CN105695157B - A kind of environment-friendly liquid cleansing composition - Google Patents
A kind of environment-friendly liquid cleansing composition Download PDFInfo
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- CN105695157B CN105695157B CN201610100838.7A CN201610100838A CN105695157B CN 105695157 B CN105695157 B CN 105695157B CN 201610100838 A CN201610100838 A CN 201610100838A CN 105695157 B CN105695157 B CN 105695157B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/381—Microorganisms
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Abstract
The invention discloses a kind of environment-friendly liquid cleansing compositions, include the raw material of following parts by weight, the polyoxyethylene-type anion surfactant of 1~5 parts by weight, the betaine type amphoteric ionic surface active agent of 1~8 parts by weight, the biosurfactant of 5~10 parts by weight, the cyclo-dextrin-modified polyethylene glycol of 1~5 parts by weight, 1~3 parts by weight chelating agent and 100 parts by weight water.It is environment-friendly liquid cleansing composition clean environment firendly disclosed by the invention, nontoxic and there is higher clean rate.
Description
Technical field
The invention belongs to field of fine chemical, are related to a kind of liquid ceanser, more particularly it relates to which one kind is used for
The environment-friendly liquid cleaning agent of fabric washing.
Background technology
Liquid ceanser is household in people's daily life, household, the essential articles for washing of personal hygiene, main use
To clean clothing, removing dirt.There are oily dirt, solids foul and some special dirts, including animals and plants in common dirt
Grease, soil, dust, iron rust, flue dust, sweat, blood etc..Wherein, liquid ceanser is compared with solid cleaner such as washing powder,
It has it is easy to use, using it is preceding without dissolving, cold washing effect it is good, system alkalinity is low, milder to fabric and skin,
The advantage that environmental pollution is few and processing cost is low.Currently, liquid ceanser product has become developed country's detergent industry
The direction of development becomes product with fastest developing speed in various cleaning agent articles for use, clear for the second major class for being only second to detergent powder
Lotion product.
Current commercial liquid ceanser product, because containing harmful chemical substance in most products therein, to human body and
Environment causes damages, and so that product is not met the requirement of environmental protection, these cause the extensive concern of people and attention already.To human body and
The harmful chemical that environment causes damages, for example, neopelex, since neopelex is petroleum base
Surfactant, upstream raw material are alkylbenzenes, the cleaning agent made of this chemical substance containing benzene be used for wash clothing or
After gourd, fruit and vegetable, which contacts human skin, is absorbed by human skin, and long-time service can cause the nervous system of people
Harm；Sodium tripolyphosphate is the hard water resistance performance for improving neopelex, still, excessive use tripolyphosphate
Sodium can cause the influence of body eutrophication worsening environment, in recent years, world many countries, area and China
Phosphorus and disabling phosphorus measure all are limited the use of to articles for washing implementation to some extent.
Hence it is highly desirable to by the improvement of formula and processing technology, to develop a kind of environment-friendly liquid cleaning agent.
Invention content
In order to solve the above-mentioned problems of the prior art, the present invention provides a kind of liquid ceanser compositions, including
Each material component of following mass percent：
The polyoxyethylene-type anion surfactant of 1~5 parts by weight；
The betaine type amphoteric ionic surface active agent of 1~8 parts by weight；
The biosurfactant of 3~10 parts by weight；
The cyclo-dextrin-modified polyethylene glycol of 1~5 parts by weight；
The chelating agent of 1~3 parts by weight；With
The water of 100 parts by weight；
The biosurfactant is fatty alcohol modified rhamnose；
The chelating agent is the compound including at least two carboxyls；
The cyclo-dextrin-modified polyethylene glycol is that cyclodextrin penetrates peg molecule chain formation compound.
In a preferred embodiment, the structural formula of the polyoxyethylene-type anion surfactant is：
Wherein, the R in formula1Can be H or C1~C6Alkane, R2Can be C4~C20Alkane, R3Can be sulfuric acid
Any one in salt, sulfonate or carboxylate, n are 1~15.
In one embodiment, the biosurfactant has the following structure formula：
The combination of middle one or more structure；Wherein, R1、R2For H, C3~C20Alkane in any one, R1、
R2It is asynchronously H.
In a preferred embodiment, the biosurfactant has the following structure formula：
Wherein, R1、R2For H or C12~C20Alkane in any one, R1、R2It is asynchronously H.
In a preferred embodiment, in the cyclo-dextrin-modified polyethylene glycol, cyclodextrin and polyethylene glycol rub
That ratio 1：10.
