CN112625811A - Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof - Google Patents
Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof Download PDFInfo
- Publication number
- CN112625811A CN112625811A CN202011520729.3A CN202011520729A CN112625811A CN 112625811 A CN112625811 A CN 112625811A CN 202011520729 A CN202011520729 A CN 202011520729A CN 112625811 A CN112625811 A CN 112625811A
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- oil stain
- betaine
- novel low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention relates to a novel low-temperature strong oil stain emulsifier which comprises 100 parts by weight of water, 20-40 parts by weight of anionic surfactant, 50-60 parts by weight of betaine type zwitterionic surfactant, 10-30 parts by weight of chelating agent, 0.1-5 parts by weight of ledum palustre extract and 5-20 parts by weight of polyether modified silicone oil. The invention also relates to a preparation method of the novel low-temperature strong oil stain emulsifier. According to the invention, 5-20 parts by weight of polyether modified silicone oil is selected, so that the water contact angle of the fabric can be greatly reduced at normal temperature, and the emulsification effect is improved.
Description
Technical Field
The invention relates to a novel low-temperature strong-effect oil stain emulsifier and a preparation method thereof.
Background
The emulsifier is mainly used for removing oil stains of table towels, napkins, kitchen clothes and the like, and is particularly used for removing mineral oil which is difficult to clean. In order to effectively wash heavy oil stain fabrics, an emulsifier is usually used together with special strong oil stain treatment powder in industrial washing to achieve the purposes of removing oil, removing dirt and recovering color and luster together. The strong oil stain treatment powder contains a large amount of strong base, and can saponify heavy-duty oil and remove granular dirt; the emulsifier mainly contains surfactant, the penetration and emulsification functions of the surfactant are favorable for the washing effect of the strong oil stain treatment powder, and particularly, the nonionic surfactant contained in the emulsifier has very good effect of removing mineral oil. The two are used in combination, and can play a better emulsification and washing effect under the combined action in the aspect of removing animal and vegetable oil and mineral oil stains.
In order to ensure the treatment effect, the emulsifier is carried out at a high temperature of between 80 and 90 ℃. Corresponding to high-temperature washing and washing procedures, the detergent mainly comprises a nonionic wetting agent, a solvent and a fluorescent whitening agent, and oil stains, particularly mineral oil stains which are difficult to remove by using the penetrating, wetting, solubilizing and emulsifying capabilities of the nonionic surfactant and the dissolving and emulsifying capabilities of the solvent are removed.
However, high temperature washing at 80-90 ℃ will consume a large amount of energy. If the electric heating is adopted, the time is too long, the efficiency requirement is high, and the problem is not only the power consumption problem but also the washing efficiency problem.
In addition, the sterilization, disinfection, bacteriostasis and inflammation diminishing effects of the oil stain emulsifier need to be enhanced.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a novel low-temperature strong oil stain emulsifier which is composed of 100 parts by weight of water, 20-40 parts by weight of anionic surfactant, 50-60 parts by weight of betaine type zwitterionic surfactant, 10-30 parts by weight of chelating agent, 0.1-5 parts by weight of ledum palustre extract and 5-20 parts by weight of polyether modified silicone oil.
The oil stain emulsifier consists of 100 parts by weight of water, 30-40 parts by weight of anionic surfactant, 55-60 parts by weight of betaine type zwitterionic surfactant, 20-30 parts by weight of chelating agent and 15-20 parts by weight of polyether modified silicone oil.
The polyether modified silicone oil is absorbed at 25 DEG CThe viscosity at the degree of falling is 500-2/s。
The chemical structural formula of the polyether modified silicone oil is as follows:
The chelating agent is selected from one or more of calcium acetate, triethyl diamine tetraacetic acid disodium calcium, calcium gluconate, sodium acid pyrophosphate, sodium metaphosphate, sodium calcium sulfate, stearin oxide, sodium diacetate, sodium thiosulfate and sorbitol.
