CN106118915B - A kind of soaping agent and its technique of soaping for highly dense flower pattern pure cotton figured cloth - Google Patents
A kind of soaping agent and its technique of soaping for highly dense flower pattern pure cotton figured cloth Download PDFInfo
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- CN106118915B CN106118915B CN201610540354.4A CN201610540354A CN106118915B CN 106118915 B CN106118915 B CN 106118915B CN 201610540354 A CN201610540354 A CN 201610540354A CN 106118915 B CN106118915 B CN 106118915B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Abstract
The invention belongs to the technical fields of dyeing and finishing, are specifically related to a kind of soaping agent for highly dense flower pattern pure cotton figured cloth and its technique of soaping.This kind is used for the soaping agent of highly dense flower pattern pure cotton figured cloth, including following raw material: n-vinyl pyrrolidone, lauryl sodium sulfate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic anhydride, polyacrylic acid, compound enzyme of soaping, octadecylamine polyoxyethylene ether, sodium secondary alkyl sulfonate and thiourea dioxide；Wherein compound enzyme of soaping by laccase, lipopeptid enzyme, Eurolan RP soaps enzyme and EOQ enzyme of soaping forms.Soaping agent foam when soaping highly dense flower pattern pure cotton figured cloth is few, short at the bubble time；Pure cotton figured cloth will not faded color after it is soaped；And for highly dense flower pattern cotton cloth in the substantially colorless difference of the dyed fabric after process of soaping described in the soaping agent collaborative combination and strength loss, compared with tradition soaps technique, color fastness is higher, and reduces process, time-saving energy-saving.
Description
Technical field
The invention belongs to the technical field of dyeing and finishing, be specifically related to a kind of soaping agent for highly dense flower pattern pure cotton figured cloth and
Its technique of soaping.
Background technique
It will be washed, be soaped after the dyeing such as reactive dye, direct dyes, acid dyes, disperse dyes, need to soap
Agent, pure cotton fabric after reactive dyeing need that soaping agent appropriate is selected to soap, to improve product quality and reduce
Energy consumption.
During reactive dyeing and stamp, reactive dye assign dyeing by Covalent bonding together and PRINTED FABRIC is excellent
Good dyefastness, but reactive dye are easy to happen hydrolysis under alkaline condition, form hydrolised dye and cannot occur with fiber
Reaction, some Dye Adsorption have neither part nor lot in covalent reaction in fiber surface, it is necessary in dyeing or the post-processing of stamp
It is cleaned up in journey, otherwise will affect the fastness of dyeing and PRINTED FABRIC.Therefore, the washing post-processing of reactive dye is entirely to contaminate
The important link of color or printing technology process is of great significance for dyeing with the fastness of PRINTED FABRIC and quality.Activity dye
Material is mainly used for dyeing and the stamp of cellulose fibre, and while upper dye and fixation, reactive dye are hydrolyzed due to being easy to happen,
Dye utilization rate is low, and loose colour is serious, not only affects the color fastness of fabric, and easily makes white background staining.Loose colour removal is dry
It is net difficult big, water consumption is big, therefore reactive dyeing and PRINTED FABRIC are soaped for effectively removing loose colour, improve dyeing and produce
The color fastness of product is particularly important.
Presently commercially available is mostly phosphorous alkaline soaping agent, and when soaping, cloth cover pH value is 9~10 in bath, and temperature is up to 98
~100 DEG C.The condition is easy to make reactive dye that scission of link occur, and washing lotion foam is more, consumes a large amount of water, is also possible in waste liquid
Containing APEO or phosphate ester surfactant, it is unfavorable for environmental protection, it is undesirable in terms of energy-saving and emission-reduction.
For highly dense flower pattern pure cotton figured cloth since color is rich and gaudy, dye dosage is big, and washing loose colour is relatively heavy, evaporates rear water
The color fastness and vividness washed are largely dependent on the effect soaped, therefore select the soaping agent of function admirable, white to preventing
It is particularly important that ground stains raising vividness.
Summary of the invention
High it is an object of the invention to be directed to current soaping agent pH value during soaping, temperature is high and leads to reactive dye
Scission of link consumes a large amount of water while washing lotion foam, is unfavorable for the problem of environmental protection and provides a kind of for highly dense flower pattern pure cotton
The soaping agent of figured cloth and its technique of soaping, soaping agent foam when soaping highly dense flower pattern pure cotton figured cloth is few, short at the bubble time；It is pure
Cotton cloth will not faded color after it is soaped；And highly dense flower pattern cotton cloth described in the soaping agent collaborative combination by soaping
The substantially colorless difference of dyed fabric and strength loss after process, compared with tradition soaps technique, color fastness is higher, and subtracts
Few process, time-saving energy-saving.
The technical solution of the present invention is as follows: a kind of soaping agent for highly dense flower pattern pure cotton figured cloth, including following raw material: N- second
Vinyl pyrrolidone, lauryl sodium sulfate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylene-1,1-diphosphonic
Acid, maleic anhydride, polyacrylic acid, compound enzyme of soaping, octadecylamine polyoxyethylene ether, sodium secondary alkyl sulfonate and thiourea dioxide；Its
In compound enzyme of soaping enzyme soaped by laccase, lipopeptid enzyme, Eurolan RP and EOQ enzyme of soaping forms.
The soaping agent for highly dense flower pattern pure cotton figured cloth, according to n-vinyl pyrrolidone described in mass ratio: 12
Sodium alkyl sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic anhydride: polypropylene
Acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide is (0.5-1.5): (1-2.5): (2-
3.5): (4-5): (1.2-2.0): (0.3-1.0): (1.1-1.5): (0.5-2.0): (3-6): (1.2-1.5): (1.0-1.6).
The soaping agent for highly dense flower pattern pure cotton figured cloth, according to n-vinyl pyrrolidone described in mass ratio: 12
Sodium alkyl sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic anhydride: polypropylene
Acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide 1.2:1.5:2:5:1.3:0.5:
1.3:1.5:4:1.3:1.5.
The soaping agent for highly dense flower pattern pure cotton figured cloth, according to n-vinyl pyrrolidone described in mass ratio: 12
Sodium alkyl sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic anhydride: polypropylene
Acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide 0.8:2.0:3.0:4.5:1.8:
0.7:1.5:0.7:3.5:1.5:1.2.
According to quality than laccase in the compound enzyme of soaping: lipopeptid enzyme: Eurolan RP soaps enzyme: EOQ enzyme of soaping is
0.2:0.5:1.0:0.6。
A kind of technique of soaping using the soaping agent for highly dense flower pattern pure cotton figured cloth, comprising the following steps:
(1) cold water is washed: being carried out cold water to highly dense flower pattern pure cotton figured cloth first and is washed 5-8 minutes；Cold water temperature is 15-20 DEG C；
(2) pickling: the pure cotton figured cloth washed through subcooled water is subjected to pickling, 0.5-1.0g/L dodecyl dimethyl hydroxyl is added
Ethylmercury chloride amine carries out pickling 10-15 minutes under the conditions of temperature is 40-45 DEG C；
(3) it soaps: the soaping agent is added and soaps under the conditions of temperature is 50-55 DEG C to the pure cotton figured cloth after pickling
5-10 minutes；
(4) hot water wash: the pure cotton figured cloth after soaping carries out hot water wash 5-8 minutes at being 70-75 DEG C in temperature.
The step (3) soap middle soaping agent dosage be 0.5-0.7g/L.It not only may be implemented using the amount ranges
To floating
Optimal adsorption, the peptizaiton of dichroic dye molecule, and it is significantly less than the dosage of current existing soaping agent.
