CN108690746A - A kind of Glass cleaner compositions and cleaning glass method - Google Patents
A kind of Glass cleaner compositions and cleaning glass method Download PDFInfo
- Publication number
- CN108690746A CN108690746A CN201810634625.1A CN201810634625A CN108690746A CN 108690746 A CN108690746 A CN 108690746A CN 201810634625 A CN201810634625 A CN 201810634625A CN 108690746 A CN108690746 A CN 108690746A
- Authority
- CN
- China
- Prior art keywords
- parts
- glass
- polyol
- cleaner compositions
- glass cleaner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 98
- 239000000203 mixture Substances 0.000 title claims abstract description 53
- 238000004140 cleaning Methods 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 18
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229920005862 polyol Polymers 0.000 claims abstract description 30
- 150000003077 polyols Chemical class 0.000 claims abstract description 30
- 230000000694 effects Effects 0.000 claims abstract description 20
- 235000019441 ethanol Nutrition 0.000 claims abstract description 20
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 17
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims abstract description 17
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 4
- 239000000725 suspension Substances 0.000 claims abstract description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 28
- -1 glycol ester Chemical class 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 5
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 2
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical class N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 229920000223 polyglycerol Polymers 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 5
- 230000003213 activating effect Effects 0.000 claims 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 239000004258 Ethoxyquin Substances 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 230000001680 brushing effect Effects 0.000 claims 1
- 229940093500 ethoxyquin Drugs 0.000 claims 1
- 235000019285 ethoxyquin Nutrition 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 239000000428 dust Substances 0.000 abstract description 7
- 238000005406 washing Methods 0.000 abstract description 6
- 238000009825 accumulation Methods 0.000 abstract description 4
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 239000003595 mist Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 3
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of Glass cleaner compositions and cleaning glass method, solve the problems, such as that existing glass cleaner cleaning effect is undesirable.Its Glass cleaner compositions is uniformly mixed suspension, and in terms of mass parts including:0.5-1 parts of anionic surfactant, 2-2.5 parts of polyol-based non-ionic surfactant, 4-8 parts of ethylene glycol n-butyl ether, 0.6-1.0 parts of disodium hydrogen phosphate, 2.5-10 parts of ammonium citrate, 1.2-1.5 parts of kaolin, 15-20 parts of ethyl alcohol, 0.7-1 parts of isopropanol, 100 parts of water.The cleaning compositions of the present invention can realize the high-efficiency washing of glass, and can realize that glass surface is anti-in a long time and haze and the effect of anti-dust accumulation.The cleaning glass method of the present invention is easy to operate, and cleaning is quick.
Description
Technical field
The present invention relates to detergent composition, especially a kind of Glass cleaner compositions and cleaning glass method.
Background technology
Detergent is a kind of cleaning production for being used for washing the things such as clothing, implement or cleaning furniture of liquid condition
Product.It uses various new surfactant, and strong detergency, rinsing is easy, non-stimulated to skin, can be used for washing kitchen tools,
Furniture and fruit, melon and vegetable.
And as the glass cleaner of tailored version, belong to public utilities hard surface cleaner range, also belongs to household cleaning
Agent.Glass cleaner is a kind of detergent of special glass door and window, minute surface and vehicle glass between floors etc..But it is traditional
Glass cleaner cleaning effect is bad, needs repeatedly to be cleaned, the duration is long.
Invention content
In order to overcome the shortcomings of that existing glass cleaner cleaning effect is undesirable, the object of the present invention is to provide one kind to have
The Glass cleaner compositions and cleaning glass method of better cleaning effect.
The technical solution adopted by the present invention to solve the technical problems is:A kind of Glass cleaner compositions, it is characterised in that:
The Glass cleaner compositions are uniformly mixed suspension, and in terms of mass parts including:Anionic surfactant
0.5-1 parts, 2-2.5 parts of polyol-based non-ionic surfactant, 4-8 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate 0.6-
1.0 parts, 2.5-10 parts of ammonium citrate, 1.2-1.5 parts of kaolin, 15-20 parts of ethyl alcohol, 0.7-1 parts of isopropanol, 100 parts of water.
