CN103602314B - The agent of a kind of normal temperature type removing fog on automobile glass - Google Patents
The agent of a kind of normal temperature type removing fog on automobile glass Download PDFInfo
- Publication number
- CN103602314B CN103602314B CN201310646271.XA CN201310646271A CN103602314B CN 103602314 B CN103602314 B CN 103602314B CN 201310646271 A CN201310646271 A CN 201310646271A CN 103602314 B CN103602314 B CN 103602314B
- Authority
- CN
- China
- Prior art keywords
- agent
- normal temperature
- temperature type
- automobile glass
- automobile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 title claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000013543 active substance Substances 0.000 claims abstract description 8
- 239000013530 defoamer Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000002608 ionic liquid Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical group O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 8
- 238000010257 thawing Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 239000005416 organic matter Substances 0.000 abstract description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- 238000010907 mechanical stirring Methods 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000004378 air conditioning Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The agent of a kind of normal temperature type removing fog on automobile glass, be applicable to the demist of windscreen and side mirror before and after automobile, defrosting, it is characterized in that, the agent of described normal temperature type removing fog on automobile glass is obtained by the raw material mix and blend of following weight percent: tensio-active agent 0.02-0.05wt%; Membrane-forming agent 0.01 ~ 0.02wt%; Defoamer 0.001 ~ 0.002wt%; Surplus is thinner; Wherein, described tensio-active agent is CH
3o(CH
3cH
2cH
2o)
n(CH
2cH
2o)
mcH
3o type nonionogenic tenside, wherein n=2 ~ 6, m=5 ~ 10.Compared with prior art, demist effect active of the present invention, lasting, environmental friendliness, do not use any volatile organic matter, harmless to the driver and crew in wheel house.
Description
Technical field
The present invention relates to the agent of a kind of normal temperature type removing fog on automobile glass, be applicable to the demist of windscreen and side mirror before and after automobile, defrosting, environment for use of the present invention is that temperature is greater than-10 DEG C.
Background technology
Time overcast and rainy, after all glass of closing automobile, people there will be much water smoke more, causes this is because the low vehicle interior temperature of temperature outside car is high.Physical principle is exactly have a large amount of water vapour in car, is liquefied as little water droplet when these water vapour run into cold car glass.It cyclostrophic is cold, is placed on the little water droplet always having one deck outside outdoor automobile, and Here it is reveals.This is because the liquefaction when night runs into temperature low automobile of water vapour in air.Time colder to winter, car also can tie the thin frost of one deck outward.Because the thickness of cab windshield is subject to certain restrictions to a certain extent, can not accomplish not only thick but also transparent.So its heat retaining property is low, conductivity is but very high.Therefore, in the winter time caused by steam cooling is condensed in near-earth gas-bearing formation, make a large amount of moisture convergence suspended in wheel house on the glass of low temperature, produce one deck ambiguous vaporific.Along with the continuous decline of temperature, windshield glass also can form thin layer ice crystal.The Working environment that visibility meter is very low, brings certain difficulty to officer's operation.The generation of these situations all can be serious affect traffic safety.
Present automobile all must enforce national demist, defrost system standard.Standard mainly adopts the air-conditioning system time of blowing down to make regulation to automobile.But the time of going the demist of unlatching air-conditioning often to have 1 ~ 2 minute once by the time haze again is delayed, if travel at motorway or in densely populated urban district, can cause very large potential safety hazard.So, before hazing, a directly selection of numerous car owners is often become at front-rear windshield glass spraying antifogging agent.
At present, the high-end market of China's windshield demisting agent mostly is import product and occupies, and low-end market exists situation of manufacturing in a rough and slipshod way, and more has numerous officers directly to add tap water in the glass cleaner retention tank of automobile.Life-time service tap water or bad windshield demisting agent processed will cause cleaning performance poor, the generation of the situation such as the swelling damage of windshield corrosion damage, wiper rubber, metal parts burn into automobile finish also can be caused stained, also can affect pilot's line of vision and cause traffic accident time serious.
Chinese patent (application number 90105353.8) discloses a kind of antifogging and antifrosting agent on automobile wind shield glass, is mixed by ethylene glycol, propylene glycol, water and butane.The proportioning of temperature ethylene glycol and propylene glycol-10 to-45 DEG C time, selects from the scope of 10: 1 to 3.44: 1, and the proportioning range of choice of total alcohol amount and water is 5: 4 to 8: 1.The hazardous gas that this invention uses butane inflammable and explosive like this, inherently dangerous environmental protection.In addition, the composition in formula is volatile component, so this demisting agent can only be and limited action time.
Based on present case, need badly research and development a kind of novel existing efficient demist, defrosting ability, again to the automobile specified glass defrosting compound of rubber, glass and metal Wu corrosive nature.
Summary of the invention
The invention provides the agent of a kind of normal temperature type removing fog on automobile glass; adopt and there is no saturated vapor pressure ionic liquid as the critical function integral part of removing fog on automobile glass agent; ionic liquid can form protective film on windscreen-wiper device surface; when rainy, rainwater assembles landing on the windshield, plays again effect of protective glass and rain brush simultaneously.
The technical scheme that the present invention specifically adopts is:
The agent of a kind of normal temperature type removing fog on automobile glass, it is characterized in that, the agent of described normal temperature type removing fog on automobile glass is obtained by the raw material mix and blend of following weight percent:
Tensio-active agent 0.02 ?0.05wt%;
Membrane-forming agent 0.01 ~ 0.02wt%;
Defoamer 0.001 ~ 0.002wt%;
Surplus is thinner;
Wherein, described tensio-active agent is CH
3o(CH
3cH
2cH
2o)
n(CH
2cH
2o)
mcH
3o type nonionogenic tenside, wherein n=2 ~ 6, m=5 ~ 10;
Described membrane-forming agent is ionic liquid, and its chemical structure is:
wherein n=20;
Described thinner is ethanol and the deionized water mixture according to weight ratio 1:6 ~ 9.
The mode of operation that the present invention is applicable to is spraying or rag wiping.
Compared with prior art, beneficial effect of the present invention is:
1, demist effect initiatively, lastingly.Evenly be coated in inside front-rear windshield glass and after side mirror and can play demist effect, and it is lasting to remove fog effect.
2, environmental friendliness, does not use any volatile organic matter, harmless to the driver and crew in wheel house.
Embodiment
To describe more comprehensively the present invention below by more preferably concrete case study on implementation:
Embodiment 1
Insert mechanical stirring successively at 2000ml, in the there-necked flask of thermometer and reflux condensing tube, add tensio-active agent CH successively
3o(CH
3cH
2cH
2o)
n(CH
2cH
2o)
mcH
3o, (n=6, m=5), 50g, ionic liquid 20g, defoamer cyclotetrasiloxane 2g, thinner alcohol 200g, thinner deionized water 1650g.Then mechanical stirring 30 minutes.Mixing liquid in four-hole boiling flask is poured in 2000ml ground wide-necked bottle and namely obtain demisting agent of the present invention.Wherein, ionic liquid chemical formula is:
This demisting agent can be loaded in Dey-Dose before using, also it evenly can be coated on textile rag.Before detecting, it is evenly coated in glass surface.
Product pH value adopts accurate pH test paper to detect, and swell rubber adopts GB GB/T14832 to detect, and corrosion adopts GB GB/T11143 to detect, and demist effect assessment adopts: remaining trace, striped are residual, light, anti-soil four grades carry out Comprehensive Assessment.Detected result is as follows:
Embodiment 2
Insert mechanical stirring successively at 2000ml, in the there-necked flask of thermometer and reflux condensing tube, add tensio-active agent CH successively
3o(CH
3cH
2cH
2o)
n(CH
2cH
2o)
mcH
3o, (n=6, m=10), 80g, ionic liquid 25g, defoamer cyclotetrasiloxane 4g, thinner alcohol 180g, thinner deionized water 1700g.Then mechanical stirring 30 minutes.Mixing liquid in four-hole boiling flask is poured in 2000ml ground wide-necked bottle, stir and obtain demisting agent of the present invention.Wherein, the chemical formula of ionic liquid is:
This demisting agent can be loaded in Dey-Dose before using, also it evenly can be coated on textile rag.Before detecting, it is evenly coated in glass surface.
