CN105602746A - Phosphate-free detergent and production method thereof - Google Patents

Phosphate-free detergent and production method thereof Download PDF

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Publication number
CN105602746A
CN105602746A CN201610050024.7A CN201610050024A CN105602746A CN 105602746 A CN105602746 A CN 105602746A CN 201610050024 A CN201610050024 A CN 201610050024A CN 105602746 A CN105602746 A CN 105602746A
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CN
China
Prior art keywords
parts
phosphate
aeo
detergent
free
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201610050024.7A
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Chinese (zh)
Inventor
江道兴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHIZHOU HANNUOWEI ELECTROMECHANICAL DEVICE TECHNOLOGY Co Ltd
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CHIZHOU HANNUOWEI ELECTROMECHANICAL DEVICE TECHNOLOGY Co Ltd
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Priority to CN201610050024.7A priority Critical patent/CN105602746A/en
Publication of CN105602746A publication Critical patent/CN105602746A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a formula of phosphate-free detergent. The phosphate-free detergent is prepared from 150-170 parts of sodium dodecyl benzene sulfonate, 185-220 parts of light sodium carbonate, 95-115 parts of anhydrous sodium metasilicate, 32-46 parts of acrylic acid-maleic acid copolymer sodium salt, 15-28 parts of disodium ethylenediamine tetraacetate, 230-270 parts of alkyl modified dicarboxylate polymers, 1-3 parts of a fluorescent whitening agent, 145-170 parts of anhydrous sodium sulphate, 20-40 parts of fatty alcohol-polyoxyethylene ether AEO-3, 30-50 parts of fatty alcohol-polyoxyethylene ether AEO-9 and 1-2 parts of lemon essence. The phosphate-free detergent of the formula can effectively overcome the defect of a phosphate-substituted additive of existing phosphate-free detergent, and chelate most calcium, magnesium and iron ions in water, the effect is far better than that of a current 4A zeolite system, and the phosphate-free detergent has the advantages of being good in hard water resistance, capable of being dissolved fast, high in detergency, mild, free of stimulation and the like; moreover, the price of the phosphate-substituted additive in the phosphate-free detergent of the formula is lower than that of the 4A zeolite system, the phosphate-substituted additive is convenient to use and popularize on a large scale, and is the new direction of detergent phosphate-free additives in the future.

