CN102071115B - Concentration type antifog glass cleaning agent - Google Patents

Concentration type antifog glass cleaning agent Download PDF

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Publication number
CN102071115B
CN102071115B CN 201110024726 CN201110024726A CN102071115B CN 102071115 B CN102071115 B CN 102071115B CN 201110024726 CN201110024726 CN 201110024726 CN 201110024726 A CN201110024726 A CN 201110024726A CN 102071115 B CN102071115 B CN 102071115B
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China
Prior art keywords
parts
surf
antifog glass
glass
ethanol
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CN 201110024726
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Chinese (zh)
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CN102071115A (en
Inventor
姜琳月
周彦林
张文静
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Daily chemical (Jiangsu) Limited by Share Ltd
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BEIJING LUOWA DAILY CHEMICAL Co Ltd
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Priority to CN 201110024726 priority Critical patent/CN102071115B/en
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Abstract

The invention relates to a concentration type antifog glass cleaning agent comprising the following components in parts by weight: 0.1-1 part of ammonia water, 0.1-5 parts of triethanolamine, 1-20 parts of surfactant, 0.1-10 parts of film-forming agent, 1-50 parts of ethanol and 0.1-5 parts of chelant. By using the product of the invention, a thinner and evener water film is formed on the surface of glass, so that drying is faster and the surface is smoother and has no stains and strips; and dirts are prevented from adhering through changing the surface charge, which is effective after many times of water cleanings. The concentration type antifog glass cleaning agent of the invention can still clean the surface of glass after being diluted by 50-100 times, thereby achieving the effects of anti-resoiling, anti-fogging and fast drying.

Description

Concentrated type antifog glass sanitising agent
Technical field
The present invention relates to a kind of glass cleaner, especially a kind of concentrated type antifog glass sanitising agent.
Background technology
Present glass cleaner on the market only has simple cleanup action mostly, does not have condensed prod, does not more have antifog function.Winter is lower because of external temperature, and is bigger with the indoor temperature difference, and the window-glass surface forms fog easily, influences daylighting, makes troubles for people's life; In winter, windshield is also often different because of internal-external temperature difference, humidity, very thin mist film occurs, influences driver's sight line, brings hidden danger to traffic; When people washed one's face and rinsed one's mouth in the bathroom, the washing mirror in the bathroom also formed the mist film later easily in bathing, temporarily can't use ... The wait factor brings inconvenience for people's life.
Moreover mostly commercially available glass cleaner is coventional type, and content all is water more than 90%; Wasted the large-tonnage product packing; Increased transportation cost, the factors such as useless circulation of production link tap water do not meet the low-carbon economy that country advocates; In sum, develop the glass cleaner that a kind of high power concentrated, had antifogging action and become a kind of trend.
Summary of the invention
The purpose of this invention is to provide a kind of concentrated type antifog glass sanitising agent, its effectively decontamination, antifog makes the glass surface smooth.
Concentrated type antifog glass sanitising agent of the present invention, its component and mass fraction thereof are:
Ammoniacal liquor 0.1-1 part
Trolamine 0.1-5 part
Membrane-forming agent 0.1-10 part
Sequestrant 0.1-5 part
Tensio-active agent 1-20 part
Ethanol 1-50 part.
As required, can also contain deionized water 9-97.6 part.
Preferably, above-mentioned membrane-forming agent is selected from least a among Surf-s110, the Surf-s210.Surf-s is a kind of functional polymer additive of uniqueness; The net effect that it can give moisture film effect and anti-flushing obtains long-acting persistent cleaning power; Can give controllable, persistent surface-treated; Not only promote the initial outward appearance on surface, and reduced adhering to and making that cleaning is easier of dirt.
Preferably, above-mentioned tensio-active agent is selected from polyoxyethylenated alcohol sodium sulfate, SAS, AEO, at least a in empgen BB (BS-12), the amine oxide.
Preferably, above-mentioned sequestrant is selected from least a in YD 30, the disodium edta.
It is understandable that glass cleaner of the present invention can add some ancillary components commonly used, for example essence or spices, pigment etc. as required.
Characteristics of the present invention are the application of membrane-forming agent; Its its specific structure makes it have good hydrophilicity; Form the bright film of one deck at glass surface when cleaning; Given glass surface a lot of good performances: to prevent that glass from polluting once more, antifog, fast doing, make the glass surface hydrophilicity better.The content of this membrane-forming agent is better effects if between 0.5 part to 10 parts.
Concentrated type antifog glass sanitising agent of the present invention has multi-efficiency, can form one deck shiny film at glass surface, give the anti-recontaminate of glass surface, hydrophilic, fast dried, antifog and wash after the excellent properties that leaves no trace.
Embodiment
Illustrate in greater detail concentrated type antifog glass sanitising agent of the present invention through embodiment below.
Embodiment 1
A kind of concentrated type antifog glass sanitising agent, its component and mass fraction thereof are:
0.5 part of ammoniacal liquor
8 parts of Surf-s110
3 parts of EDTA Disodiums (EDTA-2Na)
Fatty Alcohol(C12-C14 and C12-C18) (C 12-16) 2 parts in T 46155 (9) ether (AEO-9)
5 parts of amine oxides
6 parts of polyoxyethylenated alcohol sodium sulfate
45 parts of ethanol
0.5 part in essence
0.1 part of light blue pigment (1% aqueous solution)
29.9 parts of deionized waters
Aliphatic alcohol polyethenoxy (9) ether (AEO-9), ammonium oxide, polyoxyethylenated alcohol sodium sulfate are tensio-active agent; Ethanol is solvent; Surf-s110 is a membrane-forming agent, and available from Guangdong Xin Tu Fine Chemical Co., Ltd, EDTA Disodium (EDTA-2Na) is a sequestrant.
The preparation method of the concentrated type antifog glass sanitising agent of embodiment 1 is following:
1. add 45 parts of the ethanol measure; Add 2 parts in aliphatic alcohol polyethenoxy (9) ether (AEO-9), 5 parts of amine oxides, 6 parts of polyoxyethylenated alcohol sodium sulfate, 8 parts of Surf-s110 then, stir and make its dissolving;
2. add 29.9 parts of deionized waters, 0.5 part of ammoniacal liquor, 3 parts of EDTA-2Na, 0.5 part in essence, 0.1 part of light blue pigment (1% aqueous solution), stir and make it dissolving.
3. filtering the back with 300 mesh filter screens packs.
Embodiment 2
According to the preparation method same with embodiment 1, preparation has the concentrated type antifog glass sanitising agent of following main active component and mass fraction:
1 part of ammoniacal liquor
8 parts of Surf-s210
2 parts of EDTA Disodiums (EDTA-2Na)
Fatty Alcohol(C12-C14 and C12-C18) (C 12-16) 5 parts in T 46155 (9) ether (AEO-9)
7 parts of SASs
8 parts of empgen BBs (BS-12)
35 parts of ethanol
0.1 part in essence
Lemon yellow (1% aqueous solution) 0.1 part
33.8 parts of deionized waters
Aliphatic alcohol polyethenoxy (9) ether (AEO-9), SAS, empgen BB (BS-12) are tensio-active agent; Ethanol is solvent; Surf-s210 is a membrane-forming agent, and available from Guangdong Xin Tu Fine Chemical Co., Ltd, EDTA Disodium (EDTA-2Na) is a sequestrant.
Embodiment 3
According to the preparation method same with embodiment 1, preparation has the concentrated type antifog glass sanitising agent of following main active component and mass fraction:
0.2 part of ammoniacal liquor
3 parts of trolamines
3 parts of Surf-s110
5 parts of Surf-s210
2 parts of EDTA Disodiums (EDTA-2Na)
Fatty Alcohol(C12-C14 and C12-C18) (C 12-14) 5 parts of polyethenoxy ether sodium sulfates (AES)
3 parts of ammonium oxide
4 parts of empgen BBs (BS-12)
45 parts of ethanol
0.5 part in essence
0.2 part of light green pigment (1% aqueous solution)
29.1 parts of deionized waters
Polyoxyethylenated alcohol sodium sulfate (AES), ammonium oxide, empgen BB (BS-12) are tensio-active agent; Ethanol is solvent; Surf-s110, Surf-s210 are membrane-forming agent; Available from Guangdong Xin Tu Fine Chemical Co., Ltd, EDTA Disodium (EDTA-2Na) is a sequestrant.
The result of use evaluation of concentrated type antifog glass sanitising agent
The concentrated type antifog glass sanitising agent for preparing among the embodiment 1-3 is respectively applied for windshield, bathroom washing mirror, house glass, has obtained following ideal effect:
Behind 50 times of the dilute with waters, be used for windshield winter, the anti-fog effect continuous and effective time: more than 15 days;
Behind 80 times of the dilute with waters, just be usually used in bathroom washing mirror, the anti-fog effect continuous and effective time: more than 7 days;
Behind 100 times of the dilute with waters, be used for glass cleaning at home winter, the anti-fog effect continuous and effective time: more than 20 days.
The above is merely preferred embodiment of the present invention, is not to be used to limit protection scope of the present invention.One skilled in the art will appreciate that protection scope of the present invention is as the criterion with appending claims.

