CN105695157A - Environment-friendly liquid cleaner composition - Google Patents
Environment-friendly liquid cleaner composition Download PDFInfo
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- CN105695157A CN105695157A CN201610100838.7A CN201610100838A CN105695157A CN 105695157 A CN105695157 A CN 105695157A CN 201610100838 A CN201610100838 A CN 201610100838A CN 105695157 A CN105695157 A CN 105695157A
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- cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/381—Microorganisms
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/90—Betaines
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Abstract
The invention discloses an environment-friendly liquid cleaner composition which comprises, by weight, 1-5 parts of polyoxyethylene type anionic surfactant, 1-8 parts of betaine type zwitterionic surfactant, 5-10 parts of biosurfactant, 1-5 parts of cyclodextrin modified polyethylene glycol, 1-3 parts of chelating agent and 100 parts of water. The environment-friendly liquid cleaner composition is clean, environment-friendly, nontoxic and high in cleaning rate.
Description
Technical field
The invention belongs to field of fine chemical, relate to a kind of liquid ceanser, more particularly it relates to an for the environment-friendly liquid abluent of fabric washing。
Background technology
Liquid ceanser is domestic in people's daily life, household, the requisite articles for washing of Personal hygiene, is mainly used to clean medicated clothing, removes dirt。Common dirt has oily dirt, solids foul and some special dirts, including animal and plant fat, earth, dust, rust, flue dust, perspiration, blood etc.。Wherein, liquid ceanser compared with solid cleaner such as detergent, it have easy to use, use before without dissolve, cold washing effective, system alkalescence is low, and fabric and skin is gentleer, the advantage that environmental pollution is few and processing cost is low。At present, liquid ceanser product has become the direction of developed country's detergent industry development, becomes product with fastest developing speed in various abluent articles for use, for being only second to the second largest class abluent goods of detergent powder。
Current commercial liquid ceanser product, because containing harmful chemical substance, human body and environment being worked the mischief in most products therein, makes product not meet the requirement of environmental protection, these extensive concerns causing people already and attention。The harmful chemical that human body and environment are worked the mischief, such as, dodecylbenzene sodium sulfonate, owing to dodecylbenzene sodium sulfonate is petroleum base surfactant, its upstream raw material is alkylbenzene, the abluent made by this chemical substance containing benzene for after washing medicated clothing or gourd, fruit and vegetable, this chemical substance contact human body skin, being absorbed by human body skin, the nervous system of people can be worked the mischief by life-time service；Sodium tripolyphosphate is the hard water resistance performance improving dodecylbenzene sodium sulfonate, but, the impact of body eutrophication can be caused the environment gone from bad to worse by excessive use sodium tripolyphosphate, in the last few years, articles for washing was implemented to limit the use of phosphorus and disabling phosphorus measure by world many countries, area and China all to some extent。
Hence it is highly desirable to by the improvement of formula and processing technology, to develop a kind of environment-friendly liquid abluent。
Summary of the invention
In order to solve above-mentioned prior art Problems existing, the invention provides a kind of liquid ceanser compositions, comprise each material component of following mass percent:
The polyoxyethylene-type anion surfactant of 1～5 weight portion；
The betaine type amphoteric ionic surface active agent of 1～8 weight portion；
The biosurfactant of 3～10 weight portions；
The cyclo-dextrin-modified Polyethylene Glycol of 1～5 weight portion；
The chelating agen of 1～3 weight portion；With
The water of 100 weight portions；
Described biosurfactant is fatty alcohol modified rhamnose；
Described chelating agen is the compound at least including two carboxyls；
Described cyclo-dextrin-modified Polyethylene Glycol is that cyclodextrin penetrates peg molecule chain formation complex。
In a preferred embodiment, the structural formula of described polyoxyethylene-type anion surfactant is:
;
Wherein, the R in formula1Can be H or C1～C6Alkane, R2Can be C4～C20Alkane, R3Can being any one in sulfate, sulfonate or carboxylate, n be 1 ~ 15。
In one embodiment, described biosurfactant is structured with formula:
；
；
；
；
In the combination of one or more；
Wherein, R1、R2For H, C3～C20Alkane in any one, R1、R2It is asynchronously H。
In a preferred embodiment, described biosurfactant is structured with formula:
；
