A kind of multi-functional compound washing liquid and its production and use
Technical field
The present invention relates to a kind of cleaning mixture, relate more specifically to a kind of multi-functional compound washing liquid having antibacterial, decontamination, the effect such as soft and smooth concurrently, belong to filed of daily-use chemical industry.
Background technology
The progress of expanding economy and science and technology has not only promoted growth in the living standard, and the thing followed also has serious pollution and dust, for instance varieties of food items, oil smoke, additive etc..For this, requirement clean and tidy, health is also generally being improved by people.Especially for the cosmetics of everyday use of washing, people not only require that it possesses efficient dirt-removing power, and require that articles for washing possesses many performances such as skin irritation is little, lasting fragrance, fabric are submissive and safe and healthy.Additionally, people pay close attention to the universality of detergent in the also moment, for instance medicated clothing, kitchen cleaning, vegetable and fruit, and the article washing of various occasion, the great-leap-forward development that the raising of pervasive performance will promote detergent effectively, better meet the demand of people.
In order to make articles for washing reach higher clean result and have multiple performance concurrently, people concentrate on studies and are prepared for multiple detergent, such as petrochemical industry detergent, plant detergent, marine organisms detergent and multi-functional composite detergent etc..Existing many reports in prior art, for instance:
The patent application of CN101311257A discloses a kind of liquid multienzyme detergent, and it includes a certain proportion of surfactant, triethanolamine, ethanol, sodium silicate, ethyl hydroxybenzoate, protease, amylase, cellulase, lipase and water.This product stability is good.Decomposing organic matter ability is strong, namely dilute is easy to use.
The patent application of CN1667109A discloses a kind of food detergent containing ocean active matters, it is by a certain proportion of seawater bittern extract, sodium bicarbonate and food additive is composite forms, can be used for scrubbing water fruits and vegetables etc., effectively remove raw meat, the abnormal flavour such as smelly and ensure food safety.
A kind of non-phosphate detergent of the patent applications report of CN102115696A, it adopts the dodecylbenzene sodium sulfonate of special ratios, oxidised maize starch, fatty alcohol-polyoxyethylene ether, cocoanut oil diethan olamide, polyoxyethylenated alcohol sodium sulfate, triethanolamine, sodium silicate, additive and water formulated, solve the environmental issue that phosphorus pollutes, decrease the detergent infringement to skin, and reduce production cost.
The patent application of CN102978027A discloses a kind of Fruit detergent, and it is made up of the raw material of following components: glycerol list certain herbaceous plants with big flowers acid esters, Oleum Cocois, six polyglycerol monooleate, enuatrol, essence, water and lauric acid amide of ethanol.This detergent can effectively wash away the worm's ovum of fruit surface attachment, compensate for the deficiency of general detergent.
But, prior art yet suffers from many defects, for instance wash water amount is big, medicated clothing damage is big, fragrance is lasting not, shortage MULTIPLE COMPOSITE effect, universality are poor, etc..It is thus desirable to provide a kind of have high-efficiency cleaning ability, easily rinsing, simultaneously opposite material temperature and, the liquid detergent of low stimulation.
For the defect existed in prior art, it is contemplated that a kind of MULTIPLE COMPOSITE effect detergent compositions of research and development, appropriately selected by the particular combination of component and material ratio, and make this detergent compositions show the soft and smooth performance of efficient detergency ability, fabric, and lasting fragrance, have multiple efficacies concurrently, especially meet the growing material of consumer and spiritual demand, there is industrial applications prospect and market value widely.
Summary of the invention
In order to prepare the nano composite dope of heat-resistant, wear-resistant, this is conducted in-depth research by the present inventor, having paid substantial amounts of creative work and after further investigation is explored, thus completing the present invention.
Specifically, the invention mainly relates to three aspects.
First aspect, the present invention relates to a kind of multi-functional compound washing liquid, described cleaning mixture includes cocamido propyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, Herba Houttuyniae extract, Dryopteris fragrans (L.) Schott extract, sodium glycyrrhetate, amimethylglycine, 2-amino-2-ethyl-1-amylalcohol, 2-Methyl Butyric Acid-own-5-alkene ester, fatty acid potassium soap, poly-epoxy succinic acid and water.
