JPH07118694A - New detergent - Google Patents
New detergentInfo
- Publication number
- JPH07118694A JPH07118694A JP28563993A JP28563993A JPH07118694A JP H07118694 A JPH07118694 A JP H07118694A JP 28563993 A JP28563993 A JP 28563993A JP 28563993 A JP28563993 A JP 28563993A JP H07118694 A JPH07118694 A JP H07118694A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- detergent
- weight
- water
- new detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、特に、付着した黒黴等
菌体並びに頑固な有機物汚染の除去に有用な新洗剤に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a new detergent which is particularly useful for removing adherent fungi such as black mold and stubborn organic contaminants.
【0002】[0002]
【従来の技術】浴槽、同排水管、温水循環パイプ又は、
キチンの流し、その排水管などに付着する汚染は、所謂
有機物汚染であって、ヘドロともいうべきものである。
これらのプラスチック又は金属等に強固に付着したヘド
ロは、在来の洗剤では殆んど除去効果がないか或いは極
めて僅かである。しかも美麗なプラスチックの浴槽やス
テンレスのキチン流し等の鏡面仕上げがなされたものに
対しては、研磨剤を含有する洗剤が使用できない。ま
た、ヘドロに対し強烈な反応性を有する化学的な洗剤等
もあるが、プラスチックや金属の表面を酸化腐蝕するお
それがあって余り適当ではない。この結果、有機物の汚
染が確実に除去されるとともに、基材の表面に破損、酸
化、腐蝕等を生ぜしめない洗剤が強く要望されていたも
のである。2. Description of the Related Art Bathtubs, drainage pipes, hot water circulation pipes, or
Contamination that attaches to chitin's sink and its drainage pipe is so-called organic matter pollution and should be called sludge.
The sludge strongly adhered to these plastics or metals has almost no effect or very little removal effect with conventional detergents. Moreover, detergents containing abrasives cannot be used for beautiful plastic bathtubs and mirror finishes such as stainless steel chitin sinks. Further, there are chemical detergents and the like having a strong reactivity to sludge, but they are not suitable because they may oxidize and corrode the surfaces of plastics and metals. As a result, there has been a strong demand for a detergent that reliably removes the contamination of organic substances and does not damage, oxidize, or corrode the surface of the substrate.
【0003】[0003]
【発明が解決しようとする課題】本発明は敍上の実状に
鑑みてなされたもので、浴槽等を形成するプラスチック
の美麗な表面やキチンウエア等の金属の鏡面仕上げされ
た表面等比較的傷付き易い表面に生成した有機物汚染或
いは浴室の内壁や、浴槽、洗面台等の周辺縁部等拭浄が
比較的困難な場所の有機物汚染、さらには換気扇、レン
ジフード等の頑固な有機物、油等の汚れ個所等に適用し
て極めて有効であり、その他黒黴等の付着菌体の除去に
顕著な効果があり、しかも、使用時に垂れ落ちて周辺に
汚染を拡大する等の欠点が全くない新洗剤を提供するこ
とをその目的とするものである。SUMMARY OF THE INVENTION The present invention has been made in view of the actual condition of the lining, and has a relatively scratched surface such as a beautiful surface of plastic forming a bathtub or the like, or a mirror-finished surface of metal such as chitin wear. Contamination of organic matter generated on surfaces that easily stick to it, or contamination of areas such as the inner wall of a bathroom or the peripheral edges of bathtubs, washbasins, etc., where cleaning is relatively difficult, and stubborn organic matter such as ventilation fans and range hoods, oil, etc. It is extremely effective when applied to the soiled areas, etc., and has a remarkable effect on the removal of adhering bacterial cells such as black mold, and has no drawbacks such as dripping during use and spreading contamination around it. The purpose is to provide a detergent.
