CN110106037A - A kind of anti-colour contamination detergent - Google Patents
A kind of anti-colour contamination detergent Download PDFInfo
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- CN110106037A CN110106037A CN201910394574.4A CN201910394574A CN110106037A CN 110106037 A CN110106037 A CN 110106037A CN 201910394574 A CN201910394574 A CN 201910394574A CN 110106037 A CN110106037 A CN 110106037A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The present invention relates to detergent technical fields to provide a kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre aiming at the problem that anion in detergent is easy to be easy to interact with the cation inhaled in color substance；Solid detergent includes the component of following mass fraction: 5-28 parts of polyvinyl alcohol；5-36 parts of sldium lauryl sulfate；2-15 parts of laureth sodium sulfovinate；1-5 parts of Cocoamidopropyl betaine；1-10 parts of lauric acid amide of ethanol；0.5-6 parts of fatty alcohol polyoxyethylene ether；0.5-6 parts of fatty acid methyl ester ethoxy compound；0.1-6 parts of maleic acid-acrylic acid copolymer；0.5-5 parts of sodium citrate；0.1-2 parts of citric acid；1-5 parts of glycerol；0.5-3 parts of soapberry extract；The gross mass number of solid detergent is 105 parts, remaining group is divided into deionized water.Anion in solid detergent is not easy to offset each other with the cation inhaled in color fibre, is conducive to anti-colour contamination detergent while having both good dirt-removing functions and inhaling color function.
Description
Technical field
The present invention relates to detergent technical fields, more specifically, it relates to a kind of anti-colour contamination detergent.
Background technique
With the continuous development of society, people's lives quality increasingly improves, with washing machine clean clothing have become it is each
Family it is required.But in daily life, the clothes of different colours mixes washing, it is easy to will cause clothing string
The phenomenon that color, therefore, detergent, have the function of that anti-colour contamination is particularly important.
Currently, people mainly by washing process be added inhale color chips to solve this problem, still, most suction color
Piece is all that the product solely produced or independent packaging and detergent separate, and people need to be respectively put into when in use, troublesome in poeration,
Therefore, there is part of the manufacturer that color protection ingredient can be added in liquid detergent also to prepare and have the detergent for inhaling color function.But
Since detergent is all mainly the substance with suction color function based on strong anionic property surfactant, with strong cation
It when being mixed with mutually, may be adsorbed mutually between zwitterion, negative function be generated, so that the decontamination function of detergent
The suction color function of color protection ingredient is made also to be easy to be affected while capable of being affected.
Summary of the invention
In view of the deficienciess of the prior art, the first object of the present invention is to provide a kind of anti-colour contamination detergent, have
Good dirt-removing power is provided simultaneously with the advantages of good suction color ability.
To achieve the above object, the present invention provides the following technical scheme that
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
The solid detergent includes the component of following mass fraction:
5-28 parts of polyvinyl alcohol；
5-36 parts of sldium lauryl sulfate；
2-15 parts of laureth sodium sulfovinate；
1-5 parts of Cocoamidopropyl betaine；
1-10 parts of lauric acid amide of ethanol；
0.5-6 parts of fatty alcohol polyoxyethylene ether；
0.5-6 parts of fatty acid methyl ester ethoxy compound；
0.1-6 parts of maleic acid-acrylic acid copolymer；
0.5-5 parts of sodium citrate；
0.1-2 parts of citric acid；
1-5 parts of glycerol；
0.5-3 parts of soapberry extract；
The gross mass number of the solid detergent is 105 parts, remaining group is divided into deionized water.
The present invention is further arranged to: the solid detergent includes the component of following mass fraction:
5-20 parts of polyvinyl alcohol；
5-18 parts of sldium lauryl sulfate；
2-8 parts of laureth sodium sulfovinate；
1-3 parts of Cocoamidopropyl betaine；
1-5 parts of lauric acid amide of ethanol；
0.5-5 parts of fatty alcohol polyoxyethylene ether；
0.5-2.5 parts of fatty acid methyl ester ethoxy compound；
0.1-3 parts of maleic acid-acrylic acid copolymer；
0.5-3 parts of sodium citrate；
0.1-1 parts of citric acid；
1-3 parts of glycerol；
0.5-2 parts of soapberry extract；
The gross mass number of the solid detergent is 105 parts, remaining group is divided into deionized water.
By adopting the above technical scheme, since solid detergent and suction color fibre are in solid-like, so that solid washs
The cation in anion and suction color fibre in agent is not easy to form the form of dissociated ion in the solution, so that solid
Anion in detergent is not easy to offset each other with the cation inhaled in color fibre, and then is conducive to anti-colour contamination detergent simultaneously
It has both good dirt-removing functions and inhales color function；By addition polyvinyl alcohol, be conducive to the stickiness for enhancing solid detergent, thus
Be conducive to enhance solid detergent and inhale color fibre bonding force so that solid detergent and inhale color fibre between it is bonding more
Securely；By the cooperation of polyvinyl alcohol, sldium lauryl sulfate and fatty acid methyl ester ethoxy compound, being conducive to, which enhances solid, is washed
It washs agent and is conducive to enhance the dirt-removing power of solid detergent while inhaling the bonding force between color fibre, so that anti-colour contamination
Detergent has both better dirt-removing power simultaneously and inhales color ability.
The present invention is further arranged to: the polyvinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethoxy compound
Mass parts ratio be 1:1-1.5:0.1-0.2.
By adopting the above technical scheme, pass through control polyvinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethyoxyl chemical combination
The mass parts ratio of object is 1:1-1.5:0.1-0.2, is conducive to the stickiness for enhancing solid detergent, so that solid detergent and suction
The bonding of color fibre is stronger, meanwhile, the dirt-removing power of enhancing solid detergent is also helped, and then be conducive to anti-colour contamination and wash
It washs agent while having both better dirt-removing power and inhaling color ability.
The present invention is further arranged to: the solid detergent further includes the component of following mass fraction:
1-5 parts of 4A zeolite.
By adopting the above technical scheme, by the way that 4A zeolite is added, the adsorption ability of 4A zeolite is strong, the dirt of adsorbable suspension
Spot secondary deposition is beneficial to prevent while stain, to be conducive to enhance the dirt-removing power of solid detergent；Meanwhile 4A zeolite
It is a kind of preferable white solid of nontoxic, odorless, tasteless and mobility, no pollution to the environment, it is not easy to environment is impacted,
Be conducive to improve the environmental-protecting performance of anti-colour contamination detergent.
The present invention is further arranged to: the solid detergent further includes the component of following mass fraction:
0.1-1 parts of essence.
By adopting the above technical scheme, by the way that essence is added, be conducive to the lasting function of enhancing anti-colour contamination detergent, so that adopting
The lasting aroma retaining effect of clothing after being washed with anti-colour contamination detergent is more preferable.
The present invention is further arranged to: the alcoholysis degree of the polyvinyl alcohol is 66%-89%, the molecule of the polyvinyl alcohol
Amount is 20000-90000, and the average degree of polymerization of the polyvinyl alcohol is 550-1800.
The present invention is further arranged to: the alcoholysis degree of the polyvinyl alcohol is 86%-89%, the molecule of the polyvinyl alcohol
Amount is 25000-40000, and the average degree of polymerization of the polyvinyl alcohol is 550-1000.
By adopting the above technical scheme, by controlling alcoholysis degree, molecular weight and the average degree of polymerization of polyvinyl alcohol, be conducive to pair
The viscosity of polyvinyl alcohol is adjusted, so that polyvinyl alcohol and the bonding force for inhaling color fibre are stronger, so that favorably enhancing solid is washed
Wash the bonding fastness between agent and suction color fibre；Meanwhile be conducive to polyvinyl alcohol preferably with sldium lauryl sulfate and rouge
The cooperation of fatty acid methyl esters ethoxy compound to be conducive to enhance the dirt-removing power of solid detergent, and then is conducive to anti-colour contamination
Detergent has both better dirt-removing functions simultaneously and inhales color function.
In view of the deficienciess of the prior art, the second object of the present invention is to provide a kind of preparation of anti-colour contamination detergent
Method has the advantages that preparing resulting anti-colour contamination detergent is provided simultaneously with good dirt-removing power and inhales color ability.
To achieve the above object, the present invention provides the following technical scheme that
A kind of preparation method of anti-colour contamination detergent, comprising the following steps:
S1, polyvinyl alcohol is dissolved by heating；
S2, sldium lauryl sulfate and fatty methyl esters ethoxy compound are added into polyvinyl alcohol, are uniformly mixed,
Form mixture；
S3, the remaining ingredient that solid detergent is added into mixture, are uniformly mixed, form detergent；
S4, detergent is tentatively dried at a temperature of 80 DEG C -110 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, continues to dry solid detergent to being completely dried, so that solid
Detergent and suction color fibre form one to get anti-colour contamination detergent.
By adopting the above technical scheme, by first dissolving by heating polyvinyl alcohol, sldium lauryl sulfate and fatty first are added
Ester ethoxy compound, due to polyvinyl alcohol tool be a bit sticky, thus be conducive to polyvinyl alcohol and sldium lauryl sulfate with
And fatty methyl esters ethoxy compound is better mixed uniformly, and then is conducive to polyvinyl alcohol, sldium lauryl sulfate and fat
Preferably cooperate between methyl esters ethoxy compound, is conducive to have while enhancing the bonding force of solid detergent and suction color fibre
Conducive to enhancing solid detergent dirt-removing power, and then be conducive to anti-colour contamination detergent at the same have both better dirt-removing functions and
Inhale color function；By first partially desiccated detergent to preliminarily form solid, then color fibre will be inhaled and be attached on detergent and continue
It is dried to solid detergent to be completely dried, so that solid detergent and suction color fibre form one, so that solid detergent
In anion and inhale color fibre in cation be not easy to form free ionic forms in the solution so that solid is washed
The cation washing the anion in agent and inhaling in color fibre is not easy to offset each other and influence the decontamination function of anti-colour contamination detergent
Color function can and be inhaled, anti-colour contamination detergent is conducive to while having both better dirt-removing functions and inhaling color function；In addition, passing through
Drying solid detergent makes solid detergent and suction color fibre be integrated to form anti-colour contamination detergent, so that anti-colour contamination is washed
It washs agent to be not easy to be conducive to enhance the stability of anti-colour contamination detergent there are moisture, so that anti-colour contamination detergent is more light and handy, side
Portable belt easily facilitates transport, in addition, also helping the batch production of anti-colour contamination detergent, is conducive to improve production efficiency.
The present invention is further arranged to: in the step S1, the temperature control of heating for dissolving is 85 DEG C -95 DEG C, is heated molten
The time control of solution is 90-100min.
By adopting the above technical scheme, the temperature and time dissolved by heating by control, it is preferably molten to be conducive to polyvinyl alcohol
Solution, be preferably uniformly mixed with other compositions to be conducive to polyvinyl alcohol, and then be conducive to polyvinyl alcohol preferably with other
Components matching, so that the bonding force of solid detergent and suction color fibre is conducive to enhance the decontamination of solid detergent while stronger
Ability, so that prepare resulting anti-colour contamination detergent while having both better dirt-removing functions and inhaling color function.
The present invention is further arranged to: in the step S5, the temperature control of drying is 80 DEG C -110 DEG C.
By adopting the above technical scheme, it is 80 DEG C -110 DEG C by the temperature of control drying, is conducive to filling for solid detergent
Divide drying, is not easy to be conducive to enhance anti-colour contamination detergent there are moisture so that preparing resulting anti-colour contamination detergent
Stability easily facilitates transport so that anti-colour contamination detergent is more light and handy, is convenient for carrying.