In described cleaning mixture, with parts by weight, its concrete constituent content is as follows:
In the described cleaning mixture of the present invention, with parts by weight, its concrete component preferred content is as follows:
Cocamido propyl betaine |
10-20 |
Disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate |
5-15 |
Herba Houttuyniae extract |
5-10 |
Dryopteris fragrans (L.) Schott extract |
5-10 |
Sodium glycyrrhetate |
2-6 |
Amimethylglycine |
0.5-3 |
2-amino-2-ethyl-1-amylalcohol |
0.5-2.5 |
2-Methyl Butyric Acid-own-5-alkene ester |
0.5-2.5 |
Fatty acid potassium soap |
1-5 |
Poly-epoxy succinic acid |
1-5 |
Water |
5-12。 |
In the described cleaning mixture of the present invention, the parts by weight of cocamido propyl betaine are preferably 10-20 part, as 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts.
In the described cleaning mixture of the present invention, the parts by weight of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate are preferably 5-15 part, as 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts.
In the described cleaning mixture of the present invention, the parts by weight of Herba Houttuyniae extract are preferably 5-10 part, as 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts.
In the described cleaning mixture of the present invention, the parts by weight of Dryopteris fragrans (L.) Schott extract are preferably 5-10 part, as 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts.
In the described cleaning mixture of the present invention, the parts by weight of sodium glycyrrhetate are preferably 2-6 part, as being 1 part, 2 parts, 3 parts, 4 parts, 5 parts or 6 parts.
In the described cleaning mixture of the present invention, the parts by weight of amimethylglycine are preferably 0.5-3 part, as being 0.5 part, 1.5 parts, 2 parts, 2.5 parts or 3 parts.
In the described cleaning mixture of the present invention, the parts by weight of 2-amino-2-ethyl-1-amylalcohol are preferably 0.5-2.5 part, as being 0.5 part, 1 part, 1.5 parts, 2 parts or 2.5 parts.
In the described cleaning mixture of the present invention, the parts by weight of 2-Methyl Butyric Acid-oneself-5-alkene ester are preferably 0.5-2.5 part, as 0.5 part, 1 part, 1.5 parts, 2 parts or 2.5 parts.
In the described cleaning mixture of the present invention, the parts by weight of fatty acid potassium soap are preferably 1-5 part, as 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
In the described cleaning mixture of the present invention, the parts by weight of poly-epoxy succinic acid are preferably 1-5 part, as 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
In the described cleaning mixture of the present invention, the parts by weight of water are preferably 5-12 part, as 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts or 12 parts.
The poly-epoxy succinic acid of the present invention can be any known poly-epoxy succinic acid, for instance the poly-epoxy succinic acid adopted in an embodiment is a cube board/model is the poly-epoxy succinic acid of LF-203;The fatty acid potassium soap of the present invention is any known fatty acid potassium soap, for instance the fatty acid potassium soap adopted in an embodiment is the fatty acid potassium soap that model is DX-918 of east, Guangdong city hero Chemical Manufacture.
Additionally, the 4A zeolite powder of 500 orders of poly-epoxy succinic acid quality 1/2 also can be incorporated as in described cleaning mixture.
Second aspect, the preparation method that the present invention relates to above-mentioned multi-functional compound washing liquid, specific as follows: according to above-mentioned part by weight, by cocamido propyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, Herba Houttuyniae extract, Dryopteris fragrans (L.) Schott extract, sodium glycyrrhetate, amimethylglycine, 2-amino-2-ethyl-1-amylalcohol, 2-Methyl Butyric Acid-own-5-alkene ester, fatty acid potassium soap, poly-epoxy succinic acid and water uniform stirring 20-30min at 30-40 DEG C, then it is down to room temperature and continues stirring 15-20min, obtain the described multi-functional compound washing liquid of the present invention.
