JPH03190999A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH03190999A JPH03190999A JP33151989A JP33151989A JPH03190999A JP H03190999 A JPH03190999 A JP H03190999A JP 33151989 A JP33151989 A JP 33151989A JP 33151989 A JP33151989 A JP 33151989A JP H03190999 A JPH03190999 A JP H03190999A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning composition
- acid
- cleaning
- composition according
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 239000003599 detergent Substances 0.000 title abstract description 5
- 238000004140 cleaning Methods 0.000 claims abstract description 78
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 30
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 15
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 15
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 15
- 150000007524 organic acids Chemical class 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000000919 ceramic Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 208000009911 Urinary Calculi Diseases 0.000 claims description 8
- 208000008281 urolithiasis Diseases 0.000 claims description 8
- 239000000443 aerosol Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 12
- 239000000243 solution Substances 0.000 abstract description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract description 9
- 235000006408 oxalic acid Nutrition 0.000 abstract description 9
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract description 6
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000001630 malic acid Substances 0.000 abstract description 6
- 235000011090 malic acid Nutrition 0.000 abstract description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract description 3
- 239000011976 maleic acid Substances 0.000 abstract description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract description 3
- 206010007027 Calculus urinary Diseases 0.000 abstract description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 abstract description 2
- 239000011975 tartaric acid Substances 0.000 abstract description 2
- 235000002906 tartaric acid Nutrition 0.000 abstract description 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004042 decolorization Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 1
- 229910001942 caesium oxide Inorganic materials 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- -1 limescale Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、ガラス製品、陶磁器またはステンレス等の金
属製品を洗浄するための洗浄剤組成物に関するものであ
り、特にそれらの材質て構成されたタイル張り品等の台
所用品、工業用浄化槽に頑固に付着、蓄積した水垢、酸
化物、尿石、着色成分等を除去清掃することができる洗
浄剤組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a cleaning agent composition for cleaning glass products, ceramics, metal products such as stainless steel, etc., and particularly relates to a cleaning composition made of those materials. The present invention relates to a cleaning composition that can remove and clean stubbornly adherent and accumulated limescale, oxides, uroliths, colored components, etc. from kitchen utensils such as tiled products and industrial septic tanks.
［従来の技術］
従来、前述の如きガラス製品、陶磁器等、例えばフィル
ターの場合は、化学工場等で水をフィルターを使用して
浄化しているが、フィルターには水垢が付き易く、その
ため水量や水圧の低下が起こるので、フィルターの洗浄
か行われる。またカラス製品、陶磁器製品か便器等であ
った場合、これらの便器には尿石か蓄積する。更にステ
ンレス等の金属製品には、金属に特有の酸化被膜や酸化
膜が生成するので、それを洗浄除去する必要がある。そ
れらを洗浄するための洗浄剤組成物としては、研磨力、
琢磨力等を加味するために、非イオン系、陰イオン系等
の界面活性剤に酸化セリウム、アルミナ、ジルコニア、
粘土、鉱物等の無機粉末を混合したものが一般的に知ら
れている。[Conventional technology] Conventionally, in the case of glass products, ceramics, etc., as mentioned above, for example, filters are used to purify water in chemical factories, etc., but the filters tend to have limescale, and as a result, the amount of water is As the water pressure drops, the filter will need to be cleaned. In addition, if the toilet is made of crow, ceramic or toilet bowls, urinary stones will accumulate in these toilet bowls. Furthermore, metal products such as stainless steel produce oxide films and oxide films peculiar to metals, which must be cleaned and removed. Cleaning compositions for cleaning them include abrasive power,
In order to add polishing power, cerium oxide, alumina, zirconia, etc. are added to nonionic and anionic surfactants.
Mixtures of inorganic powders such as clay and minerals are generally known.
また頑固に付着蓄積した水垢や尿石等の除去清掃には、
酸またはアルカリを主材とした化学薬品によって溶解又
は剥離させる方法、機械的に外力を加えて削り取る方法
、酵素を混合したものて分解させる方法等がある。In addition, for cleaning and removing stubbornly accumulated limescale and urine stones,
There are methods such as dissolving or peeling with chemicals mainly based on acid or alkali, mechanically scraping off by applying external force, and decomposing with a mixture of enzymes.
