CN106118915A - A kind of soaping agent for highly dense flower pattern cotton textiles figured cloth and technique of soaping thereof - Google Patents
A kind of soaping agent for highly dense flower pattern cotton textiles figured cloth and technique of soaping thereof Download PDFInfo
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- CN106118915A CN106118915A CN201610540354.4A CN201610540354A CN106118915A CN 106118915 A CN106118915 A CN 106118915A CN 201610540354 A CN201610540354 A CN 201610540354A CN 106118915 A CN106118915 A CN 106118915A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Abstract
The invention belongs to the technical field of dyeing and finishing, be specifically related to a kind of soaping agent for highly dense flower pattern cotton textiles figured cloth and technique of soaping thereof.This kind is for the soaping agent of highly dense flower pattern cotton textiles figured cloth, including following raw material: N vinyl pyrrolidone, sodium lauryl sulphate, δ laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic anhydride, polyacrylic acid, compound soap enzyme, 18-amine. polyoxyethylene ether, SAS and thiourea dioxide;Wherein compound enzyme of soaping is soaped enzyme by laccase, lipopeptid enzyme, Eurolan RP and EOQ enzyme of soaping forms.This soaping agent foam when soaping highly dense flower pattern cotton textiles figured cloth is few, becomes the bubble time short;Textile figured cloth will not faded color after it is soaped;And the highly dense flower pattern Cotton Gossypii cloth substantially colorless difference of dyed fabric after working in coordination with the PROCESS FOR TREATMENT of soaping described in combination through this soaping agent and strength loss, compared with technique of soaping with tradition, color fastness is higher, and reduces operation, time-saving energy-saving.
Description
Technical field
The invention belongs to the technical field of dyeing and finishing, be specifically related to a kind of soaping agent for highly dense flower pattern cotton textiles figured cloth and
Its technique of soaping.
Background technology
Will carry out washing, soaping after the dyeing such as reactive dye, direct dyes, acid stain, disperse dyes, need to soap
Agent, pure cotton fabric, after reactive dyeing, needs to select suitable soaping agent to soap, to improve product quality and to reduce
Energy consumption.
During reactive dyeing and stamp, reactive dye combine imparting dyeing by covalent bond and PRINTED FABRIC is excellent
Good dyefastness, but reactive dye are susceptible to hydrolysis in the basic conditions, form hydrolised dye and can not occur with fiber
Reaction, some is dye adsorption has neither part nor lot in covalent reaction in fiber surface, it is necessary in dyeing or the post processing of stamp
Journey cleans up, otherwise can affect the fastness of dyeing and PRINTED FABRIC.Therefore, the washing post processing of reactive dye is whole dye
Color or the important step of printing technology process, significant with the fastness of PRINTED FABRIC and quality for dyeing.Activity dye
Material is mainly used in dyeing and the stamp of cellulose fibre, while upper dye and set, reactive dye owing to being susceptible to hydrolysis,
Dye utilization rate is low, and loose colour is serious, not only affects the color fastness of fabric, and easily makes white background staining.Loose colour is removed dry
Clean difficulty is big, water consumption is big, therefore reactive dyeing and PRINTED FABRIC soap for effectively removing loose colour, improve dyeing and produce
The color fastness of product is particularly important.
Presently commercially available is mostly phosphorous basic soap lotion, and when soaping, in bath, cloth cover pH value is 9~10, and temperature is up to 98
~100 DEG C.This condition easily makes reactive dye generation scission of link, and washing liquid foam is many, consumes substantial amounts of water, is also possible in waste liquid
Containing APEO or phosphate ester surfactant, it is unfavorable for environmental protection, undesirable in terms of energy-saving and emission-reduction.
Highly dense flower pattern cotton textiles figured cloth is rich and gaudy due to color, and dye dosage is big, and washing loose colour is relatively heavy, evaporates rear water
The color fastness washed and vividness are largely dependent on the effect soaped, and therefore select the soaping agent of function admirable, white to preventing
It is particularly important that ground stains raising vividness.
Summary of the invention
Present invention aims to current soaping agent pH value during soaping high, temperature is high and causes reactive dye
Scission of link, while washing liquid foam is many, consumes substantial amounts of water, is unfavorable for that the problem of environmental protection provides a kind of textile for highly dense flower pattern
The soaping agent of figured cloth and technique of soaping thereof, this soaping agent foam when soaping highly dense flower pattern cotton textiles figured cloth is few, becomes the bubble time short;Pure
Cotton Gossypii cloth will not faded color after it is soaped;And highly dense flower pattern Cotton Gossypii cloth is working in coordination with soaping described in combination through this soaping agent
The substantially colorless difference of dyed fabric after PROCESS FOR TREATMENT and strength loss, compared with technique of soaping with tradition, color fastness is higher, and subtracts
Few operation, time-saving energy-saving.
