CN105695117A - Omnipotent stain cleaning composition - Google Patents
Omnipotent stain cleaning composition Download PDFInfo
- Publication number
- CN105695117A CN105695117A CN201610181520.6A CN201610181520A CN105695117A CN 105695117 A CN105695117 A CN 105695117A CN 201610181520 A CN201610181520 A CN 201610181520A CN 105695117 A CN105695117 A CN 105695117A
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- CN
- China
- Prior art keywords
- compositions
- surfactant
- weight
- polyether
- ether
- Prior art date
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 238000004140 cleaning Methods 0.000 title claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 76
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 68
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 26
- 239000004744 fabric Substances 0.000 claims description 21
- SWGZAKPJNWCPRY-UHFFFAOYSA-N methyl-bis(trimethylsilyloxy)silicon Chemical compound C[Si](C)(C)O[Si](C)O[Si](C)(C)C SWGZAKPJNWCPRY-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229910052701 rubidium Inorganic materials 0.000 claims description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 claims description 3
- 150000001261 hydroxy acids Chemical group 0.000 claims description 3
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 abstract description 4
- -1 fatty acid salt Chemical class 0.000 description 39
- 239000000049 pigment Substances 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 15
- 239000000178 monomer Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 239000003599 detergent Substances 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000012467 final product Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 235000013599 spices Nutrition 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000002280 amphoteric surfactant Substances 0.000 description 8
- 239000003093 cationic surfactant Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000003755 preservative agent Substances 0.000 description 8
- 230000002335 preservative effect Effects 0.000 description 8
- 239000006081 fluorescent whitening agent Substances 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 230000004913 activation Effects 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 230000006837 decompression Effects 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 238000013112 stability test Methods 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- 238000005282 brightening Methods 0.000 description 4
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- ZNWNWEHQFXOPGK-UHFFFAOYSA-N decanedial Chemical compound O=CCCCCCCCCC=O ZNWNWEHQFXOPGK-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 4
- 229910017053 inorganic salt Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- SQAKQVFOMMLRPR-IWGRKNQJSA-N 2-[(e)-2-[4-[4-[(e)-2-(2-sulfophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonic acid Chemical group OS(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S(O)(=O)=O)=CC=2)C=C1 SQAKQVFOMMLRPR-IWGRKNQJSA-N 0.000 description 3
- SEBIKDIMAPSUBY-ARYZWOCPSA-N Crocin Chemical compound C([C@H]1O[C@H]([C@@H]([C@@H](O)[C@@H]1O)O)OC(=O)C(C)=CC=CC(C)=C\C=C\C=C(/C)\C=C\C=C(C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)O1)O)O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SEBIKDIMAPSUBY-ARYZWOCPSA-N 0.000 description 3
- SEBIKDIMAPSUBY-JAUCNNNOSA-N Crocin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C(=O)OC1OC(COC2OC(CO)C(O)C(O)C2O)C(O)C(O)C1O)C=CC=C(/C)C(=O)OC3OC(COC4OC(CO)C(O)C(O)C4O)C(O)C(O)C3O SEBIKDIMAPSUBY-JAUCNNNOSA-N 0.000 description 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 244000178870 Lavandula angustifolia Species 0.000 description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 230000003165 hydrotropic effect Effects 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 description 2
- VLQZJOLYNOGECD-UHFFFAOYSA-N 2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C[SiH]1O[SiH](C)O[SiH](C)O1 VLQZJOLYNOGECD-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WZUVPPKBWHMQCE-UHFFFAOYSA-N Haematoxylin Chemical compound C12=CC(O)=C(O)C=C2CC2(O)C1C1=CC=C(O)C(O)=C1OC2 WZUVPPKBWHMQCE-UHFFFAOYSA-N 0.000 description 2
- 241000322338 Loeseliastrum Species 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- FUKUFMFMCZIRNT-UHFFFAOYSA-N hydron;methanol;chloride Chemical compound Cl.OC FUKUFMFMCZIRNT-UHFFFAOYSA-N 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
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- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 2
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- 239000002304 perfume Substances 0.000 description 2
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- 238000001556 precipitation Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 2
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
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- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- IAEGWXHKWJGQAZ-UHFFFAOYSA-N trimethylpyrazine Chemical compound CC1=CN=C(C)C(C)=N1 IAEGWXHKWJGQAZ-UHFFFAOYSA-N 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
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- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
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- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000001675 jasminum grandiflorum l. oil Substances 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229930007459 p-menth-8-en-3-one Natural products 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- MENHWGVPQSXCBC-UHFFFAOYSA-N sodium;n-methylmethanamine Chemical compound [Na+].CNC MENHWGVPQSXCBC-UHFFFAOYSA-N 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 235000012751 sunset yellow FCF Nutrition 0.000 description 1
- 239000004173 sunset yellow FCF Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- YEIGUXGHHKAURB-UHFFFAOYSA-N viridine Natural products O=C1C2=C3CCC(=O)C3=CC=C2C2(C)C(O)C(OC)C(=O)C3=COC1=C23 YEIGUXGHHKAURB-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/181—Hydrocarbons linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an omnipotent stain cleaning composition which at least comprises 100 parts by weight of base component A (composed of a surfactant and deionized water) and 0.2-10 parts by weight of protective component B.