Wherein, R1、R2For H or C12～C20Alkane in any one, R1、R2It is asynchronously H。
In a preferred embodiment, in described cyclo-dextrin-modified Polyethylene Glycol, the mol ratio 1:10 of cyclodextrin and Polyethylene Glycol。
In a preferred embodiment, the number-average molecular weight 500～2000 of described Polyethylene Glycol。
In a preferred embodiment, described cyclodextrin is any one in alpha-cyclodextrin, beta-schardinger dextrin-, 6-O-α-D-Maltose group-beta-cyclodextrin, gamma-cyclodextrin。
In a preferred embodiment, described chelating agen is selected from: any one in hyaluronic acid, chitosan, citric acid, tartaric acid, glucaric acid。
In a preferred embodiment, it also includes the pH adjusting agent of 0.5～2 weight portion, and described pH adjusting agent is lactic acid。
In a preferred embodiment, it also includes the viscosity modifier of 0.5～1 weight portion, and described viscosity modifier is sodium chloride。
It is more readily understood the above-mentioned of the application and other features, aspect and advantage with reference to described further below。
Detailed description of the invention
Participate in the election of the detailed description being preferable to carry out method of the invention below and the embodiment that includes can be more easily understood present disclosure。Unless otherwise defined, all technology used herein and scientific terminology have the identical implication being generally understood that with one skilled in the art of the present invention。When there is contradiction, it is as the criterion with the definition in this specification。
Term as used herein " by ... preparation " and " comprising " synonym。Term used herein " comprises ", " including ", " having ", " containing " or its other deformation any, it is intended that cover the including of non-exclusionism。Such as, comprise the compositions of listed elements, step, method, goods or device and be not necessarily solely those key elements, but other not expressly listed key element or the intrinsic key element of this kind of compositions, step, method, goods or device can be included。
Conjunction " by ... composition " get rid of any key element, step or component do not pointed out。If in claim, this phrase will make claim be closed so that it is does not comprise the material except the material of those descriptions, but except relative customary impurities。When phrase " by ... composition " occurs in and is rather than immediately following after theme in the clause of claim main body, it is only limited to the key element described in this clause；Other key element is not excluded outside the described claim as entirety。
During the Range Representation that equivalent, concentration or other value or parameter limit with scope, preferable range or a series of upper limit preferred value and lower preferable values, this is appreciated that and specifically discloses all scopes formed by arbitrary pairing of any range limit or preferred value and any range lower limit or preferred value, regardless of whether whether this scope separately discloses。Such as, when disclosing scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc.。When numerical range is described in this article, unless otherwise indicated, otherwise this scope is intended to include its end value and all integers within the scope of this and mark。
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise。" optional " or " any one " refer to that the item described thereafter or event can occur or do not occur, and this description includes situation and the situation that do not occur of event that event occurs。
Approximate term in specification and claims is used for modifying quantity, represents that the present invention is not limited to this particular number, also includes close to this quantity acceptable without causing the part of the correction of the change of relevant basic function。Accordingly, modify a numerical value with " about ", " about " etc., mean and the invention is not restricted to this exact numerical。In some example, approximate term likely corresponds to measure the precision of the instrument of numerical value。In present specification and claims, scope limits and can combine and/or exchange, without additionally illustrating that these scopes include all subranges contained therebetween。
Additionally, indefinite article " one " before key element of the present invention or component and " one " quantitative requirement (i.e. occurrence number) unrestriction to key element or component。Therefore " one " or " one " should be read as and include one or at least one, and the key element of singulative or component also include plural form, unless the obvious purport of described quantity refers to singulative。
The invention provides a kind of environment-friendly liquid cleansing composition, comprise each material component of following mass percent:
The polyoxyethylene-type anion surfactant of 1～5 weight portion；
