ammonium 8g,Anion surfactant tolyl sodium sulfonate 6g, by name as non-ionic surface active agent commoditySilicon surface active agent 12g, sodium phosphate 20g and sodium metasilicate 10g, embodiment 1 makeStandby Shuangzi cation imidazoline quaternary ammonium salt 1g, O ' prepared by embodiment 2, O '-Diphenyl disulfide is for phosphoric acid-N, N-diethyl ammonium 3g is dissolved in deionized water, stirs about 30 minutes, to obtain final product.
Comparative example 1 metal decontamination liquid 2
By defoamer tributyl phosphate 2g, cationic surfactant chloro distearyl dimethyl ammonium 8g,Anion surfactant tolyl sodium sulfonate 6g, by name as non-ionic surface active agent commoditySilicon surface active agent 12g, sodium phosphate 20g and sodium metasilicate 10g, embodiment 1 makeStandby Shuangzi cation imidazoline quaternary ammonium salt 4g is dissolved in deionized water, stirs about 30 minutes,.
Comparative example 2 metal decontamination liquids 3
By defoamer tributyl phosphate 2g, cationic surfactant chloro distearyl dimethyl ammonium 8g,Anion surfactant tolyl sodium sulfonate 6g, by name as non-ionic surface active agent commoditySilicon surface active agent 12g, sodium phosphate 20g and sodium metasilicate 10g, embodiment 2 makeStandby O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N-diethyl ammonium 4g is dissolved in deionized water, stirs 30 pointsClock left and right, to obtain final product.
Comparative example 3 metal decontamination liquids 4
By defoamer tributyl phosphate 2g, cationic surfactant chloro distearyl dimethyl ammonium 8g,Anion surfactant tolyl sodium sulfonate 6g, by name as non-ionic surface active agent commoditySilicon surface active agent 12g, sodium phosphate 20g and sodium metasilicate 10g be dissolved in deionizationIn water, stir about 30 minutes, to obtain final product.
It is clear that the metal decontamination liquid that embodiment 1 and comparative example 1-3 are obtained carries out metallic aluminium clean surface greasy dirtWash, the results are shown in Table 1.
Cleaning rate: the greasy dirt weight/greasy dirt original weight of cleaning rate=wash;
Anticorrosive property: grading standard: 0 grade of surface is rustless, without significant change.
1 grade of surface is rustless, light discolouration or loss of gloss.
2 grades of light rust in surface or inhomogeneous variable color.
3 grades of surperficial large area corrosions.
Stability: mixed composition was placed after 4 hours, observed its layering situation, stabilize to regardless ofLayer is not muddy, and shakiness is decided to be layering or muddiness.
Table 1
| Group | Anticorrosive property | Cleaning rate | Stability |
| Embodiment 3 | 0 grade | 96.2 | Stable |
| Comparative example 1 | 2 grades | 93.9 | Stable |
| Comparative example 2 | 2 grades | 92.7 | Stable |
| Comparative example 3 | 3 grades | 90.3 | Stable |
All above-mentioned these intellectual properties of primary enforcement, do not set the other forms of enforcement of restriction thisPlant new product and/or new method. Those skilled in the art will utilize this important information, foregoing amendment,To realize similar implementation status. But all modifications or transformation belong to reservation based on new product of the present inventionRight.
The above, be only preferred embodiment of the present invention, is not that the present invention is made to other formRestriction, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changedOr be modified as the equivalent embodiment of equivalent variations. But every technical solution of the present invention content that do not depart from, complies withAny simple modification, equivalent variations and the remodeling above embodiment done according to technical spirit of the present invention,Still belong to the protection domain of technical solution of the present invention.
Claims (7)
1. a metal decontamination liquid, it is characterized in that: formed by defoamer mass percent 0.3%～5%, cationic surfactant mass percent 1%～15%, anion surfactant mass percent 1%～10%, non-ionic surface active agent mass percent 3%～15%, cleaning host mass percent 20%～40%, corrosion inhibiter 2%～5% mass percent and surplus deionized water, described corrosion inhibiter is by Shuangzi cation imidazoline quaternary ammonium salt and O, O '-Diphenyl disulfide is for phosphoric acid-N, and N-diethyl ammonium forms;
Described cleaning host is made up of sodium phosphate and sodium metasilicate, and the weight ratio between sodium phosphate and sodium metasilicate is 2～4:1;
Described Shuangzi cation imidazoline quaternary ammonium salt and O, O '-Diphenyl disulfide is for phosphoric acid-N, and the mass ratio of N-diethyl ammonium is 1:2～1:4.
2. metal decontamination liquid as claimed in claim 1, is characterized in that: described cationic surfactant is one or more mixing in chloro distearyl dimethyl ammonium, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and Cetylpyridinium Chloride.
3. metal decontamination liquid as claimed in claim 1 or 2, is characterized in that: described anion surfactant is alkyl carboxylate, poly-alkoxyl carboxylate, alcohol b-oxide carboxylate, nonylphenol ethoxylate carboxylate, sulfonate, sulfate or phosphate.
