CN107446732A - A kind of submissive whitening laundry soap composition and preparation method thereof - Google Patents
A kind of submissive whitening laundry soap composition and preparation method thereof Download PDFInfo
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- CN107446732A CN107446732A CN201710719826.7A CN201710719826A CN107446732A CN 107446732 A CN107446732 A CN 107446732A CN 201710719826 A CN201710719826 A CN 201710719826A CN 107446732 A CN107446732 A CN 107446732A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
Abstract
The present invention relates to daily chemical product technical field, specially a kind of submissive whitening laundry soap composition and preparation method thereof.The present invention is submissive, and whitening laundry soap composition improves common laundry soap product to the compliance after fabric washing, reduce the soap scum deposition that soap scum is deposited on clothing simultaneously, avoiding soap scum from being aoxidized on fabric causes clothes to turn to be yellow, and the brilliant white color of clothing can be kept containing the factor is brightened in submissive whitening laundry soap composition.The existing washing drawback of the traditional laundry soap of submissive whitening laundry soap composition for improved, has widened the washing functions of laundry soap, improves the washing function of laundry soap product.
Description
Technical field
The present invention relates to daily chemical product technical field, more particularly to a kind of submissive whitening laundry soap composition and its system
Preparation Method.
Background technology
Soap has a long history, and is most ancient articles for washing, so far the existing history of more than 4000 years, and soap is true
Just be commonly used is after 18th century.China's cleaning product industry just starts there was only soap products during development, new China into
After vertical, soap industry technology is greatly improved and improved, in continuous saponification process, grease hydrolysis and soapmaking etc. so that domestic technique
Constantly progressive, yield also increases year by year.Probably only about 30,000 tons of the yield of national soap in 1949, but it is fertile after founding of New
Soap industry obtains breakthrough, and nineteen fifty-two yield reaches 100,000 tons, rises to 59.6 ten thousand tons within 1978, until reaching for 1988
119.8 ten thousand tons of yield, and highest annual production so far.To 20 middle of century, the fast development of synthetic detergent, and
Synthetic detergent is in the various aspects function admirables such as the compatibility of hard water resistance property and inorganic salts synergy, synthetic detergent industry
Obtain rapid growth so that soap industry receives huge impact, causes soap yield to glide year by year.But soap kind produces
Because itself source is natural and dirt-removing power is strong etc., characteristic makes it still have certain vitality to product, soap kind production since 2000
The annual production of product is fluctuated in 70~750,000 tons of sections always, and yield had ascendant trend in recent years.
As a kind of conventional washing articles for use, soap has that raw material is natural, have a safety feature, biological degradability is excellent, performance
Gently, suitable the advantages that hand-washing, be free from environmental pollution.Consumer is complied with to green product and the growing interest of Environmental security, soap
Favored again by people.But the shortcomings that common soap is also it will be apparent that wherein most important shortcoming：1st, hard water
Middle performance is poor, and the calcium ions and magnesium ions in water are generated without detergency and calcium and magnesium soap not soluble in water with soap, are not only caused a large amount of
Soap be wasted, and calcium and magnesium soap is adhered to fabric face with the molecular force absorbing fats of its strong hydrophobic group acid and dirt,
And aoxidize, become sour, weaken the graying yellowing of fabric, the embrittlement that is hardened, fastness.2nd, under low temperature washing conditions, solubility of soap
It is low, have a strong impact on dirt-removing power.Many traditional compound soaps need to add substantial amounts of washing assisant, such as sodium silicate and sodium tripolyphosphate
Deng, but this does not meet the without phosphorus requirement of articles for washing, also results in soap and a large amount of free alkalis be present and stimulate skin.Washing powder and
Liquid detergent uses synthetic surfactant and auxiliary agent, substantially improve soap scum formed and redeposited phenomenon, but soap with mostly
Surfactant incompatibility, the surfactant of hard water resistance better performances is caused to add less than in conventional soap formula so that fertilizer
Soap easily makes fabric jaundice the problem of being hardened be unsolved problem always.To extend the application of soap, fertilizer is given full play to
The advantage of soap, employs new technology and soap is modified, and has its necessity so as to develop soap of new generation.
At present in Betengent product, in order to make up or slow down the phenomenon that worn after fabric repeatedly washs, increased mostly using fluorescence
White agent carries out whitening and brightening, also gives a kind of clean degree of sense organ of consumer really.Fluorescent whitening agent can absorb ultraviolet light (wavelength model
It is trapped among between 300~400nm), then launch the macroscopic bluish violet fluorescence (wave-length coverage is between 420~480nm) of people,
With the gold-tinted complementation in matrix so as to reaching whitening effect.Increasing consumer pays close attention to product safety, green, health, glimmering
The security of optical brightener causes consumer to query, and starts the cleaning product that prioritizing selection is free of fluorescent whitening agent.For soap
For product, allow after fabric washing do not harden, it is non-yellowing be a problem more in the urgent need to address.