In conclusion the invention has the following advantages:
1. due to solid detergent and inhale color fibre be in solid-like so that the anion in solid detergent be not easy with
The cation inhaled in color fibre offsets each other, and is conducive to anti-colour contamination detergent while having both good dirt-removing functions and inhaling color function
Energy；
2. being conducive to enhance solid detergent and inhaling the bonding force of color fibre, so that solid is washed by the way that polyvinyl alcohol is added
It washs bonding stronger between agent and suction color fibre；
3. passing through the cooperation of polyvinyl alcohol, sldium lauryl sulfate and fatty acid methyl ester ethoxy compound, be conducive to enhance
Solid detergent and inhale color fibre between bonding force while be conducive to enhance solid detergent dirt-removing power so that anti-string
Color detergent has both better dirt-removing power simultaneously and inhales color ability；
4. passing through the mass parts ratio of control polyvinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethoxy compound
For 1:1-1.5:0.1-0.2, be conducive to the stickiness for enhancing solid detergent, be conducive to the dirt-removing power for enhancing solid detergent,
And then is conducive to anti-colour contamination detergent while having both better dirt-removing power and inhaling color ability.
Specific embodiment
With reference to embodiments, invention is further described in detail.
In following embodiment, inhale color fibre be all made of notification number be CN103938298B Chinese patent " inhale color fibre and
Suction color fibre in the preparation method of suction color non-woven cloth ".
In following embodiment, sldium lauryl sulfate uses Shandong Dongming all into the article No. of Chemical Co., Ltd. for 325467
Sulfonate of laurate sodium sulphate.
In following embodiment, laureth sodium sulfovinate use the article No. of Hunan Li Chenao prestige Industrial Co., Ltd. for
The laureth sodium sulfovinate of ESB-70/ZA.
In following embodiment, Cocoamidopropyl betaine uses the model of Zhengzhou Yu Xiang chemical products Co., Ltd
The Cocoamidopropyl betaine of CAB-35.
In following embodiment, lauric acid amide of ethanol uses the coconut palm of the model 6501 of Jiangsu Hai'an Petrochemical Plant
Oleic acid diethyl amide.
In following embodiment, fatty alcohol polyoxyethylene ether uses the article No. of Guangzhou Nan Jia Chemical Co., Ltd. to raise for 88
Sub- BASF AEO-9.
In following embodiment, fatty acid methyl ester ethoxy compound creates the fatty acid of Yue Chemical Co., Ltd. using the city Guang Zhou
Methyl esters ethoxy compound.
In following embodiment, maleic acid-acrylic acid copolymer uses the model of Xinxiang City's multiple star dragon water process Co., Ltd
For the maleic acid-acrylic acid copolymer of JXL-103.
In following embodiment, the article No. of the peace food additives Co., Ltd that sodium citrate uses Zhengzhou good is 20188763
Sodium citrate.
In following embodiment, citric acid uses the citric acid of Henan Te meter Te Biotechnology Co., Ltd.
In following embodiment, glycerol uses the food grade glycerol of vast and boundless million Chemical Co., Ltd.s in Guangzhou.
In following embodiment, soapberry extract uses the article No. of Xi'an Feng standing grain Biotechnology Co., Ltd for FH-247's
Soapberry extract.
In following embodiment, 4A zeolite use the article No. of Wuhan Xin Hong Chemical Co., Ltd. for 1 4A zeolite powder.
In following embodiment, essence use the article No. of Nice flavors and fragrances Co., Ltd, Guangzhou Oman for 2587 plant
Essence.
Embodiment 1
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 28kg；Sldium lauryl sulfate 14kg；Laureth sodium sulfovinate 15kg；Cocamidopropyl propyl amide beet
Alkali 5kg；Lauric acid amide of ethanol 10kg；Fatty alcohol polyoxyethylene ether 5.5kg；Fatty acid methyl ester ethoxy compound 1.4kg；
Maleic acid-acrylic acid copolymer 6kg；Sodium citrate 5kg；Citric acid 2kg；Glycerol 5kg；Soapberry extract 3kg；Deionized water
5.1kg。
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 28kg being added into emulsion pot, the temperature for controlling emulsion pot is 85 DEG C, 100min is kept the temperature, so that
Polyvinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 14kg, fatty methyl esters ethoxy compound 1.4kg, stirring are sequentially added into emulsion pot
It is uniformly mixed, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 15kg, Cocoamidopropyl betaine 5kg, coconut palm
Oleic acid diethyl amide 10kg, fatty alcohol polyoxyethylene ether 5.5kg, maleic acid-acrylic acid copolymer 6kg, sodium citrate 5kg,
Citric acid 2kg, glycerol 5kg, soapberry extract 3kg, deionized water 5.1kg, are uniformly mixed, and form detergent；
S4, detergent is tentatively dried at a temperature of 80 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 110 DEG C, continues drying solid and washes
Agent is washed to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 2
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 21kg；Sldium lauryl sulfate 35.7kg；Laureth sodium sulfovinate 9kg；Cocamidopropyl propyl amide sweet tea
Dish alkali 4kg；Lauric acid amide of ethanol 6kg；Fatty alcohol polyoxyethylene ether 6kg；Fatty acid methyl ester ethoxy compound 5.25kg；
Maleic acid-acrylic acid copolymer 4kg；Sodium citrate 4kg；Citric acid 1.5kg；Glycerol 4kg；Soapberry extract 2.5kg；Go from
Sub- water 2.05kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 21kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, 90min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 35.7kg, fatty methyl esters ethoxy compound 5.25kg are sequentially added into emulsion pot, stir
Mix uniformly mixed, formation mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 9kg, Cocoamidopropyl betaine 4kg, cocounut oil
Sour diglycollic amide 6kg, fatty alcohol polyoxyethylene ether 6kg, maleic acid-acrylic acid copolymer 4kg, sodium citrate 4kg, citric acid
1.5kg, glycerol 4kg, soapberry extract 2.5kg, deionized water 2.05kg, are uniformly mixed, and form detergent；
S4, detergent is tentatively dried at a temperature of 110 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 80 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 3
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 10kg；Sldium lauryl sulfate 5kg；Laureth sodium sulfovinate 15kg；Cocamidopropyl propyl amide beet
Alkali 1kg；Lauric acid amide of ethanol 3kg；Fatty alcohol polyoxyethylene ether 5kg；Fatty acid methyl ester ethoxy compound 0.5kg；Horse
Carry out sour-acrylic copolymer 3kg；Sodium citrate 2kg；Citric acid 0.5kg；Glycerol 1.5kg；Soapberry extract 0.5kg；Go from
Sub- water 58kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-24 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-24 is 86%-89%, molecular weight 118000-124000, average degree of polymerization 2400-2500.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 10kg is added into emulsion pot, the temperature for controlling emulsion pot is 90 DEG C, 95min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 5kg, fatty methyl esters ethoxy compound 0.5kg are sequentially added into emulsion pot, stirring is mixed
It closes uniformly, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 15kg, Cocoamidopropyl betaine 1kg, coconut palm
Oleic acid diethyl amide 3kg, fatty alcohol polyoxyethylene ether 5kg, maleic acid-acrylic acid copolymer 3kg, sodium citrate 2kg, lemon
Sour 0.5kg, glycerol 1.5kg, soapberry extract 0.5kg, deionized water 58kg, are uniformly mixed, and form detergent；
S4, detergent is tentatively dried at a temperature of 80 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 110 DEG C, continues drying solid and washes
Agent is washed to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 4
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 15kg；Sldium lauryl sulfate 7.5kg；Laureth sodium sulfovinate 10kg；Cocamidopropyl propyl amide sweet tea
Dish alkali 2.5kg；Lauric acid amide of ethanol 2kg；Fatty alcohol polyoxyethylene ether 2kg；Fatty acid methyl ester ethoxy compound
0.75kg；Maleic acid-acrylic acid copolymer 0.1kg；Sodium citrate 3kg；Citric acid 0.1kg；Glycerol 2.5kg；Soapberry extracts
Object 1.8kg；Deionized water 57.75kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 15kg being added into emulsion pot, the temperature for controlling emulsion pot is 85 DEG C, 100min is kept the temperature, so that
Polyvinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 7.5kg, fatty methyl esters ethoxy compound 0.75kg are sequentially added into emulsion pot, stir
Mix uniformly mixed, formation mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 10kg, Cocoamidopropyl betaine 2.5kg,
Lauric acid amide of ethanol 2kg, fatty alcohol polyoxyethylene ether 2kg, maleic acid-acrylic acid copolymer 0.1kg, sodium citrate 3kg,
Citric acid 0.1kg, glycerol 2.5kg, soapberry extract 1.8kg, deionized water 57.75kg, are uniformly mixed, and form washing
Agent；
S4, detergent is tentatively dried at a temperature of 95 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 90 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 5
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 20kg；Sldium lauryl sulfate 10kg；Laureth sodium sulfovinate 2kg；Cocamidopropyl propyl amide beet
Alkali 2kg；Lauric acid amide of ethanol 4kg；Fatty alcohol polyoxyethylene ether 3kg；Fatty acid methyl ester ethoxy compound 1kg；Malaysia
Acid-acrylic copolymer 0.5kg；Sodium citrate 0.5kg；Citric acid 1kg；Glycerol 2kg；Soapberry extract 1kg；Deionized water
58kg。
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 20kg is added into emulsion pot, the temperature for controlling emulsion pot is 88 DEG C, 98min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 10kg, fatty methyl esters ethoxy compound 1kg are sequentially added into emulsion pot, stirring is mixed
It closes uniformly, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 2kg, Cocoamidopropyl betaine 2kg, cocounut oil
Sour diglycollic amide 4kg, fatty alcohol polyoxyethylene ether 3kg, maleic acid-acrylic acid copolymer 0.5kg, sodium citrate 0.5kg, lemon
Lemon acid 1kg, glycerol 2kg, soapberry extract 1kg, deionized water 58kg, are uniformly mixed, and form detergent；
S4, detergent is tentatively dried at a temperature of 110 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 80 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 6
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 5kg；Sldium lauryl sulfate 5kg；Laureth sodium sulfovinate 18kg；Cocoamidopropyl betaine
3kg；Lauric acid amide of ethanol 5kg；Fatty alcohol polyoxyethylene ether 0.5kg；Fatty acid methyl ester ethoxy compound 2.5kg；Horse
Carry out sour-acrylic copolymer 2kg；Sodium citrate 1kg；Citric acid 0.8kg；Glycerol 3kg；Soapberry extract 1.5kg；Deionization
Water 57.7kg.
In the present embodiment, it is 2699 that polyvinyl alcohol, which is the article No. purchased from Inner Mongol Kai Du new material Science and Technology Ltd.,
Polyvinyl alcohol, the alcoholysis degree of polyvinyl alcohol 2699 are 98%-100%, molecular weight 107800-129800, and average degree of polymerization is
2450-2650。
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 5kg is added into emulsion pot, the temperature for controlling emulsion pot is 93 DEG C, 92min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 5kg, fatty methyl esters ethoxy compound 2.5kg are sequentially added into emulsion pot, stirring is mixed
It closes uniformly, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 18kg, Cocoamidopropyl betaine 3kg, coconut palm
Oleic acid diethyl amide 5kg, fatty alcohol polyoxyethylene ether 0.5kg, maleic acid-acrylic acid copolymer 2kg, sodium citrate 1kg, lemon
Lemon acid 0.8kg, glycerol 3kg, soapberry extract 1.5kg, deionized water 57.7kg, are uniformly mixed, and form detergent；
S4, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 7
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 12kg；Sldium lauryl sulfate 18kg；Laureth sodium sulfovinate 5kg；Cocamidopropyl propyl amide beet
Alkali 1.5kg；Lauric acid amide of ethanol 1kg；Fatty alcohol polyoxyethylene ether 1kg；Fatty acid methyl ester ethoxy compound 2.4kg；
Maleic acid-acrylic acid copolymer 1kg；Sodium citrate 1.5kg；Citric acid 0.3kg；Glycerol 1kg；Soapberry extract 2kg；Go from
Sub- water 58.3kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 12kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, 90min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 18kg, fatty methyl esters ethoxy compound 2.4kg, stirring are sequentially added into emulsion pot
It is uniformly mixed, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, deionized water 58.3kg, are uniformly mixed, and form detergent；
S4, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 8
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 12kg；Sldium lauryl sulfate 18kg；Laureth sodium sulfovinate 5kg；Cocamidopropyl propyl amide beet
Alkali 1.5kg；Lauric acid amide of ethanol 1kg；Fatty alcohol polyoxyethylene ether 1kg；Fatty acid methyl ester ethoxy compound 2.4kg；
Maleic acid-acrylic acid copolymer 1kg；Sodium citrate 1.5kg；Citric acid 0.3kg；Glycerol 1kg；Soapberry extract 2kg；4A boiling
Stone 1kg；Essence 1kg；Deionized water 56.3kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 12kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, 90min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 18kg, fatty methyl esters ethoxy compound 2.4kg, stirring are sequentially added into emulsion pot
It is uniformly mixed, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, 4A zeolite 1kg, essence 1kg, deionized water 56.3kg are stirred
It is even, form detergent；
S4, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 9
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 12kg；Sldium lauryl sulfate 18kg；Laureth sodium sulfovinate 5kg；Cocamidopropyl propyl amide beet
Alkali 1.5kg；Lauric acid amide of ethanol 1kg；Fatty alcohol polyoxyethylene ether 1kg；Fatty acid methyl ester ethoxy compound 2.4kg；
Maleic acid-acrylic acid copolymer 1kg；Sodium citrate 1.5kg；Citric acid 0.3kg；Glycerol 1kg；Soapberry extract 2kg；4A boiling
Stone 2.5kg；Essence 0.1kg；Deionized water 55.7kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-17 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-17 is 86%-89%, molecular weight 84000-89000, average degree of polymerization 1700-1800.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 12kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, 90min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 18kg, fatty methyl esters ethoxy compound 2.4kg, stirring are sequentially added into emulsion pot
It is uniformly mixed, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, 4A zeolite 2.5kg, essence 0.1kg, deionized water 55.7kg, stirring are mixed
It closes uniformly, forms detergent；
S4, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Embodiment 10
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 12kg；Sldium lauryl sulfate 18kg；Laureth sodium sulfovinate 5kg；Cocamidopropyl propyl amide beet
Alkali 1.5kg；Lauric acid amide of ethanol 1kg；Fatty alcohol polyoxyethylene ether 1kg；Fatty acid methyl ester ethoxy compound 2.4kg；
Maleic acid-acrylic acid copolymer 1kg；Sodium citrate 1.5kg；Citric acid 0.3kg；Glycerol 1kg；Soapberry extract 2kg；4A boiling
Stone 5kg；Essence 0.5kg；Deionized water 52.8kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 12kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, 90min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, sldium lauryl sulfate 18kg, fatty methyl esters ethoxy compound 2.4kg, stirring are sequentially added into emulsion pot
It is uniformly mixed, forms mixture；
S3, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, 4A zeolite 5kg, essence 0.5kg, deionized water 52.8kg, are stirred
Uniformly, detergent is formed；
S4, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Comparative example 1
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Polyvinyl alcohol 12kg；Laureth sodium sulfovinate 5kg；Cocoamidopropyl betaine 1.5kg；Coconut oil diethyl
Alkylolamides 1kg；Fatty alcohol polyoxyethylene ether 1kg；Maleic acid-acrylic acid copolymer 1kg；Sodium citrate 1.5kg；Citric acid
0.3kg；Glycerol 1kg；Soapberry extract 2kg；Deionized water 78.7kg.
In the present embodiment, polyvinyl alcohol is the polyvinyl alcohol BP-05 purchased from Guangzhou Shuan Pu trade Co., Ltd, polyethylene
The alcoholysis degree of alcohol BP-05 is 86%-89%, molecular weight 27000-32000, average degree of polymerization 550-650.
Anti- colour contamination detergent the preparation method is as follows:
S1, polyvinyl alcohol 12kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, 90min is kept the temperature, so that poly-
Vinyl alcohol is completely dissolved；
S2, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, deionized water 78.7kg, are uniformly mixed, and form detergent；
S3, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S4, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Comparative example 2
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Sldium lauryl sulfate 18kg；Laureth sodium sulfovinate 5kg；Cocoamidopropyl betaine 1.5kg；Coconut oil
Diglycollic amide 1kg；Fatty alcohol polyoxyethylene ether 1kg；Maleic acid-acrylic acid copolymer 1kg；Sodium citrate 1.5kg；Citric acid
0.3kg；Glycerol 1kg；Soapberry extract 2kg；Deionized water 72.7kg.
Anti- colour contamination detergent the preparation method is as follows:
S1, sldium lauryl sulfate 18kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, keeps the temperature 90min, makes
Sldium lauryl sulfate is obtained to be completely dissolved；
S2, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, deionized water 72.7kg, are uniformly mixed, and form detergent；
S3, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S4, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Comparative example 3
A kind of anti-colour contamination detergent, including the solid detergent inhaling color fibre and sticking with suction color fibre；
Solid detergent includes the component of following mass fraction:
Laureth sodium sulfovinate 5kg；Cocoamidopropyl betaine 1.5kg；Lauric acid amide of ethanol 1kg；Rouge
Fat alcohol polyoxyethylene ether 1kg；Fatty acid methyl ester ethoxy compound 2.4kg；Maleic acid-acrylic acid copolymer 1kg；Sodium citrate
1.5kg；Citric acid 0.3kg；Glycerol 1kg；Soapberry extract 2kg；Deionized water 88.3kg.
Anti- colour contamination detergent the preparation method is as follows:
S1, fatty methyl esters ethoxy compound 2.4kg is added into emulsion pot, the temperature for controlling emulsion pot is 95 DEG C, is protected
Warm 90min, so that fatty methyl esters ethoxy compound is completely dissolved；
S2, toward emulsion pot successively in be added laureth sodium sulfovinate 5kg, Cocoamidopropyl betaine 1.5kg, coconut palm
Oleic acid diethyl amide 1kg, fatty alcohol polyoxyethylene ether 1kg, maleic acid-acrylic acid copolymer 1kg, sodium citrate 1.5kg, lemon
Lemon acid 0.3kg, glycerol 1kg, soapberry extract 2kg, deionized water 88.3kg, are uniformly mixed, and form detergent；
S3, detergent is tentatively dried at a temperature of 90 DEG C, so that detergent preliminarily forms solid；
S4, suction color fibre is attached to solid detergent surface, the temperature for controlling drying is 95 DEG C, continues to dry solid washing
Agent is to being completely dried, so that solid detergent and suction color fibre form one to get anti-colour contamination detergent.
Experiment 1
According in GB/T2792-2014 " test method of adhesive tape peel strength " method 1 detect above embodiments with
And comparative example prepares the solid detergent in resulting anti-colour contamination detergent and inhales the peel strength (N/cm) between color fibre.
Experiment 2
According to the annex in GB/T13174-2008 " dress material detergent detergency and the measurement for recycling scourability "
It is dirty that soiled cotton preparation method prepares several block-shaped carbon black greasy dirt cloth JB-01 of the same size, albumen soiled cotton JB-02, sebum respectively
Cloth JB-03, edible oil soiled cotton JB-04 and starch soiled cotton JB-05, and according to GB/T13174-2008 " dress material detergent
Detergency and the measurement for recycling scourability " it individually detects the decontamination value of solid detergent and detects above embodiments and ratio
Compared with the decontamination value that example prepares resulting anti-colour contamination detergent.
Experiment 3
10mL black ink is poured into 50mL clear water formation tusche aqueous solution, will inhale respectively color fibre and above embodiments with
And comparative example prepares resulting anti-colour contamination detergent and is added in tusche aqueous solution, stirs 5min, detection tusche aqueous solution exists respectively
It is individually added into inhale color fibre and be added before anti-colour contamination detergent and be individually added into and inhales color fibre and the anti-colour contamination detergent of addition
OD value afterwards, and calculate tusche aqueous solution and the change rate for inhaling the OD value before and after color fibre and anti-colour contamination detergent is added
(%) judges the suction color ability of anti-colour contamination detergent.
The detection data tested above is shown in Table 1.
Table 1
It can be obtained according to the data comparison of embodiment 1-10 in table 1 and detergent and suction color fibre, embodiment 1-10's is each
Type decontamination value is above detergent, and the OD value change rate of embodiment 1-10 is all larger than and inhales color fibre, that is, implements
The suction color ability of the anti-colour contamination detergent of example 1-10, which is above, inhales color fibre, illustrates by using solid detergent and inhales color fibre
The mode combined is tieed up to form anti-colour contamination detergent, so that anion in solid detergent and inhaling cation in color fibre not
Free ionic forms easy to form, so that the anion in solid detergent is not easy with the cation inhaled in color fibre
It interacts, so that the dirt-removing functions of anti-colour contamination detergent and suction color function are not readily susceptible to influence；Meanwhile passing through
It uses component and proportion of the invention to form solid detergent, is conducive to the stability for improving anti-colour contamination detergent, thus
Be conducive to anti-colour contamination detergent while having both better dirt-removing power and inhaling color ability, so that solid detergent and suction color fibre
It is stronger in conjunction with the rear dirt-removing power than solid detergent is used alone, while solid detergent is compared after inhaling in conjunction with color fibre
The suction color ability that suction color fibre is used alone is stronger.
It can be obtained according to the data comparison of embodiment 1-3 in table 1, the quality of embodiment 1 and the polyvinyl alcohol in embodiment 2
Number is in the range of 5-28 parts and not in the range of 5-20 parts, and the mass fraction of laureth sodium sulfovinate is in 2-
In the range of 15 parts and not in the range of 2-8 parts, the mass fraction of Cocoamidopropyl betaine is in the range of 1-5 parts
And not in the range of 1-3 parts, the mass fraction of lauric acid amide of ethanol is in the range of 1-10 parts and not at 1-5 parts
In range, the mass fraction of aliphatic acid polyethenoxy ether is in the range of 0.5-6 parts and not in the range of 0.5-5 parts, horse
Carry out the mass fraction of sour-acrylic copolymer in the range of 0.1-6 parts and not in the range of 0.1-3 parts, sodium citrate
Mass fraction at 0.5-5 parts and not in the range of 0.5-3 parts, the mass fraction of citric acid is in 0.1-2 parts of range
Interior and not in the range of 0.1-1 parts, the mass fraction of glycerol is in the range of 1-5 parts and not in the range of 1-3 parts, nothing
Suffer from the mass fraction of seed extract in the range of 0.5-3 parts and not in the range of 0.5-2 parts, the polyethylene of embodiment 3
The mass fraction of alcohol in the range of 5-20 parts, the mass fraction of laureth sodium sulfovinate in the range of 2-8 parts,
In the range of 1-3 parts, the mass fraction of lauric acid amide of ethanol exists the mass fraction of Cocoamidopropyl betaine
In the range of 1-5 parts, in the range of 0.5-5 parts, maleic-acrylic acid is copolymerized the mass fraction of aliphatic acid polyethenoxy ether
The mass fraction of object is in the range of 0.1-3 parts, and the mass fraction of sodium citrate is in the range of 0.5-3 parts, citric acid
Mass fraction in the range of 0.1-1 parts, the mass fraction of glycerol in the range of 1-3 parts, soapberry extract
Mass fraction in the range of 0.5-2 parts, and the solid detergent of the anti-colour contamination detergent in embodiment 3 and inhale color fibre it
Between peel strength, decontamination value and optical density change rate be above embodiment 1-2, the i.e. anti-colour contamination detergent of embodiment 3
Suction color ability be better than embodiment 1-2, illustrate to be conducive to each group by each component and ratio that control anti-colour contamination detergent
Divide and preferably cooperate, to be conducive to anti-colour contamination detergent while have both preferably inhale color ability and dirt-removing power.
It can be obtained according to the data comparison of embodiment 3-5 in table 1, if other conditions are the same, what embodiment 3 used
In the range of 86%-89%, outside the range of 20000-90000, average degree of polymerization exists molecular weight the alcoholysis degree of polyvinyl alcohol
Outside the range of 550-1800, in the range of 86%-89%, molecular weight exists the alcoholysis degree for the polyvinyl alcohol that embodiment 4 uses
In the range of 20000-90000 and not in the range of 25000-40000, average degree of polymerization is in the range of 550-1800 and not
In the range of 550-1000, in the range of 86%-89%, molecular weight exists the alcoholysis degree for the polyvinyl alcohol that embodiment 5 uses
In the range of 20000-40000, average degree of polymerization is in the range of 550-1000, and anti-colour contamination detergent in embodiment 5
Solid detergent and the peel strength inhaled between color fibre are higher than embodiment 4 higher than embodiment 3, and the decontamination value of embodiment 5 is equal
It is higher than embodiment 3 higher than embodiment 4, what the change rate of the OD value of embodiment 5 was above embodiment 4 is higher than embodiment
3, i.e., embodiment 5 inhale that color ability is higher than embodiment 4 be higher than embodiment 3, illustrate the alcoholysis by controlling polyvinyl alcohol
Degree, molecular weight and average degree of polymerization are conducive to the viscosity for improving solid detergent, so that solid detergent and suction color are fine
Bonding between dimension is stronger, and then is conducive to improve the stability of anti-colour contamination detergent, and it is same to be conducive to anti-colour contamination detergent
When have both better dirt-removing power and inhale color ability.
It can be obtained according to the data comparison of embodiment 5-7 in table 1, it is if other conditions are the same, poly- in embodiment 5
The mass parts ratio of vinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethoxy compound is 1:0.5:0.05, embodiment 6
In polyvinyl alcohol and the mass parts ratio of sldium lauryl sulfate and fatty acid methyl ester ethoxy compound be 1:1:0.5, implement
The mass parts ratio of polyvinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethoxy compound in example 7 is 1:1.5:0.2,
Peel strength between solid detergent in the anti-colour contamination detergent of embodiment 7 and suction color fibre is higher than being higher than for embodiment 6
Embodiment 5, the decontamination value of embodiment 7 is higher than embodiment 6 and is higher than embodiment 5, and the OD value change rate of embodiment 7 is higher than
Embodiment 6 is higher than embodiment 5, illustrates through control polyvinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethyoxyl chemical combination
The mass parts ratio of object is 1:1-1.5:0.1-0.2, is conducive to polyvinyl alcohol and sldium lauryl sulfate and fatty acid methyl ester ethoxy
Preferably cooperate between based compound, to be conducive to enhance solid detergent and have while inhaling the bonding force between color fibre
Conducive to enhancing solid detergent dirt-removing power, and then be conducive to anti-colour contamination detergent at the same have both better dirt-removing power and
Inhale color ability.
It can be obtained according to the data comparison of embodiment 7-10 in table 1, embodiment 8-10 has increased component 4A zeolite newly than embodiment 7
And essence, and the decontamination value of embodiment 8-10 is higher than embodiment 7, illustrates to be conducive to enhance solid by the way that 4A zeolite is added
The dirt-removing power of detergent, to be conducive to improve the dirt-removing power of anti-colour contamination detergent.
According to the data comparison of embodiment 7 and comparative example 1-3 in table 1, if other conditions are the same, embodiment 7
In component joined polyvinyl alcohol, sldium lauryl sulfate and fatty acid methyl ester ethoxy compound simultaneously, it is single in comparative example 1
It solely joined polyvinyl alcohol, sldium lauryl sulfate be individually added into comparative example 2, has been individually added into fatty acid methyl in embodiment 3
Ester ethoxy compound, and the solid detergent of the anti-colour contamination detergent in comparative example 1-3 is remote with the peel strength of color fibre is inhaled
Lower than embodiment 7, the decontamination value of comparative example 1-3 is also far below embodiment 7, illustrates by the way that polyvinyl alcohol, laruyl alcohol is added
Sodium sulphate and fatty methyl esters ethoxy compound are worked in coordination with a synergistic effect, are conducive to enhance solid detergent and are inhaled color fibre
The dirt-removing power for being conducive to enhance solid detergent while bonding fastness between dimension, to be conducive to anti-colour contamination detergent
Better dirt-removing power is had both simultaneously and inhales color ability.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this
Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it
It is interior.
Claims (10)
1. a kind of anti-colour contamination detergent, it is characterized in that: including the solid detergent inhaling color fibre and sticking with suction color fibre；
The solid detergent includes the component of following mass fraction:
5-28 parts of polyvinyl alcohol；
5-36 parts of sldium lauryl sulfate；
2-15 parts of laureth sodium sulfovinate；
1-5 parts of Cocoamidopropyl betaine；
1-10 parts of lauric acid amide of ethanol；
0.5-6 parts of fatty alcohol polyoxyethylene ether；
0.5-6 parts of fatty acid methyl ester ethoxy compound；
0.1-6 parts of maleic acid-acrylic acid copolymer；
0.5-5 parts of sodium citrate；
0.1-2 parts of citric acid；
1-5 parts of glycerol；
0.5-3 parts of soapberry extract；
The gross mass number of the solid detergent is 105 parts, remaining group is divided into deionized water.
2. anti-colour contamination detergent according to claim 1, it is characterized in that: the solid detergent includes following mass fraction
Component:
5-20 parts of polyvinyl alcohol；
5-18 parts of sldium lauryl sulfate；
2-8 parts of laureth sodium sulfovinate；
1-3 parts of Cocoamidopropyl betaine；
1-5 parts of lauric acid amide of ethanol；
0.5-5 parts of fatty alcohol polyoxyethylene ether；
0.5-2.5 parts of fatty acid methyl ester ethoxy compound；
0.1-3 parts of maleic acid-acrylic acid copolymer；
0.5-3 parts of sodium citrate；
0.1-1 parts of citric acid；
1-3 parts of glycerol；
0.5-2 parts of soapberry extract；
The gross mass number of the solid detergent is 105 parts, remaining group is divided into deionized water.
3. anti-colour contamination detergent according to claim 1 to 2, it is characterized in that: the polyvinyl alcohol and laruyl alcohol sulfuric acid
The mass parts ratio of sodium and fatty acid methyl ester ethoxy compound is 1:1-1.5:0.1-0.2.
4. anti-colour contamination detergent according to claim 1 to 2, it is characterized in that: the solid detergent further includes following
The component of mass fraction:
1-5 parts of 4A zeolite.
5. anti-colour contamination detergent according to claim 1 to 2, it is characterized in that: the solid detergent further includes following
The component of mass fraction:
0.1-1 parts of essence.
6. anti-colour contamination detergent according to claim 1 to 2, it is characterized in that: the alcoholysis degree of the polyvinyl alcohol is
66%-89%, the molecular weight of the polyvinyl alcohol are 20000-90000, and the average degree of polymerization of the polyvinyl alcohol is 550-1800.
7. anti-colour contamination detergent according to claim 6, it is characterized in that: the alcoholysis degree of the polyvinyl alcohol is 86%-89%,
The molecular weight of the polyvinyl alcohol is 25000-40000, and the average degree of polymerization of the polyvinyl alcohol is 550-1000.
8. a kind of preparation method of anti-colour contamination detergent as claimed in claim 1, it is characterized in that: including following step
It is rapid:
S1, polyvinyl alcohol is dissolved by heating；
S2, sldium lauryl sulfate and fatty methyl esters ethoxy compound are added into polyvinyl alcohol, are uniformly mixed, are formed
Mixture；
S3, the remaining ingredient that solid detergent is added into mixture, are uniformly mixed, form detergent；
S4, detergent is tentatively dried at a temperature of 80 DEG C -110 DEG C, so that detergent preliminarily forms solid；
S5, suction color fibre is attached to solid detergent surface, continues to dry solid detergent to being completely dried, so that solid washs
Agent and suction color fibre form one to get anti-colour contamination detergent.
9. the preparation method of anti-colour contamination detergent according to claim 8, it is characterized in that: being heated molten in the step S1
The temperature control of solution is 85 DEG C -95 DEG C, and the time control of heating for dissolving is 90-100min.
10. the preparation method of 8 anti-colour contamination detergent according to claim, it is characterized in that: in the step S5, drying
Temperature control is 80 DEG C -110 DEG C.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117801A (en) * | 2019-12-30 | 2020-05-08 | 广州大白生物科技有限公司 | Anti-cross-color laundry detergent and preparation method thereof |
| CN113493724A (en) * | 2021-06-22 | 2021-10-12 | 广东菁萃生物科技有限公司 | Efficient decontamination laundry detergent and preparation method thereof |
| CN114395448A (en) * | 2021-12-31 | 2022-04-26 | 上海范耐斯日用品有限公司 | Double-layer combined color-protecting washing sheet and preparation method thereof |
| CN115558558A (en) * | 2022-10-29 | 2023-01-03 | 兰溪市屹达化工试剂有限公司 | Preparation method of detergent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108441346A (en) * | 2018-04-27 | 2018-08-24 | 李茜 | A kind of laundry sheet and preparation method thereof |
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2019
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108441346A (en) * | 2018-04-27 | 2018-08-24 | 李茜 | A kind of laundry sheet and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117801A (en) * | 2019-12-30 | 2020-05-08 | 广州大白生物科技有限公司 | Anti-cross-color laundry detergent and preparation method thereof |
| CN111117801B (en) * | 2019-12-30 | 2021-11-02 | 广州大白生物科技有限公司 | Anti-cross-color laundry detergent and preparation method thereof |
| CN113493724A (en) * | 2021-06-22 | 2021-10-12 | 广东菁萃生物科技有限公司 | Efficient decontamination laundry detergent and preparation method thereof |
| CN113493724B (en) * | 2021-06-22 | 2023-05-09 | 广东菁萃生物科技有限公司 | Efficient decontamination laundry detergent and preparation method thereof |
| CN114395448A (en) * | 2021-12-31 | 2022-04-26 | 上海范耐斯日用品有限公司 | Double-layer combined color-protecting washing sheet and preparation method thereof |
| CN114395448B (en) * | 2021-12-31 | 2023-11-24 | 上海范耐斯日用品有限公司 | Double-layer combined color-protecting washing sheet and preparation method thereof |
| CN115558558A (en) * | 2022-10-29 | 2023-01-03 | 兰溪市屹达化工试剂有限公司 | Preparation method of detergent |
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| CN110106037B (en) | 2020-10-16 |
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