CN103242975B

CN103242975B - Peppermint cool detergent

Info

Publication number: CN103242975B
Application number: CN201310205036.9A
Authority: CN
Inventors: 陈龙弟
Original assignee: Shanghai Yanzi Chemical Technology Co Ltd
Current assignee: Handan Handan Handan Huayi Tableware Cleaning Service Co., Ltd.
Priority date: 2013-05-28
Filing date: 2013-05-28
Publication date: 2014-08-06
Anticipated expiration: 2033-05-28
Also published as: CN103242975A

Abstract

The invention discloses a peppermint cool detergent. The peppermint cool detergent comprises the following raw materials in parts by weight: 4-6 parts of sodium capryloamphoacetate, 4-6 parts of cocamidopropyl betaine, 2-4 parts of cocamidopropyl amine oxide, 5-7 parts of lauryl glucoside, 0.05-0.15 part of menthol and 80 parts of water. The peppermint cool detergent ensures good decontamination and washing effects and greatly reduces the irritation to the surfaces of hands by compounding a non-ionic surfactant and an amphoteric surfactant and abandoning a traditional anionic surfactant; and simultaneously, the menthol is compounded, so that the hand skin can be effectively cooled and moisturized when the peppermint cool detergent disclosed by the invention is used for cleaning tableware.

Description

The refrigerant liquid detergent of peppermint

Technical field:

The present invention relates to a kind of liquid detergent, particularly the refrigerant liquid detergent of a kind of peppermint.

Background technology:

Liquid washing agent is a large class in synthetic detergent, and in synthetic detergent, output maximum is washing powder, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities compared with solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.

Liquid washing agent is the articles for washing using water or other organic solvents as base-material, and it has the characteristic of surfactant soln.Generally the liquid product with cleaning function is called to liquid washing agent.Be divided into liquid detergent, fabric liquid detergent, shampoo and skin cleaner and hard surface cleaner according to purposes or function.

Liquid detergent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be for washing water fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.

Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent is on the market a feast for the eyes, have detersive power superpower, have concentrated type and strong sterilizing power etc.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be taking environment-friendly and green type as main flow.Except having the function of strong detersive power, harmless, sterilization and disinfection, gentle high bubble, also should easily degrade, free from environmental pollution.The effective constituent of dish washing detergent is mainly tensio-active agent, and traditional dish washing detergent is mainly taking synthetic surfactant (as LAS, AS, AES, SAS etc.) as raw material.But being difficult for degraded mostly, they maybe cannot degrade, to environment.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially, in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, particularly functional liquid detergent is just fewer.

Summary of the invention:

For prior art above shortcomings, technical problem to be solved by this invention is to provide the refrigerant liquid detergent of a kind of peppermint.

Technical problem of the present invention, is achieved by following technical proposals:

The refrigerant liquid detergent of a kind of peppermint, is made up of the raw material of following weight part: decoyl both sexes guanidine-acetic acid sodium 4-6 part, AMONYL 380LC 4-6 part, cocamidopropyl propyl amide amine oxide 2-4 part, Dodecyl Polyglucosides 5-7 part, menthol 0.05-0.15 part, 80 parts, water.

Decoyl both sexes guanidine-acetic acid sodium, AMONYL 380LC, cocamidopropyl propyl amide amine oxide, Dodecyl Polyglucosides and menthol are added to the water, are heated to 40-60 DEG C, mix, can make the refrigerant liquid detergent of this peppermint.

Raw material involved in the present invention is made to simple introduction below:

Decoyl both sexes guanidine-acetic acid sodium, SODIUM CAPRYLOAMPHOACETATE, No. CAS: 68647-46-1.

AMONYL 380LC, COCAMIDOPROPYL BETAINE, No. CAS: 61789-40-0.

Cocamidopropyl propyl amide amine oxide, English name Cocamidopropylamine oxide, CASNo.68155-09-9.

Dodecyl Polyglucosides, CAS accession number: 110615-47-9.

Menthol, English name: DL-Menthol, CAS accession number: 89-78-1, INCI title: MENTHOL.Menthol of the present invention can pass through commercially available obtaining.

The refrigerant liquid detergent of peppermint of the present invention, adopt nonionogenic tenside and amphoterics composite, abandon traditional anion surfactant, in guaranteeing good decontamination washing effect, greatly reduce the pungency to watch face, composite menthol simultaneously, use the present invention can effectively refrigerant moist hand skin in clean tableware.

Embodiment:

Embodiment further illustrates of the present invention below, instead of limits the scope of the invention.In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.

Embodiment 1

0.1 kilogram of 5 kilograms, decoyl both sexes guanidine-acetic acid sodium, 5 kilograms of AMONYL 380LC, 3 kilograms of cocamidopropyl propyl amide amine oxides, 6 kilograms of Dodecyl Polyglucosides and menthol is added in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this liquid detergent.

Comparative example 1

0.1 kilogram of 13 kilograms, decoyl both sexes guanidine-acetic acid sodium, 6 kilograms of Dodecyl Polyglucosides and menthol is added in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this liquid detergent.

Comparative example 2

0.1 kilogram of 13 kilograms of AMONYL 380LC, 6 kilograms of Dodecyl Polyglucosides and menthol is added in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this liquid detergent.

Comparative example 3

0.1 kilogram of 13 kilograms of cocamidopropyl propyl amide amine oxides, 6 kilograms of Dodecyl Polyglucosides and menthol is added in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this liquid detergent.

Test case 1:

Detergency test:

1) preparation of artificial dirt

Mixing oil formula: taking butter, lard, vegetables oil mass ratio as 0.5:0.5:1 preparation, and add the glyceryl monostearate of its total mass 5%, this is artificial dirt.

Artificial dirt is put on electric furnace and is heated to 180 DEG C, stir and keep this temperature 10min, beaker is moved to magnetic stirrer and stir, naturally cool to temperature required for subsequent use.The temperature of defiling is recommended reference: in the time that room temperature is 20 DEG C, need 80 DEG C of oil temperatures; When room temperature is 25 DEG C, need 45 DEG C of oil temperatures; When room temperature is lower than 17 DEG C or during higher than 27 DEG C, test should not be carried out, and need to carry out at air conditioning room.Should use if desired the Terg-O-Tometer of attached freezing plant.

2) preparation of dirty sheet

Edge on slide glass is drawn to 10mm line, be limited in this below line to show to defile; Edge under slide glass is drawn to 5mm line, to show that the unnecessary greasy dirt of wiping is limited in this below line.

3) newly purchasing slide glass need to boil after 15min in detergent solution, and clear water washing is put in acid wash liquid again and soaked after 1h to not hanging the globule, and clear water rinsing and distilled water flushing are put loft drier for subsequent use after dry.

4) preparation of standard dish washing detergent

Take 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts, urea, adds water to 100 parts, mixes, with hydrochloric acid or sodium hydroxide adjusting pH to 7-8, for subsequent use.

5) defile

Clean slide glass is put and weighed on frame taking four as one group, accurately weigh (accurately to 1mg) for m0 with analytical balance, the slide glass after weighing is sandwiched on film airing stand one by one, more than clip should be clipped in slide glass ascender line, film airing stand is put to ward off in dish and prepare to defile.

In the time that greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, slide glass is immersed (1-2) s, slowly taking-up to 10mm ascender line in greasy dirt by hand-held clip, after the lower speed of greasy dirt is slack-off, hangs back and on original film airing stand, prepare successively dirty sheet.After greasy dirt solidifies, by dirty sheet take off with filter paper or absorbent cotton by under dirty sheet along base in 5mm and the unnecessary greasy dirt in both sides wipe, then speckle with the absorbent cotton wiped clean of sherwood oil with tweezers folder.Under room temperature, hanging after 4h, is m1 weighing on frame with analytical balance accurate weighing.Now on every group of dirty sheet, dirty amount should ensure (0.5 ± 0.05) g.

6) testing sequence

The slide glass of the known amount of defiling is inserted in corresponding wash stand and prepares to wash.

Spotter is switched on power, and wash temperature is set to 30 DEG C, and velocity of rotation is set to 160r/min, and washing time is set to 3min.

Take 5.00g sample to be tested in 2500mL hard water, after shaking up, measure respectively 800mL test solution in three washing becks of Terg-O-Tometer, in the time that test solution temperature rises to 30 DEG C, rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand, after putting into washing beck, last wash stand starts to count soak time, rapidly agitator is installed simultaneously, while soaking 1min, start spotter, start washing, when 3min, machine auto stop, rapidly agitator is taken off, take out wash stand, press from both sides one by one and hang on original film airing stand washing rear dirty sheet, extension dries in the air and dirty sheet is put to corresponding weighing frame after 3h and weighed as m2.

(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)

In formula: m0---slide glass quality before defiling, g; M1---slide glass quality after defiling, g; M2---the quality of dirty sheet after washing, g.

The rate of deoiling test chart

	The rate of deoiling ω, %
		Embodiment 1	45.4
Standard dish washing detergent	38.2
		Comparative example 1	39.0
Comparative example 2	38.2
		Comparative example 3	38.1

The refrigerant liquid detergent of peppermint of the present invention, adopt nonionogenic tenside and amphoterics composite, abandon traditional anion surfactant, and amphoterics decoyl both sexes guanidine-acetic acid sodium, AMONYL 380LC and cocamidopropyl propyl amide amine oxide and nonionogenic tenside Dodecyl Polyglucosides composite (embodiment 1) synergy as can be seen from the above table, compare with nonionogenic tenside Dodecyl Polyglucosides composite (comparative example 1-3) with single amphoterics, detersive power obviously improves.

Test case 2:

Pungency test

Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 DEG C of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.After marking according to the standard of following table for the pungency of wrist-watch skin, average again, mark higher, pungency is less.

Pungency test data table

	Scoring
		Embodiment 1	100
Standard dish washing detergent	50
		Comparative example 1	95
Comparative example 2	90
		Comparative example 3	95

Embodiment 2

For extending the quality guaranteed period of the present invention, contriver has made following research pioneeringly.

In the prepared liquid detergent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, formed by weight by following component: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and tennecetins (CAS:7681-93-8).

; the refrigerant liquid detergent of this peppermint is made up of the raw material of following weight part: 5 kilograms, decoyl both sexes guanidine-acetic acid sodium; 5 kilograms of AMONYL 380LC; 3 kilograms of cocamidopropyl propyl amide amine oxides; 6 kilograms of Dodecyl Polyglucosides; 0.1 kilogram of menthol, 80 kilograms, water, 0.05 kilogram of composite environmental-friendly sanitas.

By adding the sanitas of specific proportioning on the basis at embodiment 1, greatly extend the quality guaranteed period of the refrigerant liquid detergent of this peppermint.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, contrast, by the general single sanitas 1 of the industry for the composite environmental-friendly sanitas in embodiment 2,3-dihydroxymethyl-5,5-T10 is replaced, and add-on is constant, and its quality guaranteed period is only December.

Claims

1. the refrigerant liquid detergent of peppermint, is characterized in that, is made up of the raw material of following weight part: decoyl both sexes guanidine-acetic acid sodium 4-6 part, AMONYL 380LC 4-6 part, cocamidopropyl propyl amide amine oxide 2-4 part, Dodecyl Polyglucosides 5-7 part, menthol 0.05-0.15 part, 80 parts, water.