In a preferred embodiment, the number-average molecular weight 500~2000 of the polyethylene glycol.
In a preferred embodiment, the cyclodextrin is alpha-cyclodextrin, beta-cyclodextrin, 6-O- α-D-Maltose
Any one in group-beta-cyclodextrin, gamma-cyclodextrin.
In a preferred embodiment, the chelating agent is selected from：Hyaluronic acid, chitosan, citric acid, tartaric acid,
Any one in glucaric acid.
In a preferred embodiment, it further includes the pH adjusting agent of 0.5~2 parts by weight, and the pH adjusting agent is
Lactic acid.
In a preferred embodiment, it further includes the viscosity modifier of 0.5~1 parts by weight, the viscosity-adjusting agent
Agent is sodium chloride.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to following detailed description.
Specific implementation mode
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with fields of the present invention
The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements
Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or
Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this
Phrase will make claim be closed, so that it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body,
It is only limited to the element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this, which should be understood as, specifically discloses by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise range intention includes its end
Value and all integers and score in the range.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " arbitrary
It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to indicate that the present invention is not limited to this
Quantity further includes the modified part of the acceptable change without lead to related basic function close to the quantity.Phase
It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, range limits can be with
Combination and/or exchange, these ranges include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component
(i.e. occurrence number) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number
The element or component of form also include plural form, unless the apparent purport of the quantity refers to singulative.
The present invention provides a kind of environment-friendly liquid cleansing compositions, include each raw material group of following mass percent
Part：
The polyoxyethylene-type anion surfactant of 1~5 parts by weight；
The betaine type amphoteric ionic surface active agent of 1~8 parts by weight；
The biosurfactant of 3~10 parts by weight；
The cyclo-dextrin-modified polyethylene glycol of 1~5 parts by weight；
The chelating agent of 1~3 parts by weight；With
The water of 100 parts by weight；
The biosurfactant is fatty alcohol modified rhamnose；
The cyclo-dextrin-modified polyethylene glycol is that cyclodextrin penetrates peg molecule chain formation compound；
The chelating agent is the compound including at least two carboxyls.
Polyoxyethylene-type anion surfactant：
In the present invention, there is no other special limitations for the polyoxyethylene-type anion surfactant.
The polyoxyethylene-type anion surfactant has the following structure formula：
Wherein, the R in formula1Can be H or C1~C6Alkane, R2Can be C4~C20Alkane
Hydrocarbon, R3Can be any one in sulfate, sulfonate or carboxylate, n is 1~15.
In some preferred embodiments, the polyoxyethylene-type anion surfactant has the following structure
Formula：
Wherein, the R in formula1Can be C4~C6Alkane, R2Can be C10~C18Alkane, R3For carboxylate, n is 5~
12。
In a preferred embodiment, the polyoxyethylene-type anion surfactant has the following structure
Formula：
Wherein, the R in formula1Can be C6Alkane, R2Can be C12Alkane, R3For carboxylate, n 7.
Betaine type amphoteric ionic surface active agent：
In the present invention, there is no other special limitations for the betaine type amphoteric ionic surface active agent, can be carboxylic
Base betaine type amphoteric ionic surface active agent；Or sulfobetaine type zwitterionic surfactant etc..
The betaine type carboxylic acid type zwitterionic surfactant can be：Cocoamidopropyl betaine, cocoyl
Glycine betaine, coco dimethyl carboxymethyl glycine betaine, dodecyl dimethyl carboxymethyl betaine, dodecyl dimethyl α-carboxylic
Bis- (2- ethoxys) carboxymethyl betaines of ethyl glycine betaine, cetyl dimethyl carboxymethyl glycine betaine, dodecyl, octadecyl
Bis- (2- hydroxypropyls) α-carboxylic second of bis- (2- hydroxypropyls) carboxymethyl betaines, oleyl alcohol dimethyl gamma-carboxypropyl glycine betaine, dodecyl
Base glycine betaine, cocoyl dimethyl sulfopropyl betaine, octadecyldimethyl azochlorosulfonate propyl lycine, coconut oleoyl amine dimethyl carboxylic
Methyl betaine, coconut oleoyl amine dimethyl sulfopropyl betaine, laurylamide dimethyl carboxymethyl betaine, cetyl acyl
One or more combinations in amine dimethyl carboxymethyl betaine, octadecyl amide dimethyl sulfopropyl betaine etc..
In a preferred embodiment, the betaine type amphoteric ionic surface active agent is selected from：Coconut oleoyl amine third
One or more combinations in base glycine betaine, coco betaine.