方、最近トイレの便器等に用いられる洗浄水に脱臭剤と
共に着色物を混入し、脱臭と共に着色水を流しされやか
な感じを与えるようにしたものか多く用いられるように
なりだ。そのためにトイレの便器等において、洗浄水か
流れ出る方向に縞状に着色した跡かつき、乾燥、水洗を
繰り返しているうちに、便器にこびりイ」いてしまう。Recently, however, it has become common to mix colored substances with deodorizers into the flushing water used in toilet bowls, etc., so that the colored water is deodorized and the flushing water feels more refreshing. As a result, colored streaks form on the toilet bowl, etc., in the direction of flushing water, and as the toilet bowl is repeatedly dried and flushed, it gets stuck in the toilet bowl.
しかして、これらの掃除にはタワシやスポンジに洗剤を
つけてこずって落すことか一般に行われている。However, the common practice for cleaning these items is to apply detergent to a scrub brush or sponge and scrub them off.
［発明が解決しようとする問題点］
しかしなから、前記ガラス製品、陶磁器、金属製品等の
洗浄に際し、非イオン系、陰イオン系等の界面活性剤に
無機粉末を混合した洗浄剤組成物を用いる方法では、ご
く初期の汚染の洗浄には効果があるが、頑固に付着、蓄
積した水垢や尿石の除去清掃には殆と゛効果がない。[Problems to be Solved by the Invention] However, when cleaning the glass products, ceramics, metal products, etc., it is necessary to use a cleaning composition containing an inorganic powder mixed with a nonionic or anionic surfactant. The method used is effective in cleaning very early stages of contamination, but it is hardly effective in cleaning and removing stubbornly adherent and accumulated water scale and urinary stones.
次に酸、アルカリを主材とした化学薬品による方法では
、例えは、ガラス製品、陶磁器またはステンレス等の金
属製品の被洗浄体を侵食して損傷を与えたり、作業者の
皮膚や作業着等を侵すことがあり、また最近では化学反
応によって発生した有毒ガスによる人体への影響が指摘
されており、衛生上および安全性上問題がある。Next, methods using chemicals based on acids and alkalis, for example, attack and damage the objects to be cleaned, such as glass products, ceramics, or metal products such as stainless steel, or damage the workers' skin or work clothes. Recently, it has been pointed out that toxic gases generated by chemical reactions can affect the human body, posing health and safety problems.
また機械的に外力を加えて削り取る方法では、多大な労
力を必要とするばかりでなく、被洗浄体にキズがつく等
の損傷が避けられない。Further, the method of mechanically applying external force to scrape off not only requires a great deal of labor but also inevitably causes damage such as scratches on the object to be cleaned.
酵素を混合したもので分解させる方法では、分解か遅く
時間的に問題がある。The method of decomposing with a mixture of enzymes has problems in terms of time and slow decomposition.
更にトイレの便器等に付着した着色物による場合は、着
色物は便器にこびり付いているので、通常の方法、タワ
シやスポンジに洗剤をつけてこする程度では、なかなか
落ちず、清掃か非常に困難であるという問題があった。Furthermore, in the case of colored matter adhering to the toilet bowl, etc., the colored matter is stuck to the toilet bowl, so the usual method of scrubbing with detergent on a scrub brush or sponge will not remove it easily, making cleaning it extremely difficult. There was a problem.
そこで木発明者は、前記問題点について種々検問した結
果、予想外にもアスコルビン酸を主成分とする洗浄剤組
成物を用いることにより、前記ガラス製品、陶磁器、金
属製品等の洗浄に十分な効果を発揮しうることを見出し
、これに基づいて本発明は完成したものである。As a result of various inquiries regarding the above-mentioned problems, the inventor of the tree unexpectedly found that by using a cleaning composition containing ascorbic acid as a main component, it was sufficiently effective for cleaning the above-mentioned glass products, ceramics, metal products, etc. The present invention has been completed based on this discovery.