The betaine type zwitterionic surfactant is selected from one or more of cocamide dimethyl carboxymethyl betaine, cocamide dimethyl sulfopropyl betaine, octadecyl bis (2-hydroxypropyl) carboxymethyl betaine, oleyl alcohol dimethyl gamma-carboxypropyl betaine, dodecyl bis (2-hydroxypropyl) alpha-carboxyethyl betaine, cocoyl dimethyl sulfopropyl betaine, octadecyl dimethyl sulfopropyl betaine, dodecyl amide dimethyl carboxymethyl betaine and octadecyl amide dimethyl sulfopropyl betaine.
The anionic surfactant is selected from one or more of polyoxyethylene alkyl ether sulfate, linear alkylbenzene sulfonate, alkyl sulfate, alcohol sulfate, secondary alkane sulfonate, alpha-olefin sulfonate, alpha-sulfo fatty acid ester salt, fatty acid polyoxyethylene ether sulfate and polyoxyethylene alkyl ether carboxylate.
A preparation method of a novel low-temperature strong oil stain emulsifier comprises the following steps:
fully mixing 100 parts by weight of water, 20-40 parts by weight of anionic surfactant, 50-60 parts by weight of betaine type zwitterionic surfactant, 10-30 parts by weight of chelating agent and 5-20 parts by weight of polyether modified silicone oil to prepare the oil stain emulsifier.
The oil stain emulsifier comprises the following preparation components: 100 parts of water, 30-40 parts of anionic surfactant, 55-60 parts of betaine type zwitterionic surfactant, 20-30 parts of chelating agent and 15-20 parts of polyether modified silicone oil.
The viscosity of the polyether modified silicone oil at 25 ℃ is 500-3500mm2/s。
According to the invention, 5-20 parts by weight of polyether modified silicone oil is selected, so that the water contact angle of the fabric can be greatly reduced at normal temperature, and the emulsification effect is improved.
The ledum palustre extract of the invention is named as traditional Chinese medicine. Is leaf of Ledum palustre L.var.dillatatum Wahl.of Ericaceae. Distributed in northeast and inner Mongolia regions. Ledum palustre extract CAS registry No. 90063-39-1. By introducing the ledum palustre extract, the sterilization, disinfection, bacteriostasis and inflammation diminishing effects of the oil stain emulsifier are improved.
The above-described and other features, aspects, and advantages of the present application will become more apparent with reference to the following detailed description.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions of the embodiments of the present invention will be clearly and completely described below. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the described embodiments of the invention without any inventive step, are within the scope of protection of the invention.
Unless defined otherwise, technical or scientific terms used herein shall have the ordinary meaning as understood by one of ordinary skill in the art to which this invention belongs. The use of "first," "second," and similar terms in the description and claims of the present application do not denote any order, quantity, or importance, but rather the terms are used to distinguish one element from another. Also, the use of the terms "a" or "an" and the like do not denote a limitation of quantity, but rather denote the presence of at least one.
Long-chain alkyl modified silicone oil CJ-1321 Zhejiang Chuang base organosilicon Material Co., Ltd
Polyether modified silicone oil CJ-1421 Zhejiang Chuang base organic silicon Material Co., Ltd
To verify the detergency of the detergent compositions of the present invention, a detergency test was performed. According to the standard of GB/T13174-2008 'determination of detergency and circular washing performance of laundry detergent for clothing', the fabric cleaning rate is tested by using vegetable oil to stain dirty cloth (the dirty cloth contains 10wt% of vegetable oil, and the area of oil stain is about 80-90%).
The experimental conditions were: adopting 250ppm hard water, washing concentration of 1-6g/L, washing time of 15min, adopting RQHL type vertical decontamination machine specified by national standard, and rotating speed of 60 r/min.
Example 1
The oil stain emulsifier comprises the following preparation components: 100 parts by weight of water, 35 parts by weight of an anionic surfactant, 60 parts by weight of a betaine-type zwitterionic surfactant, 30 parts by weight of a chelating agent, 0.1 part by weight of ledum palustre extract, and 18 parts by weight of polyether-modified silicone oil. The temperature was 45 ℃ and the fabric cleaning rate was 1.74.
Example 2
The oil stain emulsifier comprises the following preparation components: 100 parts by weight of water, 35 parts by weight of an anionic surfactant, 58 parts by weight of a betaine-type zwitterionic surfactant, 25 parts by weight of a chelating agent, 1 part by weight of ledum palustre extract, and 20 parts by weight of polyether-modified silicone oil. The temperature was 45 ℃ and the fabric cleaning rate was 1.76.
Example 3
The oil stain emulsifier comprises the following preparation components: 100 parts by weight of water, 30 parts by weight of an anionic surfactant, 55 parts by weight of a betaine-type zwitterionic surfactant, 20 parts by weight of a chelating agent, 2 parts by weight of ledum palustre extract, and 15 parts by weight of polyether-modified silicone oil. The temperature was 45 ℃ and the fabric cleaning rate was 1.84.
Comparative example 1
The oil stain emulsifier comprises the following preparation components: 100 parts by weight of water, 30 parts by weight of an anionic surfactant, 55 parts by weight of a betaine-type zwitterionic surfactant, 20 parts by weight of a chelating agent, 1 part by weight of ledum palustre extract, and 3 parts by weight of a long-chain alkyl modified silicone oil. The temperature was 45 ℃ and the fabric cleaning rate was 1.23. The temperature 65 ℃ gave a fabric cleaning yield of 1.70.
Comparative example 2
The oil stain emulsifier comprises the following preparation components: 100 parts by weight of water, 30 parts by weight of an anionic surfactant, 55 parts by weight of a betaine-type zwitterionic surfactant, 20 parts by weight of a chelating agent, and 1 part by weight of ledum palustre extract. The temperature 65 ℃ gave a fabric cleaning yield of 1.71.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and the description is given here only for clarity, and those skilled in the art should integrate the description, and the embodiments may be combined appropriately to form other embodiments understood by those skilled in the art.
Claims (10)
1. The novel low-temperature strong oil stain emulsifier is characterized by comprising 100 parts by weight of water, 20-40 parts by weight of anionic surfactant, 50-60 parts by weight of betaine type zwitterionic surfactant, 10-30 parts by weight of chelating agent, 0.1-5 parts by weight of ledum palustre extract and 5-20 parts by weight of polyether modified silicone oil.
2. A novel low-temperature strong oil stain emulsifier according to claim 1, which is characterized by comprising 100 parts by weight of water, 30-40 parts by weight of anionic surfactant, 55-60 parts by weight of betaine type zwitterionic surfactant, 20-30 parts by weight of chelating agent and 15-20 parts by weight of polyether modified silicone oil.
3. The novel low-temperature strong oil stain emulsifier as claimed in claim 1, wherein the viscosity of the polyether modified silicone oil at 25 ℃ is 500-3500mm2/s。
4. The novel low-temperature strong oil stain emulsifier according to claim 1, wherein the polyether modified silicone oil has the following chemical structural formula:
5. A novel low-temperature strong oil stain emulsifier according to claim 1, wherein the chelating agent is selected from one or more of calcium acetate, triethyl diamine tetraacetic acid disodium calcium, calcium gluconate, sodium acid pyrophosphate, sodium metaphosphate, sodium calcium sulfate, stearine oxide, sodium diacetate, sodium thiosulfate and sorbitol.
6. A novel low-temperature strong oil stain emulsifier according to claim 1, wherein the betaine type zwitterionic surfactant is selected from one or more of cocamide dimethyl carboxymethyl betaine, cocamide dimethyl sulfopropyl betaine, octadecyl bis (2-hydroxypropyl) carboxymethyl betaine, oleyl alcohol dimethyl gamma-carboxypropyl betaine, dodecyl bis (2-hydroxypropyl) alpha-carboxyethyl betaine, cocoyl dimethyl sulfopropyl betaine, octadecyl dimethyl sulfopropyl betaine, dodecyl amide dimethyl carboxymethyl betaine, octadecyl amide dimethyl sulfopropyl betaine.
7. The novel low-temperature strong oil stain emulsifier according to claim 1, wherein the anionic surfactant is selected from one or more of polyoxyethylene alkyl ether sulfate, linear alkylbenzene sulfonate, alkyl sulfate, alcohol sulfate, secondary alkane sulfonate, alpha-olefin sulfonate, alpha-sulfo fatty acid ester salt, fatty acid polyoxyethylene ether sulfate and polyoxyethylene alkyl ether carboxylate.
8. A preparation method of a novel low-temperature strong oil stain emulsifier is characterized by comprising the following steps:
fully mixing 100 parts by weight of water, 20-40 parts by weight of anionic surfactant, 50-60 parts by weight of betaine type zwitterionic surfactant, 10-30 parts by weight of chelating agent and 5-20 parts by weight of polyether modified silicone oil to prepare the oil stain emulsifier.
9. The preparation method of the novel low-temperature strong oil stain emulsifier according to claim 8, wherein the oil stain emulsifier is prepared from the following components: 100 parts of water, 30-40 parts of anionic surfactant, 55-60 parts of betaine type zwitterionic surfactant, 20-30 parts of chelating agent and 15-20 parts of polyether modified silicone oil.
10. The method for preparing the novel low-temperature strong oil stain emulsifier according to claim 8, wherein the viscosity of the polyether modified silicone oil at 25 ℃ is 500-3500mm2/s。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011520729.3A CN112625811A (en) | 2020-12-21 | 2020-12-21 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011520729.3A CN112625811A (en) | 2020-12-21 | 2020-12-21 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112625811A true CN112625811A (en) | 2021-04-09 |
Family
ID=75320384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011520729.3A Pending CN112625811A (en) | 2020-12-21 | 2020-12-21 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112625811A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646670A (en) * | 2021-01-29 | 2021-04-13 | 芭而蒂洗涤科技(天津)有限公司 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
| CN113136267A (en) * | 2021-05-03 | 2021-07-20 | 芭而蒂洗涤科技(天津)有限公司 | A cleaning product containing Ledum Palustre L extract and its preparation method |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH072632A (en) * | 1992-11-09 | 1995-01-06 | General Electric Co <Ge> | Two-in-one shampoo system and conditioner containing silicone polyether copolymer |
| CN1150173A (en) * | 1995-09-22 | 1997-05-21 | 花王株式会社 | Liquid detergent composition |
| CN1196675A (en) * | 1995-08-01 | 1998-10-21 | 科尔加特·帕尔莫利弗公司 | Ultramild aqueous cleansing compositions |
| CN103343065A (en) * | 2013-07-08 | 2013-10-09 | 山东丽波日化股份有限公司 | Non-water-based high-active-substance-content clothing detergent, preparation method thereof and packaging bag therefor |
| CN103981039A (en) * | 2014-05-15 | 2014-08-13 | 深圳市绿色欧标科技有限公司 | Detergent and preparation method thereof |
| CN105400611A (en) * | 2014-09-06 | 2016-03-16 | 天津市天亨洗涤剂有限公司 | Multifunctional laundry detergent |
| CN105695117A (en) * | 2016-03-28 | 2016-06-22 | 西安优派生物科技有限公司 | Omnipotent stain cleaning composition |
| CN106635492A (en) * | 2016-12-05 | 2017-05-10 | 天津天狮生物发展有限公司 | Range hood cleaning agent and preparation method thereof |
| CN107779295A (en) * | 2016-08-24 | 2018-03-09 | 周丽 | High-efficiency antimicrobial liquid detergent |
| CN109837142A (en) * | 2019-04-10 | 2019-06-04 | 广州洁生日化有限公司 | Solid detergent without ethoxy compound |
| CN110982629A (en) * | 2019-10-30 | 2020-04-10 | 广州市浪奇实业股份有限公司 | Antibacterial fabric detergent |
-
2020
- 2020-12-21 CN CN202011520729.3A patent/CN112625811A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH072632A (en) * | 1992-11-09 | 1995-01-06 | General Electric Co <Ge> | Two-in-one shampoo system and conditioner containing silicone polyether copolymer |
| CN1196675A (en) * | 1995-08-01 | 1998-10-21 | 科尔加特·帕尔莫利弗公司 | Ultramild aqueous cleansing compositions |
| CN1150173A (en) * | 1995-09-22 | 1997-05-21 | 花王株式会社 | Liquid detergent composition |
| CN103343065A (en) * | 2013-07-08 | 2013-10-09 | 山东丽波日化股份有限公司 | Non-water-based high-active-substance-content clothing detergent, preparation method thereof and packaging bag therefor |
| CN103981039A (en) * | 2014-05-15 | 2014-08-13 | 深圳市绿色欧标科技有限公司 | Detergent and preparation method thereof |
| CN105400611A (en) * | 2014-09-06 | 2016-03-16 | 天津市天亨洗涤剂有限公司 | Multifunctional laundry detergent |
| CN105695117A (en) * | 2016-03-28 | 2016-06-22 | 西安优派生物科技有限公司 | Omnipotent stain cleaning composition |
| CN107779295A (en) * | 2016-08-24 | 2018-03-09 | 周丽 | High-efficiency antimicrobial liquid detergent |
| CN106635492A (en) * | 2016-12-05 | 2017-05-10 | 天津天狮生物发展有限公司 | Range hood cleaning agent and preparation method thereof |
| CN109837142A (en) * | 2019-04-10 | 2019-06-04 | 广州洁生日化有限公司 | Solid detergent without ethoxy compound |
| CN110982629A (en) * | 2019-10-30 | 2020-04-10 | 广州市浪奇实业股份有限公司 | Antibacterial fabric detergent |
Non-Patent Citations (1)
| Title |
|---|
| 张燕: "杜香属植物的化学成分及药理作用研究进展", 《内蒙古医学院学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646670A (en) * | 2021-01-29 | 2021-04-13 | 芭而蒂洗涤科技(天津)有限公司 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
| CN113136267A (en) * | 2021-05-03 | 2021-07-20 | 芭而蒂洗涤科技(天津)有限公司 | A cleaning product containing Ledum Palustre L extract and its preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5885762B2 (en) | Eco-friendly water washing and dry cleaning solvent and laundry composition containing the same | |
| JPWO2019111949A1 (en) | Cloth treatment composition | |
| CN112625811A (en) | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof | |
| CN102942998B (en) | Washing auxiliary agent for removing protein stains | |
| CN102304437B (en) | High-efficiency liquid-phase washing agent with bleaching effect for colored fabric | |
| CN101660267A (en) | Tea saponin textile auxiliary agent and production technology thereof | |
| TW201800568A (en) | Liquid detergent composition for textile products | |
| CN105087197A (en) | Abrasive containing stain-removing gel used during clothes hand washing | |
| CN106118916A (en) | A kind of Superconcentrated washing sheet and production technology thereof | |
| CN112646670A (en) | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof | |
| CN102378810B (en) | Cleaning agent composition and cleaning method | |
| JP2021113271A (en) | Liquid detergent composition for textile product | |
| CN103046345A (en) | Method for performing three-proof finishing on textile fabrics and garments | |
| CN106560509B (en) | Mobile laundry service environment friendly laundry auxiliary agent and its preparation method and application | |
| CN104862112A (en) | Clothes oil removal agent and preparation method thereof | |
| JP6719121B2 (en) | Textile detergent, soil release agent, and fiber cleaning method | |
| CN103725446A (en) | Cleanser with cloth renewing function and preparation method thereof | |
| JP2003226900A (en) | Liquid detergent composition | |
| KR102327645B1 (en) | Liquid Detergent Composition | |
| JP7317691B2 (en) | liquid detergent composition | |
| CN106833929B (en) | Environment-friendly cleaning agent for mineral oil stain on surface of fabric and preparation method thereof | |
| CN111021054A (en) | Application of refining oil removal agent SP-1360 | |
| JP7408420B2 (en) | Liquid detergent composition for drum type washing machines | |
| JP7173857B2 (en) | Garment care composition | |
| KR20130021731A (en) | Amphiphilic solvent for cleaning and dry-cleaning, and composition containing the same solvent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210409 |