CN105754767B - A kind of multi-functional compound washing liquid and its preparation method and application - Google Patents
A kind of multi-functional compound washing liquid and its preparation method and application Download PDFInfo
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Abstract
The present invention relates to a kind of multi-functional compound washing liquid, the cleaning solution includes Cocoamidopropyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, houttuynia extract, dryopteris fragrans extract, Carbenoxolone Sodium, the sweet amino proline of methyl, 2- amino -2- ethyl -1- amylalcohol, 2-Methyl Butyric Acid-hex- 5- enester, fatty acid potassium soap, poly-epoxy succinic acid and water.The multi-functional compound washing liquid shows the performances such as excellent antibacterial, decontamination, soft and smooth, flavouring and low bubble, meets the consumption demand of people, has extensive industrial applications prospect.
Description
Technical field
The present invention relates to a kind of cleaning solution, relate more specifically to a kind of have both the multi-functional of antibacterial, decontamination, soft and smooth and other effects
Compound washing liquid, belongs to filed of daily-use chemical industry.
Background technique
Expanding economy and the progress of science and technology not only promote improvement of living standard, and following also serious
Pollution and dust, such as varieties of food items, oil smoke, additive etc..For this purpose, people are also generally improving clean and tidy, hygienic requirement.
Especially for the daily chemical product of washing, people not only require it to have efficient dirt-removing power, and require articles for washing
Have many performances such as small skin irritation, lasting fragrance, fabric be submissive and safe and healthy.In addition, people are closed at the also moment
Infuse the universality of detergent, such as the article washing of clothing, kitchen cleaning, vegetable and fruit and various occasions, pervasive performance
Raising will effectively push detergent great-leap-forward development, better meet the demand of people.
In order to make articles for washing reach higher washing effect and have both multiple performance, people concentrate on studies be prepared for it is a variety of
Detergent, such as petrochemical industry washing agent, plant detergent, marine organisms detergent and multi-functional composite detergent.The prior art
In there are many reports, such as:
The patent application of CN101311257A discloses a kind of liquid multienzyme detergent comprising a certain proportion of surface is living
Property agent, triethanolamine, ethyl alcohol, sodium metasilicate, ethylparaben, protease, amylase, cellulase, lipase and water.The product
Stability is good.Decomposing organic matter ability is strong, is diluted with water and can be easy to use.
The patent application of CN1667109A discloses a kind of food detergent containing ocean active matters, by certain proportion
Seawater bittern extract, sodium bicarbonate and food additives compound, can be used for purified water fruits and vegetables etc., effectively remove
The peculiar smell such as deodorization, smelly and ensure food safety.
A kind of non-phosphate detergent of the patent applications report of CN102115696A, uses the detergent alkylate of special ratios
Sodium sulfonate, oxidised maize starch, fatty alcohol polyoxyethylene ether, coconut acid diethanolamide, fatty alcohol polyoxyethylene ether sulfuric acid
Sodium, triethanolamine, sodium metasilicate, additive and water are formulated, and are solved the environmental issue of phosphorus pollution, are reduced detergent to skin
The damage of skin, and reduce production cost.
The patent application of CN102978027A discloses a kind of Fruit detergent, is made of the raw material of following components: sweet
Oily list certain herbaceous plants with big flowers acid esters, coconut oil, six polyglycerol monooleates, enuatrol, essence, water and lauric acid amide of ethanol.The detergent
The worm's ovum that fruit surface attachment can effectively be washed away, compensates for the deficiency of general detergent.
However, the prior art still has many defects, such as rinse water consumption is big, clothing damage is big, fragrance is not enough held
Long, lack MULTIPLE COMPOSITE effect, universality difference, etc..Therefore need to provide it is a kind of it is with high-efficiency cleaning ability, easily rinsing,
The liquid detergent of opposite material temperature and low stimulation simultaneously.
In view of the deficiencies in the prior art, the present invention is directed to research and develop a kind of MULTIPLE COMPOSITE effect detergent compositions, pass through
The suitable selection of the specific combination and material ratio of component, and the detergent compositions is made to show efficient detergency ability, fabric
Soft and smooth performance, and lasting fragrance, have both multiple efficacies, especially meet the growing substance of consumer and spiritual demand,
With extensive industrial applications prospect and market value.
Summary of the invention
In order to which the nano composite dope of heat-resistant, wear-resistant is prepared, the present inventor has made intensive studies this, is paying
A large amount of creative work and after further investigation is explored, so as to complete the present invention.
Specifically, the invention mainly relates to three aspects.
First aspect, the present invention relates to a kind of multi-functional compound washing liquid, and the cleaning solution includes cocamidopropyl propyl amide
Glycine betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, houttuynia extract, dryopteris fragrans extract, Carbenoxolone Sodium, the sweet amino of methyl
Proline acid, 2- amino -2- ethyl -1- amylalcohol, 2-Methyl Butyric Acid-hex- 5- enester, fatty acid potassium soap, poly-epoxy succinic acid and
Water.
In the cleaning solution, in parts by weight, concrete component content is as follows:
In the cleaning solution of the invention, in parts by weight, concrete component preferred content is as follows:
| Cocoamidopropyl betaine | 10-20 |
| Disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate | 5-15 |
| Houttuynia extract | 5-10 |
| Dryopteris fragrans extract | 5-10 |
| Carbenoxolone Sodium | 2-6 |
| The sweet amino proline of methyl | 0.5-3 |
| 2- amino -2- ethyl -1- amylalcohol | 0.5-2.5 |
| 2-Methyl Butyric Acid-hex- 5- enester | 0.5-2.5 |
| Fatty acid potassium soap | 1-5 |
| Poly-epoxy succinic acid | 1-5 |
| Water | 5-12。 |
In the cleaning solution of the invention, the parts by weight of Cocoamidopropyl betaine are preferably 10-20 parts, for example
10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts.
In the cleaning solution of the invention, the parts by weight of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate are preferably 5-15 parts,
For example 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts.
In the cleaning solution of the invention, the parts by weight of houttuynia extract are preferably 5-10 parts, for example 5 parts, 6
Part, 7 parts, 8 parts, 9 parts or 10 parts.
In the cleaning solution of the invention, the parts by weight of dryopteris fragrans extract are preferably 5-10 parts, for example 5 parts, 6
Part, 7 parts, 8 parts, 9 parts or 10 parts.
In the cleaning solution of the invention, the parts by weight of Carbenoxolone Sodium are preferably 2-6 parts, such as can be 1 part, 2 parts, 3
Part, 4 parts, 5 parts or 6 parts.
In the cleaning solution of the invention, the parts by weight of the sweet amino proline of methyl are preferably 0.5-3 parts, such as may be used
It is 0.5 part, 1.5 parts, 2 parts, 2.5 parts or 3 parts.
In the cleaning solution of the invention, the parts by weight of 2- amino -2- ethyl -1- amylalcohol are preferably 0.5-2.5 parts,
It such as can be 0.5 part, 1 part, 1.5 parts, 2 parts or 2.5 parts.
In the cleaning solution of the invention, 2-Methyl Butyric Acid-hex- 5- enester parts by weight are preferably 0.5-2.5 parts,
For example 0.5 part, 1 part, 1.5 parts, 2 parts or 2.5 parts.
In the cleaning solution of the invention, the parts by weight of fatty acid potassium soap are preferably 1-5 parts, for example 1 part, 1.5 parts,
2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
In the cleaning solution of the invention, the parts by weight of poly-epoxy succinic acid are preferably 1-5 parts, for example 1 part, 1.5
Part, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
In the cleaning solution of the invention, the parts by weight of water are preferably 5-12 parts, for example 5 parts, 6 parts, 7 parts, 8 parts, 9
Part, 10 parts, 11 parts or 12 parts.
Poly-epoxy succinic acid of the invention can be any well known poly-epoxy succinic acid, such as use in embodiment poly-
Epoxysuccinic acid is cube board/model LF-203 poly-epoxy succinic acid；Fatty acid potassium soap of the invention is any well known
Fatty acid potassium soap, such as the fatty acid potassium soap used in embodiment is the model DX-918's of the male Chemical Manufacture in Guangdong city east
Fatty acid potassium soap.
In addition, can also be incorporated as the 4A zeolite powder of 500 mesh of poly-epoxy succinic acid quality 1/2 into the cleaning solution.