したがって、本発明の目的は、カラス製品、陶磁器、金
属製品等に頑固に付着、蓄積した水垢や尿石の除去清掃
並びに着色成分の除去に安価で効果がある洗浄剤組成物
を提供することにある。Therefore, an object of the present invention is to provide a cleaning composition that is inexpensive and effective for removing limescale and urinary stones that stubbornly adhere to and accumulate on glass products, ceramics, metal products, etc., as well as removing colored components. be.
［問題点を解決するための手段］
本発明の前記目的は、
１）アスコルビン酸及び有機酸またはそれらの溶液を含
む洗浄剤組成物。[Means for Solving the Problems] The objects of the present invention are as follows: 1) A cleaning composition containing ascorbic acid and an organic acid or a solution thereof.
２）第１項記載の洗浄剤組成物に無機微粉末を含有させ
たことを特徴とする洗浄剤組成物。2) A cleaning composition characterized in that the cleaning composition according to item 1 contains an inorganic fine powder.
３）第２項記載の洗浄剤組成物が粉状であることを特徴
とする洗浄剤組成物。3) A cleaning composition according to item 2, wherein the cleaning composition is in powder form.
４）第２項記載の洗浄剤組成物がペースト状であること
を特徴とする洗浄剤組成物。4) A cleaning composition according to item 2, wherein the cleaning composition is in the form of a paste.
５）第２項記載の洗浄剤組成物が液状であることを特徴
とする洗浄剤組成物。5) A cleaning composition according to item 2, wherein the cleaning composition is in liquid form.
６）第２項記載の洗浄剤組成物がエアロゾルであること
を特徴とする洗浄剤組成物。6) A cleaning composition according to item 2, wherein the cleaning composition is an aerosol.
７）第１項〜第５項記載の洗浄剤組成物が陶磁器を洗浄
することを特徴とする洗浄剤組成物。7) A cleaning composition characterized in that the cleaning composition according to items 1 to 5 cleans ceramics.
８）第１項〜第５項記載の洗浄剤組成物が金属表面を洗
浄することを特徴とする洗浄剤組成物。8) A cleaning composition characterized in that the cleaning composition according to items 1 to 5 cleans metal surfaces.
９）第１項〜第５項記載の洗浄剤組成物が多孔質フィル
ターを洗浄することを特徴とする洗浄剤組成物。9) A cleaning composition characterized in that the cleaning composition according to items 1 to 5 cleanses a porous filter.
１０）第１項〜第５項記載の洗浄剤組成物が尿石を洗浄
除去することを特徴とする洗浄剤組成物。10) A cleaning composition characterized in that the cleaning composition according to items 1 to 5 cleans and removes urinary stones.
１１）第１項〜第５項記載の洗浄剤組成物が水あかを洗
浄除去することを特徴とする洗浄剤組成物によりそれぞ
れ達成された。11) The cleaning compositions described in Items 1 to 5 were each achieved by cleaning compositions characterized by cleaning and removing water scale.
［発明の具体的構成］
本発明に用いられる洗浄剤組成物は、アスコルビン酸を
主成分としており、これに有機酸を加えたものである。[Specific Structure of the Invention] The cleaning composition used in the present invention contains ascorbic acid as a main component, to which an organic acid is added.
この混合物はそのまま洗浄剤として使用してもよいし、
これを水ン容ン夜としてもよい。This mixture can be used as a cleaning agent, or
You can also call this a night of water.
混合物または水溶液混合物は、粉末、液状、ペースト状
、エアゾール（またはエアロゾルともいう。）等の形態
にして使用される。The mixture or aqueous mixture is used in the form of powder, liquid, paste, aerosol (also referred to as aerosol), or the like.
有機酸としては、シュウ酸、マロン酸、コハク酸、クエ
ン酸、リンゴ酸、マレイン酸、シュセキ酸等が用いられ
、これらは２種以上群合してもよい。As the organic acid, oxalic acid, malonic acid, succinic acid, citric acid, malic acid, maleic acid, schusekiic acid, etc. are used, and two or more of these may be used in combination.
アスコルビン酸と有機酸との混合比は、２０〜０３てあ
り、好ましくはｌＯ〜０５である。The mixing ratio of ascorbic acid and organic acid is 20-03, preferably 10-05.
