CN107177424A - It is a kind of to contain enzymatic detergent suitable for what low temperature was washed - Google Patents
It is a kind of to contain enzymatic detergent suitable for what low temperature was washed Download PDFInfo
- Publication number
- CN107177424A CN107177424A CN201710490162.1A CN201710490162A CN107177424A CN 107177424 A CN107177424 A CN 107177424A CN 201710490162 A CN201710490162 A CN 201710490162A CN 107177424 A CN107177424 A CN 107177424A
- Authority
- CN
- China
- Prior art keywords
- parts
- low temperature
- crab shell
- enzymatic detergent
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38681—Chemically modified or immobilised enzymes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to detergent applications, a kind of enzymatic detergent that contains suitable for low temperature washing is disclosed, including the component of lower parts by weight is made：25 35 parts of neopelex, 15 25 parts of coco-nut oil fatty acid diethanol amine embeds 13 parts of complex enzyme, 35 45 parts of filler, 0.5 1.5 parts of carboxymethyl cellulose, 24 parts of aloe extract, 13 parts of Oil-tea-cake extract, modified 13 parts of crab shell powder.The present invention's has outstanding dissolved efficiency containing enzymatic detergent in water at low temperature, and complex enzyme can keep higher activity at low temperature and under different acid or alkali environments so that washing powder has the dirt-removing power.
Description
Technical field
The present invention relates to detergent applications, more particularly to a kind of contain enzymatic detergent suitable for what low temperature was washed.
Background technology
Washing powder product category in the market is numerous.In order to further improve detergency and decompose the energy of spot
Enzyme is all added with power, the washing powder of many brands.Different enzymes have unicity, being capable of the specific spot of directional enzymatic, example
Such as, lipase can effectively digest greasy dirt, and protease being capable of effective enzymolysis protein matter etc..
Such as：Patent CN201410451148.7 discloses a kind of compound enzymatic detergent, and each component and its mass fraction are：
Complex enzyme 0.5~3%, alkyl benzene sulphonate 10~20%, soda ash 10~20%, sodium silicate 10~25%, glauber salt 30~60%,
CMC1~10%, fluorescent whitening agent 0.1~1% intersperses thing 5~15%, essence 0.5~3%.The complex enzyme is by alkaline egg
Two or more compounding in white enzyme, amylase, lipase, cellulase is formed.Washing powder of the present invention with the addition of compound
Enzyme, improves the dirt-removing power of washing powder.Patent CN201210198394.7 discloses a kind of soft washing powder, described softness
Washing powder is made up of following component according to mass fraction：2-9 parts of sodium chloride, 6-12 parts of Potassium dodecylbenzenesulfonate, soda soap 8-15
Part, 9-17 parts of tallow primary amine, -18 parts of proteinase 9,7-19 parts of essence.The present invention can play a part of soft cloth, wash out
The clothing come is more soft.Patent CN201110126361.7 discloses a kind of preparation method of enzyme-added aromatized washing powder, the production
Product belong to articles for washing field.Product of the present invention is with soda ash, sodium alkyl benzene sulfonate, laminated crystal of sodium disilicate, toluene iodine
Sour sodium, carboxymethyl cellulose, alkali protease, essence, bleach boosters, dirt dispersant are raw material, and are aided with specific technique
Come the enzyme-added aromatized washing powder prepared, the enzyme-added aromatized washing powder has clean effect good, to specific dirt (such as fruit juice, ink,
Bloodstain, milk stain, gravy, cow's milk, soy sauce etc.) dispel with specific function, play the role of sterilization, brighten, color protection increase it is gorgeous, wash
Clothing powder color is pure white, particle is uniform, and the clothing of wash-off has fragrance, has not only been suitable for hand-washing but also has been suitable for washing machine and uses.
In the prior art, enzyme is gone in the formula for be directly appended to washing powder.But, can so exist
Some problems：
1st, in water at low temperature, particularly when winter water temperature is less than 10 DEG C, because water temperature is preferable significantly lower than enzyme
Active temperature (generally between 25-40 DEG C), therefore enzyme can not give full play to its activity, cause dirt-removing power degradation.
