CN103205322B - Cornflower skin-care detergent liquid for tableware - Google Patents
Cornflower skin-care detergent liquid for tableware Download PDFInfo
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- CN103205322B CN103205322B CN201310052735.4A CN201310052735A CN103205322B CN 103205322 B CN103205322 B CN 103205322B CN 201310052735 A CN201310052735 A CN 201310052735A CN 103205322 B CN103205322 B CN 103205322B
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Abstract
The invention discloses a cornflower skin-care detergent liquid for tableware. The detergent liquid consists of the following materials by weight: 4-6 parts of lauramide propyl amine oxide, 4-6 parts of myristamide propylamine oxide, 2-4 parts of N, N-dimethyl decanoate-N-amine oxide, 5-7 parts of decyl glucoside, 0.05-0.15 parts of a cornflower extract and 80 parts of water. The invention adopts compound of a non-ionic surfactant and an amphoteric surfactant, abandons a traditional anionic surfactant, greatly reduces stimulation on hand surface while ensuring good decontamination washing effect; and compound of the cornflower extract enables the detergent liquid provided by the invention to effectively nourish hand skin while used for washing tableware and to have agreeable scent.
Description
Technical field:
The present invention relates to a kind of tableware liquid washing agent, particularly a kind of Minor centaury skin care tableware liquid washing agent.
Background technology:
Liquid washing agent is a large class in synthetic detergent, and in synthetic detergent, output maximum is washing powder, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities compared with solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is the articles for washing using water or other organic solvents as base-material, and it has the characteristic of surfactant soln.Generally the liquid product with cleaning function is called to liquid washing agent.Be divided into tableware liquid washing agent, fabric liquid detergent, shampoo and skin cleaner and hard surface cleaner according to purposes or function.
Tableware liquid washing agent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be for washing water fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent is on the market a feast for the eyes, have detersive power superpower, have concentrated type and strong sterilizing power etc.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be taking environment-friendly and green type as main flow.Except having the function of strong detersive power, harmless, sterilization and disinfection, gentle high bubble, also should easily degrade, free from environmental pollution.The effective constituent of dish washing detergent is mainly tensio-active agent, and traditional dish washing detergent is mainly taking synthetic surfactant (as LAS, AS, AES, SAS etc.) as raw material.But being difficult for degraded mostly, they maybe cannot degrade, to environment.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially, in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, particularly Chinese medicine tableware liquid washing agent is just fewer.
Summary of the invention:
For prior art above shortcomings, technical problem to be solved by this invention is to provide a kind of Minor centaury skin care tableware liquid washing agent.
Technical problem of the present invention, is achieved by following technical proposals:
A kind of Minor centaury skin care tableware liquid washing agent, raw material by following weight part forms: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, Minor centaury extracting solution 0.05-0.15 part, 80 parts, water.
By dodecanamide propyl amine oxide, myristic amide propyl group amine oxide, N, N-dimethyl decyl-N-amine oxide, Plantacare 818 and Minor centaury extracting solution are added to the water, be heated to 40-60 DEG C, mix, can make this Minor centaury skin care tableware liquid washing agent.
Raw material involved in the present invention is made to simple introduction below:
Dodecanamide propyl amine oxide, CAS accession number: 69898-00-6.
Myristic amide propyl group amine oxide, CAS accession number: 67806-10-4.
N, N-dimethyl decyl-N-amine oxide, CAS accession number: 2605-79-0.
Plantacare 818, CAS accession number: 141464-42-8.
Minor centaury, Latin formal name used at school: Centaurea cyanus Linn, another name: blue lotus, emerald green blue, lichee chrysanthemum, binominal nomenclature: Cornflower.
Minor centaury extracting solution of the present invention can pass through commercially available obtaining.Also can adopt following method preparation and obtain: after Minor centaury is pulverized, add the deionized water of 6-10 times of weight, soak 1-3 hour, ultrasonic extraction 10-15 minute, filter, centrifugal, discard precipitation by supernatant concentration, make Minor centaury extracting solution, controlling Minor centaury extracting solution density is 1.02-1.08g/cm
3.
Minor centaury skin care tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandon traditional anion surfactant, in guaranteeing good decontamination washing effect, greatly reduce the pungency to watch face, composite Minor centaury extracting solution simultaneously, uses the present invention can effectively nourish hand skin, pleasant aroma in clean tableware.
Embodiment:
Embodiment further illustrates of the present invention below, instead of limits the scope of the invention.In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.
Embodiment 1
After Minor centaury is pulverized, add the deionized water of 8 times of weight, soak 2 hours, ultrasonic extraction 15 minutes, filters, centrifugal, discards precipitation by supernatant concentration, and making density is 1.05g/cm
3minor centaury extracting solution.