The technical scheme is that a kind of soaping agent for highly dense flower pattern cotton textiles figured cloth, including following raw material: N-second
Vinyl pyrrolidone, sodium lauryl sulphate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylene-1,1-diphosphonic
Acid, maleic anhydride, polyacrylic acid, compound soap enzyme, 18-amine. polyoxyethylene ether, SAS and thiourea dioxide;Its
In compound enzyme of soaping soaped enzyme by laccase, lipopeptid enzyme, Eurolan RP and EOQ enzyme of soaping forms.
The described soaping agent for highly dense flower pattern cotton textiles figured cloth, according to NVP described in mass ratio: 12
Alkyl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic anhydride: polypropylene
Acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide is (0.5-1.5): (1-2.5): (2-
3.5): (4-5): (1.2-2.0): (0.3-1.0): (1.1-1.5): (0.5-2.0): (3-6): (1.2-1.5): (1.0-1.6).
The described soaping agent for highly dense flower pattern cotton textiles figured cloth, according to NVP described in mass ratio: 12
Alkyl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic anhydride: polypropylene
Acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide is 1.2:1.5:2:5:1.3:0.5:
1.3:1.5:4:1.3:1.5.
The described soaping agent for highly dense flower pattern cotton textiles figured cloth, according to NVP described in mass ratio: 12
Alkyl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic anhydride: polypropylene
Acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide is 0.8:2.0:3.0:4.5:1.8:
0.7:1.5:0.7:3.5:1.5:1.2.
According to quality than laccase in described compound enzyme of soaping: lipopeptid enzyme: Eurolan RP enzyme: EOQ enzyme of soaping of soaping is
0.2:0.5:1.0:0.6。
A kind of technique of soaping using the described soaping agent for highly dense flower pattern cotton textiles figured cloth, comprises the following steps:
(1) cold water is washed: first highly dense flower pattern cotton textiles figured cloth is carried out cold water and washes 5-8 minute;Cold water temperature is 15-20 DEG C;
(2) pickling: the textile figured cloth washed through subcooled water carries out pickling, adds 0.5-1.0g/L dodecyl dimethyl ethoxy
Ammonia chloride, carries out pickling 10-15 minute under the conditions of temperature is 40-45 DEG C;
(3) soap: add described soaping agent and under the conditions of temperature is 50-55 DEG C, the textile figured cloth after pickling is soaped 5-10
Minute;
(4) hot water wash: the textile figured cloth after soaping carries out hot water wash 5-8 minute at temperature is 70-75 DEG C.
The soap consumption of middle soaping agent of described step (3) is 0.5-0.7g/L.This amount ranges is used to be possible not only to realize
To floating
The optimal adsorption of dichroic dye molecule, peptizaiton, and it is significantly less than the consumption of current existing soaping agent.
Described step (3) middle pH value of soaping is 4-6.What under the conditions of this pH, collaborative described soaping agent reached soaps effect such as
Under: fastness to rubbing unlubricated friction is 5 grades, wet rubs as 4-5 level, it is seen that not only will not be because of process alkalescence mistake of soaping under this pH value condition
High so that reactive dye generation scission of link on textile figured cloth and come off, and the effect that makes to soap significantly is obviously improved.
Bath raio during described step (3) is soaped is 1:(10-30).
The invention have the benefit that the soaping agent for highly dense flower pattern cotton textiles figured cloth of the present invention, including following former
Material: NVP, sodium lauryl sulphate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, hydroxyl second
Fork di 2 ethylhexyl phosphonic acid, maleic anhydride, polyacrylic acid, compound soap enzyme, 18-amine. polyoxyethylene ether, SAS and sulfur dioxide
Urea;Wherein compound enzyme of soaping is soaped enzyme by laccase, lipopeptid enzyme, Eurolan RP and EOQ enzyme of soaping forms.
Macromolecular compound is not only compounded by described soaping agent, simultaneously by multiple for macromolecule compound collaborative biology simultaneously
Conjunction is soaped enzyme, and the carrying out after reactive dyeing is soaped, and the most under certain condition, utilizes compound enzymatic oxidation of soaping
Hydrolised dye and the reactive dye of non-set, by physics and the synergism of chemistry, make the loose colour on fabric be easier to eccysis,
But the dyestuff impact on being combined by covalent bond with fiber is the least, has excellent removal floating color ability, significantly improves dyeing
Fastness, greatly reduces the colourity of residual liquid.Compared with tradition soaping agent the resistance to soaping fastness of textile figured cloth can improve 1.5-
2 grades, moisture-proof colorfastness to rubbing can improve 1~1.5 grade, and the colourity of waste water averagely reduces more than 85%.
In use will not produce foam, dispersibility is strong, makes the cleaning after soaping be more prone to, and reduces environment dirty
Dye.This soaping agent has good colloid property simultaneously, can form complex with dyestuff, and dyestuff under preventing from washing is counter is stained with cloth cover.