The second aspect, it is specific as follows: according to above-mentioned the present invention relates to the preparation method of above-mentioned multi-functional compound washing liquid
Weight ratio mentions Cocoamidopropyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, houttuynia extract, dryopteris fragrans
Take the sweet amino proline of object, Carbenoxolone Sodium, methyl, 2- amino -2- ethyl -1- amylalcohol, 2-Methyl Butyric Acid-hex- 5- enester, rouge
Then fat acid potash soap, poly-epoxy succinic acid and water the uniform stirring 20-30 min at 30-40 DEG C are down to room temperature and continue to stir 15-
20 min are to get the multi-functional compound washing liquid of the invention.
In the cleaning solution of the invention, houttuynia extract is prepared using following steps:
Cordate houttuynia dry product is placed in the ethyl alcohol that mass percent concentration is 50-60%, is extracted under 60 W of room temperature ultrasonic power
2-3 h, it is 1/4 that filtrate, which is concentrated into volume, after filtering, and recycles ethyl alcohol；Then filter residue is add to deionized water, is warming up to
40-50 DEG C of progress second extraction 2-3 h, it is 1/4 that filtrate, which is concentrated into volume, after filtering；Finally merge the concentrate extracted twice to obtain
To houttuynia extract, stay do it is spare.Wherein, the mass volume ratio of cordate houttuynia dry product and ethyl alcohol, water is 1:5-10 g/ml.
In the cleaning solution of the invention, dryopteris fragrans extract is prepared using following steps:
The crushing of dryopteris fragrans cured leaf is placed in Microwave Extraction device, deionized water is added in 60-70 DEG C and microwave power 220
2-4 h is extracted under W, is filtered after extraction and is removed insoluble matter and residue, obtains dryopteris fragrans extract, give over to spare.Wherein,
Dryopteris fragrans cured leaf and the mass volume ratio of deionized water are 1:4-6 g/ml.
In terms of third, the present invention relates to the use that above-mentioned multi-functional compound washing liquid is used to clean fabric, fruit, tableware
On the way.
Compared with prior art, multi-functional compound washing liquid of the invention passes through the appropriate combination and ratio of functional component
Example selection, and significant synergy is unexpectedly achieved, have efficient decontamination, sterilization, flavouring, fabric smoothness
Can, meet consumer to washing effect, washing function and wash field a variety of demands, have good industrial prospect and
Market value.
Specific embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these exemplary embodiments and
Purpose is only used to enumerate the present invention, not constitutes any type of any restriction to real protection scope of the invention, more non-to incite somebody to action
Protection scope of the present invention is confined to this.
Preparation example 1: the preparation of houttuynia extract
100 g cordate houttuynia dry products are placed in the 1 L ethyl alcohol that mass percent concentration is 60%, are mentioned under 60 W of room temperature ultrasound
2.5 h are taken, it is 1/4 that filtrate, which is concentrated into volume, after filtering, and recycles ethyl alcohol；Then filter residue is added to 500 ml deionized waters
In, 50 DEG C of progress 3 h of second extraction are warming up to, it is 1/4 that filtrate, which is concentrated into volume, after filtering；Finally merge the concentration extracted twice
Liquid obtains houttuynia extract, stay do it is spare.
Preparation example 2: the preparation of dryopteris fragrans extract
The crushing of 50 g dryopteris fragrans cured leafs is placed in Microwave Extraction device, 300 ml deionized waters are added at 65 DEG C and
3 h are extracted under 220 W of microwave power, is filtered after extraction and removes insoluble matter and residue, obtained dryopteris fragrans extract, give over to
It is spare.
Embodiment 1
15 g Cocoamidopropyl betaines, 15 g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonates, the above-mentioned cordate houttuynia of 8 g are extracted
The above-mentioned dryopteris fragrans extract of object, 6 g, 6 g Carbenoxolone Sodiums, the sweet amino proline of 1.5 g methyl, 1 g2- amino -2- second
Base -1- amylalcohol, 1.5 g2- methylbutanoic acids-hex- 5- enester, 4 g fatty acid potassium soaps, 3 g poly-epoxy succinic acids and 8 g water are in 40
Then 20 min of uniform stirring at DEG C is down to room temperature and continues to stir 15 min to get the multi-functional compound washing of the invention
Liquid is named as XD-1.
Embodiment 2
By 20 g Cocoamidopropyl betaines, 10 g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonates, 5 g houttuynia extracts, 8
G dryopteris fragrans extract, 2 g Carbenoxolone Sodiums, the sweet amino proline of 3 g methyl, 2 g 2- amino -2- ethyl -1- amylalcohols, 1
G2- methylbutanoic acid-hex- 5- enester, 2 g fatty acid potassium soaps, 4 g poly-epoxy succinic acids and 10 g the water uniform stirring at 35 DEG C
Then 25 min are down to room temperature and continue to stir 20 min to get the multi-functional compound washing liquid of the invention, are named as XD-
2。
Embodiment 3
10 g Cocoamidopropyl betaines, 15 g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonates, the above-mentioned cordate houttuynia of 10 g are mentioned
Take the above-mentioned dryopteris fragrans extract of object, 5 g, 3 g Carbenoxolone Sodiums, the sweet amino proline of 0.5 g methyl, 2.5 g 2- amino-
2- ethyl -1- amylalcohol, 2.5 g2- methylbutanoic acids-hex- 5- enester, 1 g fatty acid potassium soap, 5 g poly-epoxy succinic acids and 12 g water
Then 30 min of uniform stirring at 30 DEG C is down to room temperature and continues to stir 20 min to get of the invention described multi-functional compound
Cleaning solution is named as XD-3.
Embodiment 4
15 g Cocoamidopropyl betaines, 5 g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonates, the above-mentioned cordate houttuynia of 8 g are extracted
The above-mentioned dryopteris fragrans extract of object, 10 g, 5 g Carbenoxolone Sodiums, the sweet amino proline of 2.5 g methyl, 1.5 g 2- amino -2-
Ethyl -1- amylalcohol, 1 g2- methylbutanoic acid-hex- 5- enester, 4 g fatty acid potassium soaps, 4 g poly-epoxy succinic acids and 8 g water are in 35
Then 30 min of uniform stirring at DEG C is down to room temperature and continues to stir 15 min to get the multi-functional compound washing of the invention
Liquid is named as XD-4.
Comparative example 1-7
Except not being added respectively, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, houttuynia extract, dryopteris fragrans extract, methyl are sweet
Amino proline, 2- amino -2- ethyl -1- amylalcohol, 2-Methyl Butyric Acid-hex- 5- enester, outside poly-epoxy succinic acid, respectively with
Comparative example 1-7 is implemented with the same way of embodiment 1, obtains cleaning solution D1-D7.
Comparative example 8-10
Except respectively with 2- amino-2-methyl -1- hexanol, 2- amino-2-methyl -1- octanol, 2- amino -2- phenyl -1- third
Alcohol replace 2- amino -2- ethyl -1- amylalcohol outside, respectively with embodiment 1 and implement comparative example 8-10, obtain cleaning solution D8-
D10。
Comparative example 11-12
In addition to the 4A zeolite powder that 500 mesh for accounting for poly-epoxy succinic acid quality 1/2 are additionally added, respectively with embodiment 1,
3 same way and implement comparative example 11 and 12, obtain cleaning solution D11 and D12.
Performance test
The test of the performances such as decontamination, sterilization, flavouring to multi-functional compound washing liquid.
1, there is pure and fresh, inducing resuscitation fragrance according to the multi-functional compound washing liquid that the formula is deployed, and fragrance is lasting, allows
People's spiritual happiness dries after impregnating cotton clothing 1 hour, its fragrance retention time is measured by way of physical sensation, sends out
Good fragrance atmosphere can still be maintained after existing 24 h.
2, using QB/T2738-2005 filter paper enzyme measurement cleaning solution to the inhibitory effect of growth of pathogenic bacteria: using sample injector
40 μ L are added dropwise on PDA culture medium, concentration is 1 × 105-6 ml-1Germ suspension after activation, is smoothened with glass sleaker,
Then it is flat diameter to be placed in PDA for 10 mm filter paper 3 (impregnating 0.5 h in the XD-1 cleaning solution of embodiment 1 in advance)
Plate culture medium central, at a distance of 25 mm or more between filter paper center, and with 15 mm or more of the border of plate.With comparative example
The cleaning solution of D1-D10 as a control group, 12-24 h is cultivated in 25 DEG C of insulating boxs, measures the bacterium loop diameter of each processing, ties
Fruit such as table 1.Antibacterial circle diameter changes over time that the results are shown in Table 1.
Table 1
3, clean effect is tested.Uniform spot of the same race is speckled with using the washing of multi-functional compound washing liquid prepared by the present invention
, the identical rectangle band of size, washing methods is as follows: by stained by the uniform spot of the same race, cm of 15 cm × 30
Rectangle band be put in washing machine, the multi-functional compound washing liquid of the present invention of equivalent weight is then added, starts laundry
Machine washs 20 min, then measures its fair and clear degree using whiteness instrument (leucometer).Wherein, using the white of the clean band of test
Cleanliness is averaged three times as standard reference, measurement；Experimental group with 10 soiled cotton items be one group, before testing 5 groups of cleanings respectively
The fair and clear degree of soiled cotton item, measurement be averaged three times；It uses and 5 groups of soiled cotton items is cleaned with above-mentioned identical washing methods,
Then it dries, the fair and clear degree of soiled cotton item after measurement cleaning, measurement is averaged three times.
Soil removal efficiency calculation formula is as follows:
Soil removal efficiency (%)=[(the fair and clear degree of soiled cotton item before the fair and clear degree-cleaning of soiled cotton item after cleaning)/(clean band
Fair and clear degree-cleaning before the fair and clear degree of soiled cotton item)] × 100%.Experimental result is shown in Table 2.
Table 2
4, according to the measurement of GB/T 7462-94 surfactant foaming power, using improvement Ross-Miles method, this hair
The foam of bright multi-functional compound washing liquid is significantly lower than commercial product, rinses 1 time.
5, fluffy degree test experiments.Towel is divided into several groups, every group 3, a certain amount of cleaning solution is respectively taken, is separately added into 2
L tap water is dispersed with stirring uniformly, each sample dispersion liquid is injected in 5 L beakers, each group towel is then respectively enterd each beaker
In, 5 min are soaked completely, then take out naturally dry.By the doubling twice of every piece of towel, every group of height, note are measured with graduated scale
It records and compares its height, as a result such as table 3.
Table 3
| Group | Additive amount (g) | Stack height (cm) |
| New towel control group is not washed | -- | 9.8 |
| XD-1 | 10 | 9.1 |
| XD-2 | 10 | 8.8 |
| XD-3 | 10 | 9.0 |
| XD-4 | 10 | 8.9 |
| D1-D10 | 10 | 6.5-7.9 |
| D11 | 10 | 9.2 |
| D12 | 10 | 9.3 |
(1) by above-mentioned table 1-3 it is found that multi-functional compound washing liquid of the invention has excellent sterilization, decontamination, submissive
Performance, and when lacking certain necessary components or group lease making partial replacement, then its corresponding effect reduces to a certain extent, and
And when adding appropriate 4A zeolite, additionally it is possible to further improve its various performance, it is seen that the specific combination and ratio of component are selected
It selects and produces unexpected synergistic effect.
(2) multi-functional compound washing liquid of the invention is in addition to having above-mentioned function, also shows persistently to keep fragrance and low
The characteristics of spumescence, hence it is evident that be better than commercial product, rinsing times are few, greatly save water consumption.
In summary, the present invention uses the Cocoamidopropyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, fish raw meat
Careless extract, dryopteris fragrans extract, Carbenoxolone Sodium, the sweet amino proline of methyl, 2- amino -2- ethyl -1- amylalcohol, 2- first
The component collaboration of base butyric acid-hex- 5- enester, fatty acid potassium soap, poly-epoxy succinic acid and water plays a role, with good anti-
The excellent properties such as bacterium, decontamination, soft and smooth, flavouring and low bubble, and when changing any one such component or component and replacing, then it corresponds to
Effect all will even first mate reduce, and when be added certain particle size 4A zeolite powder when, can further improve it
Performance.The cleaning solution has both multi-efficiency, sufficiently meets the consumption demand of people, has vast market prospect.
It should be appreciated that the purposes of these embodiments is merely to illustrate the present invention and is not intended to limit protection model of the invention
It encloses.In addition, it should also be understood that, after reading the technical contents of the present invention, those skilled in the art can make the present invention each
Kind change, modification and/or variation, all these equivalent forms equally fall within guarantor defined by the application the appended claims
Within the scope of shield.