In the described cleaning mixture of the present invention, Herba Houttuyniae extract adopts following steps to prepare:
Being placed in by Herba Houttuyniae dry product in the ethanol that mass percent concentration is 50-60%, extract 2-3h under room temperature ultrasonic power 60W, after filtration, filtrate is concentrated into volume is 1/4, and reclaims ethanol;Then joining in deionized water by filtering residue, be warming up to 40-50 DEG C and carry out second extraction 2-3h, after filtration, filtrate is concentrated into volume is 1/4;The concentrated solution finally merging twice extraction obtains Herba Houttuyniae extract, stay do standby.Wherein, Herba Houttuyniae dry product is 1:5-10g/ml with the mass volume ratio of ethanol, water.
In the described cleaning mixture of the present invention, Dryopteris fragrans (L.) Schott extract adopts following steps to prepare:
Being pulverized by Dryopteris fragrans (L.) Schott cured leaf and be placed in microwave extraction device, add deionized water and extract 2-4h under 60-70 DEG C and microwave power 220W, after extraction, sucking filtration removes insoluble matter and residue, obtains Dryopteris fragrans (L.) Schott extract, gives over to standby.Wherein, Dryopteris fragrans (L.) Schott cured leaf is 1:4-6g/ml with the mass volume ratio of deionized water.
3rd aspect, the present invention relates to above-mentioned multi-functional compound washing liquid for cleaning the purposes of fabric, fruit, tableware.
Compared with prior art, the multi-functional compound washing liquid of the present invention is selected by appropriate combination and the ratio of functional component, and achieve significant synergy unexpectedly, there is efficient decontamination, sterilization, flavouring, the soft and smooth performance of fabric, meet the consumer's multiple demand to clean result, washing function and washing field, there is good industrial prospect and market value.
Detailed description of the invention
Below by specific embodiment, the present invention is described in detail; but the purposes of these exemplary embodiments and purpose are only used for enumerating the present invention; not the real protection scope of the present invention is constituted any type of any restriction, more non-protection scope of the present invention is limited thereto.
Preparation example 1: the preparation of Herba Houttuyniae extract
Being placed in by 100g Herba Houttuyniae dry product in the 1L ethanol that mass percent concentration is 60%, extract 2.5h under the ultrasonic 60W of room temperature, after filtration, filtrate is concentrated into volume is 1/4, and reclaims ethanol;Then being joined in 500ml deionized water by filtering residue, be warming up to 50 DEG C and carry out second extraction 3h, after filtration, filtrate is concentrated into volume is 1/4;The concentrated solution finally merging twice extraction obtains Herba Houttuyniae extract, stay do standby.
Preparation example 2: the preparation of Dryopteris fragrans (L.) Schott extract
Being pulverized by 50g Dryopteris fragrans (L.) Schott cured leaf and be placed in microwave extraction device, add 300ml deionized water and extract 3h at 65 DEG C and under microwave power 220W, after extraction, sucking filtration removes insoluble matter and residue, obtains Dryopteris fragrans (L.) Schott extract, gives over to standby.
Embodiment 1
By 15g cocamido propyl betaine, 15g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, the above-mentioned Herba Houttuyniae extract of 8g, the above-mentioned Dryopteris fragrans (L.) Schott extract of 6g, 6g sodium glycyrrhetate, 1.5g amimethylglycine, 1g2-amino-2-ethyl-1-amylalcohol, 1.5g2-methylbutanoic acid-own-5-alkene ester, 4g fatty acid potassium soap, 3g poly-epoxy succinic acid and 8g water uniform stirring 20min at 40 DEG C, then it is down to room temperature and continues stirring 15min, obtain the described multi-functional compound washing liquid of the present invention, called after XD-1.
Embodiment 2
By 20g cocamido propyl betaine, 10g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 5g Herba Houttuyniae extract, 8g Dryopteris fragrans (L.) Schott extract, 2g sodium glycyrrhetate, 3g amimethylglycine, 2g2-amino-2-ethyl-1-amylalcohol, 1g2-methylbutanoic acid-own-5-alkene ester, 2g fatty acid potassium soap, 4g poly-epoxy succinic acid and 10g water uniform stirring 25min at 35 DEG C, then it is down to room temperature and continues stirring 20min, obtain the described multi-functional compound washing liquid of the present invention, called after XD-2.
Embodiment 3
By 10g cocamido propyl betaine, 15g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, the above-mentioned Herba Houttuyniae extract of 10g, the above-mentioned Dryopteris fragrans (L.) Schott extract of 5g, 3g sodium glycyrrhetate, 0.5g amimethylglycine, 2.5g2-amino-2-ethyl-1-amylalcohol, 2.5g2-methylbutanoic acid-own-5-alkene ester, 1g fatty acid potassium soap, 5g poly-epoxy succinic acid and 12g water uniform stirring 30min at 30 DEG C, then it is down to room temperature and continues stirring 20min, obtain the described multi-functional compound washing liquid of the present invention, called after XD-3.
Embodiment 4
By 15g cocamido propyl betaine, 5g disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, the above-mentioned Herba Houttuyniae extract of 8g, the above-mentioned Dryopteris fragrans (L.) Schott extract of 10g, 5g sodium glycyrrhetate, 2.5g amimethylglycine, 1.5g2-amino-2-ethyl-1-amylalcohol, 1g2-methylbutanoic acid-own-5-alkene ester, 4g fatty acid potassium soap, 4g poly-epoxy succinic acid and 8g water uniform stirring 30min at 35 DEG C, then it is down to room temperature and continues stirring 15min, obtain the described multi-functional compound washing liquid of the present invention, called after XD-4.
Comparative example 1-7
Except not adding disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, Herba Houttuyniae extract, Dryopteris fragrans (L.) Schott extract, amimethylglycine, 2-amino-2-ethyl-1-amylalcohol, 2-Methyl Butyric Acid-oneself-5-alkene ester, poly-epoxy succinic acid respectively, implement comparative example 1-7 with the same way with embodiment 1 respectively, obtain cleaning mixture D1-D7.
Comparative example 8-10
Except replacing except 2-amino-2-ethyl-1-amylalcohol with 2-amino-2-methyl-1-hexanol, 2-amino-2-methyl-1-capryl alcohol, 2-amino-2-phenyl-1-propanol respectively, respectively with embodiment 1 and implement comparative example 8-10, obtain cleaning mixture D8-D10.
Comparative example 11-12
Except the extra 4A zeolite powder of 500 orders adding and accounting for poly-epoxy succinic acid quality 1/2, implement comparative example 11 and 12 with the same way with embodiment 1,3 respectively, obtain cleaning mixture D11 and D12.
Performance test
Test to performances such as the decontamination of multi-functional compound washing liquid, sterilization, flavourings.
1, the multi-functional compound washing liquid allocated according to this formula has fragrance pure and fresh, refreshment, and fragrance is lasting, allow people's spiritual happiness, after cotton medicated clothing is soaked 1 hour, dry, its fragrance retention time is measured, it has been found that after 24h, be maintained to good fragrance atmosphere by the mode of physical sensation.
2, utilize QB/T2738-2005 filter paper enzyme measure the cleaning mixture inhibition to growth of pathogenic bacteria: with sample injector in PDA culture medium, drip 40 μ L, concentration is 1 × 105-6ml-1Pathogenic bacteria suspension after activation, smoothen with glass sleaker, then it is that 10mm filter paper 3 (in advance in the XD-1 cleaning mixture of embodiment 1 soak 0.5h) is placed in PDA plate culture medium central authorities by diameter, at a distance of more than 25mm between filter paper center, and with more than the border 15mm of flat board.With the cleaning mixture of comparative example D1-D10 as a control group, cultivating 12-24h, measure the bacterium loop diameter of each process in 25 DEG C of calorstats, result is table 1 such as.The time dependent result of antibacterial circle diameter is as shown in table 1.
