CN114507572A - Long-acting solid laundry detergent ball and preparation method thereof - Google Patents
Long-acting solid laundry detergent ball and preparation method thereof Download PDFInfo
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- CN114507572A CN114507572A CN202210142278.7A CN202210142278A CN114507572A CN 114507572 A CN114507572 A CN 114507572A CN 202210142278 A CN202210142278 A CN 202210142278A CN 114507572 A CN114507572 A CN 114507572A
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- long
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- laundry detergent
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- 239000007787 solid Substances 0.000 title claims abstract description 137
- 239000003599 detergent Substances 0.000 title claims abstract description 112
- 238000002360 preparation method Methods 0.000 title abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 60
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 46
- 239000011707 mineral Substances 0.000 claims abstract description 46
- 239000002994 raw material Substances 0.000 claims abstract description 43
- 239000004094 surface-active agent Substances 0.000 claims abstract description 40
- 239000010410 layer Substances 0.000 claims abstract description 37
- 239000002245 particle Substances 0.000 claims abstract description 37
- 239000000686 essence Substances 0.000 claims abstract description 31
- 239000000344 soap Substances 0.000 claims abstract description 24
- 102000004190 Enzymes Human genes 0.000 claims abstract description 22
- 108090000790 Enzymes Proteins 0.000 claims abstract description 22
- 239000011247 coating layer Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 17
- 239000008187 granular material Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 19
- 238000001035 drying Methods 0.000 claims description 12
- 239000004113 Sepiolite Substances 0.000 claims description 9
- 229910052624 sepiolite Inorganic materials 0.000 claims description 9
- 235000019355 sepiolite Nutrition 0.000 claims description 9
- 238000005469 granulation Methods 0.000 claims description 8
- 230000003179 granulation Effects 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- 244000178870 Lavandula angustifolia Species 0.000 claims description 6
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 6
- 239000001102 lavandula vera Substances 0.000 claims description 6
- 235000018219 lavender Nutrition 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 5
- 241000220317 Rosa Species 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000004575 stone Substances 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000005202 decontamination Methods 0.000 claims description 4
- 230000003588 decontaminative effect Effects 0.000 claims description 4
- 230000005923 long-lasting effect Effects 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052622 kaolinite Inorganic materials 0.000 claims description 3
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 108700004121 sarkosyl Proteins 0.000 claims description 3
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 3
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 3
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 3
- JZVZOOVZQIIUGY-UHFFFAOYSA-M sodium;tridecanoate Chemical group [Na+].CCCCCCCCCCCCC([O-])=O JZVZOOVZQIIUGY-UHFFFAOYSA-M 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 229940079988 potassium cocoyl glycinate Drugs 0.000 claims description 2
- 239000002243 precursor Substances 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 240000005385 Jasminum sambac Species 0.000 claims 2
- 244000060011 Cocos nucifera Species 0.000 claims 1
- 235000013162 Cocos nucifera Nutrition 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 32
- 238000000034 method Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000004744 fabric Substances 0.000 description 10
- 239000011324 bead Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 241000207840 Jasminum Species 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- -1 sodium alkyl benzene Chemical class 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000002210 biocatalytic effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- GZWNUORNEQHOAW-UHFFFAOYSA-M potassium;2-aminoacetate Chemical compound [K+].NCC([O-])=O GZWNUORNEQHOAW-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012629 purifying agent Substances 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/32—Protein hydrolysates; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of detergents, and particularly relates to a long-acting solid laundry detergent ball and a preparation method thereof. The solid mother particles comprise the following raw materials: a mineral and a first surfactant. The coating layer coats the solid mother particles and comprises the following raw materials: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder. The long-acting solid washing and decontaminating ball has the characteristic of repeated use. According to the preparation method of the long-acting solid laundry detergent ball, the solid mother particles are prepared by a granulating method of the granulator, then the raw materials of the coating layer are coated on the solid mother particles layer by layer to prepare the coating layer, and the prepared long-acting solid laundry detergent ball has a multilayer structure, so that the long-acting solid laundry detergent ball can be used for multiple times, and the properties and the performance of the long-acting solid laundry detergent ball are stable after the long-acting solid laundry detergent ball is used for multiple times.