In addition to influence of the temperature to enzymatic activity, it there is also an issue under the relatively low water temperature of washing powder of the prior art：Due to water
Temperature is relatively low, and washing powder can not quickly dissolve, and fully dissolving needs the long period, and is typically in cleaning process in machine washing
In washing powder is added in water by automatic washing machine is automatic, enough time does not go to wait detergent dissolving, and this will
Cause washing powder can not give full play in area to act on.And if artificially doping hot water is more bothered with improving temperature.
2nd, existing washing powder is typically all that, in alkalescence, under alkaline environment, the activity of many enzymes can also receive suppression,
Therefore enzyme can not give full play to its activity, cause dirt-removing power degradation.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides it is a kind of suitable for low temperature wash contain enzymatic detergent.This hair
Bright have outstanding dissolved efficiency containing enzymatic detergent in water at low temperature, and complex enzyme is at low temperature and different acid or alkali environments
Higher activity can be kept down so that washing powder has the dirt-removing power.
The present invention concrete technical scheme be：A kind of enzymatic detergent that contains suitable for low temperature washing, including lower parts by weight
Component is made：
25-35 parts of neopelex,
15-25 parts of coco-nut oil fatty acid diethanol amine,
1-3 parts of complex enzyme is embedded,
35-45 parts of filler,
0.5-1.5 parts of carboxymethyl cellulose,
2-4 parts of aloe extract,
1-3 parts of Oil-tea-cake extract,
Modified 1-3 parts of crab shell powder.
In the inventive solutions, complex enzyme have passed through embeddingization processing so that complex enzyme is supported on carrier, tool
Have a more stable environment, therefore its activity is influenceed smaller by the temperature and acid-base value of water body, can low temperature with
And preferably activity is kept under acid-base environment.In addition, also contain aloe extract in inventive formulation, Oil-tea-cake extract and
Modified crab shell powder；Wherein aloe extract and Oil-tea-cake extract are natural extract, and nonhazardous, aloe extract has preferable
Mildness, clothing can be played a protective role, reduce damage, and clothing can be made to keep preferable feel.Oil-tea-cake is carried
Take and contain a large amount of nonionic surfactant saponin(es and polysaccharide in thing, under low temperature and acid or alkali environment there is preferable surface to live
Property, surface tension can be effectively reduced, spot is departed from clothing, the effect for helping and washing is played, and it also has certain suppression
Bacterium ability.Modified crab shell powder is compound in washing powder, and it has a stronger hygroscopicity, and being capable of heat release after moisture absorption so that washed
Clothing powder be added in water after can fater disintegration dissolve, improve the dissolved efficiency in low water temperature.And it is in heating process
In also improve the temperature in local waters, improve the enzymatic activity of complex enzyme.
Preferably, the filler is sodium sulphate.
Sodium sulphate it is cheap, it can reduce in the hydrolysis of neopelex, washing powder and add sulphur
Sour sodium, can also relax stimulation of some highly basic to skin.
Further, the preparation method of the immobilization complex enzyme is as follows：Compound concentration is molten for 10-15% sodium alginate
Liquid, takes complex enzyme and is added in sodium alginate soln and stir, and then drips above-mentioned solution with each 0.5-1.5mL amount
Add in the calcium chloride solution that concentration is 1-5wt%, until after full cross-linked shaping, bag is made after centrifuging, filtering
Bury complex enzyme.
The present invention first mixes complex enzyme with sodium alginate soln, is then added to progress crosslinking generation in calcium chloride solution
Calcium alginate, complex enzyme has been carried out effective embedding by calcium alginate in cross-linking process so that complex enzyme is provided with one more
Stable environment, therefore its activity is influenceed smaller by the temperature and acid-base value of water body, can be in low temperature and acid-base environment
It is lower to keep preferably activity.
Preferably, the complex enzyme is included in alkali protease, neutral proteinase, lipase, cellulase, amylase
It is at least one.