In currently preferred aspect, the anionic surfactant is neopelex.
In currently preferred aspect, the polyol-based non-ionic surfactant is selected from glycol ester, glycerine
Ester, polyglycerol ester, sorbitan ester, ethoxyquin derivative, Nonyl Phenol ethoxylated.
In currently preferred aspect, the polyol-based non-ionic surfactant be glycerin monostearate or
Butyl glycol ether.
In currently preferred aspect, the polyol-based non-ionic surfactant is glycerin monostearate and second
The mixture of glycol butyl ether, and the mass ratio of the glycerin monostearate and butyl glycol ether is 100: 20-40.
In currently preferred aspect, the Glass cleaner compositions are selected from:(1)Including dodecane in terms of mass parts
0.75 part of base benzene sulfonic acid sodium salt, 2.25 parts of polyol-based non-ionic surfactant, 6 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate
0.7 part, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, 100 parts of water, and polyalcohol
Type nonionic surfactant is glycerin monostearate;(2)In terms of mass parts including, 0.85 part of neopelex,
2 parts of polyol-based non-ionic surfactant, 8 parts of ethylene glycol n-butyl ether, 0.6 part of disodium hydrogen phosphate, 10 parts of ammonium citrate,
1.2 parts of kaolin, 15 parts of ethyl alcohol, 1 part of isopropanol, 100 parts of water, and polyol-based non-ionic surfactant is second two
Alcohol butyl ether;(3)Including 0.75 part of neopelex, polyol-based non-ionic surfactant 2.25 in terms of mass parts
It is part, 6 parts of ethylene glycol n-butyl ether, 0.7 part of disodium hydrogen phosphate, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, different
0.85 part of propyl alcohol, 100 parts of water, and polyol-based non-ionic surfactant is glycerin monostearate and butyl glycol ether
Mixture, and the mass ratio of the glycerin monostearate and butyl glycol ether be 100: 30-35;(4)With mass parts
Meter includes 0.75 part of neopelex, 2.25 parts of polyol-based non-ionic surfactant, ethylene glycol n-butyl ether 6
Part, 0.7 part of disodium hydrogen phosphate, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, water 100
Part, and polyol-based non-ionic surfactant is the mixture of glycerin monostearate and butyl glycol ether, and it is described
Glycerin monostearate and butyl glycol ether mass ratio be 100: 33.5.
In other aspects of the present invention, a kind of cleaning glass method is also disclosed, the method includes step:(1)It will
Glass surface to be cleaned is sprayed using clear water;(2)By previously described Glass cleaner compositions according to 10-25 grams/m
Amount be uniformly applied to glass surface, and using hairbrush brush 3-10 minutes;(3)The glass surface that step 2 is obtained
It is sprayed using clear water, washes away the Glass cleaner compositions on surface;(4)The glass is dried up using 60-80 degrees Celsius of hot wind.
In currently preferred aspect, the method, by previously described Glass cleaner compositions in step (2)
It is uniformly applied to glass surface according to 16-20 grams/m of amount, and using hairbrush brush 5-6 minutes.
The characteristics of cleaning compositions of the present invention, is that it is possible to realize the high-efficiency washing of glass, and can be when longer
Interior realization glass surface is anti-to haze and the effect of anti-dust accumulation.The present invention composition can be widely applied to workshop, workshop glass
Glass clean operation.By using glycerin monostearate, realizing glass surface prevents from hazing the extension of time.And monostearate
The mixture of glyceride and butyl glycol ether then realize glass surface under higher temperature conditions when preventing from hazing with dust accumulation
Between extension.
Specific implementation mode
Unless additionally illustrating, Glass cleaner compositions used in the present invention are all prepared by directly mixing and stirring
It obtains, is suspension, and shake up again before the use.
