CN102503154B - Optical glass paint remover and preparation method thereof - Google Patents
Optical glass paint remover and preparation method thereof Download PDFInfo
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- CN102503154B CN102503154B CN 201110319869 CN201110319869A CN102503154B CN 102503154 B CN102503154 B CN 102503154B CN 201110319869 CN201110319869 CN 201110319869 CN 201110319869 A CN201110319869 A CN 201110319869A CN 102503154 B CN102503154 B CN 102503154B
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- remover
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- opticglass
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- paint remover
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000005304 optical glass Substances 0.000 title abstract description 5
- 239000003973 paint Substances 0.000 title abstract 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008139 complexing agent Substances 0.000 claims abstract description 8
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 8
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 10
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- -1 nonenyl succinic acid acid anhydride Chemical class 0.000 claims description 6
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 claims description 5
- 229960004418 trolamine Drugs 0.000 claims description 5
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000001384 succinic acid Substances 0.000 claims description 4
- 229940120146 EDTMP Drugs 0.000 claims description 3
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 3
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims description 2
- KCYQMQGPYWZZNJ-BQYQJAHWSA-N hydron;2-[(e)-oct-1-enyl]butanedioate Chemical compound CCCCCC\C=C\C(C(O)=O)CC(O)=O KCYQMQGPYWZZNJ-BQYQJAHWSA-N 0.000 claims description 2
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940095068 tetradecene Drugs 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 238000002156 mixing Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 3
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910001936 tantalum oxide Inorganic materials 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to an optical glass paint remover and a preparation method of the optical glass paint remover. The paint remover contains, by weight, potassium hydroxide 8% to 14%, surfactant 1% to 4%, complexing agent 4% to 9%, triethanolamine 2.5% to 5%, solvent 4% to 8%, sodium metasilicate pentahydrate 2% to 4%, sodium polyacrylate 2% to 4%, and distilled water in balance. The preparation method comprises dissolving potassium hydroxide and sodium metasilicate pentahydrate in distilled water; adding surfactant and complexing agent for reaction; adding triethanolamine and solvent; adding sodium polyacrylate; and blending. The paint remover prepared by the invention is green and nontoxic, and has good paint removing effect, no corrosion to lenses and no residues. The preparation method is simple and suitable for industrial production.
Description
Technical field
The invention belongs to the matting field, especially a kind of opticglass remover and preparation method thereof.
Background technology
Plated film only is the special honours that the camera lens of highest ranking is just enjoyed always on optical lens.The coating technique of a new generation is developed up to nineteen sixty-eight, just makes the camera lens that has plated film popular day by day.In opticglass camera lens, eyeglass production, for the optical property that improves lens wearer need plate spectrum spectro-film, antireflective light film (anti-reflection film), energy spectro-film, highly reflecting films etc. at lens surface.Plated film lens is the new technology of utilizing optical thin film and vacuum, plate certain thickness single or multiple lift optical thin film, make eyeglass obtain some premium propertiess new, that originally do not possess, to improve the ability of eyeglass reflection ray, play enhancing or reduce the effect that light sees through.The optical glass lens film divides individual layer and multilayer, and main component is inorganic, metal oxide (titanium oxide, silicon oxide, aluminum oxide, zirconium white, tantalum oxide) magnesium fluoride, zinc sulphide etc.And plated film is the technology of a more complicated, and the camera lens, the eyeglass that come of plating out has flaws such as uneven distribution unavoidably, just bad plated film need be sloughed, again plated film.
Summary of the invention
The object of the present invention is to provide a kind of optical glass lens remover and preparation method thereof.The remover of the present invention's preparation is green non-poisonous, demoulding is effective, it is residual that eyeglass is not had corrosion, and preparation technology is simple, is fit to industrial production.
The technical scheme that realizes the object of the invention is as follows:
A kind of opticglass remover, its composition and weight percent are:
All the other adding distil waters to 100%.
And described tensio-active agent is selected from one of nonenyl succinic acid acid anhydride, alkyl glycoside, positive octenyl succinic acid anhydride, dodecenylsuccinic anhydride, tetradecene base succinyl oxide or both above mixtures.
And described complexing agent is selected from one of ethylenediamine tetramethylene phosphonic acid, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, EDTA, NTA, ATMP or the mixture more than both.
And described solvent is selected from one of tetraethyleneglycol dimethyl ether, triethylene glycol dme, dimethyl sulfoxide (DMSO) or the mixture more than both.
And the molecular weight of described sodium polyacrylate is 4500.
A kind of preparation method of opticglass remover, step is as follows:
1. suitable quantity of water is added the potassium hydroxide, the metasilicate pentahydrate sodium that slowly add reacting weight in the reactor and be stirred to dissolving fully, the tensio-active agent and the complexing agent that add reacting weight when maintaining the temperature at 40-50 ℃ stir 20-30 minute to dissolving fully;
2. the trolamine and the stirring solvent dissolving extremely fully that add reacting weight successively;
3. the sodium polyacrylate that adds reacting weight at last is stirred to fully, and dissolving is the opticglass remover.
The mechanism of action of the present invention:
At first be the reaction of potassium hydroxide and tensio-active agent and complexing agent and trolamine, generate the organic salt complex compound, this complex compound has extremely strong complexing to metal oxide and other metallic compounds; Water-soluble aprotic solvent has strong solvency action to inorganicss such as (titanium oxide, silicon oxide, aluminum oxide, zirconium white, tantalum oxide) magnesium fluoride, zinc sulphide, and the demoulding of eyeglass is played crucial effects; Dispersion agent plays dissemination to the film under coming off, and prevents its glassivation surface again; The metasilicate pentahydrate sodium that adds in this product has certain corrosion inhibition to glass, and making glass mirror light behind the demoulding does not have corrosion, noresidue.
Advantage of the present invention and beneficial effect are:
(1) mechanism of action of the present invention is simple, and the synergy by each component (complexing of complexing agent and the dissolving of special solvent) makes the demoulding effect reach best.
(2) this remover can take off unitary film or multilayer film, and various metallic membranes and metal oxide plated film (magnesium fluoride, aluminum oxide, silicon oxide plated film) are all had fabulous removal effect.
(3) contain inhibiter and dispersion agent in this remover and can effectively prevent remover to the corrosion of glass, eyeglass light noresidue behind the demoulding.
(4) fast, the safety of this remover demoulding speed, environmental protection, nontoxic, economical (can dilute one times).Using method ultrasonic cleaning or immersion are used and all can.
(5) preparation method who the present invention relates to is simple, and raw materials used wide material sources, obtains easily, is highly suitable for large-scale industrial production.
Embodiment
Below in conjunction with embodiment, the present invention is further described, and following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
Embodiment 1:
The raw material of the embodiment of the invention is marketable material.
A kind of moiety of opticglass remover is (be example with 1000g opticglass remover):
A kind of preparation method's of opticglass remover step is as follows:
(1) suitable quantity of water is added the potassium hydroxide, the metasilicate pentahydrate sodium that slowly add reacting weight in the reactor and be stirred to dissolving fully.
(2) nonenyl succinic acid acid anhydride, the ethylenediamine tetramethylene phosphonic acid that adds reacting weight in the time of temperature 40-50 ℃ stirs 20-30 minute to dissolving fully.
(3) trolamine and the tetraethyleneglycol dimethyl ether that adds reacting weight mixes stirring dissolving extremely fully in 15-20 minute.
(4) extremely dissolved fully in 15-20 minute to the sodium polyacrylate stirring of reactor adding reacting weight at last.
Embodiment 2:
A kind of moiety of opticglass remover is (be example with the 1000g water-based antirust):
A kind of preparation method's of opticglass remover step is as follows:
(1) suitable quantity of water is added the potassium hydroxide, the metasilicate pentahydrate sodium that slowly add reacting weight in the reactor and be stirred to dissolving fully.
(2) nonenyl succinic acid acid anhydride, the 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid that adds reacting weight in the time of temperature 40-50 ℃ stirs 20-30 minute to dissolving fully.
(3) trolamine and the triethylene glycol dme that adds reacting weight mixes stirring dissolving extremely fully in 15-20 minute.
(4) extremely dissolved fully in 15-20 minute to the sodium polyacrylate stirring of reactor adding reacting weight at last.
Application Example 1:
In the liquid bath by stoste or dilute the remover that one times concentration adds embodiment 1, constant temperature is to 80-90 ℃, the demoulding eyeglass for the treatment of that is coated with anti-reflection film that is preheating in distilled water in advance about 50-60 ℃ was soaked 40-50 minute, rinsing is 1 minute in the distilled water of taking-up about 50 ℃, then with isopropanol dehydration or use hot-air seasoning.
The result: the eyeglass light of handling, no burn into noresidue, and compare reflective light intensity before the demoulding.
Application Example 2:
In the liquid bath by stoste or dilute the remover that one times concentration adds embodiment 2, constant temperature is to 80-90 ℃, the demoulding eyeglass for the treatment of that is coated with anti-reflection film that is preheating in distilled water in advance about 50-60 ℃ was soaked 40-50 minute, rinsing is 1 minute in the distilled water of taking-up about 50 ℃, then with hot-air seasoning or use isopropanol dehydration.
The result: the eyeglass light of handling, no burn into noresidue, and compare reflective light intensity before the demoulding.
This opticglass remover quality standard:
Outward appearance: amber transparent liquid
Molten water-based: 100%
Flash-point (℃): do not have
Boiling point (℃): 100
Density (20 ℃, g/ml): 1.161 ± 0.010
pH(1％)：12.07±0.25
Working concentration: stoste or dilute one times
Cleaning way: soak or ultrasonic wave
Time: 5-150 minute (because of different plated films and coating layers and cleaning way different)
Use temperature: 80-90 ℃ (should select low temperature when film cleans).
Claims (3)
1. opticglass remover, it is characterized in that: its composition and weight percent are:
All the other adding distil waters to 100%;
Described tensio-active agent is selected from one of nonenyl succinic acid acid anhydride, alkyl glycoside, positive octenyl succinic acid anhydride, dodecenylsuccinic anhydride, tetradecene base succinyl oxide or both above mixtures;
Described complexing agent is selected from one of ethylenediamine tetramethylene phosphonic acid, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, EDTA, NTA, ATMP or the mixture more than both;
Described solvent is selected from one of tetraethyleneglycol dimethyl ether, triethylene glycol dme, dimethyl sulfoxide (DMSO) or the mixture more than both.
2. a kind of opticglass remover according to claim 1, it is characterized in that: the molecular weight of described sodium polyacrylate is 4500.
3. the preparation method of an opticglass remover as claimed in claim 1, it is characterized in that: preparation process is as follows:
1. suitable quantity of water is added the potassium hydroxide, the metasilicate pentahydrate sodium that slowly add reacting weight in the reactor and be stirred to dissolving fully, the tensio-active agent and the complexing agent that add reacting weight when maintaining the temperature at 40-50 ℃ stir 20-30 minute to dissolving fully;
2. the trolamine and the stirring solvent dissolving extremely fully that add reacting weight successively;
3. the sodium polyacrylate that adds reacting weight at last is stirred to dissolving fully.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110319869 CN102503154B (en) | 2011-10-20 | 2011-10-20 | Optical glass paint remover and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110319869 CN102503154B (en) | 2011-10-20 | 2011-10-20 | Optical glass paint remover and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102503154A CN102503154A (en) | 2012-06-20 |
| CN102503154B true CN102503154B (en) | 2013-09-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110319869 Expired - Fee Related CN102503154B (en) | 2011-10-20 | 2011-10-20 | Optical glass paint remover and preparation method thereof |
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| Country | Link |
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| CN (1) | CN102503154B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104843992A (en) * | 2015-05-04 | 2015-08-19 | 河南师范大学 | Optical glass release agent and preparation method thereof |
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| CN108863104B (en) * | 2017-05-10 | 2021-11-23 | 蓝思科技（长沙）有限公司 | Glass stripping agent and glass stripping process |
| CN107974687A (en) * | 2017-10-24 | 2018-05-01 | 广东富行洗涤剂科技有限公司 | It is a kind of to take off mould agent for glass vacuum coating mould |
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| CN110527348B (en) * | 2019-08-28 | 2022-09-16 | 广东省资源综合利用研究所 | Aqueous transfer film release agent and preparation method and application thereof |
| CN111961544A (en) * | 2020-07-23 | 2020-11-20 | 湖北优尼科光电技术股份有限公司 | Film layer removing soaking solution applied to glass coating and application method thereof |
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| CN101092591A (en) * | 2006-06-23 | 2007-12-26 | 天津晶岭电子材料科技有限公司 | Cleaning agent for optical glass |
| CN101979491A (en) * | 2010-11-10 | 2011-02-23 | 南通海迅天恒纳米科技有限公司 | Cleaning agent for glass lens of mobile phone |
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06108092A (en) * | 1992-09-28 | 1994-04-19 | Lion Corp | Strongly alkaline liquid detergent composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1482223A (en) * | 2003-07-24 | 2004-03-17 | 山东大学 | Glass cleaning agent composite for electronic industry |
| CN101092591A (en) * | 2006-06-23 | 2007-12-26 | 天津晶岭电子材料科技有限公司 | Cleaning agent for optical glass |
| CN101979491A (en) * | 2010-11-10 | 2011-02-23 | 南通海迅天恒纳米科技有限公司 | Cleaning agent for glass lens of mobile phone |
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
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| CN104843992A (en) * | 2015-05-04 | 2015-08-19 | 河南师范大学 | Optical glass release agent and preparation method thereof |
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| CN102503154A (en) | 2012-06-20 |
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