CN101358161A - Novel energy-saving composite surface active agent post-match particle - Google Patents
Novel energy-saving composite surface active agent post-match particle Download PDFInfo
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- CN101358161A CN101358161A CNA2008100793385A CN200810079338A CN101358161A CN 101358161 A CN101358161 A CN 101358161A CN A2008100793385 A CNA2008100793385 A CN A2008100793385A CN 200810079338 A CN200810079338 A CN 200810079338A CN 101358161 A CN101358161 A CN 101358161A
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Abstract
The present invention relates to washing powder ingredient, in particular to novel energy-saving later-blended composite surfactant granule. The present invention resolves the problem on adding and applying fatty alcohol polyoxyethylene ether sulfate in the production of washing powder. The novel energy-saving composite surfactant later-blended granule contains the materials with the following weight portions: 5 to 45 portions of surfactant, 5 to 55 portions of 4A zeolite and 1 to 15 portions of calcined soda. After being uniformly mixed, the materials are packaged, cut and granulated. Being applied in the formula synthesizing washing powder, the novel energy-saving composite surfactant later-blended granule has the advantages of good low-temperature washing property, good fluidity, rich foam, low cost, low energy consumption, high efficiency, environment-friendliness, etc.
Description
Technical field
The present invention relates to a kind of washing powder batching, be specially a kind of novel energy-saving composite surface active agent post-match particle.
Background technology
At present, that sells on the market now has with the washing powder product: common high tower spraying washing powder, concentrated detergent powder, hyperconcentrated washing powder, sheet washing powder.Since the nineties in 20th century, the development of external washing composition mainly concentrates on enrichment and no phosphatization two broad aspect.Based on the consideration of preserving the ecological environment, many in the world countries particularly developed country all advance the no phosphatization of washing composition in the mode with oneself.Domestic law in the later stage nineties 20th century taboo phosphorus, limit phosphorus is put into effect successively, and on September 1st, 2004, " washing powder " national standard (GBT13171-2004) issue enforcement of new revision, and all the no phosphatization for washing powder provides the policy guarantee.
Existing slow and to Mg for overcoming with builder as substitute for phosphate 4A zeolite ion-exchange speed
2+The shortcoming that the constraint ability is weak, need increase the consumption of alkaline sedimentation type auxiliary agent, as yellow soda ash, metasilicate and δ-layered silicate etc.The adding of sedimentation type auxiliary agent, can cause the increase of deposition on the fabric, need to add polycarboxylic acid salt's coassist agent, also on forming, actives increase the consumption of anion surfactant and AEO type nonionogenic tenside simultaneously, consequently increased the raw materials cost of no phosphorus powder, equal performance time ratio contains the phosphorus powder cost and exceeds 15-20%.
Because most of washing powder belong to the high tower spray product, will be in the production process with the slip process high temperature atomization drying process of 60-70%, institute is so that the loss of thermo-sensitivity actives effective ingredient, energy consumption is bigger simultaneously, environmental pollution is serious, both increase formulation cost, also influenced the quality of product simultaneously.
Domestic washing habits mostly is cold water washing greatly, the washing powder of existing high tower spray shaping washs usefulness and can not bring into play fully under low temperature condition, and the loss in existing high tower spraying production technique of the well behaved tensio-active agent of cold washing is more, has restricted it in detergent application.
The fatty alcohol polyoxyethylene ether sulfate class.Be a good suitable cold washing performance, anti-hard water will destroy this composition, the effective technology means that also do not address this problem at present if directly add this composition according to the production technique of existing washing powder.
Summary of the invention
The present invention produces the problem of adding application and a kind of novel energy-saving composite surface active agent post-match particle is provided in order to solve the fatty alcohol polyoxyethylene ether sulfate class that exists in the prior art in washing powder.
The present invention is realized by following technical scheme, a kind of novel energy-saving composite surface active agent post-match particle, the raw material that comprises the following weight ratio example, 5～45 parts of tensio-active agents, 5～55 parts of 4A zeolites, 1～15 part of soda ash, after raw material mixed, on granulating equipment, wrap up shear granulation.
Also comprise: raw material also comprises 0～15 part of wilkinite, 0～15 part of laminated crystal of sodium disilicate, 0～30 part Sodium sulfate anhydrous.min(99), 0～10 part of gypsum.
Glass or plastic containers fatty alcohol-polyoxyethylene ether (AEO-9 and AEO-7) and or anion surfactant fatty alcohol polyoxyethylene ether sulfate (AES).