Product pH value adopts accurate pH test paper to detect, and swell rubber adopts GB GB/T14832 to detect, and corrosion adopts GB GB/T11143 to detect, and demist effect assessment adopts: remaining trace, striped are residual, light, anti-soil four grades carry out Comprehensive Assessment.Detected result is as follows:
| Test item | |
| PH value | 7.2 |
| Weather resistance | More than one month |
| Swell rubber | ＜4% |
| Corrodibility | Rustless |
| Except fog effect | Outstanding |
Claims (1)
1. the agent of normal temperature type removing fog on automobile glass, is characterized in that, the agent of described normal temperature type removing fog on automobile glass is obtained by the raw material mix and blend of following weight percent:
Tensio-active agent 0.02-0.05wt%;
Membrane-forming agent 0.01 ~ 0.02wt%;
Defoamer 0.001 ~ 0.002wt%;
Surplus is thinner;
Wherein, described tensio-active agent is CH
3o (CH
3cH
2cH
2o)
n(CH
2cH
2o)
mcH
3o type nonionogenic tenside, wherein n=2 ~ 6, m=5 ~ 10;
Described membrane-forming agent is ionic liquid, and its chemical structure is:
wherein n=20;
Described thinner is ethanol and the deionized water mixture according to weight ratio 1:6 ~ 9;
Described defoamer is cyclotetrasiloxane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310646271.XA CN103602314B (en) | 2013-12-04 | 2013-12-04 | The agent of a kind of normal temperature type removing fog on automobile glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310646271.XA CN103602314B (en) | 2013-12-04 | 2013-12-04 | The agent of a kind of normal temperature type removing fog on automobile glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103602314A CN103602314A (en) | 2014-02-26 |
| CN103602314B true CN103602314B (en) | 2015-09-16 |
Family
ID=50120585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310646271.XA Expired - Fee Related CN103602314B (en) | 2013-12-04 | 2013-12-04 | The agent of a kind of normal temperature type removing fog on automobile glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103602314B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4214908A (en) * | 1976-11-08 | 1980-07-29 | Kao Soap Co., Ltd. | Durable anti-fogging composition |
| JP2003034783A (en) * | 2001-07-25 | 2003-02-07 | Koei Chem Co Ltd | Anti-fogging agent and anti-fogging molding product using the same |
| JP2003238207A (en) * | 2002-02-20 | 2003-08-27 | Matsushita Electric Works Ltd | Anti-fogging article and method of manufacturing the same |
| CN101220257A (en) * | 2007-01-09 | 2008-07-16 | 青岛大学 | Process for producing vehicle glass antifogging agent |
| CN101768425A (en) * | 2009-01-07 | 2010-07-07 | 吴建新 | Antifogging agent for glasses |
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
| CN102703029A (en) * | 2012-06-18 | 2012-10-03 | 桑达化工（南通）有限公司 | Antifogging agent for glass |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6923997B2 (en) * | 2003-03-04 | 2005-08-02 | Pactiv Corporation | Antifogging compositions and methods for using the same |
-
2013
- 2013-12-04 CN CN201310646271.XA patent/CN103602314B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4214908A (en) * | 1976-11-08 | 1980-07-29 | Kao Soap Co., Ltd. | Durable anti-fogging composition |
| JP2003034783A (en) * | 2001-07-25 | 2003-02-07 | Koei Chem Co Ltd | Anti-fogging agent and anti-fogging molding product using the same |
| JP2003238207A (en) * | 2002-02-20 | 2003-08-27 | Matsushita Electric Works Ltd | Anti-fogging article and method of manufacturing the same |
| CN101220257A (en) * | 2007-01-09 | 2008-07-16 | 青岛大学 | Process for producing vehicle glass antifogging agent |
| CN101768425A (en) * | 2009-01-07 | 2010-07-07 | 吴建新 | Antifogging agent for glasses |
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