Embodiment 1
In the present embodiment, the preparation of Glass cleaner compositions is carried out according to proportioning below:Including 12 in terms of mass parts
0.75 part of sodium alkyl benzene sulfonate, 2.25 parts of polyol-based non-ionic surfactant, 6 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate
0.7 part, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, 100 parts of water, and polyalcohol
Type nonionic surfactant is glycerin monostearate.
Embodiment 2
In the present embodiment, the preparation of Glass cleaner compositions is carried out according to proportioning below:Including 12 in terms of mass parts
0.85 part of sodium alkyl benzene sulfonate, 2 parts of polyol-based non-ionic surfactant, 8 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate
0.6 part, 10 parts of ammonium citrate, 1.2 parts of kaolin, 15 parts of ethyl alcohol, 1 part of isopropanol, 100 parts of water, and polyol type it is non-from
Sub- surfactant is butyl glycol ether.
Embodiment 3
In the present embodiment, the preparation of Glass cleaner compositions is carried out according to proportioning below:Neopelex 1
Part, 2.5 parts of polyol-based non-ionic surfactant, 4 parts of ethylene glycol n-butyl ether, 1.0 parts of disodium hydrogen phosphate, ammonium citrate
2.5 parts, 1.2 parts of kaolin, 20 parts of ethyl alcohol, 0.7 part of isopropanol, 100 parts of water, and polyol type non-ionic surface active
Agent is butyl glycol ether.
Embodiment 4
In the present embodiment, the preparation of Glass cleaner compositions is carried out according to proportioning below:Including 12 in terms of mass parts
0.75 part of sodium alkyl benzene sulfonate, 2.25 parts of polyol-based non-ionic surfactant, 6 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate
0.7 part, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, 100 parts of water, and polyalcohol
Type nonionic surfactant is the mixture of glycerin monostearate and butyl glycol ether, and the glycerol monostearate
The mass ratio of ester and butyl glycol ether is 100: 20.
Embodiment 5
In the present embodiment, the preparation of Glass cleaner compositions is carried out according to proportioning below:Including 12 in terms of mass parts
0.75 part of sodium alkyl benzene sulfonate, 2.25 parts of polyol-based non-ionic surfactant, 6 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate
0.7 part, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, 100 parts of water, and polyalcohol
Type nonionic surfactant is the mixture of glycerin monostearate and butyl glycol ether, and the glycerol monostearate
The mass ratio of ester and butyl glycol ether is 100:33.5.
Embodiment 6
In the present embodiment, the preparation of Glass cleaner compositions is carried out according to proportioning below:Including 12 in terms of mass parts
0.75 part of sodium alkyl benzene sulfonate, 2.25 parts of polyol-based non-ionic surfactant, 6 parts of ethylene glycol n-butyl ether, disodium hydrogen phosphate
0.7 part, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, 100 parts of water, and polyalcohol
Type nonionic surfactant is the mixture of glycerin monostearate and butyl glycol ether, and the glycerol monostearate
The mass ratio of ester and butyl glycol ether is 100:70.
One, the cleaning performance contrast test of embodiment 1-6
In this experiment, experiment below is carried out in a clothing factory of the applicant local:
Test site 1:Workshop is 450 square metres of steel frame construction continuous space, and side is provided with exhaust blower.In workshop
15 industrial large-sized washing machines are provided with, and carry out the water washing operations of utility uniform.Indoor temperature is 15 degrees Celsius, and humidity is
70-75%.Outdoor temperature is 22 degrees Celsius, humidity 25-40%.8 blocks of glass have been selected on the non-solar direct projection face in the workshop
Region is cleaned respectively.
Test site 2:Workshop is 300 square metres of steel frame construction continuous space, and side is provided with exhaust blower.Vehicle
Interior to be provided with clothing dryer, indoor temperature is 35 degrees Celsius, humidity 80-85%.Outdoor temperature is 22 degrees Celsius, humidity
For 25-40%.8 pieces of glassy zones have been selected to be cleaned respectively respectively on three sides in the workshop.