The preparation method is to be major ingredient with the tensio-active agent, adding wilkinite, 4A zeolite, soda ash, laminated crystal of sodium disilicate are made binding agent and washing auxiliary detergent, adding Sodium sulfate anhydrous.min(99), gypsum are made toughener, after mixing, on granulating equipment, wrap up shear granulation, particle is sieved through 10-40 purpose screen cloth, and packing is by the particle of 10-40 eye mesh screen screening at last.
Novel energy-saving composite surface active agent post-match particle of the present invention, according to the part by weight of 1-40 part, later allotment of labor's skill and high tower spray art use in conjunction with adding in the washing powder or to add in the washing powder in the technology adding washing powder of the attached polymer molding or in dried mode of mixing.
Novel energy-saving composite surface active agent post-match particle formula for a product cold washing excellent property, with low cost, environment-friendly high-efficiency; Production technology has that facility investment is few, technology is simple, easy to operate, low power consumption and other advantages.
Its product application in synthetic detergent powder prescription, is had that the cold washing performance is good, a good fluidity, foam height, low, the less energy consumption of cost, advantages such as high-efficiency environment friendly.
Embodiment
Embodiment 1: a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
5 parts of tensio-active agents, 55 parts of 4A zeolites, 1 part of soda ash after raw material mixed, wrap up shear granulation on granulating equipment.
The parcel shear granulation is an ordinary method, concrete working method is as follows, soda ash, 4A zeolite, laminated crystal of sodium disilicate are added in the mixing tank, pouring tensio-active agent-fatty alcohol polyoxyethylene ether sulfate (AES) into stirred 10 minutes, after mixing, wrap up shear granulation on granulating equipment, particle is sieved through 10 purpose screen clothes, packing is by the particle of 10 eye mesh screens at last.The big pellet of screening gained returns mixing machine to be mixed with next pot again, and carries out granulation again.
Embodiment 2: a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
45 parts of tensio-active agents, 5 parts of 4A zeolites, 15 parts of soda ash after raw material mixed, wrap up shear granulation on granulating equipment.
The parcel shear granulation is an ordinary method, concrete working method is as follows, soda ash, 4A zeolite, laminated crystal of sodium disilicate are added in the mixing tank, pouring tensio-active agent-fatty alcohol polyoxyethylene ether sulfate (AES) into stirred 10 minutes, after mixing, wrap up shear granulation on granulating equipment, particle is sieved through 10 purpose screen clothes, packing is by the particle of 10 eye mesh screens at last.The big pellet of screening gained returns mixing machine to be mixed with next pot again, and carries out granulation again.
Embodiment 3, and a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
After 5 parts of tensio-active agents, 40 parts of 4A zeolites, 15 parts of soda ash, 15 parts of laminated crystal of sodium disilicate, 25 parts Sodium sulfate anhydrous.min(99) mix raw material, on granulating equipment, wrap up shear granulation.
The parcel shear granulation is an ordinary method, concrete working method is as follows, soda ash, 4A zeolite, laminated crystal of sodium disilicate, Sodium sulfate anhydrous.min(99) powder are added in the mixing tank, pouring tensio-active agent-fatty alcohol polyoxyethylene ether sulfate (AES) into stirred 10 minutes, after mixing, wrap up shear granulation on granulating equipment, particle is sieved through 10 purpose screen clothes, packing is by the particle of 10 eye mesh screens at last.The big pellet of screening gained returns mixing machine to be mixed with next pot again, and carries out granulation again.Its examination and test of products result is:
Table 1 example 1 is implemented the detected result of back composite surface active agent post-match particle
| Project | Index |
| Whiteness (R457): | 95 |
| The caking degree: | 0.15 |
| Tap density (g/cm 3)： | 0.87 |
| Granularity (by 10 orders): | 100％ |
| Gross activity thing (%): | 5.02 |
| Moisture content (%): | 3 |
The complexed surfactant particle the made dosage with 5 parts is added in the washing powder prescription, and through the detergency ability test, under condition of cost, sebum soiled cotton and carbon black soiled cotton performance increase more than 5%, and under the situation with performance, cost reduces by 130 yuan/T.
Require to carry out the contrast of washing powder detergency ability according to the washing powder GB, simulate the Actual laundering situation simultaneously, under 15 ℃ of low temperature and Yuncheng, Shanxi tap water (approximately 430ppm) condition, carry out detergency test.Two prescriptions of checking are with the performance comparison under the cost situation.
Decontamination performance comparison under the different wash conditions of table 2
*: carry out with the step in the mensuration of washing composition detersive power and anti-soil stain deposition capability with reference to the GB/T13174-2003 dress material.
Embodiment 4, and a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
20 parts of tensio-active agents, 40 parts of 4A zeolites, 8 parts of soda ash, 10 parts of laminated crystal of sodium disilicate, 18 parts Sodium sulfate anhydrous.min(99), 4 parts of gypsum after raw material mixed, wrap up shear granulation on granulating equipment.
The parcel shear granulation is an ordinary method, concrete working method is as follows, soda ash, 4A zeolite, laminated crystal of sodium disilicate powder are added in the mixing tank, add Sodium sulfate anhydrous.min(99), gypsum powder, slowly pour into fatty alcohol polyoxyethylene ether sulfate and or fatty alcohol-polyoxyethylene ether AEO-9 stirred 10 minutes, after mixing, on granulating equipment, wrap up shear granulation, after mixing, on granulating equipment, wrap up shear granulation, particle is sieved through 10 purpose screen clothes, and packing is by the particle of 10 eye mesh screens at last.The big pellet of screening gained returns mixing machine to be mixed with next pot again, and carries out granulation again.Its examination and test of products result is:
Table 3 embodiment 2 implements the detected result of back composite surface active agent post-match particle
| Project | Index |
| From spending (R457): | 98 |
| The caking degree: | 0.5 |
| Tap density (g/cm 3)： | 0.79 |
| Granularity (by 10 orders): | 99％ |
| Gross activity thing (%): | 20 |
| Moisture content (%): | 7 |
The complexed surfactant particle the made dosage with 20 parts is added in the washing powder, and through the detergency ability test, under condition of cost, sebum soiled cotton and carbon black soiled cotton detergency ability increase more than 10%, with performance
Under the situation, cost reduces by 200 yuan/T.
Decontamination performance comparison under the different wash conditions of table 4
*: carry out with the step in the mensuration of washing composition detersive power and anti-soil stain deposition capability with reference to the GB/T13174-2003 dress material.
Require to carry out the contrast of washing powder detergency ability according to the washing powder GB, simulate the Actual laundering situation simultaneously, under 15 ℃ of low temperature and Yuncheng, Shanxi tap water (approximately 430ppm) condition, carry out detergency test.Two prescriptions of checking are with the performance comparison under the cost situation.
Embodiment 5, and a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
40 parts of tensio-active agents, 50 parts of 4A zeolites, 2 parts of soda ash, 5 parts of wilkinites, 3 parts Sodium sulfate anhydrous.min(99) after raw material mixed, wrap up shear granulation on granulating equipment.
The parcel shear granulation is an ordinary method, concrete working method is as follows, the preparation method adds soda ash, 4A zeolite, wilkinite powder in the mixing tank, add Sodium sulfate anhydrous.min(99), slowly pour fatty alcohol polyoxyethylene ether sulfate and fatty alcohol-polyoxyethylene ether AEO-7 into and stirred 10 minutes, after mixing, on granulating equipment, wrap up shear granulation, particle is sieved through 10 purpose screen clothes, and packing is by the particle of 10 eye mesh screens at last.The big pellet of screening gained returns mixing machine to be mixed with next pot again, and carries out granulation again.Its examination and test of products result is:
Table 5 embodiment 3 implements the detected result of back composite surface active agent post-match particle
| Project | Index |
| Whiteness (R457): | 99 |
| The caking degree: | 1.0 |
| Tap density (g/cm 3)： | 0.75 |
| Granularity (by 10 orders): | 98％ |
| Gross activity thing (%): | 40 |
| Moisture content (%): | 10 |
The complexed surfactant particle of making is directly used as washing powder, and through the detergency ability test, under condition of cost, sebum soiled cotton and carbon black soiled cotton detergency ability increase more than 30%, and under the situation with performance, cost reduces by 260 yuan/T.
Require to carry out the contrast of washing powder detergency ability according to the washing powder GB, simulate the Actual laundering situation simultaneously, under 15 ℃ of low temperature and Yuncheng, Shanxi tap water (approximately 430ppm) condition, carry out detergency test.Two prescriptions of checking are with the performance comparison under the cost situation.
Decontamination performance comparison under the different wash conditions of table 6
*: carry out with the step in the mensuration of washing composition detersive power and anti-soil stain deposition capability with reference to the GB/T13174-2003 dress material.
Embodiment 6, and a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
30 parts of tensio-active agents, 25 parts of 4A zeolites, 10 parts of soda ash, 15 parts of wilkinites, 30 parts Sodium sulfate anhydrous.min(99), 10 parts of gypsum, 15 parts of laminated crystal of sodium disilicate after raw material mixed, wrap up shear granulation on granulating equipment.
Claims (6)
1, a kind of novel energy-saving composite surface active agent post-match particle is characterized in that: comprise the raw material of following weight ratio example,
5～45 parts of tensio-active agents, 5～55 parts of 4A zeolites, 1～15 part of soda ash after raw material mixed, wrap up shear granulation on granulating equipment.
2, novel energy-saving composite surface active agent post-match particle according to claim 1 is characterized in that: raw material also comprises 0～15 part of wilkinite.
3, novel energy-saving composite surface active agent post-match particle according to claim 1 is characterized in that: raw material also comprises 0～15 part of laminated crystal of sodium disilicate.
4, novel energy-saving composite surface active agent post-match particle according to claim 1 is characterized in that: raw material also comprises 0～30 part Sodium sulfate anhydrous.min(99).
5, novel energy-saving composite surface active agent post-match particle according to claim 1 is characterized in that: raw material also comprises 0～10 part of gypsum.
6, novel energy-saving composite surface active agent post-match particle according to claim 1 is characterized in that: glass or plastic containers fatty alcohol-polyoxyethylene ether and or anion surfactant fatty alcohol polyoxyethylene ether sulfate.
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| CNA2008100793385A CN101358161A (en) | 2008-09-03 | 2008-09-03 | Novel energy-saving composite surface active agent post-match particle |
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|---|---|---|---|
| CNA2008100793385A CN101358161A (en) | 2008-09-03 | 2008-09-03 | Novel energy-saving composite surface active agent post-match particle |
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| CN101358161A true CN101358161A (en) | 2009-02-04 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113996A (en) * | 2013-01-24 | 2013-05-22 | 江苏创新日化科技有限公司 | Phosphate-free washing powder and production method thereof |
| CN106085632A (en) * | 2016-06-12 | 2016-11-09 | 四川省眉山市金庄新材料科技有限公司 | A kind of instant detergent intersperses thing and detergent |
| CN106753835A (en) * | 2016-11-30 | 2017-05-31 | 深圳市优代尔互联网科技有限公司 | Carwash powder and preparation method thereof and car-washing method |
| GB2569938A (en) * | 2016-06-12 | 2019-07-10 | Sichuan Jinzhuang Tech Co Ltd | Instant washing powder speckle and washing powder |
| CN112500936A (en) * | 2020-12-11 | 2021-03-16 | 纳爱斯集团有限公司 | Washing powder and production process thereof, and granulated powder and granulation process thereof |
| CN114507572A (en) * | 2021-04-30 | 2022-05-17 | 东莞市合信新材料有限公司 | Long-acting solid laundry detergent ball and preparation method thereof |
-
2008
- 2008-09-03 CN CNA2008100793385A patent/CN101358161A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113996A (en) * | 2013-01-24 | 2013-05-22 | 江苏创新日化科技有限公司 | Phosphate-free washing powder and production method thereof |
| CN106085632A (en) * | 2016-06-12 | 2016-11-09 | 四川省眉山市金庄新材料科技有限公司 | A kind of instant detergent intersperses thing and detergent |
| WO2017215260A1 (en) * | 2016-06-12 | 2017-12-21 | 四川省眉山市金庄新材料科技有限公司 | Instant washing powder speckle and washing powder |
| GB2569938A (en) * | 2016-06-12 | 2019-07-10 | Sichuan Jinzhuang Tech Co Ltd | Instant washing powder speckle and washing powder |
| GB2569938B (en) * | 2016-06-12 | 2022-03-02 | Sichuan Jinzhuang Tech Co Ltd | Ornament of an instant detergent and detergent |
| CN106753835A (en) * | 2016-11-30 | 2017-05-31 | 深圳市优代尔互联网科技有限公司 | Carwash powder and preparation method thereof and car-washing method |
| CN112500936A (en) * | 2020-12-11 | 2021-03-16 | 纳爱斯集团有限公司 | Washing powder and production process thereof, and granulated powder and granulation process thereof |
| CN112500936B (en) * | 2020-12-11 | 2024-03-19 | 纳爱斯集团有限公司 | Washing powder and production process thereof, granulating powder and granulating process of granulating powder |
| CN114507572A (en) * | 2021-04-30 | 2022-05-17 | 东莞市合信新材料有限公司 | Long-acting solid laundry detergent ball and preparation method thereof |
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Open date: 20090204 |