Further, washing powder also includes 0.1-0.3 parts of brightening agent.
Brightening agent can increase the whiteness of clothing, make to seem more beautiful after clothing is clear, brand-new.
Further, washing powder also includes 0.1-0.3 parts of essence.
Essence can not make that certain fragrance can be kept after clothes washing.
Further, the preparation method of the modified crab shell powder is as follows：Take clean crab shell and be put in Muffle furnace
1-2h is first calcined at 250-350 DEG C, taking-up was crushed 60-120 mesh, and was placed again into after being cleaned with water in Muffle furnace in 350-
3-5h is calcined at 650 DEG C, 600-1000 mesh sieves was crushed after roasting again, and obtained crab shell powder；By crab shell powder and its quality 0.05-
0.15% sodium hydroxide is well mixed and put into high-pressure reactor, and into high-pressure reactor, input quality is crab shell powder 10-
15% liquefaction oxirane, 150-180 DEG C, polymerisation 2- are warming up in nitrogen pressurization protection and under the conditions of being sufficiently stirred for
4h, after cooling, is made modified crab shell powder.
The present invention is modified processing to crab shell powder, and the main component of crab shell powder is a large amount of calcium carbonate, a small amount of chitin
With the organic matter such as the protein of very small amount " inlaying " in the housing, after being calcined, cleaning at 240-350 DEG C, chitin and these
Most of organic matter is removed.350-650 DEG C be calcined after, calcium carbonate is decomposed at high temperature, be decomposed into calcium oxide and
Carbon dioxide.Due to chitin, the removal of organic matter and the separation of carbon dioxide during above-mentioned double roasting, in crab shell
Substantial amounts of space is left on matrix so that crab shell powder has larger specific surface area, therefore has higher reactivity, because
This its contacted with water after moisture absorption and can react rapidly, produce heat, accelerate detergent dissolving.On this basis, this hair
Bright also to have a strata oxirane in crab shell powder surface aggregate, PEO has extremely strong hygroscopicity, and it polymerize in crab shell
Behind powder surface, being dissolved in after water quickly to be absorbed water, and moisture is transferred to inside crab shell powder, reacted for crab shell powder.Simultaneously because
Crab shell powder is coated and isolated, so prevent crab shell powder directly and large area after crab shell powder surface aggregate film forming by PEO
Water haptoreaction and cause the heating of local moment too high.
Further, washing powder also includes 1-3 parts of sepiolite powder.Sepiolite is the inorganic ore with nanoaperture, right
Heavy metal ion, protein, pigment etc. have preferable adsorption capacity, are made an addition in washing powder, will can be taken off with clothing
From spot adsorb rapidly, prevent secondary precipitation, pollution.
Further, the sepiolite powder passes through surfactant surface modification treatment.After surface treatment, sepiolite
Dispersiveness in water is more preferably.
Further, washing powder also includes 1-3 parts of chitosan.Chitosan has for protein, pigment, heavy metal ion etc.
There are stronger complexing, adsorption capacity, together coordinate with sepiolite, the spot departed from clothing can be rapidly complexed, adsorbed, prevent
Only secondary precipitation, pollution.
Further, the washing powder also includes 1-5 parts of antibacterial adsorbent, and the preparation method of the antibacterial adsorbent is as follows：
Bentonite is added in the metal salt solution containing copper ion, aluminium ion and magnesium ion and is uniformly dispersed, then solution is shifted
Microwave radiation heating 5-10min is carried out into microwave applicator, heating-up temperature is 60-80 DEG C, solution is taken out after heating in room temperature
Lower standing 0.5-1.5h, is then filtrated to get sediment and uses distilled water flushing, after drying at 200-300 DEG C thermal activation 2-
4h, eventually passes the antibacterial adsorbent that grinding, dressing sieve obtain 600-1000 mesh.
