CN109837142A - Solid detergent without ethoxy compound - Google Patents
Solid detergent without ethoxy compound Download PDFInfo
- Publication number
- CN109837142A CN109837142A CN201910285224.4A CN201910285224A CN109837142A CN 109837142 A CN109837142 A CN 109837142A CN 201910285224 A CN201910285224 A CN 201910285224A CN 109837142 A CN109837142 A CN 109837142A
- Authority
- CN
- China
- Prior art keywords
- parts
- solid detergent
- polyvinyl alcohol
- ethoxy compound
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
The present invention relates to detergent applications, aiming at the problem that being easy to affect human health containing ethoxy compound in traditional detergent, a kind of solid detergent without ethoxy compound is provided, the component including following mass fraction: 4-28 parts of mono- C12-18 alkylsurfuric acid ester sodium salt；5-25 parts of polyvinyl alcohol；1-14 parts of alkyl glycosides；1-12 parts of Cocoamidopropyl betaine；1-10 parts of cocamidopropyl propyl amide amine oxide；0.5-5 parts of soapberry extract；0.5-5 parts of glycerol；0.5-5 parts of sodium citrate；0.1-5 parts of silica；0.1-5 parts of polyether modified silicon oil；0.1-3 parts of citric acid；The gross mass number of solid detergent without ethoxy compound is 120 parts, remaining group is divided into deionized water.It is used cooperatively by using alkyl glycosides nonionic surfactant and mono- C12-18 alkylsurfuric acid ester sodium salt anionic surfactant, alkyl glycosides is nontoxic, non-stimulated to skin, it is not easy to have an impact to human health, it is not easy to pollute the environment.
Description
Technical field
The present invention relates to detergent applications, more specifically, it relates to a kind of solid washing without ethoxy compound
Agent.
Background technique
Detergent is the product for being used to clean particular formulation by wash clean process, is generally used for clothes washing.Detergent
Usually it is made of main components such as surfactant, builder and additives.
It is nonionic surfactant since ethoxy compound is ethylene oxide surfactant, without ion,
The interference of ion is not readily susceptible in washing process, dirt-removing power is strong, and it is cheap, cost performance is high, therefore, existing washing
Ethoxy compound generally can all be added in agent.
But ethoxy compound is easy to produce dioxanes in the production and use process, dioxanes may deposit human body
It in potential carcinogenic risk, may affect human health, therefore, still there is improved space.
Summary of the invention
In view of the deficienciess of the prior art, the first object of the present invention be to provide it is a kind of without ethoxy compound
Solid detergent, have the advantages that natural environmental-protective, it is pollution-free, be not easy to affect human health.
To achieve the above object, the present invention provides the following technical scheme that
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
4-28 parts of mono- C12-18 alkylsurfuric acid ester sodium salt；
5-25 parts of polyvinyl alcohol；
1-14 parts of alkyl glycosides；
1-12 parts of Cocoamidopropyl betaine；
1-10 parts of cocamidopropyl propyl amide amine oxide；
0.5-5 parts of soapberry extract；
0.5-5 parts of glycerol；
0.5-5 parts of sodium citrate；
0.1-5 parts of silica；
0.1-5 parts of polyether modified silicon oil；
0.1-3 parts of citric acid；
The gross mass number of the solid detergent without ethoxy compound is 120 parts, remaining group is divided into deionization
Water.
The present invention is further arranged to: the solid detergent without ethoxy compound includes following mass fraction
Component:
5-23 parts of polyvinyl alcohol；
4-20 parts of mono- C12-18 alkylsurfuric acid ester sodium salt；
1-10 parts of alkyl glycosides；
1-4 parts of Cocoamidopropyl betaine；
1-4 parts of cocamidopropyl propyl amide amine oxide；
0.5-3 parts of soapberry extract；
0.5-3 parts of glycerol；
0.5-3 parts of sodium citrate；
0.1-3 parts of silica；
0.1-3 parts of polyether modified silicon oil；
0.1-1 parts of citric acid；
The gross mass number of the solid detergent without ethoxy compound is 120 parts, remaining group is divided into deionization
Water.
By adopting the above technical scheme, by using alkyl glycosides nonionic surfactant and mono- C12-18 alkylsurfuric acid
Ester sodium salt anionic surfactant is used cooperatively to substitute traditional ethoxylate nonionic surfactant and rouge
Fat alcohol polyethenoxy ether sodium sulfate anionic surfactant, alkyl glycosides is synthesized by glucose and fatty alcohol, glucose
From corn, it is natural origin that fatty alcohol, which derives from vegetable fat, nontoxic, non-stimulated to skin, and alkyl glycosides
Biodegrade rapidly it is thorough, have stronger broad spectrum antibiotic activity so that detergent obtained is naturally harmless, it is not easy to
Human health is had an impact, it is not easy to pollute the environment；Meanwhile passing through the amount ratio of each component in control detergent
Example is conducive to the anion of various surface active agent compositions and non-ionic cooperation in detergent, is conducive to high molecular polymer
Emulsification it is complete, thus be conducive to enhance detergent dirt-removing power；In addition, Cocoamidopropyl betaine and soapberry mention
Object is taken to derive from plant, sodium citrate and citric acid are food-grade materials, and it is natural harmless, and cocamidopropyl propyl amide amine oxygen
Compound, silica, glycerol and polyether modified silicon oil all have the irritating effect for reducing other surfaces activating agent, simultaneously
Cocamidopropyl propyl amide amine oxide and anion and nonionic surfactant cooperate, and the synthesis for also advantageously improving detergent is washed
Performance is washed, to be conducive to the mild performance for being conducive to improve detergent while improving the dirt-removing power of detergent, so that washing
It washs agent to be not easy that human skin is caused to stimulate, it is not easy to affect human health.
