CN103205327B - Red pomegranate skin-care detergent liquid for tableware - Google Patents
Red pomegranate skin-care detergent liquid for tableware Download PDFInfo
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- CN103205327B CN103205327B CN201310052888.9A CN201310052888A CN103205327B CN 103205327 B CN103205327 B CN 103205327B CN 201310052888 A CN201310052888 A CN 201310052888A CN 103205327 B CN103205327 B CN 103205327B
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- red pomegranate
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Abstract
The invention discloses a red pomegranate skin-care detergent liquid for tableware. The detergent liquid consists of the following materials by weight: 4-6 parts of lauramide propyl amine oxide, 4-6 parts of myristamide propylamine oxide, 2-4 parts of N, N-dimethyl decanoate-N-amine oxide, 5-7 parts of decyl glucoside, 0.05-0.15 part of a red pomegranate extract and 80 parts of water. The invention adopts compound of a non-ionic surfactant and an amphoteric surfactant, abandons a traditional anionic surfactant, greatly reduces stimulation on hand surface while ensuring good decontamination washing effect; and compound of the red pomegranate extract enables the detergent liquid provided by the invention to effectively nourish the hand skin while used for washing tableware.
Description
Technical field:
The present invention relates to a kind of tableware liquid washing agent, particularly a kind of red pomegranate skin care tableware liquid washing agent.
Background technology:
Liquid washing agent is a large class in synthetic detergent, and in synthetic detergent, output maximum is washing powder, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities compared with solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is to using water or other organic solvents as the articles for washing of base-material, and it has the characteristic of surfactant soln.Generally the liquid product with cleaning function is called to liquid washing agent.According to purposes or function, be divided into tableware liquid washing agent, fabric liquid detergent, shampoo and skin cleaner and hard surface cleaner.
Tableware liquid washing agent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be for washing water fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent is on the market a feast for the eyes, have superpower, that have concentrated type and the strong sterilizing power of detersive power etc.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be to take environment-friendly and green type as main flow.Except having the function of strong detersive power, harmless, sterilization and disinfection, gentle high bubble, also should easily degrade, free from environmental pollution.The effective constituent of dish washing detergent is mainly tensio-active agent, and it is raw material that traditional dish washing detergent mainly be take synthetic surfactant (as LAS, AS, AES, SAS etc.).But being difficult for degraded mostly, they maybe cannot degrade, to environment.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially, in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, particularly Chinese medicine tableware liquid washing agent is just fewer.
Summary of the invention:
For prior art above shortcomings, technical problem to be solved by this invention is to provide a kind of red pomegranate skin care tableware liquid washing agent.
Technical problem of the present invention, is achieved by following technical proposals:
A kind of red pomegranate skin care tableware liquid washing agent, raw material by following weight part forms: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, red pomegranate extracting solution 0.05-0.15 part, 80 parts, water.
By dodecanamide propyl amine oxide, myristic amide propyl group amine oxide, N, N-dimethyl decyl-N-amine oxide, Plantacare 818 and red pomegranate extracting solution are added to the water, be heated to 40-60 ℃, mix, can make this red pomegranate skin care tableware liquid washing agent.
Below, raw material involved in the present invention is made to simple introduction:
Dodecanamide propyl amine oxide, CAS accession number: 69898-00-6.
Myristic amide propyl group amine oxide, CAS accession number: 67806-10-4.
N, N-dimethyl decyl-N-amine oxide, CAS accession number: 2605-79-0.
Plantacare 818, CAS accession number: 141464-42-8.
Red pomegranate is a kind for pomegranate, because pericarp after maturation is gained the name for pink.Red pomegranate nature and flavor are sweet, sour and astringent, warm, contain the materials such as abundant vitamins C, Punica granatum L. polyphenol and anthocyanidin in fruit, have good toxin expelling, anti-oxidation efficacy.Aspect medicinal, beauty treatment, dietotherapy, all playing an important role.Modern medicine is found, contains a large amount of Punica granatum L. polyphenols and anthocyanidin in red pomegranate, and oxidation-resistance exceeds 3 times of green tea, ascorbic 20 times especially, can be effectively in and free radical, enhance metabolism, discharge toxin.