The betaine type amphoteric ionic surface active agent of 1～8 weight portion；
The biosurfactant of 3～10 weight portions；
The cyclo-dextrin-modified Polyethylene Glycol of 1～5 weight portion；
The chelating agen of 1～3 weight portion；With
The water of 100 weight portions；
Described biosurfactant is fatty alcohol modified rhamnose；
Described cyclo-dextrin-modified Polyethylene Glycol is that cyclodextrin penetrates peg molecule chain formation complex；
Described chelating agen is the compound at least including two carboxyls。
Polyoxyethylene-type anion surfactant:
In the present invention, described polyoxyethylene-type anion surfactant does not have other and limits especially。
Described polyoxyethylene-type anion surfactant is structured with formula:
;
Wherein, the R in formula1Can be H or C1～C6Alkane, R2Can be C4～C20Alkane, R3Can being any one in sulfate, sulfonate or carboxylate, n be 1 ~ 15。
Some preferred embodiment in, described polyoxyethylene-type anion surfactant is structured with formula:
；
Wherein, the R in formula1Can be C4～C6Alkane, R2Can be C10～C18Alkane, R3For carboxylate, n is 5 ~ 12。
In a preferred embodiment, described polyoxyethylene-type anion surfactant is structured with formula:
；
Wherein, the R in formula1Can be C6Alkane, R2Can be C12Alkane, R3For carboxylate, n is 7。
Betaine type amphoteric ionic surface active agent:
In the present invention, described betaine type amphoteric ionic surface active agent does not have other and limits especially, it is possible to for carboxy betaine type zwitterionic surfactant；It can also be sulfobetaine type zwitterionic surfactant etc.。
Described betaine type carboxylic acid type zwitterionic surfactant can be: cocamido propyl betaine, coco betaine, coco dimethyl carboxymethyl glycine betaine, dodecyl dimethyl carboxymethyl betaine, dodecyl dimethyl α-carboxy-ethyl betaine, cetyl dimethyl carboxymethyl glycine betaine, double, two (2-ethoxy) carboxymethyl betaine of dodecyl, double, two (2-hydroxypropyl) carboxymethyl betaine of octadecyl, oleyl alcohol dimethyl gamma-carboxypropyl glycine betaine, double, two (2-hydroxypropyl) α-carboxy-ethyl betaine of dodecyl, cocoyl dimethyl sulfopropyl betaine, octadecyldimethyl azochlorosulfonate propyl lycine, coconut oleoyl amine dimethyl carboxymethyl betaine, coconut oleoyl amine dimethyl sulfopropyl betaine, laurylamide dimethyl carboxymethyl betaine, cetyl amide dimethyl carboxymethyl betaine, one or more combination in octadecyl amide dimethyl sulfopropyl betaine etc.。
In a preferred embodiment, described betaine type amphoteric ionic surface active agent is selected from: one or more the combination in cocamido propyl betaine, coco betaine。
Described sulfobetaine type zwitterionic surfactant can be: cocamidopropyl propyl amide hydroxyl sulfo betaine, Coco-Hydroxysultaine, cocoyl sulfobetaines, erucyl amide hydroxysultaine, hydroxyl sulfo betaine, dodecanamide propyl hydroxy sulfo lycine, dodecyl hydroxyl sulfo betaine, dodecyl dimethyl sulfobetaines, myristamide hydroxysultaine, oleamide propyl group (weight ratio) propyl-dimethyl ammonium, one or more combination in tallow amidoethyl hydroxysultaine etc.。
In a preferred embodiment, described betaine type amphoteric ionic surface active agent is selected from: one or more the combination in cocamidopropyl propyl amide hydroxyl sulfo betaine, dodecanamide propyl hydroxy sulfo lycine。
Biosurfactant:
Biosurfactant is a kind of surfactant by Microbe synthesis, various structures, including glycolipid, fat skin, lipoprotein, phospholipid and neutral lipid derivant etc.。At present, on market, most surfaces activating agent is all chemosynthesis, but, use chemical surfactant can produce serious problem of environmental pollution。It is low, biodegradable that biosurfactant has toxicity, and good biocompatibility。
In one embodiment, described biosurfactant is structured with formula:
(1)；
(2)；
(3)；
(4)；
In one or more combination；
Wherein, R1、R2Can be identical, it is also possible to different, R1、R2Can be H or C3～C20Alkane in any one。
Being preferably carried out in mode in one, described biosurfactant is structured with formula:
；
Wherein, R1、R2For H, C12～C20Alkane in any one, R1、R2It is asynchronously H。
In the present invention, described biosurfactant is that fatty alcohol modified rhamnose prepares。
Heretofore described " rhamnose " is the Glycolipids Biosurfactants via that a class is secreted by Pseudomonas aeruginosa (Pseudomonasaeruginosa), it not only have can have with chemical surfactant solubilising, emulsifying, moistening, the performance such as foaming, and there is low toxicity, be readily biodegradable, the characteristic such as environmentally friendly, thus in fields such as oil development, medicine, food, daily use chemicals, environmental protection, there is very big application potential。
The not special restriction of heretofore described " rhamnose ", it is possible to by being commercially available, it is also possible to a blanking method known to those skilled in the art is synthetically derived。
