Background technology:
Liquid washing agent is a large class in synthetic detergent, and in synthetic detergent, output maximum is washing powder, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities compared with solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is to using water or other organic solvents as the articles for washing of base-material, and it has the characteristic of surfactant soln.Generally the liquid product with cleaning function is called to liquid washing agent.According to purposes or function, be divided into liquid detergent, fabric liquid detergent, shampoo and skin cleaner and hard surface cleaner.
Liquid detergent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be for washing water fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent is on the market a feast for the eyes, have superpower, that have concentrated type and the strong sterilizing power of detersive power etc.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be to take environment-friendly and green type as main flow.Except having the function of strong detersive power, harmless, sterilization and disinfection, gentle high bubble, also should easily degrade, free from environmental pollution.The effective constituent of dish washing detergent is mainly tensio-active agent, and it is raw material that traditional dish washing detergent mainly be take synthetic surfactant (as LAS, AS, AES, SAS etc.).But being difficult for degraded mostly, they maybe cannot degrade, to environment.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially, in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, particularly functional liquid detergent is just fewer.
Summary of the invention:
For prior art above shortcomings, technical problem to be solved by this invention is to provide a kind of ginger liquid detergent.
Technical problem of the present invention, is achieved by following technical proposals:
A ginger liquid detergent, is comprised of the raw material of following weight part: Yatall MA acyl both sexes base Sodium Propionate 4-6 part, lauryl hydroxyl sulfo betaine 4-6 part, babassu oil amido propyl amine oxide 2-4 part, Dodecyl Polyglucosides 5-7 part, Rhizoma Zingiberis Recens extract 0.05-0.15 part, 80 parts, water.
Yatall MA acyl both sexes base Sodium Propionate, lauryl hydroxyl sulfo betaine, babassu oil amido propyl amine oxide, Dodecyl Polyglucosides and Rhizoma Zingiberis Recens extract are added to the water, are heated to 40-60 ℃, mix, can make this ginger liquid detergent.
Below, raw material involved in the present invention is made to simple introduction:
Yatall MA acyl both sexes base Sodium Propionate, SODIUM TALLAMPHOPROPIONATE, No. CAS: 68991-88-8.
Lauryl hydroxyl sulfo betaine, LAURYL HYDROXYSULTAINE, No. CAS: 13197-76-7.
Babassu oil amido propyl amine oxide, Babassuamidopropylamine oxide, 124046-26-0.
Dodecyl Polyglucosides, CAS accession number: 110615-47-9.
Rhizoma Zingiberis Recens extract, English name: Ginger extract, CAS accession number: 84696-15-1, INCI title: ZINGIBER OFFICINALE (GINGER) EXTRACT.On the books in < < international cosmetic raw material standard Chinese catalogue (version in 2010) > >.Can pass through commercially available obtaining, also can adopt ordinary method prepare and obtain.As: after ginger is pulverized, add the deionized water of 6-10 times of weight, soak 1-3 hour, ultrasonic extraction 10-15 minute, filters, centrifugal, discards precipitation by supernatant concentration, makes Rhizoma Zingiberis Recens extract, and controlling Rhizoma Zingiberis Recens extract density is 1.02-1.08g/cm
3.
Ginger liquid detergent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, when guaranteeing good decontamination washing effect, greatly reduce the pungency to watch face, add natural ginger elite simultaneously, can effectively remove raw meat, have a strong smell, the peculiar smell such as mould, sour.
Embodiment:
Embodiment further illustrates of the present invention below, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material all be take working substance content as 100%.
Embodiment 1
0.1 kilogram of 5 kilograms of Yatall MA acyl both sexes base Sodium Propionates, 5 kilograms of lauryl hydroxyl sulfo betaines, 3 kilograms of babassu oil amido propyl amine oxides, 6 kilograms of Dodecyl Polyglucosides and Rhizoma Zingiberis Recens extract is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative example 1
0.1 kilogram of 13 kilograms of Yatall MA acyl both sexes base Sodium Propionates, 6 kilograms of Dodecyl Polyglucosides and Rhizoma Zingiberis Recens extract is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative example 2
0.1 kilogram of 13 kilograms of lauryl hydroxyl sulfo betaines, 6 kilograms of Dodecyl Polyglucosides and Rhizoma Zingiberis Recens extract is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative example 3
0.1 kilogram of 13 kilograms of babassu oil amido propyl amine oxides, 6 kilograms of Dodecyl Polyglucosides and Rhizoma Zingiberis Recens extract is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
Mixing oil formula: take butter, lard, vegetables oil mass ratio is 0.5:0.5:1 preparation, and adds the glyceryl monostearate of its total mass 5%, and this is artificial dirt.
Artificial dirt is put on electric furnace and is heated to 180 ℃, stir and keep this temperature 10min, beaker is moved to magnetic stirrer and stir, naturally cool to temperature required standby.The temperature of defiling is recommended reference: when room temperature is 20 ℃, need 80 ℃ of oil temperatures; When room temperature is 25 ℃, need 45 ℃ of oil temperatures; When room temperature is lower than 17 ℃ or during higher than 27 ℃, test should not be carried out, and need to carry out at air conditioning room.Should use the Terg-O-Tometer of attached freezing plant if desired.