Bentonite is a kind of clay rock, and it has higher cation exchange capacity and good adsorption capacity.The present invention
Many kinds of metal ions is grafted into its surface using its this characteristic.In grafting process, the present invention is using microwave radiation auxiliary
Heating, benefit is that microwave acceleration molecular can vibrate in a short time, so as to greatly improve the exchange efficiency of metal ion, is shortened
The time of ion-exchange equilibrium, and the grafting rate of metal ion is higher.Thermal activation, Neng Goujin are carried out again after microwave heating
One step improves stability of the bentonite under different temperatures and acid or alkali environment.Metal ion is grafted on behind bentonite surface, is had
Ion antibacterial activity, and due to producing potential difference after different metal ions chance water, micro- magnetic field can be produced, and make in micro- magnetic field
The antibacterial activity of metal ion itself can be further improved with lower, so as to be respectively provided with out under different temperatures and acid or alkali environment
The antibacterial effect of color.The antibacterial adsorbent of the present invention is in addition to antibacterial action, because bentonite itself also can be to the egg in water
The spots such as white matter, fat, dyestuff are adsorbed, therefore can also prevent spot from being precipitated again in clothing surface and forming secondary dirt
Dye, achieves many things at one stroke.
Further, the concentration of copper ion, aluminium ion and magnesium ion is 0.2-0.4mol/L, institute in the metal salt solution
The mass ratio for stating bentonite and metal salt solution is 1:3-7.
The invention has the advantages that：The present invention's in water at low temperature there is outstanding dissolving to imitate containing enzymatic detergent
Rate, and complex enzyme can keep higher activity at low temperature and under different acid or alkali environments so that and washing powder has what is
Dirt-removing power.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
It is a kind of to contain enzymatic detergent suitable for what low temperature was washed, including the component of lower parts by weight is made：DBSA
32 parts of sodium, 18 parts of coco-nut oil fatty acid diethanol amine embeds 2 parts of complex enzyme, 40 parts of sodium sulphate, 1 part of carboxymethyl cellulose, aloe
3 parts of extract, 2 parts of Oil-tea-cake extract, modified 2 parts of crab shell powder.
The preparation method of immobilization complex enzyme is as follows：Compound concentration is 12wt% sodium alginate soln, takes complex enzyme (alkali
Property protease, neutral proteinase, lipase, cellulase, amylase) and be added in sodium alginate soln and stir, so
During above-mentioned solution using each 1mL amount are added dropwise into concentration as 3wt% calcium chloride solution afterwards, until after full cross-linked shaping,
Embedding complex enzyme is made after centrifuging, filtering.
The preparation method of modified crab shell powder is as follows：Take clean crab shell and be put in Muffle furnace and first roasted at 300 DEG C
1.5h is burnt, taking-up crushed 100 mesh, and was placed again into after being cleaned with water in Muffle furnace and 4h is calcined at 500 DEG C, wheat-middlings again after roasting
The broken mesh sieve of mistake 800, obtains crab shell powder；Crab shell powder is well mixed with the sodium hydroxide of its quality 0.1% and reaction under high pressure is put into
In device, into high-pressure reactor, input quality is the liquefaction oxirane of crab shell powder 10%, pressurizes and protects and abundant in nitrogen
170 DEG C are warming up under stirring condition, after cooling, modified crab shell powder is made in polymerisation 3h.
Embodiment 2
It is a kind of to contain enzymatic detergent suitable for what low temperature was washed, including the component of lower parts by weight is made：DBSA
25 parts of sodium, 25 parts of coco-nut oil fatty acid diethanol amine embeds 1 part of complex enzyme, 35 parts of sodium sulphate, 1.5 parts of carboxymethyl cellulose, reed
2 parts of luxuriant growth extract, 1 part of Oil-tea-cake extract, modified 3 parts of crab shell powder, 0.2 part of brightening agent, 0.3 part of essence, sepiolite powder (passes through
Surfactant surface modification treatment) 3 parts, 3 parts of chitosan.
The preparation method of immobilization complex enzyme is as follows：Compound concentration is 10% sodium alginate soln, takes complex enzyme (alkalescence
Protease, lipase, amylase) and be added in sodium alginate soln and stir, then by above-mentioned solution with each 0.5mL
Amount be added dropwise in the calcium chloride solution that concentration is 1%, until after full cross-linked shaping, be made by centrifuging, after filtering
Embed complex enzyme.
The preparation method of modified crab shell powder is as follows：Take clean crab shell and be put in Muffle furnace and first roasted at 250 DEG C
2h is burnt, taking-up crushed 60 mesh, and was placed again into after being cleaned with water in Muffle furnace and is calcined 5h at 350 DEG C, crushed again after roasting
600 mesh sieves are crossed, crab shell powder is obtained；Crab shell powder is well mixed with the sodium hydroxide of its quality 0.05% and high-pressure reactor is put into
In, into high-pressure reactor, input quality is the liquefaction oxirane of crab shell powder 10%, is pressurizeed in nitrogen and protects and fully stir
150 DEG C are warming up under the conditions of mixing, after cooling, modified crab shell powder is made in polymerisation 4h.
Embodiment 3
It is a kind of to contain enzymatic detergent suitable for what low temperature was washed, including the component of lower parts by weight is made：DBSA
30 parts of sodium, 15 parts of coco-nut oil fatty acid diethanol amine embeds 3 parts of complex enzyme, 45 parts of sodium sulphate, 0.5 part of carboxymethyl cellulose, reed
2 parts of luxuriant growth extract, 1 part of Oil-tea-cake extract, modified 1 part of crab shell powder, 0.2 part of brightening agent, 0.3 part of essence, sepiolite powder (passes through
Surfactant surface modification treatment) 1 part, 1 part of chitosan.
The preparation method of immobilization complex enzyme is as follows：Compound concentration is 15% sodium alginate soln, takes complex enzyme (neutral
Protease, lipase, amylase) and be added in sodium alginate soln and stir, then by above-mentioned solution with each 1.5mL
Amount be added dropwise in the calcium chloride solution that concentration is 5wt%, until after full cross-linked shaping, made by centrifuging, after filtering
Complex enzyme must be embedded.
The preparation method of modified crab shell powder is as follows：Take clean crab shell and be put in Muffle furnace and first roasted at 350 DEG C
1h is burnt, taking-up crushed 120 mesh, and was placed again into after being cleaned with water in Muffle furnace and is calcined 3h at 650 DEG C, crushed again after roasting
1000 mesh sieves are crossed, crab shell powder is obtained；Crab shell powder is well mixed with the sodium hydroxide of its quality 0.15% and reaction under high pressure is put into
In device, into high-pressure reactor, input quality is the liquefaction oxirane of crab shell powder 15%, pressurizes and protects and abundant in nitrogen
180 DEG C are warming up under stirring condition, after cooling, modified crab shell powder is made in polymerisation 2h.
Embodiment 4
It is a kind of to contain enzymatic detergent suitable for what low temperature was washed, including the component of lower parts by weight is made：DBSA
35 parts of sodium, 15 parts of coco-nut oil fatty acid diethanol amine embeds 2 parts of complex enzyme, 35 parts of sodium sulphate, 1 part of carboxymethyl cellulose, aloe
4 parts of extract, 3 parts of Oil-tea-cake extract, modified 1 part of crab shell powder, sepiolite powder (by surfactant surface modification treatment) 2
Part, 2 parts of chitosan.
The preparation method of immobilization complex enzyme is as follows：Compound concentration is 13% sodium alginate soln, takes complex enzyme (alkalescence
Protease, lipase, amylase) and be added in sodium alginate soln and stir, then by above-mentioned solution with each 1mL's
Amount is added dropwise in the calcium chloride solution that concentration is 4wt%, until after full cross-linked shaping, being made after centrifuging, filtering
Embed complex enzyme.