またｐＨは１〜１３てあり、好ましくは２〜６である。Further, the pH is 1 to 13, preferably 2 to 6.
また前記洗浄剤組成物には、無機微粉末を加えることが
でき、用いられるものとしては、アルミナ、ジルコニア
、酸化セシウム、酸化チタン、酸化亜鉛、タルク、粘土
、二酸化硅素、鉱物等が挙げられる。Further, an inorganic fine powder can be added to the cleaning composition, and examples of those used include alumina, zirconia, cesium oxide, titanium oxide, zinc oxide, talc, clay, silicon dioxide, minerals, and the like.
この無機微粉末の粒径はｉｏｏμｍ〜１μｍであり、好
ましくは２０μｍ〜１μｍである。The particle size of this inorganic fine powder is iooμm to 1μm, preferably 20μm to 1μm.
前記洗浄剤組成物には、他の添加剤を加えることかでき
、例えは脱色促進剤、安定剤、微生物、酵素等を加える
ことかてきる。脱色促進剤としては少量の硫酸か用いら
れ、安定剤としては酒石酸が用いられる。Other additives may be added to the cleaning composition, such as decolorization accelerators, stabilizers, microorganisms, enzymes, etc. A small amount of sulfuric acid is used as a decolorization accelerator, and tartaric acid is used as a stabilizer.
本発明の洗浄剤組成物には、必要に応じて他の酸又はア
ルカリを加えてもよく、更に機械的洗浄を併用しても良
い。Other acids or alkalis may be added to the cleaning composition of the present invention as required, and mechanical cleaning may also be used in combination.
洗浄に用いられるカラス製品、陶磁器、金属製品として
は、例えは、浄水タンク、浄化槽フィルター、便器、ま
たはタイル、ステンレススチール、銅板、鉄板等で製作
された家庭用品又は工業用品等が挙げられる。Examples of glass products, ceramics, and metal products used for cleaning include water purification tanks, septic tank filters, toilet bowls, and household or industrial products made of tiles, stainless steel, copper plates, iron plates, etc.
［実施例］
以下、実施例を用いて未発明を更に詳細に説明するか、
これにより本発明が制限されるものではない。[Example] Hereinafter, the uninvention will be explained in more detail using Examples.
This does not limit the invention.
実施例１
アスコルビン酸 １００ｇシュウ酸
１００ｇ水
１０００ｇ前記各成分
を十分混合して洗浄剤組成物の溶液を製造した。Example 1 Ascorbic acid 100g oxalic acid
100g water
1000 g of each of the above ingredients were thoroughly mixed to prepare a solution of a cleaning composition.
該洗浄剤組成物の溶液をたわしにつけて縞状に着色され
た家庭用便器を軽くこすり、水洗したところ、着色か落
ちてきれいになった。また人体にも安全てあった。When a domestic toilet bowl colored in stripes was lightly rubbed with a solution of the cleaning composition on a scrubbing brush and washed with water, the coloring came off and the toilet bowl became clean. It was also safe for humans.
このトイレは従来の洗浄剤で洗浄しても着色はとれなか
った。Even if this toilet was cleaned with conventional cleaning agents, the stain could not be removed.
実施例２
アスコルビン酸 １００ｇシュウ酸
１００ｇアルミナ粉末
＋、 ｏ ｏ ｏ ｇ水
１０００ｇ前記各成分
を十分混合してペースト状の洗浄剤組成物を製造した。Example 2 Ascorbic acid 100g Oxalic acid 100g Alumina powder
+, o o o g water
1000 g of each of the above components were thoroughly mixed to prepare a paste-like cleaning composition.
該ペースト状の洗浄剤組成物を縞状に着色されたステン
レス製の車両用トイレの便器に塗布し、２分〜３分後、
スポンジで軽くこすり水洗したところ、着色か落ちてき
れいになった。このときステンレス表面の酸化物のみか
同時に溶解除去された。The paste-like cleaning composition was applied to a colored stainless steel vehicle toilet bowl in stripes, and after 2 to 3 minutes,
When I rubbed it lightly with a sponge and washed it with water, the coloring came off and it became clean. At this time, only the oxides on the stainless steel surface were dissolved and removed at the same time.