The step (3) soaps middle pH value as 4-6.Cooperate with what the soaping agent reached to soap effect such as under the conditions of the pH
Under: fastness to rubbing unlubricated friction is 5 grades, and wet rub is 4-5 grades, it is seen that not only will not be because of process alkalinity mistake of soaping under the pH value condition
Height, so that reactive dye on pure cotton figured cloth occur scission of link and fall off, and the effect that soap significantly is obviously improved.
The step (3) soap in bath raio be 1:(10-30).
The invention has the benefit that the soaping agent of the present invention for highly dense flower pattern pure cotton figured cloth, including following original
Material: n-vinyl pyrrolidone, lauryl sodium sulfate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, hydroxyl second
Pitch di 2 ethylhexyl phosphonic acid, maleic anhydride, polyacrylic acid, compound enzyme of soaping, octadecylamine polyoxyethylene ether, sodium secondary alkyl sulfonate and sulfur dioxide
Urea；Wherein compound enzyme of soaping by laccase, lipopeptid enzyme, Eurolan RP soaps enzyme and EOQ enzyme of soaping forms.
The soaping agent not only compounds high-molecular compound, while cooperateing with biology multiple simultaneously macromolecule compound
Conjunction enzyme of soaping for soap after reactive dyeing so under certain condition, utilizes compound enzymatic oxidation of soaping
Hydrolised dye and not fixed reactive dye make the loose colour on fabric be easier to remove by the synergistic effect of physics and chemistry,
But on very little is influenced by the dyestuff of Covalent bonding together with fiber, there is excellent removal floating color ability, significantly improve dyeing
Fastness greatly reduces the coloration of raffinate.The resistance to soaping fastness of pure cotton figured cloth can be improved 1.5-compared with traditional soaping agent
2 grades, moisture-proof colorfastness to rubbing can be improved 1~1.5 grade, and the coloration of waste water averagely reduces 85% or more.
Foam will not be generated in use, and dispersibility is strong, is more easier the cleaning after soaping, and it is dirty to reduce environment
Dye.The soaping agent has good colloid property simultaneously, can form complex compound with dyestuff, prevent the dyestuff under washing is counter to be stained with cloth cover.
Therefore it can be effectively removed loose colour, improve effect of soaping.
By the determining optimum process condition for using the soaping agent to soap of orthogonal experiment for 50-55 DEG C of temperature, when
Between 10-15 minutes, the soaping agent combine the temperature and time to soap after pure cotton figured cloth color fastness to washing, rub resistance color jail
Degree, the especially more existing soaping agent of fastness to wet rubbing can be improved 1-2 grades.Reduce process as a result, and shorten the washing time,
It saves and uses water, but effect of soaping generally is not so good as conventional technique of soaping.It soaps process ration, shortens when soaping after dye with tradition
Between, production efficiency is improved, is greatly saved " water, electricity, vapour ", sewage discharge and cost of sewage disposal is reduced, reduces and be produced into
This.
The more existing conventional soaping agent of the use temperature of the soaping agent can reduce 40-48 DEG C, thus reduce steam consumption 5~
7 t/t cloth, cloth per ton can be 35~45 tons water-saving, reduce process costs of soaping, and the duty cycle for technique of entirely soaping shortens 2-
It 2.5 hours, saves energy consumption and improves working efficiency；And the more conventional soaping agent of the indexs such as the color fastness of product improves at least 1
Grade.
COMPREHENSIVE CALCULATING, cloth per ton can reduce at least thousand yuan of production cost, have significant economic benefit.
In conclusion soaping agent foam when soaping highly dense flower pattern pure cotton figured cloth is few, it is short at the bubble time；Pure cotton figured cloth warp
It will not faded color after soaping；And highly dense flower pattern cotton cloth is by process of soaping described in the soaping agent collaborative combination
The substantially colorless difference of dyed fabric afterwards and strength loss, compared with tradition soaps technique, color fastness is higher, and reduction process,
Time-saving energy-saving.
Specific embodiment
Below by embodiment, the present invention will be described in detail.