Claims (4)
1. a kind of multi-functional compound washing liquid, the cleaning solution includes Cocoamidopropyl betaine, dodecyl diphenyl oxide two
Sodium sulfonate, houttuynia extract, dryopteris fragrans extract, Carbenoxolone Sodium, the sweet amino proline of methyl, 2- amino -2- ethyl -
1- amylalcohol, 2-Methyl Butyric Acid-hex- 5- enester, fatty acid potassium soap, poly-epoxy succinic acid, water and 500 mesh 4A zeolite powder；
In parts by weight, concrete component content is as follows:
The 4A zeolite powder content of 500 mesh is the 1/2 of poly-epoxy succinic acid quality；
The houttuynia extract uses following steps to prepare: cordate houttuynia dry product is placed in mass percent concentration as 50-60%
Ethyl alcohol in, 2-3h is extracted under ultrasonic power 60W at room temperature, filtrate is concentrated into the 1/4 of volume after filtering, and recycles ethyl alcohol；So
Filter residue is add to deionized water afterwards, is warming up to 40-50 DEG C of progress second extraction 2-3h, filtrate is concentrated into volume and is after filtering
1/4；Finally merge the concentrate extracted twice and obtains houttuynia extract；Wherein, the matter of cordate houttuynia dry product and the ethyl alcohol, water
Measuring volume ratio is 1:5-10g/ml；
The dryopteris fragrans extract is prepared using following steps: the crushing of dryopteris fragrans cured leaf is placed in Microwave Extraction device,
Deionized water is added and extracts 2-4h under 60-70 DEG C and microwave power 220W, is filtered after extraction and removes insoluble matter and residue,
Obtain dryopteris fragrans extract；Wherein, dryopteris fragrans cured leaf and the mass volume ratio of deionized water are 1:4-6g/ml.
2. multi-functional compound washing liquid as described in claim 1, it is characterised in that: in parts by weight, concrete component content
It is as follows:
The 4A zeolite powder content of 500 mesh is the 1/2 of poly-epoxy succinic acid quality.
3. such as the preparation method of the described in any item multi-functional compound washing liquid of claim 1-2, it is characterised in that: according to above-mentioned
Weight ratio mentions Cocoamidopropyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, houttuynia extract, dryopteris fragrans
Take the sweet amino proline of object, Carbenoxolone Sodium, methyl, 2- amino -2- ethyl -1- amylalcohol, 2-Methyl Butyric Acid-hex- 5- enester, rouge
Fat acid potash soap, poly-epoxy succinic acid, water and 500 mesh 4A zeolite powder at 30-40 DEG C uniform stirring 20-30min, then drop
Continue to stir 15-20min to room temperature to get the multi-functional compound washing liquid.
4. as the described in any item multi-functional compound washing liquid of claim 1-2 are used to clean the purposes of fabric, fruit, tableware.
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| CN108048245A (en) * | 2017-12-25 | 2018-05-18 | 上海和黄白猫有限公司 | Natural concentrated type foam tableware detergent |
| CN110664632A (en) * | 2019-10-28 | 2020-01-10 | 东北农业大学 | Antibacterial hand sanitizer containing dryopteris fragrans extract and preparation method thereof |
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| CN101514308A (en) * | 2009-03-19 | 2009-08-26 | 同济大学 | Environmental friendly synthetic detergent taking poly epoxy succinic acid as washing assistant |
| CN102026541A (en) * | 2008-05-15 | 2011-04-20 | 安格斯化学公司 | Improved corrosion and microbial control in hydrocarbonaceous compositions |
| CN102766538A (en) * | 2012-07-27 | 2012-11-07 | 宁波御坊堂生物科技有限公司 | Edible detergent and preparation method thereof |
| CN104178372A (en) * | 2014-09-02 | 2014-12-03 | 宁波镇海祺高清洁制品有限公司 | Environment-friendly cleanout fluid |
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|---|---|---|---|---|
| CN102026541A (en) * | 2008-05-15 | 2011-04-20 | 安格斯化学公司 | Improved corrosion and microbial control in hydrocarbonaceous compositions |
| CN101514308A (en) * | 2009-03-19 | 2009-08-26 | 同济大学 | Environmental friendly synthetic detergent taking poly epoxy succinic acid as washing assistant |
| CN102766538A (en) * | 2012-07-27 | 2012-11-07 | 宁波御坊堂生物科技有限公司 | Edible detergent and preparation method thereof |
| CN104178372A (en) * | 2014-09-02 | 2014-12-03 | 宁波镇海祺高清洁制品有限公司 | Environment-friendly cleanout fluid |
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