【0004】特に、本発明は、ソジウム・モンモリロナ
イト水膨潤体と尿素との複合体を使用してこれが各種の
有機物等と容易に反応し、該有機物等を包接する特性を
利用してなされたものであるが、かかるソジウム・モン
モリロナイト水膨潤体を洗剤として使用する試みは今日
まで全くなされていなかった。ソジウム・モンモリロナ
イトは粘土鉱物のひとつで、化粧品原料基準に収載さ
れ、また、食品添加物にも収載されているものであっ
て、人体等に対する危険性は全くなく、使用上安全であ
り、従来黒黴に使用されていた塩素系の洗剤等と異な
る。また、ソジウム・モンモリロナイトの水膨潤ゲル体
は粘性を有し、流動について極めて良好なチキソトロピ
ー性を有する。従って、ソジウム・モンモリロナイト水
膨潤ゲル体は、浴槽内面、垂直壁、或いは、天井部位等
に噴霧又は塗布しても、垂下又は流下することがない。
また、スプレイすることにより容易に粘度を低下してノ
ズルから噴出し、壁面等に付着すると粘度を回復し垂下
又は流下等しない。In particular, the present invention is made by utilizing a complex of a water-swelling body of sodium montmorillonite and urea, which easily reacts with various organic substances and the inclusion of the organic substances. However, no attempt has been made to date to use such a water-swelled body of sodium montmorillonite as a detergent. Sodium montmorillonite is one of the clay minerals, which is listed in the cosmetics raw material standard and is also listed in food additives.There is no danger to the human body, it is safe to use, and it is black It is different from the chlorine-based detergent used for mold. Further, the water-swelling gel body of sodium montmorillonite has viscosity and has very good thixotropy for flow. Therefore, the sodium-montmorillonite water-swelling gel body does not droop or flow down even if it is sprayed or applied to the inner surface of the bathtub, the vertical wall, the ceiling portion, or the like.
Further, when sprayed, the viscosity is easily reduced and ejected from the nozzle, and when it adheres to a wall surface or the like, the viscosity is recovered and does not droop or flow down.
【0005】[0005]
【課題を解決するための手段】本発明は、ソジウム・モ
ンモリロナイト水膨潤ゲルに尿素を添加してなる複合体
を主成分として構成される新洗剤を要旨とするもので、
該新洗剤には、テルペン類に属するリモネン、ピネン、
ミルセン、カレン、オシメン、カンフェン、テルピノン
のうちの1種又は2種以上を添加するものを含むととも
に、界面活性剤を添加するものをも含むものである。Means for Solving the Problems The gist of the present invention is a new detergent composed mainly of a complex obtained by adding urea to a sodium-montmorillonite water-swollen gel.
The new detergent includes limonene, pinene, which belongs to terpenes,
It includes one to which one or more of myrcene, karen, ocimene, camphene, and terpinone are added, and one to which a surfactant is added.
【0006】本発明に係るソジウム・モンモリロナイト
はベントナイト原鉱を粉砕して水に投じて膨潤させて希
薄なゾルを作るとともに共存するシルト分を完全に沈降
除去し、ついで、該希薄ゾルを濃縮して洗剤の材料とし
て使用するものであるが、極めてクリーミーな状態を呈
している。この水膨潤体は有機物特にたんぱく質、アミ
ノ酸等を容易に包接・吸着する。このため、浴室、厨
房、洗面所等における比較的頑固な有機物汚染を除去す
ることができる。本発明に係るソジウム・モンモリロナ
イトの水膨潤体の洗滌性能は若干量の尿素を添加して生
成される複合体の場合にさらに効果的である。特に黒黴
の菌体に作用してこれを溶解し、水膨潤体の包接・吸着
作用に付加して優れた菌体除去作用を有する。処理法と
しては、複合体を主体とする洗剤をスプレー又は塗布等
することにより10時間程度経過後水洗すれば汚染が容
易に除去される。この際強く擦る等の手段を殆んど必要
としない。しかも、何等の危険もなく、有毒ガスの発生
等全くない。The sodium montmorillonite according to the present invention is prepared by crushing bentonite raw ore and swelling it in water to form a dilute sol and completely removing coexisting silt components, and then concentrating the dilute sol. Although it is used as a detergent material, it is extremely creamy. This water swollen body easily includes and adsorbs organic substances, particularly proteins and amino acids. Therefore, it is possible to remove relatively stubborn organic contaminants in bathrooms, kitchens, washrooms, and the like. The cleaning performance of the water-swelled body of sodium montmorillonite according to the present invention is more effective in the case of the complex formed by adding a slight amount of urea. In particular, it acts on the black mold cells to dissolve them, and in addition to the inclusion and adsorption of the water-swelled body, it has an excellent cell removal effect. As a treatment method, a detergent containing a composite as a main component is sprayed or applied, and after washing for about 10 hours, water is washed to easily remove the contamination. At this time, almost no means such as strong rubbing is required. Moreover, there is no danger and no toxic gas is generated.
【0007】さらに、請求項2で挙げられるテルペン類
の諸化合物及び又は請求項の界面活性剤は本願に係る新
洗剤の有機物除去効果を更に高めうるものである。かか
るテルペン類及び界面活性剤の添加混入は、洗剤に良好
なチキソトロピー性を付与して、天井又は垂直面に適用
される場合にも、施工面から落下又は流下しない状態
で、洗滌能力を格段に付加向上し、有機物汚染をより迅
速に、かつ、効率よく除去しうるものである。Furthermore, the compounds of the terpenes mentioned in claim 2 and / or the surfactant of the claims can further enhance the organic substance removing effect of the new detergent according to the present application. Addition and mixing of such terpenes and surfactants impart good thixotropy to the detergent, and even when applied to the ceiling or vertical surface, the cleaning ability is markedly reduced without falling or flowing down from the construction surface. It is possible to improve the addition and remove the organic contaminants more quickly and efficiently.
【0008】[0008]
【実施例】以下、実施例に基づいて本洗剤の組成につい
て述べる。 その1.主としてスプレー用に供するもの(合計100重量部) ソジウム・モンモリロナイト 2.8〜1.5重量部 水 95.4〜93.9重量部 尿素 1.5〜1.3重量部 界面活性剤 1.7〜1.3重量部 制菌剤 0.3〜0.2重量部 その2.主としてペースト状で使用するもの(合計100重量部) ソジウム・モンモリロナイト 6.5〜3.0重量部 水 92.3〜84.2重量部 尿素 6.0〜3.0重量部 界面活性剤 3.0〜1.5重量部 制菌剤 0.3〜0.2重量部 その3.主としてスプレー用に供するもの(合計100重量部) ソジウム・モンモリロナイト 3.5〜2.5重量部 水 90.8〜86.9重量部 尿素 2.3〜1.5重量部 ミルセン(テルペン属) 7.3〜5.2重量部 その4.主としてペースト状で使用するもの(合計100重量部) ソジウム・モンモリロナイト 5.5〜3.5重量部 水 89.1〜84.3重量部 尿素 3.2〜2.4重量部 ミルセン(テルペン属) 7.0〜5.0重量部EXAMPLES The composition of the present detergent will be described below based on examples. Part 1. Mainly used for spraying (total 100 parts by weight) Sodium montmorillonite 2.8 to 1.5 parts by weight Water 95.4 to 93.9 parts by weight Urea 1.5 to 1.3 parts by weight Surfactant 1.7 ~ 1.3 parts by weight Antibacterial agent 0.3 to 0.2 parts by weight Part 2. Mainly used in paste form (total 100 parts by weight) Sodium montmorillonite 6.5-3.0 parts by weight Water 92.3-84.2 parts by weight Urea 6.0-3.0 parts by weight Surfactant 3. 0-1.5 parts by weight Antibacterial agent 0.3-0.2 parts by weight Part 3. Mainly used for spraying (total 100 parts by weight) Sodium montmorillonite 3.5-2.5 parts by weight Water 90.8-86.9 parts by weight Urea 2.3-1.5 parts by weight Myrcene (terpene) 7 .3 to 5.2 parts by weight Mainly used in paste form (total 100 parts by weight) Sodium montmorillonite 5.5 to 3.5 parts by weight Water 89.1 to 84.3 parts by weight Urea 3.2 to 2.4 parts by weight Myrcene (terpene) 7.0 to 5.0 parts by weight
【0009】[0009]
【発明の効果】本発明は、以上の如く、ソジウム・モン
モリロナイト水膨潤ゲルに尿素を添加してなる複合体を
主成分としてなるものであって、その複合体が有機物を
包接・吸着する作用が顕著であるから黒黴等の菌体や頑
固な付着物を容易に除去しうるものであり、さらに、特
にテルペン類及び界面活性剤の混入は、洗剤に良好なチ
キソトロピー性を付与して、天井又は垂直面に適用され
る場合に、施工面から落下又は流下しない状態で、しか
も洗滌能力を格段に付加向上せしめ、有機物汚染を迅速
にかつ、効率よく除去しうるもので、極めて有用な新洗
