CN104194964A - Automobile glass cleaner and preparation method thereof - Google Patents
Automobile glass cleaner and preparation method thereof Download PDFInfo
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- CN104194964A CN104194964A CN201410369554.9A CN201410369554A CN104194964A CN 104194964 A CN104194964 A CN 104194964A CN 201410369554 A CN201410369554 A CN 201410369554A CN 104194964 A CN104194964 A CN 104194964A
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Abstract
The invention discloses an automobile glass cleaner and a preparation method thereof. A non-ionic fluorinated surfactant is combined with other surfactants, so that the cleansing power can be enhanced, and scattering of a light beam which passes through a windshield can be greatly reduced and an excellent anti-dazzle effect can be achieved; meanwhile, excellent anti-tog and high-flow properties can be also achieved even under the circumstance of low temperatures below zero DEG C.
Description
Technical field
The present invention relates to a kind of sanitising agent and preparation method thereof, especially a kind of automobile glass cleaning agent and preparation method thereof.
Background technology
Summer, sunlight was dazzling, and in automobile cab, sunlight is easy to see through windshield glass, and the eyes that stimulate officer, easily produce traffic accident; And in car steering process in the winter time, the moisture convergences that suspend in a large number in wheel house are on glass low temperature, produce one deck ambiguous vaporific, along with the continuous decline of temperature, on windshield glass, also can form the ice crystal of thin layer, the driving environment that visibility meter is very low, brings certain difficulty to the operation of navigating mate, very easily causes a traffic accident, current automobile wind screen defrosting adopts Hot-air fan to blow drying method mostly, this method power consumption is many, and easily forms fog, is difficult to leave fast.
Summary of the invention
The object of this invention is to provide a kind of automobile glass cleaning agent and preparation method thereof, use non-ion fluorin surfactant and other surfactant compound mode, not only strengthen soil removability, can also greatly reduce light beam by windshield glass time, there is scattering, reach good anti-dazzle effect, under the low temperature condition below 0 DEG C, also can play well antifog, the high performance flowing simultaneously.
A kind of automobile glass cleaning agent, is made up of the raw material of following mass fraction: pigment 0.1-0.5 part, non-ion fluorin surfactant 1.0-4.5 part, polyether silicone oil 0.1-3.0 part, ethoxylated dodecyl alcohol 0.01-0.1 part, polyoxyethylene nonylphenol ether 0.01-0.1 part, C8-C10 alkyl glycoside 0.05-0.5 part, 1, ammediol 2.0-10.0 part, ethanol 2.0-60.0 part, dodecyl benzyl dimethyl ammonium chloride 0.01-0.5 part, composite corrosion inhibitor 0.01-0.5 part, sanitas 0.2-0.5 part.Disodium ethylene diamine tetraacetate 0.001-0.5 part, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 50-70r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
Wherein non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is light blue pigment or methyl red pigment.
The invention has the advantages that:
1, nonionogenic tenside selects ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether to play wetting and emulsifying agent soil-removing action.
2, can further reduce surface tension adding of non-ion fluorin surfactant, make surface tension of liquid drop to 17-19dyn/cm(25 DEG C), obviously improve soaking and penetrating power of product, improve cleaning performance.Non-ion fluorin surfactant is because containing multiple fluorocarbon group, make it and glass surface have extraordinary bonding force, the fine glass surface that is attached to of energy when cleaning panes of motor vehicle, because it has Superhydrophilic, the water smoke (and even steam) of any temperature, mist pearl, just can infiltrate immediately and sprawl into transparent moisture film once contacting with glass surface, because making moisture film, moves rapidly its Superhydrophilic, drip and can not be gathered into, good anti-fog effect (also can play well antifog, high drip performance under the low temperature condition below 0 DEG C.) can reduce the consumption of other tensio-active agent simultaneously, reduce costs.
3, non-ion fluorin surfactant and polyether silicone oil are used in conjunction with, can greatly reduce light beam by windshield glass time, there is scattering (light beam is mainly reflective from motorway street lamp, dipped headlights, road surface or the water surface etc.), and affect officer's vision, can play good anti-dazzle effect.
4, dodecyl benzyl dimethyl ammonium chloride can be eliminated due to fricative static, to reduce adsorbing again of dust, plays sterilization and anticorrosion effect simultaneously, coordinates have wetting and soil-removing action with nonionic.
5, polyether silicone oil and alkyl glycoside can increase and lubricate in the time cleaning, and reduce and scrape water resistance and the damage of wiper rubber sheet, can play and increase wiper rubber elastic contribution, scrape water more thorough.
embodiment:
Embodiment 1:
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following mass fraction: 0.05 part of 0.1 part of pigment, 1.0 parts of non-ion fluorin surfactants, 0.1 part of polyether silicone oil, 0.01 part of ethoxylated dodecyl alcohol, 0.01 part of polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, 1,2.0 parts of ammediols, 2.0 parts of ethanol, 0.01 part of dodecyl benzyl dimethyl ammonium chloride, 0.01 part of composite corrosion inhibitor, 0.2 part of sanitas.0.001 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 50r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
Wherein non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is light blue pigment.