2) preparation of dirty sheet
Edge on slide glass is drawn to 10mm line, to show to defile, be limited in this below line; Edge under slide glass is drawn to 5mm line, to show that the unnecessary greasy dirt of wiping is limited in this below line.
3) newly purchasing slide glass need to boil after 15min in detergent solution, and clear water washing is not put in acid wash liquid again and soaked after 1h to not hanging the globule, and clear water rinsing and distilled water flushing are put loft drier standby after dry.
4) preparation of standard dish washing detergent
Take 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts, urea, adds water to 100 parts, mixes, and with hydrochloric acid or sodium hydroxide, regulates pH to 7-8, standby.
5) defile
By clean slide glass take four put and weigh on frame as one group, with analytical balance, accurately weigh (accurately to 1mg) for m0, the slide glass after weighing is sandwiched on film airing stand one by one, more than clip should be clipped in slide glass ascender line, film airing stand is put to ward off in dish and prepares to defile.
When greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, hand-held clip immerses (1-2) s, slowly taking-up to 10mm ascender line in greasy dirt by slide glass, after the lower speed of greasy dirt is slack-off, hangs back and on original film airing stand, prepare successively dirty sheet.After greasy dirt solidifies, by dirty sheet take off with filter paper or absorbent cotton by under dirty sheet along base in 5mm and the unnecessary greasy dirt in both sides wipe, then with tweezers folder, speckle with the absorbent cotton wiped clean of sherwood oil.Under room temperature, hanging after 4h, is m1 weighing on frame with analytical balance accurate weighing.Now on every group of dirty sheet, dirty amount should guarantee (0.5 ± 0.05) g.
6) testing sequence
The slide glass of the known amount of defiling is inserted in corresponding wash stand and prepares to wash.
Spotter is switched on power, and wash temperature is set to 30 ℃, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take 5.00g sample to be tested in 2500mL hard water, after shaking up, measure respectively 800mL test solution in three washing becks of Terg-O-Tometer, when test solution temperature rises to 30 ℃, rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand, after putting into washing beck, last wash stand starts to count soak time, rapidly agitator is installed simultaneously, while soaking 1min, start spotter, start washing, during 3min, machine auto stop, rapidly agitator is taken off, take out wash stand, by washing rear dirty sheet, press from both sides one by one and hang on original film airing stand, extension dries in the air and dirty sheet is put to corresponding weighing frame after 3h and weighed as m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In formula: m0---slide glass quality before defiling, g; M1---slide glass quality after defiling, g; M2---the quality of dirty sheet after washing, g.
The rate of deoiling test chart
? |
The rate of deoiling ω, % |
Embodiment 1 |
44.8 |
Standard dish washing detergent |
38.2 |
Comparative example 1 |
38.8 |
Comparative example 2 |
38.2 |
Comparative example 3 |
39.6 |
Ginger liquid detergent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, and amphoterics Yatall MA acyl both sexes base Sodium Propionate, lauryl hydroxyl sulfo betaine and babassu oil amido propyl amine oxide and nonionogenic tenside Dodecyl Polyglucosides composite (embodiment 1) synergy as can be seen from the above table, compare with nonionogenic tenside Dodecyl Polyglucosides composite (comparative example 1-3) with single amphoterics, detersive power obviously improves.
Test case 2:
Pungency test
Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 ℃ of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.After marking according to the standard of following table for the pungency of wrist-watch skin, average again, mark higher, pungency is less.
Pungency test data table
? |
Scoring |
Embodiment 1 |
100 |
Standard dish washing detergent |
50 |
Comparative example 1 |
95 |
Comparative example 2 |
90 |
Comparative example 3 |
95 |
Embodiment 2
For extending the quality guaranteed period of the present invention, contriver has made following research pioneeringly.
In the prepared liquid detergent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, by following component, formed by weight: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and tennecetins (CAS:7681-93-8).
; this ginger liquid detergent is comprised of the raw material of following weight part: 5 kilograms of Yatall MA acyl both sexes base Sodium Propionates; 5 kilograms of lauryl hydroxyl sulfo betaines; 3 kilograms of babassu oil amido propyl amine oxides; 6 kilograms of Dodecyl Polyglucosides; 0.1 kilogram of Rhizoma Zingiberis Recens extract, 80 kilograms, water, 0.05 kilogram of composite environmental-friendly sanitas.
By adding the sanitas of specific proportioning on the basis at embodiment 1, greatly extended the quality guaranteed period of this ginger liquid detergent.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, contrast, by the general single sanitas 1 of the industry for the composite environmental-friendly sanitas in embodiment 2,3-dihydroxymethyl-5,5-T10 is replaced, and add-on is constant, and its quality guaranteed period is only December.