Table 1
3, clean effect test.The washing of the multi-functional compound washing liquid prepared by the present invention is used to speckle with rectangle band uniform spot of the same race, equivalently-sized, washing methods is as follows: be put in washing machine by rectangle band that stained by uniform spot of the same race, 15cm × 30cm, it is subsequently adding the multi-functional compound washing liquid of the present invention of equivalent weight, start washing machine, washing 20min, then uses whiteness instrument (leucometer) to measure its fair and clear degree.Wherein, adopt the fair and clear degree testing clean band as standard reference, measure and average for three times;Experimental group, with 10 soiled cotton bars for one group, is tested the fair and clear degree of soiled cotton bar before 5 groups of cleanings respectively, is measured and average for three times;Adopt and with above-mentioned identical washing methods, 5 groups of soiled cotton bars are carried out, then dry, measure the fair and clear degree of soiled cotton bar after cleaning, measure and average for three times.
Soil removal efficiency computing formula is as follows:
Soil removal efficiency (%)=[(the fair and clear degree of soiled cotton bar before the fair and clear degree-cleaning of soiled cotton bar after cleaning)/(the fair and clear degree of soiled cotton bar before the fair and clear degree-cleaning of clean band)] × 100%.Experimental result is in Table 2.
Table 2
4, the mensuration according to GB/T7462-94 surfactant foaming power, adopts and improves Ross-Miles method, and the foam of the multi-functional compound washing liquid of the present invention, significantly lower than commercially available prod, rinses 1 time.
5, loft test experiments.Towel is divided into some groups, and often group 3, respectively takes a certain amount of cleaning mixture, is separately added into 2L tap water, and dispersed with stirring is uniform, is injected in 5L beaker by each sample dispersion liquid, then respectively enters in each beaker by each group of towel, soak 5min completely, then take out nature and dry.By twice doubling of every piece of towel, measuring with rule and often organize height, record and compare its height, result is table 3 such as.
Table 3
Group |
Addition (g) |
Stack height (cm) |
Do not wash new towel matched group |
-- |
9.8 |
XD-1 |
10 |
9.1 |
XD-2 |
10 |
8.8 |
XD-3 |
10 |
9.0 |
XD-4 |
10 |
8.9 |
D1-D10 |
10 |
6.5-7.9 |
D11 |
10 |
9.2 |
D12 |
10 |
9.3 |
(1) from above-mentioned table 1-3, the multi-functional compound washing liquid of the present invention has the sterilization of excellence, decontamination, submissive performance, and when lacking some necessary component or component through partial replacement, then its corresponding effect reduces to a certain extent, and when adding appropriate 4A zeolite, its various performances can also be improved further, it is seen that the particular combination of component and ratio select to create unexpected synergism.
(2) the multi-functional compound washing liquid of the present invention is except possessing above-mentioned functions, also shows the feature persistently keeping fragrance and low spumescence, hence it is evident that being better than commercially available prod, its rinsing times is few, is greatly saved water consumption.
Summary, the present invention adopts described cocamido propyl betaine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, Herba Houttuyniae extract, Dryopteris fragrans (L.) Schott extract, sodium glycyrrhetate, amimethylglycine, 2-amino-2-ethyl-1-amylalcohol, 2-Methyl Butyric Acid-own-5-alkene ester, fatty acid potassium soap, the component of poly-epoxy succinic acid and water is collaborative to play a role, it has good antibacterial, decontamination, soft and smooth, the excellent properties such as flavouring and low bubble, and when changing any a kind of component therein or component replacement, then corresponding effect all will to some extent or even first mate's reduction, and when adding the 4A zeolite powder of certain particle size, its performance can be improved further.This cleaning mixture has multi-efficiency concurrently, fully meets the consumption demand of people, possesses wide market prospect.
Should be appreciated that the purposes of these embodiments is merely to illustrate the present invention and is not intended to limit the scope of the invention.In addition; it is also contemplated that; after the technology contents having read the present invention, the present invention can be made various change, amendment and/or modification by those skilled in the art, and all these equivalent form of value falls within the application appended claims protection defined equally.