このトイレは従来の洗浄剤で洗浄した場合は勿論のこと
、塩素系の洗浄剤でも着色がとれなかった。The coloring of this toilet could not be removed not only by conventional cleaning agents, but also by chlorine-based cleaning agents.
更に塩酸、硫酸等の酸性液を使用する場合には、ステン
レス等の材質を腐食する原因となった。Furthermore, when acidic liquids such as hydrochloric acid and sulfuric acid are used, they cause corrosion of materials such as stainless steel.
実施例３
アスコルビン酸 １００ｇシュウ酸
５０ｇリンゴ酸
５０ｇクエン酸
５０ｇマレイン酸
５０ｇ水
１０００ｇ前記各成分を十分混合して洗浄剤組成
物の溶液を製造した。Example 3 Ascorbic acid 100g Oxalic acid 50g Malic acid
50g citric acid
50g maleic acid
50g water
1000 g of each of the above ingredients were thoroughly mixed to prepare a solution of a cleaning composition.
化学工場で使用済の水垢の付着したセラミックフィルタ
ーを前記洗浄剤組成物の溶液で洗浄したところ、ずゐや
かに水垢を洗浄除去することかでき、十分再使用するこ
とができた。When a ceramic filter that had been used in a chemical factory and had limescale on it was washed with a solution of the cleaning composition, the limescale could be quickly removed and the filter could be reused.
実施例４
アスコルビン酸 １００ｇシュウ酸
１００ｇリンゴ酸
１００ｇ前記各成分の混合溶液８０容
量％とＬＰＧ２０客量％の混合物を排出機構をもつ圧力
容器に圧力２Ｋｇ／ｍ２で封入して洗浄剤組成物のエア
ロゾルを製造した。Example 4 Ascorbic acid 100g oxalic acid
100g malic acid
A mixture of 100 g of the above-mentioned mixed solution of each component (80% by volume) and 20% by volume of LPG was sealed in a pressure vessel with a discharge mechanism at a pressure of 2 kg/m2 to produce an aerosol of a cleaning composition.
該洗浄剤組成物を水垢のイ」着した家庭用便器に吹きつ
りて軽くこすり、水洗したところ、速やかに水垢が溶解
除去されてきれいになった。また従来のように塩素系で
はないので、人体にも安全てあった。When the cleaning composition was sprayed onto a household toilet bowl covered with limescale, rubbed lightly, and washed with water, the limescale was quickly dissolved and removed, leaving the toilet bowl clean. Also, unlike conventional products, it is not chlorine-based, so it is safe for humans.
このトイレは従来の洗浄剤で洗浄しても水垢はとれなか
った。Even if this toilet was cleaned with conventional cleaning agents, the limescale could not be removed.
実施例５
アスコルビン酸 １００ｇシュウ酸
５０ｇリンゴ酸
５０ｇシュセキ酸
５０ｇコハク酸
５０ｇ水
１０００ｇ前記各成分を十分混合して洗浄剤組成物の
溶液を製造した。Example 5 Ascorbic acid 100g oxalic acid
50g malic acid
50g Shusekic acid
50g succinic acid
50g water
1000 g of each of the above ingredients were thoroughly mixed to prepare a solution of a cleaning composition.
該洗浄剤組成物の溶液をたわしにつけて尿石の付着した
家庭用便器を軽くこすり、水洗したとこ１
２
ろ、尿石が速やかに分解し除去されきれいになると共に
尿臭を抑えることができた。また人体にも安全であった
。When a household toilet bowl with urinary stones adhering to it was lightly scrubbed with a solution of the cleaning composition on a scrubbing brush and washed with water, the urinary stones were quickly decomposed and removed, leaving the toilet clean and the smell of urine suppressed. . It was also safe for humans.
このトイレは従来の洗浄剤で洗浄しても着色はとれなか
った。Even if this toilet was cleaned with conventional cleaning agents, the stain could not be removed.
実施例６
アスコルビン酸 １００ｇシュウ酸
５０ｇリンゴ酸
５０ｇクエン酸
５０ｇ水
１ ０００ｇ前記各成分を十分混合して洗浄
剤組成物の溶液を製造した。Example 6 Ascorbic acid 100g oxalic acid
50g malic acid
50g citric acid
50g water
1,000 g of each of the above ingredients were thoroughly mixed to prepare a solution of a cleaning composition.
水垢の付着したトイレの便器を前記洗浄剤組成物の溶液
で洗浄したところ、すみやかに水垢を分解除去すること
ができた。When a toilet bowl with limescale adhering to it was cleaned with a solution of the cleaning composition, the limescale could be quickly decomposed and removed.
実施例７
アスコルビン酸 １００ｇシュウ酸
５０ｇマロン酸
５０ｇ水
ｉ ０００ｇ前記各成分を十分混合
して洗浄剤組成物の溶液を製造した。Example 7 Ascorbic acid 100g oxalic acid
50g malonic acid
50g water
i 000g The above components were thoroughly mixed to prepare a solution of the cleaning composition.
該洗浄剤組成物の溶液をたわしにつけて家庭用浴槽を軽
くこすり、水洗したところ、水垢や油脂酸化物等が分解
除去されきれいになった。また人体にも安全であった。When a domestic bathtub was lightly scrubbed with a solution of the cleaning composition on a scrubbing brush and washed with water, limescale, oil and fat oxides, etc. were decomposed and removed and the bathtub became clean. It was also safe for humans.
この浴槽は従来の洗浄剤で洗浄しても水垢や油脂酸化物
等はとれなかった。Even if this bathtub was cleaned with conventional cleaning agents, limescale and fat oxides could not be removed.
［発明の効果］
本発明は、アスコルビン酸を主成分とする洗浄剤組成物
を用いることにより、ガラス製品、陶磁器、金属製品等
に頑固に付着、蓄積した水垢や尿石の除去清掃並びに着
色成分の除去を安価で効果的に行うことができる。[Effects of the Invention] By using a cleaning composition containing ascorbic acid as a main component, the present invention can remove and clean limescale and urinary stones that stubbornly adhere to and accumulate on glass products, ceramics, metal products, etc., and also remove coloring components. can be removed inexpensively and effectively.
Claims (1)
む洗浄剤組成物。 ２）請求項１記載の洗浄剤組成物に無機微粉末を含有さ
せたことを特徴とする洗浄剤組成物。 ３）請求項２記載の洗浄剤組成物が粉状であることを特
徴とする洗浄剤組成物。 ４）請求項２記載の洗浄剤組成物がペースト状であるこ
とを特徴とする洗浄剤組成物。 ５）請求項２記載の洗浄剤組成物が液状であることを特
徴とする洗浄剤組成物。 ６）請求項２記載の洗浄剤組成物がエアロゾルであるこ
とを特徴とする洗浄剤組成物。 ７）請求項１〜請求項５記載の洗浄剤組成物が陶磁器を
洗浄することを特徴とする洗浄剤組成物。 ８）請求項１〜請求項５記載の洗浄剤組成物が金属表面
を洗浄することを特徴とする洗浄剤組成物。 ９）請求項１〜請求項５記載の洗浄剤組成物が多孔質フ
ィルターを洗浄することを特徴とする洗浄剤組成物。 １０）請求項１〜請求項５記載の洗浄剤組成物が尿石を
洗浄除去することを特徴とする洗浄剤組成物。 １１）請求項１〜請求項５記載の洗浄剤組成物が水あか
を洗浄除去することを特徴とする洗浄剤組成物。[Scope of Claims] 1) A cleaning composition containing ascorbic acid and an organic acid or a solution thereof. 2) A cleaning composition characterized in that the cleaning composition according to claim 1 contains an inorganic fine powder. 3) A cleaning composition according to claim 2, wherein the cleaning composition is in powder form. 4) A cleaning composition according to claim 2, wherein the cleaning composition is in the form of a paste. 5) A cleaning composition according to claim 2, wherein the cleaning composition is in liquid form. 6) A cleaning composition according to claim 2, wherein the cleaning composition is an aerosol. 7) A cleaning composition, characterized in that the cleaning composition according to claims 1 to 5 cleans ceramics. 8) A cleaning composition, characterized in that the cleaning composition according to any one of claims 1 to 5 cleans a metal surface. 9) A cleaning composition, characterized in that the cleaning composition according to any one of claims 1 to 5 cleans a porous filter. 10) A cleaning composition according to any one of claims 1 to 5, which cleans and removes urinary stones. 11) A cleaning composition according to any one of claims 1 to 5, characterized in that it cleans and removes water scale.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33151989A JPH03190999A (en) | 1989-12-20 | 1989-12-20 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33151989A JPH03190999A (en) | 1989-12-20 | 1989-12-20 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03190999A true JPH03190999A (en) | 1991-08-20 |