Embodiment 2:
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following mass fraction: 0.25 part of 0.3 part of pigment, 2.5 parts of non-ion fluorin surfactants, 1.5 parts of polyether silicone oils, 0.05 part of ethoxylated dodecyl alcohol, 0.05 part of polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, 1,6.0 parts of ammediols, 31.0 parts of ethanol, 0.25 part of dodecyl benzyl dimethyl ammonium chloride, 0.25 part of composite corrosion inhibitor, 0.3 part of sanitas.0.25 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 60r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
Wherein non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is methyl red pigment.
Embodiment 3:
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following mass fraction: 0.5 part of 0.5 part of pigment, 4.5 parts of non-ion fluorin surfactants, 3.0 parts of polyether silicone oils, 0.1 part of ethoxylated dodecyl alcohol, 0.1 part of polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, 1,10.0 parts of ammediols, 60.0 parts of ethanol, 0.5 part of dodecyl benzyl dimethyl ammonium chloride, 0.5 part of composite corrosion inhibitor, 0.5 part of sanitas.0.5 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 70r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
Wherein non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is methyl red pigment.
Embodiment 4:
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following mass fraction: 0.03 part of 0.08 part of pigment, 0.7 part of non-ion fluorin surfactant, 0.08 part of polyether silicone oil, 0.007 part of ethoxylated dodecyl alcohol, 0.009 part of polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, 1,1.0 parts of ammediols, 1.0 parts of ethanol, 0.007 part of dodecyl benzyl dimethyl ammonium chloride, 0.009 part of composite corrosion inhibitor, 0.1 part of sanitas.0.0009 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 40r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
Wherein non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is light blue pigment.
Embodiment 5:
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following mass fraction: 0.6 part of 0.6 part of pigment, 5.0 parts of non-ion fluorin surfactants, 4.0 parts of polyether silicone oils, 0.2 part of ethoxylated dodecyl alcohol, 0.2 part of polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, 1,12.0 parts of ammediols, 65.0 parts of ethanol, 0.7 part of dodecyl benzyl dimethyl ammonium chloride, 0.6 part of composite corrosion inhibitor, 0.7 part of sanitas.0.7 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 80r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
Wherein non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is methyl red pigment.
The present invention is made to the vehicle glass of embodiment 1-5 automobile glass cleaning agent for same model, not having clean same model vehicle glass to contrast as a comparison case, test mist degree and light transmission rate (using transmittance mist degree determinator WGT-S to detect) contrast, and result is as shown in the table:
? | Mist degree (0-30%) | Light transmission rate (0-100%) |
Embodiment 1 | 1.49% | 92.9% |
Embodiment 2 | 1.40% | 95.2% |
Embodiment 3 | 1.45% | 94.3% |
Embodiment 4 | 2.44% | 90.6% |
Embodiment 5 | 2.42% | 90.2% |
Comparative example (not using) | 4.81% | 79.3% |
Can find out from upper table result, the successful that embodiment 1-3 in processing range of the present invention makes automobile glass cleaning agent is better than embodiment 4,5 and the comparative example outside processing range, especially with embodiment 2 best results, therefore when the present invention can reduce light beam greatly by windshield glass, there is scattering, reach good anti-dazzle effect, also can play good anti-fog effect simultaneously.
Claims (5)
1. an automobile glass cleaning agent, it is characterized by: the raw material by following mass fraction is made: pigment 0.1-0.5 part, non-ion fluorin surfactant 1.0-4.5 part, polyether silicone oil 0.1-3.0 part, ethoxylated dodecyl alcohol 0.01-0.1 part, polyoxyethylene nonylphenol ether 0.01-0.1 part, alkyl glycoside (C8-C10) 0.05-0.5 part, 1, ammediol 2.0-10.0 part, ethanol 2.0-60.0 part, dodecyl benzyl dimethyl ammonium chloride 0.01-0.5 part, composite corrosion inhibitor 0.01-0.5 part, sanitas 0.2-0.5 part, disodium ethylene diamine tetraacetate 0.001-0.5 part, remainder is deionized water, totally 100 parts.