By 5 kilograms of dodecanamide propyl amine oxides, 5 kilograms of myristic amide propyl group amine oxides, N, 0.1 kilogram of 3 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned Minor centaury extracting solution making add in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 1
0.1 kilogram of 13 kilograms of dodecanamide propyl amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned Minor centaury extracting solution making is added in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 2
0.1 kilogram of 13 kilograms of myristic amide propyl group amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned Minor centaury extracting solution making is added in the deionized water of 80 kilograms, be heated to 50 DEG C, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative example 3
By N, 0.1 kilogram of 13 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned Minor centaury extracting solution making add in the deionized water of 80 kilograms, are heated to 50 DEG C, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
Mixing oil formula: taking butter, lard, vegetables oil mass ratio as 0.5:0.5:1 preparation, and add the glyceryl monostearate of its total mass 5%, this is artificial dirt.
Artificial dirt is put on electric furnace and is heated to 180 DEG C, stir and keep this temperature 10min, beaker is moved to magnetic stirrer and stir, naturally cool to temperature required for subsequent use.The temperature of defiling is recommended reference: in the time that room temperature is 20 DEG C, need 80 DEG C of oil temperatures; When room temperature is 25 DEG C, need 45 DEG C of oil temperatures; When room temperature is lower than 17 DEG C or during higher than 27 DEG C, test should not be carried out, and need to carry out at air conditioning room.Should use if desired the Terg-O-Tometer of attached freezing plant.
2) preparation of dirty sheet
Edge on slide glass is drawn to 10mm line, be limited in this below line to show to defile; Edge under slide glass is drawn to 5mm line, to show that the unnecessary greasy dirt of wiping is limited in this below line.
3) newly purchasing slide glass need to boil after 15min in detergent solution, and clear water washing is put in acid wash liquid again and soaked after 1h to not hanging the globule, and clear water rinsing and distilled water flushing are put loft drier for subsequent use after dry.
4) preparation of standard dish washing detergent
Take 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts, urea, adds water to 100 parts, mixes, with hydrochloric acid or sodium hydroxide adjusting pH to 7-8, for subsequent use.
5) defile
Clean slide glass is put and weighed on frame taking four as one group, accurately weigh (accurately to 1mg) for m0 with analytical balance, the slide glass after weighing is sandwiched on film airing stand one by one, more than clip should be clipped in slide glass ascender line, film airing stand is put to ward off in dish and prepare to defile.
In the time that greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, slide glass is immersed (1-2) s, slowly taking-up to 10mm ascender line in greasy dirt by hand-held clip, after the lower speed of greasy dirt is slack-off, hangs back and on original film airing stand, prepare successively dirty sheet.After greasy dirt solidifies, by dirty sheet take off with filter paper or absorbent cotton by under dirty sheet along base in 5mm and the unnecessary greasy dirt in both sides wipe, then speckle with the absorbent cotton wiped clean of sherwood oil with tweezers folder.Under room temperature, hanging after 4h, is m1 weighing on frame with analytical balance accurate weighing.Now on every group of dirty sheet, dirty amount should ensure (0.5 ± 0.05) g.
6) testing sequence
The slide glass of the known amount of defiling is inserted in corresponding wash stand and prepares to wash.
Spotter is switched on power, and wash temperature is set to 30 DEG C, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take 5.00g sample to be tested in 2500mL hard water, after shaking up, measure respectively 800mL test solution in three washing becks of Terg-O-Tometer, in the time that test solution temperature rises to 30 DEG C, rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand, after putting into washing beck, last wash stand starts to count soak time, rapidly agitator is installed simultaneously, while soaking 1min, start spotter, start washing, when 3min, machine auto stop, rapidly agitator is taken off, take out wash stand, press from both sides one by one and hang on original film airing stand washing rear dirty sheet, extension dries in the air and dirty sheet is put to corresponding weighing frame after 3h and weighed as m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In formula: m0---slide glass quality before defiling, g; M1---slide glass quality after defiling, g; M2---the quality of dirty sheet after washing, g.
The rate of deoiling test chart
| ? | The rate of deoiling ω, % |
| Embodiment 1 | 46.8 |
| Standard dish washing detergent | 38.2 |
| Comparative example 1 | 38.0 |
| Comparative example 2 | 38.5 |
| Comparative example 3 | 38.4 |
Minor centaury skin care tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandon traditional anion surfactant, and amphoterics osmanthus LAO as can be seen from the above table, myristic amide propyl group amine oxide and N, N-dimethyl decyl-N-amine oxide and nonionogenic tenside Plantacare 818 composite (embodiment 1) synergy, compare with nonionogenic tenside Plantacare 818 composite (comparative example 1-3) with single amphoterics, detersive power obviously improves.