Description

A kind of non-phosphide detergent and production method thereof
Technical field
The present invention relates to a kind of non-phosphide detergent, belong to filed of daily-use chemical industry.
Background technology
Washing powder is our conventional daily necessities, and washing powder is divided into Powdered Detergent Containing Phosphate and non-phosphide detergent, phosphorous laundryPowder is taking phosphate as main auxiliary agent, and P elements easily causes environment water eutrophication, thereby destroys water quality, contaminated environment. NothingPhosphorus washing powder, without this shortcoming, is conducive to water body environment protection. For the health of our living environment, suggestion is used without phosphorus washingClothing powder. In current non-phosphide detergent, builder as substitute for phosphate is substantially all 4A system of zeolites, and 4A zeolite disadvantage is water insoluble,Cause calcium in chelating water, magnesium ion efficiency low, but also may cause some to be washed the damage of fabric. In addition 4A zeolite pair,In water, magnesium ion exchange velocity is slow, need to add high price alkaline assistant to make up, and this causes this non-phosphide detergent cost very high,Be difficult to promote the use of.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of anti-hard water good, dissolve fast, decontaminationNon-phosphide detergent and production method thereof that power is strong, gentleness is non-stimulated and cost is low.
A kind of non-phosphide detergent, described washing powder composition and composition proportion are as follows: neopelex 150-170Part, light sodium carbonate 185-220 part, anhydrous sodium metasilicate 95-115 part, acrylic acid-maleic acid sodium salt 32-46 part, secondEdetate disodium 15-28 part, alkyl-modified dicarboxylate polymer 230-270 part, fluorescent whitening agent 1-3 part, first brightPowder 145-170 part, AEO AEO-320-40 part, AEO AEO-930-50 part, lemonEssence 1-2 part.
Production method comprises the following steps:
(1) get raw material neopelex, light sodium carbonate, anhydrous sodium metasilicate, disodium ethylene diamine tetraacetate, fluorescence increasingWhite agent, glauber salt are placed in mix and blend in spiral ribbon mixer, obtain semi-finished product A.
(2) separately get AEO AEO-3 and AEO AEO-9 is heated to molten condition, willLemon extract joins in melt substance, stirs, and obtains mixture B.
(3) under the condition stirring, by acrylic acid-maleic acid sodium salt, alkyl-modified dicarboxylate polymerBe added drop-wise in semi-finished product A with mixture B, be stirred to that all liq composition is all absorbed and to be dry powder granular, make this laundryPowder.
Mixing time in step (1) is 2-3 minute.
Compared with the prior art, beneficial effect of the present invention is embodied in: this formulation product can effectively solve existing at presentThe defect of non-phosphide detergent builder as substitute for phosphate, acrylic acid-maleic acid sodium salt PMA-90 and disodium ethylene diamine tetraacetateEDTA-2Na coordinate the alkyl-modified dicarboxylate polymer of novel builder as substitute for phosphate can chelating water in most calcium, magnesium, ironIon, effect is much better than current 4A system of zeolites, have anti-hard water good, dissolve fast, strong detergency, the gentle spy such as non-stimulatedPoint, and builder as substitute for phosphate cost ratio 4A system of zeolites in this formulation product is low, is convenient to large-scale popularization and uses, and is to do washing from now onThe new direction of powder phosphorus-free adjuvant.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, but not office of protection scope of the present inventionBe limited to this.
Embodiment 1:
(1) get 160 parts of raw material neopelexes, 200 parts of light sodium carbonates, 100 parts of anhydrous sodium metasilicates, ethylenediamine tetraacetic157 parts of 20 parts of acetic acid disodiums, 2 parts of fluorescent whitening agents, glauber salt are placed in mix and blend in spiral ribbon mixer, and mixing time is 2-3Minute, obtain semi-finished product A1.
(2) separately get AEO AEO-330 part and AEO AEO-940 part is heated to meltMelt state, the lemon extract that is 1 by deal joins in melt substance, stirs, and obtains mixture B1.
(3), under the condition stirring, 40 parts of acrylic acid-maleic acid sodium salts, alkyl-modified dicarboxylate are gathered250 parts of compounds and mixture B1 are added drop-wise in semi-finished product A1, are stirred to that all liq composition is all absorbed and to be dry powder granular,Make this washing powder.
Embodiment 2:
(1) get 150 parts of raw material neopelexes, 210 parts of light sodium carbonates, 110 parts of anhydrous sodium metasilicates, ethylenediamine tetraacetic165 parts of 25 parts of acetic acid disodiums, 3 parts of fluorescent whitening agents, glauber salt are placed in mix and blend in spiral ribbon mixer, and mixing time is 2-3Minute, obtain semi-finished product A2.
(2) separately get AEO AEO-325 part and AEO AEO-935 part is heated to meltMelt state, the lemon extract that is 2 by deal joins in melt substance, stirs, and obtains mixture B2.
(3), under the condition stirring, 35 parts of acrylic acid-maleic acid sodium salts, alkyl-modified dicarboxylate are gathered240 parts of compounds and mixture B2 are added drop-wise in semi-finished product A2, are stirred to that all liq composition is all absorbed and to be dry powder granular,Make this washing powder.
Embodiment 3:
The present invention replaces the comparison of the dirt-removing power of STPP and 4A zeolite and similar products at home and abroad, taking standard washing powder as baseStandard, clean effect is as table 1.
Table 1
As table 1 experimental result data shows, the present invention is after cancelling 4A system of zeolites, and the dirt-removing power of novel builder as substitute for phosphate hasVery good performance, in dirt-removing power, surmount domestic 4A system of zeolites far away, with the dirt-removing power of STPP and BASFSubstantially be consistent.
Embodiment 4:
Under the same conditions, measure chelating ability and the dispersion force of formula of the present invention and STPP and similar products at home and abroad, withSTPP is standard, and specific experiment data are table 2.
Table 2
As the experimental data of table 2 shows, the chelating ability of formulation product of the present invention and dispersion force are all considerably beyond domestic itsHis like product, chelating effect is much better than current 4A system of zeolites, and the effect of demineralized water and anti-deposition is very good.
This formulation product can effectively solve the defect of current existing non-phosphide detergent builder as substitute for phosphate, acrylic acid-maleic acidCopolymer sodium salt PMA-90 and disodium ethylene diamine tetraacetate EDTA-2Na coordinate the alkyl-modified dicarboxylic acids of novel builder as substitute for phosphateSalt polymer can chelating water in most calcium, magnesium, iron ion, effect is much better than current 4A system of zeolites, has anti-hardWater-based is good, dissolving is fast, strong detergency, the gentle feature such as non-stimulated, and builder as substitute for phosphate cost ratio 4A in this formulation product boilsStone system is low, and be convenient to large-scale popularization and use, be the new direction of washing powder phosphorus-free adjuvant from now on.

Claims (3)

1. a non-phosphide detergent, is characterized in that: described washing powder composition and composition proportion are as follows: neopelex150-170 part, light sodium carbonate 185-220 part, anhydrous sodium metasilicate 95-115 part, acrylic acid-maleic acid sodium salt 32-46 parts, disodium ethylene diamine tetraacetate 15-28 part, alkyl-modified dicarboxylate polymer 230-270 part, fluorescent whitening agent 1-3Part, glauber salt 145-170 part, AEO AEO-320-40 part, AEO AEO-930-50Part, lemon extract 1-2 part.
2. a production method for non-phosphide detergent described in claim 1, is characterized in that: production method comprises the following steps:
(1) get raw material neopelex, light sodium carbonate, anhydrous sodium metasilicate, disodium ethylene diamine tetraacetate, fluorescence increasingWhite agent, glauber salt are placed in mix and blend in spiral ribbon mixer, obtain semi-finished product A;
(2) separately get AEO AEO-3 and AEO AEO-9 is heated to molten condition, by lemonEssence joins in melt substance, stirs, and obtains mixture B;
(3) under the condition stirring, by acrylic acid-maleic acid sodium salt, alkyl-modified dicarboxylate polymer and mixedCompound B is added drop-wise in semi-finished product A, is stirred to that all liq composition is all absorbed and to be dry powder granular, makes this washing powder.
3. the production method of described a kind of non-phosphide detergent according to claim 2, is characterized in that: stirring in step (1)The time of mixing is 2-3 minute.
CN201610050024.7A 2016-01-26 2016-01-26 Phosphate-free detergent and production method thereof Pending CN105602746A (en)

Priority Applications (1)

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CN201610050024.7A CN105602746A (en) 2016-01-26 2016-01-26 Phosphate-free detergent and production method thereof

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Application Number Priority Date Filing Date Title
CN201610050024.7A CN105602746A (en) 2016-01-26 2016-01-26 Phosphate-free detergent and production method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867688A (en) * 2017-03-13 2017-06-20 中山市绿浪助剂有限公司 A kind of phosphate-free synthesized detergent Builder
CN107687102A (en) * 2017-09-29 2018-02-13 界首市恒吉服饰有限责任公司 A kind of method of wool fiber dyeing
CN109652226A (en) * 2018-12-24 2019-04-19 广州市丽高洗涤用品有限公司 Easily whiten washing powder and preparation method thereof

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CN101617034A (en) * 2007-02-21 2009-12-30 Lg生活健康株式会社 Contain powder detergent of acidic water-soluble polymer and preparation method thereof
US20110052726A1 (en) * 2008-12-09 2011-03-03 The Clorox Company Solid-layered bleach compositions and methods of use
CN102660396A (en) * 2012-05-22 2012-09-12 河北永泰皮化化工有限公司 Fur fat removal agent
CN103911225A (en) * 2013-01-04 2014-07-09 埃科莱布美国股份有限公司 Solid tablet unit dose oven cleaner
CN103131554A (en) * 2013-02-01 2013-06-05 广东工业大学 Non-phosphorus washing auxiliary detergent and manufacture method thereof
CN103695194A (en) * 2013-11-28 2014-04-02 南通市通州区大达麻纺织有限公司 High density washing powder for fabric and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867688A (en) * 2017-03-13 2017-06-20 中山市绿浪助剂有限公司 A kind of phosphate-free synthesized detergent Builder
CN107687102A (en) * 2017-09-29 2018-02-13 界首市恒吉服饰有限责任公司 A kind of method of wool fiber dyeing
CN109652226A (en) * 2018-12-24 2019-04-19 广州市丽高洗涤用品有限公司 Easily whiten washing powder and preparation method thereof

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Application publication date: 20160525