The sulfobetaine type zwitterionic surfactant can be：Cocamidopropyl propyl amide hydroxyl sulfo betaine,
Coco-Hydroxysultaine, cocoyl sulfobetaines, erucyl amide hydroxysultaine, weight ratio beet
Alkali, dodecanamide propyl hydroxy sulfo lycine, dodecyl hydroxyl sulfo betaine, dodecyl dimethyl sulfobetaines,
Myristamide hydroxysultaine, oleamide propyl (weight ratio) propyl-dimethyl ammonium, tallow amidoethyl propyl hydroxyl
One or more combinations in base sulfobetaines etc..
In a preferred embodiment, the betaine type amphoteric ionic surface active agent is selected from：Coconut oleoyl amine third
One or more combinations in base hydroxyl sulfo betaine, dodecanamide propyl hydroxy sulfo lycine.
Biosurfactant：
Biosurfactant is a kind of by Microbe synthesis, the surface reactive material of various structures, including glycolipid, fat
Skin, lipoprotein, phosphatide and neutral lipid derivative etc..Currently, most surfaces activating agent is all chemical synthesis in the market,
However, will produce serious problem of environmental pollution using chemical surfactant.Biosurfactant is with toxicity is low, can give birth to
Object is degraded, and good biocompatibility.
In one embodiment, the biosurfactant has the following structure formula：
In one or more combinations；
Wherein, R1、R2It may be the same or different, R1、R2Can be H or C3~C20Alkane in it is any one
Kind.
It is preferably carried out in mode in one kind, the biosurfactant has the following structure formula：
Wherein, R1、R2For H, C12~C20Alkane in any one, R1、R2It is asynchronously H.
In the present invention, the biosurfactant is made for fatty alcohol modified rhamnose.
Heretofore described " rhamnose " is a kind of by pseudomonas aeruginosa (Pseudomonas aeruginosa) point
The Glycolipids Biosurfactantss secreted, it not only have can with possessed by chemical surfactant solubilising, emulsification, wetting,
The performances such as foaming, and with low toxicity, the characteristics such as be readily biodegradable, be environmentally friendly, thus in oil development, medicine, food
The fields such as product, daily use chemicals, environmental protection have prodigious application potential.
Heretofore described " rhamnose " is not particularly limited, can be by being commercially available, or ability
What the blanking method known to field technique personnel synthesized.
The rhamnose has the following structure formula：
In the present invention, the fatty alcohol is not particularly limited, and commercially available acquisition can also pass through art technology
A blanking method known to personnel obtains.
In one embodiment, the fatty alcohol has the following structure formula：R-OH；
Preferably, R is the alkane that carbon atom number is 1~20；It is further preferred that the straight chain that it is 8~15 that R, which is carbon atom number,
Alkane.
In the present invention, the preparation method of the biosurfactant may be used Koenings-Khorr reactions and prepare
Method, Enzyme catalyzed synthesis method, acetylation alcoholysis method, sugar Betamethasone Ketal structures alcoholysis method, direct glucosides method and turn glucosides method.Due to directly sugared
Glycosides method have technological process is short, low energy consumption, easy to operate and cost is few, production process need not carry out under explosion-proof environment, instead
Answer procedure parameter control stringenter, products obtained therefrom is high-quality, lighter color and the advantages that odorlessness, in the present invention, with direct glucosides
For method.
The preparation method of the biosurfactant is：
It is 1 by molar ratio：1~2 rhamnose is added with fatty alcohol with reflux condensate device, thermometer, electric stirring
In device and the four-hole boiling flask of vacuum system, heat to 90 DEG C in oil bath, it is to be mixed uniformly after, be added 0.1mol to first
Benzene sulfonic acid and phosphoric acid are stirred to react 3h, and pressure control is 3KPa, and solution temperature is down to 60 DEG C, under normal pressure, is added 5%
Sodium hydroxide solution neutralizes solution to pH=8.Vacuum distillation, obtains biosurfactant.
Biosurfactant in the present invention be by rhamnose hydroxyl or carboxyl and fatty alcohol in hydroxyl, in acid
Catalysis under lose composite biosurfactant obtained from a molecular water, obtained biosurfactant is with surface
Power is low, foaming abundancy is fine and smooth and stablize, dirt-removing power it is strong, not only with nonionic surfactant, the anion table in the present invention
The compatibility of face activating agent is good, but also can reduce the dosage of nonionic surfactant, anion surfactant.This hair
In bright, polyoxyethylene-type anion surfactant, betaine type amphoteric ionic surface active agent and biosurfactant
Compatibility makes each active material synergistic effect in each surfactant, improves the clean rate of fabric jointly.
Cyclo-dextrin-modified polyethylene glycol：
Heretofore described " cyclo-dextrin-modified polyethylene glycol " refers to that cyclodextrin penetrates peg molecule chain formation packet
Containing compound, molecule necklace is formed.
In one embodiment, the molar ratio 1 of the polyethylene glycol and cyclodextrin：1~10.
In a preferred embodiment, the molar ratio 1 of the polyethylene glycol and cyclodextrin：1~4.
In one embodiment, the number-average molecular weight of the polyethylene glycol is 500~2000.
In a preferred embodiment, the number-average molecular weight of the polyethylene glycol is 1200~1600.
Heretofore described cyclodextrin is not particularly limited, and can be cyclodextrin, or cyclodextrin derives
Object.
Heretofore described cyclodextrin and cyclodextrine derivatives such as, but not limited to, cyclodextrin such as alpha-cyclodextrin, β-ring
Dextrin and gamma-cyclodextrin；Cyclodextrine derivatives such as Dimethyl cyclodextrin, glucose cyclodextrin, 2- Hydroxyproply-α-cyclodextrins, 2,
Bis--O- methyl-alphacyclodextrins of 6-, 6-O- α-malt-base-alpha-cyclodextrin, 6-O- α-D- glucityls-alpha-cyclodextrin, six (2,3,
Tri--O- acetyl group of 6-)-alpha-cyclodextrin, six (2,3,6- tri--O- methyl)-alpha-cyclodextrins, six (6-O- tosyls)-α-rings
Dextrin, six (6- amino -6- deoxidations)-alpha-cyclodextrins, six (the bromo- 6- deoxidations of 2,3- acetyl group -6-)-alpha-cyclodextrins, six (2,3,6-
Three-O- octyls)-alpha-cyclodextrin, list (2-O- phosphoryls)-alpha-cyclodextrin, list [2, (3)-O- (carboxymethyl)]-alpha-cyclodextrin, eight
(6-O- t-butyldimethylsilyls)-alpha-cyclodextrin, succinyl-alpha-cyclodextrin, glucuronyl- glucityl-β-ring paste
Essence, seven (2,6- bis--O- methyl)-beta-cyclodextrins, seven (2,6- bis--O- ethyls)-beta-cyclodextrins, seven (6-O- sulfo groups)-β-rings paste
Essence, seven (2,3- bis--O- acetyl group -6-O- sulfo groups)-beta-cyclodextrins, seven (2,3- bis--O- methyl -6-O- sulfo groups)-beta-cyclodextrins,
Seven (2,3,6- tri--O- acetyl group)-beta-cyclodextrins, seven (2,3,6- tri--O- benzoyls)-beta-cyclodextrins, seven (2,3,6- tri--
O- methyl)-beta-cyclodextrin, seven (bis--O- methyl of 3-O- acetyl group -2,6-)-beta-cyclodextrins, seven (2,3-O- acetyl group -6- are bromo-
6- deoxidations)-beta-cyclodextrin, 2- hydroxyethyl-β-cyclodextrins, hydroxypropyl-β-cyclodextrin, 2-HP-BETA-CD, (2- hydroxyls-
3-N, N, N- dimethylamino) propyl-beta-cyclodextrin, 6-O- α-malt sugar group-beta-cyclodextrin, methyl-B-cyclodextrin, six (6- ammonia
Base -6- deoxidations)-beta-cyclodextrin, bis- (6- nitrine -6- deoxidations)-beta-cyclodextrins, list (2-O- phosphoryls)-beta-cyclodextrin, six [6-
Deoxidation -6- (1- imidazole radicals)]-beta-cyclodextrin, single acetyl group-beta-cyclodextrin, triacetyl group-beta-cyclodextrin, monochloro triazine radical-β -
Cyclodextrin, 6-O- α-D- glucose group-beta-cyclodextrin, 6-O- α-D-Maltose group-beta-cyclodextrin, succinyl-beta-cyclodextrin, amber
Acyl-(2- hydroxypropyls)-beta-cyclodextrin, 2- carboxymethyl-beta-cyclodextrins, 2- carboxyethyls-beta-cyclodextrin, fourth group-beta-cyclodextrin, sulphur third
Group-beta-cyclodextrin, 6- monodeoxy -6- monoamines group-beta-cyclodextrin, silicyl [bis--O- second of (6-O- fert-butyidimethylsilyls) 2,3-
Acyl group]-beta-cyclodextrin, 2- ethoxys-gamma-cyclodextrin, 2- hydropropyl-y-cyclodextrins, butyl-gamma-cyclodextrin, 3A- amino-
3A- deoxidations-(2AS, 3AS)-gamma-cyclodextrin, mono- 2-O- (p-toluenesulfonyl)-gamma-cyclodextrin, mono- 6-O- are (to toluene sulphur
Acyl group)-gamma-cyclodextrin, mono- 6-O- mesitylene sulfonyl-gamma-cyclodextrin, eight (2,3,6- tri--O- methyl)-γ-rings paste
Essence, eight (2,6- bis--O- phenyl)-gamma-cyclodextrins, eight (6-O- t-butyldimethylsilyls)-gamma-cyclodextrins and eight (2,
3,6- tri--O- acetyl group)-gamma-cyclodextrin.These cyclodextrin can be used alone or are used in combination with it.Wherein, α-
Cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin and its derivative are preferred.From the viewpoint of the connecing property of packet of linear molecule, particularly preferably
Beta-cyclodextrin and its derivative.
The preparation method of the cyclo-dextrin-modified polyethylene glycol is as follows：
It is at 40~80 DEG C, a certain amount of beta-cyclodextrin is soluble in water, the saturated aqueous solution of beta-cyclodextrin is made.To β-
In the saturated aqueous solution of cyclodextrin, according to the molar ratio 1 of polyethylene glycol and cyclodextrin：1~10 composition is made into reaction solution, and machine
Tool stirs 1h, at room temperature, stands for 24 hours, sediment occurs.By sediment vacuumizing filtration, washing, 30 DEG C are dried under vacuum to perseverance
Weight, obtains cyclo-dextrin-modified polyethylene glycol.
Since there is cyclodextrin special hydrophobic cavity and hydrophilic edge structure, peg molecule chain to have hydrophobicity
Segment and hydrophily ehter bond, hydroxyl.Hydrophobic chain segment in peg molecule chain may replace the high energy knot in cyclodextrin cavity
Heshui, and hydrophily ehter bond, the hydroxyl in peg molecule chain can generate hydrogen with the hydroxyl of the hydrophilic edge of cyclodextrin
Key acts on, to make entire compound system be in stable state.
The inventors discovered that cyclo-dextrin-modified polyethylene glycol is added in the system of cleansing composition, on the one hand improve
The hydrophily of cyclodextrin, on the other hand, cyclo-dextrin-modified polyethylene glycol can play synergistic effect with biosurfactant,
Reach clean effect.The present inventor is found surprisingly that, when cleaning fabric using cleansing composition, due to cyclo-dextrin-modified
Contain a large amount of hydroxyl on polyethylene glycol, hydrogen bond action can occur with plant fiber, to make it be adsorbed on the surface of fiber
On, on the one hand this absorption behavior can prevent dirt from reproducing deposition, on the other hand can reduce the friction between washing clothing,
Play the role of protecting clothing.The present inventor is also found surprisingly that cyclo-dextrin-modified polyethylene glycol can also live with biological surface
Property dosage form at micella interact, further increase the interaction of hydrophilic radical, hinder the spilling of dirt, improve
The rate of cleaning.And cyclodextrin belongs to nontoxic, environment-friendly type substance with polyethylene glycol, thus, provide beneficial effects of the present invention.
Chelating agent：
Heretofore described " chelating agent " is the compound including at least two carboxyls.
Can be as the example of the chelating agent in the present invention：Hyaluronic acid, chitosan, citric acid, tartaric acid, glucose
Diacid etc..From the point of view of chelate effect, preferably, hyaluronic acid, chitosan.
Contain carboxyl in chelating agent in the present invention, the oxygen element in carboxyl contains the electronics not to be coordinated to can be with water
The hole of the metal ions such as middle calcium, magnesium is coordinated, and so as to improve the hardness of water, further improves cleaning performance.
It is other：
Various additives can be contained within the scope without prejudice to the object of the present invention.
Can as the specific example of additive, for example, preservative, essence, pH adjusting agent, viscosity modifier, moisturizer,
It is one or more in conditioning agent, fungicide etc..In addition, other than the additive, the cleansing composition can be into one
Step includes Chinese herbal medicine extract, fruit extract, vitamin, pigment etc..
In one embodiment, it is different anti-bad to can be selected from methyl p-hydroxybenzoate, potassium sorbate, D- for the preservative
One or more of the different plug azoles Lin ketone of hematic acid sodium, p-hydroxybenzoate, Metagin, methyl chloride, methylisothiazolinone
Combination.
The fragrance can be selected from natural essence (fruity, Chinese herbal medicine perfume, minty note etc.) or artificial essence, such as limonene.
In one embodiment, the pH adjusting agent can be selected from inorganic acid, organic acid and its salt.For example, pH adjusting agent
It can be selected from citric acid, sodium citrate, phosphoric acid, sodium phosphate, lactic acid etc..
In one embodiment, the viscosity modifier can be selected from coconut oleoyl amine MEA, coconut oleoyl amine DEA, sodium chloride,
Ammonium chloride etc..
In one embodiment, can also include plant, seaweed or thalline in cleansing composition of the invention
Extract, such as can be from arithoke, indigo plant, arnica, aloe, hollyhock, Angelica Keiskei, malpighia glabra, apricot, almond, soil
Changshan, the stem pith of the rice-paper plant, anise, avocado, Artemisia capillaris, nettle, strawberry, fennel, turmeric, bisnaga, oolong tea, high mallow, fructus rosae,
Narrow leaf Echinacea, oat, trilliaceae, edelweiss, Nasturtium officinale, cork tree, radix scutellariae, the coptis, banaba, hypericum erectum, fragrant citrus,
Gumbo, olive leaf, blackcurrant, valeriana fauriei, persimmon, fiery spine, chamomile, Ka Muguo, carrot, tarragon, wild oat, Radix Glycyrrhizae, Huang
Melon, semen armeniacae amarae, Kiwi berry, quinine skin, Quillaia saponaria, water chestnut leaf ivy, Jia Yelong tea, raspberry, kuh-seng, Indocalamus leaf, mulberry tree, walnut,
Grape fruit, East Asia geranium wilfordii, felwort, moon peach, salacia reticulata, burdock, comfrey, wheat embryo, oriental cherry, crystal soda grass, mouse
Tail grass, Japanese hawthorn, asarum, funicle, cape jasmine fruit, meadow sweet, cordate houttuynia, Ma Ying, calamus, ginger, alkanet, purple perilla, white birch
Tree, Chinese herbaceous peony, glutinous rehmannia, flat real lemon, (simon No.1) sweet potato, written dish, carambola, high mallow, Rhizoma Chuanxiong, sharp thorn hawthorn, ivy, west
It is foreign pears, white willow, Salvia japonica, Japanese Swertia patens, soybean, bigarabe, thyme, citrus, thyme, tamarind, tealeaves, cloves, old
Skin, camellia, cordate houttuynia, Radix Angelicae Sinensis, peach kernel, dry orange peel, tomato, marigold, vine tea, septfoil, corn, margosa, hardship
Peppermint, elder, garlic, carrot, multiflora rose, myristica argentea Warburg, Japan, parsley, banana, rose, adlay, white feather fan hyacinth bean, mountain
Walnut, Japan cypress, hyssop, Himalaya raspberry, very thin geranium wilfordii, Asiatic sweet leaf, whortle, loquat, plum, grape,
Daffodil, butterfly bush, Portugal, peppermint, safflower, sponge gourd, ribwort, white Wormwood, somewhat-white magnolia, bodhi tree, strand
The root of purple-flowered peucedanum, tree peony, hop, Jojoba, Quinces Quince, rose, horse chestnut, pine tree, orange, soapberry, balm, oenothera biennis, peach, maple
Tree, Rodgersia podophylla A. Gray, kiss-me, eucalyptus, lily, shaddock, coix seed, wormwood, orchid, bitter orange, lavender romaine lettuce, apple, wilderness wormwood artemisia,
Doctor's tea, Chinese milk vetch, lemon, lemon balm, fructus rosae, rosemary, green alga, red algae, brown alga, Poria cocos, mushroom, grain gill fungus, bracket fungus,
White fungus, ganoderma lucidum, cordyceps sinensis, yeast, lactic acid bacteria, the herb of rhizobium, leaf, stem, root, fruit, seed, flower, fructification, thalline
In, use water；Or the organic solvent of glycerine, propylene glycol, ethyl alcohol, butanediol etc.；Or their mixed liquor；Or olive
Extract obtained from the finish etc. of oil, macadimia nut oil etc. extracts.Chlorophyll also corresponds to plant extracts.In addition,
Bacterium is removed in spite of the culture solution of fresh milk, fruit juice, synthetic media, the lactic acid bacteria of semisynthetic medium, yeast will have been used
Body can use.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used
In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field
Some the nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available, purchase the limited public affairs of Chinese medicines group chemical reagent
Department, and number used in following material is parts by weight.
Raw material：
Polyoxyethylene-type anion surfactant：
Betaine type amphoteric ionic surface active agent：
B1：Cocoamidopropyl betaine
B2：Cocamidopropyl propyl amide hydroxyl sulfo betaine, coco betaine (cocamidopropyl propyl amide hydroxyl sulfo betaine
Weight percent 50%, the weight percent 50% of coco betaine)
B3：Dodecanamide propyl hydroxy sulfo lycine
C1：Glucose
D1：Rhamnose has the following structure formula
Biosurfactant：
E1：
Wherein, R1For H；R2For C20Linear paraffin.
Preparation method：
E2：
Wherein, R1For H；R2For C12Linear paraffin.
E3：
Wherein, R1、R2It is C16Linear paraffin.
E4：
Wherein, R1For C3Linear paraffin, R2For C15Linear paraffin.F1：Cyclodextrin
G1：Polyethylene glycol
Cyclo-dextrin-modified polyethylene glycol：
H1：The molar ratio 1 of polyethylene glycol and cyclodextrin：1；The number-average molecular weight of polyethylene glycol is 500；Cyclodextrin is：α-
Cyclodextrin.
H2：The molar ratio 1 of polyethylene glycol and cyclodextrin：4；The number-average molecular weight of polyethylene glycol is 1200；Cyclodextrin is：β-
Cyclodextrin.
H3：The molar ratio 1 of polyethylene glycol and cyclodextrin：6；The number-average molecular weight of polyethylene glycol is 1600；Cyclodextrin is：6-
O- α-D-Maltose group-beta-cyclodextrin.
H4：The molar ratio 1 of polyethylene glycol and cyclodextrin：10；The number-average molecular weight of polyethylene glycol is 2000；Cyclodextrin is：
Gamma-cyclodextrin.
Chelating agent:
J1：Chitosan
J2：Citric acid
J3：Hyaluronic acid
J4：Tartaric acid
Preservative:
K1：Potassium sorbate
PH adjusting agent:
L1：Lactic acid
Viscosity modifier:
M1：Sodium chloride
Plant extracts:
N1：Elderberry extract
N2：Ribwort extract, porous fungus extract
O1：Water
Evaluation method：
1, toxotest
Experimental white mouse skin is tested, and standard GB/T 7919-87 skin irritatin strength grading standards are shown in Table 1.
The evaluation criterion of 1 Skin-test of table and compare
The green environmental protection of test agent is evaluated by mouse skin toxicity test.
Experiment material：Oilpaper, elbow scissors, gauze, adhesive plaster, syringe, bandage, cotton swab, cage tool；APG-12
It is made by oneself for laboratory, product mass fraction of solids is more than 50%；Physiological saline；Medicinal alcohol etc..
Animal for research：It is provided by medical college of Shanghai Second Emdical University, small white mouse (cleaning grade, 10~20g of weight).In advance
First in temperature (24 ± 2) DEG C, the animal house of humidity 55% ± 10% feeds 4d, and drinking water is tap water.Take cleaning health little Bai
Mouse 30 adapts to environment 4d.15 therein are taken, before experiment for 24 hours, diamond wool among its back is cut into general 3cm × 3cm.
Tested material is smeared uniformly in hair removal section, is used in combination double gauze and oilpaper to cover, then go to be subject to nonirritant bandage and adhesive plaster
It is fixed, it is cleaned afterwards with warm water for 24 hours." # " word scar is drawn on depilation skin with disinfection syringe needle before other 15 experiments, is with oozing of blood
Degree, administrations are identical with intact skin group.The death condition of small white mouse and systemic toxicity profiles performance after applying tested material are checked daily.
2, fabric cleans rate
In order to verify the detergency of cleansing composition of the present invention, detergency test is carried out.With reference to GB/T13174-
2008《Dress material laundry detergents detergency and the measurement for recycling scourability》Standard, using national standard carbon black JB-01, national standard albumen
Tri- kinds of JB-02, national standard sebum JB-03 soiled cottons carry out test fabric and clean rate.
Experiment condition is：Using 250ppm hard water, wash concentration 1-6g/L, wash time 15min, 25 DEG C of temperature, use
RQHL types Terg-O-Tometer, the rotating speed 60r/min of national regulations.
Data above can be seen that and the product phase without using biosurfactant and cyclo-dextrin-modified polyethylene glycol
There is preferably clean rate than, cleansing composition of the invention, and the cleaning agent clean environment firendly of the present invention, nontoxic, therefore carries
The advantageous effects of the present invention are supplied.
Example above-mentioned is merely illustrative, some features of the feature for explaining the disclosure.The attached claims
It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment
Combination selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention
Feature exemplary selectional restriction.And the progress in science and technology will be formed language express inaccuracy due to and not
The possible equivalent or son being presently considered are replaced, and these variations also should in the conceived case be interpreted by appended
Claim covers.
Claims (10)
1. a kind of environment-friendly liquid cleansing composition, which is characterized in that include the raw material of following parts by weight,
The polyoxyethylene-type anion surfactant of 1~5 parts by weight；
The betaine type amphoteric ionic surface active agent of 1~8 parts by weight；
The biosurfactant of 3~10 parts by weight；
The cyclo-dextrin-modified polyethylene glycol of 1~5 parts by weight；
The chelating agent of 1~3 parts by weight；With
The water of 100 parts by weight；
The biosurfactant is fatty alcohol modified rhamnose；
The chelating agent is the compound including at least two carboxyls；
The cyclo-dextrin-modified polyethylene glycol is that cyclodextrin penetrates peg molecule chain formation compound.
2. environment-friendly liquid cleansing composition as described in claim 1, which is characterized in that the polyoxyethylene-type anion
The structural formula of surfactant is：
Wherein, the R in formula1Can be H or C1~C6Alkane, R2Can be C4~C20Alkane, R3Can be sulfate, sulphur
Any one in hydrochlorate or carboxylate, n are 1~15.
3. environment-friendly liquid cleansing composition as described in claim 1, which is characterized in that the biosurfactant tool
Just like lower structure formula：
The combination of middle one or more structure；Wherein, R1、R2For H, C3~C20Alkane in any one, R1、R2It is different
When be H.
4. environment-friendly liquid cleansing composition as described in claim 1, which is characterized in that the biosurfactant tool
Just like lower structure formula：
Wherein, R1、R2For H, C12~C20Alkane in any one, R1、R2It is asynchronously H.
5. environment-friendly liquid cleansing composition as described in claim 1, which is characterized in that the poly- second of the cyclo-dextrin-modified two
In alcohol, the molar ratio 1 of cyclodextrin and polyethylene glycol：10.
6. environment-friendly liquid cleansing composition as claimed in claim 5, which is characterized in that the number of the polyethylene glycol is divided equally
Son amount 500~2000.
7. environment-friendly liquid cleansing composition as claimed in claim 5, which is characterized in that the cyclodextrin is α-ring paste
Any one in essence, beta-cyclodextrin, 6-O- α-D-Maltose group-beta-cyclodextrin, gamma-cyclodextrin.
8. environment-friendly liquid cleansing composition as described in claim 1, which is characterized in that the chelating agent is selected from：It is transparent
Any one in matter acid, chitosan, citric acid, tartaric acid, glucaric acid.
9. environment-friendly liquid cleansing composition as described in claim 1, which is characterized in that it further includes 0.5~1 parts by weight
PH adjusting agent, the pH adjusting agent be lactic acid.
10. environment-friendly liquid cleansing composition as claimed in claim 9, which is characterized in that it further includes 0.5~1 weight
The viscosity modifier of part, the viscosity modifier are sodium chloride.
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| CN107099394A (en) * | 2017-05-30 | 2017-08-29 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of cleaning fluid for removing dyestuff and preparation method thereof |
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| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
| CN103261234A (en) * | 2010-12-16 | 2013-08-21 | 住友精化株式会社 | Method for producing refined polyrotaxane |
| CN103930537A (en) * | 2011-09-15 | 2014-07-16 | 花王株式会社 | Liquid detergent composition |
| CN105331447A (en) * | 2015-11-20 | 2016-02-17 | 李碧丹 | Sterilizing cleaning composition with rich and stable foam |
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| CN103261234A (en) * | 2010-12-16 | 2013-08-21 | 住友精化株式会社 | Method for producing refined polyrotaxane |
| CN103930537A (en) * | 2011-09-15 | 2014-07-16 | 花王株式会社 | Liquid detergent composition |
| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
| CN105331447A (en) * | 2015-11-20 | 2016-02-17 | 李碧丹 | Sterilizing cleaning composition with rich and stable foam |
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