Described rhamnose is structured with formula:
；
；
；
。
In the present invention, the not special restriction of described fatty alcohol, it is possible to commercially available acquisition, it is also possible to obtained by the blanking method known to those skilled in the art。
In one embodiment, described fatty alcohol is structured with formula: R-OH；
Preferably, R is carbon number is the alkane of 1～20；It is further preferred that R is carbon number is the linear paraffin of 8～15。
In the present invention, the preparation method of described biosurfactant can adopt Koenings-Khorr react preparation method, Enzyme catalyzed synthesis method, acetylation alcoholysis method, sugared Betamethasone Ketal structures alcoholysis method, direct glucosides method and turn glucosides method。Due to direct glucosides method have that technological process is short, energy consumption is low, easy operation and cost few, production process need not carry out under explosion-proof environment, and course of reaction state modulator is relatively strict, the advantage such as products obtained therefrom quality is good, lighter color and odorlessness, in the present invention, for direct glucosides method。
The preparation method of described biosurfactant is:
The rhamnose that mol ratio is 1:1～2 is added in the four-hole boiling flask with reflux condensate device, thermometer, motor stirrer and vacuum system with fatty alcohol, oil bath heats to 90 DEG C, to be mixed uniformly after, adding p-methyl benzenesulfonic acid and phosphoric acid, the stirring reaction 3h of 0.1mol, Stress control is 3KPa, solution temperature is down to 60 DEG C, at ambient pressure, add the sodium hydroxide solution of 5%, solution is neutralized pH=8。Vacuum distilling, obtains biosurfactant。
Biosurfactant in the present invention is by hydroxyl in the hydroxyl in rhamnose or carboxyl and fatty alcohol, the composite biosurfactant losing a part water under the catalysis of acid and obtain, the biosurfactant obtained have that surface tension is low, foaming abundancy is fine and smooth and stablize, dirt-removing power strong, not only good with the compatibility of the nonionic surfactant in the present invention, anion surfactant, but also the consumption of nonionic surfactant, anion surfactant can be reduced。In the present invention, polyoxyethylene-type anion surfactant, betaine type amphoteric ionic surface active agent and biosurfactant compatibility, make each active substance synergism in each surfactant, jointly improve the clean rate of fabric。
Cyclo-dextrin-modified Polyethylene Glycol:
Heretofore described " cyclo-dextrin-modified Polyethylene Glycol " refers to that cyclodextrin penetrates peg molecule chain formation and comprises complex, forms molecule necklace。
In one embodiment, mol ratio 1:1～10 of described Polyethylene Glycol and cyclodextrin。
In a preferred embodiment, mol ratio 1:1～4 of described Polyethylene Glycol and cyclodextrin。
In one embodiment, the number-average molecular weight of described Polyethylene Glycol is 500～2000。
In a preferred embodiment, the number-average molecular weight of described Polyethylene Glycol is 1200～1600。
The not special restriction of heretofore described cyclodextrin, it is possible to for cyclodextrin, it is also possible to for cyclodextrin derivative。
Heretofore described cyclodextrin and cyclodextrin derivative are such as, but not limited to, cyclodextrin such as alpha-cyclodextrin, beta-schardinger dextrin-and gamma-cyclodextrin；Cyclodextrin derivative is Dimethyl cyclodextrin such as, glucityl cyclodextrin, 2-Hydroxyproply-α-cyclodextrin, 2,6-bis--O-methyl-alphacyclodextrin, 6-O-α-malt-base-alpha-cyclodextrin, 6-O-α-D-glucityl-alpha-cyclodextrin, six (2,3,6-tri--O-acetyl group)-alpha-cyclodextrin, six (2,3,6-tri--O-methyl)-alpha-cyclodextrin, six (6-O-tosyl)-alpha-cyclodextrin, six (6-amino-6-deoxidation)-alpha-cyclodextrin, six (2, the 3-bromo-6-deoxidation of acetyl group-6-)-alpha-cyclodextrin, six (2,3,6-tri--O-octyl group)-alpha-cyclodextrin, single (2-O-phosphoryl)-alpha-cyclodextrin, single [2, (3)-O-(carboxymethyl)]-alpha-cyclodextrin, eight (6-O-t-butyldimethylsilyl)-alpha-cyclodextrin, succinyl-alpha-cyclodextrin, glucuronyl-glucose group-beta-cyclodextrin, seven (2,6-bis--O-methyl)-beta-schardinger dextrin-, seven (2,6-bis--O-ethyl)-beta-schardinger dextrin-, seven (6-O-sulfo group)-beta-schardinger dextrin-, seven (2,3-bis--O-acetyl group-6-O-sulfo group)-beta-schardinger dextrin-, seven (2,3-bis--O-methyl-6-O-sulfo group)-beta-schardinger dextrin-, seven (2,3,6-tri--O-acetyl group)-beta-schardinger dextrin-, seven (2,3,6-tri--O-benzoyl)-beta-schardinger dextrin-, seven (2,3,6-tri--O-methyl)-beta-schardinger dextrin-, seven (3-O-acetyl group-2,6-bis--O-methyl)-beta-schardinger dextrin-, seven (2, the 3-O-bromo-6-deoxidation of acetyl group-6-)-beta-schardinger dextrin-, 2-hydroxyethyl-β-cyclodextrin, HP-β-CD, 2-HP-BETA-CD, (2-hydroxyl-3-N, N, N-dimethylamino) propyl-beta-cyclodextrin, 6-O-α-malt sugar group-beta-cyclodextrin, methyl-B-cyclodextrin, six (6-amino-6-deoxidation)-beta-schardinger dextrin-, double, two (6-nitrine-6-deoxidation)-beta-schardinger dextrin-, single (2-O-phosphoryl)-beta-schardinger dextrin-, six [6-deoxidation-6-(1-imidazole radicals)]-beta-schardinger dextrin-, single acetyl group-beta-cyclodextrin, triacetyl group-beta-cyclodextrin, monochloro triazine group-beta-cyclodextrin, 6-O-α-D-glucose group-beta-cyclodextrin, 6-O-α-D-Maltose group-beta-cyclodextrin, succinyl-beta-cyclodextrin, succinyl-(2-hydroxypropyl)-beta-schardinger dextrin-, 2-carboxymethyl-beta-cyclodextrin, 2-carboxyethyl-beta-schardinger dextrin-, fourth group-beta-cyclodextrin, sulfopropyl-p-cyclodextrin, 6-monodeoxy-6-monoamine group-beta-cyclodextrin, silicyl [(6-O-fert-butyidimethylsilyl) 2,3-bis--O-acetyl group]-beta-schardinger dextrin-, 2-ethoxy-gamma-cyclodextrin, 2-hydropropyl-y-cyclodextrin, butyl-gamma-cyclodextrin, 3A-amino-3A-deoxidation-(2AS, 3AS)-gamma-cyclodextrin, single-2-O-(p-toluenesulfonyl)-gamma-cyclodextrin, single-6-O-(p-toluenesulfonyl)-gamma-cyclodextrin, single-6-O-sym-trimethylbenzene. sulfonyl-gamma-cyclodextrin, eight (2,3,6-tri--O-methyl)-gamma-cyclodextrin, eight (2,6-bis--O-phenyl)-gamma-cyclodextrin, eight (6-O-t-butyldimethylsilyl)-gamma-cyclodextrins and eight (2,3,6-tri--O-acetyl group)-gamma-cyclodextrin。These cyclodextrin can be used alone or be used in combination with it。Wherein, alpha-cyclodextrin, beta-schardinger dextrin-, gamma-cyclodextrin and derivant thereof are preferred。Viewpoint from the connecing property of bag of linear molecule, it is particularly preferred to beta-schardinger dextrin-and derivant thereof。
The preparation method of described cyclo-dextrin-modified Polyethylene Glycol is as follows:
At 40～80 DEG C, by soluble in water for a certain amount of beta-schardinger dextrin-, prepare the saturated aqueous solution of beta-schardinger dextrin-。In the saturated aqueous solution of beta-schardinger dextrin-, it is made into reactant liquor mechanical agitation 1h according to the composition of Polyethylene Glycol Yu mol ratio 1:1～10 of cyclodextrin, under room temperature, stands 24h, precipitate occurs。By precipitate vacuumizing filtration, washing, 30 DEG C of vacuum dryings, to constant weight, obtain cyclo-dextrin-modified Polyethylene Glycol。
Have special hydrophobic cavity and hydrophilic edge structure due to cyclodextrin, peg molecule chain has hydrophobic chain segment and hydrophilic ehter bond, hydroxyl。Hydrophobic chain segment in peg molecule chain may replace the high energy Bound moisture in cyclodextrin cavity, and hydrophilic ehter bond, hydroxyl in peg molecule chain can produce hydrogen bond action with the hydroxyl of the hydrophilic edge of cyclodextrin, so that whole compound system is in steady statue。
The inventors discovered that, add cyclo-dextrin-modified Polyethylene Glycol, improve the hydrophilic of cyclodextrin on the one hand in the system of cleansing composition, on the other hand, cyclo-dextrin-modified Polyethylene Glycol can play synergism with biosurfactant, arrives the effect of cleaning。The present inventor is found surprisingly that; when using cleansing composition to clean fabric; owing to cyclo-dextrin-modified Polyethylene Glycol containing substantial amounts of hydroxyl; hydrogen bond action can be there is with Plant fiber; so that its absorption is on the surface of the fiber; this absorption behavior is possible to prevent dirt to reproduce deposition on the one hand, can reduce the friction between washing medicated clothing on the other hand, play the effect of protection medicated clothing。The present inventor is also found surprisingly that, the micellar phase mutual effect that cyclo-dextrin-modified Polyethylene Glycol can also be formed with biosurfactant, further increases the interaction of hydrophilic group, hinders the spilling of dirt, improves clean rate。And cyclodextrin and Polyethylene Glycol belong to nontoxic, environment-friendly type material, thus, it is provided that beneficial effects of the present invention。
Chelating agen:
Heretofore described " chelating agen " is the compound at least including two carboxyls。
Can be as the example of the chelating agen in the present invention: hyaluronic acid, chitosan, citric acid, tartaric acid, glucaric acid etc.。From chelate effect, it is preferred to, hyaluronic acid, chitosan。
Containing carboxyl in chelating agen in the present invention, the electronics containing promising non-coordination of the oxygen element in carboxyl, to carrying out coordination with the hole of the metal ion such as calcium, magnesium in water, thus improving hardness of water, further increases cleaning performance。
Other:
Various additives can be contained within the scope without prejudice to the object of the present invention。
Can as the object lesson of additive, for instance, one or more in preservative, essence, pH adjusting agent, viscosity modifier, wetting agent, regulator, antibacterial etc.。Additionally, except described additive, described cleansing composition can further include Chinese herbal medicine extract, fruit extract, vitamin, pigment etc.。
In one embodiment, described preservative is selected from the combination of one or more in methyl parahydroxybenzoate, potassium sorbate, sodium D-isoascorbate, p-Hydroxybenzoate, Metagin, the different plug oxazolone of methyl chloride, Methylisothiazolinone。
Described spice is selected from natural essence (fruital, medium-height grass medicated incense, minty note etc.) or artificial essence, for instance limonene。
In one embodiment, described pH adjusting agent is selected from mineral acid, organic acid and salt thereof。Such as, pH adjusting agent is selected from citric acid, sodium citrate, phosphoric acid, sodium phosphate, lactic acid etc.。
In one embodiment, described viscosity modifier is selected from coconut oleoyl amine MEA, coconut oleoyl amine DEA, sodium chloride, ammonium chloride etc.。
In one embodiment, the cleansing composition of the present invention can also include plant, the extract of Sargassum or thalline, for instance can be from arithoke, polygonum tinctorium ait., Arnica montana, Aloe, Althaea rosea (L.) Cavan., angelica keiskei koidzumi, west Indian cherry, Fructus Pruni, Semen Armeniacae Amarum, Radix Hydrangeae Strigosae, Medulla Tetrapanacis, Pimpinella anisum Linn., American Avocado Tree, Herba Artemisiae Scopariae, Herba Urticae Cannabinae, Fructus Fragariae Ananssae, Fructus Foeniculi, Rhizoma Curcumae Longae, bisnaga, oolong tea, Radix Malvae sylvestris, Rosehips, Echinacea angustifolia, Herba bromi japonici, Trillium tschonoskii Maxim, edelweiss, Nasturtium officinale, Cortex Phellodendri, Radix Scutellariae, Rhizoma Coptidis, Flos Caryophylli Lagerstroemia indica L., Herba Hyperici Erecti, fragrant citrus, Flos abelmoschi manihot, Folium olive, black currant, Valeriana fauriei, Fructus Kaki, fire spine, Flos Matricariae chamomillae, Camu Camu, Radix Dauci Sativae, Artemisia dracunculus, wild oat, Radix Glycyrrhizae, Fructus Cucumidis sativi, Semen Armeniacae Amarum, Fructus actinidiae chinensis, quinine skin, Quillaia saponaria, Folium Trapae Caulis Hederae Sinensis, Jia Yelong tea, Fructus Rubi, Radix Sophorae Flavescentis, Sasa veitchii(Carr.)Rehd., mulberry, Semen Juglandis, grapefruit, East Asia Herba Erodii, Radix Gentianae, Alpinia nutaus, salacia reticulata, Fructus Arctii, Symphytum officinale, Fructus Tritici aestivi, oriental cherry, alkalium grass, Salvia japonica Thunb., Japan Fructus Crataegi, Herba Asari, funicle, fruit of Fructus Gardeniae, Ramulus et Folium Spiraeae Salicifolia, Herba Houttuyniae, Ma Ying, Rhizoma Acori Graminei, Rhizoma Zingiberis Recens, Radix Arnebiae (Radix Lithospermi), Folium Perillae, silver birch, Radix Paeoniae, Radix Rehmanniae, flat real Fructus Citri Limoniae, (simon one) Rhizoma Dioscoreae esculentae, Herba Equiseti Arvinsis, carambola, Radix Malvae sylvestris, Rhizoma Chuanxiong, Crataegus Oxyacantha, Caulis Hederae Sinensis, Pyrus communis, Salix alba, Salvia japonica Thunb., Japan's Herba Swertiae bimaculatae, Semen sojae atricolor, bigarabe, Herba thymi vulgaris, Citrus, Herba thymi vulgaris, tamarind, Folium Camelliae sinensis, Flos Caryophylli, Pericarpium Citri Reticulatae, Flos Camelliae Japonicae, Herba Houttuyniae, Radix Angelicae Sinensis, Semen Persicae, dry Pericarpium Citri junoris, Fructus Lycopersici esculenti, Flos Tagetis Erectae, Ampelopsis grossedentata, septfoil, Semen Maydis, margosa, Hoarhound., Ramulus Sambuci Williamsii, Bulbus Allii, Radix Dauci Sativae, Flos rosae multiflorae, myristica argentea Warburg, Hibiscus rosa-sinensis, parsley, Fructus Musae, Flos Rosae Rugosae, Semen Coicis, white feather fan Seem Lablab Album, hickory nut, Cupressus funebris, hyssop, Himalaya Fructus Rubi, very thin Herba Erodii, Symplocoris Paniculatae, European Pericarpium Citri tangerinae, Folium Eriobotryae, Fructus Pruni salicinae, Fructus Vitis viniferae, Flos Narcissi chinensis, Buddleia davidii, Jambul, Herba Menthae, Flos Carthami, Fructus Luffae, buckhorn plantain, white Wormwood, somewhat-white magnolia, bodhi tree, Peucedanum japonicum Thunb., Paeonia suffruticosa, hop, Jojoba, , Flos Rosae Rugosae, Aesculus chinensis Bunge, pinaster, Fructus Citri tangerinae, Fructus Sapindi Mukouossi, Herba Melissae officinalis, Radix Oenotherae erythrosepalae, Fructus Persicae, maple, Rodgersia podophylla A. Gray, Herba Saxifragae, Eucalyptus, Bulbus Lilii, Fructus Citri grandis, Semen Coicis, Folium Artemisiae Argyi, Cymbidium ensifolium (L.) Sw., Citrus aurantium Linn., lavandula angustifolia Caulis et Folium Lactucae Sativae, Fructus Mali pumilae, wilderness Artemisia, doctor's tea, Herba Astragali Melilotoidis (Herba Astragali Sinici), Fructus Citri Limoniae, Herba melissae axillaris, Rosehips, Herba Rosmarini Officinalis, chlorella, red algae, Brown algae, Poria, Lentinus Edodes, foxtail millet gill fungus, polypor, Tremella, Ganoderma, Cordyceps, yeast, lactic acid bacteria, the herb of root nodule bacteria, leaf, stem, root, fruit, seed, flower, sporophore, in thalline, use water；Or the organic solvent of glycerol, propylene glycol, ethanol, butanediol etc.；Or their mixed liquor；Or the extract that the oil preparation of olive oil, macadimia nut wet goods etc. carries out extracting and obtains。Chlorophyll also corresponds to plant extract。It addition, in spite of the culture fluid removing thalline by employing fresh milk, fruit juice, synthetic medium, the lactic acid bacteria of semisynthetic medium, yeast, all can use。
