CN1071452A - Detergent mixture and its production and use - Google Patents
Detergent mixture and its production and use Download PDFInfo
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- CN1071452A CN1071452A CN 91107507 CN91107507A CN1071452A CN 1071452 A CN1071452 A CN 1071452A CN 91107507 CN91107507 CN 91107507 CN 91107507 A CN91107507 A CN 91107507A CN 1071452 A CN1071452 A CN 1071452A
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Abstract
What the present invention relates to is Powdered detergent mixture and its production and use.This method comprises: the various tensio-active agents that will form clean-out system mix with the mineral powder that 30 orders-500 order (Tyler mesh) has adsorptivity, thereby obtain scribbling the mixture with adsorptivity of these tensio-active agents.The mineral powder can be selected diatomite, wilkinite, sub-bentonite, Fuller's earth, zeolite or swelling perlite powder for use.Detergent mixture of the present invention is used for metal and other crust smeary and cleans, and effect is splendid.And can at room temperature use.Be used for civilian can be as having the broad spectrum sterilized cleanser.
Description
It is the method and the purposes of the detergent mixture of major ingredient with adsorptivity mineral powder that the present invention has provided preparation.Be clean-out system and disinfecting and decontaminating agent field in the daily chemical industry.
Commercially available metal cleaner or dish washing detergent are one for its composition can be dissolved each other, and the water that needs to add 30-70% is as solubility promoter, so poor stability, cleaning performance also has much room for improvement, the packed and transported difficulty.
Sterilization insecticide washing powder described in No. 85100011.8, the Chinese patent, washing and sterilising effect are fine, but because the sterilant that adopts is chloramine-T, Surchlor GR 60, so bigger irritating smell is in use arranged, on the substrate peculiar smell is arranged also simultaneously, need with big water gaging flushing.
Purpose of the present invention provides a kind of detergent mixture based on the stronger mineral powder of adsorptivity in order to overcome above-mentioned shortcoming exactly.Tensio-active agent is selected non-ionic type and cationic for use, and its kind and weight percent are:
Title weight percent best values
Trihydroxy ethylamine oleate soap 1-50 5-30
Soxylat A 25-7 alkylphenol 1-80 3-30
Dodecyl dixylyl quaternary amine hydrochlorate 1-20 3-10
Dodecyl diglycollic amide 1-90 5-60
Oleum Cocois alkylol amide phosphoric acid fat 1-90 5-60
Adsorptivity mineral powder is selected for use: diatomite, wilkinite, sub-bentonite, zeolite, pearlstone.Use one or more all can.Fineness is standard sieve 30 order to 500 orders.
For the ease of narration, the composition of above-mentioned promoting agent is called the liquid phase component, the mineral powder with absorption property is called the solid phase component.
Each material of the liquid phase component that the present invention selects for use can both be molten with any ratio and water, and they produce synergy in the scavenging solution aqueous solution, all fine to various smeary cleaning performances.Every kind of material in the solid phase component that the present invention selects for use, through after the general processing treatment, the specific surface of powder is all bigger.Be a kind of bulk body, its loose volume weight is a 0.1-0.6 gram/square centimeter.Have stronger adsorptive power, stable chemical performance, water insoluble, react with not with liquid phase component compatibility the time.In the cleaning objects process, very easily washed out by water.During greasy dirt on cleaning crust, it is not all right only adopting the solid phase component.But only adopt the liquid phase component to be fine, cleaning greasy dirt kind is more extensive, to plant, animal and mineral greasy dirt and comprehensive greasy dirt, all has better cleaning effect.Just consumption is big, foam is many, needs after the cleaning with a large amount of water flushings.As being subjected to the restriction of national pollution exhaust criteria when using in that industrial and mining enterprises are large batch of.Simultaneously this liquid phase component is when being mixed with washing composition, and for mutual dissolving need add the moisture content of 30%-70%, making needs the easy layering of product and rotten to adopt charging basket (irony or plastics) packing on these, and this extremely frigid zones that is packaged in is easily by bursting by freezing.Packing and transportation cost are all very big.
The invention solves above-mentioned difficulties.Because the solid phase component is to form with the stronger mineral powder of adsorptivity, when it mixed with the liquid phase component, just mixing and stirring was just passable on the technology, mixed product is the wet shape powder of semi-drying meal or oil, do not have flowability, to subzero 30 ℃ environment, do not tie lump, never degenerate at 100 ℃.Can adopt plastic bag packaging, owing to do not have the adding of moisture content, constant product quality, but standing storage.This user to extremely frigid zones provides very big convenience beyond doubt.
Adopt detergent mixture of the present invention, under identical situation, lack when cleaning greasy dirt than the tensio-active agent that clean-out system consumed of independent use liquid phase component.Be coated in equably on 100 square centimeters the sheet glass as artificial greasy dirt (HB-5226-82), at room temperature clean 1 gram.As use detergent mixture of the present invention, need 0.33 gram, wherein surfactant content and 0.33x15%=0.05 gram.As use best brand of product 664 clean-out systems of Shanghai petrochemical complex three factories, and then needing the tensio-active agent of 0.07 gram, unit consumption has increased 0.07-0.05
〔-=0.4〕
0.05
40%。This is because the adding of solid phase component has adsorbing mineral dust greasy dirt has been played certain adsorption, thereby reduced the consumption of tensio-active agent.
Adopt the disinfecting and decontaminating powder of the present invention's preparation, do not have any irritating smell, non-corrosiveness, strong detergency, sterilization effect is good.Dodecyl dixylyl quaternary amine hydrochlorate is a cationic surfactant, and 45% effective concentration is the oily body at normal temperatures, is the broad spectrum type sterilant.To gram-positive microorganism and Gram-negative bacteria such as streptococcus aureus, mould etc., through contact in several minutes, protein of bacteria was solidified, reach sterilization functions.This product can not with the anion surfactant compatibility, can with the nonionogenic tenside compatibility.So when adopting this product preparation sterilant all is liquids.The present invention is with the dodecyl dixylyl quaternary amine hydrochlorate of 45% effective concentration, on mineral dust with high absorption property, with the tensio-active agent compatibility of non-ionic type, this just exists with pulverous form again, and this preparation method is had no effect to its effect of going out.More convenient in the use.
Embodiment 1
Component title weight percent
Trihydroxy ethylamine oleate soap 2.25
Soxylat A 25-7 alkylphenol 1.80
Dodecyl dixylyl quaternary amine hydrochlorate 0.45
Dodecyl diglycollic amide 5.25
Oleum Cocois alkylol amide phosphoric acid fat 5.25
Adsorptivity mineral dust 85.00
Compound method: with the liquid phase component respectively or mix and be sprayed on the adsorptivity mineral dust, both mix can.Mixed meal still has sorption property preferably.In use, powder being sprinkling upon on the surface that is cleaned thing, is flowable as greasy dirt, then be attracted to immediately on the powder, then with a little hydromining with scrubbing or cleaning.Tensio-active agent in the powder is soluble in water at this moment, and produces emulsifying effect with the greasy dirt that is cleaned the thing surface, and some greasy dirt is adsorbed by mineral dust simultaneously.Secondary so repeatedly, just available a little water flushing.Then the substrate surface is washed completely, and light as before.Detergent mixture of the present invention is applicable to the artificial leather product; Metal products; Glass, ceramic; Baking vanish, enamelware; Crust objects such as plastics.
Thicker as grease, scavenging period will extend.
Embodiment 2
Component title weight percent
Soxylat A 25-7 alkylphenol 5
Dodecyl dixylyl quaternary amine hydrochlorate 3
Dodecyl diglycollic amide 7
Adsorptivity mineral dust 85
Compound method: with the liquid phase component respectively or mix and be sprayed on the adsorptivity mineral dust, both mix can.
Mixed meal still has sorption property preferably.The disinfection clean that can be used for toilet washbowl, bathtub, toilet, ceramic tile wall and ground.
The disinfection clean that is used for kitchen utensils.
The disinfection clean of the apparatus in room.
Claims (8)
1, a kind of method for preparing Powdered detergent mixture, it is characterized by: the various tensio-active agents of forming clean-out system, be the mineral powder that standard sieve 30 orders----500 purposes have adsorptivity with granular size respectively, mix uniformly, generation scribbles the different sorts tensio-active agent therefrom, the absorbability particle meal is together composite with them again, and mixes
Maybe will form the various tensio-active agents of clean-out system, mix, this mixture mixed the absorbability particle meal that generation therefrom scribbles tensio-active agent with adsorptivity mineral powder.
2, kinds of surfactants and weight percent thereof are in the claim 1:
Title weight percent best values
Trihydroxy ethylamine oleate soap 1---50 5---30
Soxylat A 25-7 alkylphenol 1---80 3---30
The dodecyl dimethylamino benzylidene
Quaternary amine hydrochlorate 1---20 3---10
Dodecyl diglycollic amide 1---90 5---60
Oleum Cocois alkyl alcohol acyl
Amine phosphoric acid fat 1---90 5---60
3, adsorptivity mineral powder fineness is a standard sieve 30-500 order in the claim 1, can select one or more diatomite, wilkinite, sub-bentonite, zeolite and pearlstone for use.
4, among the claim 1-3, the tensio-active agent summation is the 1%-300% of adsorptivity mineral powder by weight.
5, described in the claim 1-4 and tensio-active agent, wherein any two or more and adsorptivity mineral powder mixture.
6, the surfactant mixture addressed of power 1 is used for the cleaning of metal and other crust greasy dirts, non-setting adhesive or other organic dopes.
7, be used for the disinfecting and decontaminating powder, it is characterized in that being used to kill gram-positive microorganism and Gram-negative bacteria, as full staphylococcus aureus, mould etc.And can be to the utensil cleaning and disinfecting, to chemical plant installations water disinfecting algae removal.
When 8, being used for the disinfecting and decontaminating powder, the consumption of dodecyl dixylyl quaternary amine hydrochlorate is 3% to 10% of detergent mixture by weight percentage, preferably 5%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 91107507 CN1071452A (en) | 1991-10-17 | 1991-10-17 | Detergent mixture and its production and use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 91107507 CN1071452A (en) | 1991-10-17 | 1991-10-17 | Detergent mixture and its production and use |
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CN1071452A true CN1071452A (en) | 1993-04-28 |
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CN 91107507 Pending CN1071452A (en) | 1991-10-17 | 1991-10-17 | Detergent mixture and its production and use |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101146904B (en) * | 2005-03-22 | 2011-02-09 | 荷兰联合利华有限公司 | Soluble speckle granule |
CN101280126B (en) * | 2008-05-26 | 2011-07-13 | 广州立白企业集团有限公司 | Modified bentonite and laundry powder |
CN102242019A (en) * | 2011-05-10 | 2011-11-16 | 王银河 | Dry cleaning agent for cleaning kitchens and hand oil stains |
CN103525572A (en) * | 2013-09-30 | 2014-01-22 | 西南石油大学 | Solid-liquid phase change heavy oil dirt cleaning agent packaged by porous medium and preparation method thereof |
CN104312752A (en) * | 2014-10-10 | 2015-01-28 | 安徽唯宝印刷科技有限公司 | Aromatic cleaning powder |
-
1991
- 1991-10-17 CN CN 91107507 patent/CN1071452A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101146904B (en) * | 2005-03-22 | 2011-02-09 | 荷兰联合利华有限公司 | Soluble speckle granule |
CN101280126B (en) * | 2008-05-26 | 2011-07-13 | 广州立白企业集团有限公司 | Modified bentonite and laundry powder |
CN102242019A (en) * | 2011-05-10 | 2011-11-16 | 王银河 | Dry cleaning agent for cleaning kitchens and hand oil stains |
CN103525572A (en) * | 2013-09-30 | 2014-01-22 | 西南石油大学 | Solid-liquid phase change heavy oil dirt cleaning agent packaged by porous medium and preparation method thereof |
CN103525572B (en) * | 2013-09-30 | 2015-04-08 | 西南石油大学 | Solid-liquid phase change heavy oil dirt cleaning agent packaged by porous medium and preparation method thereof |
CN104312752A (en) * | 2014-10-10 | 2015-01-28 | 安徽唯宝印刷科技有限公司 | Aromatic cleaning powder |
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