Family
ID=18244557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33151989A Pending JPH03190999A (en) | 1989-12-20 | 1989-12-20 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03190999A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07252498A (en) * | 1994-03-17 | 1995-10-03 | Puronetsuto:Kk | Detergent |
| WO1999032592A1 (en) * | 1997-12-22 | 1999-07-01 | S. C. Johnson & Son, Inc. | Cleaning compositions for ceramic and porcelain surfaces and related methods |
| KR100808373B1 (en) * | 2007-08-30 | 2008-02-27 | (주)켐씨텍 | Composition of ecological cleaning agents for cleaning service of indoor water supply pipes |
| JP2009527588A (en) * | 2006-02-20 | 2009-07-30 | アラー，ジル | Products for processing toilet flush cisterns and toilet bowls |
| JP2013046679A (en) * | 2011-08-29 | 2013-03-07 | Daio Paper Corp | Toilet paper product having function of toilet cleaning and stain prevention |
| JP2013203926A (en) * | 2012-03-29 | 2013-10-07 | Sincere Co Ltd | Method for producing aqueous liquid detergent composition |
| JP2014098057A (en) * | 2012-11-13 | 2014-05-29 | Sincere Co Ltd | Method of manufacturing aqueous liquid detergent and aqueous liquid detergent for iron rust-based scale removing |
| US10329522B2 (en) | 2016-05-19 | 2019-06-25 | Ecolab Usa Inc. | Cleaning compositions for use with calcite-based stone |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59164398A (en) * | 1983-03-08 | 1984-09-17 | 栗田工業株式会社 | Water tank detergent |
| JPS6354500A (en) * | 1986-08-22 | 1988-03-08 | 石井 勝美 | Detergent based on ascorbic acid |
-
1989
- 1989-12-20 JP JP33151989A patent/JPH03190999A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59164398A (en) * | 1983-03-08 | 1984-09-17 | 栗田工業株式会社 | Water tank detergent |
| JPS6354500A (en) * | 1986-08-22 | 1988-03-08 | 石井 勝美 | Detergent based on ascorbic acid |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07252498A (en) * | 1994-03-17 | 1995-10-03 | Puronetsuto:Kk | Detergent |
| WO1999032592A1 (en) * | 1997-12-22 | 1999-07-01 | S. C. Johnson & Son, Inc. | Cleaning compositions for ceramic and porcelain surfaces and related methods |
| JP2009527588A (en) * | 2006-02-20 | 2009-07-30 | アラー，ジル | Products for processing toilet flush cisterns and toilet bowls |
| KR100808373B1 (en) * | 2007-08-30 | 2008-02-27 | (주)켐씨텍 | Composition of ecological cleaning agents for cleaning service of indoor water supply pipes |
| WO2009028757A1 (en) * | 2007-08-30 | 2009-03-05 | Chem-C Tech Co., Ltd. | Environmentally-friendly aqueous cleaning agent composition for cleaning indoor water supply pipes |
| JP2013046679A (en) * | 2011-08-29 | 2013-03-07 | Daio Paper Corp | Toilet paper product having function of toilet cleaning and stain prevention |
| JP2013203926A (en) * | 2012-03-29 | 2013-10-07 | Sincere Co Ltd | Method for producing aqueous liquid detergent composition |
| JP2014098057A (en) * | 2012-11-13 | 2014-05-29 | Sincere Co Ltd | Method of manufacturing aqueous liquid detergent and aqueous liquid detergent for iron rust-based scale removing |
| US10329522B2 (en) | 2016-05-19 | 2019-06-25 | Ecolab Usa Inc. | Cleaning compositions for use with calcite-based stone |
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