At present there is phenomenon in laundry soap field and technical problem is as follows：
1st, professional and technical personnel also can expect soap and other surfaces activating agent except expecting adding a large amount of inorganic assistants
Compounding, reduce soap scum formation and reduce soap scum being deposited on fabric, but often select the improper or limited use of surfactant
Amount can not effectively reduce soap scum.And soap mentioned above and most surfactant are also incompatible, are mainly embodied in：Surface
After activating agent is added to laundry soap, laundry soap soap body tissue is loose, cracking, it is impossible to effectively shaping.Existing public technology is not looked for
It is to a kind of suitable mode that surfactant is friendly compatible with laundry soap, and accomplish scale production.
2nd, softener has good submissive effect, is primarily due to softener by being attached to clothing surface, makes fiber
Like charges, mutually exclusive are taken, so as to reduce coefficient of friction, enhance mobility, the intrinsic smooth, extension of fiber,
Compression performance is also recovered, and then causes fabric to become submissive.Softener composition is mainly cationic surfactant, but
With the anion surfactant such as the main wash constituents fats acid sodium-salt in laundry soap product and incompatible, if using meeting simultaneously
Both performances are reduced, and after rinse stage, the cationic surfactant rested on fabric greatly reduces, Wu Faqi
To submissive effect.Comparatively speaking, laundry soap is due to own limitations, it is easier to hardened after making fabric washing, many soap products
Declare that adding softener reaches submissive effect, actually but produces little effect even without effect.
3rd, successful cleaning product of the listing with whitening effect, is nearly all to improve fabric whiteness by fluorescent whitening agent
, and fluorescent whitening agent is gradually understood as dangerous composition by consumer.Some in certain detergent also with the addition of SODIUM PERCARBONATE
Etc. compound, certain bleaching effect can be played, using by compared with big limitation.Also laundry soap declares that addition SODIUM PERCARBONATE is reachable
Contain 20% or so moisture to bleaching and then declare with whitening effect, but in actually common laundry, SODIUM PERCARBONATE is at this
It is that can not keep existing for a long time under environment, will decomposition failure in the short time, it is impossible to be really applied in laundry soap.
4th, in order to reduce soap scum in conventional technology, most commonly used is exactly to add the builders such as inorganic salts, is on the one hand subtracted
The content of few fatty acid sodium salt, to human body skin when on the other hand improving detergency by increasing alkalescence, but adding washing
Excitant, it is most important that after adding a large amount of inorganic salts, easily there are quality problems in laundry soap, such as emits frost, phenomena such as becoming mildewed,
And it is broken during use laundry soap to be caused seriously to ftracture, and reduces laundry soap practicality, and cause to waste.
The content of the invention
The present invention easily makes fabric jaundice be hardened for existing laundry soap using rear, and adds surfactant presence
Because it causes with soap body poor compatibility that soap body tissue is loose, cracking, it is impossible to the problem of being effectively molded, there is provided one kind is lived containing surface
Property agent and it is good with soap body compatibility, be easy to the submissive whitening laundry soap of shaping, and the preparation method of this kind of laundry soap.
To achieve the above object, the present invention uses following technical scheme.
A kind of submissive whitening laundry soap composition, include each component of following parts by weight：
60~96 parts of neat soap；
2~25 parts of surfactant；
0.1~10 part of forming agent；
0.01~5 part of chelating agent；
Other 0~5 part of auxiliary agents；
And the weight of surfactant and neat soap ratio is 1:48~1:2.5.
Preferably, the submissive whitening laundry soap composition also includes parts by weight and is 0.01~2 part brightening the factor or increasing
White particle.
Preferably, the parts by weight of each component are in the submissive whitening laundry soap composition：
65~90 parts of neat soap；
5~22 parts of surfactant；
1.5~10 parts of forming agent；
0.01~5 part of chelating agent；
Other 0~5 part of auxiliary agents.
It is furthermore preferred that the parts by weight of each component are in the submissive whitening laundry soap composition：
75~90 parts of neat soap；
7~13 parts of surfactant；
1.5~5 parts of forming agent；
0.01~5 part of chelating agent；
Other 0~5 part of auxiliary agents.
Above-described forming agent is poly alkyl alcohol ethers nonionic, microcrystalline cellulose, sodium carboxymethylcellulose, palm
Wax, sodium carboxymethyl starch, polyethylene adjoin pyrrolidone, polyethylene glycol, dextrin, guar gum, acrylic resin, polycarboxylic acids sodium, propylene
At least one of homopolymer and copolymer of acid and maleic acid.
Research process are found, can cleverly make fatty acid sodium salt and various by adding above-mentioned forming agent in formula
Surfactant merges, and successfully compounds, and ensures soap body even compact, soap body tissue is no longer loose, and can smoothly be molded, scale
Production, reaches long-lived effect.Therefore these materials are referred to as forming agent.
It is above-described brighten the factor or brighten particle be containing Tinolux PSA15, Violet 452, Blue FBL,
The material of at least one of Duasyn Violet 4BN, Duasyn Red N6B and alizarol saphirol etc..
The compounding of mating surface activating agent, brightens the factor or brightens the addition of particle and discharge active oxygen under light action, from
Whitening effect substantially is played to fabric, synergy is played together with surfactant.Laundering of textile fabrics brilliant white can effectively be made
Increase the addition of gorgeous, to break traditions fluorescent whitening agent, and break through peroxide and limit to the effect of laundry soap can not add.
Above-described surfactant is fatty alcohol polyoxyethylene ether sulfate, linear alkylbenzene sulfonate (LAS), fatty alcohol
Ether carboxylate, α-sodium olefin sulfonate, lauryl sodium sulfate, SAS, MES, C12~C18
AEO, C12~C14 APGs, C12~C18 alcohol and ethylene oxide/propylene oxide block copolymer
Condensation product, C8~C20 branched-chain alcohos APEO, dodecyl alanine salt, dodecyl ethyoxyl sulfobetaines, ten
Dialkyl group hydroxypropyl sulfobetaines, dodecyl azochlorosulfonate propyl lycine, octadecyl dihydroxy ethyl amine oxide, coconut oleoyl amine third
At least one of base hydroxy sulfo lycine, cocamidopropyl propyl amide amine oxide, dodecanamide propyl amine oxide.
The compounding of neat soap and surfactant in composition, the hard water resistance effect of laundry soap is greatly improved, makes soap in water
Dirt significantly reduces, and reduces deposition of the soap scum on fabric to greatest extent, is sent out after innovative improvement laundry soap washing clothing
Hard yellowing phenomenon.Fundamentally solve the limitation of compound soap application, be not required to add the anti-soap scum of a large amount of inorganic additives, also have
Effect evades the negative effect that fluorescent whitening agent is brought.Above-mentioned one or more kinds of surfactants are only with the addition of, and are reached
To higher amount, the soap scum in water could be effectively reduced, just the soap scum formed in hard water can be made to be dispersed in water and wash away not residual
Stay on clothing.
Above-described chelating agent be citric acid and its salt, hydroxy ethylene diphosphonic acid and its salt, ethylenediamine tetra-acetic acid and
Its salt, the sodium of glutamic acid diacetic acid four, diethylene triamine penta(methylene phosphonic acid), EDTMP, hexamethylene diamine
Four (methylene phosphonic acids), diethylene-triamine pentaacetic acid, ethylenediamine disuccinic acid and its salt, the sodium of iminodisuccinic acid four, second
At least one of the diacid of diamines two, 2- hydroxyl propane diamine disuccinic acids and its salt.
A certain amount of chelating agent can make product quality more stable, avoid the shadow for the metal ion that other raw bands come
Ring, product is become sour oxidation, while can also chelate the calcium ions and magnesium ions in water, reduce and fatty acid sodium salt forms insoluble fat
Sour calcium and magnesium, and further prevent to form soap scum, soap scum is reduced and plays certain booster action.
Above-described neat soap is fatty acid sodium salt, and the fatty acid sodium salt is anti-through hydrolysis and saponification by natural oil
It should be made.The natural oil be butter, sheep oil, lard, chicken fat, duck oil, palm oil, palm-kernel oil, coconut oil, rapeseed oil,
At least one of the various natural animal oil such as sunflower oil, soybean oil and vegetable oil.
Fatty acid sodium salt carbochain composition is different in the neat soap of different grease ratios, its fatty acid calcium and fatty acid magnesium for being formed
Different Deng infusible precipitate, good grease formula can reach excellent dirt-removing power, while and can reduces insoluble soa as far as possible
The generation of dirt.
Above-described other auxiliary agents include functional aid, antioxidant applied in soap product etc..
Adding other auxiliary agents makes submissive whitening laundry soap composition form a complete formula system or feature supplement.Work(
Energy property auxiliary agent etc. enables some specific functions of formula to be superimposed, and abundant product specific use effect is played, such as bacteria remover, enzyme system
Agent, opacifier etc..Antioxidant etc. makes the stability of formula system be improved significantly, and keeps product quality within the shelf-life steady
Determine and there is excellent performance.
The perfume (or spice) that parts by weight are 0.01~5 part can be also added in the formula of above-described submissive whitening laundry soap composition
Essence.
The preparation method of above-described submissive whitening laundry soap composition, comprises the following steps：
S1, by weight ratio weigh each component respectively, standby；
S2, neat soap is added into agitated kettle and stirs crushing uniformly；
S3, continuously add forming agent into agitated kettle and stir；
S4, continuously add surfactant into agitated kettle and stir；
S5, chelating agent and other auxiliary agents are continuously added into agitated kettle, and stirred；
By refiner, three-roll grinder, vacuum plodding machine, stripping and slicing processing, laundry soap is made successively in S6, mixture.
Preferably, before step S6, in addition to continuously added into agitated kettle and brighten the factor or brighten particle and stir equal
It is even.
Whitening substance can in two forms add in laundry soap soap body and (brighten the factor or brighten particle), and a kind of mode is
By brighten the factor be directly added into laundry soap composition formula system.Another way is will first to brighten the factor and make particle to add again
Enter in soap composition of doing washing, i.e., will brighten the factor in advance and particle is made, particle is brightened in formation, standby；Use soap solid particle
The continuous adding device of thing will uniformly brighten particle and be added in agitated kettle in good time, stir.
Brighten the production technology of factor granulation：By factor proportion in particle is brightened is brightened, the factor and each will be brightened
Kind auxiliary agent or carrier, which are added in agitator, to stir, and is molded by extrusion under vacuum or other modes needed for being made and brightens grain
Son.
The preparation method of the submissive whitening laundry soap composition of the present invention is simple and easy, existing regular laundry soap can be used to give birth to
Production equipment is produced, and large-scale production can be carried out in existing legacy equipment.
The factor will be brightened and be prefabricated into whitening particulate, adding can make it relatively independent with soap body in the form of granules, not complete
It is dispersed in entirely in soap body, therefore the influence for brightening factor self color to laundry soap soap body color can be reduced, will not also makes
Into quality problems such as laundry soap discolorations.Meanwhile brighten the factor and add in the form of granules that to be that laundry soap is not only restricted to outward appearance single,
And can more stable being present in product play whitening effect, also have and intersperse or other feature effects.Surveyed through overstability
After examination, brightening particle can stablize, be independently present in soap body, and and can hair is dissolved when dissolving each other phenomenon, but washing in the absence of with soap body
Wave its efficacy effect.Above-described neat soap is made up of natural oil, and preparing for neat soap is as follows：According to a certain percentage by various days
After right grease is well mixed refining treatment, aliphatic acid and glycerine are hydrolyzed into high pressure grease hydrolysis device, wherein aliphatic acid passes through
Liquid caustic soda neutralizes, and adds a certain amount of auxiliary agent etc. and soap base is made, and soap base is vacuum dried to obtain sodium soap salt composite i.e. soap
Grain, it is standby.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention is lived to solve the problems, such as fabric can be caused to harden using after laundry soap laundering of textile fabrics by various surfaces
Property agent screening and different proportion compounding, make soap with sodium soap, reduce soap scum and reduce soap scum on fabric
Deposition, so as to reach the effect that laundering of textile fabrics does not harden, and plays the non-yellowing effect of color protection.Equivalent to fundamentally solution hair
Hard problem, rather than extra addition softener etc. produce physical action and play submissive effect.
In fact with sodium soap (neat soap) and unfriendly compatible, the addition of surfactant often makes various surfactants
Soap feels like jelly, organizes loose, soap body cracking, can not be molded in process of production.The technology of the present invention is by selecting appropriate material
(several materials disclosed in this invention) can effectively solve surfactant and neat soap consistency problem as forming agent, make screening
Surfactant farthest successfully compounded with fatty acid sodium salt, soap body tissue is no longer loose, and can smoothly be molded, industry
Metaplasia is produced.
Prior art uses fluorescent whitening agent and chemical bleaching mostly, but the security of fluorescent whitening agent is gradually disappeared
The query of the person of expense, chemical bleaching agent can not be successfully joined in laundry soap formula because of homeostasis sex chromosome mosaicism.The technology of the present invention is created
The method that the screening of new property brightens the factor using addition, during clothes washing drying, the factor is brightened in the presence of light
Active oxygen is discharged, so as to play whitening effect, while the factor is brightened and plays synergy with surfactant, common play is washed
Polyester fabric whitening effect.The inventive method technical security, unharmful substance residual, have no side effect.The fluorescent brightening to break traditions
Agent adds, and breaks through the limitation that peroxide can not add in laundry soap.
The submissive whitening laundry soap composition of the present invention improves common laundry soap product to the compliance after fabric washing,
Reduce the soap scum deposition that soap scum is deposited on clothing simultaneously, avoiding soap scum from being aoxidized on fabric causes clothes to harden, and
Containing the factor is brightened in submissive whitening laundry soap composition, the brilliant white color of clothing can be kept.Submissive whitening laundry soap composition changes
It has been apt to the existing washing drawback of traditional laundry soap, has widened the washing functions of laundry soap, improved the washing work(of laundry soap product
Can property.
Embodiment
In order to more fully understand the technology contents of the present invention, with reference to specific embodiment to technical scheme
It is described further and illustrates.
The dosage of each component is as shown in table 1 below in submissive whitening laundry soap composition described in Examples below 1~8, table 1
The measurement unit of middle each component dosage is gram (g).
The preparation method of the specifically used material of each component and submissive whitening laundry soap composition is as follows in embodiment 1~8：
Embodiment 1
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects miscella neat soap, and miscella neat soap refers to that aliphatic acid used in the neat soap is by animal oil and vegetable oil root
Hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art forms, and the neutralized neat soap being dried to obtain.Surfactant is from fat
Alcohol polyoxyethylene ether sulfate and α-sodium olefin sulfonate compounding, fatty alcohol polyoxyethylene ether sulfate and α-sodium olefin sulfonate
Mass ratio is 3:4.Forming agent selects sodium carboxymethylcellulose, and chelating agent selects the sodium of hydroxy ethylene diphosphonic acid four, brightens the factor
From Tinolux PSA15, essence selects jasmin flavor essence, other selection of auxiliary antioxidant dibutyl hydroxy toluenes
(BHT)。
The preparation method of submissive whitening laundry soap composition：
(1) load weighted neat soap is added into agitated kettle, stirring 2min crushes uniform；
(2) load weighted forming agent sodium carboxymethylcellulose is added；Stir 1min；
(3) load weighted surfactant fatty alcohol polyoxyethylene ether sulfate and α-sodium olefin sulfonate will be shifted to an earlier date, added
Agitated kettle stirring 1.5min is uniform；
(4) it is uniform to add the sodium stirring 1min of chelating agent hydroxy ethylene diphosphonic acid four.
(5) other auxiliary agents of formula ratio are eventually adding, brighten the factor and essence, stirring 2min makes mixture uniform, obtains
Homogeneous mixture；Homogeneous mixture is passed through into refiner, three-roll grinder successively, be molded through vacuum plodding, roll printing (or printing),
Stripping and slicing, it is packaged to be laundry soap.
Embodiment 2
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects complete vegetable oil neat soap, and so-called complete vegetable oil neat soap refers to that aliphatic acid used in the neat soap is by single plant
The hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art of oily (palm oil, palm-kernel oil or coconut oil) or different vegetable oil forms,
And the neutralized neat soap being dried to obtain.Surfactant selects AEO, forming agent selection PEG-4000, chelating
Hydroxy ethylene diphosphonic acid disodium is selected in agent, is brightened the factor and is selected Violet 452, and essence selects lavender perfume (or spice) flavor essence, its
Its selection of auxiliary enzyme preparation.
The preparation method of the submissive whitening laundry soap composition of this implementation is identical with embodiment 1.
Embodiment 3
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects miscella neat soap, and miscella neat soap refers to that aliphatic acid used in the neat soap is by animal oil and vegetable oil root
Hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art forms, and the neutralized neat soap being dried to obtain, and surfactant is from fat
The quality of alcohol APEO and MES collocation, A AEOs and MES
Than for 3：8.The non-selected addition forming agent of the embodiment, chelating agent select hydroxy ethylene diphosphonic acid disodium, brighten the factor
From Duasyn Red N6B, essence selects citrus flavor essence, other selection of auxiliary antioxidant dibutyl hydroxy toluenes
(BHT)。
The preparation method of the preparation method and embodiment 1 of the submissive whitening laundry soap composition of this implementation is essentially identical, different
Part is because the present embodiment is not added with forming agent, so relative embodiment 1 has lacked step (3) operation.
Embodiment 4
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects miscella neat soap, and miscella neat soap refers to that aliphatic acid used in the neat soap is by animal oil and vegetable oil root
Hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art forms, and the neutralized neat soap being dried to obtain.Surfactant from C12~
C14 APGs and fatty alcohol polyoxyethylene ether sulfate collocation, C12~C14 APGs and AEO sulphur
The mass ratio of hydrochlorate is 5：7.Forming agent selection cetearyl alcohol alcohol ether -50, chelating agent select tetrasodium ethylenediamine tetraacetate (EDTA-
4Na), brighten the factor and select alizarol saphirol, essence selects citrus flavor essence, other selection of auxiliary bacteria removers.
The preparation method of the submissive whitening laundry soap composition of this implementation is identical with embodiment 1.
Embodiment 5
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects complete vegetable oil neat soap, and so-called complete vegetable oil neat soap refers to that aliphatic acid used in the neat soap is by single plant
Thing oil (palm oil, palm-kernel oil or coconut oil) or different vegetable oil according to prior art according to a certain percentage arrange in pairs or groups hydrolysis and
Into, and the neutralized neat soap being dried to obtain.Surfactant selects fatty alcohol polyoxyethylene ether sulfate and fatty acid methyl ester sulphur
Hydrochlorate is arranged in pairs or groups, and the mass ratio of polyoxyethylene ether sulfate and MES is 5：8.Forming agent selects acrylic acid tree
Fat, chelating agent select tetrasodium ethylenediamine tetraacetate, brighten the factor and select Tinolux PSA15, and essence selects lemongrass flavor essence,
Other auxiliary agent selection bacteria removers and titanium dioxide.
The preparation method of the submissive whitening laundry soap composition of this implementation is identical with embodiment 1.
Embodiment 6
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects complete vegetable oil neat soap, and so-called complete vegetable oil neat soap refers to that aliphatic acid used in the neat soap is by single plant
The hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art of oily (palm oil, palm-kernel oil or coconut oil) or different vegetable oil forms,
And the neutralized neat soap being dried to obtain, surfactant select C12~C14 APGs, MES and α-alkene
Base sodium sulfonate is arranged in pairs or groups, and the mass ratio of C12~C14 APGs, MES and α-sodium olefin sulfonate is 5：10：7.
Forming agent selects acid-co-maleic acid, and chelating agent selects ethylenediamine tetra-acetic acid, brightens the factor and select alizarol saphirol, essence
From citrus flavor essence, other auxiliary agents select antioxidant BHT.
The preparation method of the preparation method of the submissive whitening laundry soap composition of this implementation is as follows：
(1) preparation of particle is brightened；
Using bentonite as inorganic additive, microcrystalline cellulose selects alizarol saphirol to be used as and brightens the factor as adhesive.Open
Mixer is opened, a certain amount of process water is added into ingredients pot, each raw material is separately added into proportion and is made into uniform slurry like material, is passed through
Fluidized bed molding or through extrusion under vacuum or other modes, is made the required particle that brightens, standby.Brighten the raw material of particle
Mass percent is as follows：Neat soap 21.5%, bentonite 50.5%, microcrystalline cellulose 18.0%, pigment blue 1 0%.
(2) load weighted neat soap is added into agitated kettle, stirring 2min crushes uniform；
(3) load weighted forming agent acid-co-maleic acid is added；Stir 1min；
(4) surfactant C12~C14 APGs, MES and α-the alkenyl sulphur that will be weighed in advance
Sour sodium, it is uniform to add agitated kettle stirring 2.5min；
(5) it is uniform to add chelating agent ethylenediamine tetra-acetic acid stirring 1min.
(6) be eventually adding formula ratio brightens particle (being fed intake using soap with the continuous adding device of solid particulate matter), perfume
Essence and BHT stirrings 2min are uniform, by homogeneous material successively by refiner, three-roll grinder, (or are beaten through vacuum plodding, roll printing
Print) shaping, stripping and slicing, it is packaged to be laundry soap.
Embodiment 7
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects complete vegetable oil neat soap, and so-called complete vegetable oil neat soap refers to that aliphatic acid used in the neat soap is by single plant
The hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art of oily (palm oil, palm-kernel oil or coconut oil) or different vegetable oil forms,
And the neutralized neat soap being dried to obtain.Surfactant selects AEO and cocamidopropyl propyl amide hydroxyl sulfobetaines
Alkali is arranged in pairs or groups, and the mass ratio of AEO and cocamidopropyl propyl amide hydroxy sulfo lycine is 4：5.Forming agent selects poly- second
Alkene adjoins pyrrolidone, and chelating agent selects hydroxy ethylene diphosphonic acid disodium, and the embodiment is not added with brightening the factor, and essence selects jasmine
Flavor essence, other auxiliary agents select enzyme preparation.
The preparation method of the preparation method and embodiment 1 of the submissive whitening laundry soap composition of this implementation is essentially identical, different
Part is, because the present embodiment is not added with brightening the factor, correspondingly adds and brightens not into agitated kettle in step (5)
The operation of the factor.
Embodiment 8
The specifically used material of each component is as follows in the submissive whitening laundry soap composition of the present embodiment：
Neat soap selects miscella neat soap, and miscella neat soap refers to that aliphatic acid used in the neat soap is by animal oil and vegetable oil root
Hydrolysis of being arranged in pairs or groups according to a certain percentage according to prior art forms, and the neutralized neat soap being dried to obtain.Surfactant selects cocounut oil
Amido propyl hydroxy sulfo lycine and MES collocation, cocamidopropyl propyl amide hydroxy sulfo lycine and fatty acid methyl
The mass ratio of sulfonated ester is 1：4.Forming agent selects microcrystalline cellulose, and chelating agent selects tetrasodium ethylenediamine tetraacetate (EDTA-
4Na), brighten the factor and select Violet 452, essence selects lavender flavor type essence, other selection of auxiliary bacteria removers.
The preparation method of the submissive whitening laundry soap composition of this implementation is identical with embodiment 1.
Above-described embodiment 1~8 (removing embodiment 3) when preparing submissive whitening laundry soap composition can smoothly shaping, have
Effect shaping, shaping situation is very good, and by simulation Actual laundering three times, does not occur that soap body tissue is loose, problems of crack.
Simulate washing test method：Directly rinse under a tap, take towel on the other hand by soap on the other hand, with soap surface smear towel, often
After two minutes, soap box is dried secondary smearing in soap holding chamber, towel rinsing is dried, and circulates washing three times with this within second day, observation
Whether soap body loosely ftractures.Test result is as shown in table 2 below.
The laundry soap composition molding effect of the embodiment 1~8 of table 2
The clean result evaluation method of the submissive whitening laundry soap composition of above-described embodiment 1~8 is as follows：
1st, submissive measure of merit is washed：
Method of testing：The square cotton towels of 30cm × 30cm are chosen, respectively with the submissive whitening laundry soap of embodiment 1~7
Composition is bought common laundry soap with market and washed, and above-mentioned each laundry soap is uniformly applied on towel respectively and simulates reality
Border washing carries out washing 5min by rubbing with the hands, and rinses 2 times, dries.Operation repeated washing 5 times more than.It is soft for consumer
Performance selects professional group member (10 people) to carry out subjective touching test mainly by sensory judgments such as tactiles, to general
Towel after logical laundry soap and the submissive whitening laundry soap cleaning compositions of embodiment 1~8 carries out sense organ evaluation and test, and best result 5 divides
It is best to represent the submissive effect of washing, minimum point of 1 point of submissive effect of washing is worst, and finally 10 people's marking values are averaged.As a result
It is as shown in table 2 below.
The laundry soap composition of the embodiment 1~8 of table 3 and the submissive measure of merit result of washing of common laundry soap
2nd, whitening effect is tested：
Method of testing：Soiled cotton is cut into the square pieces of cloth of 6cm × 6cm respectively, is uniformly applied to laundry soap after pieces of cloth moistening
On pieces of cloth, washing test is carried out using Terg-O-Tometer.Wash conditions：Wash solution 250ppm hard water, 30 DEG C ± 1 DEG C, press
GB/T13174《Dress material detergent detergency and the measure of circulation scourability》Method carries out simulation washing, and by after washing
Pieces of cloth be placed under sunlight or fluorescent lamp and dry, comparing embodiment 1~8 do washing soap composition with before and after the washing of common laundry soap
Soiled cotton whiteness difference before and after sample washing, it is as a result as shown in table 3 below.Use the dirt of the laundry soap cleaning compositions of embodiment 1~8
Cloth is substantially than the soiled cotton brilliant white of common laundry soap washing.
The pieces of cloth of table 4 use the front and rear whiteness difference of different laundry soap washings
The technology contents described above that the present invention is only further illustrated with embodiment, in order to which reader is easier to understand,
But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this
Bright protection.
Claims (10)
1. a kind of submissive whitening laundry soap composition, it is characterised in that include each component of following parts by weight：
60~96 parts of neat soap；
2~25 parts of surfactant；
0.1~10 part of forming agent；
0.01~5 part of chelating agent；
Other 0~5 part of auxiliary agents；
And the weight of surfactant and neat soap ratio is 1:48~1:2.5.
A kind of 2. submissive whitening laundry soap composition according to claim 1, it is characterised in that also including parts by weight be 0.01
~2 parts brighten the factor or brighten particle.
3. a kind of submissive whitening laundry soap composition according to claim 1, it is characterised in that including each of following parts by weight
Component：
65~90 parts of neat soap；
5~22 parts of surfactant；
1.5~10 parts of forming agent；
0.01~5 part of chelating agent；
Other 0~5 part of auxiliary agents.
4. a kind of submissive whitening laundry soap composition according to claim 1, it is characterised in that the forming agent is fatty alcohol
Polyethers nonionic, microcrystalline cellulose, sodium carboxymethylcellulose, palm wax, sodium carboxymethyl starch, polyethylene adjoin pyrrolidone, gathered
Ethylene glycol, dextrin, guar gum, acrylic resin, polycarboxylic acids sodium, acrylic acid and maleic acid homopolymer and copolymer at least
It is a kind of.
5. a kind of submissive whitening laundry soap composition according to claim 1, it is characterised in that described to brighten the factor or brighten
Particle is to contain Tinolux PSA15, Violet 452, Blue FBL, Duasyn Violet 4BN, Duasyn Red N6B
With the material of at least one of alizarol saphirol.
6. a kind of submissive whitening laundry soap composition according to claim 1, it is characterised in that the surfactant is fat
Fat alcohol polyoxyethylene ether sulfate, linear alkylbenzene sulfonate (LAS), Fatty Alcohol Ether Carboxylate, α-sodium olefin sulfonate, dodecyl sulphur
Sour sodium, SAS, MES, C12~C18 AEO, C12~C14 alkyl sugar
Glycosides, the condensation product of C12~C18 alcohol and ethylene oxide/propylene oxide block copolymer, C8~C20 branched-chain alcohos APEO, ten
Dialkyl amido propionate, dodecyl ethyoxyl sulfobetaines, dodecyl hydroxypropyl sulfobetaines, dodecyl sulphur
CAB, octadecyl dihydroxy ethyl amine oxide, cocamidopropyl propyl amide hydroxy sulfo lycine, cocamidopropyl propyl amide oxidation
At least one of amine, dodecanamide propyl amine oxide.
7. a kind of submissive whitening laundry soap composition according to claim 1, it is characterised in that the chelating agent is citric acid
And its salt, hydroxy ethylene diphosphonic acid and its salt, ethylenediamine tetra-acetic acid and its salt, the sodium of glutamic acid diacetic acid four, diethylidene three
Amine five (methylene phosphonic acid), EDTMP, hexamethylene diamine four (methylene phosphonic acid), the second of diethylenetriamines five
Acid, ethylenediamine disuccinic acid and its salt, the sodium of iminodisuccinic acid four, the diacid of ethylenediamine two, 2- hydroxyl propane diamine disuccinic acids
And its at least one of salt.
8. a kind of submissive whitening laundry soap composition according to claim 1, it is characterised in that the neat soap is sodium soap
Salt, the fatty acid sodium salt are made by natural oil through hydrolysis and saponification.
9. a kind of preparation method of submissive whitening laundry soap composition as claimed in claim 1, it is characterised in that including following step
Suddenly：
S1, by weight ratio weigh each component respectively, standby；
S2, neat soap is added into agitated kettle and stirs crushing uniformly；
S3, continuously add forming agent into agitated kettle and stir；
S4, continuously add surfactant into agitated kettle and stir；
S5, chelating agent and other auxiliary agents are continuously added into agitated kettle, and stirred；
By refiner, three-roll grinder, vacuum plodding machine, stripping and slicing processing, laundry soap is made successively in S6, mixture.
10. a kind of preparation method of submissive whitening laundry soap composition according to claim 9, it is characterised in that in step
Before S6, continuously added into agitated kettle and brighten the factor or brighten particle and stir.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109439474A (en) * | 2018-12-28 | 2019-03-08 | 广州立白企业集团有限公司 | A kind of cleansing soap of cation-containing copolymer and preparation method thereof |
| CN112900091A (en) * | 2021-01-26 | 2021-06-04 | 纳爱斯浙江科技有限公司 | Softener composition with quick-drying function for fabric and preparation method thereof |
| CN113604294A (en) * | 2021-09-16 | 2021-11-05 | 廊坊佰美生物科技有限公司 | Commercial laundry detergent and preparation method thereof |
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| CN1240227A (en) * | 1999-07-23 | 2000-01-05 | 李志军 | Multi-function washing powder and productive process |
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| CN1131185A (en) * | 1995-12-20 | 1996-09-18 | 北京洛娃新型化工材料技术开发有限公司 | Making bleaching compound soap power containing oxygen |
| CN1240227A (en) * | 1999-07-23 | 2000-01-05 | 李志军 | Multi-function washing powder and productive process |
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| CN109439474A (en) * | 2018-12-28 | 2019-03-08 | 广州立白企业集团有限公司 | A kind of cleansing soap of cation-containing copolymer and preparation method thereof |
| CN112900091A (en) * | 2021-01-26 | 2021-06-04 | 纳爱斯浙江科技有限公司 | Softener composition with quick-drying function for fabric and preparation method thereof |
| CN113604294A (en) * | 2021-09-16 | 2021-11-05 | 廊坊佰美生物科技有限公司 | Commercial laundry detergent and preparation method thereof |
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| CN107446732B (en) | 2020-08-04 |
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