All glassy zones are the glassy zone that broken-bridge aluminum alloy window frame is surrounded, and not direct by sun institute
Irradiation, is not directly blown onto by workshop fan, also has 5 meters or more of distance apart from exhaust blower(Specifically, it is not located at exhaust blower
On same face wall).
The cleaning condition of glass is as follows:
Method X1:(1)Glass surface to be cleaned is sprayed using clear water;(2)By Glass cleaner compositions according to 18 grams/square
The amount of rice is uniformly applied to glass surface, and using hairbrush brush 5.5 minutes;(3)The glass surface that step 2 is obtained
It is sprayed using clear water, washes away the Glass cleaner compositions on surface;(4)The glass is dried up using 75 degrees Celsius of hot winds.
Method X2:(1)Glass surface to be cleaned is sprayed using clear water;(2)Without using Glass cleaner compositions, simply
Scrub 5.5 minutes;(3)The glass surface that step 2 obtains is sprayed using clear water;(4)Using 75 degrees Celsius of hot winds by the glass
Glass dries up.
Method X3:(1)Glass surface to be cleaned is sprayed using clear water;(2)By Glass cleaner compositions according to 18 grams/
Square metre amount be uniformly applied to glass surface, and using hairbrush brush 5.5 minutes;(3)The glass that step 2 is obtained
Surface is sprayed using clear water, washes away the Glass cleaner compositions on surface;(4)Glass wiping is done.
Above cleaning includes all being cleaned to glass inner side and outside.
The cleaning of each glassy zone is carried out according to the method described in table 1.
Table 1:The cleaning condition of each glassy zone
| Glassy zone | Test site | Composition | Cleaning method |
| 1 | 1 | Embodiment 1 | X1 |
| 2 | 1 | Embodiment 2 | X1 |
| 3 | 1 | Embodiment 3 | X1 |
| 4 | 1 | Embodiment 4 | X1 |
| 5 | 1 | Embodiment 5 | X1 |
| 6 | 1 | Embodiment 6 | X1 |
| 7 | 1 | ---- | X2 |
| 8 | 1 | Embodiment 5 | X3 |
| 9 | 2 | Embodiment 1 | X1 |
| 10 | 2 | Embodiment 2 | X1 |
| 11 | 2 | Embodiment 3 | X1 |
| 12 | 2 | Embodiment 4 | X1 |
| 13 | 2 | Embodiment 5 | X1 |
| 14 | 2 | Embodiment 6 | X1 |
| 15 | 2 | ---- | X2 |
| 16 | 2 | Embodiment 5 | X3 |
That is, being carried out cleaning compositions the method according to the invention of a 1-6 respectively under each test site
Cleaner assay, and carried out clear water cleaning control, and the final control that do not dry.
After the 16 blocks of above glass are cleaned respectively, the finish of glass is carried out respectively as follows
Judge:
(1)After cleaning finishes, under conditions of keeping indoor temperature and humidity, after 10 minutes, 4 hours and 12 hours
Observe whether each glass at edge apparent condensation vapor phenomenon occurs respectively.
If each glass any condensation vapor does not occur in edge, it is recorded as 0 point.
If it is the slight condensation vapor phenomenon within 3 centimetres that each glass width occurs in edge, it is recorded as 1
Point.
If there is the severe condensation vapor phenomenon that width is 3 centimetres or more in edge in each glass, but does not have
There is steam and flow down phenomenon, is recorded as 2 points.
If the condensed water and current mark of big drop occurs in each glass, it is recorded as 3 points.