Red pomegranate extracting solution of the present invention can pass through commercially available obtaining.Also can adopt following method preparation and obtain: after red pomegranate is pulverized, the deionized water that adds 6-10 times of weight, soak 1-3 hour, ultrasonic extraction 10-15 minute, filter, centrifugal, discard precipitation by supernatant concentration, make red pomegranate extracting solution, controlling red pomegranate extracting solution density is 1.02-1.08g/cm
3.
Red pomegranate skin care tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, when guaranteeing good decontamination washing effect, greatly reduce the pungency to watch face, composite red pomegranate extracting solution, uses the present invention can effectively nourish soft and moist hand skin in clean tableware simultaneously.
Embodiment:
Embodiment further illustrates of the present invention below, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material all be take working substance content as 100%.
Embodiment 1
After red pomegranate is pulverized, add the deionized water of 8 times of weight, soak 2 hours, ultrasonic extraction 15 minutes, filters, centrifugal, discards precipitation by supernatant concentration, and making density is 1.05g/cm
3red pomegranate extracting solution.
By 5 kilograms of dodecanamide propyl amine oxides, 5 kilograms of myristic amide propyl group amine oxides, N, 0.1 kilogram of 3 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned red pomegranate extracting solution making add in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 1
0.1 kilogram of 13 kilograms of dodecanamide propyl amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned red pomegranate extracting solution making is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 2
0.1 kilogram of 13 kilograms of myristic amide propyl group amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned red pomegranate extracting solution making is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 3
By N, 0.1 kilogram of 13 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned red pomegranate extracting solution making add in the deionized water of 80 kilograms, are heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
Mixing oil formula: take butter, lard, vegetables oil mass ratio is 0.5:0.5:1 preparation, and adds the glyceryl monostearate of its total mass 5%, and this is artificial dirt.
Artificial dirt is put on electric furnace and is heated to 180 ℃, stir and keep this temperature 10min, beaker is moved to magnetic stirrer and stir, naturally cool to temperature required standby.The temperature of defiling is recommended reference: when room temperature is 20 ℃, need 80 ℃ of oil temperatures; When room temperature is 25 ℃, need 45 ℃ of oil temperatures; When room temperature is lower than 17 ℃ or during higher than 27 ℃, test should not be carried out, and need to carry out at air conditioning room.Should use the Terg-O-Tometer of attached freezing plant if desired.
2) preparation of dirty sheet
Edge on slide glass is drawn to 10mm line, to show to defile, be limited in this below line; Edge under slide glass is drawn to 5mm line, to show that the unnecessary greasy dirt of wiping is limited in this below line.
3) newly purchasing slide glass need to boil after 15min in detergent solution, and clear water washing is not put in acid wash liquid again and soaked after 1h to not hanging the globule, and clear water rinsing and distilled water flushing are put loft drier standby after dry.
4) preparation of standard dish washing detergent
Take 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts, urea, adds water to 100 parts, mixes, and with hydrochloric acid or sodium hydroxide, regulates pH to 7-8, standby.
5) defile
By clean slide glass take four put and weigh on frame as one group, with analytical balance, accurately weigh (accurately to 1mg) for m0, the slide glass after weighing is sandwiched on film airing stand one by one, more than clip should be clipped in slide glass ascender line, film airing stand is put to ward off in dish and prepares to defile.
When greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, hand-held clip immerses (1-2) s, slowly taking-up to 10mm ascender line in greasy dirt by slide glass, after the lower speed of greasy dirt is slack-off, hangs back and on original film airing stand, prepare successively dirty sheet.After greasy dirt solidifies, by dirty sheet take off with filter paper or absorbent cotton by under dirty sheet along base in 5mm and the unnecessary greasy dirt in both sides wipe, then with tweezers folder, speckle with the absorbent cotton wiped clean of sherwood oil.Under room temperature, hanging after 4h, is m1 weighing on frame with analytical balance accurate weighing.Now on every group of dirty sheet, dirty amount should guarantee (0.5 ± 0.05) g.
6) testing sequence
The slide glass of the known amount of defiling is inserted in corresponding wash stand and prepares to wash.
Spotter is switched on power, and wash temperature is set to 30 ℃, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take 5.00g sample to be tested in 2500mL hard water, after shaking up, measure respectively 800mL test solution in three washing becks of Terg-O-Tometer, when test solution temperature rises to 30 ℃, rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand, after putting into washing beck, last wash stand starts to count soak time, rapidly agitator is installed simultaneously, while soaking 1min, start spotter, start washing, during 3min, machine auto stop, rapidly agitator is taken off, take out wash stand, by washing rear dirty sheet, press from both sides one by one and hang on original film airing stand, extension dries in the air and dirty sheet is put to corresponding weighing frame after 3h and weighed as m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In formula: m0---slide glass quality before defiling, g; M1---slide glass quality after defiling, g; M2---the quality of dirty sheet after washing, g.
The rate of deoiling test chart
| ? | The rate of deoiling ω, % |
| Embodiment 1 | 46.3 |
| Standard dish washing detergent | 38.2 |
| Comparative example 1 | 38.2 |
| Comparative example 2 | 38.4 |
| Comparative example 3 | 38.1 |
Red pomegranate skin care tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, and amphoterics osmanthus LAO as can be seen from the above table, myristic amide propyl group amine oxide and N, N-dimethyl decyl-N-amine oxide and nonionogenic tenside Plantacare 818 composite (embodiment 1) synergy, compare with nonionogenic tenside Plantacare 818 composite (comparative example 1-3) with single amphoterics, detersive power obviously improves.
Test case 2:
Pungency test
Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 ℃ of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.After marking according to the standard of following table for the pungency of wrist-watch skin, average again, mark higher, pungency is less.
Pungency test data table
| ? | Scoring |
| Embodiment 1 | 100 |
| Standard dish washing detergent | 50 |
| Comparative example 1 | 95 |
| Comparative example 2 | 90 |
| Comparative example 3 | 95 |
Embodiment 2
Further, owing to having added Chinese medicine extract in formula, inevitable, its quality guaranteed period will decline.For extending the quality guaranteed period of the present invention, contriver has made following research pioneeringly.
In the prepared tableware liquid washing agent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, by following component, formed by weight: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and Salvins (CAS:3650-09-7).
; this red pomegranate skin care tableware liquid washing agent is comprised of the raw material of following weight part: 5 kilograms of dodecanamide propyl amine oxides; 5 kilograms of myristic amide propyl group amine oxides; N; 3 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s, 0.1 kilogram of red pomegranate extracting solution; 80 kilograms, water, 0.05 kilogram of composite environmental-friendly sanitas.
By adding the sanitas of specific proportioning on the basis at embodiment 1, greatly extended the quality guaranteed period of this red pomegranate skin care tableware liquid washing agent.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, contrast, by the general single sanitas 1 of the industry for the composite environmental-friendly sanitas in embodiment 2,3-dihydroxymethyl-5,5-T10 is replaced, and add-on is constant, and its quality guaranteed period is December.
Claims (1)
1. a red pomegranate skin care tableware liquid washing agent, raw material by following weight part forms: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, red pomegranate extracting solution 0.05-0.15 part, 80 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310052888.9A CN103205327B (en) | 2013-02-18 | 2013-02-18 | Red pomegranate skin-care detergent liquid for tableware |
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| CN201310052888.9A CN103205327B (en) | 2013-02-18 | 2013-02-18 | Red pomegranate skin-care detergent liquid for tableware |
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| CN103205327B true CN103205327B (en) | 2014-04-09 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103275820B (en) * | 2013-05-28 | 2015-01-21 | 安徽省林锦记食品工业有限公司 | Mango seed oil skin-protecting detergent |
| CN105368599B (en) * | 2015-11-09 | 2018-12-14 | 长安大学 | A kind of detergent containing active constituent in juice of my pomegranate |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019441A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| WO2008157754A2 (en) * | 2007-06-20 | 2008-12-24 | The Clorox Company | Natural cleaning composition |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019441A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| WO2008157754A2 (en) * | 2007-06-20 | 2008-12-24 | The Clorox Company | Natural cleaning composition |
Non-Patent Citations (2)
| Title |
|---|
| 《脂肪酰胺丙基二甲基氧化胺的合成及在酸性体系中的增稠研究》;刘庆刚 等;《日用化学品科学》;20120531;第35卷(第5期);28-31 * |
| 刘庆刚 等.《脂肪酰胺丙基二甲基氧化胺的合成及在酸性体系中的增稠研究》.《日用化学品科学》.2012,第35卷(第5期), |
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Effective date of registration: 20190724 Address after: 430000 No. 5 Shipailing East Second Road, Donghu New Technology Development Zone, Wuhan City, Hubei Province Patentee after: Wuhan Donghuxing Technology Co., Ltd. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: Shanghai Yanzi Chemical Technology Co., Ltd. |
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