Description
Technical field
The invention belongs to daily use chemicals articles for washing technical field, more specifically, a kind of all-round spot Cleasing compositions。
Background technology
In kitchen, building site, the places such as ore deposit, due to reasons such as environment, the spot being difficult to clean often is had in the chest of clothes, cuff, collar etc., in conventional cleaning process, generally require the stronger soap of alkalescence and need longer soak time, and different spots needs different cleaning supplies。
Human body is had very strong zest by the stronger soap of alkalescence, and the shortcoming such as the immersion of long period often occurs that the spot in water deposits to the surface of fabric, fiber again, occurs that fabric is hardening, and cleaning effect is not good。
For the problems referred to above, need now a kind of Almightiness type stain cleaning agent badly, be possible not only to efficiently remove multiple spot, fabric, fiber can be had certain protective capability so that medicated clothing has long-acting submissive sense and gloss light simultaneously。
Summary of the invention
For the problems referred to above, the present invention relates to a kind of all-round spot Cleasing compositions, by weight, include at least:
100 parts by weight of base component A: surfactant, deionized water；
0.2-10 weight portion protects the polyether-modified trisiloxanes of the material 1 of component B:0.1-9 weight portion, 0.1-1 weight portion；
The structural formula of described material 1 is as follows:
Wherein, described R1～R4It each is selected from hydrion, alkyl ,-(CH2)pOne in R, described R is ionogen, and is negative charge after ionization；
Described R5Selected from-(CH2)m, described m is 10-20；
Described n is the integer more than 0；
Described R1～R4Carbon chain length respectively p1～p4, and 0.5m < Max(p1+p3, p2+p4) < m；
Described polyether-modified trisiloxanes is to be raw material by 1-propenol-3 polyoxyalkyl ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane, is prepared by solvent-free polymeric。
As a kind of embodiment, described R is the one in hydroxy-acid group, sulfonic acid group and phosphate group。
As a kind of embodiment, described R1～R4In have at least one for-(CH2)pR。
As a kind of embodiment, described protection component B also includes material 2, and the structural formula of described material 2 is as follows:
Wherein, described Ra、Rb、Rc、RdIt each is selected from methyl ,-(CH2)pRxIn one；
Described RxFor ionogen, and it is positive charge after ionization；
Described p is 1-8。
As a kind of embodiment, described RxOne in fatty amine primary, secondary, tertiary, amidino groups。
As a kind of embodiment, the weight ratio of described material 1 and material 2 is (1-9): (10-20)。
As a kind of embodiment, the weight ratio of described material 1 and material 2 is (1-6): (15-20)。
As a kind of embodiment, in described 1-propenol-3 polyoxyalkyl ether, containing 7-8 ethylene oxide group in polyether segment。
As a kind of embodiment, the weight average molecular weight of described material 1 is 1000-10000。
The preparation method that a second aspect of the present invention relates to described all-round spot Cleasing compositions, comprises the following steps:
According to described parts by weight, being poured into by the 25-35% of deionized water total amount in material still, heating, to 60-80 DEG C, is then sequentially added into surfactant, polyether-modified trisiloxanes, material 1, auxiliary agent, material 2 while stirring, after stirring, add remaining deionized water, after material all dissolves, cooling, add preservative, essence and stir, it is 7.0-7.5 with Fructus Citri Limoniae acid for adjusting pH value, filters, to obtain final product。
A third aspect of the present invention relates to the using method of described all-round spot Cleasing compositions, comprises the following steps:
(1) appropriate all-round spot Cleasing compositions and proper amount of clear water are mixed；
(2) medicated clothing to be cleaned is soaked in water, soaks 5 minutes；
(3) wash by rubbing with the hands with have gentle hands is micro-, can rinse。
A fourth aspect of the present invention relates to a kind of clean fabric agent, and described clean fabric agent comprises described all-round spot Cleasing compositions。
The existence form of described clean fabric agent, it is possible to be any form existed on the market, for instance liquid detergent, laundry detergents, washing cream, collar agent, laundry solidifying pearl, detergent, laundry bars etc.。
Detailed description of the invention
Participate in the election of the detailed description being preferable to carry out method of the invention below and the embodiment that includes can be more easily understood present disclosure。Unless otherwise defined, all technology used herein and scientific terminology have the identical implication being generally understood that with one skilled in the art of the present invention。When there is contradiction, it is as the criterion with the definition in this specification。
Term as used herein " by ... preparation " and " comprising " synonym。Term used herein " comprises ", " including ", " having ", " containing " or its other deformation any, it is intended that cover the including of non-exclusionism。Such as, comprise the compositions of listed elements, step, method, goods or device and be not necessarily solely those key elements, but other not expressly listed key element or the intrinsic key element of this kind of compositions, step, method, goods or device can be included。
Conjunction " by ... composition " get rid of any key element, step or component do not pointed out。If in claim, this phrase will make claim be closed so that it is does not comprise the material except the material of those descriptions, but except relative customary impurities。When phrase " by ... composition " occurs in and is rather than immediately following after theme in the clause of claim main body, it is only limited to the key element described in this clause；Other key element is not excluded outside the described claim as entirety。
During the Range Representation that equivalent, concentration or other value or parameter limit with scope, preferable range or a series of upper limit preferred value and lower preferable values, this is appreciated that and specifically discloses all scopes formed by arbitrary pairing of any range limit or preferred value and any range lower limit or preferred value, regardless of whether whether this scope separately discloses。Such as, when disclosing scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc.。When numerical range is described in this article, unless otherwise indicated, otherwise this scope is intended to include its end value and all integers within the scope of this and mark。
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise。" optional " or " any one " refer to that the item described thereafter or event can occur or do not occur, and this description includes situation and the situation that do not occur of event that event occurs。
Approximate term in specification and claims is used for modifying quantity, represents that the present invention is not limited to this particular number, also includes close to this quantity acceptable without causing the part of the correction of the change of relevant basic function。Accordingly, modify a numerical value with " about ", " about " etc., mean and the invention is not restricted to this exact numerical。In some example, approximate term likely corresponds to measure the precision of the instrument of numerical value。In present specification and claims, scope limits and can combine and/or exchange, without additionally illustrating that these scopes include all subranges contained therebetween。
Additionally, indefinite article " one " before key element of the present invention or component and " one " quantitative requirement (i.e. occurrence number) unrestriction to key element or component。Therefore " one " or " one " should be read as and include one or at least one, and the key element of singulative or component also include plural form, unless the obvious purport of described quantity refers to singulative。
" polymer " means the polymerizable compound prepared by the monomer by being polymerized identical or different type。Generic term " polymer " comprises term " homopolymer ", " copolymer ", " terpolymer " and " copolymer "。
" copolymer " means by being polymerized polymer prepared by least two different monomers。Generic term " copolymer " includes term " copolymer " (it is generally in order to refer to the polymer prepared by two kinds of different monomers) and term " terpolymer " (it is generally in order to refer to the polymer prepared by three kinds of different monomers)。It also comprises the polymer manufactured by polymerization four or more kinds of monomer。" blend " mean two or more polymer by physics or the method for chemistry jointly mix and the polymer that formed。
The present invention relates to a kind of all-round spot Cleasing compositions, by weight, include at least:
100 parts by weight of base component A: surfactant, deionized water；
0.2-10 weight portion protects the polyether-modified trisiloxanes of the material 1 of component B:0.1-9 weight portion, 0.1-1 weight portion；
The structural formula of described material 1 is as follows:
Wherein, described R1～R4It each is selected from hydrion, alkyl ,-(CH2)pOne in R, described R is ionogen, and is negative charge after ionization；
Described R5Selected from-(CH2)m, described m is 10-20；
Described n is the integer more than 0；
Described R1～R4Carbon chain length respectively p1～p4, and 0.5m < Max(p1+p3, p2+p4) < m；
Described all can also comprise auxiliary agent by spot Cleasing compositions, by weight, include at least:
Hydrotropic agent 5-15 part
Inorganic salt 2-8 part
Chelating agen 1-12 part
Sodium citrate 1-5 part
Preservative 0.1-1 part
Fluorescent whitening agent 0-2 part
Pigment 0-0.3 part
Essence 1-2.5 part。
Basic components A:
Surfactant:
Surfactant (surfactant), refers to the material adding the interface state generation significant change that can make its solution system on a small quantity。There is fixing hydrophilic and oleophilic group, can align on the surface of solution。The molecular structure of surfactant has amphipathic: one end is hydrophilic group, and the other end is hydrophobic group；Hydrophilic group is often polar group, and such as carboxylic acid, sulfonic acid, sulphuric acid, amino or amido and salt thereof, hydroxyl, amide groups, ehter bond etc. also can as polar hydrophilic groups；And hydrophobic group is often nonpolar hydrocarbon chain, such as 8 above hydrocarbon chains of carbon atom。Surfactant is divided into ionic surfactant (including cationic surfactant and anion surfactant), nonionic surfactant, amphoteric surfactant, compound surfactant, other surfactants etc.。
Conventional anion surfactant has higher fatty acid salt, sulfonate, sulfate, fatty acyl-peptide condensation substance and phosphate ester salt；
Suitable anion surfactant includes: alkali alkyl sulfate such as sodium lauryl sulphate or lauryl sulphate acid potassium；Alkylsurfuric acid ammonium such as ammonium lauryl sulfate；The alkali metal salt of Brij-35 sodium sulfate, sodium sulfonate and sulfonated olefins；Alkyl sulfate enters the ammonium salt of sulfonated olefins；Soap such as sodium laurate, triethanolamine oleate or rosin acid triethanolamine；The alkali metal sulfates of alkylaryl sulfonates such as dodecylbenzene sodium sulfonate or alkaline phenol ethoxy；Senior alkyl naphthalene sulfonate, naphthalene sulfonic acid-formaldehyde condensation product。
Conventional cationic surfactant has amine salt cationic surfactant and quaternary ammonium salt cationic surfactant；
Suitable cationic surfactant includes: alkyl trimethyl ammonium sodium, dialkyl dimethyl ammonium sodium and alkyl dimethyl benzyl ammonium sodium。Quaternary ammonium salt cationic surfactant has low-corrosiveness and gentle abnormal smells from the patient and heat, pH and Organic substance is had high stability。
The advantage of cationic surface active agent is in that, cationic surface active agent has the affinity for all kinds plant, there is low-down toxicity, even at being also very effective when wherein using very small amount of cationic surface active agent, and be tasteless and odorless。It addition, cationic surface active agent is better than other surfactant in smooth and soft。But, when cationic surface active agent is used too much wherein, cationic surface active agent can be deposited on fabric, and result tinted article is likely to decolouring and reduces the hydrophilic of fabric, and this prevents decontamination。
Conventional amphoteric surfactant has amino acid type amphoteric surface active agent, betaine type amphoteric surfac-tant, imidazoline type amphoteric surfactant and amine oxide。
Suitable amphoteric surfactant includes: alkyl dimethyl betaine, alkylamide, alkyl dimethyl betaine, alkyl dihydroxyalkyl glycine betaine, sulfobetaine type amphoteric surfactant；Alkyl aminopropionic acid type, alkyliminodipropionic type, alkyl taurine type。