By the examples below the present invention is specifically described。Be necessary it is pointed out here that be; following example are served only for that the invention will be further described; it is not intended that limiting the scope of the invention; some nonessential improvement and adjustment that professional and technical personnel in the field makes according to the content of the invention described above, still fall within protection scope of the present invention。
It addition, illustrate without other, raw materials used is all commercially available, Jun Gou Chemical Reagent Co., Ltd., Sinopharm Group, and number used by following material is weight portion。
Raw material:
Polyoxyethylene-type anion surfactant:
Betaine type amphoteric ionic surface active agent:
B1: cocamido propyl betaine
B2: cocamidopropyl propyl amide hydroxyl sulfo betaine, the coco betaine percetage by weight 50% of coco betaine (percetage by weight 50% of cocamidopropyl propyl amide hydroxyl sulfo betaine)
B3: dodecanamide propyl hydroxy sulfo lycine
C1: glucose
D1: rhamnose, is structured with formula
Biosurfactant:
E1:
Wherein, R1For H；R2For C20Linear paraffin。
Preparation method:
E2:
Wherein, R1For H；R2For C12Linear paraffin。
E3:
Wherein, R1、R2It is C16Linear paraffin。
E4:
Wherein, R1For C3Linear paraffin, R2For C15Linear paraffin。
F1: cyclodextrin
G1: Polyethylene Glycol
Cyclo-dextrin-modified Polyethylene Glycol:
H1: the mol ratio 1:1 of Polyethylene Glycol and cyclodextrin；The number-average molecular weight of Polyethylene Glycol is 500；Cyclodextrin is: alpha-cyclodextrin。
H2: the mol ratio 1:4 of Polyethylene Glycol and cyclodextrin；The number-average molecular weight of Polyethylene Glycol is 1200；Cyclodextrin is: beta-schardinger dextrin-。
H3: the mol ratio 1:6 of Polyethylene Glycol and cyclodextrin；The number-average molecular weight of Polyethylene Glycol is 1600；Cyclodextrin is: 6-O-α-D-Maltose group-beta-cyclodextrin。
H4: the mol ratio 1:10 of Polyethylene Glycol and cyclodextrin；The number-average molecular weight of Polyethylene Glycol is 2000；Cyclodextrin is: gamma-cyclodextrin。
Chelating agen:
J1: chitosan
J2: citric acid
J3: hyaluronic acid
J4: tartaric acid
Preservative:
K1: potassium sorbate
PH adjusting agent:
L1: lactic acid
Viscosity modifier:
M1: sodium chloride
Plant extract:
N1: Ramulus Sambuci Williamsii extract
N2: buckhorn plantain extract, polypor extract
O1: water
Evaluation methodology:
1, toxotest
Experimental white mouse skin is tested, and standard GB/T 7919-87 skin irritation strength grading standard is in Table 1。
The evaluation criterion of table 1 tuerculoderma and comparing
By mouse skin toxicity test, the green environmental protection of test agent is evaluated。
Experiment material: oilpaper, elbow shears, gauze, adhesive plaster, syringe, binder, cotton swab, cage have；APG-12
Making by oneself for laboratory, product mass fraction of solids is more than 50%；Normal saline；Medical alcohol etc.。
Animal for research: provided by Shanghai Second Emdical University's medical college, white mice (cleaning grade, body weight 10～20g)。In advance in temperature (24 ± 2) DEG C, the Animal House of humidity 55% ± 10% feeds 4d, and drinking water is tap water。Take cleaning healthy mice 30, adapt to environment 4d。Take 15 therein, 24h before experiment, cuts general 3cm × 3cm by diamond wool in the middle of its back。Tested material is smeared uniformly in depilation district, and covers with double gauze and oilpaper, then go to be fixed with nonirritant binder and adhesive plaster, clean with warm water after 24h。Drawing " # " word scar with sterilization syringe needle on depilation skin before other 15 experiments, with oozing of blood for degree, administrations is identical with intact skin group。Check that death condition and the systemic toxicity profiles of white mice after being coated with tested material show every day。
2, fabric cleans rate
In order to verify the detergency of cleansing composition of the present invention, carry out detergency test。With reference to GB/T13174-2008 " the dress material mensuration of laundry detergents detergency and circulation scourability " standard, adopt GB white carbon black JB-01, GB albumen JB-02, tri-kinds of soiled cottons of GB sebum JB-03 to carry out test fabric and clean rate。
Experiment condition is: adopting 250ppm hard water, wash concentration 1-6g/L, wash time 15min, temperature 25 DEG C, adopting the RQHL type Terg-O-Tometer of national regulations, rotating speed is 60r/min。
Data above can be seen that, compared with the product not using biosurfactant and cyclo-dextrin-modified Polyethylene Glycol, the cleansing composition of the present invention has a rate of cleaning preferably, and the abluent clean environment firendly of the present invention, nontoxic, is thus provided that the Advantageous Effects of the present invention。
Aforesaid example is merely illustrative, for explaining some features of the feature of the disclosure。Appended claim is intended to the scope wide as far as possible that requirement it is contemplated that, and embodiments as presented herein is only the explanation of embodiment of selection of combination according to all possible embodiment。Therefore, the selectional restriction of the example that the claim that the purpose of applicant is appended is not illustrated inventive feature。And the progress in science and technology will form the possible equivalent not being presently considered due to the inaccurate reason of language performance or son replacement, and these changes also should be interpreted to be covered by appended claim in the conceived case。
Claims (10)
1. an environment-friendly liquid cleansing composition, it is characterised in that include the raw material of following weight portion,
The polyoxyethylene-type anion surfactant of 1～5 weight portion；
The betaine type amphoteric ionic surface active agent of 1～8 weight portion；
The biosurfactant of 3～10 weight portions；
The cyclo-dextrin-modified Polyethylene Glycol of 1～5 weight portion；
The chelating agen of 1～3 weight portion；With
The water of 100 weight portions；
Described biosurfactant is fatty alcohol modified rhamnose；
Described chelating agen is the compound at least including two carboxyls；
Described cyclo-dextrin-modified Polyethylene Glycol is that cyclodextrin penetrates peg molecule chain formation complex。
2. cleansing composition as claimed in claim 1, it is characterised in that the structural formula of described polyoxyethylene-type anion surfactant is:
;
Wherein, the R in formula1Can be H or C1～C6Alkane, R2Can be C4～C20Alkane, R3Can being any one in sulfate, sulfonate or carboxylate, n be 1 ~ 15。
3. cleansing composition as claimed in claim 1, it is characterised in that described biosurfactant is structured with formula:
；；
；；
In the combination of one or more structures；Wherein, R1、R2For H, C3～C20Alkane in any one, R1、R2It is asynchronously H。
4. cleansing composition as claimed in claim 1, it is characterised in that described biosurfactant is structured with formula:
；
Wherein, R1、R2For H, C12～C20Alkane in any one, R1、R2It is asynchronously H。
5. cleansing composition as claimed in claim 1, it is characterised in that in described cyclo-dextrin-modified Polyethylene Glycol, the mol ratio 1:10 of cyclodextrin and Polyethylene Glycol。
6. cleansing composition as claimed in claim 5, it is characterised in that the number-average molecular weight 500～2000 of described Polyethylene Glycol。
7. cleansing composition as claimed in claim 5, it is characterised in that described cyclodextrin is any one in alpha-cyclodextrin, beta-schardinger dextrin-, 6-O-α-D-Maltose group-beta-cyclodextrin, gamma-cyclodextrin。
8. as claimed in claim 1 cleansing composition, it is characterised in that described chelating agen is selected from: any one in hyaluronic acid, chitosan, citric acid, tartaric acid, glucaric acid。
9. cleansing composition as claimed in claim 1, it is characterised in that it also includes the pH adjusting agent of 0.5～1 weight portion, and described pH adjusting agent is lactic acid。
10. cleansing composition as claimed in claim 9, it is characterised in that it also includes the viscosity modifier of 0.5～1 weight portion, and described viscosity modifier is sodium chloride。
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106947626A (en) * | 2017-04-14 | 2017-07-14 | 佛山市海科知识产权交易有限公司 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
| CN107099394A (en) * | 2017-05-30 | 2017-08-29 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of cleaning fluid for removing dyestuff and preparation method thereof |
| CN107177424A (en) * | 2017-06-25 | 2017-09-19 | 长沙善道新材料科技有限公司 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
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| CN106947626A (en) * | 2017-04-14 | 2017-07-14 | 佛山市海科知识产权交易有限公司 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
| CN107099394A (en) * | 2017-05-30 | 2017-08-29 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of cleaning fluid for removing dyestuff and preparation method thereof |
| CN107177424A (en) * | 2017-06-25 | 2017-09-19 | 长沙善道新材料科技有限公司 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
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