2. a kind of automobile glass cleaning agent as claimed in claim 1, it is characterized by: a kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 50-70r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
3. a kind of automobile glass cleaning agent as claimed in claim 1, it is characterized by: preparation method is: a kind of automobile glass cleaning agent and preparation method thereof, raw material by following mass fraction is made: 0.3 part of pigment, 2.5 parts of non-ion fluorin surfactants, 1.5 parts of polyether silicone oils, 0.05 part of ethoxylated dodecyl alcohol, 0.05 part of polyoxyethylene nonylphenol ether, 0.25 part of C8-C10 alkyl glycoside, 1, 6.0 parts of ammediols, 31.0 parts of ethanol, 0.25 part of dodecyl benzyl dimethyl ammonium chloride, 0.25 part of composite corrosion inhibitor, 0.3 part of sanitas, 0.25 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100 parts.
4. a kind of automobile glass cleaning agent as claimed in claim 2 and preparation method thereof, it is characterized by: preparation method is: a kind of automobile glass cleaning agent, preparation method is: pigment is put into stainless steel cauldron, then in reactor, add deionized water, ethanol and 1, ammediol, open stainless steel stirring arm, control stirring velocity is 60r/min, make pigment dissolve and be stirred, under whipped state, in stainless steel cauldron, add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, polyoxyethylene nonylphenol ether, C8-C10 alkyl glycoside, dodecyl benzyl dimethyl ammonium chloride, sanitas, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, after material stirring is even, be automobile glass cleaning agent.
5. as the wherein a kind of automobile glass cleaning agent as described in of claim 1-4, it is characterized by: non-ion fluorin surfactant is the non-ion fluorin surfactant Capstone FS-3100 of Du Pont, composite corrosion inhibitor by etc. the ZnSO of quality
4, Na
2siO
3and Na
2wO
4composition, sanitas is isothiazolinone, pigment is light blue pigment or methyl red pigment.
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CN201410369554.9A CN104194964B (en) | 2014-07-30 | 2014-07-30 | A kind of automobile glass cleaning agent and preparation method thereof |
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CN104194964B CN104194964B (en) | 2017-06-20 |
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Cited By (9)
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CN106635470A (en) * | 2016-09-30 | 2017-05-10 | 东莞市蓝鲸化工科技有限公司 | Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof |
CN106929866A (en) * | 2017-04-20 | 2017-07-07 | 合肥华清金属表面处理有限责任公司 | A kind of Phosphateless environmentally friendly rust-removing and-preventing agent |
CN107881024A (en) * | 2017-11-14 | 2018-04-06 | 广州沿江科技有限公司 | A kind of cleanser for vehicle windscreen and preparation method thereof |
CN108441331A (en) * | 2018-04-18 | 2018-08-24 | 鹤山市金润纳新型材料有限公司 | A kind of automobile glass cleaning agent and preparation method thereof |
CN109152291A (en) * | 2018-09-06 | 2019-01-04 | 上海理工大学 | A method of strengthening misting cooling heat exchange property |
CN109370797A (en) * | 2018-12-26 | 2019-02-22 | 合肥普庆新材料科技有限公司 | Neutral cleaning agent for mobile phone cover plate glass |
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CN113105868A (en) * | 2021-04-19 | 2021-07-13 | 江苏南创化学与生命健康研究院有限公司 | Antibacterial antifogging agent and antibacterial long-acting antifogging wet tissue prepared from same |
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CN106929866A (en) * | 2017-04-20 | 2017-07-07 | 合肥华清金属表面处理有限责任公司 | A kind of Phosphateless environmentally friendly rust-removing and-preventing agent |
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CN108441331A (en) * | 2018-04-18 | 2018-08-24 | 鹤山市金润纳新型材料有限公司 | A kind of automobile glass cleaning agent and preparation method thereof |
CN109152291A (en) * | 2018-09-06 | 2019-01-04 | 上海理工大学 | A method of strengthening misting cooling heat exchange property |
CN109385337A (en) * | 2018-11-20 | 2019-02-26 | 萍乡亨厚新材科技有限公司 | A kind of automobile exempts to clean car washing liquid and its application method |
CN109370797A (en) * | 2018-12-26 | 2019-02-22 | 合肥普庆新材料科技有限公司 | Neutral cleaning agent for mobile phone cover plate glass |
CN109370797B (en) * | 2018-12-26 | 2021-01-01 | 合肥普庆新材料科技有限公司 | Neutral cleaning agent for mobile phone cover plate glass |
CN113105868A (en) * | 2021-04-19 | 2021-07-13 | 江苏南创化学与生命健康研究院有限公司 | Antibacterial antifogging agent and antibacterial long-acting antifogging wet tissue prepared from same |
CN113105868B (en) * | 2021-04-19 | 2022-05-17 | 江苏南创化学与生命健康研究院有限公司 | Antibacterial antifogging agent and antibacterial long-acting antifogging wet tissue prepared from same |
CN117511504A (en) * | 2024-01-04 | 2024-02-06 | 荷塘探索国际健康科技发展(北京)有限公司 | Medical antifogging agent, preparation method and antifogging mirror cloth prepared from medical antifogging agent |
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