剤といいうるものである。As described above, the present invention is mainly composed of a complex obtained by adding urea to a sodium-montmorillonite water-swelling gel, and the action of the complex to include and adsorb an organic substance. It is possible to easily remove spores and stubborn deposits such as black mold because it is remarkable, and further, especially mixing of terpenes and a surfactant imparts good thixotropy to the detergent, When applied to a ceiling or a vertical surface, it does not drop or flow down from the construction surface, and the cleaning ability can be markedly improved, and organic contaminants can be removed quickly and efficiently. It can be called a detergent.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 (C11D 7/60 7:20 7:32 7:24) ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Office reference number FI technical display location (C11D 7/60 7:20 7:32 7:24)
Claims (3)
に尿素を添加してなる複合体を主成分として構成される
新洗剤。1. A new detergent comprising a complex obtained by adding urea to a sodium-montmorillonite water-swelling gel as a main component.
ン、カレン、オシメン、カンフェン、テルピノンのうち
の1種又は2種以上を添加してなる請求項1に記載の新
洗剤。2. The new detergent according to claim 1, wherein one or more of limonene, pinene, myrcene, karen, ocimene, camphene and terpinone of the terpene genus are added.
請求項2に記載の新洗剤。3. The new detergent according to claim 1 or 2, wherein a surfactant is added.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28563993A JPH07118694A (en) | 1993-10-21 | 1993-10-21 | New detergent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28563993A JPH07118694A (en) | 1993-10-21 | 1993-10-21 | New detergent |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH07118694A true JPH07118694A (en) | 1995-05-09 |
Family
ID=17694140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP28563993A Pending JPH07118694A (en) | 1993-10-21 | 1993-10-21 | New detergent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07118694A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002010328A1 (en) * | 2000-07-14 | 2002-02-07 | Lee Chang Sub | A detergent composition for tablewares having germicidal effect |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01190622A (en) * | 1988-01-25 | 1989-07-31 | Nikkei New Bijinesu Kk | Novel hair shampoo |
JPH04258699A (en) * | 1991-02-12 | 1992-09-14 | Nendo Kagaku Kenkyusho:Kk | New cleaner |
-
1993
- 1993-10-21 JP JP28563993A patent/JPH07118694A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01190622A (en) * | 1988-01-25 | 1989-07-31 | Nikkei New Bijinesu Kk | Novel hair shampoo |
JPH04258699A (en) * | 1991-02-12 | 1992-09-14 | Nendo Kagaku Kenkyusho:Kk | New cleaner |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002010328A1 (en) * | 2000-07-14 | 2002-02-07 | Lee Chang Sub | A detergent composition for tablewares having germicidal effect |
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