CN1834216A - High efficiency soap cleaning agent compsn. for textile dyeing soap cleaning and prepn. process - Google Patents
High efficiency soap cleaning agent compsn. for textile dyeing soap cleaning and prepn. process Download PDFInfo
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- CN1834216A CN1834216A CN 200510037588 CN200510037588A CN1834216A CN 1834216 A CN1834216 A CN 1834216A CN 200510037588 CN200510037588 CN 200510037588 CN 200510037588 A CN200510037588 A CN 200510037588A CN 1834216 A CN1834216 A CN 1834216A
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Abstract
This invention provides a method for manufacturing a high-efficiency environment-friendly soaping agent composition for cleaning printed fabrics. The soaping agent composition is manufactured by mixing and adequately stirring C12 fatty alcohol polyoxyethylene ether, coconut diethanolamide, sodium secondary alkane sulfonate (SAS), dyeing-proof salt (S), sodium tripolyphosphate and water. The soaping agent composition has good soaping and anti-contaminating effects on printed fabrics, and can improve the strength of printed fabrics.
Description
Technical field
The present invention relates to a kind of high-efficiency environment friendly soaping agent composition and method of making the same.More particularly, the present invention relates to a kind of textile printing and dyeing soaps with high-efficiency environment friendly soaping agent composition and method of making the same.
Background technology
The technology of soaping is occupied crucial status in the post-treatment process of cotton textiles and BLENDED FABRIC thereof.The technology of soaping is at present used soap powder or is used soda ash to add the soaping agent that detergent 209 develops into the use specialty from tradition.Traditional common soaping agent, the weak effect of soaping, product includes outside the carcinogenic compositions such as APEO, and foam is very high, and residual soaping agent also is difficult to clean on the cloth cover, in addition, there is a lot of soaping agents to adopt traditional materials such as oleic acid synthetic, finished color is Vandyke brown, to the shallow ground of stamp or bigger influence is arranged in vain, does not prevent staiing function in vain at all.
Along with the adding of WTO, China Textile is produced and presented stronger growth, and is in the market competition of fierceness, also more and more stricter to the various indexs of textiles.Wherein environmental requirement and the colour fastness (soaping fastness and dried, fastness to wet rubbing) to fabric is even more important.Need reach corresponding international standard mostly.
Summary of the invention
The purpose of this invention is to provide a kind of textile printing and dyeing soaps with high-efficiency environment friendly soaping agent composition, to solve the above-mentioned problems in the prior art, cotton textiles and BLENDED FABRIC thereof, the reactive dyestuffs of washing binding textiles, direct dyeing or the PRINTED FABRIC crossed with this high-efficiency environment friendly soaping agent compositions-treated of the present invention have well soaps and anti-contamination effect, and can improve fabric color vividness after soaping, improve the doing of fabric, wet friction and soaping fastness effectively.
Another object of the present invention provides a kind of textile printing and dyeing and soaps with high-efficiency environment friendly soaping agent preparation of compositions method.
The technological principle of soaping of high-efficiency environment friendly soaping agent of the present invention is:
The basic role of high-efficiency environment friendly soaping agent has two aspects: be to have stronger washing power on the one hand, auxiliary agent and the unconjugated dyestuff that remains on the fabric washed; Be dissemination on the other hand, auxiliary agent, dyestuff that washing is got off are evenly dispersed in the solution, form micella, prevent to stain on the cloth cover once more, thereby have reached the purpose of soaping.It has following performance:
The border is molten: increase the auxiliary agent remain on the fabric and the solvability of unconjugated dyestuff.
Chelating: play sequestering action with high volence metal ion, the softening washing water.
Disperse: the solid dirt is had poly-effect of anti-freezing and dissemination.
Washing: the auxiliary agent and the unconjugated dyestuff that will remain on the fabric wash.
Emulsification and anti-contamination effect: auxiliary agent, the dyestuff with washing is emulsified in the solution equably on the one hand, forms micella, prevents to stain on the fabric again, forms micella at fabric face on the other hand, and the auxiliary agent, the dyestuff that stop washing to be got off stain on the fabric again.
Shock absorption: replace using in the general washing alkaline matters such as soda ash.
Environmental protection: this product does not contain carcinogenic substances such as APEO, meets European Union's ecological textile environmental protection standard.
Textile printing and dyeing of the present invention is soaped with high-efficiency environment friendly soaping agent composition, and said composition is composed of the following components by weight percentage:
C12 aliphatic alcohol polyethenoxy (9) ether 5.0%-20.0%
Oleum Cocois (acid) diglycollic amide 6501 8.0%-10.0%
Seconary Alkane Sulphonate Sodium SAS 3.0%-6.0%
Tripoly phosphate sodium STPP 2.0%-4.0%
Reservehao S 2.0%-5.0%
Water 65.0%-70.0%
In above-mentioned high-efficiency environment friendly soaping agent composition, C12 aliphatic alcohol polyethenoxy (9) ether is to have superpower washing, emulsification, anti-contamination effect; Oleum Cocois (acid) diglycollic amide 6501 has good solubilising, washing function; Seconary Alkane Sulphonate Sodium SAS has good infiltration, washing effect; Reservehao S has solubilising, anti-contamination effect, especially has to improve the doing of fabric, fastness to wet rubbing and soaping fastness; Tripoly phosphate sodium STPP has good chelating, dispersion and pooling feature.The above-mentioned percentage range of the combination of these components and each component, determine by a large amount of tests, cotton textiles and BLENDED FABRIC thereof, the reactive dyestuffs of washing binding textiles, direct dyeing or the PRINTED FABRIC that aforesaid combination and percentage range were handled the present invention has well soaps and anti-contamination effect, and can improve fabric color vividness after soaping, improve the doing of fabric, wet friction and soaping fastness effectively.
In above-mentioned high-efficiency environment friendly soaping agent composition, the content of C12 aliphatic alcohol polyethenoxy (9) ether is preferably 8.0%-15.0%, and perhaps the content of Seconary Alkane Sulphonate Sodium SAS is preferably 4.0%-5.0%.
Preparing high-efficiency environment friendly soaping agent method for compositions of the present invention is made up of following steps successively:
A, in reactor, add entry and tripoly phosphate sodium STPP, stirred 1 hour, form solution;
B, C12 aliphatic alcohol polyethenoxy (9) ether, Oleum Cocois (acid) diglycollic amide 6501 and Seconary Alkane Sulphonate Sodium SAS are joined in the above-mentioned solution;
C, with this solution stirring 4 hours;
D, add reservehao S to this solution;
E, stirring 1 hour are finished product.
Above steps is all carried out at normal temperatures and pressures.
High-efficiency environment friendly soaping agent composition of the present invention can be applied on the fabric with following method:
Take by weighing 0.3 part of soaping agent and be dissolved in 92.7 parts of water, add 7 parts of emerald green blue DYED FABRICS of the knitting activity of cotton, be warming up to 98 ℃ and soaped 10 minutes, cooling, cold wash oven dry.
Embodiment
Further specify the present invention below by embodiment and Comparative Examples.In the following Examples and Comparative Examples, with numeric representation do, fastness to wet rubbing, soaping fastness and anti-fouling index.Numerical value is big more, illustrates that this performance is excellent more, and this soaping agent performance is good more.
Embodiment 1
At normal temperatures and pressures, specified each component is made by following steps successively in the according to the form below 1 respectively: add entry and tripoly phosphate sodium STPP in reactor, stirred 1 hour, form solution; C12 aliphatic alcohol polyethenoxy (9) ether, Oleum Cocois (acid) diglycollic amide 6501 and Seconary Alkane Sulphonate Sodium SAS are joined in the above-mentioned solution; This solution stirring 4 hours; Add reservehao S to this solution; Stirred 1 hour, and be finished product.Adopt following method to be applied on the fabric: to take by weighing 0.3 part of soaping agent and be dissolved in 92.7 parts of water, add 7 parts of emerald green blue DYED FABRICS of the knitting activity of cotton, be warming up to 98 ℃ and soaped 10 minutes, cooling, cold wash oven dry.Test then that it is done, fastness to wet rubbing, soaping fastness and anti-fouling index, in table 1, listed test result.
Embodiment 2
Specified each component concentration repeats the method for embodiment 1 in the according to the form below 1, but adopts C12 aliphatic alcohol polyethenoxy (9) ether, and the content preferable range of Seconary Alkane Sulphonate Sodium SAS has been listed test result in table 1.
Comparative Examples 1
At normal temperatures and pressures, specified each component concentration directly adds C12 aliphatic alcohol polyethenoxy (9) ether, Oleum Cocois (acid) diglycollic amide 6501, Seconary Alkane Sulphonate Sodium SAS, tripoly phosphate sodium STPP, reservehao S, water together in the according to the form below 1, stirs the soaping agent composition of making after 5 hours.Adopt following method to be applied on the fabric: to take by weighing 0.3 part of soaping agent and be dissolved in 92.7 parts of water, add 7 parts of emerald green blue DYED FABRICS of the knitting activity of cotton, be warming up to 98 ℃ and soaped 10 minutes, cooling, cold wash oven dry.Test then that it is done, fastness to wet rubbing, soaping fastness and anti-fouling index, in table 1, listed test result.