Claims (2)

1. concentrated type antifog glass sanitising agent, component that comprises and mass fraction thereof are:
0.5 part of ammoniacal liquor
8 parts of Surf-s110
3 parts of EDTA Disodium EDTA-2Na
Fatty Alcohol(C12-C14 and C12-C18) C 12-162 parts of T 46155 (9) ether AEO-9
5 parts of amine oxides
6 parts of polyoxyethylenated alcohol sodium sulfate
45 parts of ethanol
0.5 part in essence
0.1 part of light blue pigment 1% aqueous solution
29.9 parts of deionized waters.
2. concentrated type antifog glass sanitising agent, component that comprises and mass fraction thereof are:
1 part of ammoniacal liquor
8 parts of Surf-s210
2 parts of EDTA Disodium EDTA-2Na
Fatty Alcohol(C12-C14 and C12-C18) C 12-165 parts of T 46155 (9) ether AEO-9
7 parts of SASs
8 parts of empgen BB BS-12
35 parts of ethanol
0.1 part in essence
0.1 part of lemon yellow 1% aqueous solution
33.8 parts of deionized waters.
3. concentrated type antifog glass sanitising agent, component that comprises and mass fraction thereof are:
0.2 part of ammoniacal liquor
3 parts of trolamines
3 parts of Surf-s110
5 parts of Surf-s210
2 parts of EDTA Disodium EDTA-2Na
Fatty Alcohol(C12-C14 and C12-C18) C 12-145 parts of polyethenoxy ether sodium sulfate AES
3 parts of ammonium oxide
4 parts of empgen BB BS-12
45 parts of ethanol
0.5 part in essence
0.2 part of light green pigment 1% aqueous solution
29.1 parts of deionized waters.
CN 201110024726 2011-01-24 2011-01-24 Concentration type antifog glass cleaning agent Active CN102071115B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201110024726 CN102071115B (en) 2011-01-24 2011-01-24 Concentration type antifog glass cleaning agent

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CN102071115A CN102071115A (en) 2011-05-25
CN102071115B true CN102071115B (en) 2012-12-26

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104845750A (en) * 2015-05-05 2015-08-19 柳州立洁科技有限公司 Anti-fog glass cleaner
CN105695134A (en) * 2016-03-04 2016-06-22 苏州圣谱拉新材料科技有限公司 Glass cleaning agent with antifogging function

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CN102503154B (en) * 2011-10-20 2013-09-11 华阳新兴科技(天津)集团有限公司 Optical glass paint remover and preparation method thereof
CN102864050A (en) * 2012-09-06 2013-01-09 南通华豪巨电子科技有限公司 Automobile anti-fog glass cleaner
CN103865698A (en) * 2012-12-11 2014-06-18 董方民 Multi-surface cleaning agent
CN103060138A (en) * 2013-01-07 2013-04-24 北京洛娃日化有限公司 Automotive glass-washing fluid
CN103396897B (en) * 2013-08-06 2014-12-31 张家港迪克汽车化学品有限公司 Automobile wind window washing liquid
CN103709994B (en) * 2013-12-04 2015-09-16 宁波保税区安德利斯机械有限公司 The agent of a kind of low temperature modification removing fog on automobile glass
CN103602314B (en) * 2013-12-04 2015-09-16 宁波保税区安德利斯机械有限公司 The agent of a kind of normal temperature type removing fog on automobile glass
CN103865676A (en) * 2014-02-13 2014-06-18 上海方木精细化工有限公司 Concentrated liquid detergent
CN106609193A (en) * 2015-10-21 2017-05-03 中国石油化工股份有限公司 Vehicle headlamp cleaning agent
CN105296169A (en) * 2015-12-02 2016-02-03 苏州龙腾万里化工科技有限公司 Efficient decontamination glass cleaner
CN105733843B (en) * 2016-04-25 2018-08-10 河南城建学院 A kind of cleaning glass antifoggant and preparation method thereof
CN105950309A (en) * 2016-05-13 2016-09-21 宁波市乾东网络科技有限公司 Cleaning agent for automotive body and preparation method of cleaning agent
CN106350290A (en) * 2016-08-23 2017-01-25 余姚市德派日用品有限公司 Concentrated glass cleaning product and preparation method thereof
CN106318658A (en) * 2016-08-25 2017-01-11 董晓 Preparing method for anti-recontamination glass cleaning agent
CN106590959B (en) * 2016-11-27 2018-10-12 湖南金裕化工有限公司 A kind of glass lens cleaning agent and preparation method thereof
CN106701341A (en) * 2016-11-29 2017-05-24 枞阳县铭瑞电子科技有限公司 Glass washing solution
CN107022342A (en) * 2017-05-31 2017-08-08 江苏精盾节能科技有限公司 A kind of glass antidimmer and preparation method thereof
CN107446719A (en) * 2017-08-25 2017-12-08 中山市优贝科技股份有限公司 Car surface cleaning agent and preparation method thereof
CN107937161A (en) * 2017-10-26 2018-04-20 上海发凯化工有限公司 A kind of concentrated type antifog glass cleaning agent
CN108165377A (en) * 2017-12-24 2018-06-15 洛阳名力科技开发有限公司 Concentrate rain brush essence
CN108728265A (en) * 2018-06-30 2018-11-02 江南大学 A kind of ultra-clean agent and preparation method
CN109135673A (en) * 2018-08-24 2019-01-04 广州番禺职业技术学院 A kind of formula and its application method of lens antifogging spray
CN110066639A (en) * 2019-04-17 2019-07-30 上海和黄白猫有限公司 A kind of anti-scratch type glass antidimmer and preparation method thereof
CN113046196A (en) * 2019-12-27 2021-06-29 张家港迪克汽车化学品有限公司 Solid cleaning liquid concentrating agent and preparation method and application thereof

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN104845750A (en) * 2015-05-05 2015-08-19 柳州立洁科技有限公司 Anti-fog glass cleaner
CN105695134A (en) * 2016-03-04 2016-06-22 苏州圣谱拉新材料科技有限公司 Glass cleaning agent with antifogging function

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Effective date of registration: 20151229

Address after: 226400, Jiangsu County, Rudong Province Economic Development Zone on the north side of Jialing River Road, Mount Lu Road West

Patentee after: Panxi (Jiangsu) Biological Technology Co., Ltd.

Address before: 100102 Beijing city Chaoyang District Wangjing 2 District No. 203 Lize Park

Patentee before: Beijing Luowa Daily Chemical Co., Ltd.

C56 Change in the name or address of the patentee
CP01 Change in the name or title of a patent holder

Address after: 226400, Jiangsu County, Rudong Province Economic Development Zone on the north side of Jialing River Road, Mount Lu Road West

Patentee after: The biological Polytron Technologies Inc of Jiangsu

Address before: 226400, Jiangsu County, Rudong Province Economic Development Zone on the north side of Jialing River Road, Mount Lu Road West

Patentee before: Panxi (Jiangsu) Biological Technology Co., Ltd.

CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 216400 Rudong Economic Development Zone, Rudong County, Jiangsu City, Nantong Province, on the north side of Jialing River Road and on the west side of Mount Lu Road

Patentee after: Daily chemical (Jiangsu) Limited by Share Ltd

Address before: 226400, Jiangsu County, Rudong Province Economic Development Zone on the north side of Jialing River Road, Mount Lu Road West

Patentee before: The biological Polytron Technologies Inc of Jiangsu