The condensation vapor phenomenon of each test site is had recorded in table 2:
Table 2:The condensation vapor phenomenon of each test site
| Glassy zone | 10 minutes | 4 hours | 12 hours |
| 1 | 0 | 0 | 1 |
| 2 | 0 | 1 | 1 |
| 3 | 0 | 1 | 1 |
| 4 | 0 | 0 | 0 |
| 5 | 0 | 0 | 0 |
| 6 | 0 | 1 | 1 |
| 7 | 1 | 2 | 2 |
| 8 | 0 | 1 | 2 |
| 9 | 0 | 0 | 1 |
| 10 | 0 | 1 | 1 |
| 11 | 0 | 1 | 1 |
| 12 | 0 | 0 | 0 |
| 13 | 0 | 0 | 1 |
| 14 | 0 | 1 | 1 |
| 15 | 2 | 3 | 3 |
| 16 | 1 | 2 | 2 |
Conclusion below can be obtained from above each group experiment:
For test site 1(Room temperature, higher humidity):
(1)Glassy zone 1 uses the scheme of embodiment 1, that is, the cleaning compositions using glycerin monostearate.It can see
Into the test group, surface is maintained in a long time without product mist, occurs less glass water mist after 12 hours.
(2)Butyl glycol ether is used in glassy zone 2-3, as a result, surface area mist is shifted to an earlier date, but it is basic always
On maintain less product mist phenomenon.
(3)Compound nonionic surfactant has been used in glassy zone 4-5, it can be seen that its product mist phenomenon is minimum,
Effect is kept to be preferably also.
(4)Compound nonionic surfactant used in glassy zone 6 has the ratio beyond limitation, it can be seen that
The effect of its product fog effect is similar with embodiment 1, compound nonionic surfactant is not embodied substantially.
(5)Glassy zone 7 has only used clear water to be cleaned, hence it is evident that and it is visible to begin to long-pending mist occur quickly, do not have completely
There is the effect on protective glass surface.
(6)Difference lies in do not dried finally for glassy zone 8 and embodiment 5.The result shows that baking step
Exempt so that fogging shifts to an earlier date, and final fogging effect becomes heavier.
For test site 2(High temperature, high humidity)
(1)Glassy zone 9-11 corresponds respectively to embodiment 1-3, all realizes preferable glass and hazes and delays effect, wherein in fact
The effect for applying example 1 is better.
(2)Glass in glassy zone 12-13, which hazes, delays effect best.This demonstrate complex compositions to play centainly
The effect of.And the effect in glassy zone 14 shows that ratio is critically important, inappropriate ratio has been difficult to realize fog effect
Delay.
(3)Glassy zone 15, that is, clear water cleaning area do not have any protection effect.
(4)Also occurs the serious phenomenon that hazes in glassy zone 16, that is, the region of non-drying quickly.
Two, the dust accumulation effect observation after cleaning experiment
After completing above experiment, glassy zone 1-16 is observed respectively after 72 hours, it was found that following
The phenomenon that:The outer surface of glass is observed, and comes cleaning glass window surface using clean paper handkerchief.It was found that glassy zone 7 and 15
Outside has all had accumulated a large amount of dust, and has apparent black dust on paper handkerchief.And other each group glass outer sides accumulate
Dust it is obviously less.
Claims (8)
1. a kind of Glass cleaner compositions, it is characterised in that:The Glass cleaner compositions are uniformly mixed suspension, and
And in terms of mass parts including 0.5-1 parts of anionic surfactant, 2-2.5 parts of polyol-based non-ionic surfactant,
4-8 parts of ethylene glycol n-butyl ether, 0.6-1.0 parts of disodium hydrogen phosphate, 2.5-10 parts of ammonium citrate, 1.2-1.5 parts of kaolin, second
15-20 parts of alcohol, 0.7-1 parts of isopropanol, 100 parts of water.
2. a kind of Glass cleaner compositions according to claim 1, it is characterised in that:The anionic surface activity
Agent is neopelex.
3. a kind of Glass cleaner compositions according to claim 1, it is characterised in that:The polyol type nonionic table
Face activating agent is selected from glycol ester, glycerine ester, polyglycerol ester, sorbitan ester, ethoxyquin derivative, ethoxyquin nonyl
Base phenol.
4. a kind of Glass cleaner compositions according to claim 1, it is characterised in that:The polyol type nonionic table
Face activating agent is glycerin monostearate or butyl glycol ether.
5. a kind of Glass cleaner compositions according to claim 1, it is characterised in that:The polyol type nonionic table
Face activating agent is the mixture of glycerin monostearate and butyl glycol ether, and the glycerin monostearate and ethylene glycol
The mass ratio of butyl ether is 100: 20-40.
6. a kind of Glass cleaner compositions according to claim 1, it is characterised in that:The Glass cleaner compositions choosing
From:(1)Including 0.75 part of neopelex, 2.25 parts of polyol-based non-ionic surfactant, second in terms of mass parts
6 parts of glycol n-butyl ether, 0.7 part of disodium hydrogen phosphate, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, 18 parts of ethyl alcohol, isopropanol
0.85 part, 100 parts of water, and polyol-based non-ionic surfactant is glycerin monostearate;(2)It is wrapped in terms of mass parts
It includes, 0.85 part of neopelex, 2 parts of polyol-based non-ionic surfactant, 8 parts of ethylene glycol n-butyl ether, phosphoric acid
0.6 part of disodium hydrogen, 10 parts of ammonium citrate, 1.2 parts of kaolin, 15 parts of ethyl alcohol, 1 part of isopropanol, 100 parts of water, and it is polynary
Alcohol type nonionic surfactant is butyl glycol ether;(3)Including, 0.75 part of neopelex, more in terms of mass parts
2.25 parts of first alcohol type nonionic surfactant, 6 parts of ethylene glycol n-butyl ether, 0.7 part of disodium hydrogen phosphate, ammonium citrate 6.5
Part, 1.4 parts of kaolin, 18 parts of ethyl alcohol, 0.85 part of isopropanol, 100 parts of water, and polyol-based non-ionic surfactant
It is the mixture of glycerin monostearate and butyl glycol ether, and the matter of the glycerin monostearate and butyl glycol ether
Amount is than being 100: 30-35;(4)Including 0.75 part of neopelex, polyol type non-ionic surface in terms of mass parts
2.25 parts of activating agent, 6 parts of ethylene glycol n-butyl ether, 0.7 part of disodium hydrogen phosphate, 6.5 parts of ammonium citrate, 1.4 parts of kaolin, second
18 parts of alcohol, 0.85 part of isopropanol, 100 parts of water, and polyol-based non-ionic surfactant be glycerin monostearate and
The mixture of butyl glycol ether, and the mass ratio of the glycerin monostearate and butyl glycol ether is 100: 33.5.
7. a kind of cleaning glass method, it is characterised in that:The method includes step:(1)Glass surface to be cleaned is made
It is sprayed with clear water;(2)By the Glass cleaner compositions described in any one of claim 1-6 according to 10-25 grams/m of amount
It is uniformly applied to glass surface, and using hairbrush brush 3-10 minutes;(3)The glass surface that step 2 is obtained uses
Clear water sprays, and washes away the Glass cleaner compositions on surface;(4)The glass is dried up using 60-80 degrees Celsius of hot wind.
8. a kind of cleaning glass method according to claim 7, it is characterised in that:It will be previously described in step (2)
Glass cleaner compositions are uniformly applied to glass surface according to 16-20 grams/m of amount, and carry out brushing 5- using hairbrush
6 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810634625.1A CN108690746A (en) | 2018-06-20 | 2018-06-20 | A kind of Glass cleaner compositions and cleaning glass method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810634625.1A CN108690746A (en) | 2018-06-20 | 2018-06-20 | A kind of Glass cleaner compositions and cleaning glass method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108690746A true CN108690746A (en) | 2018-10-23 |
Family
ID=63848447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810634625.1A Pending CN108690746A (en) | 2018-06-20 | 2018-06-20 | A kind of Glass cleaner compositions and cleaning glass method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108690746A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015517A (en) * | 2021-11-25 | 2022-02-08 | 北京玻名堂玻璃有限公司 | Low-reflection glass cleaning agent for museum showcase and preparation method thereof |
| CN115305159A (en) * | 2022-05-24 | 2022-11-08 | 西安优露清科技股份有限公司 | Hard surface cleaning composition and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1114350A (en) * | 1994-06-29 | 1996-01-03 | 首钢总公司 | General-purpose hard surface detergent |
| CN101255381A (en) * | 2007-02-27 | 2008-09-03 | 3M创新有限公司 | Cleaning method and combination |
| CN101538512A (en) * | 2009-03-11 | 2009-09-23 | 上海九盛实业有限公司 | Water-based cleaner |
| CN101942364A (en) * | 2010-01-15 | 2011-01-12 | 中山榄菊日化实业有限公司 | Cleaning agent composition and preparation method thereof |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
-
2018
- 2018-06-20 CN CN201810634625.1A patent/CN108690746A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1114350A (en) * | 1994-06-29 | 1996-01-03 | 首钢总公司 | General-purpose hard surface detergent |
| CN101255381A (en) * | 2007-02-27 | 2008-09-03 | 3M创新有限公司 | Cleaning method and combination |
| CN101538512A (en) * | 2009-03-11 | 2009-09-23 | 上海九盛实业有限公司 | Water-based cleaner |
| CN101942364A (en) * | 2010-01-15 | 2011-01-12 | 中山榄菊日化实业有限公司 | Cleaning agent composition and preparation method thereof |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陈三斌: "《160种实用化工产品配方与制造》", 30 November 1996, 金盾出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015517A (en) * | 2021-11-25 | 2022-02-08 | 北京玻名堂玻璃有限公司 | Low-reflection glass cleaning agent for museum showcase and preparation method thereof |
| CN114015517B (en) * | 2021-11-25 | 2024-04-05 | 北京玻名堂玻璃有限公司 | Low-reflection glass cleaner for museum showcase and preparation method thereof |
| CN115305159A (en) * | 2022-05-24 | 2022-11-08 | 西安优露清科技股份有限公司 | Hard surface cleaning composition and preparation method thereof |
| CN115305159B (en) * | 2022-05-24 | 2024-05-07 | 西安优露清科技股份有限公司 | Hard surface washing composition and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7547670B2 (en) | Low odor ester-based microemulsions for cleaning hard surfaces | |
| CA2727123C (en) | Hard surface cleaning composition | |
| CN103820228B (en) | A kind of glass cleaner composition | |
| CN103131546A (en) | Cleaning composition | |
| CN107937161A (en) | A kind of concentrated type antifog glass cleaning agent | |
| CN108690746A (en) | A kind of Glass cleaner compositions and cleaning glass method | |
| CN102154068A (en) | Multifunctional detergent and preparation method thereof | |
| CA1231879A (en) | Liquid all-purpose cleaner | |
| CA2007566A1 (en) | Hard surface cleaning composition | |
| AU724432B2 (en) | Rinseable hard surface cleaner | |
| CN104403825A (en) | Glass cleaning agent and preparation method thereof | |
| US11866674B2 (en) | Neutral floor cleaner compositions | |
| CN107937168A (en) | A kind of production method of environment-friendly type degreasing cleaning agent | |
| EP1509587A1 (en) | Cleaning and degreasing premix compositions with low voc | |
| CN103789095A (en) | Glass cleaner composition | |
| CN107574032A (en) | A kind of liquid detergent and preparation method | |
| US20180201880A1 (en) | Cleaning Compositions Comprising at Least One Modified Acrylic Polyamide | |
| CN104017663A (en) | Fabric sofa cleaning agent | |
| CN106835170A (en) | A kind of stainless steel nurses cleaning agent | |
| CN105062717A (en) | Glass window scale remover and preparation method thereof | |
| CN105132202B (en) | Carwash detergent | |
| AU2012370005A1 (en) | Cleaning composition | |
| CN106675819A (en) | Antifogging detergent and preparation method thereof | |
| JPH1025492A (en) | Detergent composition for hard surface | |
| CN105985752A (en) | Fragrant glass anti-fogging cleaning cloth |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181023 |