CN104312746A - Low-foaming spraying hard surface cleaning agent, and preparation method therefor - Google Patents
Low-foaming spraying hard surface cleaning agent, and preparation method therefor Download PDFInfo
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- CN104312746A CN104312746A CN201410616415.1A CN201410616415A CN104312746A CN 104312746 A CN104312746 A CN 104312746A CN 201410616415 A CN201410616415 A CN 201410616415A CN 104312746 A CN104312746 A CN 104312746A
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- hard surface
- surface cleaner
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- soxylat
- low bubble
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Abstract
A low-foaming spraying hard surface cleaning agent comprises components with the following weight percentages: 1 to 10 percent of isomeric alcohol ethoxylates, 1 to 5 percent of polyether modified trisilioxnae, 1 to 5 percent of alkyne diol alcohol ethoxylates, 0 to 0.5 percent of sodium benzoate, 0 to 0.5 percent of sodium ethylene diamine tetracetate, and water. The cleaning agent provided by the invention has the advantages of high spreadability and detersive power, and low foams.
Description
Technical field
The present invention relates to a kind of low bubble spray hard surface cleaner and preparation method thereof.
Background technology
There is many Highrise buildingss in the quickening along with urban construction process, external wall of high-rise building owing to exposing to wind and rain, solar radiation, dust pollution add some reasons that are artificial or accidentalia, after using for some time, exterior wall surface all will have many dirts, exterior wall surface is made to become dirty gloomy, affect attractive in appearance, need often to clean.Existing external wall of high-rise building purging method is mainly: cleaning workman will be promoted near cleaning surface with Special Equipment, manually cleans or rinses metope and tap water rinses.But the spray hard surface cleaner used at present is sprawled comparatively slow mostly at fouled surfaces, also do not cleaned, clean-out system tumbles surface, and foam is more, and cleaning performance is bad.
For solving the problem existing for prior art, being necessary to provide a kind of hard surface cleaner, effectively can removing dirt while sprawling surface fast, and the characteristic such as foam is low.
Summary of the invention
The object of the present invention is to provide a kind of clean-out system spreadability good, strong detergency, and the low bubble spray hard surface cleaner that foam is low.
Another object of the present invention is the preparation technology providing a kind of low bubble spray hard surface cleaner.
Clean-out system of the present invention by screening obtain have the strong organic silicon surfactant of low dynamic surface tension, low foaming alkyne diol polyoxyethylene ether surface active agent and low equilibrium surface tension, power of deoiling and isomery ether surfactants composite after be prepared from, this is highly suitable for cleaning showers.
The object of the invention is to be achieved through the following technical solutions:
A kind of low bubble spray hard surface cleaner, its weight percent consists of: isomery fatty alcohol-polyoxyethylene ether 1 ~ 10%; Polyether-modified trisiloxanes 1 ~ 5%; Alkyne diol Soxylat A 25-7 1 ~ 5%; Sodium Benzoate 0 ~ 0.5%; Sodium ethylene diamine tetracetate (EDTA) 0 ~ 0.5%; All the other are water.
Isomery fatty alcohol-polyoxyethylene ether as above is:
R in formula
1the alkyl of C1 ~ C4, R
2be the alkyl of C6 ~ C15, m is 3 ~ 9.
Polyether-modified trisiloxanes as above is:
R in formula is H, CH
3, Bu etc., m is 3 ~ 9.
Alkyne diol Soxylat A 25-7 as above is:
M in formula is 1 ~ 4, n is 3 ~ 9.
The present invention is prepared by following method:
At 30-80 DEG C of temperature, isomery fatty alcohol-polyoxyethylene ether and alkyne diol Soxylat A 25-7 are added in water, be stirred to material all to dissolve, cool to room temperature, adds polyether-modified trisiloxanes, after stirring, continue stirring 30 minutes, add Sodium Benzoate, EDTA successively, continue stirring 30 minutes, obtain desired hard surface cleaner.Product appearance is water white transparency hard surface cleaner.
The present invention compared with prior art tool has the following advantages:
1. the starting isomeric fatty alcohol-polyoxyethylene ether that the present invention selects has good soil removability and emulsifying capacity, selects polyether-modified trisiloxanes and isomery fatty alcohol-polyoxyethylene ether to carry out the composite soil removability that improve hard surface cleaner of the present invention.
2. the polyether-modified trisiloxanes of raw material that the present invention selects has super spreadability, can improve the spreading property of clean-out system at oily dirt crust.
3. the raw material alkyne diol Soxylat A 25-7 that the present invention selects has low dynamic surface tension, clean-out system can be improved in the instantaneous spreading ability of oily dirt crust, and alkyne diol Soxylat A 25-7 has the effect suppressing foam, reduces the foam of hard surface cleaner of the present invention.
4. the present invention is environmentally friendly, also less to skin irritation during use, and according to the test-improvement Ross-Mile method of GB/T7462-94 tensio-active agent foaming power, the foam of hard surface cleaner of the present invention is starkly lower than commercially available prod,
5. be suitable for cleaning showers operation.
Embodiment
Embodiment 1
Isomery fatty alcohol-polyoxyethylene ether (9) accounts for 10wt%; Polyether-modified trisiloxanes (8) accounts for 1wt%; Alkyne diol Soxylat A 25-7 (3.5) accounts for 1wt%; Sodium Benzoate accounts for 0.5wt%; EDTA accounts for 0.5wt%; All the other are water.
At 80 DEG C, isomery fatty alcohol-polyoxyethylene ether (9) and alkyne diol Soxylat A 25-7 (3.5) are added in water, be stirred to material all to dissolve, cool to room temperature, adds polyether-modified trisiloxanes (8), after stirring, continue stirring 30 minutes, add Sodium Benzoate, EDTA successively, continue stirring 30 minutes, obtain desired hard surface cleaner.Product appearance is colourless transparent solution.
Embodiment 2
Isomery fatty alcohol-polyoxyethylene ether (7) accounts for 8wt%; Polyether-modified trisiloxanes (6) accounts for 3wt%; Alkyne diol Soxylat A 25-7 (10) accounts for 2wt%; Sodium Benzoate accounts for 0.3wt%; EDTA accounts for 0.2wt%; All the other are water.
At 50 DEG C, isomery fatty alcohol-polyoxyethylene ether (7) and alkyne diol Soxylat A 25-7 (10) are added in water, be stirred to material all to dissolve, cool to room temperature, adds polyether-modified trisiloxanes (6), after stirring, continue stirring 30 minutes, add Sodium Benzoate, EDTA successively, continue stirring 30 minutes, obtain desired hard surface cleaner.Product appearance is colourless transparent solution.
Embodiment 3
Isomery fatty alcohol-polyoxyethylene ether (5) accounts for 5wt%; Polyether-modified trisiloxanes (10) accounts for 5wt%; Alkyne diol Soxylat A 25-7 (10) accounts for 5wt%; Sodium Benzoate accounts for 0.1wt%; EDTA accounts for 0.1wt%; All the other are water.
At 70 DEG C, isomery fatty alcohol-polyoxyethylene ether (5) and alkyne diol Soxylat A 25-7 (10) are added in water, be stirred to material all to dissolve, cool to room temperature, adds polyether-modified trisiloxanes (10), after stirring, continue stirring 30 minutes, add Sodium Benzoate, EDTA successively, continue stirring 30 minutes, obtain desired hard surface cleaner.Product appearance is colourless transparent solution.
Embodiment 4
Isomery fatty alcohol-polyoxyethylene ether (3) accounts for 4wt%; Polyether-modified trisiloxanes (9) accounts for 4wt%; Alkyne diol Soxylat A 25-7 (0) accounts for 4wt%; Sodium Benzoate accounts for 0.1wt%; EDTA accounts for 0.4wt%; All the other are water.
At 30 DEG C, isomery fatty alcohol-polyoxyethylene ether (3) and alkyne diol Soxylat A 25-7 (0) are added in water, be stirred to material all to dissolve, cool to room temperature, adds polyether-modified trisiloxanes (9), after stirring, continue stirring 30 minutes, add Sodium Benzoate, EDTA successively, continue stirring 30 minutes, obtain desired hard surface cleaner.Product appearance is colourless transparent solution.
Each component described in the present embodiment is the conventional products that market is sold;
In this enforcement, each component in described hard surface cleaner can in the ratio range provided flexible combination, do not enumerate one by one at this.
The above-mentioned spreading property preparing sample is characterized by the contact angle on Parafilm surface, foaming properties is tested according to the testing improvement Ross-Mile method of GB/T7462-94 tensio-active agent foaming power, detersive power is tested according to GB (QB/T1224-2007), and as follows with the comparing result of commercially available common hard surface cleaner (principal constituent is fatty alcohol-polyoxyethylene ether and Sodium dodecylbenzene sulfonate):
Claims (5)
1. a low bubble spray hard surface cleaner, is characterized in that the weight percent of low bubble spray hard surface cleaner consists of: isomery fatty alcohol-polyoxyethylene ether 1 ~ 10%; Polyether-modified trisiloxanes 1 ~ 5%; Alkyne diol Soxylat A 25-7 1 ~ 5%; Sodium Benzoate 0 ~ 0.5%; Sodium ethylene diamine tetracetate 0 ~ 0.5%; All the other are water.
2. a kind of low bubble spray hard surface cleaner as claimed in claim 1, is characterized in that described isomery fatty alcohol-polyoxyethylene ether is:
R in formula
1the alkyl of C1 ~ C4, R
2be the alkyl of C6 ~ C15, m is 3 ~ 9.
3. a kind of low bubble spray hard surface cleaner as claimed in claim 1, is characterized in that described polyether-modified trisiloxanes is:
R in formula is H, CH
3, Bu etc., m is 3 ~ 9.
4. a kind of low bubble spray hard surface cleaner as claimed in claim 1, is characterized in that described alkyne diol Soxylat A 25-7 is:
M in formula is 1 ~ 4, n is 3 ~ 9.
5. the preparation method of a kind of low bubble spray hard surface cleaner as described in any one of claim 1-4, is characterized in that comprising the steps:
At 30-80 DEG C of temperature, isomery fatty alcohol-polyoxyethylene ether and alkyne diol Soxylat A 25-7 are added in water, be stirred to material all to dissolve, cool to room temperature, adds polyether-modified trisiloxanes, after stirring, continue stirring 30 minutes, add Sodium Benzoate, sodium ethylene diamine tetracetate successively, continue stirring 30 minutes, obtain desired hard surface cleaner.Product appearance is water white transparency hard surface cleaner.
Priority Applications (1)
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| CN201410616415.1A CN104312746A (en) | 2014-11-05 | 2014-11-05 | Low-foaming spraying hard surface cleaning agent, and preparation method therefor |
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| CN201410616415.1A CN104312746A (en) | 2014-11-05 | 2014-11-05 | Low-foaming spraying hard surface cleaning agent, and preparation method therefor |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105695117A (en) * | 2016-03-28 | 2016-06-22 | 西安优派生物科技有限公司 | Omnipotent stain cleaning composition |
| CN106434034A (en) * | 2016-07-11 | 2017-02-22 | 成都嘉鹏科技有限公司 | Glass cleaning agent suitable for spray cleaning and preparation method thereof |
| CN108004050A (en) * | 2017-12-15 | 2018-05-08 | 上海东大化学有限公司 | A kind of spray cleaning agent and preparation method thereof |
| CN108165381A (en) * | 2016-12-07 | 2018-06-15 | 上海东大化学有限公司 | A kind of spray cleaning agent and preparation method thereof |
| CN108211985A (en) * | 2017-12-08 | 2018-06-29 | 武汉奥克特种化学有限公司 | A kind of low bubble Environment protection cleaning surfactant |
| CN113385103A (en) * | 2021-05-12 | 2021-09-14 | 湖南兴弘新材料科技有限公司 | Surfactant composition, preparation method and application |
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| CN103275324A (en) * | 2013-06-04 | 2013-09-04 | 中国日用化学工业研究院 | Alkynyl diol ethyl oxide polyether or alkynyl diol propyl oxide polyether co-modified polysiloxane and preparation method thereof |
| CN103585926A (en) * | 2013-11-22 | 2014-02-19 | 东华大学 | Acid-base resistant polyether modified trisiloxane surfactant as well as preparation and application thereof |
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| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105695117A (en) * | 2016-03-28 | 2016-06-22 | 西安优派生物科技有限公司 | Omnipotent stain cleaning composition |
| CN105695117B (en) * | 2016-03-28 | 2018-04-17 | 西安优派生物科技有限公司 | A kind of all-round spot Cleasing compositions |
| CN106434034A (en) * | 2016-07-11 | 2017-02-22 | 成都嘉鹏科技有限公司 | Glass cleaning agent suitable for spray cleaning and preparation method thereof |
| CN108165381A (en) * | 2016-12-07 | 2018-06-15 | 上海东大化学有限公司 | A kind of spray cleaning agent and preparation method thereof |
| CN108165381B (en) * | 2016-12-07 | 2020-04-28 | 上海东大化学有限公司 | Cleaning agent for spraying and preparation method thereof |
| CN108211985A (en) * | 2017-12-08 | 2018-06-29 | 武汉奥克特种化学有限公司 | A kind of low bubble Environment protection cleaning surfactant |
| CN108211985B (en) * | 2017-12-08 | 2020-01-24 | 武汉奥克特种化学有限公司 | Low-foam environment-friendly cleaning surfactant |
| CN108004050A (en) * | 2017-12-15 | 2018-05-08 | 上海东大化学有限公司 | A kind of spray cleaning agent and preparation method thereof |
| CN108004050B (en) * | 2017-12-15 | 2020-03-31 | 上海东大化学有限公司 | Cleaning agent for spraying and preparation method thereof |
| CN113385103A (en) * | 2021-05-12 | 2021-09-14 | 湖南兴弘新材料科技有限公司 | Surfactant composition, preparation method and application |
| CN113385103B (en) * | 2021-05-12 | 2022-12-13 | 湖南兴弘新材料科技有限公司 | Surfactant composition, preparation method and application |
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Application publication date: 20150128 |