Test case 2:
Pungency test
Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 DEG C of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.After marking according to the standard of following table for the pungency of wrist-watch skin, average again, mark higher, pungency is less.
Pungency test data table
| ? | Scoring |
| Embodiment 1 | 100 |
| Standard dish washing detergent | 50 |
| Comparative example 1 | 95 |
| Comparative example 2 | 90 |
| Comparative example 3 | 95 |
Embodiment 2
Further, owing to having added Chinese medicine extract in formula, inevitable, its quality guaranteed period will decline.For extending the quality guaranteed period of the present invention, contriver has made following research pioneeringly.
In the prepared tableware liquid washing agent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, formed by weight by following component: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and Salvins (CAS:3650-09-7).
; this Minor centaury skin care tableware liquid washing agent is made up of the raw material of following weight part: 5 kilograms of dodecanamide propyl amine oxides; 5 kilograms of myristic amide propyl group amine oxides; N; 3 kilograms of N-dimethyl decyl-N-amine oxides, 6 kilograms of Plantacare 818s, 0.1 kilogram of Minor centaury extracting solution; 80 kilograms, water, 0.05 kilogram of composite environmental-friendly sanitas.
By adding the sanitas of specific proportioning on the basis at embodiment 1, greatly extend the quality guaranteed period of this Minor centaury skin care tableware liquid washing agent.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, contrast, by the general single sanitas 1 of the industry for the composite environmental-friendly sanitas in embodiment 2,3-dihydroxymethyl-5,5-T10 is replaced, and add-on is constant, and its quality guaranteed period is December.
Claims (1)
1. a Minor centaury skin care tableware liquid washing agent, raw material by following weight part forms: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, Minor centaury extracting solution 0.05-0.15 part, 80 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310052735.4A CN103205322B (en) | 2013-02-18 | 2013-02-18 | Cornflower skin-care detergent liquid for tableware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310052735.4A CN103205322B (en) | 2013-02-18 | 2013-02-18 | Cornflower skin-care detergent liquid for tableware |
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| Publication Number | Publication Date |
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| CN103205322A CN103205322A (en) | 2013-07-17 |
| CN103205322B true CN103205322B (en) | 2014-06-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310052735.4A Active CN103205322B (en) | 2013-02-18 | 2013-02-18 | Cornflower skin-care detergent liquid for tableware |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275820B (en) * | 2013-05-28 | 2015-01-21 | 安徽省林锦记食品工业有限公司 | Mango seed oil skin-protecting detergent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019441A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| WO2008157754A2 (en) * | 2007-06-20 | 2008-12-24 | The Clorox Company | Natural cleaning composition |
| CN102597202A (en) * | 2009-09-16 | 2012-07-18 | 比诺里卡公司 | Detergent, cleaning agent or disinfectant containing hydrolyzates made of plant extracts |
-
2013
- 2013-02-18 CN CN201310052735.4A patent/CN103205322B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019441A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| WO2008157754A2 (en) * | 2007-06-20 | 2008-12-24 | The Clorox Company | Natural cleaning composition |
| CN102597202A (en) * | 2009-09-16 | 2012-07-18 | 比诺里卡公司 | Detergent, cleaning agent or disinfectant containing hydrolyzates made of plant extracts |
Non-Patent Citations (4)
| Title |
|---|
| 刘庆刚 等.脂肪酰胺丙基二甲基氧化胺的合成及在酸性体系中的增稠研究".《日用化学品科学》.2012,第35卷(第05期),28-31. |
| 天然植物在化妆品中的功效;王雨来;《广西轻工业》;19961231(第01期);49-51 * |
| 王雨来.天然植物在化妆品中的功效.《广西轻工业》.1996,(第01期),49-51. |
| 脂肪酰胺丙基二甲基氧化胺的合成及在酸性体系中的增稠研究";刘庆刚 等;《日用化学品科学》;20120531;第35卷(第05期);28-31 * |
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Effective date of registration: 20230323 Address after: West of Huangjiahu Avenue, Xingyuanchang Village, Daqiao New District, Jiangxia Economic Development Zone, Wuhan City, Hubei Province 430000 Patentee after: WUHAN CHAOHAO BIOTECHNOLOGY CO.,LTD. Address before: 233010 1st floor, incubation workshop, Industrial Automation Research Institute, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee before: Bengbu Xingshi Intellectual Property Operations Co.,Ltd. |
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