Conventional nonionic surfactant: polyethylene glycol type nonionic surfactant, polyol-based non-ionic surfactant；
Suitable nonionic surfactant includes polyoxyethylene ether, polyoxyethylene propylidene alkyl ether, polyoxyethylene phenyl ether and polyoxyethylene fatty acid ester。Particularly with stability preferably polyoxyethylene ether, polyoxyethylene propylidene alkyl ether and polyoxyethylene phenyl ether。Suitable example includes polyoxyethylene Octyl Ether, polyoxyethylene nonyl ethers, polyoxyethylene certain herbaceous plants with big flowers base ether, polyoxyethylene propylidene certain herbaceous plants with big flowers base ether, polyoxyethylenelauryl ether, polyoxyethylene propylidene lauryl ether, polyoxyethylene tridecyl ether, polyoxyethylene propylidene tridecyl ether, polyoxyethylene myristyl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene octyl phenyl ether, polyoxyethylene nonylplenyl ether and polyoxyethylene styrenated phenyl ether。
Protection component B:
The structural formula of described material 1 is as follows:
Wherein, described R1～R4It each is selected from hydrion, alkyl ,-(CH2)pOne in R；
Described R is ionogen, and in negative charge after ionization；Described R5Selected from-(CH2)m；
Described R1、R2、R3、R4Carbon chain length respectively p1、p2、p3、p4, and 0.5m < Max(p1+p3, p2+p4) < m；
As a kind of embodiment, described m is 10-20。
In the present invention, described term " Max(p1+p3, p2+p4) " refer to R1And R3Carbon chain length sum and R2And R4Carbon chain length sum, take maximum value among both。
In the present invention, described term " 0.5m < Max(p1+p3, p2+p4) < m " it is meant to R1And R3Carbon chain length sum and R2And R4Both carbon chain length sums among maximum value between 0.5m and m。
Such as m=10, then Max(p1+p3, p2+p4) between 5-10。
Described alkyl refers to the one in alkane, alkene, alkynes；
As a kind of embodiment, described R is selected from one or more in hydroxy-acid group, sulfonic acid group and phosphate group。
As a kind of embodiment, R1、R2、R3、R4In have at least a group selected from-(CH2)pR。
Work as n=1, m=12, R1=R3=H, R2=R4=-(CH2)4During COOH, described material 1 is 1,22-bis-caproic acids-docosane, and No. CAS is 2450-31-9。
As n > 1 time, the method for the synthesis of described material 1 can adopt any method well known by persons skilled in the art to prepare。
In the present invention, the main mode adopting hydroxyl polymeric prepares。
Such as, m=8, R2=R4=H, R1=R3=-(CH2)3SO3During H, described monomer of preparing is
The preparation course of reaction of described monomer is as follows:
Concrete reactions steps is as follows:
(1) carbon dioxide, 1,7-octadiene under the effect of catalyst, with toluene for solvent, at 60 DEG C, react generation 1,10-decanedial；
(2) 1,10-decanedial is at NaHSO4Aqueous solution under stoichiometric number hour, be subsequently adding dichloromethane and hydrochloric acid, collect solid, separatory is collected dichloromethane, is drained, and to obtain final product。
The preparation process of described material 1 is as follows:
By the above-mentioned monomer prepared, dissolve with certain solvent, then dropwise instill in hydrogen peroxide, instill 1h, after titration, continue stirred for several hour, be subsequently adding in the methanol solution of 5% hydrochloric acid, after producing precipitation, sucking filtration, washs with methanol hydrochloride solution, filter 23-5 times, vacuum drying a few hours, to obtain final product。
The weight average molecular weight of described material 1 is 1000-10000。
Weight average molecular weight is based on gel permeation chromatography (hreinafter referred to as " GPC "。) measure and carry out the value after polystyrene conversion。The condition determination of GPC adopts the condition test that this area is conventional, for instance, following mode can be adopted to test and to obtain。
Post: following post is connected in series and uses。
" TSKgelG5000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG4000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG3000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG2000 " (7.8mmI.D. × 30cm) × 1 piece
Detector: RI (differential refractometer)；Column temperature: 40 DEG C；Eluent: oxolane (THF)；Flow velocity: 1.0mL/ minute；Injection rate: 100 μ L (tetrahydrofuran solution of sample solution concentration 4mg/mL)；Standard specimen: use following monodisperse polystyrene, makes standard curve。
Material 2:
The structural formula of described material 2 is as follows:
Wherein, described Ra、Rb、Rc、RdIt each is selected from alkyl, the tert-butyl group ,-(CH2)pRxIn one；
As a kind of embodiment, described RxFor ionogen, and in positive charge after ionization。
As a kind of embodiment, described RxOne in fatty amine primary, secondary, tertiary, amidino groups, guanidine radicals。
As a kind of embodiment, described p is 1-8, has preferably 1-5 further。
In the present invention, according to practical situation, the preparation method of condensed type is selected to prepare。
Work as Ra、RbSelected from butylamine, Rc、RdSelected from being methyl, described monomer of preparing isPrepare material 2。
The described preparation method preparing monomer is as follows:
At 5-10 DEG C of temperature, being added in 50ml ether by above-mentioned for 1.2g monomer, dropwise instill deionized water, after dropwising, warming-in-water, to 55 DEG C, stirs, reacts 20min。Stratification, divides and removes sour water layer, be the NaHCO of 2% with mass fraction3Solution washing twice, then it is washed till neutrality with NaCl aqueous solution, to obtain final product。
In the present invention, as a kind of embodiment, the weight ratio of described material 1 and material 2 is (1-9): (10-20), it is more preferable to for (1-6): (15-20), more preferably 5:18。
Polyether-modified trisiloxanes:
The modified trisiloxanes of described nonionic polyether is to be raw material by 1-propenol-3 polyoxyalkyl ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane, is prepared by solvent-free polymeric。
Term of the present invention " polyether-modified trisiloxanes " is by oxirane, 1-propenol-3 polyoxyalkyl ether and 1,1,1; 3,5,5; 5-heptamethyltrisiloxane is raw material, by solvent-free polymeric, obtains through the preparation of Karstedt catalyzing addition reaction of silicon with hydrogen under nitrogen protection。The preparation method of described polyether-modified trisiloxanes: so that the 1-propenol-3 polyoxyalkyl ether of 10.5mol and the Karstedt catalyst of 0.02mol are equipped with reflux condensing tube, in the reaction there-necked flask of stirrer, present 80 DEG C mix 30min with stirring under the protection of nitrogen, make activation of catalyst, it is sufficiently formed alkene-metal complex, then, temperature is increased to 110 DEG C, start slowly to drip 1, 1, 1, 3, 5, 5, 5-heptamethyltrisiloxane 30min, after question response terminates, decompression removes unreacted 1, 1, 1, 3, 5, 5, 5-heptamethyltrisiloxane and other low-boiling-point substances, obtain。
As a kind of embodiment, in described 1-propenol-3 polyoxyalkyl ether, containing 7-8 ethylene oxide group in polyether segment。
As a kind of embodiment, the average relative molecular mass of described 1-propenol-3 polyoxyalkyl ether is 350-400。
As a kind of embodiment, the average relative molecular mass of described 1-propenol-3 polyoxyalkyl ether is 380。
As a kind of embodiment, described protection component C also includes secondary alkyl sulfonate, and the structural formula of described secondary alkyl sulfonate is, term of the present invention " secondary alkyl sulfonate " is a kind of anionic surfactant, is reacted through sulfoxidation with sulfur dioxide and oxygen by n-alkane, prepares then through neutralization。The hydrophilic group of described secondary alkyl sulfonate is connected on hydrophobic secondary carbon, causes that its character and hydrophilic group LAS on primary carbon atom have a great difference。Secondary alkyl sulfonate has good dissolubility, mobility, and it has extremely strong penetration, it is possible to rapid osmotic, disintegrate the stain of obligation fiber depths, improves the dirt-removing power of liquid detergent。Additionally, described secondary alkyl sulfonate has certain compatibilization, it is possible to significantly improve other surfactants and the auxiliary agent dissolubility in liquid detergent, thus to the highly enriched requirement of liquid detergent。But detergency ability when secondary alkyl sulfonate is used alone not is very prominent, but through substantial amounts of test, present invention applicant finds that secondary alkyl sulfonate and isomeric alcohol polyethenoxy ether are when weight part ratio is 0.53-2.2, there is good synergistic function, improve dirt-removing power and the stability of liquid detergent。Being preferably carried out in mode in one, secondary alkyl sulfonate and isomeric alcohol polyethenoxy ether are 1.56 at weight part ratio。
As in a kind of embodiment, in described secondary alkyl sulfonate, n is 9 or 12。
Auxiliary agent:
Hydrotropic agent: the benzenesulfonic acid or its salt that replace such as are occurred 1～3 position the concrete preferred compound of described hydrotropic agent by the alkyl of carbon number 1～3。More particularly preferred p-toluenesulfonic acid, m-xylene monosulfonic acid, p-isopropyl sulfonic acid, EBSA, if using salt, particular certain cancers, potassium salt, magnesium salt。
Inorganic salt: " inorganic salt " of the present invention plays thickening power in the liquid formulations of the present invention。
Being preferably carried out in mode in one, described inorganic salt is one or both combination in sodium chloride or magnesium chloride。
Chelating agen: described chelating agen is ethylenediaminetetraacetic acid, disodium edta, ethylenediamine tetrapropionic acid, ethylenediamine tetrapropionic acid sodium salt, nitrilotriacetic acid or nitrilotriacetic acid sodium salt。
Preservative: described preservative is KF88, P-hydroxybenzoic acid alkane ester, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate and phenyl phenol preservative。
Fluorescent whitening agent: as fluorescent whitening agent, such as 4,4 '-bis--(2-sulfostyryl)-biphenyl salt, 4,4 '-bis--(the chloro-3-sulfostyryl of 4-)-biphenyl salt, 2-(styryl phenyl) naphthothiazoles derivant, 4, the 4 '-fluorescent whitening agent of bis-(triazole-2-base) derivants and double; two-(triazine radical amido) disulfonic acid derivatives etc.。
Being preferably carried out in mode in one, described fluorescent whitening agent is DSBP brightening agent or CBS-X brightening agent。
As fluorescent whitening agent, it is possible to be used alone a kind, it is also possible to two or more appropriately combined use。
The combined amount of fluorescent whitening agent, relative to the total amount of cleaning combination, it is preferable that below more than 0.001 mass %, 1 mass %。
Pigment: the pigment that " pigment " of the present invention is commonly used for the industry。
As colored pigment, it is possible to enumerate: the inorganic red pigment of ferrum oxide, hydrated ferric oxide. and iron titanate；The inorganic brown series pigments such as gamma-iron oxide；The inorganic yellow series pigments such as iron oxide yellow, loess；The inorganic black pigments such as iron oxide black, white carbon black；The inorganic violet pigment such as manganese violet, cobalt violet；The inorganic viridine greens such as chromic oxide gel, chromium oxide, cobalt oxide and cobalt titanate；The inorganic blue series pigment such as barba hispanica, ultramarine；By the pigment in tar system pigment color lake, by the pigment in natural pigment color lake and by the synthetic resin powder etc. of these powder Composites。
As pearlescent pigment, it is possible to enumerate: the Muscovitum being coated to titanium oxide, the mica powder being coated to titanium oxide, bismuth oxychloride, be coated to the bismuth oxychloride of titanium oxide, be coated to the Talcum of titanium oxide, guanin and be coated to the colored Muscovitum etc. of titanium oxide。
As metallic powdery pigment, it is possible to enumerate aluminium powder, copper powders and powder of stainless steel etc.。
As tar colorant, can enumerate: red No. 3, red No. 104, red No. 106, red No. 201, red No. 202, red No. 204, red No. 205, red No. 220, red No. 226, red No. 227, red No. 228, red No. 230, red No. 401, red No. 505, yellow 4, Sunset Yellow FCF, yellow 202, yellow 203, yellow 204, yellow 401, blue No. 1, blue No. 2, blue No. 201, blue No. 404, green No. 3, green No. 201, green No. 204, green No. 205, orange No. 201, orange No. 203, orange No. 204, orange No. 206 and orange No. 207 etc.。
As natural pigment, it is possible to enumerate: carminic acid, lac acid (laccaicacid), carthamin, hematoxylin (brazilin) and crocin etc.。
Spice: " spice " of the present invention for the industry frequently with spice。As spice, can be combined and use following known spice material: Oleum menthae, Oleum Menthae Rotundifoliae, Oleum Anisi Stellati, Eucalyptus oil, wintergreen oil, Oleum Cinnamomi, Oleum Caryophylli, thyme oil, sage oil, Fructus Citri Limoniae oil, orange oil, Oleum menthae, Cardamom oil, Fructus Coriandri oil, tangerine oil, lime oil, Oleum lavandula angustifolia, oil of rosemary, bay oil, Flos Matricariae chamomillae oil, caraway oil, Majorana hortensis oil, laurel, Indian oil of verbena, Herba Origani oil, pinke needle oil, orange blossom oil, Oleum Rosae Rugosae, Jasmin oil, oil of grapefruit, Sweetieoil, grape-fruit seed oil, concrete of iris, Herba Menthae absolute oil, rose absolute, the natural perfume materials such as Orange Blossom, with processed (the front-end volatiles removal to these natural perfume materials, tails is removed, fractional distillation, liquid-liquid extraction, refine, powdered flavour etc.) after spice；And menthol, carvone, anethole, eucalyptole, methyl salicylate, cinnamic aldehyde, acetaminol, 3-L-menthoxypropane-1, 2-glycol, thymol, linalool, linalyl acetate, limonene, menthone, menthyl acetate, N-replacement-to terpane-3-Methanamide, pinene, octanal, citral, pulegone, methyl acetate, anisaldehyde, ethyl acetate, ethyl n-butyrate., allyl cyclohexane propionic ester, methyl 2-aminobenzoate, ethyl methyl phenyl (+)-2,3-Epoxy-1-propanol, vanillin, undecalactone, hexanal, butanol, isoamyl alcohol, hexenol, dimethyl sulfide, methyl cyclopentenyl ketone, bran aldehyde, trimethylpyrazine, ethyl lactate, the single spice such as ethylenebis dithiocarbamate acetas；Also have the mediation spice etc. such as strawberry essence, apple essence, flavoring banana essence, flavoring pineapple essence, grape essence, Fructus Mangifera Indicae essence, butter flavor, milk flavour, fruit mixing essence, tropical fruit (tree) essence。
The basic components A of the present invention has basic cleaning function, in immersion process, it is possible to disintegrate the spot of fabric face；Described protection component C can be ionized into positive and negative electric charge in water; the protection component C of negative charge can take away the spot having been detached from fabric; simultaneously the protection component C of positive charge can be attached to the surface of fabric and carries out layer protective layer, it is prevented that the spot having been detached from deposits on fabric again。
Present inventor is found surprisingly that; in protection component C, material 1 is owing to having the side chain of suitable length; therefore " taking away " ability to spot can be improved; because spot can be formed " taking away circle " by the side chain of suitable length; when described branch lengths is long, winding between side chain, can be formed；And time too short, described " taking away circle " cannot be formed again。The surface of fabric can be formed protective layer again by material 2 simultaneously, and the feel of fabric, dyeing are all had certain protection。Conventional siloxanes is poly-organosilicon, fabric has certain absorbability, but the short chain material 2 adopted in the present invention can reduce winding, improves the protective capability to fabric。Meanwhile, the addition of described polyether-modified trisiloxanes can improve material 1 to " taking away " ability of spot and the material 2 protective capability to fabric, especially for pure cotton fabric, has super strong cleaning, protection and arrangement ability。The addition that its possible reason is polyether-modified trisiloxanes can reduce the capillary ionization equilibrium simultaneously changed in solution。Therefore, the all-round stain cleaning agent of the present invention, it is possible to comprehensively, quickly disintegrate the spot of medicated clothing depths, while having very strong dirt-removing power, has again certain textile finishing ability, does not damage fabric。
By the examples below the present invention is specifically described。Be necessary it is pointed out here that be; following example are served only for that the invention will be further described; it is not intended that limiting the scope of the invention; some nonessential improvement and adjustment that professional and technical personnel in the field makes according to the content of the invention described above, still fall within protection scope of the present invention。
It addition, illustrate without other, raw materials used is all commercially available。
A1: surfactant (anion surfactant)
Described anion surfactant is sodium lauryl sulphate, and model is: K12；Producer is: Wujiang Correspondent Chemical Co., Ltd.；
A2: surfactant (cationic surfactant)
Described cationic surfactant is hexadecyltrimethylammonium chloride, and model is: 1631；Producer is: Zibo Pan Ze Chemical Industry Science Co., Ltd；
A3: surfactant (nonionic surfactant)
Described nonionic surfactant is: NPE, and model is: TX-5；Producer is: Linyi wholesale city Yuan Fu industrial chemicals firm；
A4: surfactant (amphoteric surfactant)
Described amphoteric surfactant is dodecyldimethylammonium hydroxide inner salt, and model is: BS-12；Producer is: Linyi City Lanshan District Lv Sen Chemical Co., Ltd.；
B1: polyether-modified trisiloxanes (only 1-propenol-3 polyoxyalkyl ether)
Producer is: Jiangsu Hai'an Petrochemical Plant；
B2: polyether-modified trisiloxanes (only 1,1,1,3,5,5,5-heptamethyltrisiloxane)
No. CAS: 1873-88-7, product coding: H1267；Buy producer: ladder is uncommon likes chemical conversion industrial development company limited；
B3: polyether-modified trisiloxanes (1-propenol-3 polyoxyalkyl ether and 2,4,6-trimethyl cyclotrisiloxane are raw material)
Raw material: the described same B1 of 1-propenol-3 polyoxyalkyl ether, No. CAS of described 2,4,6-trimethyl cyclotrisiloxane is 13269-39-1, producer: Nanjing Xi Sibo organosilicon company limited；
Preparation method: so that the 1-propenol-3 polyoxyalkyl ether of 10.5mol and the Karstedt catalyst of 0.02mol are equipped with in the reaction there-necked flask of reflux condensing tube, stirrer; present 80 DEG C mix 30min with stirring under the protection of nitrogen; make activation of catalyst; it is sufficiently formed alkene-metal complex; then; temperature is increased to 110 DEG C; start slowly to drip 2; 4; 6-trimethyl cyclotrisiloxane 30min, after question response terminates, decompression removes unreacted 1,3; 5-trimethyl trisiloxanes and other low-boiling-point substances, to obtain final product。
B4: polyether-modified trisiloxanes (1-propenol-3 polyoxyalkyl ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane are raw material, and containing 10 ethylene oxide groups in polyether segment, the average relative molecular mass of 1-propenol-3 polyoxyalkyl ether is 500)