The present invention is further arranged to: the alcoholysis degree of the polyvinyl alcohol is 66%-89%, the molecule of the polyvinyl alcohol
Amount is 20000-120000, and the average degree of polymerization of the polyvinyl alcohol is 550-2700.
The present invention is further arranged to: the alcoholysis degree of the polyvinyl alcohol is 85%-89%, the molecule of the polyvinyl alcohol
Amount is 25000-90000, and the average degree of polymerization of the polyvinyl alcohol is 550-1800.
By adopting the above technical scheme, by repeatedly practicing and testing, by control the alcoholysis degree of polyvinyl alcohol, molecular weight with
And average degree of polymerization, be conducive to polyvinyl alcohol and preferably cooperate with the other components in detergent, is conducive to enhance detergent
The mildness for being conducive to improve detergent while dirt-removing power, so that detergent is not easy to cause to stimulate to human skin, no
It is easy to affect human health.
The present invention is further arranged to: the carbon atom number of the alkyl glycosides is 8-18.
By adopting the above technical scheme, by control alkyl glycosides carbon atom number be 8-18, be conducive to alkyl glycosides with it is mono-
C12-18 alkylsurfuric acid ester sodium salt preferably coordinated is to play decontamination, so that advantageous while detergent is naturally harmless
In the dirt-removing power of enhancing detergent.
The present invention is further arranged to: further include the component of following mass fraction:
2-10 parts of kaolin.
By adopting the above technical scheme, by the way that kaolin is added as builder, be conducive to the dirt-removing power for enhancing detergent；
Meanwhile kaolin be from a kind of natural clay, it is nontoxic so that detergent is not easy to generate shadow to human health
It rings, kaolin also has adhesive effect to each component, is better mixed uniformly to be conducive to each component, so that the property of detergent
It can be more stable.
The present invention is further arranged to: further include the component of following mass fraction:
0.1-1 parts of potassium sorbate.
By adopting the above technical scheme, by the way that potassium sorbate is added in detergent, potassium sorbate is food grade preservative, is had
Antimicrobial preservative function conducive to enhancing detergent is conducive to extend the storage life of detergent so that detergent is not easy to be oxidized
Limit, so that the performance of detergent is not readily susceptible to influence；Meanwhile being conducive to improve the mildness of detergent, so that washing
Agent is not easy to cause to stimulate to skin.
The present invention is further arranged to: further include the component of following mass fraction:
0.1-0.5 parts of plant essence.
By adopting the above technical scheme, by be added plant essence so that detergent collect clothing help wash, lasting function is in one
Body is conducive to clothing lasting, so that detergent is more suitable for social actual needs, meanwhile, plant essence is extracted from plant, natural nothing
Evil, so that detergent is not easy to cause to stimulate to skin, while making detergent be not easy to impact environment.
The present invention is further arranged to: the glycerol is food grade glycerol, and the silica is food grade silicon dioxide.
By adopting the above technical scheme, by using food grade glycerol and food grade silicon dioxide, be conducive to improve washing
The mildness of agent so that detergent is not easy to cause to stimulate to human skin, while making detergent be not easy to cause environment
It influences.
In view of the deficienciess of the prior art, the second object of the present invention be to provide it is a kind of without ethoxy compound
The preparation method of solid detergent, have the advantages that natural environmental-protective, it is pollution-free, be not easy to affect human health.
A kind of preparation method of the solid detergent without ethoxy compound, it is characterized in that: the following steps are included:
S1, deionized water is added in the reaction vessel, polyvinyl alcohol is added while stirring, be heated to polyvinyl alcohol and go from
Sub- water is completely dissolved uniformly；
S2, kaolin, silica is added, stirs so that mixture is completely dissolved uniformly；
S3, the mono- C12-18 alkylsurfuric acid ester sodium salt of addition and stirring to mixture are completely dissolved uniformly；
S4, be added without ethoxy compound solid detergent remaining ingredient, stirring to be completely dissolved uniformly and make
Piece obtains product.
By adopting the above technical scheme, by adjusting the addition sequence of each component, each component be conducive in detergent is more preferable
Ground is mixed to form detergent, while being conducive to the emulsification of the high molecular polymer in detergent completely, so that preparation formation is washed
The dirt-removing power for washing agent is stronger, meanwhile, so that detergent is not easy to cause to stimulate to human skin, be conducive to improve detergent
Security performance；Meanwhile by the way that sheet products are made in detergent so that product have it is light, be easy to carry about with one, be readily transported it is excellent
Point, meanwhile, so that detergent is more convenient to use, only solid sheet detergent need to be added to the water to dissolution and impregnate clothing i.e.
It can.
In conclusion the invention has the following advantages:
1. by using alkyl glycosides nonionic surfactant and mono- C12-18 alkylsurfuric acid ester sodium salt anionic surface
Activating agent is used cooperatively to substitute traditional ethoxylate nonionic surfactant and fatty alcohol polyoxyethylene ether sulphur
Sour sodium anionic surfactant, alkyl glycosides is nontoxic, non-stimulated to skin, and the biodegrade of alkyl glycosides is thorough rapidly
Bottom has stronger broad spectrum antibiotic activity, so that solid detergent obtained is naturally harmless, it is not easy to produce to human health
It is raw to influence, it is not easy to pollute the environment；
2. being conducive to various surface active agent compositions in detergent by the usage ratio of each component in control detergent
Anion and non-ionic cooperation, the emulsification for being conducive to high molecular polymer is complete, to be conducive to enhance detergent
Dirty ability；
3. Cocoamidopropyl betaine and soapberry extract derive from plant, sodium citrate and citric acid are equal
It is natural harmless for food-grade materials, and cocamidopropyl propyl amide amine oxide, silica, glycerol and polyether modified silicon oil are equal
Irritating effect with reduction other surfaces activating agent, while cocamidopropyl propyl amide amine oxide and anion and nonionic
Surfactant cooperation, also advantageously improves the synthesis scourability of detergent, is conducive to the dirt-removing power for improving detergent
The mild performance for being conducive to improve detergent simultaneously, so that detergent is not easy to cause to stimulate to human skin, it is not easy to people
Body health impacts.
Specific embodiment
With reference to embodiments, invention is further described in detail.
In following embodiment, mono- C12-18- alkylsurfuric acid ester sodium salt is mono- using the happy Industrial Co., Ltd. of Shanghai Jin Jin
C12-18- alkylsurfuric acid ester sodium salt.
In following embodiment, Cocoamidopropyl betaine uses the model CAB-35 of Guangzhou Le Heng Chemical Co., Ltd.
Cocoamidopropyl betaine.
In following embodiment, cocamidopropyl propyl amide amine oxide use the article No. of Shanghai Tian Kan Biotechnology Co., Ltd for
The cocamidopropyl propyl amide amine oxide of TK21.
In following embodiment, soapberry extract uses the article No. of Xi'an Feng standing grain Biotechnology Co., Ltd for FH-247's
Soapberry extract.
In following embodiment, silica uses the food of the model 001 of Zibo Zhong Long petrochemical industry Science and Technology Ltd.
Grade silica.
In following embodiment, the article No. of the peace food additives Co., Ltd that sodium citrate uses Zhengzhou good is 20188763
Sodium citrate.
In following embodiment, citric acid uses the citric acid of Henan Te meter Te Biotechnology Co., Ltd.
In following embodiment, glycerol uses the food grade glycerol of vast and boundless million Chemical Co., Ltd.s in Guangzhou.
In following embodiment, polyether modified silicon oil uses the article No. of Laiyang City Zhong Xing organosilicon Co., Ltd for ZX-101's
Polyether modified silicon oil.
In following embodiment, kaolin uses the kaolin of Dehua County Mei Long Mining Development Co., Ltd.
In following embodiment, potassium sorbate uses the potassium sorbate of the preeminent chemical products Co., Ltd in Zhengzhou.
In following embodiment, plant essence uses the article No. of Nice flavors and fragrances Co., Ltd, Guangzhou Oman for 2587
Plant essence.
Embodiment 1
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Mono- C12-18- alkylsurfuric acid ester sodium salt 28kg；Polyvinyl alcohol 24kg；Deionized water 13kg；Alkyl glycosides 12kg；
Cocoamidopropyl betaine 12kg；Cocamidopropyl propyl amide oxide 7kg；Sodium citrate 5kg；Polyether modified silicon oil 5kg；Without trouble
Seed extract 4kg；Silica 4kg；Glycerol 4kg；Citric acid 2kg.
In the present embodiment, it is 2699 that polyvinyl alcohol, which is the article No. purchased from Inner Mongol Kai Du new material Science and Technology Ltd.,
Polyvinyl alcohol, the alcoholysis degree of polyvinyl alcohol 2699 are 98%-100%, molecular weight 107800-129800, and average degree of polymerization is
2450-2650。
In the present embodiment, alkyl glycosides APG0810.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 13kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, is delayed under stiring
It is slow that polyvinyl alcohol 24kg is added, 85 DEG C are heated to, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling are molten
Solution is uniform；
S2, it is slowly added to silica 4kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 28kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, be added alkyl glycosides 12kg, Cocoamidopropyl betaine 12kg, cocamidopropyl propyl amide oxide 7kg, without trouble
Seed extract 4kg, sodium citrate 5kg, citric acid 2kg, glycerol 4kg, polyether modified silicon oil 5kg, and each component is stirred evenly
To after being completely dissolved, it is delivered to film-making in pelleter and forms, obtain the solid detergent without ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 2
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Polyvinyl alcohol 25kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 25kg；Alkyl glycosides 14kg；Deionized water 12kg；
Cocamidopropyl propyl amide oxide 10kg；Cocoamidopropyl betaine 8kg；Soapberry extract 5kg；Silica 5kg；Glycerol
5kg；Sodium citrate 4kg；Polyether modified silicon oil 4kg；Citric acid 3kg.
In the present embodiment, polyvinyl alcohol is the poly- of the model 2499 purchased from the good Chemical Industry Science Co., Ltd of Shanghai fond dream
Vinyl alcohol, the alcoholysis degree of polyvinyl alcohol 2499 are 55%-65%, molecular weight 101200-110000, and average degree of polymerization is
2300-2500。
In the present embodiment, alkyl glycosides APG1214.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 12kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, is delayed under stiring
It is slow that polyvinyl alcohol 25kg is added, 90 DEG C are heated to, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling are molten
Solution is uniform；
S2, it is slowly added to silica 5kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 25kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, be added alkyl glycosides 14kg, Cocoamidopropyl betaine 8kg, cocamidopropyl propyl amide oxide 10kg, without trouble
Seed extract 5kg, sodium citrate 4kg, citric acid 3kg, glycerol 5kg, polyether modified silicon oil 4kg, and each component is stirred evenly
To after being completely dissolved, it is delivered to film-making in pelleter and forms, obtain the solid detergent without ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 3
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 76kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 20kg；Polyvinyl alcohol 5kg；Cocamidopropyl propyl amide sweet tea
Dish alkali 4kg；Cocamidopropyl propyl amide oxide 3kg；Silica 3kg；Polyether modified silicon oil 3kg；Sodium citrate 2kg；Glycerol
2kg；Alkyl glycosides 1kg；Soapberry extract 0.5kg；Citric acid 0.5kg；.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-26 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-26 is 86%-89%, molecular weight 124000-130000, average degree of polymerization 2500-2650.
In the present embodiment, alkyl glycosides APG0814.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 76kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, is delayed under stiring
It is slow that polyvinyl alcohol 5kg is added, 85 DEG C are heated to, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling dissolve
Uniformly；
S2, it is slowly added to silica 3kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 20kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, alkyl glycosides 1kg, Cocoamidopropyl betaine 4kg, cocamidopropyl propyl amide oxide 3kg, soapberry is added
Extract 0.5kg, sodium citrate 2kg, citric acid 0.5kg, glycerol 2kg, polyether modified silicon oil 3kg, and each component is stirred
It is even to be delivered to film-making molding in pelleter to after being completely dissolved, obtain the solid detergent for being free of ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 4
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 77kg；Polyvinyl alcohol 14kg；Alkyl glycosides 10kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 4kg；Coconut palm
Oleamide propyl oxide 4kg；Sodium citrate 3kg；Cocoamidopropyl betaine 2kg；Soapberry extract 2kg；Titanium dioxide
Silicon 1kg；Citric acid 1kg；Glycerol 1kg；Polyether modified silicon oil 1kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-24 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-24 is 86%-89%, molecular weight 118000-124000, average degree of polymerization 2400-2500.
In the present embodiment, alkyl glycosides APG0816.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 77kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, is delayed under stiring
It is slow that polyvinyl alcohol 14kg is added, 85 DEG C are heated to, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling are molten
Solution is uniform；
S2, it is slowly added to silica 1 kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 4kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, be added alkyl glycosides 10kg, Cocoamidopropyl betaine 2kg, cocamidopropyl propyl amide oxide 4kg, without trouble
Seed extract 2kg, sodium citrate 3kg, citric acid 1kg, glycerol 1kg, polyether modified silicon oil 1kg, and each component is stirred evenly
To after being completely dissolved, it is delivered to film-making in pelleter and forms, obtain the solid detergent without ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 5
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 69.9kg；Polyvinyl alcohol 23kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 12kg；Alkyl glycosides 5kg；
Glycerol 3kg；Cocamidopropyl propyl amide oxide 2kg；Silica 2kg；Cocoamidopropyl betaine 1kg；Soapberry extract
1kg；Sodium citrate 0.5kg；Polyether modified silicon oil 0.5kg；Citric acid 0.1kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
In the present embodiment, alkyl glycosides APG1216.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 69.9kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, under stiring
It is slowly added to polyvinyl alcohol 23kg, is heated to 90 DEG C, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling
It is uniformly dissolved；
S2, it is slowly added to silica 2kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 12kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, alkyl glycosides 5kg, Cocoamidopropyl betaine 1kg, cocamidopropyl propyl amide oxide 2kg, soapberry is added
Extract 1kg, sodium citrate 0.5kg, citric acid 0.1kg, glycerol 3kg, polyether modified silicon oil 0.5kg, and each component is stirred
Uniformly to after being completely dissolved, it is delivered to film-making in pelleter and forms, obtain the solid detergent without ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 6
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 72.5kg；Polyvinyl alcohol 20kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 10kg；Alkyl glycosides 8kg；
Cocoamidopropyl betaine 3kg；Soapberry extract 3kg；Cocamidopropyl propyl amide oxide 1kg；Sodium citrate 1kg；Lemon
Sour 0.8kg；Glycerol 0.5kg；Silica 0.1kg；Polyether modified silicon oil 0.1kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
In the present embodiment, alkyl glycosides APG0810.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 72.5kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, under stiring
It is slowly added to polyvinyl alcohol 20kg, is heated to 90 DEG C, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling
It is uniformly dissolved；
S2, it is slowly added to silica 0.1kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 10kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, alkyl glycosides 8kg, Cocoamidopropyl betaine 3kg, cocamidopropyl propyl amide oxide 1kg, soapberry is added
Extract 3kg, sodium citrate 1kg, citric acid 0.8kg, glycerol 0.5kg, polyether modified silicon oil 0.1kg, and each component is stirred
Uniformly to after being completely dissolved, it is delivered to film-making in pelleter and forms, obtain the solid detergent without ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 7
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 69.2kg；Polyvinyl alcohol 20kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 10kg；Alkyl glycosides 8kg；
Cocoamidopropyl betaine 3kg；Soapberry extract 3kg；Kaolin 2kg；Cocamidopropyl propyl amide oxide 1kg；Citric acid
Sodium 1kg；Potassium sorbate 1kg；Citric acid 0.8kg；Glycerol 0.5kg；Plant essence 0.3kg；Silica 0.1kg；It is polyether-modified
Silicone oil 0.1kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
In the present embodiment, alkyl glycosides APG0810.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 69.2kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, under stiring
It is slowly added to polyvinyl alcohol 20kg, is heated to 85 DEG C, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling
It is uniformly dissolved；
S2, it is slowly added to kaolin 2kg, silica 0.1kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 10kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, alkyl glycosides 8kg, Cocoamidopropyl betaine 3kg, cocamidopropyl propyl amide oxide 1kg, soapberry is added
Extract 3kg, it sodium citrate 1kg, citric acid 0.8kg, glycerol 0.5kg, polyether modified silicon oil 0.1kg, potassium sorbate 1kg, plants
Object essence 0.3kg, and after each component is evenly stirred until being completely dissolved, it is delivered to film-making in pelleter and forms, obtain without second
The solid detergent of oxo-compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 8
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 65.9kg；Polyvinyl alcohol 20kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 10kg；Alkyl glycosides 8kg；
Kaolin 6kg；Cocoamidopropyl betaine 3kg；Soapberry extract 3kg；Cocamidopropyl propyl amide oxide 1kg；Citric acid
Sodium 1kg；Citric acid 0.8kg；Glycerol 0.5kg；Potassium sorbate 0.5kg；Silica 0.1kg；Polyether modified silicon oil 0.1kg；It plants
Object essence 0.1kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
In the present embodiment, alkyl glycosides APG1214.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 65.9kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, under stiring
It is slowly added to polyvinyl alcohol 20kg, is heated to 85 DEG C, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling
It is uniformly dissolved；
S2, it is slowly added to kaolin 6kg, silica 0.1kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 10kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, alkyl glycosides 8kg, Cocoamidopropyl betaine 3kg, cocamidopropyl propyl amide oxide 1kg, soapberry is added
Extract 3kg, sodium citrate 1kg, citric acid 0.8kg, glycerol 0.5kg, polyether modified silicon oil 0.1kg, potassium sorbate 0.5kg,
Plant essence 0.1kg, and after each component is evenly stirred until being completely dissolved, it is delivered to film-making in pelleter and forms, be free of
The solid detergent of ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Embodiment 9
A kind of solid detergent without ethoxy compound, the component including following mass fraction:
Deionized water 61.9kg；Polyvinyl alcohol 20kg；Mono- C12-18- alkylsurfuric acid ester sodium salt 10kg；Kaolin 10kg；
Alkyl glycosides 8kg；Cocoamidopropyl betaine 3kg；Soapberry extract 3kg；Cocamidopropyl propyl amide oxide 1kg；Lemon
Sour sodium 1kg；Citric acid 0.8kg；Glycerol 0.5kg；Plant essence 0.5kg；Silica 0.1kg；Polyether modified silicon oil 0.1kg；
Potassium sorbate 0.1kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
In the present embodiment, alkyl glycosides APG0814.
Solid detergent without ethoxy compound the preparation method is as follows:
S1, deionized water 61.9kg is added in 150L stirred tank, is stirred with the revolving speed of 120r/min, under stiring
It is slowly added to polyvinyl alcohol 20kg, is heated to 85 DEG C, constant temperature 120min to deionized water and polyvinyl alcohol complete swelling
It is uniformly dissolved；
S2, it is slowly added to kaolin 10kg, silica 0.1kg, and stirred so that mixture is completely dissolved uniformly；
S3, mono- C12-18 alkylsurfuric acid ester sodium salt 10kg is added, and stirs to mixture and is completely dissolved uniformly；
S4, alkyl glycosides 8kg, Cocoamidopropyl betaine 3kg, cocamidopropyl propyl amide oxide 1kg, soapberry is added
Extract 3kg, sodium citrate 1kg, citric acid 0.8kg, glycerol 0.5kg, polyether modified silicon oil 0.1kg, potassium sorbate 0.1kg,
Plant essence 0.5kg, and after each component is evenly stirred until being completely dissolved, it is delivered to film-making in pelleter and forms, be free of
The solid detergent of ethoxy compound.
The application method of solid detergent without ethoxy compound is as follows:
Directly the solid detergent without ethoxy compound is put into the water for being used to wash clothing, so that being free of ethoxy
The solid detergent of based compound is dissolved in the water, soaking and washing clothing.
Using Chinese patent application file " a kind of environment-friendly type liquid detergent and its preparation side of Publication No. CN106479722A
Method " in embodiment as comparative example.
Comparative example 1
A kind of environment-friendly type liquid detergent, the component including following mass fraction:
Water 57.8kg；Coco-nut oil fatty acid potassium 8kg；Alcohol ether carboxylate AEC7kg；Fatty alcohol polyoxyethylene ether 5kg；Ethylene
Ether sodium sulfate 4.5kg；Propylene glycol 4kg；The trans- block copolymer GenifolPRF2520 4kg of one propylene oxide of ethylene oxide；Third
Olefin(e) acid/maleic acid Alcosperse415 3kg；Coconut oil diethanol amide 2kg；Citric acid 1kg；EDTA-4Na1kg；
1-hydroxy ethylidene-1,1-diphosphonic acid 0.6kg；Kathon 0.6kg；Essence 0.6kg；The compound alkaline washing enzyme 0.5kg of fatty alcohol polyoxy；Sodium chloride
0.4kg。
Environment-friendly type liquid detergent the preparation method is as follows:
First water 57.8kg is added in material-compound tank, stirring is opened, alcohol ether carboxylate AEC7kg, propylene glycol 4kg, hydroxyl second
Pitch di 2 ethylhexyl phosphonic acid 0.6kg, fatty alcohol polyoxyethylene ether 5kg, sodium sulfate of polyethenoxy ether of fatty alcohol 4.5kg, coco-nut oil fatty acid potassium
Trans- block copolymer GenifolPRF2520 4kg of 8kg, one propylene oxide of ethylene oxide, coconut oil diethanol amide 2kg, third
Olefin(e) acid/maleic acid Alcosperse415 3kg, citric acid 1kg, compound alkaline washing enzyme 0.5kg, EDTA-4Na1kg
It is added in agitator tank, is after mixing evenly 7 with lemon acid for adjusting pH value, Kathon 0.6kg and essence 0.6kg is added, uses sodium chloride
0.4kg adjusts viscosity, settles 24 hours and filters.
Comparative example 2
Water 62.3kg；Alcohol ether carboxylate AEC8kg；Coco-nut oil fatty acid potassium 6kg；Fatty alcohol polyoxyethylene ether 5kg；Fat
Alcohol polyethenoxy ether sodium sulfate 4kg；Coconut oil diethanol amide 4kg；Acrylic acid/maleic acid Alcosperse415
3kg；The trans- block copolymer GenifolPRF25202kg of one propylene oxide of ethylene oxide；Propylene glycol 1kg；Citric acid 1kg；
EDTA-4Na1kg；Compound alkaline washing enzyme 1kg；1-hydroxy ethylidene-1,1-diphosphonic acid 0.6kg；Sodium chloride 0.5kg；Kathon 0.3kg；Essence
0.3kg。
Environment-friendly type liquid detergent the preparation method is as follows:
First water 62.3kg is added in material-compound tank, stirring is opened, alcohol ether carboxylate AEC8kg, propylene glycol 1kg, hydroxyl second
Pitch di 2 ethylhexyl phosphonic acid 0.6kg, fatty alcohol polyoxyethylene ether 5kg, sodium sulfate of polyethenoxy ether of fatty alcohol 4kg, coco-nut oil fatty acid potassium
Trans- block copolymer GenifolPRF2520 2kg of 6kg, one propylene oxide of ethylene oxide, coconut oil diethanol amide 4kg, third
Olefin(e) acid/maleic acid Alcosperse415 3kg, citric acid 1kg, compound alkaline washing enzyme 1kg, EDTA-4Na1kg add
Enter in agitator tank, is after mixing evenly 7 with lemon acid for adjusting pH value, Kathon 0.3kg and essence 0.3kg is added, uses sodium chloride
0.5kg adjusts viscosity, settles 24 hours and filters.
Experiment 1
Above embodiments and comparative example are prepared resulting detergent substantially uniformity to be dissolved in the water, it is molten to form detergent
Liquid, and using the Contents of Dioxane (μ g/mL) in gas chromatography-mass spectrography detection detergent solution.
Experiment 2
It takes 10g above embodiments and comparative example to prepare resulting detergent respectively to be dissolved in the water of 100g, forms washing
Agent solution, according to the dirt of the annex in GB/T13174-2008 " dress material detergent detergency and the measurement for recycling scourability "
Cloth preparation method prepares several block-shaped carbon black greasy dirt cloth JB-01 of the same size, albumen soiled cotton JB-02, sebum soiled cotton respectively
JB-03, edible oil soiled cotton JB-04 and starch soiled cotton JB-05, and " dress material is gone with detergent according to GB/T13174-2008
Dirty power and the measurement for recycling scourability " each embodiment of detection and comparative example prepare the decontamination value of resulting detergent.
Each embodiment and the detection data of comparative example are shown in Table 1.
Table 1
It can be obtained according to the data comparison of embodiment 1-9 and comparative example 1-2 in table 1, embodiment 1-9 is all made of of the invention
Component proportion and preparation method without ethoxy compound prepare detergent, and comparative example 1-2 is all made of traditional containing ethoxy
The component proportion and preparation method of based compound prepare detergent, and prepared by embodiment 1-9 does not contain in resulting detergent
Dioxanes, the detergent of comparative example 1-2 contain a small amount of dioxanes, illustrate by using the group assignment system for being free of ethoxy compound
Detergent is formed, the content of the dioxanes in detergent is advantageously reduced, so that detergent is not easy to make human health
At influence；Meanwhile the decontamination value of the detergent of embodiment 1-9 quite even compares with the decontamination value of the detergent of comparative example 1-2
Comparative example 1-2's is higher, illustrates by using the alkyl glycosides and mono- C12-18 alkyl sulfate sodium for being free of ethoxy compound
Salt is used cooperatively, and is conducive to the dirt-removing power for being conducive to enhance detergent while improving the natural environmental-protective performance of detergent.
It can be obtained according to the data comparison of embodiment 1-6 in table 1, the alcoholysis degree of the polyvinyl alcohol of embodiment 1 and embodiment 2
Other than the range of 66%-89%, and the molecular weight of the polyvinyl alcohol of embodiment 1 is other than the range of 20000-120000,
The molecular weight of the polyvinyl alcohol of embodiment 2 is within the scope of 20000-120000；The polyethylene of embodiment 3 and embodiment 4
Within the scope of 20000-120000 and other than the range of 25000-90000, polyvinyl alcohol is averaged the molecular weight of alcohol
The degree of polymerization is within the scope of 550-2700 and other than the range of 550-1800；The polyethylene of embodiment 5 and embodiment 6
The molecular weight of alcohol within the scope of 25000-90000, the average degree of polymerization of polyvinyl alcohol the range of 550-1800 with
Interior, the decontamination value of embodiment 5 and embodiment 6 is greater than embodiment 3 and the embodiment 2 that is greater than of embodiment 4 is greater than embodiment 1, says
Alcoholysis degree, molecular weight and the average degree of polymerization of bright proportion and control polyvinyl alcohol by controlling each component, are conducive to wash
The each component preferably coordinated in agent is washed to play emulsification and decontamination, so that the dirt-removing power of detergent is more
By force, so that the decontamination value of detergent increases.
It can be obtained according to the data comparison of embodiment 5-6 in table 1 and embodiment 7-9, the component ratio embodiment in embodiment 7-9
The component of 5-6 has increased kaolin, potassium sorbate and plant essence newly, and the decontamination value of embodiment 7-9 is big to a certain extent
In embodiment 5-6, illustrate to be conducive to each component in detergent by the way that kaolin, potassium sorbate and plant essence is added
Bonding is better mixed, is conducive to the anti-corrosive antibacterial performance for enhancing detergent, so that the performance of detergent is more stable, to make
The dirt-removing power for obtaining detergent is not readily susceptible to influence, so that the decontamination value of detergent is higher.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this
Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it
It is interior.
Claims (10)
1. a kind of solid detergent without ethoxy compound, it is characterized in that: including the component of following mass fraction:
4-28 parts of mono- C12-18 alkylsurfuric acid ester sodium salt；
5-25 parts of polyvinyl alcohol；
1-14 parts of alkyl glycosides；
1-12 parts of Cocoamidopropyl betaine；
1-10 parts of cocamidopropyl propyl amide amine oxide；
0.5-5 parts of soapberry extract；
0.5-5 parts of glycerol；
0.5-5 parts of sodium citrate；
0.1-5 parts of silica；
0.1-5 parts of polyether modified silicon oil；
0.1-3 parts of citric acid；
The gross mass number of the solid detergent without ethoxy compound is 120 parts, remaining group is divided into deionized water.
2. the solid detergent according to claim 1 without ethoxy compound, it is characterized in that: described be free of ethyoxyl
The solid detergent of compound includes the component of following mass fraction:
5-23 parts of polyvinyl alcohol；
4-20 parts of mono- C12-18 alkylsurfuric acid ester sodium salt；
1-10 parts of alkyl glycosides；
1-4 parts of Cocoamidopropyl betaine；
1-4 parts of cocamidopropyl propyl amide amine oxide；
0.5-3 parts of soapberry extract；
0.5-3 parts of glycerol；
0.5-3 parts of sodium citrate；
0.1-3 parts of silica；
0.1-3 parts of polyether modified silicon oil；
0.1-1 parts of citric acid；
The gross mass number of the solid detergent without ethoxy compound is 120 parts, remaining group is divided into deionized water.
3. the solid detergent according to claim 1 to 2 without ethoxy compound, it is characterized in that: the poly- second
The alcoholysis degree of enol is 66%-89%, and the molecular weight of the polyvinyl alcohol is 20000-120000, and the average of the polyvinyl alcohol gathers
Right is 550-2700.
4. the solid detergent according to claim 3 without ethoxy compound, it is characterized in that: the polyvinyl alcohol
Alcoholysis degree is 85%-89%, and the molecular weight of the polyvinyl alcohol is 25000-90000, and the average degree of polymerization of the polyvinyl alcohol is
550-1800。
5. the solid detergent according to claim 1 to 2 without ethoxy compound, it is characterized in that: the alkyl
The carbon atom number of glucosides is 8-18.
6. the solid detergent according to claim 1 to 2 without ethoxy compound, it is characterized in that: further include with
The component of lower mass fraction:
2-10 parts of kaolin.
7. the solid detergent according to claim 1 to 2 without ethoxy compound, it is characterized in that: further include with
The component of lower mass fraction:
0.1-1 parts of potassium sorbate.
8. the solid detergent according to claim 1 to 2 without ethoxy compound, it is characterized in that: further include with
The component of lower mass fraction:
0.1-0.5 parts of plant essence.
9. the solid detergent according to claim 1 to 2 without ethoxy compound, it is characterized in that: the glycerol
For food grade glycerol, the silica is food grade silicon dioxide.
10. a kind of preparation method of the solid detergent without ethoxy compound as described in claim 1-9 is any, special
Sign is: the following steps are included:
S1, deionized water is added in the reaction vessel, polyvinyl alcohol is added while stirring, be heated to polyvinyl alcohol and deionized water
It is completely dissolved uniformly；
S2, kaolin, silica is added, stirs so that mixture is completely dissolved uniformly；
S3, the mono- C12-18 alkylsurfuric acid ester sodium salt of addition and stirring to mixture are completely dissolved uniformly；
S4, the remaining ingredient for being free of the solid detergent of ethoxy compound is added, stirring is obtained to uniform and film-making is completely dissolved
Product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910285224.4A CN109837142B (en) | 2019-04-10 | 2019-04-10 | Solid detergents without ethoxylates |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910285224.4A CN109837142B (en) | 2019-04-10 | 2019-04-10 | Solid detergents without ethoxylates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109837142A true CN109837142A (en) | 2019-06-04 |
| CN109837142B CN109837142B (en) | 2021-01-26 |
Family
ID=66886977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910285224.4A Active CN109837142B (en) | 2019-04-10 | 2019-04-10 | Solid detergents without ethoxylates |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109837142B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112625811A (en) * | 2020-12-21 | 2021-04-09 | 芭而蒂洗涤科技(天津)有限公司 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
| CN114395450A (en) * | 2021-12-31 | 2022-04-26 | 上海范耐斯日用品有限公司 | Environment-friendly solid washing tablet and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492573A (en) * | 2011-12-06 | 2012-06-13 | 大连晟骊商贸有限公司 | Laundry sheet |
| CN102885740A (en) * | 2012-10-22 | 2013-01-23 | 广州立白企业集团有限公司 | Hair cleanser containing no dioxane residue and preparation method of hair cleanser |
| CN105316119A (en) * | 2015-10-20 | 2016-02-10 | 成都市三禾田生物技术有限公司 | Sapindoside infant laundry detergent and preparation method thereof |
-
2019
- 2019-04-10 CN CN201910285224.4A patent/CN109837142B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492573A (en) * | 2011-12-06 | 2012-06-13 | 大连晟骊商贸有限公司 | Laundry sheet |
| CN102885740A (en) * | 2012-10-22 | 2013-01-23 | 广州立白企业集团有限公司 | Hair cleanser containing no dioxane residue and preparation method of hair cleanser |
| CN105316119A (en) * | 2015-10-20 | 2016-02-10 | 成都市三禾田生物技术有限公司 | Sapindoside infant laundry detergent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112625811A (en) * | 2020-12-21 | 2021-04-09 | 芭而蒂洗涤科技(天津)有限公司 | Novel low-temperature strong-effect oil stain emulsifier and preparation method thereof |
| CN114395450A (en) * | 2021-12-31 | 2022-04-26 | 上海范耐斯日用品有限公司 | Environment-friendly solid washing tablet and preparation method thereof |
| CN114395450B (en) * | 2021-12-31 | 2024-04-16 | 上海范耐斯日用品有限公司 | Environment-friendly solid washing tablet and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109837142B (en) | 2021-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108841463B (en) | Detergent composition | |
| EP3122854B1 (en) | Cleaning compositions containing cationic polymers in an aes-enriched surfactant system | |
| CN104818168B (en) | A kind of laundry soap lye and preparation method thereof | |
| CN106047522B (en) | A kind of anhydrous liquid detergent of hyperconcetration type and preparation method thereof and solidifying pearl of doing washing | |
| JP6911039B2 (en) | Home care composition | |
| DE10021726A1 (en) | Nanoparticles are used for loosening dirt and/or reducing resoiling of hard surface or textile, especially in a textile finish, washing, pretreatment or after-treatment agent | |
| EP2961822B1 (en) | Formulations, use of same as or for manufacture of dishwashing agents and their manufacture | |
| CN105695148B (en) | A kind of environment protection solid cleansing composition | |
| EA023284B1 (en) | Liquid surfactant compositions structured with fibrous polymer and further comprising citrus fibers having no flow instability or shear banding | |
| CN103834481A (en) | Compound medical equipment multi-enzyme cleaning agent | |
| CN109837142A (en) | Solid detergent without ethoxy compound | |
| CN109135954A (en) | A kind of environment-friendly high-efficiency liquid detergent | |
| CN107603771A (en) | One kind concentration liquid detergent and preparation method | |
| CN113174297A (en) | Long-acting antibacterial mite-killing washing sheet and production process thereof | |
| KR20180007521A (en) | A natural detergent composition and method for preparing the same | |
| CN110106037A (en) | A kind of anti-colour contamination detergent | |
| CN104560457A (en) | Infant laundry detergent and preparation method thereof | |
| JP4181217B2 (en) | Aqueous pearlescent agent concentrate | |
| DE10004677A1 (en) | Surfactant mixture used in detergent and rinse agents, comprises anionic surfactants and plant-based fatty alcohol ethoxylate of specific iodine number and conjugate content | |
| EP2295030B1 (en) | Use of isosorbide ethers in detergents and cleaners | |
| EP1904613B1 (en) | Cleaning care product with improved emulsification properties | |
| CN110257186B (en) | Liquid detergent and preparation method and application thereof | |
| CN105002000B (en) | A kind of cleanser and its production and use | |
| DE2153460A1 (en) | DISHWASHING LIQUID | |
| CN108165376B (en) | Detergent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |