JPH0229497A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH0229497A JPH0229497A JP17907488A JP17907488A JPH0229497A JP H0229497 A JPH0229497 A JP H0229497A JP 17907488 A JP17907488 A JP 17907488A JP 17907488 A JP17907488 A JP 17907488A JP H0229497 A JPH0229497 A JP H0229497A
- Authority
- JP
- Japan
- Prior art keywords
- hydroxyapatite
- detergent composition
- surfactant
- spray
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 33
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims abstract description 36
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims abstract description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000003925 fat Substances 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000010419 fine particle Substances 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010411 cooking Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011246 composite particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はクレンザ−タイプの洗剤組成物に関し、詳しく
は、潟アカ、油脂による汚れまたはカビの発生による汚
れを効率よく除去することができるクレンザ−タイプの
洗剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a cleanser-type detergent composition, and more particularly, to a cleanser that can efficiently remove stains caused by lagoon scale, oil stains, or mold growth. - type of detergent composition.
本発明の洗剤組成物は、浴槽用の洗剤、台所用の洗剤、
食器洗い用の洗剤などの住宅用ならびに調理用の広範囲
の用途に利用することができる。The detergent composition of the present invention includes bathtub detergents, kitchen detergents,
It can be used in a wide range of household and cooking applications, such as dishwashing detergent.
台所や調理場は湿気が多く、その壁面はカビの発生によ
る汚れの付着が多いばかりでなく、また調理の際に飛散
する油汚れの付着することも多い。Kitchens and cooking areas are humid, and their walls are often contaminated with dirt due to mold growth, as well as oil stains that are scattered during cooking.
また浴槽には、湯アカを始め、黒ずんだ汚れや脂汚れの
付着することが多い。In addition, bathtubs often have hot water scale, dark dirt, and greasy stains attached to them.
このような汚れは、洗剤の界面活性によって除去するこ
とができないので、ａ）タワシやブラシによって物理的
に汚れを除去する方法、ｂ）物理的に汚れを除去する方
法において、洗剤、界面活性剤または研磨材を併用して
、汚れの脱離を促進する方法、および汚れの成分を化学
的に変質しうる化学品を併用して、汚れの脱離を促進す
る方法が広く用いられるが、ａ）の物理的に汚れを除去
する方法は、凹み、溝または隅に付着する汚れを除去す
るには多大の労力を要し、またｂ）の化学品を併用する
汚れを除去する方法は、化学品の選択の如何によって、
汚れの付着する面の塗装あるいは素材を変質・劣化する
ことがあり、このような変質・劣化を生じない様にする
には、使用する洗剤倶酸物における化学品に細心の注意
を必要とし、これらの汚れを除去する方法は、相当に厄
介なものである。Such stains cannot be removed by the surfactant of detergents, so a) a method of physically removing the stains with a scrub brush or brush, b) a method of physically removing the stains using detergents, surfactants, etc. Alternatively, a method of promoting the removal of dirt by using an abrasive in combination, and a method of promoting the removal of dirt by using a chemical that can chemically alter the components of the dirt are widely used. The method of physically removing dirt in (b) requires a lot of effort to remove dirt that adheres to dents, grooves, or corners, and the method of b) that uses chemicals in combination requires chemical removal. Depending on the selection of products,
This may cause deterioration or deterioration of the paint or material on the surface to which dirt adheres, and in order to prevent such deterioration or deterioration, it is necessary to pay close attention to the chemicals used in the detergent compound. The method of removing these stains is quite cumbersome.
このような汚れを除去する方法において、研磨材に界面
活性剤を併用した洗剤組成物（注、クレンザ−タイプ）
が提案され、その方法が広く行なわれている。In the method of removing such stains, a detergent composition (note, cleanser type) that uses a surfactant in combination with an abrasive material is used.
has been proposed and is widely used.
本発明者は、水酸アパタイトについて、永年研究を続け
ているが、その研究において、水酸アパタイトの微粒子
が油脂を吸着しやすいことを見出し、その知見に基づい
て本発明に到達した。The present inventor has been conducting research on hydroxyapatite for many years, and in his research, he discovered that fine particles of hydroxyapatite easily adsorb fats and oils, and based on that knowledge, he arrived at the present invention.
本発明の目的は、油汚れなどの除去し難い汚れを少ない
労力によって除去することができるクレンザ−タイプの
洗剤組成物を提供することにあり、詳しくは、油汚れな
どの除去し難い汚れを吸着して除去することができるク
レンザ−タイプの洗剤組成物を提供することにある。An object of the present invention is to provide a cleanser-type detergent composition that can remove hard-to-remove stains such as oil stains with little effort. An object of the present invention is to provide a cleanser-type detergent composition that can be used to remove the skin.
本発明は、研磨材に界面活性剤を配合した洗剤組成物に
おいて、研磨材として水酸アパタイトを配合したことを
特徴とする洗剤組成物である。The present invention is a detergent composition in which a surfactant is blended into an abrasive, and the detergent composition is characterized in that hydroxyapatite is blended as an abrasive.
本発明の洗剤組成物におけろ水酸アパタイトは、水酸ア
パタイトのスラリーを噴霧乾燥して得られた多孔質の水
酸アパタイトを使用することができ、また水酸アパタイ
トのスラリーに界面活性剤を加えた液状の洗剤組成物と
することもできる。As the hydroxyapatite in the detergent composition of the present invention, porous hydroxyapatite obtained by spray-drying a hydroxyapatite slurry can be used. A liquid detergent composition may also be prepared.
本発明の洗剤組成物は、水酸アパタイトに界面活性剤を
配合することによって得られる。The detergent composition of the present invention is obtained by blending a surfactant with hydroxyapatite.
本発明の洗剤組成物におけろ水酸アパタイトと界面活性
剤は、水酸アパタイト１００重量部に対して１０〜５０
重量部（好ましくは２０〜４０重量部）の比率において
配合する。In the detergent composition of the present invention, the amount of hydroxyapatite and surfactant is 10 to 50 parts by weight per 100 parts by weight of hydroxyapatite.
It is blended in a ratio of 20 to 40 parts by weight (preferably 20 to 40 parts by weight).
本発明の洗剤組成物は、粉状のものであってもよく、ま
た界面活性剤に微粒子状の水酸アパタイトが分散した液
状のものであってもよい。粉状の洗剤組成物の場合は、
粉末状の水酸アパタイトに界面活性剤を配合するが、界
面活性剤の溶液に微粒子状の水酸アパタイトが分散した
液状の洗剤組成物を噴霧乾燥し、水酸アパタイト−界面
活性剤複合体の微粒子とすることもできる。The detergent composition of the present invention may be in powder form or may be in liquid form in which fine particulate hydroxyapatite is dispersed in a surfactant. For powdered detergent compositions,
A surfactant is blended into powdered hydroxyapatite, and a liquid detergent composition in which fine particulate hydroxyapatite is dispersed in a surfactant solution is spray-dried to form a hydroxyapatite-surfactant complex. It can also be made into fine particles.
粉状の水酸アパタイトは、１００ミクロン以下の粒径の
ものを使用するが、１０ミクロン以下（特に好ましくは
１ミクロン程度）のものを使用するのが好ましい。粉状
の水酸アパタイトの粒径が小さくなると、その比表面積
が増大し、それによって水酸アパタイトに吸着される汚
れの量が増加し、それによって本発明の洗剤組成物の汚
れの除去効率が増大する。Powdered hydroxyapatite with a particle size of 100 microns or less is used, and it is preferable to use one with a particle size of 10 microns or less (particularly preferably about 1 micron). As the particle size of the powdered hydroxyapatite decreases, its specific surface area increases, thereby increasing the amount of soil adsorbed on the hydroxyapatite, thereby increasing the soil removal efficiency of the detergent composition of the present invention. increase
粉状の水酸アパタイトは、水酸アパタイトのスラリーを
ａｍ乾燥して得られた噴霧乾燥品を使用するのが好まし
い。水酸アパタイトの＠霧乾燥品は、その粒径が非常に
小さい水酸アパタイトの微粒子が相互に結合した複合粒
子であり、多孔質のものであるから、その比表面積は大
きく、それによって汚れの吸着量が増大して、その洗浄
効率を向上する。As the powdered hydroxyapatite, it is preferable to use a spray-dried product obtained by am-drying a slurry of hydroxyapatite. Hydroxyapatite @ mist-dried products are composite particles in which fine hydroxyapatite particles with very small particle sizes are bonded to each other, and because they are porous, their specific surface area is large, which makes them difficult to stain. The amount of adsorption increases and the cleaning efficiency is improved.
界面活性剤は、陽イオン性のもの、陰イオン性のものま
たは非イオン性のものの、いずれのものであっても、こ
れを使用することができる。The surfactant can be any of cationic, anionic, or nonionic surfactants.
本発明の紗状の洗剤組成物は、微粒子状の水酸アパタイ
トが界面活性剤の溶液に分散しているものである。液状
の洗剤組成物は、水酸アパタイトの微粒子のスラリーに
界面活性剤を加え、溶解して調製する。The gauze-like detergent composition of the present invention has fine particulate hydroxyapatite dispersed in a surfactant solution. A liquid detergent composition is prepared by adding and dissolving a surfactant into a slurry of fine particles of hydroxyapatite.
本発明の洗剤組成物は、これをタワシまたはブラシに付
着させ、洗剤組成物の付着したタワシまたはブラシで汚
れを生じた面を擦（こす）ると、汚れは水酸アパタイト
の微粒子により汚れを生じた面より離脱し、水酸アパタ
イトの微粒子に吸着して、除去される。When the detergent composition of the present invention is applied to a scrubbing brush or a brush and the scrubbing brush or brush to which the detergent composition has been applied is rubbed on a stained surface, the dirt is removed by fine particles of hydroxyapatite. It separates from the generated surface, adsorbs to fine particles of hydroxyapatite, and is removed.
以下において、参考例および実施例により本発明をさら
に詳しく説明する。The present invention will be explained in more detail below using reference examples and examples.
参考例（水酸アパタイトスラリーの噴霧乾燥品）水酸化
カルシウムＩ Ｋｇを水１０に９に分散し、撹拌しなが
らこれに濃リン酸（ＨＰＯ）を、ｐＨが１０．０になる
まで滴下して、水酸アパタイトのスラリーを調製した。Reference example (spray-dried product of hydroxyapatite slurry) I kg of calcium hydroxide was dispersed in 9 parts to 10 parts of water, and concentrated phosphoric acid (HPO) was added dropwise to this while stirring until the pH reached 10.0. , a slurry of hydroxyapatite was prepared.
この水酸アパタイトのスラリーをスプレードライヤーに
おいて噴霧乾燥して、水酸アバタイ１〜の噴霧乾燥品１
．３Ｋｇを得た。This slurry of hydroxyapatite is spray-dried in a spray dryer to form spray-dried products 1 of hydroxyapatite 1 to 1.
．． Obtained 3Kg.
実施例１
参考例の水酸アパタイトの噴霧乾燥品Ｉ Ｋ９に界面活
性剤０．２に９を加え、充分に混合して、洗剤粉末１・
２に９を得た。Example 1 Add 0.2 to 9 parts of surfactant to spray-dried hydroxyapatite product I K9 of Reference Example, mix thoroughly, and prepare detergent powder 1.
Got 9 on 2.
実施例２
参考例の水酸アパタイトのスラリー１０に９に、界面活
性剤０．２Ｋｇを溶解し、その水酸アパタイトのスラリ
ーをスプレードライヤーにおいて噴霧乾燥して、洗剤粉
末１．５Ｋｇを得た。Example 2 0.2 kg of surfactant was dissolved in the hydroxyapatite slurry 10 to 9 of Reference Example, and the hydroxyapatite slurry was spray-dried in a spray dryer to obtain 1.5 kg of detergent powder.
実施例３
参考例の水酸アパタイトのスラリー１０に９に、界面活
性剤０．２に９を加え、充分に撹拌して洗剤液１．２に
９を得た。Example 3 9 was added to 10 parts of the hydroxyapatite slurry of the reference example, and 9 parts were added to 0.2 parts of the surfactant, and thoroughly stirred to obtain 1.2 parts of detergent solution 9.
壁面、床面、浴槽の内底面などの面にコビリついた汚れ
であっても、間車に除去することができる。Even stubborn dirt on surfaces such as walls, floors, and the inner bottom of bathtubs can be removed using the spacer.
出頭人 積水化成品工業株式会社Applicant: Sekisui Plastics Co., Ltd.
Claims (2)
いて、研磨材として水酸アパタイトが配合されているこ
とを特徴とする洗剤組成物。(1) A detergent composition comprising an abrasive and a surfactant, which contains hydroxyapatite as the abrasive.
であることを特徴とする特許請求の範囲第１項に記載の
洗剤組成物。(2) The detergent composition according to claim 1, wherein the hydroxyapatite is a spray-dried product of hydroxyapatite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63179074A JPH0733520B2 (en) | 1988-07-20 | 1988-07-20 | Polishing detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63179074A JPH0733520B2 (en) | 1988-07-20 | 1988-07-20 | Polishing detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0229497A true JPH0229497A (en) | 1990-01-31 |
| JPH0733520B2 JPH0733520B2 (en) | 1995-04-12 |
Family
ID=16059636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63179074A Expired - Fee Related JPH0733520B2 (en) | 1988-07-20 | 1988-07-20 | Polishing detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0733520B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996037433A1 (en) * | 1995-05-22 | 1996-11-28 | Advance Co., Ltd. | Method of treating bone charcoal, product of said method, method of extracting apatite from untreated bone or bone ash, and apatitic material |
| US6096324A (en) * | 1995-06-13 | 2000-08-01 | Laboratory Skin Care | Methods of delivering materials into the skin, and compositions used therein |
| WO2016096328A1 (en) | 2014-12-18 | 2016-06-23 | Unilever N.V. | Powder composition for hard surface cleaning |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01186814A (en) * | 1988-01-19 | 1989-07-26 | Sangi:Kk | Face-washing, shampooing and bathing agent |
| JPH01192869A (en) * | 1988-01-26 | 1989-08-02 | Kenichi Kawasaki | Liquid detergent for cleaning silk product |
-
1988
- 1988-07-20 JP JP63179074A patent/JPH0733520B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01186814A (en) * | 1988-01-19 | 1989-07-26 | Sangi:Kk | Face-washing, shampooing and bathing agent |
| JPH01192869A (en) * | 1988-01-26 | 1989-08-02 | Kenichi Kawasaki | Liquid detergent for cleaning silk product |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996037433A1 (en) * | 1995-05-22 | 1996-11-28 | Advance Co., Ltd. | Method of treating bone charcoal, product of said method, method of extracting apatite from untreated bone or bone ash, and apatitic material |
| US6096324A (en) * | 1995-06-13 | 2000-08-01 | Laboratory Skin Care | Methods of delivering materials into the skin, and compositions used therein |
| US6099849A (en) * | 1995-06-13 | 2000-08-08 | Mansouri; Zari | Skin care moisturizers and cleansers |
| US6120782A (en) * | 1995-06-13 | 2000-09-19 | Mansouri; Zari | Methods of delivering materials into the skin, and compositions used therein |
| WO2016096328A1 (en) | 2014-12-18 | 2016-06-23 | Unilever N.V. | Powder composition for hard surface cleaning |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0733520B2 (en) | 1995-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |