CN100395323C - Fast effect detergent and its preparation method - Google Patents

Abstract

The invention relates to an ultra-concentrated, high-density, solid synthetic detergent, suitable for trace washing and able to release its components in normal or low temperature water in the preset mode, not only applied to washing fabrics, manually and by traditional washers but also washing of environmental protection washers without using washing powder.

Description

A kind of fast effect detergent and preparation method thereof

Technical field

The present invention relates to a kind of hyperconcentration, high-density solid synthesis of detergent thing, refer more particularly to a kind of in normal temperature or water at low temperature quickly disintegrated clothes washing thing, not only be applicable to hand washing, conventional washer laundering of textile fabrics, and be applicable to the washing of what is called without the environment protection washing machine of washing powder.

Background of the present invention

Articles for washing field, the whole world mainly contains two series products: the first, and fertile (perfume (or spice)) soap.It accounts for the global articles for washing market share about 14%.The second, synthetic detergent.It accounts for the global articles for washing market share about 86%.In the synthetic detergent, washing powder accounts for 2/3, and liquid washing agent accounts for 1/3, and solid synthesis of detergent thing is very rare.

In the textile washing field, soap, particle or powdery washing powder, clear liquid or paste liquid washing composition are the most general.Wherein, soap is the sodium salt or the sylvite of various lipid acid, generally by grease and alkali generation saponification, by the method for boiling entirely, partly boil method, method of cooling, carbonation etc. are made.As, according to the method for boiling entirely, grease and alkali lye are put into the saponification still, and heated and boiled is treated to change the pond of saltouing over to after the saponification, and the enriching salt solution is saltoutd, and upper strata soap precision work forms the bar soap product; Lower floor's glycerine reclaims processing as byproduct.The raw material aspect, soap can be selected tallow, suet, bone fat, Oleum Cocois, skin oil, Semen Lini oil, cotton oil, peanut oil, wild plant wet goods for use, in the practice, soapmaking need consume a large amount of caustic soda (caustic soda), salt, soda ash, Ke Xingjia, SODIUM SILICATE, sodium bicarbonate, Di-Sodium Phosphate etc.As, in the legal system soap process of boiling entirely, per hundred jin of absolute oil often need add 30-40 jin caustic soda.

Soap has a lot of shortcomings.The first, consume a large amount of greases.Every production a cake of soap approximately consumes three liang natural fats and oils.Can replace animal-plant oil with the petroleum products synthetic fatty acid, but this soap soil removability is poor, washes the back textiles and be clamminess easily.The second, washing effect is poor, may residual obvious dirt.Soap runs into and chemical reaction can take place behind the mineral substance in the hard water and produce the powdery soap scum, and this dirt is easy to influence cleaning effect attached on the clothing, especially during the light or monochromatic clothing of washing, may make residual soil more obvious.For example, during with hard water washing textiles, calcium ion, magnesium ion in soap meeting and the water generate calcium soap, magnesium soap, not only waste soap, and the jaundice of textiles color, lining are hardened.The 3rd, versatility is poor.Soapmaking need be used a large amount of caustic soda, and this makes soap alkalescence, corrodibility too strong, is not suitable for washing silk, wool fabric, and some man-made fiber fabric.The 4th, quality be cannot say for sure to demonstrate,prove.For example, rigid oil is too much in the soap, and zero pour is higher, and then product ftractures easily, hardens, and washing usefulness seriously reduces.The 5th, pungent unpleasant peculiar smell is arranged.Soap itself often has pungent unpleasant peculiar smell.If not rinsing repeatedly, long-term exposure, this smell can remain on the textiles.The 6th, skin irritation.The sodium hydrate content of soap is higher usually, and soap body alkalescence, corrodibility are strengthened greatly.On the contrary, people's skin is generally weakly acidic condition, and during hand washing, soap is bigger to the stimulation of skin, damage, and the underclothes of soap washing is skin irritation also, the sense of discomfort that the people is produced be clamminess, have a fever.The 7th, be not easy metering and use.Soap does not generally use by automatic disintegration, dissolution mechanism, and often is coated to textile surface by mechanical friction.How much soap the single-piece textiles uses, and this does not have the measurement standard that can control fully.Use too much soap, then textile fiber sustains damage easily, and peculiar smell is residual more.Use very few soap, then textiles is not easy washes clean.Because soap has above shortcoming, in the last few years, synthetic detergent had become the main products in textile washing field gradually.

The soil removability of synthetic detergent is relevant with the molecular structure of the actives that it comprises.This actives is from various tensio-active agents, and its basic molecular structure is that an end is formed hydrophobic group or oleophilic group by long hydrocarbon chain, and is water insoluble, and is dissolved in oil; The other end is by short polar group, as carboxylic acid group-COOH, sulfonic group-SO ₃H forms hydrophilic group or lipophobic group, is dissolved in oil, and water insoluble.After tensio-active agent added in the entry, oleophilic moiety and water were scolded in the molecule, stretch to air, and hydrophilic segment is attracted by water molecules, and adsorption phenomena takes place, and formed the densely covered thin layer of lipophilicity group in solution surface.Like this, aqueous solution surface forms the hydrocarbon chain interface, greatly reduces the surface tension of solution, and wetting, infiltration, emulsification, the soil removability of solution are strengthened.Synthetic detergent mainly comprises washing powder and liquid lotion.

Washing powder mainly is to add a large amount of inorganic assistant agents with linear alkylbenzene sulphonic acid, sodium alkyl benzene sulfonate, as five sodium, water glass, yellow soda ash, sodium sulfate etc., makes fluffy exsiccant powder by spraying, mixes packs such as adding washing auxiliary detergent then and uses.At present, occurred some washing powder product innovations on the market,, improved washing effect as in washing powder, adding a small amount of nonionogenic tenside, enzyme etc.But, generally contain a large amount of tripoly phosphate sodium STPPs in the washing powder.Tripoly phosphate sodium STPP is a kind of important scrubbed component, and its effect mainly contains: softening water prevents metal ion failure surface promoting agent; Dispersion, emulsification, peptization spot; Avoid the spot redeposition, keep the bright-coloured color of substrate; Certain alkalescence is provided, keeps washings, reduce stimulation skin in suitable pH value; Absorb moisture and prevent the washing powder caking, keep dry and comfortable granular.But, phosphorated washing powder discharging of waste liquid causes serious eutrophication easily in environment, and water ecosystem is broken, and causes water quality deterioration.For example, the annual 4000000 tons of washing composition producing of China 600,000-700,000 tons of tripoly phosphate sodium STPPs of using up approximately.These phosphoric acid salt finally enter rivers,lakes and seas with waste water, make the water quality eutrophication, cause rapid, a large amount of breeding of phycophyta in the water, finally produce red tide in the coastal waters, annual about 10,000,000,000 Renminbi of financial loss that cause to China.

At present, on the domestic and international market non-phosphide detergent has appearred.It mainly is to substitute tripoly phosphate sodium STPP with the 4A zeolite to do washing assistant.The 4A zeolite is the calcium ion in the planar water well, but relatively poor to the adsorptivity of magnesium ion, so its washing aid performance has been subjected to certain limitation.In addition, the 4A zeolite is water insoluble, is unfavorable for rinsing on easily attached to clothing with the washing composition of 4A zeolite synthesis when the washing clothes.Developed countries such as America and Europe generally adopt a layer water glass to make the washing assistant synthetic detergent powder.Layer water glass has good water softening performance, ability of cleaning greasy dirt is strong, strong with the tensio-active agent cooperative ability, to perviousness, dispersiveness, emulsifying property and the sterilization of dirt, antirust, non-corrosibility is better, environmental pollution is minimum in existing industrialization washing assistant, is the only detergent builders that substitutes phosphorous washing assistant at present.Layer water glass all has good adsorption property to the Ca in the water, Mg ion, especially to Mg ionic adsorptivity considerably beyond the 4A zeolite, therefore its wash-aid effect is significantly better than the 4A zeolite, and it is better than 4A zeolite to do washing assistant synthetic detergent dissolving performance with layer water glass, be beneficial to rinsing, reduced secondary pollution clothing.But, under weak acid, weakly alkaline gentle wash environment, especially under the gentle wash environment of normal temperature, water at low temperature, the washing aid performance of layer water glass a little less than.

Along with senior lining, especially hair, suede, silk, fiber crops, blending, and senior chemical fiber plus material is universal day by day, and washing under weak acid, weak base, the gentle wash environment of neutral, nursing textiles, this has become new technical need.Of particular concern is that Chinese washing habits is different with the west.Chinese like washing textiles in normal temperature, water at low temperature.Generally speaking, water temperature raises, and then the surface tension of washing water reduces, and the washing composition that needs reduces.Water temperature reduces, and then the surface tension of washing water raises, and the washing composition that needs increases.Seek synthetic detergent component and medicine compatibility method efficiently for the gentle wash environment of normal temperature, water at low temperature, this is one of important research direction of Chinese technician always.

Except above-mentioned technical development demand, washing powder also has other weak points:

The first, degreasing is strong, damages clothes fiber and skin easily.For example, staff touches washing powder burning sensation, and life-time service can cause pachylosis, dry and cracked.

The second, the waste water power.The kind of the tensio-active agent that different washing powder is used is different, and the tensio-active agent that has still has good foaming power under the situation of minute quantity, be difficult for washing down.Washing powder can produce a large amount of foams, needs to use a large amount of water to come rinsing clothes, more wastes water power more than soap.

The 3rd, have residually easily, and damage clothing easily.The washing powder consumption is on the high side, and then unnecessary washing powder not only can not increase detersive power, remains in easily on the contrary on the clothing, and easy cleaning is not gone back Diazolidinyl Urea, contains bleaching action as washing powder, and excessive use can make clothing fade, damage.

The 4th, wash concentration is wayward, and washing effect is poor.Wash concentration depends on indexs such as washing powder consumption, washing water volume, is not easy very much to control.Generally speaking, the washing powder consumption all can be bigger than normal, causes waste easily, and increase the washing powder consumption inadequately, and this can reduce detersive power on the contrary.For example, when washing powder reaches finite concentration, the surfactivity of the aqueous solution reaches after the maximum value, and detersive power increases and increased with regard to the add-on along with washing powder no longer, on the contrary the trend that can occur reducing.Scientific experimentation shows that the best wash concentration of washing powder is generally 0.1%-0.3%, and the solution surface of this concentration is active maximum, and clean effect is preferable.Concentration surpasses 0.3%, and the washing soil removability descends on the contrary.Excess washing powder can not increase clean effect again, and can garment fabric be damaged to some extent because of the increase of solution neutral and alkali.

The 5th, density is little, and it is very huge that plastics load the volume of apparatus, and after making moist or being extruded, washing powder lumps easily influences washing effect.Washing powder is general more fluffy, the only about 0.28-0.45g/ml of density, so plastics loading apparatus volume ratio is huger, is generally soft plastics bag.Generally no longer sealing makes the washing powder caking that makes moist easily behind the plastics bag opening.In addition, washing powder is a kind of hollow bead, in soft plastics bag, be easy to be squeezed, and then broken, caking.The washing powder of caking is not easy to dissolve, thereby destroys washing effect.

The 6th, washing powder is not easy metering and uses.The volume of washing powder and density are not easy control, and this mainly is that preparation technology causes.Washing powder pulp density, slip pressure, spray gun diameter, advance tower air quantity, gas and carry air quantity, back compounding and close volume and the density that factor such as situation may influence washing powder, the washing powder quantity that the single-piece clothing is needed is difficult for measuring and calculating.And because particle proportion difference, the distributions in soft washing powder particle such as enzyme, SYNTHETIC OPTICAL WHITNER, zeolite are also inhomogeneous.Even the user accurately calculates the washing powder quantity that the single wash task need be thrown in by auxiliary means, each component wherein also departs from the numerical value of actual needs easily as the content of washing composition, washing auxiliary detergent etc.Therefore, how each scrubbed component fixed sealing of the specific washing task of correspondence is contained in the washing composition monomer, this is a very urgent demand of user.

The 7th, behind the Kaifeng, washing powder is apt to deteriorate.Under shady and cool, exsiccant environment, the washing powder of sealing can be deposited half a year to nine month.Behind the Kaifeng, airborne moisture content can make the washing powder caking, and make some components, as deterioration, the especially enzyme of enzyme, SYNTHETIC OPTICAL WHITNER etc., the protein structure of the free acid meeting destructive enzyme in the washing powder, its function is lowered greatly, usually, enzyme after depositing half a year, its washing function 15%-60% that can fail.Under some situation, as the washing powder of high-temperature storage, its enzyme can completely lose activity.In addition, essence is volatilization fast behind washing powder Kaifeng, and in time, the variation of condition such as temperature may all volatilize totally.

The 8th, the versatility of washing powder is poor.Washing powder is suitable for washing cotton, fiber crops, chemical fibre and BLENDED FABRIC thereof.But the general meta-alkalescence of washing powder can make protein denaturation, and hair, silk etc. is had certain damage.Therefore, most of washing powder are not suitable for washing hair, silk fabric or its BLENDED FABRIC.Its versatility is relatively poor.

The 9th, the time that each component of washing powder plays a role is easy-regulating not.Dirt on the clothing mainly comprises solid dirt, oily soil, liquid dirt etc., and mode that various dirts are eliminated in washing process and order are variant.For example, solid solubility dirt most of soluble can be removed through immersion and mechanical friction fast in water.Insoluble dirt generally needs to remove by washing composition, and some also needs to use solvent, oxidative bleaching agent, reducing bleach etc.The mode and the order of effects such as in the washing process, the tensio-active agent performance is wetting, emulsification, dispersion, solubilising, foaming, froth breaking, sterilization are not identical yet.The granulation of suitably setting between each component according to fiber properties and decontamination principle mixes, applies relation, thereby sets scrubbed component dissolving, the mode that discharges and order, and this is highly beneficial to improving washing effect.But, dissolve in washing water after, each component of washing powder offer an opportunity for above-mentioned setting almost simultaneously and washing water or contact with clothing.In a word, the physical structure of washing powder and preparation technology do not allow people to carry out above-mentioned setting.

Except washing powder, another kind of important synthetic detergent is a liquid lotion.To be that the water of kinds of surface promoting agent and 40-80% is composite form liquid lotion.Because it is well water-soluble that tensio-active agent all has,, more excellent wash characteristics is arranged at low temperatures so the feature of liquid lotion maximum is exactly fabulous water-soluble.In addition, liquid lotion is less to the stimulation of human skin, does not have the burning sensation of alkalescence.But, liquid lotion also has some shortcomings.

The first, liquid lotion is owing to the compatibility problems of solubility limit and tensio-active agent, and inorganic assistant agent adds kind and quantity all is subjected to very big the influence.So in liquid lotion, some good auxiliary agents can't add or can only add by trace, this has weakened the washing effect of liquid lotion greatly.For example, can add inorganic assistant agent in the washing powder prescription, and the inorganic assistant agent add-on of liquid lotion is generally 3-10% up to 40-60%.

The second, the liquid lotion latherability is strong, causes foam abundant, makes clothing be difficult for rinsing, wastes water source and electric energy in a large number.

The 3rd, the general moisture content that adds 40-80% in the liquid lotion, opposite scrubbed component content is little, and this makes the liquid lotion product consume a large amount of water sources and trucking costs.In addition, liquid lotion is generally with Plastic Bottle, bucket dispensing, equally with washing powder also can produce a large amount of plastic garbages.

Except clothes washing products such as common above-mentioned soap, washing powder, liquid lotion, patent documentations such as GB911204, US3953350, JP60-015500A, EP711827A have been put down in writing a kind of small-sized solids wash thing.But, these washes belong to small-sized soap, small-sized compacting laundry powder agglomates etc. basically.Compare with the present invention, its volume is very huge, and monomer weight generally surpasses 100 grams, and density is a little more than washing powder, and minimum is not less than 50 grams, and its working substance content is low, and washing effect is poor, lacks the marketing prospect.Other documents also disclosed similar small-sized solids wash thing.For example, " the detergent formulation workshop manual " that Xu Baocai, Zhou Yawen, Wang Hongzhong write, Chemical Industry Press's in January, 2006 first version, the 239th page discloses a kind of heavy about 30 grams, the small-sized solids wash thing of the about 2mm of diameter." detergent raw material and fill a prescription selected " that Liao Wensheng writes, Chemical Industry Press's in March, 2006 first version, the 102-103 page or leaf also discloses the solids wash thing of some monomer weights up to tens of grams, but it belongs to the laundry powder agglomates or the soap blank of compacting basically, and bulky, also lack market application foreground.Because scientific research and business circles lack technology and market development expection to small-sized solids wash thing, other scientific and technical literatures are not paid close attention to it yet.For example, all not mentioned such washes of following document.Tang Yu democracy is compiled, " synthetic detergent and application thereof ", China Textiles Press's in May, 2006 first version.Ma Zhengsheng writes, " non-phosphorus washing assistant ", Chemical Industry Press's in March, 2005 first version.The Li Dongguang chief editor, " detergent raw material handbook, Chemical Industry Press's in January, 2006 second edition.Brilliant work is prosperous, Xu Qing writes, " detergent enzyme application manual ", China Light Industry Press's in July, 1999 first version.Platinum spring, Bao Yuquan compile, " application of tensio-active agent in washing industry ", chemistry and applied chemistry publishing centre in July, 2003 first version.

But, inner feelings Ping Hai chief editor's " tensio-active agent principle and application prescription ", Jiangxi science tech publishing house in May, 2005 first version points out for 33 pages, and the main development trend of washing composition is hyperconcentration, high-density, the low bubble of low temperature, to environment and human body safety and have various functions.However, this book does not openly meet the solids wash thing of this trend.The present invention can overcome deficiency and the defective that main flow cleaning products such as soap, washing powder, liquid lotion exist, utilize unique prescription and technology make hyperconcentration, high-density, the low bubble of low temperature, to environment and human body safety and gentle cleaning product with various functions.

In addition, the electrolysis, electromagnetism washing machine technology that need not drop into soapless soap emerge in multitude.For example, the CN03143941.1 document relates to a kind of washing machine washing method without washing composition.It can carry out modified or activation to bath water, carries out electrolysis then, and the pH value of the physical strength of control washing or time, brine electrolysis realizes the washing that need not to throw in soapless soap.The CN03143942.X document relates to a kind of washing machine.It has used the washing methods without washing composition.The washing methods of claim one protection of this patent is washing water to be carried out electrolysis its pH value is reached between the 9.5-10.6.The alkaline water that utilizes electrolysis to produce, washing machine can carry out high-efficient washing, and has exempted rinsing.The sour water that utilizes electrolysis to produce, washing machine can be to fabric sterilization, sterilization, nursing etc.A kind of so-called tap water modification agent can strengthen washing effect in without the environment protection washing machine of washing composition.For example, CN200310113629.9 patent application, ZL03143941.1 patent, and some other non-patent literature all discloses component of tap water modification agent and uses thereof.

Without the washing machine of the washing composition patent direction of disposing still not, wash a business development direction of industry especially.In business circles, SANYO GS company releases a kind of brine electrolysis washing machine without washing powder the earliest.2004, company of Haier also released a kind of brine electrolysis washing machine without washing powder.At present, the turbine of company of Haier, roller washing machine have all had the new architecture without washing powder.Present what is called mainly can realize decontamination, sterilizing function without the washing machine of washing powder.But, washing process is not only decontamination, sterilization.The effect of washing auxiliary detergents such as the proteolytic enzyme in the synthetic detergent, essence, SYNTHETIC OPTICAL WHITNER is irreplaceable.Add specific washing composition or washing assistant in this washing machine, this can allow people obtain better washing effect.The present invention not only relates to hand washing, used solids wash thing and the preparation technology thereof of conventional washer washing clothes, and relates to the correlation technique invention of what is called without the environment protection washing machine of washing powder.

The present invention's general introduction

Among the present invention, logical fingers such as " clothing ", " fabric ", " textiles " are various can be by the goods of hand washing, washing machine washing, " solids wash thing " logical independent solid monomer that refers to self can keep its physical form and structure can be homogeneous phase or heterogeneous monomer.Technical scheme of the present invention is by selecting the component of specified property, the multi-functional component of preferred high actives content, according to predefined actives delivery mode and time, component is carried out composite targetedly, and mixing by creating, granulation, preparation technologies such as compressing tablet make hyperconcentration, highdensity subminiature solid trace washing composition, allow in cold washing water, single-piece washing object be carried out gentleness, whole scrubbed component of complete biodegradable washing are as the high-efficient washing component, gentle washing component, the main no machine aided that disintegrates of washing is washed, help the washing component, function washing component, the disintegration hydrotropy helps quilts such as washing the sterilization component accurately, stable, efficiently, safety, careful, intelligently seal up for safekeeping in a solids wash thing monomer.And, components selection, compatibility, mixing, granulation, compressing tablet process in fact " memory " disintegration, the chemical combination between the scrubbed component, help functional relationship information such as wash, and the usefulness of each scrubbed component performance mode and temporal information.These are actually " instruction " that people set for the solids wash thing by physics and chemical process by the predefined information of people, and it also is stored, is encapsulated in the solids wash thing monomer.From throw in this monomer to washing water, the above-mentioned material of being sealed up for safekeeping obtains discharging successively, above-mentionedly is stored, encapsulated information or instruction be released and carry out by washing process such as dissolving, disintegration, wetting, solubilising, foaming, froth breaking, emulsification, breakdown of emulsion, dispersion, gathering, flocculation, separation, sterilization, sterilization, nursing, conditioning, bleachings.Like this, washing process has become the information-based execution process instruction that artificial intelligence is controlled in advance.Wherein, artificial intelligence has been set almost all physics and chemical process, and the user only needs a simple input action and an instruction that starts washing, just can make this process obtain actual reproduction.Therefore, in fact the present invention relates to a kind of solid synthesis of detergent thing that becomes more meticulous of presetting and storing washing manual command infosystem, and is used to store, encapsulate the working method that becomes more meticulous of this infosystem.The present invention makes the disposable accurate input of washing composition can break away from any auxiliary measuring instrument or measurer.

In the washes of the present invention, each component " by accurate, stable, efficient, safe, careful, intelligently seal up for safekeeping in a solids wash thing monomer ".Wherein, " accurately " be meant that each required component of one of washing or many clothings is by dosage comparatively suitably; " stablize " and be meant that washing one or many each required component of clothing are sealed up for safekeeping in the solid monomer at physics and chemical aspect, can volatilization, inactivation, chemical combination, hydration, escape, deposition, move etc., its physics and chemical state remain unchanged substantially; " efficiently " is meant that the efficient and the effect of sealing up for safekeeping are fine, and in the lotion of other types such as soap, washing powder, liquid lotion, this sealing up for safekeeping can not be taken place, also can not be effectively; " safely " be meant conventional compression shock, concussion, upset, push, tan by the sun, make moist, break a seal, beat etc. and can not change or destroy the above-mentioned state of sealing up for safekeeping; " careful " is meant the clothing at special fiber, weight, volume, and each component is all by compatibility subtly with seal up for safekeeping, compatibility and seal technology up for safekeeping and preestablished following washing required almost all physics and chemical process, and this can not realize in other lotions; " intellectuality " is meant that components selection, compatibility, mixing, granulation, compressing tablet process remembered disintegration, chemical combination between the scrubbed component, helped functional relationship information such as wash, and the usefulness of each scrubbed component performance mode and temporal information, so " sealing up for safekeeping " is to be used to set and the intellectuality of reproducing physics, chemical process is sealed up for safekeeping.We can say that washes of the present invention is actually a kind of intelligent lotion.

The innovative point of its technology and the technology prejudice that overcomes thereof are:

The first, according to conventional art prejudice, the monomer washes of compacting is exactly that conventional washing things such as washing powder, soap class are pressed into more closely knit detergent block.Solids wash thing of the present invention is not selected washing powder or soap class for use, but independent washing composition, the washing auxiliary detergent etc. selected, the unique particle of granulation process preparation by uniqueness, final one or more particles of compacting, perhaps the mixture of compressed granulate and powder produces unique solids wash thing.

The second, according to conventional art prejudice, the dissolving of solids wash thing and disintegration are equal to simple acid-base neutralisation reaction, and the soda acid proportioning should realize that chemistry is balanced.Dissolving of the present invention and disintegrating procedue be suitable for to increase kapillary content, and adopt modes such as swelling type, effervescence type, high-dissolvability material, with and hybrid mode realize the dissolving and the disintegration of washes.And in the effervescence type disintegration, the stoicheiometry of acid-base material is preferably unbalanced, should need more than a times of acid amount as surpassing acid-base reaction with the acid amount.Because this unbalanced, the soda acid component contact velocity between variable grain, probability promote greatly, thereby have greatly improved disintegration rate.Wherein, excessive acid or alkali preferably has washing, helps the component of washing function.

The 3rd, according to conventional art prejudice, the low foam detergent detersive power is poor.By preferred the foaming power low still new component and the medicine compatibility method of strong detergency, washes of the present invention can be accomplished to bubble to lack and strengthen detersive power on the contrary.Foaming power is poor, and this can reduce rinsing number of times and water consumption greatly.For silk, cashmere fabric etc., the user can not need rinsing just can finish washing process, and water-saving result is better.

The 4th, according to conventional art prejudice, cationic and anionic surfactant can not compatibility.For example, inner feelings Ping Hai chief editor's " tensio-active agent principle with use prescription ", Jiangxi science tech publishing house in May, 2005 first version points out for 3 pages, cats product can not be directly and the use of anion surfactant compatibility.At traditional lotion, especially in the liquid lotion, the generally unsuitable directly compatibility of cationic and anionic surfactant uses.But, in the present invention, cationic and anionic surfactant directly compatibility uses, after the washes disintegration, anion surfactant immerses fiber rapidly brings into play due usefulness, but the cats product controlled delayed release be not subjected under the anion surfactant interferential situation independent performance desinsection, function such as antistatic substantially.

The 5th, according to conventional art prejudice, behind the disposable input washing composition, the delivery mode of scrubbed component and time can't preestablish.The present invention sets different component collocation in links such as mixing, spraying, granulations, can control the delivery mode and the time of scrubbed component effectively.For example, behind the mixture pelleting of anion surfactant, washing auxiliary detergent, spray again and collapse the component secondary granulation soon, this can make above-mentioned scrubbed component snap-out release, on the contrary, cats product can be collapsed component slowly and be sprayed, thereby makes relevant component realize slowly-releasing.

The 6th, according to conventional art prejudice, be lower than 5 the gram, especially be lower than 3 the gram, even be lower than 1.5 the gram washes can not wash one adult formal dress.Existing patent, non-patent literature openly do not wash 5 grams of single-piece adult formal dress, the following single solids wash thing of especially 3 grams, even 1.5 grams.The component of the preferred high actives content of the present invention, and rational proportion have been designed this hyperconcentration, high-density solids wash thing.Through measuring and calculating repeatedly, in this washes, the working substance content of a kind of tensio-active agent of consumption maximum can not be lower than 50%.Take temperature from the use of solids wash thing, the present invention has realized micro-washing for the first time, promptly uses the washing of micro-synthetic detergent.

The 7th, according to conventional art prejudice, during disposable input solid detergent, the user can not realize controllability proportioning to each component in the washing composition.During solid detergents such as disposable input washing powder, owing to skewness between the washing powder hollow bead such as the different enzyme of proportion, SYNTHETIC OPTICAL WHITNER, zeolites, this causes each component in the washing composition can not realize the controllability proportioning.Along with appearance of the present invention, this situation is changed.Because the different component of proportion is sealed in monomeric particle of solid or monomer up for safekeeping complete controlledization of said ratio.

The 8th, according to conventional art prejudice, do not rely on any auxiliary measuring instrument or measurer, fibre content, volume or weight that the volume, weight that user's single is thrown in washes and density parameter can not corresponding single washing objects of while.In fields such as washing powder, liquid lotion, unless rely on auxiliary measuring instrument or measurer, fibre content, volume or weight that the volume, weight that user's single is thrown in washes and density parameter really can not corresponding single washing objects of while.The present invention can realize the input mode of the corresponding solids wash thing of dress.This makes people can break away from any auxiliary measuring instrument or measurer, realizes accurately throwing in targetedly.

The 9th, according to conventional art prejudice, itself can not seal up for safekeeping the solids wash thing components such as enzyme, essence, prevents the reduction of washes quality.After solids wash things such as washing powder were opened packing, enzymic activity generally can decay about 50% before washing powder is used up, and essence then can volatilize totally basically.The present invention in granulation, make in the sheet process enzyme, essence etc. sealed up for safekeeping in particle or body, prevent its reaction of making moist, rotten, decay or escape.Especially in the solids wash thing of protective coating was arranged, relevant component was sealed up for safekeeping, is protected more intactly.

The tenth, according to conventional art prejudice, the solids wash thing should mix the minority tackiness agent, forms lotion compression moulding again, also has technology prejudice to think that the solids wash thing should adopt soap preparing process to prepare.The present invention adopts biological medicine technology in conjunction with the washing composition compounded technology, has opened up the novel process of production solids wash thing.The present invention need implement reprocessing to starting material, and has found out a spray, and four mix, the three optimum process technology routes of granulating.Particularly, the present invention is applied to liquid to the boiling spray method and becomes in the solid washing composition manufacturing technology, and the efficient liquid tensio-active agent can be applied in preparation solids wash thing.The present invention also carries out four times to mix to component, granulates for three times according to disintegration mode and time design, effective constituent delivery mode and time set, mixes the solids wash thing among the present invention of several particle high velocity compacted at last.This assembly, granulation mode belong to innovation part of the present invention, and the particle of its acquisition and washes body also belong to innovation part of the present invention.

The technological difficulties that the present invention overcomes mainly contain: in conjunction with temperature condition and washing process demand, and the dissolution rate of control solids wash thing; In conjunction with mode and the time that component discharges, carry out the preparation moulding of granulation and solids wash thing; According to single washes at washing object and soil types and degree, component reasonable in design, proportioning, technology; Realize the integrated of solids wash and fabric-conditioning performance; The hand washing effect that the solid formulation washing is reached do not hinder hand; Natural biological is extracted albumen inject the solids wash thing, realize the impaired new technology viewpoint that also will replenish, remedy of fabric fibre; Select disintegrating agent and disintegration mode according to demand, especially realize the quick disintegration of high density detergent thing, the quick or slow-releasing disintegration of the quick disintegration of specific region and specific components.

The present invention describes in detail

The present invention at first relates to a kind of hyperconcentration, high-density solids wash thing by granulation of high actives content tensio-active agent and compacting, wherein, the tensio-active agent of one or more good water solubility serves as disintegrating component in the particle periphery, and the volume of single washes, weight and density parameter be fibre content, volume or the weight of corresponding single washing object simultaneously, fabric of preferred washes washing, and the working substance content of a kind of tensio-active agent of consumption maximum is not less than 50%.Through repetition test and measuring and calculating, the present invention points out, needs a kind of working substance content of tensio-active agent to be not less than 50% at least less than 5 grams and less than the portable solid washing monomer of 1 cubic centimetre subminiature.According to component of the present invention, compatibility and technology, can after dropping into washing water, in nine minutes, finish disintegration less than hyperconcentration, the high-density solids wash thing monomer of 5 grams at two seconds, finish disintegration in preferred five seconds to one minute.But the particle of some washing auxiliary detergent after by disintegration coats, and can expend longer slow-release time.The combination of sodium lauroyl sareosine and sodium lauryl sulphate is that the present invention is used for washing composition for the first time.Evidence, the weight sum of these two kinds of components account between the 5%-80% of whole washing weights can obtain washing effect preferably, and between the preferred 40%-70%, then the washes performance is more outstanding.Through measuring and calculating, be applicable to component of the present invention and compatibility requirement, and the component of granulation of the present invention and compressing tablet process can be powder or particle, the powder median size is between 10nm-10 μ m, and the particle median size is between 10 μ m-1mm.Through repetition test, the present invention points out the single-piece washing object of corresponding small-sized underwear to down jackets, effective single solids wash thing weight can be between 0.3 gram-5 grams, density is between 1g/ml-20g/ml, preferred pin is to normal laundry, described weight is that density is between the 1.07g/ml-6g/ml between 0.8 gram-1.5 grams.

In the component apolegamy, washing powder is generally selected a large amount of alkali inorganic salt and anion surfactant for use, and a small amount of nonionic component.Liquid lotion is generally based on negatively charged ion, and alternative also comprises big water gaging component with a small amount of nonionic and micro-inorganic salt.Different with it is that the present invention can select one or several tensio-active agents for use, also can realize comprehensive assembly of various tensio-active agents such as negatively charged ion, nonionic, positively charged ion, zwitter-ion.Compare with present general washing powder, liquid lotion, the present invention has creatively realized the direct compatibility of yin, yang ionic surface active agent.On working substance content, the negatively charged ion of washing powder, nonionogenic tenside working substance content are generally 10-20%, liquid lotion is generally 20～30%, among the present invention, the working substance content of at least a tensio-active agent is not less than 50%, and preferred working substance content is up to 92～97% tensio-active agent.

Different with washing powder, liquid lotion, that the present invention all selects for use is harmless, environmental protection, biodegradable component.For example, aspect anion surfactant, the optional α-sodium olefin sulfonate of the present invention, sodium lauroyl sareosine, sodium lauryl sulphate.Aspect cats product, the optional .TA101 softening agent of the present invention (distearyl dimethyl ammonium chloride).Aspect nonionogenic tenside, the optional fatty alkanol amide of the present invention, plant erucicamide surface slip agent.Aspect inorganic assistant agent, the present invention can select sodium bicarbonate, Succinic Acid, Sodium peroxoborate, SPC-D for use.Aspect functional agent, the present invention can select proteolytic enzyme for use, remove and hide agent, HQS albumen, essence etc. from.Among the present invention, Succinic Acid, polyvinylpyrrolidone, lauroyl flesh sodium sulfonate, TA101 softening agent, HQS native protein, remove and hide the application of agent component on laundering of textile fabrics from and belong to the first, in washing powder, liquid lotion, be not used.The invention still further relates to DRIETNE collagen protein, the first Application of niacinamide component in skin care solids wash sheet.

The strong component of decontamination is often selected in the conventional washing agent for use, and selection standard has both the component of degreasing, soil removability often.This class component is exactly damaged various fibers easily, and the fiber collagen protein, even the micro-lanolin (content about 0.3～1.5%) that natural cashmere, wool have all washes away from fiber, thus the major injury fabric fibre.In fact, great variety has taken place in modern's sanitation and hygiene custom, washes from washing by the moon, washing in week to have become everyday, how to select to nurse the gentle cleaning product of fabric fibre, and this has been new technical need.Find that after deliberation the combination of α-sodium olefin sulfonate and sodium lauroyl sareosine can reach the target that fat is not hindered in gentle washing decontamination.Sodium lauroyl sareosine is than seven times of gentlenesses such as sodium laurylsulfonate SLES, and is more powerful but decontamination is renderd a service, and bacterium is had restraining effect.Use said components, the pH value of washings can be stabilized between 5～7.5.Like this, the neutral wash environment of meta-acid can be protected people's skin and fabric fibre.After the washing, fabric fibre elongation, brute force does not have any damage, and has and prevent fiber balling-up, anti-scald special-effect.

Preparation technology of the present invention is preferably:

The first, boiling spraying one-step palletizing.Under 60 ℃, liquid lotion is become the mist attitude, evenly be sprayed onto on the grouping bonded component, reach the effect that tensio-active agent coats inorganic assistant agent.In the spray process, chemical reaction does not take place in each component, and makes tensio-active agent form film coated inorganic auxiliary agent, under 15～25 ℃, and the common molecule that forms with empty pocket structure.In the present invention, the blending ingredients life that obtains according to this step respectively is RO-1.

The second, about 70 ℃, will comprise or not contain the small-particle of RO-1 or powdered components and drop in the Vacuumdrier and carry out dry mixed, then by dry granulation, prepared particle component called after RO-2.

The 3rd, below 40 ℃, small-particle that comprises or do not contain RO-1, RO-2 or powdered components are carried out the vacuum-drying mixing, then by dry granulation, prepared grain fraction called after RO-3.

The 4th, below 30 ℃, small-particle that comprises or do not contain RO-1, RO-2, RO-3 or powdered components are carried out the vacuum-drying mixing, then by dry granulation, prepared grain fraction called after RO-4.

The 5th, below 50 ℃, choose the some or all of of RO-1, RO-2, RO-3, RO-4, perhaps add component in addition and carry out the vacuum-drying mixing, high velocity compacted moulding under normal temperature condition then produces solids wash thing of the present invention.

At process aspect, the present invention has overcome scrubbed component and has been mixed into the prejudice that powder just can be pressed into solid piece, sheet, test finds that this technology prejudice can not produce the solids wash thing of smooth surface, firm, the easy demoulding of physical structure, and it can not realize the technical purpose of the present invention aspect disintegration, slowly-releasing, and finds out at least the optimization technique route that is pressed into solid piece, sheet after the powder mixes with the particle of 70% weight and 30% weight at the most.

In addition, the present invention selects water-soluble strong tensio-active agent for use, also utilizes polyvinylpyrrolidone to cook disintegrating agent.Polyvinylpyrrolidone is polymer PVP, can suppress the migration of dyestuff in the solution.The present invention also selects the distearyl dimethyl ammonium chloride component for use, it has good softness to fabric, can make fabric sofetening fluffy, have and well wash old as new sense organ and good hand feeling, can also improve cotton, nylon, hair, artificial synthetic fiber's antistatic performance, make boiling hot Ironing thing not have vestige, can also prevent the fiber balling-up.What the present invention had also utilized and crossed carbon, crossed the boron active oxygen puts oxygen hydrotropy function.The present invention selects for use Succinic Acid to mix containing with α-sodium olefin sulfonate component, thereby improves disintegration and washing effect.The present invention selects polymkeric substance chelated dispersants and edetate disodium for use, makes water demineralization, can also strengthen water soluble characteristic.The present invention also can use the mixed composition of fatty alkanol amide and sodium bicarbonate, bay alkyd sodium sulfate, trimethyl-glycine cocounut oil glucoside, thereby improves dissolving and scourability.

Solids wash thing according to the present invention's preparation can be under 20～40 ℃ of water temperature environment, and disintegration discharges washing, helps and wash component fast, and clean single-piece adult down jackets with the single solids wash thing of 1.5-5g.Cleaning single-piece adult sweater, cashmere underwear, cotton knits required single solids wash thing such as underwear and can be lower than 1.5 grams.

Particularly, the component and the compatibility thereof that use of the present invention, details are as follows for the preparation method:

One, anion surfactant

Asymmetric, polar characteristics that water soluble surfactant active's molecular structure has.Molecule has hydrophilic group and oleophilic group simultaneously.Hydrophilic group has carboxyl, sulfonic group, sulfate group, ether, amino, hydroxyl etc., is that some are soluble in water or by the atomic group of water-wet.Oleophilic group is to have affinity with oil, and is common as alkyl.Tensio-active agent can be divided into anion surfactant, cats product, zwitterionics, nonionogenic tenside, mixed type ionic surface active agent etc., all can be used for the present invention.Wherein, anion surfactant mainly contains: the first, and higher fatty acid soap: R-COONa can make washing composition and emulsifying agent.The second, alkyl-sulphate: R-OSO ₃Na can make washing composition and whipping agent, and good stability in hard water, solution are neutrality or slight alkalinity, is the liquid lotion main raw material.The 3rd, alkylsulfonate: R-SO ₃Na, different alkyl chain lengths show different surfactivitys, can be divided into emulsifying agent, wetting agent, permeate agent, whipping agent, defoamer etc. in view of the above, are widely used in liquid lotion.The 4th, alkyl amido betaine: it is to be raw material synthetic anion surfactant with amino acid, and general formula is RCONHR ' COONa, and it is many and stable to produce foam, stimulates little, suitable baby's shampoo and cleaning agent for mouth cavity.The 5th, alkylphosphonic acid carboxylic acid lipid: R-OPO ₃Na has emulsification, froth breaking, antistatic, thickening power.According to the size of solids wash thing and disintegration, washing function requirement, the preferred α-sodium olefin sulfonate of the present invention, sodium lauroyl sareosine, sodium lauryl sulphate are as anion surfactant.

α-sodium olefin sulfonate possesses excellent water-soluble, soil removability efficiently, and working substance content can be up to 90～97%.Among the present invention, α-sodium olefin sulfonate and Succinic Acid contain mixed pelletization mutually, can improve soil removability greatly, improve the water-soluble of solids wash thing.This is because after the combination earlier of Succinic Acid and α-sodium olefin sulfonate, can produce collaborative soil-removing action, also can improve the disintegration effect.The component complexity of α-sodium olefin sulfonate mainly is alkene sulfonate, hydroxyalkylated sulfonic acid salt, and a spot of stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate etc., concentration was more than or equal to 40% o'clock easy viscose.It is acidproof, and is alkaline-resisting, insensitive to hard water.Its biological degradability is good, general only needs finish with regard to biodegradable in five days, and pungency is little, and toxicity is little, and washing back fabric feeling is good, can prevent the powdered detergent caking.Its seepage force is good, and wettability is with C ₁₂The strongest.α-sodium olefin sulfonate can be used as heavy-duty laundry detergent, Wool detergent, hand cleaner etc.α-sodium olefin sulfonate has the good low-temperature decontamination and removes the stain performance in without phosphorus, carbonato washing composition, stability in hard water is strong.Be characterized in possessing good wettability, detersive power, good foaming power, froth stability, emulsifying power are arranged; Very easily water-soluble, extremely strong dispersion of calcium soap, resistance to hard water are arranged; Have favorable biological degradability, and to the skin gentleness; Compatibility is good; The washing effect that is suitable for α-sodium olefin sulfonate is exquisiteness, good hand touch, easy rinsing etc.

Sodium lauroyl sareosine is generally the liquid of achromaticity and clarification.It is to derive from natural acid and sarcosine to form, and the effect of conditioning nursing fabric fibre is arranged, and characteristics are the characteristics with foam enhancing and stable foam, and can reduce other amendment to the foamy restraining effect; Can carry out compositely with other various tensio-active agents, improve active and reduce the pungency of product; In the pH value is that maximum surfactivity was arranged in 4～7 o'clock, can demonstrate stronger sterilization effect; Can make the dissolved lotion stable, increase transparent feel; Can form the hydrophobic protective membrane of one deck in skin-protection product, protection skin is not subjected to the invasion and attack of objectionable impurities, prevents the loss of moisture of skin.It also has fabulous biodegradability and is adapted at preserving between 10 ℃ to 49 ℃ and using.In general, it is a kind of anion surfactant powerful but that character is extremely gentle of rendeing a service, and in the present invention, its active constituent content can be up to 95%.Preparation technology of the present invention aspect, it mixes with positively charged ion TA101 nonionic slipping agent (distearyl dimethyl ammonium chloride), HQS albumen low-temperature vacuum drying in the prescription, each component contains maintenance effect separately mutually, is fit to low-temperature mixed and compressing tablet, does not preferably participate in drying and granulating.

Sodium lauryl sulfate is a kind of negatively charged ion emulsification, decontamination, whipping agent, and suitable pH value is 6～7.In the present invention, can cooperate above-mentioned two kinds of anion surfactants to use.

Two, cats product

Cats product does not generally possess detersive power, still, has at fabric fibre under the situation of cationic charge and uses, and washs in weakly acidic solution as silk, wool fabric, and cationic active agent has good washing effect.Its sterilizing ability is good, can be adsorbed on the frictional coefficient that solid surface significantly reduces fabric fibre, can make fabric softener, also can be used as levelling agent, laking agent, sterilant, static inhibitor.It generally can not be directly and the direct compatibility of anion surfactant use the precedent that in washing powder, liquid lotion, does not have the direct compatibility of cationic and anionic surfactant to use.Main cats product has: the first, and quaternary amine: mainly as softening agent, static inhibitor, sterilant, emulsion splitter etc., nontoxic odorless, non-stimulated to skin.The second, pyridinium halide: Corynebacterium diphtheriae, streptococcus aureus are killed ability, locate to use as cleaning disinfectant at food-processing, dining room, feedlot, swimming pool etc.The 3rd, the tetrahydroglyoxaline thing: it is typical cyclic amine compound, mainly uses hairdo moisturizing agent, amendment, sterilant, static inhibitor, fabric softener etc.The 4th, alkyl phosphate replaces amine: can make emulsifying agent, amendment and static inhibitor.

Preferred cationic surfactants of the present invention is TA101 softening agent (distearyl dimethyl ammonium chloride).It can be used as static inhibitor, fabric softener, disinfection sanitizer, asphalt emulsifier, acrylic fiber levelling agent, fiber conbidioning agent and dye additive etc.In the present invention, it can be used as the component of mixing granulation, effectively improves washing effect.Distearyl dimethyl ammonium chloride and positively charged ion, nonionogenic tenside or dyestuff have excellent compatibility, avoid and anion surfactant, dyestuff or additive compatibility.Given this, preparation technology of the present invention selects distearyl dimethyl ammonium chloride to avoid and anion surfactant, dyestuff or additive compatibility mixing granulation, in the mode of activeconstituents release with on the time, also avoid anion surfactant, dyestuff or auxiliary agent as far as possible.

Three, nonionogenic tenside

Nonionogenic tenside is not ionic condition in the aqueous solution, and its stability is high, and the influence of acid and alkali alkali is good with the tensio-active agent intermiscibility of other types.It is soluble in water, and is all very stable to soda acid, and fiber is not had bonding force, very easily cleans after using, and can use with positively charged ion, anion surfactant compatibility.In, acid, in the basic solution, it all has cleaning function preferably, emulsifying power is strong, decontamination, emulsification, dispersion, wetting, solubilising, anti-redeposition are good, generally also have antistatic property.Its foam is generally less, is fit to make low foam detergent.Nonionogenic tenside mainly contains fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, ester type, aliphatic amide etc.

Preferred fat alcohol amide of the present invention.Its detersive power, foaming power are strong, the fabric sofetening light of washing.In preparation process, it can mix with other liquid essences, with boiling spraying hydrocarbon polymer etc. is coated on the inside, coats back cooling granulation, high speed compressing tablet after mixing with other components then.This technology can improve detersive power, the solvency power of lotion.The nonionogenic tenside that the present invention also can select for use plant erucicamide surface slip agent to use as granulation, compressing tablet.

Four, inorganic assistant agent

The present invention also can select inorganic assistant agents such as Succinic Acid, sodium bicarbonate, Sodium peroxoborate, SPC-D for use.For example, the intumescence disintegrating property of Succinic Acid is good, also can be used as washing auxiliary detergent softening fibre, sterilization, sterilization.The present invention can use α-sodium olefin sulfonate and Succinic Acid to contain even granulation mutually, and granulation behind preferred α-sodium olefin sulfonate coating Succinic Acid prevents that Succinic Acid and sodium bicarbonate from the effervesce reaction taking place too early.And the preferred Succinic Acid content of the present invention surpasses more than the twice of the required Succinic Acid content of effervesce disintegration chemical reaction.This promotes contact velocity and the probability of the required component of effervescent effect in washing water greatly, thereby greatly improves the disintegration rate of solids wash thing.In addition, sodium bicarbonate has the intumescence disintegration, also help to wash and promote the powder granulation, and be that liquid ingredient is combined to solid main body sorbent material.It can be selected for use in a plurality of granulation step.Among the preparation technology of the present invention, preferred sodium bicarbonate is coated the back mixing granulation by the film forming liquid surfactant of multiple spraying.This can make the effervesce disintegration of sodium bicarbonate and Succinic Acid be reflected at the controlled stage and environment takes place down.Cross carbon, Sodium peroxoborate is put oxygen, hydrotropy, is helped disintegration, also has disinfection, but and bleached woven fabric make it beautiful in colour.

Except above-mentioned effervescence type disintegration material, the present invention also can select the disintegrating agent of other types for use.Be applicable to that disintegrating agent of the present invention can be divided into following a few class: the material of the material of swelling type disintegrating agent, effervescence type disintegrating agent, high-dissolvability, increase capillary densities etc.The swelling type disintegrating agent mainly contains: inorganic swelling disintegrating agent, as wilkinite, clay etc.; Organism, as starch, cereal, corn, rice, yam starch, starch derivative, carboxymethyl starch, sodium starch glycol; Mierocrystalline cellulose, as beech Mierocrystalline cellulose, beech-sulfite cellulose, cotton cellulose, pine tree Mierocrystalline cellulose, and the plain derivatives of other kind Mierocrystalline cellulose condensating fibers, Xylo-Mucine, cross-linking modified Mierocrystalline cellulose, Microcrystalline Cellulose, synthetic organic polymer, polyoxyethylene glycol, crosslinked Polyvinylpyrolidone (PVP) etc.Preferably polyethylene pyrrolidone of the present invention is as the particle disintegrating agent.It is water insoluble, but water-retaining capacity is strong, and along with its quick swelling, solids wash thing of the present invention disintegration fast is a small-particle.

For the effervescence type disintegrating agent, the present invention is not limited to said components, and can comprise various weak acid or hydrochlorate with the combination of alkaline carbonate or supercarbonate, citric acid for example, oxysuccinic acid, tartrate etc.In addition, the material of high-dissolvability, the material etc. that increases capillary densities also can be used as disintegrating agent of the present invention.For example, following table () has been put down in writing the water solubility of part disintegrating agent.Wherein, the water solubility height of urea, and low price, the disintegrating agent of Ceng Zuowei washing powder pressing block.But, innovate owing to lacking on component selection, composite mode, the manufacture method, and bulky, fluffy frangible, and this kind product makes no public appearances on market substantially.According to mode and the time requirement that each component discharges, the present invention can select the dissolving and the disintegration of the disintegrating agent regulation and control solids wash thing of one or more types for use.

The water solubility of table (one) part material relatively

Material	Water solubility (g/100g)
		Two hydration Trisodium Citrates	72
Salt of wormwood	112
		Urea	Greater than 100
Sodium acetate (anhydrous)	119
		Sodium acetate trihydrate	76
Seven hydrated sodium acetates	71
		Potassium acetate	Greater than 200

The present invention also can select following component for use: the TA101 softening agent, make fabric sofetening, and anti-electrostatic, anti-balling-up, it is anti-old for new to wash the back; HQS albumen can replenish, nurse impaired scleroproein, prevents balling-up, and is antistatic, improves the glossiness of fabric, recovers the texture of fiber surface, also can anti-scaldly press vestige; Plant erucicamide slipping agent can improve the fabric smooth feeling; Remove and hide agent from, can eliminate and hide worm from, guarantee that fabric fibre is to HUMAN HEALTH; The wave power low-temperature protease can pass through biological mode softness, polishing fabric, removes specific spot; Essence can be removed the fabric peculiar smell, gives and washes the happy people's fragrance of back fabric.

From commercial angle of innovation, the solids wash thing among the present invention can be done globulate, avette, oval spherical, the positive cubic bodily form long cube shaped, sheet shape, heart, cylindrical, no sharp cone distal, imitative animal shape, imitative cartoon figure's shape, imitate trade mark shape or imitative literal shape.In addition, in order to realize other commercial purposes, pattern, safety notice, environmental mark, product operation instruction, safety instruction, trade mark, trading company, ripple, decorative pattern or picture that this at least one surface of solids wash thing can have projection or depression to show.For colored text or figure, picture are set on the solids wash thing, part particle, part surface or all surfaces of solids wash thing can be applied by pigment, dyestuff or other tinting materials.

The invention still further relates to the purposes of relevant solids wash thing in washing machine, throw in the tap water of wherein said washes before electrolysis.This washes can be given up a large amount of negatively charged ion, nonionogenic tenside, can increase the consumption of washing auxiliary detergent and cats product.In addition, the solids wash thing can also be after electrolysis alkaline water or sour water in throw in, in order to improve washing effect, anion surfactant, nonionogenic tenside or zwitterionics content are higher relatively in the washes of input alkaline water, and cationic surfactant concentration is higher relatively in the washes of input sour water.

By adjusting the consumption and the distribution of disintegrating agent, the solids wash thing can be finished disintegration after object contacts with being cleaned at brine electrolysis, perhaps brine electrolysis be cleaned object and contact before finish disintegration substantially.From controlling the angle of disintegration effect in advance, in the multi component particle thing of solids wash thing, disintegrating component can be near the surface or the nuclear core of particulate matter.In addition, in order to prevent the wearing and tearing of solids wash thing, to become damp, solids wash thing of the present invention can increase a coating that increases hardness and moisture resistance ability.Find by retrieval, Succinic Acid, polyvinylpyrrolidone, lauroyl flesh sodium sulfonate, TA101 softening agent, HQS native protein, remove and hide the purposes of agent in preparation solids wash thing from.Therefore, the present invention also should be contained these purposes technical schemes.

Except overcoming scientific research, business circles to developing the above-mentioned technology prejudice that solids wash produce product exist, except solving scientific research, business circles to developing the above-mentioned technical barrier that solids wash produce product run into, the present invention also has the following innovation:

The first, preferentially select after disintegration, the dissolving washing is arranged, help wash, the component of functions such as sterilization, nursing is as disintegrating agent.Simple disintegrating component increases the weight and volume of solids wash thing, but can significantly not improve washing effect.After preferred disintegration, the dissolving washing is arranged, help wash, the component of functions such as sterilization, nursing, this can reduce the weight and volume at the single washes of single-piece clothing.This optimal way is one of innovative point of the present invention.

The second, break away from surface active agent composition, compatibility mode, preparation method that soap, washing powder, liquid lotion use fully.Except tensio-active agent, the present invention has also adopted the unique technique design aspect components selection, compatibility, the preparation fully helping to wash.For example, according to the trace of solids wash thing washing requirement, the present invention by a large amount of composite test and Selection efficiently, high actives content, multi-functional tensio-active agent.Wherein, it is comparatively general to be fit to carry out the solid surfactant component of gentleness, environment friendly washing.In addition, by repetition test, the present invention has opened up the new component that zwitterion can be effectively composite.In the disintegration and tensio-active agent of main scrubbed component, working substance content can be up to 92-99.8%.For example, the following 200-800 that is applicable to restrains in the mix proportion scheme of clothing, and the working substance content of each main basic scrubbed component all surpasses 92%, and the monomer washing weight is no more than 3 grams, and volume is no more than 1 cubic centimetre:

Main scrubbed component 45-55%

A. high-efficient washing component

1. α-sodium olefin sulfonate 10-40%

2. sodium laurylsulfonate 3-35%

B. gentle scrubbed component

1. sodium lauroyl sareosine 3-6%

2. alcohol ether carboxylic salt 0.3-5%

C. not having machine aided washes

Sodium bicarbonate 10-15%

Help and wash scrubbed component 5-7%

A. polymkeric substance chelated dispersants 445G0.3-5%

B. fatty alkanol amide 1-3%

C. sodium ethylene diamine tetracetate 0.1-0.6%

Function scrubbed component 6-10%

A. wave power low-temperature protease 0.6-1.2%

B. remove and hide agent 0.1-0.3% from

C. plant type erucicamide slipping agent 1-3%

D.TA101 softening agent 3-10%

E.HQS native protein 0.1-2%

The disintegration hydrotropy helps washes sterile components 30-40%

A. Succinic Acid 10-30%

B. SPC-D 5-10%

C. Sodium peroxoborate 5-10%

D. polyvinylpyrrolidone 0.5-3%

E. essence 1-2%

The 3rd, coat the combination specific components by the boiling spraying, to granulate by cryodrying then, this is the innovative technology of proposition of the present invention.This technology has solved the technical barrier of adding liquid surfactant, essence etc., and coats different effervescence components with this technology, stops acidity and basic component to produce inorganic salt under unwanted conditions and environment.

The 4th, by the consolidated structure of solid densification, washes of the present invention can be protected internal composition not fail, escape effectively or other unnecessary physics, chemical transformation take place.Generally speaking, only there is the several months washing powder quality guaranteed period behind the Kaifeng.The packing less liquid lotion quality guaranteed period is shorter.By contrast, evidence, the solids wash thing among the present invention can expose under normal temperature, normal wet environment, guarantees the quality at least 3 years, and the solids wash thing quality guaranteed period of seal coat is longer.

Aspect and effect thereof that the present invention overcomes soap field prior art defective are embodied in following aspect:

The first, a large amount of greases of soap consumption.The present invention does not need to expend grease.The second, the soap washing effect is poor.Soap runs into and chemical reaction can take place behind the mineral substance in the hard water and produce the powdery soap scum, and this dirt is easy to influence cleaning effect attached on the clothing.The present invention does not have this shortcoming.The 3rd, the soap versatility is poor.Soapmaking need be used a large amount of caustic soda, and this makes soap alkalescence, corrodibility too strong, is not suitable for washing silk, wool fabric, and some man-made fiber fabric.The present invention is fit to the gentleness washing of various fabrics.The 4th, the quality of soap be cannot say for sure to demonstrate,prove.For example, rigid oil is too much in the soap, and zero pour is higher, and then product ftractures easily, hardens, and washing usefulness seriously reduces.The present invention does not have this shortcoming.The 5th, soap has pungent unpleasant peculiar smell.The present invention is without any peculiar smell, especially unpleasant peculiar smell.The present invention can also make tasteless solids wash piece, and the lotion of delicate fragrance is perhaps arranged.The 6th, soap may skin irritation.The sodium hydrate content of soap is higher usually, and soap body alkalescence, corrodibility are strengthened greatly.The present invention uses weak base, weak acid, the washing of neutral problem, generally skin irritation not.The 7th, soap is not easy metering and uses.Soap does not generally use by automatic disintegration, dissolution mechanism, and often is coated to textile surface by mechanical friction.How much soap the single-piece textiles uses, and this does not have the measurement standard that can control fully.Clothing of the preferred solids wash thing monomer washing of the present invention, it throws in simple, and metering is accurately.

Aspect and effect thereof that the present invention overcomes washing powder field prior art defective are embodied in following aspect:

The first, the washing powder degreasing is strong.The present invention is fit to gentle washing, not degreasing substantially, not injured skin.The second, washing powder waste water power.Washing powder generally can produce a large amount of foams, needs to use a large amount of water to come rinsing clothes, wastes very much water power.It is few that the present invention is bubbled, and silk goods, cashmere fabric, woollen fabrics etc. are not needed rinsing substantially, to the rinsing of other clothings also seldom.The 3rd, washing powder has residual easily, especially makes moist or the washing powder of pressurized caking, and it is residual general more and obviously.Solid lotion of the present invention disintegration successively finishes, and does not have residual.The 4th, the wash concentration of washing powder is wayward, and washing effect is poor.The present invention can make the user control wash concentration comparatively accurately, obtains the good washing effect.The 5th, washing powder density is little, and it is very huge that plastics load the volume of apparatus, and after making moist or being extruded, washing powder lumps easily influences washing effect.Lotion density of the present invention is big, and conventional extruding, beat, make moist etc. does not influence the physics and the chemical moral character of lotion of the present invention.The 6th, washing powder is not easy metering and uses.The volume of washing powder and density are not easy control, and this mainly is that preparation technology causes.Washing powder pulp density, slip pressure, spray gun diameter, advance tower air quantity, gas and carry air quantity, back compounding and close volume and the density that factor such as situation may influence washing powder, the washing powder quantity that the single-piece clothing is needed is difficult for measuring and calculating.And because particle proportion difference, the distributions in soft washing powder particle such as enzyme, SYNTHETIC OPTICAL WHITNER, zeolite are also inhomogeneous.Even the user accurately calculates the washing powder quantity that the single wash task need be thrown in by auxiliary means, each component wherein also departs from the numerical value of actual needs easily as the content of washing composition, washing auxiliary detergent etc.Solid lotion of the present invention is contained in each scrubbed component fixed sealing of corresponding specific washing task in the washing composition monomer, can eliminate the above-mentioned drawback of washing powder.

The 7th, behind the Kaifeng, washing powder is apt to deteriorate.Among the present invention, the component of solid lotion is encapsulated in the highdensity compacting washing monomer, and the outside also can apply a protection against the tide, anti-pressure, antiwear coating, is not easy to go bad.The 8th, the versatility of washing powder is poor.Washing powder is suitable for washing cotton, fiber crops, chemical fibre and BLENDED FABRIC thereof.But the general meta-alkalescence of washing powder can make protein denaturation, and hair, silk etc. is had certain damage.Therefore, most of washing powder are not suitable for washing hair, silk fabric or its BLENDED FABRIC.Solid lotion of the present invention especially is fit to washing wool, cashmere, silk or its BLENDED FABRIC, also can wash other various fabrics such as cotton, fiber crops, and versatility is fine.The 9th, the time that each component of washing powder plays a role is easy-regulating not.The present invention suitably sets mixing, granulation, coating relation between each component of solid lotion according to fiber properties and decontamination principle, thereby sets the mode and the order of each components dissolved, release, and this can improve washing effect greatly.But the physical structure of washing powder and preparation technology do not allow people to carry out this setting.

Aspect and effect thereof that the present invention overcomes liquid lotion field prior art defective are embodied in following aspect:

The first, liquid lotion is owing to the compatibility problems of solubility limit and tensio-active agent, and inorganic assistant agent adds kind and quantity all is subjected to very big the influence.So in liquid lotion, some good auxiliary agents can't add or can only add by trace, this has weakened the washing effect of liquid lotion greatly.Lotion of the present invention can add the auxiliary agent of any kind, quantity as required.The second, the liquid lotion latherability is strong, causes foam abundant, makes clothing be difficult for rinsing, wastes water source and electric energy in a large number.Lotion foam of the present invention is few, does not generally need rinsing, perhaps only needs a small amount of rinsing just can finish washing process.The 3rd, the general moisture content that adds 40-80% in the liquid lotion, opposite scrubbed component content is little, and this makes the liquid lotion product consume a large amount of water sources and trucking costs.In addition, liquid lotion is generally with Plastic Bottle, bucket dispensing, equally with washing powder also can produce a large amount of plastic garbages.The moisture content that solid lotion of the present invention comprises is few, and can any Plastic Bottle, the bucket packing, can reduce environmental pollution.

Compare with soap, washing powder, liquid lotion, the present invention also has another very outstanding advantage: easy to carry, and be fit to be assemblied in the Trade mark hanging plate and sell with clothing, also be fit to go on business, the travelling personnel carry.Solid lotion of the present invention can be made monobasic even one fen Renminbi coin's size, thickness is the sequin of 2 to 10 mm thick, and can not use special sealing, loading apparatus, as plastics bag, packing bag, bottle, bucket etc., even not adding any packing just can be with other article portable of packing.Volume is little, compact structure, quality are hard, form is solid, can corresponding washing designated volume, the fabric of weight, fiber etc., these characteristics are primary conditions that lotion of the present invention has above-mentioned outstanding advantage, and the combination of these characteristics then is that technical scheme of the present invention is exclusive.

Aspect and effect thereof that the present invention overcomes solids wash thing art difficult point are embodied in following aspect:

The first, in conjunction with temperature condition and washing process demand, the dissolution rate of control solids wash thing; The present invention is according to considering in advance wash temperature condition and washing process demand, by selecting component, the compatibility of component, the component disintegration ability on solid lotion surface, the disintegrating component concentration on solid lotion surface, and the mixing between the component, granulation combination etc. have solved this technological difficulties.The second, in conjunction with mode and the time that component discharges, carry out the preparation moulding of granulation and solids wash thing; The repetition test of the present invention by manually throwing in different components successively, mode, time, sequential scheduling that component discharges have been selected, in order to realize this selected combination, the present invention to each design of components corresponding composite, grouping mixes, grouping granulation, compressing tablet, coating apply countermeasure, has solved above-mentioned technical barrier.The 3rd, according to single washes at washing object and soil types and degree, component reasonable in design, proportioning, technology; Distribute by statistics, the fiber type of analyzing fabric, volume, weight, soil types, solids wash thing of the present invention has designed preferred pin each component quantity to the single-piece fabric, then by special prepared washes, thereby overcome above-mentioned technical barrier.The 4th, realize the integrated of solids wash and fabric-conditioning performance; Solid lotion of the present invention has added conditioning component, can realize gentle washing, and to effective conditioning of fabric.The 5th, the hand washing effect that the solid formulation washing is reached do not hinder hand; Alkalescence of the present invention is low, also can be the washing of neutrality or slightly acidic, does not have degreasing, corrosion component, and can add the component of nursing skin, can reach the effect of not hindering hand.The 6th, natural biological is extracted albumen inject the solids wash thing, realize the impaired new technology viewpoint that also will replenish, remedy of fabric fibre; The present invention is encapsulated into native protein in the solid monomer, protects its non-inactivation, rotten, has realized the gentleness washing target of maintenance fabric fibre for the first time.The 7th, select disintegrating agent and disintegration mode according to demand, especially realize the quick disintegration of high density detergent thing, the quick or slow-releasing disintegration of the quick disintegration of specific region and specific components; By selecting disintegrating agent, disintegrating agent concentration in distribution and the collocation etc. between variable grain of the distribution of washing sheet particle or body, disintegrating agent, the present invention can solve above-mentioned technical barrier.

Embodiment 1

The part disintegration of setting according to the disintegration object, help and wash amounts of components arranging scheme example:

Embodiment 2

Embodiment 2 relates to a kind of weight and is not more than 1.5 grams, and density is not less than high-density, the subminiature solids wash thing of 2g/ml, is applicable to the gentleness washing of various fabrics.Screening multifunctional meter surface-active agent, and its working substance content 〉=90%.As α-sodium olefin sulfonate effective content 〉=93%; Sodium lauroyl sareosine effective content 〉=95%; Sodium lauryl sulphate effective content 〉=93%.Simultaneously, make disintegrating agent with Succinic Acid.Succinic Acid and hydrocarbon generation neutralization reaction reach effervesce disintegration effect.But break molecular equilibrium in a large number, strengthen the Succinic Acid consumption more than 1 times according to the required Succinic Acid consumption of effervesce chemical reaction, preferred more than 1.5 times, then Succinic Acid and efficient surfactant generate a kind of compounded combination, not only do not influence washing, produce on the contrary and help beneficial effects such as washing, quicken disintegration, degerming.

Embodiment 3

Embodiment 3 relates to a kind of technology of preparing scheme of double-layer bi-color washing sheet.

Processing step: the first, mix micro liquid, essence, disintegrating component, help and wash component and make the RO-1 component in the spray mixing of boiling below 60 ℃.The second, disintegrating agent, washing auxiliary detergent are in dry mixed under 70 ℃ of left and right sides vacuum environments, and the low temperature dry granulation is made the RO-2 component.The 3rd, help wash, the vacuum-drying at room temperature of function scrubbed component mixes, drying and granulating obtains the RO-3 component.The 4th, RO-1, RO-2, RO-3, other low temperature functional auxiliary agent are at low temperature. and dry mixed under the vacuum environment of low humidity obtains the required finished granule of compressing tablet.The 5th, the high speed compression molding is made the solids wash thing at ambient temperature, packs automatically with the plastic-aluminum bubble-cap, then solids wash thing finished product is carried out packing.

Utilize above-mentioned technology, disintegration required Succinic Acid and sodium bicarbonate layering color separation.Other washing composition and auxiliary agent branch are added in granulation respectively in two kinds of disintegrating agents, and making monolithic weight by double-colored tabletting machine is 1.2-2.5g, granularity 〉=16 orders, and size distribution reaches more than 75%, the double-layer bi-color solids wash thing of moisture 3-3.5%.

Embodiment 4

Embodiment 4 relates to fleece fabrics solids wash thing technical scheme.

Every weight/size: 1.5～1.8g, volume is less than 1 cubic centimetre.

Every each component title and content (comprise high-efficient washing component, gentle washing component, main the no machine aided that disintegrates of washing wash, help washing component, function washing component, disintegration hydrotropy to help and wash the component of sterilizing):

High-efficient washing component: α-sodium olefin sulfonate 20-30%, working substance content 92-97%

Sodium lauryl sulphate 10-20%, working substance content 92-95%

Gentle washing component: sodium lauroyl sareosine 3-10%, working substance content 95%

Fatty alkanol amide 2-5%, working substance content 100%

The main disintegration inorganic assistant agent of washing: Succinic Acid or citric acid 15-30%, working substance content 99.5-99.8

Sodium bicarbonate 20-30%

Polymkeric substance chelated dispersants 0.3-5%

Functional agent: proteolytic enzyme 1%

HQS albumen 0.2-0.5%

TA101 3-10％

Remove and hide agent 0.1% from

Essence 0.2%

Polyvinylpyrrolidone 0.5-3%

Disodium ethylene diamine tetraacetate 0.2%

Plant type erucicamide slipping agent 1-3%

The washing object: each solids wash thing can wash one of fleece fabrics, the about 200g-400g of this fabric.Because of the about 200-280g of cashmere woman shirt, the about 250-400g of male shirt, other fleece fabrics as scarf, gloves all in this weight range.From the angle of fibre content, cashmere fiber is very thin, and scale layer, lamina corticalis, marrow layer three part are arranged.Cashmere is subject to water stain, and cashmere promptly wets into one entirely within the several seconds, and cashmere is relatively more responsive to acid, alkali and thermal response in addition, and fibre-tendering is more remarkable.Cashmere to the susceptibility of chlorion more so, the cashmere fiber textile stains that therefore is in the suds is more easily removed.The lotion that the present invention selects to reach detersive power 0.8-1.0% just can reach the purpose of removal fiber spot fully.The washing of cashmere fiber priorly is to protect fiber injury-free, so strengthen gentle washing and conditioning, functions such as protection supplementary fibre albumen are particularly important.Moreover cashmere sweater is a kind of high-grade clothing fabric.See that according to the crowd who dresses the user this kind fabric can not be very dirty, spot can be very not obstinate yet, and cashmere is animal fibre, and surface-brightening, plentiful, smooth is so be easy to gentle washing.The present invention adopts the gentle washing lotion of pH value for 5.5-6.5, does not damage cashmere fiber, and strengthens the protection cashmere fiber with albumen TA101.

Embodiment 5

Embodiment 5 relates to a kind of cotton fabric solids wash thing technical scheme.

Every weight/size: 1.8-2.1 gram, small-sized underwear are the 0.8-1.2% gram.

Every each component title and content (comprise high-efficient washing component, gentle washing component, main the no machine aided that disintegrates of washing wash, help washing component, function washing component, disintegration hydrotropy to help and wash the component of sterilizing):

High-efficient washing component: α-sodium olefin sulfonate 15-25%, working substance content 92-97%

Sodium lauryl sulphate 15-30, working substance content 93-95%

Gentle washing component: alcohol ether carboxylic salt AECl-2%, working substance content 97%

Sodium lauroyl sareosine 3-5%, working substance content 95%

Main washing cut the body inorganic assistant agent: Succinic Acid 15-25%, working substance content 99.5-99.85%

Sodium bicarbonate 15-25%

SPC-D or Sodium peroxoborate 8-10%

Help the washing component: polymkeric substance chelated dispersants 445G0.3-5%

Anhydrous sodium sulphate 5-8%

Function helps washes component: disodium ethylene diamine tetraacetate 0.1-0.3%

TA101 5-8％

Polyvinylpyrrolidone 1-3%

Remove and hide agent 0.1-0.2% from

Proteolytic enzyme 1-1.5%

Essence 0.5-1%

Plant type erucicamide slipping agent 1-3%

Cotton fabric has two kinds: the first, and small-sized underwear, underpants, 1 solids wash thing of single-piece consumption, about 0.8-1.5g.The second, cotton fabric, as cold-proof underwear, cotton fabric shirt, T-shirt etc., single-piece is used a slice solids wash thing, about 1.8-2.1g.Though cotton fibre has a large amount of hydrophilic hydroxyl groups, it water insoluble only can be expanded limitedly, this mainly be since cellulosic molecule between exist stronger hydrogen bond and Van der Waals force.Cotton fibre is alkaline-resisting not acidproof, and acid is strong especially to cellulosic effect, makes the cellulose hydrolysis long key of cut-out and presents tendering.Cotton fibre molecule intensity is higher, and the relatively poor rebound resilience of fiber molecule " flexibility " is limited simultaneously.Hot acid and microorganism all have very big influence to cotton fibre.This makes that cotton fibre fades easily, flavescence, making moist easily produces bacterium, present embodiment adopts the pH value to be the gentleness washing of weakly alkaline (7-7.5), and increasing detersive power, select the strong sodium lauryl sulphate of decontamination fat for use, reach more than 68% with cloudy, non-, cats product working substance content, calculate with every 2g, it is 2g * 68%=1.36g that each solids wash thing contains the tensio-active agent working substance, can remove spot with the trace washing.

Embodiment 6

Embodiment 6 relates to a kind of wool fabric solids wash thing technical scheme.

Every weight/size: 1.5-1.8g.

Every each component title and content (comprise high-efficient washing component, gentle washing component, main the no machine aided that disintegrates of washing wash, help washing component, function washing component, disintegration hydrotropy to help and wash the component of sterilizing):

High-efficient washing component: α-sodium olefin sulfonate 20-30%

Sodium lauryl sulphate 15-25%

Gentle washing component: sodium lauroyl sareosine 3-6%

Polyoxyethylenated alcohol sodium sulfate AES 2-3%

Help to wash and cut the body inorganic assistant agent: Succinic Acid. citric acid 20-30%

Sodium bicarbonate 20-30%

Sodium peroxoborate 5-8%

Anhydrous sodium sulphate 1-4%

Functional agent: proteolytic enzyme 1-1.5%TA101 3-8%

Polyvinylpyrrolidone 0.2-2%

Disodium ethylene diamine tetraacetate 0.2%

Plant type mustard acid amides slipping agent 1-2%

Essence 0.2%

The washing object: monomer weight is 1.5-1.8g, can wash a wool fabric.About every woollen sweater, woolen pants average out to 300g.1.5-1.8g monomer solid washes comprises effective constituent 1.02-1.22 gram, can realize the trace washing to a 300g left and right sides wool fabric.

The wool fiber thickness is widely different, between the 30-75 micron, decomposes in highly basic, damages in weak base, and friction produces fulling milling in diluted acid or alkali.Wool fiber is difficult for water stain, not anti-damaging by worms.Wool fiber is warming, wear good, and gloss is decided by complete, the tight arrangement of hair fibre scale.Present embodiment adopts the washing of 6-6.5pH slightly acidic; thereby the protection wool fiber is injury-free; and, soak into the wool fabric fiber by the efficient surfactant combination, after activeconstituents immerses fiber and dirt; can reduce the bonding force of dirt and fiber; make dirt break away from wool fiber under the acting in conjunction of decontamination, emulsification, component such as wetting, soft smooth care component makes complete, the tight arrangement of wool fiber scale, makes not fulling milling of fabric; not balling-up, light is endurable.

Embodiment 7

Embodiment 7 relates to a kind of solids wash thing technical scheme of silk fabrics.

Every weight/size: 0.8-1.5g.

Every each component title and content (comprise high-efficient washing component, gentle washing component, main the no machine aided that disintegrates of washing wash, help washing component, function washing component, disintegration hydrotropy to help and wash the component of sterilizing):

Gentle washing component: sodium lauroyl sareosine 3-10%

High-efficient washing component: α-sodium olefin sulfonate 30-50%

Main washing cut the body inorganic additive: Succinic Acid, citric acid 15-25%

Sodium bicarbonate 20-30%

Functional agent: proteolytic enzyme 1-2%

TA101 4-8％

Polyvinylpyrrolidone 0.2-2

Disodium ethylene diamine tetraacetate 0.2%

Remove and hide agent 0.1-0.3% from

Essence 0.2%

The washing object: monomer weight is that the solids wash thing of 0.8g can wash a small-sized silk weaving underwear, underpants, and the solids wash thing of 1.5g can wash a silk weaving shirt, skirt and trousers.Silk results from natural protein fibre animal glandular secretion liquid, is made up of silk gum and fibroin, and the latter accounts for the 72%-80% of silk total amount (dry measure).Silk has special gloss and feel.But silk gum is easily dissolving in basic solution, and fibroin is also corroded easily, so will protect the gloss of silk fabrics will protect silk gum, fibroin not to be corroded.Silk goods are short general wash(ing)cycle, and dirt is based on micro-floating dust in oil stain, sweat stain, the air, and the user is accustomed to hand washing.Therefore, present embodiment adopts soft tensio-active agent, adopts the formula combination of heavily gentle fine laundering.Suitable washings pH value is between the 6-7.

Embodiment 8

Embodiment 8 relates to a kind of solids wash thing technical scheme of linen.

Every weight/size: 1.0-1.5g.

Every each component title and content (comprise high-efficient washing component, gentle washing component, main washing cut a body and do not have machine aided and wash, help washing component, function washing component, disintegration hydrotropy to help to wash the sterilization component):

Gentle washing component: sodium lauroyl sareosine 3-10%

High-efficient washing component: sodium lauryl sulphate 20-30%

α-sodium olefin sulfonate 15-20%

Main washing cut the body inorganic assistant agent: Succinic Acid. citric acid 20-30%

Sodium bicarbonate 20-30%

SPC-D 10-15%

Functional agent: proteolytic enzyme 1-2%

TA101 3-7％

Polyvinylpyrrolidone 0.2-2%

Disodium ethylene diamine tetraacetate 0.2%

The washing object: each 1.0-1.5g solids wash sheet can be washed a fabric, and general the employing hand-washed.Disposable immersion decontamination, degerming, sweat stain and dirt are just capable of washing clean, and do not damage fiber.Linen is a native cellulose fibre, generally extracts the fabric flaxen fiber with flax, hemp, jute, ramie.The weaving fiber crops are the flaxen fibers that get from axis, and tensile strength is high, and is very strong to the resistance of bacterium and salt corrosion, stretches the rate minimum, and the bending resistance degree is strong and clinging power is little, thereby can make efficient textile fiber.Linen has the most excellent nice and cool property characteristics, is the optimal selection of people's clothes in summer.The flaxen fiber alkali resistance is good, and is anti-insect, but corroded by mushroom.According to these characteristics, the present invention adopts the weakly alkaline washing of pH value 7-7.5.

Embodiment 9

Embodiment 9 relates to a kind of solids wash thing technical scheme of BLENDED FABRIC.

Every weight/size: 1.2-1.8g.

Every each component title and content (comprise high-efficient washing component, gentle washing component, main washing cut a body and do not have machine aided and wash, help washing component, function washing component, disintegration hydrotropy to help to wash the sterilization component):

The efficient cleaning: α-sodium olefin sulfonate 20-30%

Sodium lauryl sulphate 10-20%

Gentle lotion: sodium lauroyl sareosine 3-6%

Fatty alkanol amide 1-3%

Disintegration inorganic assistant agent: Succinic Acid. citric acid 15-30%

Sodium bicarbonate 20-30%

SPC-D 5-8%

Functional agent: Permalose chemical ﹠ blended fabric clean-out system 0.5-2%

Proteolytic enzyme 1-1.5%

TA101 2-5％

Polyvinylpyrrolidone 0.2-2%

Disodium ethylene diamine tetraacetate 0.2%

Essence 0.2%

The washing object: BLENDED FABRIC, between 300-400g, weight is the single solids wash thing of a 1.2-1.8g BLENDED FABRIC capable of washing as weight such as shirt, trousers.BLENDED FABRIC generally is that cashmere, wool, cotton and regenerated fiber blending form, based on regenerated fiber.Regenerated fiber then divides organic fibre and inorganic fibre, is mainly used in the deficiency of replenishing natural fiber, and its intensity height, good springiness, wear-resisting, chemical-resistant reagent are difficult for mouldy damaging by worms, and its textiles dimensional stabilizing is stand wear and tear.The shortcoming of BLENDED FABRIC is that the static reaction is easily arranged.The present invention adopts the gentleness washing of pH value between 6.5-7.5, can be antistatic, and washing effect is good.

Detect through how tame third party authoritative institution, solid lotion of the present invention can be obtained excellent washing effect, especially for fabrics such as cashmere, silk, fiber crops, wool, cottons, the examining report that the third-party institution provides shows, solid lotion scavenging period of the present invention is short, generally do not need rinsing, but washing effect surpasses washing powder, liquid lotion etc.For example, at the product of embodiment 4, fleece clothing manufacturing enterprise the biggest in the world---test experience chamber, Erdos, Inner Mongol cashmere group technique center has been issued the NO:065007 survey report on July 14th, 2006 to the censorship people.Detect according to being: Q/DDS 001-2000 " cashmere sweater clean-out system, softening agent ".Report shows: solid lotion of the present invention is that solid state white chromophoric monomer, odor type free from extraneous odour, gross activity thing content are 68%, and criterion of acceptability only is 20%; The pH value of solid lotion of the present invention in 25 degrees centigrade, 0.1% solution is 6.2, and standard code is 5.5-7.5; Solid lotion of the present invention does not contain any fluorescent brightening powder.The result of examining report shows: solid lotion washability of the present invention surpasses used liquid lotion.Third party's examining report to other fabrics such as linen, silk fabrics, cotton fabric, wool fabric, BLENDED FABRIC shows generally that also solid lotion washability of the present invention surpasses washing powder, liquid lotion, is their substitute products.

Calculate according to Erdos cashmere group, 6000 of solids wash monomers of the present invention can wash 6000 cashmere sweaters respectively, its whole trucking costs only are 5.2 yuan, the bottling liquid lotion of 6000 cashmere sweaters of washing then need expend 163.2 yuan of trucking costs, and liquid lotion packing plastic bottle expense needs 600 yuan in addition.Dispensing aspect, solids wash monomer of the present invention can embed that Trade mark hanging plate is wholesale in the lump in company with fabric, retail, need not to pay in addition any dispensing expense.On the contrary, liquid lotion need be divided and installed in the bottle, is dispensed into each point-of-sale terminal, on average sells the ability of 200 cashmere sweaters with each terminal and calculates, and then 6000 cashmere sweaters are dispensed into about 1500 yuan of all charges of a terminal.Therefore, solids wash monomer of the present invention is compared with liquid lotion, and the expense of saving in transportation and dispensing has reduced more than 423 times altogether.Given this, Erdos cashmere group and other domestic and international top dress manufacturers be formally decision, annual will be in company with its number in the solids wash monomer of the present invention of providing and delivering of clothes necessarily, thereby with synthesis of detergent products such as the comprehensively alternative original washing powder of solids wash monomer of the present invention, liquid lotion.But, technical scheme of the present invention is not limited to make the textiles lotion, and is applicable to that manufacturing is applicable to other various synthetic detergents of washing health, hair, tableware, instrument etc.

Different with other currently available productss, the monomeric surface of solids wash thing of the present invention can be provided with monochromatic or chromatic figure, pattern, literal, trade mark, trading company etc., not only can fit on the clothes label drop of sale functions such as performance is false proof, guide, happy interest, and can indicate the object type, quantity, washing time, washing methods etc. of washing.

In addition, without phosphorus, the no white dyes of solids wash monomer of the present invention, and all are to the deleterious material of human body skin, it is the green product of a kind of cleaning, environmental protection, different with other currently available productss, solids wash thing monomer of the present invention also can be compressed to specific moulding such as spatial literal, the heart, biology, trade mark, map, thoroughly changes traditional situation that synthetic detergent can't free moulding, starts the unlimited prospect of synthetic detergent shape-designing.According to initiative technical scheme of the present invention, only in shape-designing, solids wash monomer of the present invention can be born and a large amount of new technologies and product innovation, greatly enriches daily life, and changes the looks of articles for washing industry deeply.

The effervesce disintegrating component that a kind of usefulness is broken molecular equilibrium serves as the solid detergent monomer of disintegrating agent, it comprises tensio-active agent, washing auxiliary detergent and disintegrating component, the consumption that it is characterized in that at least a disintegrating component exceeds more than a times of its effervescent effect requirement, wherein the working substance content of a kind of tensio-active agent of consumption maximum is not less than 50%, described disintegrating component comprises Succinic Acid, and wherein used tensio-active agent α-sodium olefin sulfonate and Succinic Acid are to contain mixed pelletization mutually.

Monomeric each component of solid detergent of the present invention and weight percent content are: sodium lauroyl sareosine 3-10%; Sodium lauryl sulphate 20-30%; A-sodium olefin sulfonate 15-20%; Succinic Acid or citric acid 20-30%; Sodium bicarbonate 20-30%; SPC-D 10-15%; Proteolytic enzyme 1-2%; Polyvinylpyrrolidone 0.2-2%; Disodium ethylene diamine tetraacetate 0.2-1%.

Claims (15)

1. solid detergent monomer that serves as disintegrating agent with the effervesce disintegrating component of breaking molecular equilibrium, it comprises tensio-active agent, washing auxiliary detergent and disintegrating component, the consumption that it is characterized in that at least a disintegrating component exceeds more than a times of its effervescent effect requirement, wherein the working substance content of a kind of tensio-active agent of consumption maximum is not less than 50%, described disintegrating component comprises Succinic Acid, and wherein used tensio-active agent α-sodium olefin sulfonate and Succinic Acid are to contain mixed pelletization mutually.

2. according to the solid detergent monomer of claim 1, wherein said tensio-active agent also comprises one or more in sodium lauroyl sareosine, sodium lauryl sulphate, distearyl dimethyl ammonium chloride, fatty alkanol amide, the plant erucicamide surface slip agent.

3. according to the solid detergent monomer of claim 1, wherein said tensio-active agent comprises the combination of sodium lauroyl sareosine and sodium lauryl sulphate, and the weight sum of these two kinds of components accounts for the 40%-70% of all solids washing composition monomer weight.

4. according to the solid detergent monomer of claim 1, wherein said tensio-active agent comprises the combination of α-sodium olefin sulfonate and sodium lauroyl sareosine.

5. the solid detergent monomer any according to claim 2-4, the monomeric weight of wherein single solid detergent are that density is between the 1g/ml-20g/ml between 0.3 gram-5 grams.

6. according to the solid detergent monomer of claim 5, the monomeric weight of wherein single solid detergent is that density is between the 1.07g/ml-6g/ml between 0.8 gram-1.5 grams.

7. according to the solid detergent monomer of claim 6, wherein less than the solids wash thing monomers of 5 grams after dropping into washing water, in 2 seconds-9 minutes, finish disintegration.

8. according to the solid detergent monomer of claim 7, wherein said washing auxiliary detergent comprises TA101 softening agent, HQS native protein, remove and hide in the agent one or more from,

9. solid detergent monomer according to Claim 8, wherein said disintegrating component also comprises one or more in sodium bicarbonate, Sodium peroxoborate, SPC-D, polyvinylpyrrolidone, citric acid, oxysuccinic acid, the tartrate.

10. according to the solid detergent monomer of claim 9, wherein said disintegrating component is the combination of Succinic Acid and sodium bicarbonate.

11. according to the solid detergent monomer of claim 1, wherein each component and weight percent content are: sodium lauroyl sareosine 3-10%; Sodium lauryl sulphate 20-30%; A-sodium olefin sulfonate 15-20%; Succinic Acid or citric acid 20-30%; Sodium bicarbonate 20-30%; SPC-D 10-15%; Proteolytic enzyme 1-2%; Polyvinylpyrrolidone 0.2-2%; Disodium ethylene diamine tetraacetate 0.2-1%.

12. according to the solid detergent monomer of claim 11, wherein said solid detergent monomer is spherical, avette, oval sphere, the positive cubic bodily form, long cube shaped, sheet shape, heart, cylindrical, no sharp cone distal, imitative animal shape, imitates cartoon figure's shape, imitates trade mark shape or imitative literal shape.

13. according to the solid detergent monomer of claim 12, pattern, safety notice, environmental mark, product operation instruction, safety instruction, trade mark, trading company, ripple, decorative pattern or picture that at least one surface of wherein said solid detergent monomer has projection or depression to show.

14. according to the solid detergent monomer of claim 13, the monomeric part particle of wherein said solid detergent, part surface or all surfaces are applied by pigment, dyestuff or other tinting materials.

15. the solid detergent monomer of above-mentioned any claim is used to the purposes of doing washing in washing machine.