CN113046196A - Solid cleaning liquid concentrating agent and preparation method and application thereof - Google Patents
Solid cleaning liquid concentrating agent and preparation method and application thereof Download PDFInfo
- Publication number
- CN113046196A CN113046196A CN201911374823.XA CN201911374823A CN113046196A CN 113046196 A CN113046196 A CN 113046196A CN 201911374823 A CN201911374823 A CN 201911374823A CN 113046196 A CN113046196 A CN 113046196A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning solution
- solid cleaning
- agent
- concentrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 113
- 239000007787 solid Substances 0.000 title claims abstract description 84
- 239000007788 liquid Substances 0.000 title abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 63
- 239000000203 mixture Substances 0.000 claims abstract description 36
- -1 perfluorododecyl betaine Chemical compound 0.000 claims abstract description 33
- 239000003755 preservative agent Substances 0.000 claims abstract description 26
- 230000002335 preservative effect Effects 0.000 claims abstract description 25
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 20
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 20
- 229960003237 betaine Drugs 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 150000001412 amines Chemical class 0.000 claims abstract description 16
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 15
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012141 concentrate Substances 0.000 claims description 62
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000011521 glass Substances 0.000 claims description 19
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 14
- 239000012964 benzotriazole Substances 0.000 claims description 14
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 13
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 13
- 229920002472 Starch Polymers 0.000 claims description 12
- 239000001913 cellulose Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000008107 starch Substances 0.000 claims description 12
- 235000019698 starch Nutrition 0.000 claims description 12
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 11
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000012459 cleaning agent Substances 0.000 claims description 9
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 8
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 3
- 229940120146 EDTMP Drugs 0.000 claims description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 3
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 3
- UXYAJXBVMZFRMS-UHFFFAOYSA-N 2-hydroxy-1,3,2$l^{5}-dioxaphosphepane 2-oxide Chemical compound OP1(=O)OCCCCO1 UXYAJXBVMZFRMS-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 2
- XYZZKVRWGOWVGO-UHFFFAOYSA-N Glycerol-phosphate Chemical compound OP(O)(O)=O.OCC(O)CO XYZZKVRWGOWVGO-UHFFFAOYSA-N 0.000 claims description 2
- 229930195725 Mannitol Natural products 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000594 mannitol Substances 0.000 claims description 2
- 235000010355 mannitol Nutrition 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229940116351 sebacate Drugs 0.000 claims description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 23
- 230000007797 corrosion Effects 0.000 abstract description 22
- 230000032683 aging Effects 0.000 abstract description 10
- 239000006185 dispersion Substances 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract description 2
- 239000012530 fluid Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 description 51
- 235000008504 concentrate Nutrition 0.000 description 41
- 238000012360 testing method Methods 0.000 description 24
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- LGNQGTFARHLQFB-UHFFFAOYSA-N 1-dodecyl-2-phenoxybenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1OC1=CC=CC=C1 LGNQGTFARHLQFB-UHFFFAOYSA-N 0.000 description 10
- 238000011056 performance test Methods 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- 239000013579 wash concentrate Substances 0.000 description 7
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- 238000005536 corrosion prevention Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000000686 essence Substances 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 235000014666 liquid concentrate Nutrition 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000003137 locomotive effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
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- Chemical & Material Sciences (AREA)
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Abstract
The invention relates to the field of cleaning fluid, and discloses a solid cleaning fluid concentrating agent, and a preparation method and application thereof. Wherein, the solid cleaning solution concentrating agent comprises the following components: 3-9 parts of composite surfactant, 0.5-7 parts of sodium dodecyl sulfate, 0.5-2 parts of polyalcohol amine, 0.9-4.2 parts of preservative and 0.1-4 parts of anti-scaling agent; wherein the composite surfactant is a mixture of perfluorododecyl betaine and alkyl diphenyl ether disulfonate. The cleaning liquid prepared by the solid cleaning liquid concentrating agent has the functions of corrosion resistance, scale prevention, dispersion and ageing resistance.
Description
Technical Field
The invention relates to the field of cleaning liquid, in particular to a solid cleaning liquid concentrating agent, and a preparation method and application thereof.
Background
In the actual life of people, transparent glass is used for enclosing walls of a plurality of buildings, the glass is easily polluted by oil stain, dust and other impurities after being exposed in the air for a long time, so that the glass needs to be cleaned regularly, the cleaning requirements are simple, the corrosion prevention is basically not involved, and for motor vehicles such as automobiles, trains and locomotives, dust, bird excrement, insect corpses and the like are easily accumulated on windows and bodies of the motor vehicles such as automobiles, trains and locomotives in the long-term running process and the placing process. The glass surface is easy to fog and freeze in winter; in summer, a lot of shellac is often contaminated, oil stain, dust and the like are inevitably attached to the windshield at ordinary times, the sight of a driver is seriously influenced, potential safety hazards are generated in the driving process, the attractiveness and the service life of a vehicle, particularly the service life of a paint surface, are influenced, the requirement response of the cleaning liquid is strict, the glass surface can be effectively cleaned, and the cleaned residual liquid is required not to corrode adhesive tapes on the surface of the vehicle window and the surrounding finish paint and a coating film.
The automobile window cleaning liquid has higher requirement, but the price is cheaper, the transportation of the glass cleaning liquid with low freezing point also relates to the transportation and storage of dangerous goods, the use is very inconvenient, and the transportation cost of the originally very cheap product accounts for more than 50 percent, so that the cost of the automobile cleaning liquid is high. In recent years, the non-freezing point glass cleaning solution sold in supermarkets cannot be used in winter, has poor quality, cannot meet the requirements of convenience in carrying and economy, and is not suitable for long-term use of vehicles.
At present, the sale of solid wiper essences begins to appear in the domestic market, most of the solid wiper essences are produced by small workshops, only the cleaning and instant dissolving effects are considered, and the functions of corrosion prevention, ageing resistance, scaling resistance and the like of metal parts of a wiper system are not considered, so that the long-term application of the wiper essences can not only accelerate the aging of wiper strips, but also lead to the corrosion and fracture of blades or shafts of a wiper motor pump, and further lead to quality accidents.
CN104099188A discloses solid glass water and a preparation method thereof. Wherein, the solid glass water comprises the following raw materials: 2-5 parts of nonylphenol oxy polyoxyethylene ether alcohol, 1-3 parts of 1, 2-ethylene tetraacetic acid tetrasodium salt, 5.5-9 parts of sodium lauryl sulfate, 5-7 parts of sodium carbonate, 3-5.5 parts of sodium bicarbonate and 0.5-0.7 part of citric acid. However, the requirement of corrosion prevention and scale dispersion is not considered, the contained citric acid can only play a slight scale removal role, a large amount of scale is easily caused to block a nozzle for vehicles which are widely diluted by tap water, the solid glass water is most suitable for cleaning household glass and building glass which are not high in requirement, the glass water prepared by the formula cannot meet the standard requirement of GB23436-2009 and cannot be used for cleaning automobile windows and train windows, and meanwhile, a specific solution used in winter is not provided in the patent.
Therefore, the research and development of the solid cleaning solution concentrating agent with the functions of corrosion prevention, scale prevention, dispersion and aging resistance have important significance.
Disclosure of Invention
The invention aims to overcome the defects of poor corrosion resistance of cleaning liquid and poor scale dispersing effect in the prior art, and provides a solid cleaning liquid concentrating agent, a preparation method and application thereof.
In order to achieve the above object, a first aspect of the present invention provides a solid cleaning solution concentrate, wherein the solid cleaning solution concentrate comprises: 3-9 parts of composite surfactant, 0.5-7 parts of sodium dodecyl sulfate, 0.5-2 parts of polyalcohol amine, 0.9-4.2 parts of preservative and 0.1-4 parts of anti-scaling agent; wherein the composite surfactant is a mixture of perfluorododecyl betaine and alkyl diphenyl ether disulfonate.
In a second aspect, the present invention provides a method for preparing the above-mentioned concentrate, wherein the method comprises:
(1) mixing water, a composite surfactant and sodium dodecyl sulfate to obtain a first mixture;
(2) sequentially contacting the first mixture with polyalcohol amine, a preservative and an anti-scaling agent to obtain a second mixture, and extruding and granulating the second mixture.
In a third aspect, the invention provides a use of the aforementioned solid cleaning solution concentrate for cleaning glass.
By adopting the technical scheme, the solid cleaning solution concentrate with specific components and component contents can be compounded with water according to the change of seasonal temperature, so that the solid cleaning solution concentrate is suitable for being used in summer (for example, the temperature is 0-50 ℃); or, the solid cleaning solution concentrate is compounded with alcohol or the solid cleaning solution concentrate is compounded with alcohol and water, so that the cleaning solution concentrate is suitable for winter use (for example, the temperature is-5 ℃ to-30 ℃); the solid cleaning solution concentrate disclosed by the invention has excellent anti-corrosion performance, and also has the functions of removing scales, brightening window glass and resisting aging.
Detailed Description
The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual points, and between the individual points may be combined with each other to give one or more new ranges of values, and these ranges of values should be considered as specifically disclosed herein.
The invention provides a solid cleaning solution concentrating agent in a first aspect, wherein the solid cleaning solution concentrating agent comprises the following components: 3-9 parts of composite surfactant, 0.5-7 parts of sodium dodecyl sulfate, 0.5-2 parts of polyalcohol amine, 0.9-4.2 parts of preservative and 0.1-4 parts of anti-scaling agent; wherein the composite surfactant is a mixture of perfluorododecyl betaine and alkyl diphenyl ether disulfonate.
In the present invention, it is to be noted that the solid cleaning solution concentrate is prepared according to the parts by weight of the charged surfactant, sodium lauryl sulfate, polyalcohol amine, preservative and anti-scaling agent, that is, the parts by weight of the component contents of each component constituting the solid cleaning solution concentrate also satisfy: the weight ratio of the surfactant to the lauryl sodium sulfate to the polyalcohol amine to the preservative to the anti-scaling agent is (3-9): (0.5-7): (0.5-2): (0.9-4.2): (0.1-4). The following similar parts are not described in detail.
In addition, in the present invention, it is to be noted that, in the present invention, similarly to the given value of the range of "3 to 9 parts by weight", it is expressed that: in the present invention, the range values given include each of the range values and any value in the range of any two of these values. For example, specifically, it may be any value in a range of 3 parts by weight, 3.1 parts by weight, 3.2 parts by weight, 3.5 parts by weight, 3.8 parts by weight, 4 parts by weight, 4.2 parts by weight, 4.5 parts by weight, 4.7 parts by weight, 5 parts by weight, 5.2 parts by weight, 5.5 parts by weight, 5.7 parts by weight, 6 parts by weight, 6.5 parts by weight, 7 parts by weight, 7.5 parts by weight, 8 parts by weight, 8.5 parts by weight, and 9 parts by weight and any two of these points. The following similar parts are not described in detail.
According to the present invention, it is preferable that the solid cleaning solution concentrate has a composition of: 5-7 parts of composite surfactant, 0.8-3 parts of sodium dodecyl sulfate, 0.7-1.5 parts of polyalcohol amine, 1.3-2.5 parts of preservative and 0.2-0.6 part of anti-scaling agent.
Preferably, the weight ratio of the perfluorododecyl betaine to the alkyl diphenyl ether disulfonate is 1: (5-10); preferably, the weight ratio of the perfluorododecyl betaine to the alkyl diphenyl oxide sulfonate is 1: (8-10) the cleaning liquid concentrate produced the best foam and cleaning property.
In the present invention, perfluorododecyl betaine refers to a light yellow aqueous solution having a concentration of not less than 27%.
In the present invention, the alkyl diphenyl oxide disulfonate refers to a powder or solid of a sodium salt of alkyl diphenyl oxide disulfonate having a content of not less than 90%, preferably, the alkyl diphenyl oxide disulfonate is sodium dodecyl diphenyl oxide disulfonate.
In the present invention, sodium lauryl sulfate refers to a premium grade solution having an active content of not less than 30%. The sodium dodecyl sulfate plays a role in assisting in foaming and taking away dirt in cleaning, and can improve the dispersing capacity of the cleaning solution concentrate in an aqueous solution and the cleaning capacity of the cleaning solution concentrate on the dirt.
In the invention, the composite surfactant is adopted, and the weight ratio of the contents of the alkyl diphenyl ether disulfonate and the perfluorododecyl betaine in the composite surfactant is controlled within the range defined above, so that the glass cleaning agent has the advantages of providing excellent low-foaming performance and low surface tension, effectively removing stubborn dirt on the surface of glass, having good oil stain permeability, forming a film uniformly after cleaning, and having better defrosting and antifogging effects.
According to the invention, the polyalcohol amine is selected from diethanolamine and/or triethanolamine, preferably diethanolamine.
According to the invention, the preservative is selected from one or more of benzoate, silicate, benzotriazole, oleate, phosphate, sebacate and octodecanoate; preferably one or more of benzoate, silicate and benzotriazole.
According to the invention, in the solid cleaning solution concentrate, the preservative comprises the following components: 0.1 to 0.7 part by weight of benzoate; 0.5-2 parts by weight of silicate; 0.3-1.5 parts by weight of benzotriazole; more preferably, in the solid cleaning solution concentrate, the preservative comprises the following components: 0.2 to 0.5 weight portion of benzoate, 0.6 to 1 weight portion of silicate and 0.5 to 1 weight portion of benzotriazole.
In the present invention, the use of the preservative, the components and the content of the preservative being limited to the ranges defined above, enables the solid cleaning solution concentrate to have an excellent preservative function, and the preservative is effective in forming a black light protective film layer on the surface of the metal parts of the cleaning system, thereby preventing the corrosion and breakage of the metal parts (e.g., pump blades, nozzles, and pump shafts), and particularly has an excellent corrosion protection effect on various metal parts (steel, copper, galvanized iron) of the wiper system.
According to the invention, the anti-scaling agent is selected from one or more of polyanionic cellulose, ethylene diamine tetra methylene phosphoric acid, polyacrylate, aminotrimethylene phosphonic Acid (ATMP), hydroxyethylidene diphosphonic acid (HEDP), 2-phosphonobutane-1, 2, 4-tricarboxylic acid (PBTC) and polyoxyethylene ether glycerol phosphate; preferably polyanionic cellulose and/or ethylenediaminetetramethylenephosphonic acid.
According to the invention, in the solid cleaning solution concentrate, the anti-scaling agent comprises the following components: 0.05-2 parts of polyanionic cellulose and 0.05-2 parts of ethylene diamine tetramethylene phosphate; more preferably, in the solid cleaning solution concentrate, the anti-scaling agent consists of: 0.1-0.3 weight portion of polyanionic cellulose and 0.1-0.3 weight portion of ethylenediamine tetramethylene phosphoric acid.
According to the invention, the anti-scaling agent is adopted, and the components and the component content of the anti-scaling agent are limited within the range defined above, so that the solid cleaning solution concentrate has excellent anti-scaling and dispersing performances, the anti-scaling agent can effectively disperse calcium and magnesium ions contained in water, for example, the anti-scaling agent has the effects of aggregation resistance and dispersion in the car window spraying and drying process, in addition, the anti-scaling agent has the effect of skewing the crystal lattice layer of the surface film in the drying process, so that the firm deposition of the film layer is prevented, the glass surface can be effectively protected from being scratched, the anti-scaling agent can be quickly dissolved and removed after water spraying, and the car window glass is bright and has a good effect. In addition, the anti-scaling agent is adopted, so that the scaling problem caused by using tap water can be prevented, and the anti-aging function of the wiper strip rubber can be further prolonged.
According to the invention, the solid cleaning solution concentrating agent also comprises 1-21 parts by weight of a binder; preferably, the binder is selected from one or more of sodium bicarbonate, water-soluble starch, sodium carbonate, powdered sugar, inorganic salts and mannitol; sodium bicarbonate and/or water-soluble starch are preferred.
According to the present invention, in the solid cleaning solution concentrate, the binder is composed of: 0.5-10 parts of sodium bicarbonate and 0.5-11 parts of water-soluble starch; more preferably, in the solid cleaning solution concentrate, the binder has a composition of: 3-6 parts of sodium bicarbonate and 2-5 parts of water-soluble starch.
In the invention, the binder is adopted, and the components and the component content of the binder are limited in the range defined in the specification, so that the extrusion granulation can be facilitated, and the granules after the granulation are loose in gaps and easy to dissolve.
According to the invention, the solid cleaning solution concentrate also comprises 0.06-1 part by weight of dye and/or bittering agent.
According to the invention, the solid cleaning solution concentrate also comprises: 0.03 to 0.5 parts by weight of said dye, 0.03 to 0.5 parts by weight of said bittering agent; more preferably, the solid cleaning solution concentrate further comprises: 0.05-0.1 weight part of the dye and 0.05-0.1 weight part of the bittering agent.
In the invention, the added bittering agent can effectively prevent children from swallowing, and the storage safety of the product is greatly improved.
According to the invention, the dye is selected from one or more of edible cyan No. 1 pigment, lemon yellow, phthalocyanine blue and carmine, preferably edible cyan No. 1 pigment.
In a second aspect, the present invention provides a method for preparing the above-mentioned concentrate, wherein the method comprises:
(1) mixing water, a composite surfactant and sodium dodecyl sulfate to obtain a first mixture;
(2) sequentially contacting the first mixture with polyalcohol amine, a preservative and an anti-scaling agent to obtain a second mixture, and extruding and granulating the second mixture.
According to the invention, the extrusion granulation is carried out by a wet granulator, and the concentrate is in the form of tablets.
According to the invention, the process is carried out under stirring conditions, wherein the stirring conditions comprise: the stirring rate is 60 to 90 revolutions per minute, preferably 85 revolutions per minute.
According to the invention, the process is carried out at a temperature of 40 to 60 ℃.
According to the invention, in the step (2), after the polyalcohol amine, the preservative and the anti-scaling agent are completely dissolved and transparent, the pH value of the solution is adjusted by slowly adding isooctanoic acid, so that the pH value of the solution is kept at 7.5 or above 7.5, and preferably, the pH value is 8.0-9.0.
According to the present invention, preferably, in the step (2), the first mixture is sequentially contacted with the polyalcohol amine, the preservative and the anti-scaling agent, and each contact is separated by 5 to 10 minutes, preferably 10 minutes, so as to enable better uniform mixing.
In a third aspect, the invention provides a use of the aforementioned solid cleaning solution concentrate for cleaning glass.
According to the invention, the conditions of the application include:
wherein, in summer, for example, under the condition of 0-50 ℃, the concentrate is compounded with water to prepare the cleaning agent, and the using amount of the water is 3-4L relative to 1g of the concentrate;
wherein, in the northeast cold region, for example, under the condition of the temperature of-25 ℃ to-30 ℃, the concentrate and alcohol are compounded to prepare the cleaning agent, and relative to 1g of the concentrate, the dosage of the alcohol is 1900-; preferably, in order to prevent freezing, the high-alcohol spirit can be directly diluted for use when the average temperature in the northeast cold region is-30 ℃, or the medical alcohol and the edible alcohol are prepared into 50% concentration by volume ratio for use, wherein the alcohol content of the high-alcohol spirit is 52-60 ℃, the concentration of the medical alcohol is not less than 95, and the concentration of the edible alcohol is not less than 95%.
Wherein, in winter in south, under the condition of-5 ℃ to-10 ℃, the concentrated agent and alcohol are compounded to prepare the cleaning agent, or the concentrated agent, alcohol and water are compounded to prepare the cleaning agent, and relative to 1g of the concentrated agent, the dosage of the alcohol is 560-; preferably, 2 bottles (500ml) of white spirit and 3500ml of water can be added to dilute the white spirit in an area with the average temperature of not less than-5 ℃, or 15% volume ratio concentration of monohydric alcohols such as medical alcohol, edible alcohol and the like can be used, wherein the degree of the white spirit is 52-60 ℃, the concentration of the medical alcohol is not less than 95, and the concentration of the edible alcohol is not less than 95%.
According to the present invention, in order to enhance the anti-frost and anti-fog effects, one or more of glycerol, diethylene glycol and ethylene glycol may be added to the diluted aqueous solution in an amount of 5% by volume or less, and preferably, about 150ml or less of glycerol and ethylene glycol are added and mixed.
According to the invention, the concentration of said alcohol is not less than 95%; preferably, the alcohol may be selected from one or more of methanol, ethanol and isopropanol, and the alcohol may also be selected from one or more of white spirit, medical alcohol and edible alcohol.
The present invention will be described in detail below by way of examples.
The raw materials for sodium lauryl sulfate, polyalcohol amine, alkyl diphenyl ether disulfonate, perfluorododecyl betaine, preservative, anti-kogation agent, edible cyan No. 1 pigment, isooctanoic acid, etc., used in the following examples and comparative examples, are commercially available, for example, from the national pharmaceutical group chemicals, ltd.
Example 1
This example is intended to illustrate the solid cleaning solution concentrate of the present invention.
5kg of the composition of the perfluorododecyl betaine and the dodecyl diphenyl ether disulfonate, wherein the weight ratio of the usage amount of the perfluorododecyl betaine to the usage amount of the dodecyl diphenyl ether disulfonate is 1: 10, 1.9kg of sodium dodecyl sulfate is put into a container with a stirrer, the mixture is slowly stirred and dissolved under the condition that the stirring speed is 85 revolutions per minute, the temperature is raised to 60 ℃, 0.7kg of diethanolamine, 0.35kg of benzoate, 0.6kg of silicate, 0.75kg of benzotriazole, 0.05kg of edible cyan No. 1 pigment, 0.075kg of bittering agent and 0.1kg of ethylene diamine tetra methyl phosphoric acid are sequentially added at intervals of 10 minutes, a proper amount of deionized water is added for slow stirring, isooctanoic acid is added after the mixture is completely dissolved uniformly to adjust the pH value of the solution to be 7.5, 0.3kg of polyanionic cellulose, 6kg of sodium bicarbonate and 2kg of water-soluble starch are added, and the mixture is mixed, dried and granulated by a wet granulator to prepare the multi-particle loose solid cleaning solution concentrator with uniform quality.
Example 2
This example is intended to illustrate the solid cleaning solution concentrate of the present invention.
The total weight of the composition of the perfluorododecyl betaine and the dodecyl diphenyl ether disulfonate is 7kg, wherein the weight ratio of the usage amount of the perfluorododecyl betaine to the usage amount of the dodecyl diphenyl ether disulfonate is 1: and 8, placing 0.8kg of sodium dodecyl sulfate into a container with a stirrer, slowly stirring and dissolving the sodium dodecyl sulfate under the condition that the stirring speed is 85 revolutions per minute, heating the mixture to 60 ℃, sequentially adding 1.1kg of diethanolamine, 0.5kg of benzoate, 0.8kg of silicate, 1kg of benzotriazole, 0.075kg of edible cyan 1 pigment, 0.1kg of bittering agent and 0.3kg of ethylene diamine tetramethylphosphoric acid at intervals of 10 minutes, adding a proper amount of deionized water, slowly stirring the mixture, slowly adding isooctanoic acid to adjust the pH value of the solution after the mixture is completely dissolved uniformly so as to keep the pH value of the solution at 8, adding 0.2kg of polyanionic cellulose as auxiliary materials, 3kg of sodium bicarbonate and 5kg of water-soluble starch, and mixing, drying and granulating the mixture by a wet granulator to prepare the uniform-quality multi-particle flaky solid loose cleaning solution concentrator.
Example 3
This example is intended to illustrate the solid cleaning solution concentrate of the present invention.
The total amount of the composition of the perfluorododecyl betaine and the dodecyl diphenyl ether disulfonate is 6kg, wherein the weight ratio of the usage amount of the perfluorododecyl betaine to the usage amount of the dodecyl diphenyl ether disulfonate is 1: 9, 3.0kg of sodium dodecyl sulfate is put into a container with a stirrer, slowly stirred and dissolved under the condition that the stirring speed is 85 revolutions per minute, the temperature is raised to 60 ℃, 1.1kg of diethanolamine, 0.2kg of benzoate, 1.0kg of silicate, 0.5kg of benzotriazole, 0.1kg of edible cyan No. 1 pigment, 0.05kg of bittering agent and 0.2kg of ethylene diamine tetramethylphosphoric acid are sequentially added at intervals of 10 minutes, a proper amount of deionized water is added for slow stirring, isooctanoic acid is added after complete dissolution to adjust the pH value of the solution to 8.5, 0.1kg of polyanionic cellulose, 4.5kg of sodium bicarbonate and 3.5kg of water-soluble starch are added for mixing, drying and granulation through a wet granulator, and the multi-particle loose solid cleaning solution concentrator with uniform quality is prepared.
Example 4
This example is intended to illustrate the solid cleaning solution concentrate of the present invention.
The total weight of the composition of dodecyl diphenyl ether disulfonate and perfluorododecyl betaine is 8kg, wherein the weight ratio of the usage amount of the perfluorododecyl betaine to the usage amount of the dodecyl diphenyl ether disulfonate is 1: 5, placing 0.5kg of sodium dodecyl sulfate into a container with a stirrer, slowly stirring and dissolving the sodium dodecyl sulfate under the condition that the stirring speed is 85 revolutions per minute, heating the mixture to 60 ℃, sequentially adding 1.1kg of diethanolamine, 0.2kg of benzoate, 0.5kg of silicate, 0.5kg of benzotriazole, 0.1kg of edible cyan No. 1 pigment, 0.05kg of bittering agent and 0.07kg of ethylene diamine tetramethylphosphoric acid every 5 minutes, adding a proper amount of deionized water, slowly stirring the mixture, adding isooctanoic acid to adjust the pH value of the solution after the mixture is completely dissolved uniformly so as to keep the pH value of the solution at 9, adding 0.1kg of polyanionic cellulose, 10kg of sodium bicarbonate and 0.5kg of water-soluble starch, mixing, drying and granulating the mixture by a wet granulator to prepare the uniform-quality multi-particle loose solid cleaning solution concentrator.
Application example 1
The 0 ℃ window wash formulated using the solid wash concentrate prepared in example 1 was tested for primary performance according to the standard of GB23436-2009 (where the metal corrosion test was carried out over 120 hours, which is 72 hours longer than the 48 hours specified in the GB23436 standard), and the soil removal rate was tested by the hanging piece method, with the results shown in table 1.
TABLE 1
The results are shown in table 1, and the practical test results show that the vehicle window cleaning liquid blended by using the solid cleaning liquid concentrating agent has good corrosion resistance, ageing resistance and ultra-clean cleaning performance.
Application example 2
The primary performance test (120 hours for the metal corrosion test, 72 hours longer than the 48 hours specified in GB 23436) was carried out according to the standard of GB23436-2009 using 99% methanol from the company plus the-5 ℃ window wash formulated from the solid wash concentrate prepared in example 2, with the results shown in table 2.
TABLE 2
The results are shown in table 2, which shows that the actual test results show that the vehicle window cleaning liquid blended by using the solid cleaning liquid concentrating agent has good corrosion resistance, ageing resistance and ultra-clean cleaning performance.
Application example 3
The primary performance test (120 hours for the metal corrosion test, 72 hours longer than the 48 hours specified in GB 23436) was performed on a-25 ℃ window wash formulated using 95% ethanol from the company as purchased according to the standard GB23436-2009 with the solid wash concentrate prepared in example 3, with the results shown in table 3.
TABLE 3
The results are shown in table 3, which indicates that the actual test results show that the dirt removal rate in the cleaning effect is the best in example 3, and the vehicle window cleaning liquid blended by using the solid cleaning liquid concentrating agent has good corrosion resistance, ageing resistance and ultra-clean cleaning performance.
Application example 4
The primary performance test (120 hours for the metal corrosion test and 72 hours extension from the GB23436 standard specification of 48 hours) was carried out according to GB23436-2009 using 95% ethanol from the company plus the solid cleaning solution concentrate prepared in example 4 at-40℃, with the results shown in Table 4.
TABLE 4
The results are shown in table 4, which shows that the actual test effect is reduced compared with the cleaning performance of the comparative examples 1 to 3, the weight loss of the test piece is increased, but the vehicle window cleaning liquid blended by using the solid cleaning liquid concentrating agent still has good corrosion resistance, ageing resistance and ultra-clean cleaning performance.
Comparative example 1
A concentrate was prepared under the same conditions as in example 1, except that: the cleaning effect test was carried out without using complex surfactants (perfluorododecyl betaine and dodecyl diphenyl ether disulfonate) using 5kg of detergent as a surfactant.
Comparative example 2
A concentrate was prepared under the same conditions as in example 1, except that: the weight ratio of the dosage of the perfluorododecyl betaine to the dosage of the dodecyl diphenyl ether disulfonate is 1: 3.
comparative example 3
A concentrate was prepared under the same conditions as in example 1, except that: benzotriazole was not added as a preservative.
Comparative example 4
A concentrate was prepared under the same conditions as in example 1, except that: the preservatives benzoate, silicate and benzotriazole were not added.
Application example 5
The primary performance test (120 hours for the metal corrosion test and 72 hours longer than the 48 hours specified in the GB23436 standard) was performed on 0 ℃ window wash formulated using the solid wash concentrate prepared in comparative example 1 according to the GB23436-2009 results are shown in table 5.
TABLE 5
The results are shown in table 5, which indicates that the actual test effect is obviously poorer than the cleaning performance of comparative examples 1-4, the weight loss of the test piece is normal, but the influence of the vehicle window cleaning liquid blended by using the solid cleaning liquid concentrating agent on rubber and other non-metal parts is obviously increased, and the wiper strip can be damaged after long-term use.
Application example 6
The primary performance test (120 hours for the metal corrosion test and 72 hours longer than the 48 hours specified in the GB23436 standard) was performed on 0 ℃ window wash formulated with the solid wash concentrate prepared in comparative example 2 according to the GB23436-2009 standard, with the results shown in table 6.
TABLE 6
The results are shown in table 6, which shows that the actual test results of the comparative examples 1 to 4 show that the dirt removal rates of the examples 1 to 4 after cleaning are all above 30%, the dirt removal rate of the table 6 is lower than 30%, and other indexes are normal.
Application example 7
The primary performance test (120 hours for the metal corrosion test and 72 hours longer than the 48 hours specified in the GB23436 standard) was performed on 0 ℃ window wash formulated with the solid wash concentrate prepared in comparative example 3 according to the GB23436-2009 criteria and the results are shown in table 7.
TABLE 7
The results are shown in Table 7, which shows that the actual test effect is compared with the corrosion of the brass test piece in the examples 1-4, the adhesion corrosion exists on the galvanized steel sheet, the weight loss of the test piece exceeds the standard, the weight loss of the aluminum sheet is obviously increased, and the use requirement is not met.
Application example 8
The primary performance test (120 hours for the metal corrosion test and 72 hours longer than the 48 hours specified in GB 23436) was performed on a-40 ℃ window wash formulated using 95% ethanol plus the solid wash concentrate prepared in comparative example 4 according to GB23436-2009 with the results shown in table 8.
TABLE 8
The results are shown in Table 8, which shows that the test pieces in the practical test effects of comparative examples 1 to 4 are obviously seriously corroded, the weight loss of the test pieces exceeds the standard, the use effect is extremely poor, and the corrosion-resistant steel can not be used as a corrosion-resistant product.
In conclusion, according to the test surfaces of the window cleaning liquid prepared from the solid cleaning liquid concentrate at 0 ℃ and-40 ℃, the window cleaning liquid prepared from the solid cleaning liquid concentrate disclosed by the invention completely meets the technical requirement of GB23436 in each performance index, has the corrosion resistance exceeding the national standard requirement, can be widely applied to cleaning of inner and outer window glass of automobiles, trains, airplanes, buildings and the like, and has excellent corrosion resistance, rubber resistance, coating film aging resistance and oxidation resistance.
The preferred embodiments of the present invention have been described above in detail, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, many simple modifications can be made to the technical solution of the invention, including combinations of various technical features in any other suitable way, and these simple modifications and combinations should also be regarded as the disclosure of the invention, and all fall within the scope of the invention.
Claims (10)
1. The solid cleaning solution concentrate is characterized by comprising the following components: 3-9 parts of composite surfactant, 0.5-7 parts of sodium dodecyl sulfate, 0.5-2 parts of polyalcohol amine, 0.9-4.2 parts of preservative and 0.1-4 parts of anti-scaling agent; wherein the composite surfactant is a mixture of perfluorododecyl betaine and alkyl diphenyl ether disulfonate.
2. The concentrate of claim 1 wherein the solid cleaning solution concentrate has a composition of: 5-7 parts of composite surfactant, 0.8-3 parts of sodium dodecyl sulfate, 0.7-1.5 parts of polyalcohol amine, 1.3-2.5 parts of preservative and 0.2-0.6 part of anti-scaling agent;
preferably, the weight ratio of the perfluorododecyl betaine to the alkyl diphenyl ether disulfonate is 1: (5-10).
3. The concentrate of claim 1 or 2, wherein the polyalcohol amine is selected from diethanolamine and/or triethanolamine, preferably diethanolamine.
4. The concentrate of claim 1 or 2, wherein the preservative is selected from one or more of benzoate, silicate, benzotriazole, oleate, phosphate, sebacate and octodecanoate; preferably one or more of benzoate, silicate and benzotriazole;
preferably, in the solid cleaning solution concentrate, the preservative comprises the following components: 0.1-0.7 weight part of benzoate, 0.5-2 weight parts of silicate and 0.3-1.5 weight parts of benzotriazole;
preferably, in the solid cleaning solution concentrate, the preservative comprises the following components: 0.2 to 0.5 part by weight of benzoate; 0.6 to 1 weight portion of silicate and 0.5 to 1 weight portion of benzotriazole.
5. The concentrate of claim 1 or 2, wherein the anti-kogation agent is selected from one or more of polyanionic cellulose, ethylene diamine tetra methylene phosphonic acid, polyacrylate, aminotrimethylene phosphonic acid, hydroxyethylidene diphosphonic acid, 2-phosphonobutane-1, 2, 4-tricarboxylic acid, and polyoxyethylene ether glycerol phosphate; preferably polyanionic cellulose and/or ethylenediaminetetramethylenephosphonic acid;
preferably, in the solid cleaning solution concentrate, the anti-scaling agent comprises the following components: 0.05-2 parts of polyanionic cellulose and 0.05-2 parts of ethylene diamine tetramethylene phosphate;
more preferably, in the solid cleaning solution concentrate, the anti-scaling agent consists of: 0.1-0.3 weight portion of polyanionic cellulose and 0.1-0.3 weight portion of ethylenediamine tetramethylene phosphoric acid.
6. The concentrate of any of claims 1-5, wherein the solid cleaning solution concentrate further comprises 1-21 parts by weight of a binder; preferably, the binder is selected from one or more of sodium bicarbonate, water-soluble starch, sodium carbonate, powdered sugar, inorganic salts and mannitol; preferably sodium bicarbonate and/or water-soluble starch;
preferably, in the solid cleaning solution concentrate, the binder is composed of: 0.5-10 parts of sodium bicarbonate and 0.5-11 parts of water-soluble starch;
more preferably, in the solid cleaning solution concentrate, the binder has a composition of: 3-6 parts by weight of sodium bicarbonate; 2-5 parts of water-soluble starch.
7. The concentrate of any of claims 1-6 wherein the solid cleaning solution concentrate further comprises from 0.06 to 1 part by weight of a dye and/or bittering agent;
preferably, the solid cleaning solution concentrate further comprises: 0.03 to 0.5 parts by weight of said dye, 0.03 to 0.5 parts by weight of said bittering agent;
more preferably, the solid cleaning solution concentrate further comprises: 0.05-0.1 weight part of the dye and 0.05-0.1 weight part of the bittering agent.
8. A method of making a solid cleaning solution concentrate according to any of claims 1 to 7, comprising:
(1) mixing water, a composite surfactant and sodium dodecyl sulfate to obtain a first mixture;
(2) sequentially contacting the first mixture with polyalcohol amine, a preservative and an anti-scaling agent to obtain a second mixture, and extruding and granulating the second mixture.
9. Use of a solid cleaning solution concentrate according to any of claims 1 to 7 for cleaning glass.
10. The application of claim 9, wherein the application comprises:
the first method comprises the following steps: under the condition that the temperature is 0-50 ℃, the solid cleaning solution concentrating agent and water are compounded to prepare the cleaning agent, and the using amount of the water is 3000-4000mL relative to 1g of the solid cleaning solution concentrating agent;
and the second method comprises the following steps: under the condition that the temperature is-5 ℃ to-10 ℃, the solid cleaning solution concentrating agent and alcohol are compounded to prepare the cleaning agent, or the solid cleaning solution concentrating agent, alcohol and water are compounded to prepare the cleaning agent, and relative to 1g of the solid cleaning solution concentrating agent, the using amount of the alcohol is 560-;
and the third is that: under the condition that the temperature is-25 ℃ to-30 ℃, the solid cleaning solution concentrating agent and alcohol are compounded to prepare the cleaning agent, and relative to 1g of the solid cleaning solution concentrating agent, the dosage of the alcohol is 1900-.
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| WO2008017668A1 (en) * | 2006-08-09 | 2008-02-14 | Henkel Ag & Co. Kgaa | Washing and cleaning agent containing oxidoreductases and bleach activators |
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
| CN103221030A (en) * | 2010-01-12 | 2013-07-24 | 宝洁公司 | Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same |
| CN107937161A (en) * | 2017-10-26 | 2018-04-20 | 上海发凯化工有限公司 | A kind of concentrated type antifog glass cleaning agent |
| US20180251707A1 (en) * | 2017-03-01 | 2018-09-06 | Rust-Oleum Corporation | Gutter Cleaning Composition and Method |
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| US5074358A (en) * | 1990-07-03 | 1991-12-24 | Alberta Oil Sands Technology And Research Authority | Surfactant-stabilized foams for enhanced oil recovery |
| DE202005004452U1 (en) * | 2005-03-18 | 2005-05-25 | Wigo-Werk Kreuznach Chemische Fabrik Gmbh | Winter window cleaner concentrate, used at various dilutions for cleaning vehicle windows and lamps at low ambient temperature, contains bioalcohol, propantriol, propylene glycol, surfactant and optionally chelant |
| WO2008017668A1 (en) * | 2006-08-09 | 2008-02-14 | Henkel Ag & Co. Kgaa | Washing and cleaning agent containing oxidoreductases and bleach activators |
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