Embodiment 1
The soaping agent for highly dense flower pattern pure cotton figured cloth, including following raw material: n-vinyl pyrrolidone, dodecane
Base sulphur
Sour sodium, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic anhydride, poly- third
Olefin(e) acid, compound enzyme of soaping, octadecylamine polyoxyethylene ether, sodium secondary alkyl sulfonate and thiourea dioxide；According to N- second described in mass ratio
Vinyl pyrrolidone: lauryl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylene-1,1-diphosphonic
Acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide is
1.2:1.5:2:5:1.3:0.5:1.3:1.5:4:1.3:1.5.Wherein compound enzyme of soaping is by laccase, lipopeptid enzyme, Eurolan RP
It soaps enzyme and EOQ soaps enzyme composition；According to quality than laccase in the compound enzyme of soaping: lipopeptid enzyme: Eurolan RP soaps enzyme:
EOQ soaps enzyme as 0.2:0.5:1.0:0.6.
Using the technique of soaping of the soaping agent for highly dense flower pattern pure cotton figured cloth, comprising the following steps:
(1) cold water is washed: being carried out cold water to highly dense flower pattern pure cotton figured cloth first and is washed 6 minutes；Cold water temperature is 18 DEG C；
(2) pickling: the pure cotton figured cloth washed through subcooled water is subjected to pickling, 0.7g/L dodecyl dimethyl ethoxy is added
Ammonium chloride carries out pickling 10 minutes under the conditions of temperature is 45 DEG C；
(3) it soaps: the soaping agent is added, the pure cotton figured cloth after pickling soap 8 points under the conditions of temperature is 53 DEG C
Clock；The dosage of soaping agent is 0.6g/L；PH value is 5；Bath raio is 1:15；
(4) hot water wash: the pure cotton figured cloth after soaping carries out hot water wash 6 minutes at being 72 DEG C in temperature.
Embodiment 2
The soaping agent for highly dense flower pattern pure cotton figured cloth, including following raw material: n-vinyl pyrrolidone, dodecane
Base sulphur
Sour sodium, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic anhydride, poly- third
Olefin(e) acid, compound enzyme of soaping, octadecylamine polyoxyethylene ether, sodium secondary alkyl sulfonate and thiourea dioxide；According to N- second described in mass ratio
Vinyl pyrrolidone: lauryl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylene-1,1-diphosphonic
Acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide is
0.8:2.0:3.0:4.5:1.8:0.7:1.5:0.7:3.5:1.5:1.2.Wherein it is compound soap enzyme by laccase, lipopeptid enzyme,
Eurolan RP soaps enzyme and EOQ soaps enzyme composition；According to quality than laccase in the compound enzyme of soaping: lipopeptid enzyme: Eurolan
RP soaps enzyme: EOQ enzyme of soaping is 0.2:0.5:1.0:0.6.
A kind of technique of soaping using the soaping agent for highly dense flower pattern pure cotton figured cloth, comprising the following steps:
(1) cold water is washed: being carried out cold water to highly dense flower pattern pure cotton figured cloth first and is washed 8 minutes；Cold water temperature is 15 DEG C；
(2) pickling: the pure cotton figured cloth washed through subcooled water is subjected to pickling, 0.5g/L dodecyl dimethyl ethoxy is added
Ammonium chloride carries out pickling 15 minutes under the conditions of temperature is 40 DEG C；
(3) it soaps: the soaping agent is added and soap 10 to the pure cotton figured cloth after pickling under the conditions of temperature is 50 DEG C
Minute；The dosage of soaping agent is 0.5-0.7g/L；PH value is 4-6；Bath raio is 1:(10-30)；
(4) hot water wash: the pure cotton figured cloth after soaping carries out hot water wash 5 minutes at being 75 DEG C in temperature.
Claims (7)
1. a kind of soaping agent for highly dense flower pattern pure cotton figured cloth, which is characterized in that be prepared from the following raw materials: N- vinyl pyrrole
Alkanone, lauryl sodium sulfate, δ-laminate sodium metasilicate, dodecyldimethylammonium hydroxide inner salt, 1-hydroxy ethylidene-1,1-diphosphonic acid, maleic acid
Acid anhydride, polyacrylic acid, compound enzyme of soaping, octadecylamine polyoxyethylene ether, sodium secondary alkyl sulfonate and thiourea dioxide；It is wherein compound to soap
Enzyme by laccase, lipopeptid enzyme, Eurolan RP soaps enzyme and EOQ soaps, and enzyme forms；According to N- ethenyl pyrrolidone described in mass ratio
Ketone: lauryl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: 1-hydroxy ethylidene-1,1-diphosphonic acid: maleic acid
Acid anhydride: polyacrylic acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide is (0.5-1.5):
(1-2.5): (2-3.5): (4-5): (1.2-2.0): (0.3-1.0): (1.1-1.5): (0.5-2.0): (3-6): (1.2-
1.5): (1.0-1.6)；According to quality than laccase in the compound enzyme of soaping: lipopeptid enzyme: Eurolan RP soaps enzyme: EOQ soaps
Enzyme is 0.2:0.5:1.0:0.6.
2. being used for the soaping agent of highly dense flower pattern pure cotton figured cloth according to claim 1, which is characterized in that according to described in mass ratio
N-vinyl pyrrolidone: lauryl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: hydroxy ethylidene
Di 2 ethylhexyl phosphonic acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide
For 1.2:1.5:2:5:1.3:0.5:1.3:1.5:4:1.3:1.5.
3. being used for the soaping agent of highly dense flower pattern pure cotton figured cloth according to claim 1, which is characterized in that according to described in mass ratio
N-vinyl pyrrolidone: lauryl sodium sulfate: δ-laminate sodium metasilicate: dodecyldimethylammonium hydroxide inner salt: hydroxy ethylidene
Di 2 ethylhexyl phosphonic acid: maleic anhydride: polyacrylic acid: compound enzyme of soaping: octadecylamine polyoxyethylene ether: sodium secondary alkyl sulfonate: thiourea dioxide
For 0.8:2.0:3.0:4.5:1.8:0.7:1.5:0.7:3.5:1.5:1.2.
4. a kind of technique of soaping using the soaping agent for being used for highly dense flower pattern pure cotton figured cloth described in claim 1, including following step
It is rapid:
(1) cold water is washed: being carried out cold water to highly dense flower pattern pure cotton figured cloth first and is washed 5-8 minutes；Cold water temperature is 15-20 DEG C；
(2) pickling: the pure cotton figured cloth washed through subcooled water is subjected to pickling, 0.5-1.0g/L dodecyl dimethyl ethoxy is added
Ammonium chloride carries out pickling 10-15 minutes under the conditions of temperature is 40-45 DEG C；
(3) it soaps: the soaping agent is added, the 5-10 that soaps is carried out to the pure cotton figured cloth after pickling under the conditions of temperature is 50-55 DEG C
Minute；
(4) hot water wash: the pure cotton figured cloth after soaping carries out hot water wash 5-8 minutes at being 70-75 DEG C in temperature.
5. technique of soaping according to claim 4, which is characterized in that the soap dosage of middle soaping agent of the step (3) is
0.5-0.7g/L。
6. technique of soaping according to claim 4, which is characterized in that the step (3) soaps middle pH value as 4-6.
7. technique of soaping according to claim 4, which is characterized in that the step (3) soap in bath raio be 1:(10-
30).
Priority Applications (1)
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| CN107955724A (en) * | 2017-11-29 | 2018-04-24 | 鹿寨卡森洗涤服务有限公司 | Cloth grass detergent |
| CN108708196B (en) * | 2018-05-10 | 2020-12-11 | 浙江科峰新材料有限公司 | Soaping agent and preparation process thereof |
| CN112695549B (en) * | 2020-12-28 | 2022-07-29 | 浙江震东新材料有限公司 | Low-temperature soaping agent for reactive dye printing and preparation method thereof |
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