CN103205325B - Garden burnet sterilizing detergent liquid for tableware - Google Patents
Garden burnet sterilizing detergent liquid for tableware Download PDFInfo
- Publication number
- CN103205325B CN103205325B CN201310052883.6A CN201310052883A CN103205325B CN 103205325 B CN103205325 B CN 103205325B CN 201310052883 A CN201310052883 A CN 201310052883A CN 103205325 B CN103205325 B CN 103205325B
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- Prior art keywords
- garden burnet
- parts
- tableware
- amine oxide
- detergent liquid
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- 239000007788 liquid Substances 0.000 title claims abstract description 30
- 235000008291 Poterium sanguisorba Nutrition 0.000 title claims abstract description 29
- 235000008282 Sanguisorba officinalis Nutrition 0.000 title claims abstract description 29
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 13
- 244000173853 Sanguisorba officinalis Species 0.000 title claims abstract description 11
- 239000003599 detergent Substances 0.000 title abstract description 15
- 238000005406 washing Methods 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims abstract description 16
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims abstract description 16
- -1 propylamine oxide Chemical compound 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 abstract description 3
- 239000000284 extract Substances 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 abstract description 2
- 238000005202 decontamination Methods 0.000 abstract description 2
- 230000003588 decontaminative effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 abstract 1
- 239000002280 amphoteric surfactant Substances 0.000 abstract 1
- 229940073499 decyl glucoside Drugs 0.000 abstract 1
- 229940116335 lauramide Drugs 0.000 abstract 1
- QEALYLRSRQDCRA-UHFFFAOYSA-N myristamide Chemical compound CCCCCCCCCCCCCC(N)=O QEALYLRSRQDCRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 230000000638 stimulation Effects 0.000 abstract 1
- 240000004064 Poterium sanguisorba Species 0.000 description 18
- 239000000243 solution Substances 0.000 description 14
- 239000011521 glass Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000002131 composite material Substances 0.000 description 9
- 238000004851 dishwashing Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 235000019633 pungent taste Nutrition 0.000 description 5
- 238000005303 weighing Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- 238000002137 ultrasound extraction Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 241000581682 Sanguisorba Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229960003861 mephenesin Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Abstract
The invention discloses a garden burnet sterilizing detergent liquid for tableware. The detergent liquid consists of the following materials by weight proportion: 4-6 parts of lauramide propyl amine oxide, 4-6 parts of myristamide propylamine oxide, 2-4 parts of N, N-dimethyl decanoate-N-amine oxide, 5-7 parts of decyl glucoside, 0.05-0.15 part of a garden burnet extract and 80 parts of water. The invention adopts compound of a non-ionic surfactant and an amphoteric surfactant, abandons a traditional anionic surfactant, and greatly reduces stimulation on hand surface while ensuring good decontamination washing effect; and compound of garden burnet extract enables the detergent liquid provided by the invention to effectively kill bacteria while used for washing tableware by hands.
Description
Technical field:
The present invention relates to a kind of tableware liquid washing agent, particularly a kind of garden burnet sterilizing tableware liquid washing agent.
Background technology:
Liquid washing agent is a large class in synthetic detergent, and in synthetic detergent, output maximum is washing powder, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities compared with solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is the articles for washing using water or other organic solvents as base-material, and it has the characteristic of surfactant soln.Generally the liquid product with cleaning function is called to liquid washing agent.According to purposes or function, be divided into tableware liquid washing agent, fabric liquid detergent, shampoo and skin cleaner and hard surface cleaner.
Tableware liquid washing agent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be for washing water fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent is on the market a feast for the eyes, have detersive power superpower, have concentrated type and strong sterilizing power etc.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be take environment-friendly and green type as main flow.Except having the function of strong detersive power, harmless, sterilization and disinfection, gentle high bubble, also should easily degrade, free from environmental pollution.The effective constituent of dish washing detergent is mainly tensio-active agent, and traditional dish washing detergent is mainly take synthetic surfactant (as LAS, AS, AES, SAS etc.) as raw material.But being difficult for degraded mostly, they maybe cannot degrade, to environment.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially, in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, particularly Chinese medicine tableware liquid washing agent is just fewer.
Summary of the invention:
For prior art above shortcomings, technical problem to be solved by this invention is to provide a kind of garden burnet sterilizing tableware liquid washing agent.
Technical problem of the present invention, is achieved by following technical proposals:
A kind of garden burnet sterilizing tableware liquid washing agent, raw material by following weight part forms: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, garden burnet extracting solution 0.05-0.15 part, 80 parts, water.
By dodecanamide propyl amine oxide, myristic amide propyl group amine oxide, N, N-dimethyl decyl-N-amine oxide, Plantacare 818 and garden burnet extracting solution are added to the water, be heated to 40-60 ℃, mix, can make this garden burnet sterilizing tableware liquid washing agent.
Raw material involved in the present invention is made to simple introduction below:
Dodecanamide propyl amine oxide, CAS accession number: 69898-00-6.
Myristic amide propyl group amine oxide, CAS accession number: 67806-10-4.
N, N-dimethyl decyl-N-amine oxide, CAS accession number: 2605-79-0.
Plantacare 818, CAS accession number: 141464-42-8.
Garden burnet, is a kind of conventional Chinese medicine, at Chinese Pharmacopoeia, within 2010, in version, is documented.
Garden burnet extracting solution of the present invention can pass through commercially available obtaining.Also can adopt following method preparation and obtain: after garden burnet is pulverized, adding the deionized water of 6-10 times of weight, soak 1-3 hour, ultrasonic extraction 10-15 minute, filters, centrifugal, discard precipitation by supernatant concentration, make garden burnet extracting solution, controlling garden burnet extracting solution density is 1.02-1.08g/cm
3.
Garden burnet sterilizing tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, when guaranteeing good decontamination washing effect, greatly reduce the pungency to watch face, composite garden burnet extracting solution simultaneously, while using manual dishwashing of the present invention, effectively kill bacteria.
Embodiment:
Embodiment further illustrates of the present invention below, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material is all take working substance content as 100%.
Embodiment 1
After garden burnet is pulverized, add the deionized water of 8 times of weight, soak 2 hours, ultrasonic extraction 15 minutes, filters, centrifugal, discards precipitation by supernatant concentration, and making density is 1.05g/cm
3garden burnet extracting solution.
By 5 kilograms of dodecanamide propyl amine oxides, 5 kilograms of myristic amide propyl group amine oxides, N, 0.1 kilogram of 3 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned garden burnet extracting solution making add in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 1
0.1 kilogram of 13 kilograms of dodecanamide propyl amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned garden burnet extracting solution making is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 2
0.1 kilogram of 13 kilograms of myristic amide propyl group amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned garden burnet extracting solution making is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 3
By N, 0.1 kilogram of 13 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned garden burnet extracting solution making add in the deionized water of 80 kilograms, are heated to 50 ℃, mix, and are cooled to room temperature, can make this tableware liquid washing agent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
Mixing oil formula: take butter, lard, vegetables oil mass ratio as 0.5:0.5:1 preparation, and add the glyceryl monostearate of its total mass 5%, this is artificial dirt.
Artificial dirt is put on electric furnace and is heated to 180 ℃, stir and keep this temperature 10min, beaker is moved to magnetic stirrer and stir, naturally cool to temperature required standby.The temperature of defiling is recommended reference: when room temperature is 20 ℃, need 80 ℃ of oil temperatures; When room temperature is 25 ℃, need 45 ℃ of oil temperatures; When room temperature is lower than 17 ℃ or during higher than 27 ℃, test should not be carried out, and need to carry out at air conditioning room.Should use if desired the Terg-O-Tometer of attached freezing plant.
2) preparation of dirty sheet
Edge on slide glass is drawn to 10mm line, to show to defile, be limited in this below line; Edge under slide glass is drawn to 5mm line, to show that the unnecessary greasy dirt of wiping is limited in this below line.
3) newly purchasing slide glass need to boil after 15min in detergent solution, and clear water washing is put in acid wash liquid again and soaked after 1h to not hanging the globule, and clear water rinsing and distilled water flushing are put loft drier standby after dry.
4) preparation of standard dish washing detergent
Take 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts, urea, adds water to 100 parts, mixes, with hydrochloric acid or sodium hydroxide adjusting pH to 7-8, standby.
5) defile
Clean slide glass is put and weighed on frame take four as one group, with analytical balance, accurately weigh (accurately to 1mg) for m0, the slide glass after weighing is sandwiched on film airing stand one by one, more than clip should be clipped in slide glass ascender line, film airing stand is put to ward off in dish and prepare to defile.
When greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, hand-held clip immerses (1-2) s, slowly taking-up to 10mm ascender line in greasy dirt by slide glass, after the lower speed of greasy dirt is slack-off, hangs back and on original film airing stand, prepare successively dirty sheet.After greasy dirt solidifies, by dirty sheet take off with filter paper or absorbent cotton by under dirty sheet along base in 5mm and the unnecessary greasy dirt in both sides wipe, then with tweezers folder, speckle with the absorbent cotton wiped clean of sherwood oil.Under room temperature, hanging after 4h, is m1 weighing on frame with analytical balance accurate weighing.Now on every group of dirty sheet, dirty amount should guarantee (0.5 ± 0.05) g.
6) testing sequence
The slide glass of the known amount of defiling is inserted in corresponding wash stand and prepares to wash.
Spotter is switched on power, and wash temperature is set to 30 ℃, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take 5.00g sample to be tested in 2500mL hard water, after shaking up, measure respectively 800mL test solution in three washing becks of Terg-O-Tometer, when test solution temperature rises to 30 ℃, rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand, after putting into washing beck, last wash stand starts to count soak time, rapidly agitator is installed simultaneously, while soaking 1min, start spotter, start washing, during 3min, machine auto stop, rapidly agitator is taken off, take out wash stand, by washing rear dirty sheet, press from both sides one by one and hang on original film airing stand, extension dries in the air and dirty sheet is put to corresponding weighing frame after 3h and weighed as m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In formula: m0---slide glass quality before defiling, g; M1---slide glass quality after defiling, g; M2---the quality of dirty sheet after washing, g.
The rate of deoiling test chart
| ? | The rate of deoiling ω, % |
| Embodiment 1 | 45.6 |
| Standard dish washing detergent | 38.2 |
| Comparative example 1 | 39.1 |
| Comparative example 2 | 38.0 |
| Comparative example 3 | 38.4 |
Garden burnet sterilizing tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, and amphoterics osmanthus LAO, myristic amide propyl group amine oxide and N as can be seen from the above table, N-dimethyl decyl-N-amine oxide and nonionogenic tenside Plantacare 818 composite (embodiment 1) synergy, compare with nonionogenic tenside Plantacare 818 composite (comparative example 1-3) with single amphoterics, detersive power obviously improves.
Test case 2:
Pungency test
Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 ℃ of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.After marking according to the standard of following table for the pungency of wrist-watch skin, average again, mark higher, pungency is less.
Pungency test data table
| ? | Scoring |
| Embodiment 1 | 100 |
| Standard dish washing detergent | 50 |
| Comparative example 1 | 95 |
| Comparative example 2 | 90 |
| Comparative example 3 | 95 |
Embodiment 2
Further, owing to having added Chinese medicine extract in formula, inevitable, its quality guaranteed period will decline.For extending the quality guaranteed period of the present invention, contriver has made following research pioneeringly.
In the prepared tableware liquid washing agent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, by following component, formed by weight: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and Salvins (CAS:3650-09-7).
; this garden burnet sterilizing tableware liquid washing agent is comprised of the raw material of following weight part: 5 kilograms of dodecanamide propyl amine oxides; 5 kilograms of myristic amide propyl group amine oxides; N; 3 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s, 0.1 kilogram of garden burnet extracting solution; 80 kilograms, water, 0.05 kilogram of composite environmental-friendly sanitas.
By adding the sanitas of specific proportioning on the basis at embodiment 1, greatly extended the quality guaranteed period of this garden burnet sterilizing tableware liquid washing agent.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, contrast, by the general single sanitas 1 of the industry for the composite environmental-friendly sanitas in embodiment 2,3-dihydroxymethyl-5,5-T10 is replaced, and add-on is constant, and its quality guaranteed period is December.
Claims (1)
1. a garden burnet sterilizing tableware liquid washing agent, it is characterized in that, raw material by following weight part forms: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, garden burnet extracting solution 0.05-0.15 part, 80 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310052883.6A CN103205325B (en) | 2013-02-18 | 2013-02-18 | Garden burnet sterilizing detergent liquid for tableware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310052883.6A CN103205325B (en) | 2013-02-18 | 2013-02-18 | Garden burnet sterilizing detergent liquid for tableware |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103205325A CN103205325A (en) | 2013-07-17 |
| CN103205325B true CN103205325B (en) | 2014-05-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310052883.6A Expired - Fee Related CN103205325B (en) | 2013-02-18 | 2013-02-18 | Garden burnet sterilizing detergent liquid for tableware |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106947637A (en) * | 2017-03-24 | 2017-07-14 | 柳州立洁科技有限公司 | A kind of cleaning agent for kitchen use and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0916718A1 (en) * | 1997-10-14 | 1999-05-19 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| US7465700B1 (en) * | 2007-06-20 | 2008-12-16 | The Clorox Company | Natural cleaning compositions |
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