4. metal decontamination liquid as claimed in claim 1 or 2, it is characterized in that: described non-ionic surface active agent be chloro-, benzyl-, methyl-, ethyl-, propyl group-, the polyglycol ether of the fatty alcohol of butyl-end-blocking, alkyl poly glucoside, anhydro sorbitol, amine oxide, alcohol alkoxide, nonylphenol ethoxylate, polyoxyethylene glycol ether, carboxylate or carboxylic acid amide.
5. metal decontamination liquid as claimed in claim 1, is characterized in that: the preparation method of described Shuangzi cation imidazoline quaternary ammonium salt is specially,
The first step, get 34.8g oleic acid and 15.3g diethylenetriamine, 0.2g aluminum trioxide catalyst is put in the there-necked flask that thermometer, reflux condensing tube and water knockout drum are housed, add band aqua dimethylbenzene 40mL simultaneously, adopt 140 DEG C, 170 DEG C, 220 DEG C ladder-elevating temperature methods, dewater, generate until no longer include water, be down to 140 DEG C of decompression distillation, slough dimethylbenzene, generate acid amides cyclisation and obtain imidazoline intermediate;
Second step, by imidazoline intermediate and benzyl chloride in molar ratio 1:1 join in there-necked flask, load onto condenser pipe and thermometer, stir and be warming up to 90 DEG C～110 DEG C reaction 4h, add again epoxychloropropane 4mL, holding temperature is constant, continues reaction 5h, is cooled to room temperature, obtain crude product, with acetone/isopropanol recrystallization 5 times, 50 DEG C of vacuum drying 48h, obtain Shuangzi cation imidazoline quaternary ammonium salt.
6. metal decontamination liquid as claimed in claim 1, it is characterized in that: described O, O '-Diphenyl disulfide is for phosphoric acid-N, and the preparation method of N-diethyl ammonium is specially the phosphorus pentasulfide by 22.2g, 37.6g phenol joins in 250mL there-necked flask, adds 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to 100 DEG C of reaction 45min; Again heat up until reflux, backflow 3h, in course of reaction, solid fades away; Solution is slightly cold, adds a small amount of active carbon boiling decoloring, filters while hot, and filtrate is cooled to room temperature; Gained filtrate is transferred in beaker, and water-bath is cooling and under agitation dropwise drip 22mL diethylamine, and reaction system is emitted a large amount of heat, and liquid color gradually becomes Chinese red, uses glass bar rapid stirring, has precipitation to produce, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is white needle-like crystals; Toluene recrystallization, filtration under diminished pressure, vacuum drying, obtains white crystal, obtains sterling.
7. metal decontamination liquid as claimed in claim 1 or 2, is characterized in that: described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310508506.9A CN103603003B (en) | 2013-10-25 | 2013-10-25 | Environment-friendly metal decontamination liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310508506.9A CN103603003B (en) | 2013-10-25 | 2013-10-25 | Environment-friendly metal decontamination liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103603003A CN103603003A (en) | 2014-02-26 |
| CN103603003B true CN103603003B (en) | 2016-05-04 |
Family
ID=50121264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310508506.9A Active CN103603003B (en) | 2013-10-25 | 2013-10-25 | Environment-friendly metal decontamination liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103603003B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105040012A (en) * | 2015-04-29 | 2015-11-11 | 安徽长城输送机械制造有限公司 | Metal cleaning agent and preparation method thereof |
| CN107841747A (en) * | 2017-11-08 | 2018-03-27 | 中国科学院海洋研究所 | Acid corrosion-resistant compound corrosion inhibitor a kind of efficient and with self-repair function and preparation method and application |
| CN108625167A (en) * | 2018-03-23 | 2018-10-09 | 江苏凯美斯环保科技有限公司 | A kind of anti-fall slurry oil-control agent of water-jet loom efficient and environment-friendly type and its application |
| CN108949380A (en) * | 2018-08-15 | 2018-12-07 | 南通科星化工有限公司 | heavy oil dirt cleaning agent |
| CN109912506A (en) * | 2019-03-22 | 2019-06-21 | 徐州工程学院 | A kind of synthetic method of symmetric form imidazoline Gemini surface active |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5486508A (en) * | 1977-12-23 | 1979-07-10 | Nippon Paint Co Ltd | Degreasing detergent |
| CN1056904A (en) * | 1990-05-30 | 1991-12-11 | 李洪耀 | High efficiency clening agent for engine of vehicle |
| CN101979711A (en) * | 2010-11-10 | 2011-02-23 | 南通海迅天恒纳米科技有限公司 | Stainless steel degreasing agent |
| CN102345137A (en) * | 2010-08-04 | 2012-02-08 | 太仓市联林活性炭厂 | Degreasing agent |
| KR101135915B1 (en) * | 2003-05-28 | 2012-04-16 | 론자 인코포레이티드 | Use of quaternary ammonium carbonates and bicarbonates as anticorrosive agents, method for inhibiting corrosion and anticorrosive coatings using these agents |
| CN102888614A (en) * | 2012-10-17 | 2013-01-23 | 无锡日冠机电制造有限公司 | Washing liquid special for cold rolled silicon steel plate |
-
2013
- 2013-10-25 CN CN201310508506.9A patent/CN103603003B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5486508A (en) * | 1977-12-23 | 1979-07-10 | Nippon Paint Co Ltd | Degreasing detergent |
| CN1056904A (en) * | 1990-05-30 | 1991-12-11 | 李洪耀 | High efficiency clening agent for engine of vehicle |
| KR101135915B1 (en) * | 2003-05-28 | 2012-04-16 | 론자 인코포레이티드 | Use of quaternary ammonium carbonates and bicarbonates as anticorrosive agents, method for inhibiting corrosion and anticorrosive coatings using these agents |
| CN102345137A (en) * | 2010-08-04 | 2012-02-08 | 太仓市联林活性炭厂 | Degreasing agent |
| CN101979711A (en) * | 2010-11-10 | 2011-02-23 | 南通海迅天恒纳米科技有限公司 | Stainless steel degreasing agent |
| CN102888614A (en) * | 2012-10-17 | 2013-01-23 | 无锡日冠机电制造有限公司 | Washing liquid special for cold rolled silicon steel plate |
Non-Patent Citations (2)
| Title |
|---|
| O,O’-二苯基二硫代磷酸-N,N-二乙铵的合成及其缓蚀性能;谢斌等;《材料保护》;20111231;第44卷(第12期);第63页左栏第1段-第64页左栏第1段，第65页右栏倒数第1段 * |
| 咪唑啉基季铵盐型双子表面活性剂的合成与性能;葛君等;《精细化工》;20110531;第28卷(第5期);第447-450页1.2 合成路线及1.3步骤、1.4 产物的性能测试及2.结果讨论 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103603003A (en) | 2014-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103603003B (en) | Environment-friendly metal decontamination liquid | |
| CN103614734B (en) | There is the Environment-Protect Metal Cleaning Agents of corrosion proof function | |
| CN103510100B (en) | Metal cleaner | |
| CN102041140B (en) | Anti-micro pitting gear oil composite additive | |
| CN103774164A (en) | Water-based metal-degreasing cleaning agent | |
| CN104674259A (en) | Metallic slag oil-water base cleaning agent | |
| CN104845595B (en) | A kind of automobile engine water-free cooling composition | |
| CN104313614B (en) | Low-foam detergent and preparation method thereof | |
| CN102409349A (en) | Metal washing agent | |
| CN103602995B (en) | Environmental protection type metal detergency agent | |
| JP6082873B2 (en) | Antifouling agent and antifouling method for water-safe treatment facilities | |
| CN103774157A (en) | Metal cleaning agent and its preparation method | |
| CN106637263B (en) | A kind of environment-friendly type Aluminum Alloy Room Temperature aqueous cleaning agent and its application | |
| CN110387292A (en) | A kind of cleaning solution and preparation method applied to optical glass substrate | |
| CN109321373A (en) | A kind of aircraft surfaces externally and internally cleaning agent | |
| CN101134891A (en) | Automobile engine winterization fluid | |
| CN105525300B (en) | A kind of water base metal cleaning agent | |
| CN104120439A (en) | Environment-friendly type water-based metal cleaning agent and manufacturing method thereof | |
| CN105525303A (en) | Metal cleaning agent | |
| CN102925905A (en) | Acid-washing corrosion inhibitor for copper and alloy device | |
| US11186913B2 (en) | Corrosion inhibitor and water conditioning agent | |
| CN107446673A (en) | A kind of automatic start-stop special-purpose protecting agent and preparation method thereof | |
| SE521569C2 (en) | Aqueous liquid containing a zwitterionic surfactant and another zwitterionic surfactant for friction reduction, use of a surfactant composition and a surfactant composition | |
| TWI643944B (en) | Automotive engine coolant composition, automotive engine concentrated coolant composition, and method of operating internal combustion engine | |
| CN104388196A (en) | Detergent for tank truck and preparation method of detergent for tank truck |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160330 Address after: 266001 Shandong city of Qingdao province Chongqing District Road No. 27 Building No. 1 room 402, unit 2 Applicant after: Zhang Xuwei Address before: 266071 Shandong city of Qingdao province Hongkong City Road No. 32 Minmetals building room 801-A Applicant before: Qingdao Huaren Technology Incubator Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Ji Inventor before: Sun Xia |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170306 Address after: Jiangdong Road 200137 Shanghai city Pudong New Area Lingqiao Industrial Zone 1726 Lane 149 Patentee after: Shanghai Petrofer Special Lubricant Co.,Ltd. Address before: 266001 Shandong city of Qingdao province Chongqing District Road No. 27 Building No. 1 room 402, unit 2 Patentee before: Zhang Xuwei |