Comparative Examples 2
At normal temperatures and pressures, specified each component concentration directly adds Oleum Cocois (acid) diglycollic amide 6501, Seconary Alkane Sulphonate Sodium SAS, tripoly phosphate sodium STPP, water together in the according to the form below 1, stirs the soaping agent composition of making after 5 hours.Adopt following method to be applied on the fabric: to take by weighing 0.3 part of soaping agent and be dissolved in 92.7 parts of water, add 7 parts of emerald green blue DYED FABRICS of the knitting activity of cotton, be warming up to 98 ℃ and soaped 10 minutes, cooling, cold wash oven dry.Test then that it is done, fastness to wet rubbing, soaping fastness and anti-fouling index, in table 1, listed test result.
The test data explanation of the doing of fabric, fastness to wet rubbing, soaping fastness and anti-fouling index in each embodiment and the Comparative Examples in the following table 1, no matter on single performance, still on over-all properties, every performance of high-efficiency environment friendly soaping agent composition of the present invention all is better than the soaping agent composition of Comparative Examples significantly.Table 1 is as follows:
| Each component concentration (weight part) and fabric property | Embodiment 1 | Embodiment 2 | Comparative Examples 1 | Comparative Examples 2 |
| C12 aliphatic alcohol polyethenoxy (9) ether | 16 | 12 | 3 | |
| Oleum Cocois (acid) diglycollic amide 6501 | 8 | 9 | 12 | 15 |
| Seconary Alkane Sulphonate Sodium SAS | 6 | 5 | 8 | 10 |
| Tripoly phosphate sodium STPP | 3 | 4 | 6 | 5 |
| Reservehao S | 2 | 3 | 1 | |
| Water | 65 | 67 | 70 | 70 |
| Dry fastness | 4.5 | 4.7 | 3.8 | 3.3 |
| Fastness to wet rubbing | 3.4 | 3.6 | 3.0 | 2.6 |
| Soaping fastness | 3.6 | 3.8 | 3.0 | 2.5 |
| Anti-fouling index | 4.0 | 4.5 | 2.5 | 2.0 |
Claims (5)
1, a kind of textile printing and dyeing is soaped with high-efficiency environment friendly soaping agent composition, and said composition is composed of the following components by weight percentage:
C12 aliphatic alcohol polyethenoxy (9) ether 5.0%-20.0%
Oleum Cocois (acid) diglycollic amide 6501 8.0%-10.0%
Seconary Alkane Sulphonate Sodium SAS 3.0%-6.0%
Tripoly phosphate sodium STPP 2.0%-4.0%
Reservehao S 2.0%-5.0%
Water 65.0%-70.0%
2, according to the described high-efficiency environment friendly soaping agent of claim 1 composition, wherein, the content of C12 aliphatic alcohol polyethenoxy (9) ether is 8.0%-15.0%.
3, according to the described high-efficiency environment friendly soaping agent of claim 1 composition, wherein, the content of Seconary Alkane Sulphonate Sodium SAS is 4.0%-5.0%.
4, the described high-efficiency environment friendly soaping agent of preparation claim 1 method for compositions is characterized in that this method may further comprise the steps composition:
A, in reactor, add entry and tripoly phosphate sodium STPP, stirred 1 hour, form solution;
B, C12 aliphatic alcohol polyethenoxy (9) ether, Oleum Cocois (acid) diglycollic amide 6501 and Seconary Alkane Sulphonate Sodium SAS are joined in the above-mentioned solution;
C, with this solution stirring 4 hours;
D, add reservehao S to this solution;
E, stirring 1 hour are finished product.
Above step is all carried out at normal temperatures and pressures.