Description
Technical Field
The invention belongs to the technical field of detergents, and particularly relates to a long-acting solid laundry detergent ball and a preparation method thereof.
Background
Traditional laundry detergents are primarily laundry powders, laundry detergents and laundry beads. The washing powder is a powdery (granular) synthetic detergent. The main components of the washing powder are anionic surfactant, sodium alkyl benzene sulfonate, small amount of non-ionic surfactant, some assistant, phosphate, silicate, anhydrous sodium sulphate, fluorescent agent, enzyme, etc. and the washing powder is prepared through mixing, powder spraying and other processes. The laundry detergent mostly adopts nonionic surfactants, the pH is close to neutral, the laundry detergent is mild to the skin, and after the laundry detergent is discharged into the nature, the laundry detergent is degraded faster than washing powder, so the laundry detergent becomes a new generation of detergent. The washing gel bead is also called as a washing bead, is an innovative washing product, and is named as a washing gel bead because the shape of the washing gel bead is similar to a bead.
The detergent is a disposable detergent, namely, the detergent is added once every time the detergent is washed, so that the step of adding the detergent is carried out every time the detergent is washed. There is also no detergent in the prior art that can be used multiple times.
Disclosure of Invention
The invention aims to provide a long-acting solid laundry detergent ball and a preparation method thereof, and aims to solve the technical problem that a detergent which can be used for multiple times is lacked in the prior art.
In order to achieve the above object, an embodiment of the present invention provides a long-acting solid laundry detergent ball, including:
a solid precursor particle comprising the following starting materials: a mineral and a first surfactant; and
a wrapping layer wrapping the solid mother particles, wherein the wrapping layer comprises the following raw materials: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder.
Optionally, the solid parent particle comprises the following raw materials: 0.1-1 parts by weight of a mineral and 0.1-3 parts by weight of a first surfactant;
the wrapping layer comprises the following raw materials: 1-8 parts of soap powder, 0.5-5 parts of biological enzyme, 0.1-1 part of second surfactant, 0.1-1 part of thickening agent, 0.05-0.5 part of essence and 0.1-1 part of mineral powder.
Optionally, the solid parent particle comprises the following raw materials: 0.3-0.7 parts by weight of a mineral and 0.5-1.5 parts by weight of a first surfactant;
the wrapping layer comprises the following raw materials: 1-5 parts of soap powder, 1-3 parts of biological enzyme, 0.1-0.5 part of second surfactant, 0.3-0.7 part of thickening agent, 0.1-0.3 part of essence and 0.3-0.7 part of mineral powder.
Optionally, the mineral is selected from any one or a mixture of at least two of medical stone, talc, kaolinite, montmorillonite or zeolite.
Optionally, the mineral has a particle size of 50-150 mesh.
Optionally, the mineral powder is sepiolite powder.
Optionally, the first surfactant is selected from any one or a mixture of at least two of cocoyl diethanolamine, potassium cocoyl glycinate, sodium cocoyl glutamate and sodium lauroyl sarcosinate; the second surfactant is sodium tridecanoate or sodium fatty acid methyl ester sulfonate; the essence is selected from any one of lavender essence, rose essence, jasmine essence or fruit essence or a mixture of at least two of the lavender essence, the rose essence, the jasmine essence and the fruit essence.
Optionally, the soap powder is a natural plant soap powder.
One or more technical schemes in the long-acting solid laundry and decontamination ball provided by the embodiment of the invention have at least one of the following technical effects:
1. the long-acting solid laundry detergent ball has the characteristic of being reusable, and through testing, the long-acting solid laundry detergent ball with the diameter of 12mm is mixed with 1L-2L of water (the amount of a washing solution in conventional washing), after water is added for many times, the long-acting solid laundry detergent ball is measured, and the diameter change of the long-acting solid laundry detergent ball used in each time of average water adding is calculated to be 0.05mm-0.1 mm; the long-acting solid laundry detergent ball can keep stable detergent power in 60-100 times of use; in practical application, the long-acting solid laundry detergent ball can be matched with an adding device and a washing machine, the long-acting solid laundry detergent ball is placed in the adding device, tap water is mixed with the long-acting solid laundry detergent ball through the adding device to release a detergent, and the detergent is added into the washing machine, so that the trouble that the detergent needs to be added every time of washing is avoided, and the use is more convenient;
2. the long-acting solid laundry detergent ball has excellent detergency, and the specific values of the detergency of the specified dirty cloth measured according to GB/T13174-2088 'determination of detergents for clothing and circulating washing performance' are respectively as follows: 1. carbon black greasy dirt cloth: 1.05; 2. protein-polluted cloth: 1.8; 3. sebum-stained cloth: 1.8;
3. the raw materials of the long-acting solid laundry detergent ball are environment-friendly and safe.
In order to achieve the above object, the preparation method of the long-acting solid laundry detergent ball provided by the embodiment of the present invention comprises the following steps:
1) preparing solid mother particles: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, and starting the granulator to mix materials until solid mother granules with the diameter of 1mm-5mm are formed; pouring out the solid mother particles, drying and cooling;
2) preparing a wrapping layer: weighing the raw materials of the wrapping layer: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder; and (2) reintroducing the completely cooled solid mother granules into a granulation tank of a granulator, starting the granulator, wetting the solid mother granules by using a sprayer, mixing the raw materials of the coating layer, adding the mixture into the granulation tank in a grading manner, wherein the raw materials of the coating layer are coated on the solid mother granules layer by layer at intervals of 2-8 seconds every time until granular spheres with diameters of 6-15 mm are formed, and drying the granular spheres to obtain the long-acting solid laundry detergent ball.
One or more technical schemes in the preparation method of the long-acting solid laundry detergent ball provided by the embodiment of the invention have at least one of the following technical effects: according to the preparation method of the long-acting solid laundry detergent ball, the solid mother particles are prepared by a granulating method of the granulator, then the raw materials of the coating layer are coated on the solid mother particles layer by layer to prepare the coating layer, and the prepared long-acting solid laundry detergent ball has a multilayer structure, so that the long-acting solid laundry detergent ball can be used for multiple times, and the properties and the performance of the long-acting solid laundry detergent ball are stable after the long-acting solid laundry detergent ball is used for multiple times.
In order to achieve the above object, an embodiment of the present invention provides a method for preparing a long-acting solid laundry detergent ball, including the following steps:
1) preparing solid mother particles: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, and starting the granulator to mix materials until solid mother granules with the diameter of 1mm-5mm are formed; pouring out the solid mother particles, drying and cooling;
2) preparing a wrapping layer: weighing the raw materials of the wrapping layer: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder; and adding the mixed raw materials of the coating layer and the solid mother particles into a plodder for layering, and then dicing to prepare the long-acting solid laundry detergent ball.
One or more technical schemes in the preparation method of the long-acting solid laundry detergent ball provided by the embodiment of the invention have at least one of the following technical effects: the long-acting solid laundry detergent ball prepared by the preparation method of the long-acting solid laundry detergent ball through the plodder has the characteristics of high production effect and high production speed.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the embodiments or the prior art descriptions will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise.
Fig. 1 is a schematic diagram of a photograph of a long-acting solid laundry detergent ball according to an embodiment of the present invention.
Fig. 2 is a structural solid diagram of a long-acting solid laundry detergent ball provided in an embodiment of the present invention.
Detailed Description
The present invention will be further described with reference to the following examples, but the embodiments of the present invention are not limited thereto.
In an embodiment of the present invention, illustrated in fig. 1-2, there is provided a long-lasting solid laundry detergent ball comprising a solid matrix particle 1 and a coating 2, it being understood that fig. 2 illustrates only the structure of the long-lasting solid laundry detergent ball and is not intended to be limiting as to its size and proportions. The solid mother particle 1 comprises the following raw materials: a mineral and a first surfactant. The coating layer 2 coats the solid mother particles 1, and the coating layer 2 comprises the following raw materials: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder.
In an embodiment of the invention, the solid mother particle 1 comprises the following raw materials: 0.1-1 parts by weight of mineral and 0.1-3 parts by weight of first surfactant.
The wrapping layer 2 comprises the following raw materials: 1-8 parts of soap powder, 0.5-5 parts of biological enzyme, 0.1-1 part of second surfactant, 0.1-1 part of thickening agent, 0.05-0.5 part of essence and 0.1-1 part of mineral powder.
In an embodiment of the invention, the solid mother particle 1 comprises the following raw materials: 0.3-0.7 parts by weight of mineral and 0.5-1.5 parts by weight of first surfactant.
The wrapping layer 2 comprises the following raw materials: 1-5 parts of soap powder, 1-3 parts of biological enzyme, 0.1-0.5 part of second surfactant, 0.3-0.7 part of thickening agent, 0.1-0.3 part of essence and 0.3-0.7 part of mineral powder.
In an embodiment of the invention, the mineral is selected from any one or a mixture of at least two of medical stone, talc, kaolinite, montmorillonite or zeolite. Furthermore, the mineral is preferably medical stone which is a natural silicate mineral and is non-toxic. The medical stone is a compound mineral which is non-toxic and harmless to organisms and has certain bioactivity, has strong adsorption force and water purification effect, and is particularly suitable for manufacturing the long-acting solid laundry detergent ball.
In the examples of the present invention, the mineral has a particle size of 50 to 150 mesh. The minerals having the above particle diameters are easy to mix and disperse, and are suitable as carriers.
In an embodiment of the invention, the mineral powder is sepiolite powder. Sepiolite powder is a water-containing magnesium-rich silicate clay mineral powder with a layer chain structure. Sepiolite powder is a very useful filter aid, and its filter aid capacity is combined with its adsorptive properties. Sepiolite powder can also be used as a purifying agent: can be used as softener for hard water, and cation of clay is used for exchanging calcium and magnesium ions in water. Sepiolite powder has a large active surface area, retains the active product and can be used as an excipient. In addition, the sepiolite powder also has multiple functions of a decolorizing agent, an additive carrier and the like. The sepiolite powder can greatly improve the efficiency of the invention.
In an embodiment of the invention, the essence is selected from any one of lavender essence, rose essence, jasmine essence or fruit essence or a mixture of at least two of the same. Specifically, the essence is lavender essence.
In an embodiment of the invention, the first surfactant is selected from any one of or a mixture of at least two of cocoyl diethanolamine, cocoyl potassium glycinate, sodium cocoyl glutamate and sodium lauroyl sarcosinate. The second surfactant is sodium tridecanoate or sodium fatty acid methyl ester sulfonate.
In an embodiment of the present invention, the soap powder is a natural plant soap powder. The natural plant soap powder has the characteristics of naturalness, strong decontamination, ultra-low foam, easy rinsing and the like, has low irritation to skin, protects fabrics, enables washed clothes to be fluffy and soft without using a softener, and solves the problems of dirt deposition, hardening, static electrification and the like of the fabrics after multiple times of washing.
In the embodiment of the invention, the biological enzyme is a macromolecular protein, and compared with a synthetic detergent, the biological enzyme only transfers stains from the surface of an article to a washing solution, the cleaning principle of the biological enzyme is to convert the stains into water-soluble small molecules by utilizing the biocatalytic decomposition effect, and the biological enzyme has the main characteristics of zero pollution, safety, no toxicity and high-efficiency cleaning.
Therefore, most of the raw materials of the long-acting solid laundry detergent ball are environment-friendly and safe raw materials, and the long-acting solid laundry detergent ball has little stimulation to human bodies.
The long-acting solid laundry detergent ball has the characteristic of being reusable, and through testing, the long-acting solid laundry detergent ball with the diameter of 12mm is mixed with 1L-2L (the amount of a washing solution in conventional washing), after water is added for many times, the long-acting solid laundry detergent ball is measured, and the diameter change of the long-acting solid laundry detergent ball used in each time of average water adding is calculated to be 0.05mm-0.1 mm; the long-acting solid laundry detergent ball can keep stable detergent power in 60-100 times of use; in practical application, an adding device (such as a detergent dispenser disclosed in the publication No. CN 113308311A) and a washing machine can be matched, the long-acting solid laundry detergent ball is placed in the adding device, tap water is mixed with the long-acting solid laundry detergent ball through the adding device to release detergent, and the detergent is added into the washing machine, so that the trouble that the detergent needs to be added every time of washing is avoided, and the use is more convenient.
The long-acting solid laundry detergent ball has excellent detergency, and the specific values of the detergency of the specified dirty cloth measured according to GB/T13174-2088 'determination of detergents for clothing and circulating washing performance' are respectively as follows: 1. carbon black greasy dirt cloth: 1.05; 2. protein-polluted cloth: 1.8; 3. sebum-stained cloth: 1.8.
in an embodiment of the present invention, a preparation method of the long-acting solid laundry detergent ball is provided, including the following steps:
1) preparation of solid mother granules 1: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, starting the granulator to mix materials, and stabilizing the rotation speed of the granulator at 50-60 rpm/s until solid mother granules 1 with the diameter of 1-5 mm are formed; pouring out the solid mother particles 1, drying and cooling;
2) preparing a wrapping layer 2: weighing the raw materials of the wrapping layer 2: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder; and (2) reintroducing the completely cooled solid mother granules 1 into a granulation tank of a granulator, starting the granulator, wetting the solid mother granules 1 by using a sprayer, mixing the raw materials of the coating layer 2, adding the mixture into the granulation tank in batches at intervals of 2-8 seconds every time, coating the raw materials of the coating layer 2 on the solid mother granules 1 layer by layer until granular spheres with diameters of 6-15 mm are formed, and drying the granular spheres to obtain the long-acting solid laundry detergent ball.
In the embodiment of the invention, the long-acting solid laundry detergent ball can be prepared by adding a coagulant to avoid a drying step.
In an embodiment of the present invention, there is provided another preparation method of the long-acting solid laundry detergent ball, including the following steps:
1) preparation of solid mother granules 1: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, and starting the granulator to mix materials until solid mother granules 1 with the diameter of 1mm-5mm are formed; pouring out the solid mother particles 1, drying and cooling;
2) preparing a wrapping layer 2: weighing the raw materials of the wrapping layer 2: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder; and adding the mixed raw materials of the coating layer 2 and the solid mother particles 1 into a plodder for layering, and then cutting into granules to prepare the long-acting solid laundry detergent ball.
For a further understanding of the invention, reference will now be made to the preferred embodiments of the invention by way of example, and it is to be understood that the description is intended to further illustrate features and advantages of the invention, and not to limit the scope of the claims.
The raw materials and the proportions used in examples 1 to 5 are shown in Table 1.
Examples 1 to 5
The method of making the long-lasting solid laundry detergent ball of examples 1-5, comprising the steps of:
1) preparation of solid mother granules 1: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, starting the granulator to mix materials, and stabilizing the rotation speed of the granulator at 50-60 rpm/s until solid mother granules 1 with the diameter of 1-5 mm are formed; pouring out the solid mother particles 1, drying and cooling;
2) preparing a wrapping layer 2: weighing the raw materials of the wrapping layer 2: soap powder, biological enzyme and/or secondary surfactant, thickener, essence and mineral powder; and (2) reintroducing the completely cooled solid mother granules 1 into a granulation tank of a granulator, starting the granulator, wetting the solid mother granules 1 by using a sprayer, mixing the raw materials of the coating layer 2, adding the mixture into the granulation tank in batches at intervals of 2-8 seconds every time, coating the raw materials of the coating layer 2 on the solid mother granules 1 layer by layer until granular spheres with diameters of 6-15 mm are formed, and drying the granular spheres to obtain the long-acting solid laundry detergent ball.
Example 6
In this example, the long-acting solid laundry detergent ball (as shown in FIG. 1) prepared in example 3 was tested for its detergency and long-acting detergency according to GB/T13174-2088, measurement of laundry detergent and cycle washing performance, and the test results are shown in tables 2 and 3.
TABLE 2
From the test results in table 2, it can be seen that the long-acting solid laundry detergent ball of the present invention has a higher detergency against various specified soiled cloths than the standard laundry detergent, and also laterally reflects that the long-acting solid laundry detergent ball of the present invention has a stronger detergency.
The long-acting dirt-removing capacity test method of the long-acting solid laundry dirt-removing ball comprises the following steps: the diameter of the long-acting solid laundry detergent ball is measured after the long-acting solid laundry detergent ball with the diameter of 12mm is mixed with 1L of water (the amount of a washing solution in conventional washing) and is dried after water is added for a plurality of times.
TABLE 3
Calculating to obtain the diameter change of the long-acting solid washing and decontaminating ball used for washing clothes every time, which is 0.05mm-0.1 mm; namely, the detergent is not consumed after being added with water for many times, and the internal decontamination components are released continuously. The long-acting solid laundry detergent ball can keep stable detergent capacity at least in 60-100 times of use; in practical application, the long-acting solid laundry detergent ball can be matched with an adding device and a washing machine, the long-acting solid laundry detergent ball is placed in the adding device, tap water is mixed with the long-acting solid laundry detergent ball through the adding device to release a detergent, and the detergent is added into the washing machine, so that the trouble that the detergent needs to be added every time of washing is avoided, and the use is more convenient.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (10)
1. A long-lasting solid laundry detergent ball comprising:
a solid precursor particle comprising the following starting materials: a mineral and a first surfactant; and
a wrapping layer wrapping the solid mother particles, wherein the wrapping layer comprises the following raw materials: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder.
2. The long-acting solid laundry detergent ball according to claim 1, wherein the solid parent particle comprises the following raw materials: 0.1-1 parts by weight of a mineral and 0.1-3 parts by weight of a first surfactant;
the wrapping layer comprises the following raw materials: 1-8 parts of soap powder, 0.5-5 parts of biological enzyme, 0.1-1 part of second surfactant, 0.1-1 part of thickening agent, 0.05-0.5 part of essence and 0.1-1 part of mineral powder.
3. The long-acting solid laundry detergent ball according to claim 1, wherein the solid parent particle comprises the following raw materials: 0.3-0.7 parts by weight of a mineral and 0.5-1.5 parts by weight of a first surfactant;
the wrapping layer comprises the following raw materials: 1-5 parts of soap powder, 1-3 parts of biological enzyme, 0.1-0.5 part of second surfactant, 0.3-0.7 part of thickening agent, 0.1-0.3 part of essence and 0.3-0.7 part of mineral powder.
4. A long-acting solid laundry detergent ball as claimed in any one of claims 1 to 3, characterised in that the mineral is selected from any one or a mixture of at least two of medical stone, talc, kaolinite, montmorillonite or zeolite.
5. The long-acting solid laundry detergent ball according to any one of claims 1-3, wherein the mineral has a particle size of 50-150 mesh.
6. The long-acting solid laundry detergent ball according to any one of claims 1-3, wherein the mineral powder is sepiolite powder.
7. The long-acting solid laundry detergent ball according to any one of claims 1-3, wherein the first surfactant is selected from any one or a mixture of at least two of coconut diethanol amide, potassium cocoyl glycinate, sodium cocoyl glutamate and sodium lauroyl sarcosinate; the second surfactant is sodium tridecanoate or sodium fatty acid methyl ester sulfonate; the essence is selected from any one of lavender essence, rose essence, jasmine essence or fruit essence or a mixture of at least two of the lavender essence, the rose essence, the jasmine essence and the fruit essence.
8. The long-acting solid laundry detergent ball according to any of claims 1-3, wherein the soap powder is a natural plant soap powder.
9. A method of making a long-acting solid laundry detergent ball according to any of claims 1-8, comprising the steps of:
1) preparing solid mother particles: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, and starting the granulator to mix materials until solid mother granules with the diameter of 1mm-5mm are formed; pouring out the solid mother particles, drying and cooling;
2) preparing a wrapping layer: weighing the raw materials of the wrapping layer: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder; and (2) reintroducing the completely cooled solid mother granules into a granulation tank of a granulator, starting the granulator, wetting the solid mother granules by using a sprayer, mixing the raw materials of the coating layer, adding the mixed raw materials into the granulation tank in a grading manner, wherein the interval of each time is 2-8 seconds, coating the raw materials of the coating layer on the solid mother granules layer by layer until granular spheres with the diameter of 6-15 mm are formed, and drying the granular spheres to obtain the long-acting solid laundry and decontamination ball.
10. A method of making a long-acting solid laundry detergent ball according to any of claims 1-8, comprising the steps of:
1) preparing solid mother particles: uniformly stirring the minerals and the first surfactant, pouring the mixture into a granulating tank of a granulator, and starting the granulator to mix materials until solid mother granules with the diameter of 1mm-5mm are formed; pouring out the solid mother particles, drying and cooling;
2) preparing a wrapping layer: weighing the raw materials of the wrapping layer: soap powder, biological enzyme, a second surfactant, a thickening agent, essence and mineral powder; and adding the mixed raw materials of the coating layer and the solid mother particles into a plodder for layering, and then dicing to prepare the long-acting solid laundry detergent ball.
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| CN2021104801051 | 2021-04-30 | ||
| CN202110480105.1A CN113136266A (en) | 2021-04-30 | 2021-04-30 | Solid laundry detergent ball and preparation method thereof |
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| GB8318537D0 (en) * | 1982-07-09 | 1983-08-10 | Colgate Palmolive Co | Detergent composition |
| WO1998050509A1 (en) * | 1997-05-02 | 1998-11-12 | Clariant Gmbh | Method for producing granulates with a long shelf life containing soil release polymers and the use thereof for the production of solid detergents and cleaning agents |
| CN1225940A (en) * | 1998-02-13 | 1999-08-18 | 吕秀娟 | High-molecular active solid detergent composition and making method thereof |
| WO2002053697A1 (en) * | 2001-01-08 | 2002-07-11 | Reckitt Benckiser N.V. | A process for the production of cleaning agents |
| US20070111919A1 (en) * | 2003-12-19 | 2007-05-17 | Renee Boerefijn | Detergent granules and process for their manufacture |
| WO2008040152A1 (en) * | 2006-09-01 | 2008-04-10 | Tao Wang | A solid detergent and its preparation method |
| CN101358161A (en) * | 2008-09-03 | 2009-02-04 | 南风化工集团股份有限公司 | Novel energy-saving composite surface active agent post-match particle |
| CN107177424A (en) * | 2017-06-25 | 2017-09-19 | 长沙善道新材料科技有限公司 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
| CN108300623A (en) * | 2018-03-02 | 2018-07-20 | 胡小玲 | Granular laundry agent and preparation method thereof |
-
2021
- 2021-04-30 CN CN202110480105.1A patent/CN113136266A/en not_active Withdrawn
-
2022
- 2022-02-16 CN CN202210142278.7A patent/CN114507572A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8318537D0 (en) * | 1982-07-09 | 1983-08-10 | Colgate Palmolive Co | Detergent composition |
| WO1998050509A1 (en) * | 1997-05-02 | 1998-11-12 | Clariant Gmbh | Method for producing granulates with a long shelf life containing soil release polymers and the use thereof for the production of solid detergents and cleaning agents |
| CN1225940A (en) * | 1998-02-13 | 1999-08-18 | 吕秀娟 | High-molecular active solid detergent composition and making method thereof |
| WO2002053697A1 (en) * | 2001-01-08 | 2002-07-11 | Reckitt Benckiser N.V. | A process for the production of cleaning agents |
| US20070111919A1 (en) * | 2003-12-19 | 2007-05-17 | Renee Boerefijn | Detergent granules and process for their manufacture |
| WO2008040152A1 (en) * | 2006-09-01 | 2008-04-10 | Tao Wang | A solid detergent and its preparation method |
| CN101358161A (en) * | 2008-09-03 | 2009-02-04 | 南风化工集团股份有限公司 | Novel energy-saving composite surface active agent post-match particle |
| CN107177424A (en) * | 2017-06-25 | 2017-09-19 | 长沙善道新材料科技有限公司 | It is a kind of to contain enzymatic detergent suitable for what low temperature was washed |
| CN108300623A (en) * | 2018-03-02 | 2018-07-20 | 胡小玲 | Granular laundry agent and preparation method thereof |
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Application publication date: 20220517 |