The preparation method of modified crab shell powder is as follows：Take clean crab shell and be put in Muffle furnace and first roasted at 320 DEG C
2h is burnt, taking-up crushed 80 mesh, and was placed again into after being cleaned with water in Muffle furnace and 4.5h is calcined at 550 DEG C, wheat-middlings again after roasting
The broken mesh sieve of mistake 800, obtains crab shell powder；Crab shell powder is well mixed with the sodium hydroxide of its quality 0.1% and reaction under high pressure is put into
In device, into high-pressure reactor, input quality is the liquefaction oxirane of crab shell powder 12%, pressurizes and protects and abundant in nitrogen
160 DEG C are warming up under stirring condition, after cooling, modified crab shell powder is made in polymerisation 3h.
Embodiment 5
It is a kind of to contain enzymatic detergent suitable for what low temperature was washed, including the component of lower parts by weight is made：DBSA
30 parts of sodium, 20 parts of coco-nut oil fatty acid diethanol amine embeds 2 parts of complex enzyme, 37 parts of sodium sulphate, 0.8 part of carboxymethyl cellulose, reed
3 parts of luxuriant growth extract, 2 parts of Oil-tea-cake extract, modified 3 parts of crab shell powder, 0.1 part of brightening agent, 0.1 part of essence, antibacterial adsorbent 3
Part.
The preparation method of immobilization complex enzyme is as follows：Compound concentration is 10% sodium alginate soln, takes complex enzyme (alkalescence
Protease, lipase, amylase) and be added in sodium alginate soln and stir, then by above-mentioned solution with each 1mL's
Amount is added dropwise in the calcium chloride solution that concentration is 1wt%, until after full cross-linked shaping, being made after centrifuging, filtering
Embed complex enzyme.
The preparation method of modified crab shell powder is as follows：Take clean crab shell and be put in Muffle furnace and first roasted at 350 DEG C
1h is burnt, taking-up crushed 100 mesh, and was placed again into after being cleaned with water in Muffle furnace and is calcined 3h at 600 DEG C, crushed again after roasting
900 mesh sieves are crossed, crab shell powder is obtained；Crab shell powder is well mixed with the sodium hydroxide of its quality 0.1% and high-pressure reactor is put into
In, into high-pressure reactor, input quality is the liquefaction oxirane of crab shell powder 10%, is pressurizeed in nitrogen and protects and fully stir
165 DEG C are warming up under the conditions of mixing, after cooling, modified crab shell powder is made in polymerisation 2.5h.
The preparation method of antibacterial adsorbent is as follows：Bentonite is added to the gold containing copper ion, aluminium ion and magnesium ion
It is uniformly dispersed in category salting liquid, the concentration of copper ion, aluminium ion and magnesium ion is 0.3mol/L in the metal salt solution, described
The mass ratio of bentonite and metal salt solution is 1:5.Then solution is transferred to progress microwave radiation heating in microwave applicator
8min, heating-up temperature is 70 DEG C, and solution is taken out after heating and stands 1h at room temperature, sediment is then filtrated to get and uses distilled water
Rinse, after drying at 250 DEG C thermal activation 3h, eventually pass the antibacterial adsorbent that grinding, dressing sieve obtain 800 mesh.
The washing powder of embodiment 1 is subjected to low water temperature solute effect efficiency test with product containing enzymatic detergent purchased in market：
| Average grain diameter | 5 DEG C of water temperatures are completely dissolved the time | 10 DEG C of water temperatures are completely dissolved the time | |
| Embodiment 1 | 1mm | 40-60sec | 20-35sec |
| It is purchased in market to contain enzymatic detergent 1 | 1mm | 2-5min | 1-2min |
| It is purchased in market to contain enzymatic detergent 2 | 1mm | 2-4min | 1-2min |
Raw materials used in the present invention, equipment, is the conventional raw material, equipment of this area unless otherwise noted；In the present invention
Method therefor, is the conventional method of this area unless otherwise noted.
It is described above, only it is presently preferred embodiments of the present invention, not the present invention is imposed any restrictions, it is every according to the present invention
Any simple modification, change and equivalent transformation that technical spirit is made to above example, still fall within the technology of the present invention side
The protection domain of case.
Claims (10)
1. a kind of contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that the component including lower parts by weight is made：
25-35 parts of neopelex,
15-25 parts of coco-nut oil fatty acid diethanol amine,
1-3 parts of complex enzyme is embedded,
35-45 parts of filler,
0.5-1.5 parts of carboxymethyl cellulose,
2-4 parts of aloe extract,
1-3 parts of Oil-tea-cake extract,
Modified 1-3 parts of crab shell powder.
2. a kind of as claimed in claim 1 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that the filler is sulphur
Sour sodium.
3. a kind of as claimed in claim 1 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that the immobilization is answered
The preparation method of synthase is as follows：Compound concentration is 10-15% sodium alginate soln, takes complex enzyme and to be added to sodium alginate molten
Stirred in liquid, then above-mentioned solution be added dropwise to concentration 1-5wt% calcium chloride solution with each 0.5-1.5mL amount
In, until after full cross-linked shaping, embedding complex enzyme is made after centrifuging, filtering.
4. a kind of as claimed in claim 3 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that the complex enzyme bag
Include at least one of alkali protease, neutral proteinase, lipase, cellulase, amylase.
5. a kind of as claimed in claim 1 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that also including brightening agent
0.1-0.3 parts.
6. a kind of as claimed in claim 1 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that also including essence
0.1-0.3 parts.
7. a kind of as claimed in claim 1 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that the modified crab shell
The preparation method of powder is as follows：Take clean crab shell and be put in Muffle furnace at 250-350 DEG C and be first calcined 1-2h, take out powder
It is broken to cross 60-120 mesh, it is placed again into after being cleaned with water in Muffle furnace and is calcined 3-5h at 350-650 DEG C, was crushed again after roasting
600-1000 mesh sieves, obtain crab shell powder；Crab shell powder is well mixed with its quality 0.05-0.15% sodium hydroxide and height is put into
Press in reactor, into high-pressure reactor, input quality is crab shell powder 10-15% liquefaction oxirane, pressurizes and protects in nitrogen
And it is warming up to 150-180 DEG C under the conditions of being sufficiently stirred for, after cooling, modified crab shell powder is made in polymerisation 2-4h.
8. as described in one of claim 1-7 it is a kind of suitable for low temperature wash contain enzymatic detergent, it is characterised in that also include
1-3 parts of sepiolite powder.
9. a kind of as claimed in claim 8 contain enzymatic detergent suitable for what low temperature was washed, it is characterised in that the sepiolite powder
By surfactant surface modification treatment.
10. as described in one of claim 1-7 it is a kind of suitable for low temperature wash contain enzymatic detergent, it is characterised in that also wrap
Include 1-3 parts of chitosan.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710490162.1A CN107177424A (en) | 2017-06-25 | 2017-06-25 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710490162.1A CN107177424A (en) | 2017-06-25 | 2017-06-25 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107177424A true CN107177424A (en) | 2017-09-19 |
Family
ID=59844685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710490162.1A Pending CN107177424A (en) | 2017-06-25 | 2017-06-25 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107177424A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108251223A (en) * | 2018-03-09 | 2018-07-06 | 王连队 | It is a kind of to contain enzymatic detergent and preparation method thereof suitable for low temperature washing |
| CN108330016A (en) * | 2018-03-05 | 2018-07-27 | 江兵 | A kind of efficient sterilizing descaling type cashmere bio-enzyme cleaning agent |
| CN108531307A (en) * | 2018-03-05 | 2018-09-14 | 江兵 | A kind of method for washing improving natural feather fluffy degree |
| CN108546662A (en) * | 2018-05-07 | 2018-09-18 | 中国海洋大学 | Using the method for nitrifying bacteria community-bacillus Combined Treatment breeding wastewater of immobilization respectively |
| CN114507572A (en) * | 2021-04-30 | 2022-05-17 | 东莞市合信新材料有限公司 | Long-acting solid laundry detergent ball and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462695A (en) * | 2014-09-06 | 2016-04-06 | 天津市天亨洗涤剂有限公司 | Compound enzyme detergent powder |
| CN105695157A (en) * | 2016-02-24 | 2016-06-22 | 江阴市佐恩精品衣物洗涤护理有限公司 | Environment-friendly liquid cleaner composition |
-
2017
- 2017-06-25 CN CN201710490162.1A patent/CN107177424A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462695A (en) * | 2014-09-06 | 2016-04-06 | 天津市天亨洗涤剂有限公司 | Compound enzyme detergent powder |
| CN105695157A (en) * | 2016-02-24 | 2016-06-22 | 江阴市佐恩精品衣物洗涤护理有限公司 | Environment-friendly liquid cleaner composition |
Non-Patent Citations (2)
| Title |
|---|
| 何文婷: "有机改性海泡石对阴离子染料的吸附试验研究", 《湖南大学硕士学位论文》 * |
| 王桂芳等: ""膨润土作为药用辅料的研究现状"", 《金属矿山》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108330016A (en) * | 2018-03-05 | 2018-07-27 | 江兵 | A kind of efficient sterilizing descaling type cashmere bio-enzyme cleaning agent |
| CN108531307A (en) * | 2018-03-05 | 2018-09-14 | 江兵 | A kind of method for washing improving natural feather fluffy degree |
| CN108251223A (en) * | 2018-03-09 | 2018-07-06 | 王连队 | It is a kind of to contain enzymatic detergent and preparation method thereof suitable for low temperature washing |
| CN108546662A (en) * | 2018-05-07 | 2018-09-18 | 中国海洋大学 | Using the method for nitrifying bacteria community-bacillus Combined Treatment breeding wastewater of immobilization respectively |
| CN108546662B (en) * | 2018-05-07 | 2021-01-29 | 中国海洋大学 | Method for jointly treating aquaculture wastewater by respectively immobilized nitrifying bacteria group-bacillus |
| CN114507572A (en) * | 2021-04-30 | 2022-05-17 | 东莞市合信新材料有限公司 | Long-acting solid laundry detergent ball and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107177424A (en) | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed | |
| CN106947626A (en) | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed | |
| US3979314A (en) | Detergent compositions | |
| CN1244677C (en) | Treatment for fabrics | |
| CN103468444A (en) | Laundry soap powder composition | |
| JP2002543270A (en) | Cleaning compositions and tablets | |
| CN106676838B (en) | A kind of clothes washing water treating apparatus | |
| CN108529658B (en) | Method for recovering aluminum hydroxide from aluminum ash | |
| TWI449785B (en) | Detergent builder granules | |
| CN101264885A (en) | Method for preparing high grade activated carbon from rice husk ash | |
| CN113047038A (en) | Composite tea saponin and preparation method thereof | |
| CN107892998A (en) | A kind of washing powder of strong dirt-removing stain | |
| Rieck | Builders: the backbone of powdered detergents | |
| CN107446732A (en) | A kind of submissive whitening laundry soap composition and preparation method thereof | |
| CN106929178A (en) | A kind of acid scouring agent and preparation method thereof | |
| WO1995029978A1 (en) | Process for producing silicate-like builder granulates of high bulk density | |
| CN105602746A (en) | Phosphate-free detergent and production method thereof | |
| CN101514314B (en) | Transparent neutral laundry detergent containing high-concentration chelating agent and preparation method thereof | |
| CN102787028A (en) | Preparation method for ordinary laundry powder | |
| US6908896B2 (en) | Builder composition prepared by heat-treating a crystalline layered Na silicate | |
| CN107164107A (en) | A kind of washing powder with antibacterial adsorption function | |
| US7132390B2 (en) | Phyllosilicate adsorbate and its use | |
| CN100400635C (en) | Green broad spectrum soap powder | |
| CN110484389A (en) | A method of making washing assisant using p-zeolite | |
| CN106591607B (en) | A kind of liquid caustic soda decomposition method of high-grade mixed rare earth concentrates |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170919 |