Prepare raw material: the same B1 of 1-propenol-3 polyoxyalkyl ether；1,1,1,3,5,5, the 5-same B2 of heptamethyltrisiloxane。
Preparation method: so that the 1-propenol-3 polyoxyalkyl ether of 10.5mol and the Karstedt catalyst of 0.02mol are equipped with in the reaction there-necked flask of reflux condensing tube, stirrer, present 80 DEG C mix 30min with stirring under the protection of nitrogen, make activation of catalyst; it is sufficiently formed alkene-metal complex; then, temperature is increased to 110 DEG C, starts slowly to drip 1; 1; 1,3,5; 5; 5-heptamethyltrisiloxane 30min, after question response terminates, decompression removes unreacted 1,1; 1; 3,5,5; 5-heptamethyltrisiloxane and other low-boiling-point substances, to obtain final product。
B5: polyether-modified trisiloxanes (1-propenol-3 polyoxyalkyl ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane are raw material, and containing 7 ethylene oxide groups in polyether segment, the average relative molecular mass of 1-propenol-3 polyoxyalkyl ether is 380)
Prepare raw material: 1-propenol-3 polyoxyalkyl ether is purchased from Jiangsu Hai'an Petrochemical Plant；1,1,1,3,5,5, the 5-same B2 of heptamethyltrisiloxane。
Preparation method: so that the 1-propenol-3 polyoxyalkyl ether of 10.5mol and the Karstedt catalyst of 0.02mol are equipped with in the reaction there-necked flask of reflux condensing tube, stirrer, present 80 DEG C mix 30min with stirring under the protection of nitrogen, make activation of catalyst; it is sufficiently formed alkene-metal complex; then, temperature is increased to 110 DEG C, starts slowly to drip 1; 1; 1,3,5; 5; 5-heptamethyltrisiloxane 30min, after question response terminates, decompression removes unreacted 1,1; 1; 3,5,5; 5-heptamethyltrisiloxane and other low-boiling-point substances, to obtain final product。
B6: polyether-modified trisiloxanes (1-propenol-3 polyoxyalkyl ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane are raw material, and containing 7 ethylene oxide groups in polyether segment, the average relative molecular mass of 1-propenol-3 polyoxyalkyl ether is 380)
Prepare raw material: the same B5 of 1-propenol-3 polyoxyalkyl ether；1,1,1,3,5,5, the 5-same B5 of heptamethyltrisiloxane。
Preparation method: so that the 1-propenol-3 polyoxyalkyl ether of 10.5mol and the Karstedt catalyst of 0.1mol are equipped with in the reaction there-necked flask of reflux condensing tube, stirrer, present 80 DEG C mix 30min with stirring under the protection of nitrogen, make activation of catalyst; it is sufficiently formed alkene-metal complex; then, temperature is increased to 110 DEG C, starts slowly to drip 1; 1; 1,3,5; 5; 5-heptamethyltrisiloxane 30min, after question response terminates, decompression removes unreacted 1,1; 1; 3,5,5; 5-heptamethyltrisiloxane and other low-boiling-point substances, to obtain final product。
C1: component C(material 1(Max(p1+p3, p2+p4) > m))
N=1, m=1, R1=R3=H, R2=R4=-CH2During COOH, described material 1 is 1,3-propanedicarboxylic acid, and No. CAS is 110-94-1, and production code member is G0069, buys producer and is: ladder is uncommon likes chemical conversion industrial development company limited；
C2: component C(material 1(Max(p1+p3, p2+p4) < 0.5m))
N=1, m=8, R1=R3=H, R2=R4=-CH2During COOH, described material 1 is tetracosandioic acid, and No. CAS is 821-38-5, and production code member is T0704, buys producer and is: ladder is uncommon likes chemical conversion industrial development company limited；
C3: component C(material 1:R1、R2、R3、R4Without ionogen in group)
Work as n=1, m=12, R1=R3=R2=R4During=H, described material 1 is n-tetradecane, and No. CAS is 629-59-4, and production code member is T0079, buys producer and is: ladder is uncommon likes chemical conversion industrial development company limited。
C4: component C(material 1:0.5m < Max(p1+p3, p2+p4) < m；M=8, R1=R3=H, R2=R4=-(CH2)3SO3H), n > 1)
Preparation method:
(1) carbon dioxide, 1,7-octadiene under the effect of catalyst, with toluene for solvent, at 60 DEG C, react generation 1,10-decanedial；
(2) 1,10-decanedial is at NaHSO4Aqueous solution under stoichiometric number hour, be subsequently adding dichloromethane and hydrochloric acid, collect solid, separatory is collected dichloromethane, is drained, and obtains material (2)。
(3) by the above-mentioned material (2) prepared, dropwise instill in hydrogen peroxide, instill 1h, after titration, continue stirred for several hour, be subsequently adding in the methanol solution of 5% hydrochloric acid, after producing precipitation, sucking filtration, wash with methanol hydrochloride solution, filter 23-5 times, vacuum drying a few hours, to obtain final product。
C5: component C(material 2:Ra、Rb、Rc、RdWithout ionogen in group)
Ra、Rb、Rc、RdFor methyl, described material 2 is 1,1,3,3,5,5,7,7-prestox-1,7-tetrasiloxane glycol。
C6: component C(material 2:Ra、RbSelected from butylamine, Rc、RdBeing selected from is methyl)
Described monomer of preparing is:
The described preparation method preparing monomer is as follows:
At 5-10 DEG C of temperature, being added in 50ml ether by above-mentioned for 1.2g monomer, dropwise instill deionized water, after dropwising, warming-in-water, to 55 DEG C, stirs, reacts 20min。Stratification, divides and removes sour water layer, be the NaHCO of 2% with mass fraction3Solution washing twice, then it is washed till neutrality with NaCl aqueous solution, to obtain final product。
C7: component C(material 1+ material 2, the weight ratio of material 1 and material 2 is 1:6)
Material 1 is C4, and material 2 is C6；Material 1 and material 2 are simple physical mixed。
C8: component C(material 1+ material 2, the weight ratio of material 1 and material 2 is 6:3)
Material 1 is C4, and material 2 is C6；Material 1 and material 2 are simple physical mixed。
D1: auxiliary agent (Oleum lavandula angustifolia, crocin, sodium chloride, KF88 preservative, DSBP brightening agent)
Oleum lavandula angustifolia: be purchased from Ji'an City Sen Hai spice company limited；Crocin: be purchased from Hui Lin bio tech ltd, Xi'an；Sodium chloride: be purchased from traditional Chinese medicines；KF88 preservative: model GY-KATHON, is purchased from Changzhou Run Yang Chemical Co., Ltd.；DSBP brightening agent: be purchased from Shanghai Feng Xian Chemical Industry Science Co., Ltd。
E1: deionized water
The preparation method of heretofore described all-round spot Cleasing compositions, comprises the following steps:
According to described parts by weight, being poured into by the 25-35% of deionized water total amount in material still, heating, to 60-80 DEG C, is then sequentially added into surfactant, polyether-modified trisiloxanes, material 1, auxiliary agent, material 2 while stirring, after stirring, add remaining deionized water, after material all dissolves, cooling, add preservative, essence and stir, it is 7.0-7.5 with Fructus Citri Limoniae acid for adjusting pH value, filters, to obtain final product。
Table 1 embodiment is arranged
Method of testing:
1. stability test: carry out-5 DEG C of stability tests, 45 DEG C of stability tests and cold cycling test。
-5 DEG C of stability test conditions: place one month in-5 DEG C of calorstats, observing outward appearance has without exception；
45 DEG C of stability test conditions: place one month in 45 DEG C of calorstats, observing outward appearance has without exception；
Cold cycling is tested :-18 DEG C of calorstats are placed 24 hours, is then transferred to 45 DEG C of calorstats and places 24 hours, continues 3 circulations, and observing outward appearance has without exception。
2. detergency test:
In order to verify the detergency of liquid detergent of the present invention, liquid detergent is carried out detergency test。
Adopt GB white carbon black soiled cotton JB-01, GB albumen soiled cotton JB-02, GB sebum soiled cotton JB-03, reference is done with the wash concentration 2g/L of standard liquid detergent, the wash concentration of selected test liquid detergent is 0.04g/L, and the formula of standard liquid detergent and other experiment conditions and method are with reference to QB1224-2012。
3. antiredeposition test: testing standard GB/T13174-2003
After detergency test, taking out soiled cotton, retain cleanout fluid, put into international fluorescence calico JB-00 and 2.0g standard loess dirt (5.6) in cleaning fluid cylinder, experiment condition and method according to standard GB/T13174-2003 detect, and test whiteness value。
After detergency test, taking out soiled cotton, retain cleanout fluid, put into textile calico and 2.0g standard loess dirt (5.6) in cleaning fluid cylinder, experiment condition and method according to standard GB/T13174-2003 detect, and test whiteness value。
Test result is in Table 2。
The performance test results of table 2 liquid detergent
In sum, it is known that, the laundry article of the present invention, compared with not containing protection component B, has the ability of very strong clean-up performance, permeability and antiredeposition。
Aforesaid example is merely illustrative, for explaining some features of inventive feature。Appended claim is intended to the scope wide as far as possible that requirement it is contemplated that, and embodiments as presented herein is only the explanation of embodiment of selection of combination according to all possible embodiment。Therefore, the selectional restriction of the example that the claim that the purpose of applicant is appended is not illustrated inventive feature。And the progress in science and technology will form the possible equivalent not being presently considered due to the inaccurate reason of language performance or son replacement, and these changes also should be interpreted to be covered by appended claim in the conceived case。
Claims (10)
1. an all-round spot Cleasing compositions, by weight, includes at least:
100 parts by weight of base component A: surfactant, deionized water；
0.2-10 weight portion protects the polyether-modified trisiloxanes of the material 1 of component B:0.1-9 weight portion, 0.1-1 weight portion；
The structural formula of described material 1 is as follows:
Wherein, described R1～R4It each is selected from hydrion, alkyl ,-(CH2)pOne in R, described R is ionogen, and is negative charge after ionization；
Described R5Selected from-(CH2)m, described m is 10-20；
Described n is the integer more than 0；
Described R1～R4Carbon chain length respectively p1～p4, and 0.5m < Max(p1+p3, p2+p4) < m；
Described polyether-modified trisiloxanes is to be raw material by 1-propenol-3 polyoxyalkyl ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane, is prepared by solvent-free polymeric。
2. the compositions described in claim 1, described R is the one in hydroxy-acid group, sulfonic acid group and phosphate group。
3. the compositions described in claim 1, described R1～R4In have at least one for-(CH2)pR。
4. the compositions described in claim 1, described protection component B also includes material 2, and the structural formula of described material 2 is as follows:
Wherein, described Ra、Rb、Rc、RdIt each is selected from methyl ,-(CH2)pRxIn one；
Described RxFor ionogen, and it is positive charge after ionization；
Described p is 1-8。
5. the compositions described in claim 4, described RxOne in fatty amine primary, secondary, tertiary, amidino groups。
6. the compositions described in claim 4, the weight ratio of described material 1 and material 2 is (1-9): (10-20)。
7. the compositions described in claim 4, the weight ratio of described material 1 and material 2 is (1-6): (15-20)。
8. the compositions described in claim 1, in described 1-propenol-3 polyoxyalkyl ether, containing 7-8 ethylene oxide group in polyether segment。
9. the compositions described in claim 1, it is in the cleaning process of fabric。
10. cleaning supplies for fabric, it uses the compositions described in claim 1～9。
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| CN106544196A (en) * | 2016-10-14 | 2017-03-29 | 西安优派生物科技有限公司 | A kind of liquid detergent and preparation method thereof |
| CN112625811A (en) * | 2020-12-21 | 2021-04-09 | 芭而蒂洗涤科技(天津)有限公司 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
| CN113544250A (en) * | 2019-03-26 | 2021-10-22 | 联合利华知识产权控股有限公司 | Composition comprising a metal oxide and a metal oxide |
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| CN106544196A (en) * | 2016-10-14 | 2017-03-29 | 西安优派生物科技有限公司 | A kind of liquid detergent and preparation method thereof |
| CN113544250A (en) * | 2019-03-26 | 2021-10-22 | 联合利华知识产权控股有限公司 | Composition comprising a metal oxide and a metal oxide |
| CN112625811A (en) * | 2020-12-21 | 2021-04-09 | 芭而蒂洗涤科技(天津)有限公司 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
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Address after: Yuchu Town, Jinghe Industrial Park, Gaoling District, Xi'an City, Shaanxi Province 710200 Patentee after: XI'AN YOULUQING TECHNOLOGY Co.,Ltd. Address before: Yuchu Town, Jinghe Industrial Park, Gaoling District, Xi'an City, Shaanxi Province 710200 Patentee before: XI'AN YOUPAI BIOTECHNOLOGY CO.,LTD. |