5, according to claim 1,4 described high-efficiency environment friendly soaping agent preparation of compositions methods, said composition has following physico-chemical property:
1. outward appearance: water white transparency thick liquid
2. pH value: 6.0-8.0
3. solid content: 30.0-40.0%
4. solvability: soluble in water
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100375889A CN100432205C (en) | 2005-09-29 | 2005-09-29 | High efficiency soap cleaning agent compsn. for textile dyeing soap cleaning and prepn. process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100375889A CN100432205C (en) | 2005-09-29 | 2005-09-29 | High efficiency soap cleaning agent compsn. for textile dyeing soap cleaning and prepn. process |
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| CN1834216A true CN1834216A (en) | 2006-09-20 |
| CN100432205C CN100432205C (en) | 2008-11-12 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781613B (en) * | 2009-01-19 | 2012-03-21 | 浙江传化股份有限公司 | Acid soaping agent |
| CN102454126A (en) * | 2010-10-18 | 2012-05-16 | 南通曙光染织有限公司 | Efficient environment-friendly neutral soaping agent for reactive dye and preparation method for efficient environment-friendly neutral soaping agent |
| CN103388269A (en) * | 2010-10-18 | 2013-11-13 | 南通斯恩特纺织科技有限公司 | Preparation method of high-efficiency environmentally-friendly soaping agent of reactive dye |
| CN104263567A (en) * | 2014-09-27 | 2015-01-07 | 无锡市东北塘宏良染色厂 | Surfactant for printing and dyeing |
| CN106118915A (en) * | 2016-07-11 | 2016-11-16 | 山东如意科技集团有限公司 | A kind of soaping agent for highly dense flower pattern cotton textiles figured cloth and technique of soaping thereof |
| CN106380543A (en) * | 2016-08-29 | 2017-02-08 | 上海东升新材料有限公司 | Preparation method of environment-friendly soaping agent and product thereof |
| CN106833940A (en) * | 2017-02-10 | 2017-06-13 | 苏州市统业化工有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN111748418A (en) * | 2020-07-23 | 2020-10-09 | 石狮市瑞鹰纺织科技有限公司 | Low-temperature cleaning agent and application thereof in washing process after dyeing of polyester knitted fabric |
| CN111764186A (en) * | 2019-03-31 | 2020-10-13 | 江苏海云花新材料有限公司 | Preparation method of soaping agent for polyester-polyurethane fastness |
| CN111979061A (en) * | 2019-05-23 | 2020-11-24 | 合肥科源应用化工研究所 | Foam detergent for nuclear facilities and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058228A (en) * | 1990-07-14 | 1992-01-29 | 萧山市化学助剂厂 | A kind of chemical detergent powder and manufacture method |
| CN1354233A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Cleaning agent for removing dyeing and printing loose colour |
-
2005
- 2005-09-29 CN CNB2005100375889A patent/CN100432205C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781613B (en) * | 2009-01-19 | 2012-03-21 | 浙江传化股份有限公司 | Acid soaping agent |
| CN102454126A (en) * | 2010-10-18 | 2012-05-16 | 南通曙光染织有限公司 | Efficient environment-friendly neutral soaping agent for reactive dye and preparation method for efficient environment-friendly neutral soaping agent |
| CN103388269A (en) * | 2010-10-18 | 2013-11-13 | 南通斯恩特纺织科技有限公司 | Preparation method of high-efficiency environmentally-friendly soaping agent of reactive dye |
| CN102454126B (en) * | 2010-10-18 | 2014-04-23 | 南通斯恩特纺织科技有限公司 | Efficient environment-friendly neutral soaping agent for reactive dye and preparation method for efficient environment-friendly neutral soaping agent |
| CN103388269B (en) * | 2010-10-18 | 2014-12-10 | 南通斯恩特纺织科技有限公司 | Preparation method of high-efficiency environmentally-friendly soaping agent of reactive dye |
| CN104263567A (en) * | 2014-09-27 | 2015-01-07 | 无锡市东北塘宏良染色厂 | Surfactant for printing and dyeing |
| CN106118915A (en) * | 2016-07-11 | 2016-11-16 | 山东如意科技集团有限公司 | A kind of soaping agent for highly dense flower pattern cotton textiles figured cloth and technique of soaping thereof |
| CN106118915B (en) * | 2016-07-11 | 2019-01-22 | 山东如意科技集团有限公司 | A kind of soaping agent and its technique of soaping for highly dense flower pattern pure cotton figured cloth |
| CN106380543A (en) * | 2016-08-29 | 2017-02-08 | 上海东升新材料有限公司 | Preparation method of environment-friendly soaping agent and product thereof |
| CN106380543B (en) * | 2016-08-29 | 2018-12-18 | 上海东升新材料有限公司 | A kind of preparation method and products thereof of environment-friendly type soaping agent |
| CN106833940A (en) * | 2017-02-10 | 2017-06-13 | 苏州市统业化工有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN111764186A (en) * | 2019-03-31 | 2020-10-13 | 江苏海云花新材料有限公司 | Preparation method of soaping agent for polyester-polyurethane fastness |
| CN111979061A (en) * | 2019-05-23 | 2020-11-24 | 合肥科源应用化工研究所 | Foam detergent for nuclear facilities and preparation method thereof |
| CN111748418A (en) * | 2020-07-23 | 2020-10-09 | 石狮市瑞鹰纺织科技有限公司 | Low-temperature cleaning agent and application thereof in washing process after dyeing of polyester knitted fabric |
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| CN100432205C (en) | 2008-11-12 |
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