Therefore can effectively remove loose colour, improve effect of soaping.
Determine that the optimum process condition using described soaping agent to carry out soaping is temperature 50-55 DEG C by orthogonal experiment, time
Between 10-15 minute, described soaping agent combine the textile figured cloth color fastness to washing after this temperature and time is soaped, rub resistance color jail
Degree, the especially more existing soaping agent of fastness to wet rubbing all can improve 1-2 level.Thus, decrease operation and shorten the washing time,
Save with water, but effect of soaping is generally not as routine is soaped technique.Soap process ration with tradition, when soaping after shortening dye
Between, improve production efficiency, be greatly saved " water, electricity, vapour ", reduce sewage discharge and cost of sewage disposal, reduce and produce into
This.
The more existing conventional soaping agent of the use temperature of described soaping agent can reduce 40-48 DEG C, thus reduce steam consumption 5~
7 t/t cloth, cloth per ton can economize on water 35~45 tons, reduces process costs of soaping, and the working cycle of whole technique of soaping shortens 2-
2.5 hours, save energy consumption and improve work efficiency;And the most more conventional soaping agent of the indexs such as the color fastness of product improves at least 1
Level.
COMPREHENSIVE CALCULATING, cloth per ton can reduce production cost at least thousand yuan, has significant economic benefit.
In sum, this soaping agent foam when soaping highly dense flower pattern cotton textiles figured cloth is few, becomes the bubble time short;Textile figured cloth warp
It will not faded color after soaping;And highly dense flower pattern Cotton Gossypii cloth is working in coordination with the PROCESS FOR TREATMENT of soaping described in combination through this soaping agent
After the substantially colorless difference of dyed fabric and strength loss, compared with technique of soaping with tradition, color fastness is higher, and reduce operation,
Time-saving energy-saving.
Detailed description of the invention
Below by embodiment, the present invention will be described in detail.
Embodiment 1
The described soaping agent for highly dense flower pattern cotton textiles figured cloth, including following raw material: NVP, dodecyl sulfur
Acid sodium, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic anhydride, polypropylene
Acid, compound soap enzyme, 18-amine. polyoxyethylene ether, SAS and thiourea dioxide;According to N-ethylene described in mass ratio
Base ketopyrrolidine: sodium lauryl sulphate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid:
Maleic anhydride: polyacrylic acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide is 1.2:
1.5:2:5:1.3:0.5:1.3:1.5:4:1.3:1.5.Wherein compound enzyme of soaping is soaped by laccase, lipopeptid enzyme, Eurolan RP
Enzyme and EOQ soap enzyme composition;According to quality than laccase in described compound enzyme of soaping: lipopeptid enzyme: Eurolan RP soaps enzyme: EOQ
Enzyme of soaping is 0.2:0.5:1.0:0.6.
Use the technique of soaping of the described soaping agent for highly dense flower pattern cotton textiles figured cloth, comprise the following steps:
(1) cold water is washed: first highly dense flower pattern cotton textiles figured cloth is carried out cold water and washes 6 minutes;Cold water temperature is 18 DEG C;
(2) pickling: the textile figured cloth washed through subcooled water carries out pickling, adds 0.7g/L dodecyl dimethyl ethoxy chlorination
Amine, carries out pickling 10 minutes under the conditions of temperature is 45 DEG C;
(3) soap: add described soaping agent and under the conditions of temperature is 53 DEG C, the textile figured cloth after pickling is soaped 8 minutes;
The consumption of soaping agent is 0.6g/L;PH value is 5;Bath raio is 1:15;
(4) hot water wash: the textile figured cloth after soaping carries out hot water wash 6 minutes at temperature is 72 DEG C.
Embodiment 2
The described soaping agent for highly dense flower pattern cotton textiles figured cloth, including following raw material: NVP, dodecyl sulfur
Acid sodium, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic anhydride, polypropylene
Acid, compound soap enzyme, 18-amine. polyoxyethylene ether, SAS and thiourea dioxide;According to N-ethylene described in mass ratio
Base ketopyrrolidine: sodium lauryl sulphate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid:
Maleic anhydride: polyacrylic acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide is 0.8:
2.0:3.0:4.5:1.8:0.7:1.5:0.7:3.5:1.5:1.2.Wherein it is combined and soaps enzyme by laccase, lipopeptid enzyme, Eurolan
RP soaps enzyme and EOQ soaps enzyme composition;According to quality than laccase in described compound enzyme of soaping: lipopeptid enzyme: Eurolan RP soaps
Enzyme: EOQ enzyme of soaping is 0.2:0.5:1.0:0.6.
A kind of technique of soaping using the described soaping agent for highly dense flower pattern cotton textiles figured cloth, comprises the following steps:
(1) cold water is washed: first highly dense flower pattern cotton textiles figured cloth is carried out cold water and washes 8 minutes;Cold water temperature is 15 DEG C;
(2) pickling: the textile figured cloth washed through subcooled water carries out pickling, adds 0.5g/L dodecyl dimethyl ethoxy chlorination
Amine, carries out pickling 15 minutes under the conditions of temperature is 40 DEG C;
(3) soap: add described soaping agent and under the conditions of temperature is 50 DEG C, the textile figured cloth after pickling is soaped 10 minutes;
The consumption of soaping agent is 0.5-0.7g/L;PH value is 4-6;Bath raio is 1:(10-30);
(4) hot water wash: the textile figured cloth after soaping carries out hot water wash 5 minutes at temperature is 75 DEG C.
Claims (9)
1. the soaping agent for highly dense flower pattern cotton textiles figured cloth, it is characterised in that include following raw material: N-ethenyl pyrrolidone
Ketone, sodium lauryl sulphate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic acid
Acid anhydride, polyacrylic acid, compound soap enzyme, 18-amine. polyoxyethylene ether, SAS and thiourea dioxide;Wherein it is combined and soaps
Enzyme is soaped enzyme by laccase, lipopeptid enzyme, Eurolan RP and EOQ soaps, and enzyme forms.
The most according to claim 1 for the soaping agent of highly dense flower pattern cotton textiles figured cloth, it is characterised in that described in mass ratio
NVP: sodium lauryl sulphate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: hydroxy ethylidene
Di 2 ethylhexyl phosphonic acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide
For (0.5-1.5): (1-2.5): (2-3.5): (4-5): (1.2-2.0): (0.3-1.0): (1.1-1.5): (0.5-2.0): (3-
6): (1.2-1.5): (1.0-1.6).
The most according to claim 2 for the soaping agent of highly dense flower pattern cotton textiles figured cloth, it is characterised in that described in mass ratio
NVP: sodium lauryl sulphate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: hydroxy ethylidene
Di 2 ethylhexyl phosphonic acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide
For 1.2:1.5:2:5:1.3:0.5:1.3:1.5:4:1.3:1.5.
The most according to claim 2 for the soaping agent of highly dense flower pattern cotton textiles figured cloth, it is characterised in that described in mass ratio
NVP: sodium lauryl sulphate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: hydroxy ethylidene
Di 2 ethylhexyl phosphonic acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: 18-amine. polyoxyethylene ether: SAS: thiourea dioxide
For 0.8:2.0:3.0:4.5:1.8:0.7:1.5:0.7:3.5:1.5:1.2.
5. according to the soaping agent being used for highly dense flower pattern cotton textiles figured cloth according to any one of claim 1-4, it is characterised in that described
According to quality than laccase in compound enzyme of soaping: lipopeptid enzyme: Eurolan RP enzyme: EOQ enzyme of soaping of soaping is 0.2:0.5:1.0:
0.6。
6. use the technique of soaping of soaping agent for highly dense flower pattern cotton textiles figured cloth described in claim 1, including following step
Rapid:
(1) cold water is washed: first highly dense flower pattern cotton textiles figured cloth is carried out cold water and washes 5-8 minute;Cold water temperature is 15-20 DEG C;
(2) pickling: the textile figured cloth washed through subcooled water carries out pickling, adds 0.5-1.0g/L dodecyl dimethyl ethoxy
Ammonia chloride, carries out pickling 10-15 minute under the conditions of temperature is 40-45 DEG C;
(3) soap: add described soaping agent and under the conditions of temperature is 50-55 DEG C, the textile figured cloth after pickling is soaped 5-10
Minute;
(4) hot water wash: the textile figured cloth after soaping carries out hot water wash 5-8 minute at temperature is 70-75 DEG C.
Soap the most according to claim 6 technique, it is characterised in that the soap consumption of middle soaping agent of described step (3) is
0.5-0.7g/L。
Soap the most according to claim 6 technique, it is characterised in that described step (3) middle pH value of soaping is 4-6.
Soap the most according to claim 6 technique, it is characterised in that the bath raio during described step (3) is soaped is 1:(10-
30).
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CN201610540354.4A CN106118915B (en) | 2016-07-11 | 2016-07-11 | A kind of soaping agent and its technique of soaping for highly dense flower pattern pure cotton figured cloth |
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CN107955724A (en) * | 2017-11-29 | 2018-04-24 | 鹿寨卡森洗涤服务有限公司 | Cloth grass detergent |
CN108708196A (en) * | 2018-05-10 | 2018-10-26 | 浙江科峰新材料有限公司 | A kind of soaping agent and its preparation process |
CN112695549A (en) * | 2020-12-28 | 2021-04-23 | 浙江震东新材料有限公司 | Low-temperature soaping agent for printing of reactive dye and preparation method thereof |
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