| CN102703029A (en) * | 2012-06-18 | 2012-10-03 | 桑达化工（南通）有限公司 | Antifogging agent for glass |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103602314A (en) | 2014-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5772912A (en) | Environmentally friendly anti-icing | |
| CN102329597B (en) | Novel airplane de-icing/anti-icing liquid and preparation method thereof | |
| WO1996023043A9 (en) | Anti-icing fluid or deicing fluid | |
| CN107686278B (en) | Anti-freezing material based on temperature regulation and control, and preparation method and application thereof | |
| CN103468213A (en) | Preparation methods of antifog composition and antifog automobile glass | |
| US20030116748A1 (en) | Environmentally friendly compositions having anti-icing, deicing or graffiti prevention properties | |
| CN103709994B (en) | The agent of a kind of low temperature modification removing fog on automobile glass | |
| CN109627974A (en) | A kind of anticoagulant ice coating of super-hydrophobic bituminous pavement and preparation method thereof | |
| CN103602314B (en) | The agent of a kind of normal temperature type removing fog on automobile glass | |
| CN106833524A (en) | Glass pane antifoggant and preparation method thereof in automobile | |
| WO2000000568A1 (en) | Environmentally friendly compositions having anti-icing, deicing or graffiti prevention properties | |
| CN105861170A (en) | Water expelling type automobile windscreen cleaning agent and preparation method | |
| CN103614251B (en) | Automobile glass detergent for removing stubborn dirt | |
| US20030098438A1 (en) | Environmentally friendly compositions having antiicing, deicing or graffiti prevention properties | |
| CN108148552B (en) | Efficient anti-icing and defogging agent and device | |
| CN102994047A (en) | Fog and frost preventing agent for glass | |
| CN106701371A (en) | Environment-friendly and all-purpose windshield washer fluid | |
| Zilioniene et al. | De-icing experience in Lithuania | |
| US20040036054A1 (en) | Environmentally friendly compositions having antiicing, deicing or graffiti prevention properties | |
| Zhang et al. | A new sustainable additive for self-deicing asphalt | |
| CN110394059A (en) | - 25 DEG C of antifreeze urea for vehicle of one kind and preparation method thereof | |
| CN108276961B (en) | A kind of new-energy automobile aerosol | |
| CN110028935A (en) | It is a kind of for the dust suppressant of non-hard surface and its preparation, application method | |
| CN104357014A (en) | Long-acting antifogging agent for car glass | |
| Zhang et al. | A New Sustainable Additive for Anti-Icing Pavement |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: NINGBO BONDED ZONE ANDRIS MACHINERY CO., LTD. Free format text: FORMER OWNER: NINGBO SAINTER TECHNOLOGY SERVICE CO., LTD. Effective date: 20150513 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20150513 Address after: 315800 Zhejiang Province, Ningbo Free Trade Zone Foxconn 530-9 Trade Building Applicant after: Ningbo Free Trade Zone Andris Machinery Co.,Ltd. Address before: 315100 Yinzhou District, Ningbo, South Street, the first emerging industrial park Applicant before: NINGBO SAINTER TECHNOLOGY SERVICE Co.,Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yin Xiangjiang Inventor after: Chen Jingwu Inventor after: Liu Jiyang Inventor before: He Ji |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170316 Address after: 523430 Dongguan City, Liaobu Province town of stone road, stone step, No. 91, No. Patentee after: DONGGUAN FANYA CHEMICAL PRODUCTS Co.,Ltd. Address before: 315800 Zhejiang Province, Ningbo Free Trade Zone Foxconn 530-9 Trade Building Patentee before: Ningbo Free Trade Zone Andris Machinery Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150916 Termination date: 20211204 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |