CN116004328A - Long-acting antibacterial floor cleaner composition and preparation method thereof - Google Patents
Long-acting antibacterial floor cleaner composition and preparation method thereof Download PDFInfo
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- CN116004328A CN116004328A CN202211686361.7A CN202211686361A CN116004328A CN 116004328 A CN116004328 A CN 116004328A CN 202211686361 A CN202211686361 A CN 202211686361A CN 116004328 A CN116004328 A CN 116004328A
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003899 bactericide agent Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000654 additive Substances 0.000 claims abstract description 16
- 239000002274 desiccant Substances 0.000 claims abstract description 15
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
- 239000006184 cosolvent Substances 0.000 claims abstract description 12
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 238000004140 cleaning Methods 0.000 claims description 14
- 230000003385 bacteriostatic effect Effects 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 8
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 8
- -1 silver ions Chemical class 0.000 claims description 8
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 6
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 6
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229960005323 phenoxyethanol Drugs 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 6
- 235000010234 sodium benzoate Nutrition 0.000 claims description 6
- 239000004299 sodium benzoate Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 4
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 claims description 3
- YHCCCMIWRBJYHG-UHFFFAOYSA-N 3-(2-ethylhexoxymethyl)heptane Chemical compound CCCCC(CC)COCC(CC)CCCC YHCCCMIWRBJYHG-UHFFFAOYSA-N 0.000 claims description 3
- PCWGTDULNUVNBN-UHFFFAOYSA-N 4-methylpentan-1-ol Chemical compound CC(C)CCCO PCWGTDULNUVNBN-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 claims description 3
- 239000002738 chelating agent Substances 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- 239000003605 opacifier Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 claims description 2
- 230000003115 biocidal effect Effects 0.000 claims 2
- 239000003139 biocide Substances 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 11
- 238000001035 drying Methods 0.000 abstract description 10
- 239000003599 detergent Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 241000894006 Bacteria Species 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000004519 grease Substances 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000000686 essence Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000013641 positive control Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a long-acting antibacterial floor cleaner composition and a preparation method thereof, wherein the cleaner comprises the following components: 0.5 to 10 percent of first bactericide, 0.5 to 3 percent of second bactericide, 0.05 to 3 percent of quick-drying agent, 4 to 50 percent of nonionic surfactant, 0.5 to 20 percent of cosolvent, 0.1 to 2 percent of additive and the balance of deionized water; the detergent composition prepared according to the proportion can keep long-term bacteriostasis for 48 hours after being used, and has low foam, easy rinsing and high drying speed.
Description
Technical Field
The invention relates to the technical field of cleaning gel beads, in particular to a long-acting antibacterial floor cleaner composition and a preparation method thereof.
Background
In recent years, consumers pay more and more attention to the problem of floor cleaning, but clean water mopping only can remove dust on the floor, cannot remove stubborn dirt, has no sterilization and bacteriostasis effects, is slow to dry, and wets and sticks feet. Chinese patent CN109294750A discloses antibacterial cleaning nano water and a preparation method thereof, but the antibacterial effect is poor, and the long-acting antibacterial effect can not be ensured under the cleaning effect.
Disclosure of Invention
The invention solves one of the problems existing in the related art to a certain extent, and therefore, the invention aims to provide a long-acting antibacterial floor cleaner composition which can realize long-acting antibacterial within 48 hours on the premise of keeping the cleaning force.
The above object is achieved by the following technical scheme:
a long-acting antibacterial floor cleaner composition comprises the following raw materials in percentage by mass: 0.1 to 10 percent of first bactericide, 0.1 to 3 percent of second bactericide, 0.05 to 3 percent of quick-drying agent, 4 to 50 percent of nonionic surfactant, 0.5 to 20 percent of cosolvent, 0.1 to 2 percent of additive and the balance of deionized water.
As a further improvement of the invention, the invention comprises the following raw material components in percentage by weight: 0.15 to 9 percent of first bactericide, 0.15 to 2.5 percent of second bactericide, 0.06 to 2.5 percent of quick-drying agent, 4.5 to 49 percent of nonionic surfactant, 1 to 19 percent of cosolvent, 0.15 to 1.5 percent of additive and the balance of deionized water.
As a further improvement of the invention, the first bactericide is one or more of 4,4' -dichloro-2-hydroxydiphenyl ether, benzalkonium chloride, sodium benzoate, silver ions and phenoxyethanol.
As a further improvement of the invention, the second bactericide is one or more of benzalkonium chloride, sodium benzoate, silver ions, phenoxyethanol and quaternary ammonium compounds.
As a further improvement of the invention, the quick-drying agent is one or more of 2-butoxyethanol, N-di (hydroxyethyl) cocoamide and 2-chloroethanol.
As a further improvement of the invention, the nonionic surfactant comprises one or more of branched fatty alcohol alkoxylation surfactant, isomeric tridecyl alcohol polyoxyethylene ether, branched grease vinyl ether and amine ether, polymer of methyl ethylene oxide and mono (2-ethylhexyl) ether, and alkyl polyglycoside.
As a further improvement of the invention, the cosolvent is one or more of glycerol, propylene glycol, sorbitol, ethylene glycol, mannitol and isohexanol.
As a further improvement of the invention, the additive is one or more of chelating agent, cosolvent, defoamer, essence, preservative, pigment and opacifier.
The invention aims to provide a long-acting antibacterial floor cleaner composition and a preparation method thereof, and long-acting antibacterial is realized within 48 hours on the premise of keeping cleaning force.
The above object is achieved by the following technical scheme:
a method of preparing a long-acting bacteriostatic floor cleaner composition comprising the steps of:
the preparation method of the cleaning agent comprises the following steps:
step one, adding a nonionic surfactant into a reaction kettle, and uniformly stirring;
step two, adding the solvent into a reaction kettle, and uniformly stirring;
step three, adding the first bactericide into the reaction kettle, and uniformly stirring;
step four, adding second bactericide water into the reaction kettle, and uniformly stirring;
step five, adding water into the reaction kettle, and uniformly stirring;
step six, adding the quick-drying agent into a reaction kettle, and uniformly stirring;
and seventhly, adding other additives into the reaction kettle, and uniformly stirring.
Compared with the prior art, the invention at least comprises the following beneficial effects:
1. the invention provides a long-acting antibacterial floor cleaner composition and a preparation method thereof, which realize long-acting antibacterial effect for 48 hours on the premise of keeping cleaning force, reduce foaming performance, reduce rinsing times of cleaning tools and achieve the effect of quick drying.
Detailed Description
The following examples illustrate the invention, but the invention is not limited to these examples. Modifications and equivalents of some of the technical features of the specific embodiments of the present invention may be made without departing from the spirit of the present invention, and they are all included in the scope of the claimed invention.
Embodiment one:
the long-acting antibacterial floor cleaner composition comprises the following raw materials in percentage by weight: 0.1 to 10 percent of first bactericide, 0.1 to 3 percent of second bactericide, 0.05 to 3 percent of quick-drying agent, 4 to 50 percent of nonionic surfactant, 0.5 to 20 percent of cosolvent, 0.1 to 2 percent of additive and the balance of deionized water.
The invention provides a long-acting antibacterial floor cleaner composition, which realizes long-acting antibacterial effect for 48 hours on the premise of keeping cleaning force, reduces foaming performance, reduces rinsing times of cleaning tools and achieves the effect of quick drying.
In some embodiments, the composition comprises the following raw materials in weight percent: 0.15 to 9 percent of first bactericide, 0.15 to 2.5 percent of second bactericide, 0.06 to 2.5 percent of quick-drying agent, 4.5 to 49 percent of nonionic surfactant, 1 to 19 percent of cosolvent, 0.15 to 1.5 percent of additive and the balance of deionized water.
The first bactericide is one or more of 4,4' -dichloro-2-hydroxydiphenyl ether, benzalkonium chloride, sodium benzoate, silver ions and phenoxyethanol.
The second bactericide is one or more of benzalkonium chloride, sodium benzoate, silver ions, phenoxyethanol and quaternary ammonium compounds.
The quick-drying agent is one or more of 2-butoxyethanol, N-di (hydroxyethyl) cocoamide and 2-chloroethanol.
The nonionic surfactant comprises one or more of branched fatty alcohol alkoxylation surfactant, isotridecyl alcohol polyoxyethylene ether, branched grease vinyl ether, amine ether, polymer of methyl ethylene oxide and mono (2-ethylhexyl) ether and alkyl polyglycoside.
The cosolvent is one or more of glycerol, propylene glycol, sorbitol, ethylene glycol, mannitol and isohexanol.
The additive is one or more of chelating agent, cosolvent, defoamer, essence, preservative, pigment and opacifier.
Embodiment two:
a method of preparing a long-acting bacteriostatic floor cleaner composition comprising the steps of:
the preparation method of the cleaning agent comprises the following steps:
step one, adding a nonionic surfactant into a reaction kettle, and uniformly stirring;
step two, adding the solvent into a reaction kettle, and uniformly stirring;
step three, adding the first bactericide into the reaction kettle, and uniformly stirring;
step four, adding second bactericide water into the reaction kettle, and uniformly stirring;
step five, adding water into the reaction kettle, and uniformly stirring;
step six, adding the quick-drying agent into a reaction kettle, and uniformly stirring;
and seventhly, adding other additives into the reaction kettle, and uniformly stirring.
Table 1 shows the proportions of the components of examples 1 to 5
TABLE 1 Table 2 shows the component ratios for examples 6-10
TABLE 2 Table 3 shows the component ratios for examples 11-15
TABLE 3 Table 3
And comparative examples 1 to 4 were set as follows:
comparative example 1
0.5% of benzalkonium chloride, 0.5% of 2-butoxyethanol, 5% of N-N-di (hydroxyethyl) cocoamide, 5% of branched grease vinyl ether and amine ether, 2% of alkyl polyglycoside, 4% of isohexide, 3% of other additives and the balance of water.
Comparative example 2
1% of benzalkonium chloride, 0.5% of 2-butoxyethanol, 5% of N-N-di (hydroxyethyl) cocoamide, 5% of branched grease vinyl ether and amine ether, 2% of alkyl polyglycoside, 4% of isohexide, 3% of other additives and the balance of water.
Comparative example 3
0.8% of 4,4' -dichloro-2-hydroxydiphenyl ether, 0.5% of 2-butoxyethanol, 5% of N-N-di (hydroxyethyl) cocoamide, 5% of branched grease vinyl ether and amine ether, 2% of alkyl polyglycoside, 4% of isohexide, 3% of other additives and the balance of water.
Comparative example 4
Commercially available floor cleaner
The examples 1 to 15 and comparative examples 1 to 4 were subjected to a bacteriostasis test, a detergency test, a foam amount test, a quick-drying test, respectively.
The 48-hour bacteriostasis test method is as follows
1ml of test bacterial suspension is evenly dripped on a sample, so that the even distribution of the test bacterial suspension is ensured, no residual liquid is remained on a flat plate, a plate cover is covered, and a sealing film is used for sealing so as to prevent evaporation.
Taking a group of test sample and control sample of bacteria, respectively putting into triangular flask with 100ml of 0.03mol/L phosphoric acid buffer solution, placing into a constant temperature shaking table at 37 ℃ for 250r/min, shaking for 10min to wash bacteria, taking 1ml for 10-time gradient dilution, and inoculating the flat plate with proper dilution by a pouring method to obtain 0h "
Time of exposure sample and number of bacteria of positive control.
The other group of plates for inoculating samples are placed in a 37 ℃ incubator for culturing '48' h, then added into a 100ml triangular flask of phosphoric acid buffer solution, placed in a 250r/min constant temperature shaking table at 37 ℃ for washing bacteria, shaken for 10min, 1ml is taken for 10-time gradient dilution, and the plates are inoculated by a pouring method with proper dilution to be used as the bacterial count of the samples with the contact time of '48' h.
The pour inoculation plate was placed in an incubator at 37℃and incubated for 48 hours, and the colony count was counted.
The 48-hour bacteriostasis rate (%) = [ B or C or (B+C)/2-A ]/[ B or C or (B+C)/2 ]. Times.100
A. Bacterial count on the "48" h test group samples;
B. "0"h number of bacteria on contact time sample;
C. "0"h contact time control number of bacteria on fabric;
table 4 shows the results of the bacteriostasis test for examples 1-15 and comparative examples 1-4:
TABLE 4 Table 4
As can be seen from the bacteriostasis test, the bacteriostasis effect of examples 14 and 15 is the best.
Detergency test was carried out according to the method 4.7 in QB/T4532-2013
Foam amount the initial foam amount (0 min) and the 5min foam amount were recorded as a 1:400 dilution, tested according to GB/T13173-2008 ross-mill method.
Quick-drying test, test method is as follows
Cleaning glazed tile with tap water, diluting the antibacterial cleaning floor gel beads with tap water 400 times, and mopping floor with a sponge mop or a cotton cloth mop. Recording the time of finishing the evaporation of the water of the glazed tile by using a stopwatch, wherein the water is evaporated to score 9-10 minutes in 2 minutes on the glazed tile, the water is evaporated to score 7-8 minutes in 4 minutes on the glazed tile, the water is evaporated to score 5-6 minutes in 6 minutes on the glazed tile, the water is evaporated to score 3-4 minutes in 8 minutes on the glazed tile, the water is evaporated to score 1-2 minutes in 10 minutes on the glazed tile, the water is evaporated to score 0 minutes above 10 minutes on the glazed tile,
table 5 shows the detergency, foam amount and drying rate test results for examples 1-15 and comparative examples 1-4:
| sample of | Detergency% | Foam amount ml 0min | Foam amount ml for 5min | Drying speed (full 10) |
| Example 1 | 90.56％ | 85 | 40 | 5 |
| Example 2 | 90.19％ | 85 | 40 | 5 |
| Example 3 | 90.88％ | 85 | 40 | 5 |
| Example 4 | 90.65％ | 85 | 40 | 5 |
| Example 5 | 90.78％ | 85 | 40 | 5 |
| Example 6 | 97.56％ | 80 | 35 | 6 |
| Example 7 | 97.68％ | 80 | 35 | 7 |
| Example 8 | 96.56％ | 75 | 35 | 9 |
| Example 9 | 96.33％ | 75 | 35 | 7 |
| Example 10 | 96.56％ | 75 | 35 | 8 |
| Example 11 | 98.98％ | 50 | 20 | 6 |
| Example 12 | 99.10％ | 50 | 20 | 7 |
| Example 13 | 97.67％ | 40 | 15 | 9 |
| Example 14 | 97.86％ | 40 | 15 | 9 |
| Example 15 | 96.56％ | 40 | 15 | 9 |
| Comparative example 1 | 90.77％ | 60 | 30 | 5 |
| Comparative example 2 | 90.89％ | 60 | 30 | 5 |
| Comparative example 3 | 91.56％ | 60 | 30 | 5 |
| Comparative example 4 | 90.23％ | 90 | 50 | 4 |
TABLE 5
To sum up the test results, the detergency of examples 11 to 15, the foam properties and the drying speed were superior to those of other examples and comparative examples, of which 13 to 15 were more preferable.
It can be seen from a combination of tables 1-5: the antibacterial performance and the antibacterial agent have a larger reasonable compounding relationship, the foam performance is closely related to the selection and compounding of the nonionic surfactant, and the drying speed is related to the selection and compounding of the quick-drying agent.
In summary, the embodiment of the invention provides a long-acting antibacterial floor cleaner composition, which utilizes reasonable selection and compounding of bactericides, quick-drying agents and nonionic surfactants to achieve long-acting antibacterial effect for 48 hours and good cleaning power, and also has the advantages of low foam and no rinsing, thus realizing green and environment-friendly call, good quick-drying performance, dryness and no sticking to feet.
The above examples illustrate only a few embodiments of the invention, which are described in detail and are not to be construed as limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.
The above-mentioned preferred embodiments should be regarded as illustrative examples of embodiments of the present application, and all such technical deductions, substitutions, improvements and the like which are made on the basis of the embodiments of the present application, are considered to be within the scope of protection of the present patent.
Claims (9)
1. A long-acting bacteriostatic floor cleaner composition, which is characterized by comprising the following components in percentage by mass: 0.1 to 10 percent of first bactericide, 0.1 to 3 percent of second bactericide, 0.05 to 3 percent of quick-drying agent, 4 to 50 percent of nonionic surfactant, 0.5 to 20 percent of cosolvent, 0.1 to 2 percent of additive and the balance of deionized water.
2. A long-acting bacteriostatic floor cleaner composition according to claim 1, characterized by the following composition in mass percent: 0.15 to 9 percent of first bactericide, 0.15 to 2.5 percent of second bactericide, 0.06 to 2.5 percent of quick-drying agent, 4.5 to 49 percent of nonionic surfactant, 1 to 19 percent of cosolvent, 0.15 to 1.5 percent of additive and the balance of deionized water.
3. A long-acting bacteriostatic floor cleaner composition according to claim 1, wherein said first biocide is one or more of 4,4' dichloro-2-hydroxydiphenyl ether, benzalkonium chloride, sodium benzoate, silver ions, phenoxyethanol.
4. A long-acting bacteriostatic floor cleaner composition according to claim 1, wherein said second biocide is one or more of benzalkonium chloride, sodium benzoate, silver ions, phenoxyethanol, quaternary ammonium compounds.
5. A long-acting bacteriostatic cleaning floor cleaner composition according to claim 1, characterized in that said quick-drying agent is one or more of 2-butoxyethanol, N-di (hydroxyethyl) cocoamide, 2-chloroethanol.
6. A long-acting bacteriostatic floor cleaner composition according to claim 1, characterized in that said nonionic surfactant comprises one or more of branched fatty alcohol alkoxylate surfactants, isotridecyl alcohol polyoxyethylene ethers, branched fatty vinyl ethers and amine ethers, polymers of methyl ethylene oxide with ethylene oxide and mono (2-ethylhexyl) ether, alkyl polyglycosides.
7. A long-acting bacteriostatic floor cleaner composition according to claim 1, wherein the co-solvent is one or more of glycerol, propylene glycol, sorbitol, ethylene glycol, mannitol, isohexanol.
8. A long-acting bacteriostatic floor cleaner composition according to claim 1, wherein said additive is one or more of chelating agents, co-solvents, defoamers, fragrances, preservatives, pigments, opacifiers.
9. A long-acting antibacterial floor cleaner composition and a preparation method thereof are characterized in that,
the preparation method of the bacteriostat comprises the following steps:
step one, adding a nonionic surfactant into a reaction kettle, and uniformly stirring;
step two, adding the solvent into a reaction kettle, and uniformly stirring;
step three, adding the first bactericide into the reaction kettle, and uniformly stirring;
step four, adding second bactericide water into the reaction kettle, and uniformly stirring;
step five, adding water into the reaction kettle, and uniformly stirring;
step six, adding the quick-drying agent into a reaction kettle, and uniformly stirring;
and seventhly, adding other additives into the reaction kettle, and uniformly stirring.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116948750A (en) * | 2023-09-20 | 2023-10-27 | 广州洁宜日化用品有限公司 | Preparation method of floor water for sweeping robot |
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| CN116948750B (en) * | 2023-09-20 | 2023-12-15 | 广州洁宜日化用品有限公司 | Preparation method of floor water for sweeping robot |
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