CN106867688A - A kind of phosphate-free synthesized detergent Builder - Google Patents
A kind of phosphate-free synthesized detergent Builder Download PDFInfo
- Publication number
- CN106867688A CN106867688A CN201710145509.9A CN201710145509A CN106867688A CN 106867688 A CN106867688 A CN 106867688A CN 201710145509 A CN201710145509 A CN 201710145509A CN 106867688 A CN106867688 A CN 106867688A
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- weight portion
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- weight
- phosphate
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
Abstract
The present invention provides a kind of phosphate-free synthesized detergent Builder, is made up of the raw material of following weight portion：The weight portion of neopelex 24, the weight portion of disodium ethylene diamine tetraacetate 13, the weight portion of sodium succinate 57, the weight portion of acrylic acid maleic acid sodium salt 10 12, the weight portion of sodium metasilicate 10 12, the weight portion of zeolite 10 12, the weight portion of aloe extract 24, the weight portion of sodium perborate 8 10, the weight portion of sodium tripolyphosphate 68, the weight portion of sodium carbonate 23, the weight portion of anhydrous sodium metasilicate 79, the weight portion of sodium carboxymethylcellulose 12, the weight portion of bentonite 14 36, compared with prior art, the present invention has following beneficial effect：Most calcium, magnesium, iron ion in water can be chelated, effect is much better than current 4A system of zeolites, with hard water resistance property is good, dissolving fast, strong detergency, it is gentle non-stimulated the features such as, and builder as substitute for phosphate price in this formulation product is lower than 4A system of zeolites, it is easy to large-scale popularization to use, is the new direction of washing powder phosphorus-free adjuvant from now on.
Description
Technical field
The present invention is a kind of phosphate-free synthesized detergent Builder, belongs to washing powder technical field.
Background technology
Washing powder is one kind of synthetic detergent, is essential household supplies.Washing powder in the market is main
There are following three kinds of classification, differ from one another.1. regular powder and concentrated detergent powder：Regular powder, particle is big and loose, dissolving
Hurry up, foam is compared with horn of plenty, but detergency is relatively weak, be difficult rinsing, be generally suitable for hand washing；Concentrated detergent powder particle is small, close
Degree is big, and foam is less, but strong detergency（At least twice of regular powder）, it is easy to clean, economize on water, be generally applicable to machine
Wash.2. Powdered Detergent Containing Phosphate and non-phosphide detergent：Powdered Detergent Containing Phosphate is main auxiliary agent with phosphate, and P elements easily cause ambient water
Body eutrophication, so as to destroy water quality, pollutes environment.Non-phosphide detergent is conducive to water body environment to protect then without this shortcoming.3.
Enzymatic laundry powder and aromatized washing powder：Enzymatic laundry powder be exactly in washing powder added with enzyme, aromatized washing powder be exactly in washing powder plus
There is essence.Enzymatic laundry powder is to specific dirt（Such as fruit juice, ink, bloodstain, milk stain, gravy, cow's milk, soy sauce）Dispel tool
Have specific function, at the same some of which certain enzyme can also play it is sterilized, brighten, color protection increases the effect such as gorgeous.Aromatized washing powder exists
Allow clothing to distribute fragrance while meeting clean result, make one to feel more comfortable.
Although there is non-phosphide detergent in the market, in its formula or containing the composition for polluting environment, and
And detergency is limited, density is low, packed and transported high cost.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the present invention to provide a kind of phosphate-free synthesized detergent Builder, to solve the above-mentioned back of the body
The problem proposed in scape technology.
To achieve these goals, the present invention is to realize by the following technical solutions：A kind of phosphate-free synthesized detergent Builder, by
The raw material of following weight portion is constituted：Neopelex 2-4 weight portions, disodium ethylene diamine tetraacetate 1-3 weight portions, fourth two
Sour sodium 5-7 weight portions, acid-co-maleic acid sodium salt 10-12 weight portions, sodium metasilicate 10-12 weight portions, zeolite 10-12
Weight portion, aloe extract 2-4 weight portions, sodium perborate 8-10 weight portions, sodium tripolyphosphate 6-8 weight portions, sodium carbonate 2-3 weights
Amount part, anhydrous sodium metasilicate 7-9 weight portions, sodium carboxymethylcellulose 1-2 weight portions, bentonite 14-36 weight portions.
Further, the aloe in aloe extract is a kind of aloe, using McAnalley and Coats cold treatments
Method is extracted, will Chinese aloe leaf clean peeling, be milled to slurry, remove cellulosic, alcohol precipitation, centrifugal filtration, freeze-drying is finally made
Aloe extract in raw material.
Further, the bentonite is a kind of with bentonite as raw material, using the lamellar knot of montmorillonite in bentonite
Structure and its swelling in water or organic solvent colloid clay characteristic can be dispersed into, organic covering is inserted by ion exchange technique
Agent, the organobentonite being made.
Further, ammonia and water and carbon dioxide reaction generate the ammonium hydrogen carbonate of a molecule, then by ammonium hydrogen carbonate with
Sodium chloride reaction generation sodium acid carbonate precipitation and ammonium chloride, through being filtrated to get sodium bicarbonate solid, the sodium acid carbonate of generation are added
Thermal decomposition, the sodium carbonate in generation raw material.
Further, with quartzy rock dust and caustic soda as raw material, in autoclave, reacted under 0.6~1.0 MPa steam,
Sodium metasilicate in generation raw material.
Further, the weight portion of neopelex 4 is contained in the raw material of every 100 weight portion, every 100 weight portion
Contain the weight portion of disodium ethylene diamine tetraacetate 1 in raw material, the weight portion of sodium succinate 7 is contained in the raw material of every 100 weight portion, often
Contain the weight portion of acid-co-maleic acid sodium salt 10 in the raw material of 100 weight portions, contain in the raw material of every 100 weight portion
The weight portion of sodium metasilicate 12, contains the weight portion of zeolite 10 in the raw material of every 100 weight portion, reed is contained in the raw material of every 100 weight portion
The weight portion of luxuriant growth extract 4, contains the weight portion of sodium perborate 8 in the raw material of every 100 weight portion, contain in the raw material of every 100 weight portion
There is the weight portion of sodium tripolyphosphate 8, the weight portion of sodium carbonate 2 is contained in the raw material of every 100 weight portion, in the raw material of every 100 weight portion
Containing the weight portion of anhydrous sodium metasilicate 9, the weight portion of sodium carboxymethylcellulose 1, every 100 weight are contained in the raw material of every 100 weight portion
Contain the weight portion of bentonite 24 in the raw material of amount part.
Beneficial effects of the present invention：A kind of phosphate-free synthesized detergent Builder of the invention, can chelate most calcium in water, magnesium,
Iron ion, effect is much better than current 4A system of zeolites, with hard water resistance property is good, dissolving fast, strong detergency, gentle non-stimulated etc.
Builder as substitute for phosphate price in feature, and this formulation product is lower than 4A system of zeolites, is easy to large-scale popularization to use, and is to wash from now on
The new direction of clothing powder phosphorus-free adjuvant.
Specific embodiment
For technological means, creation characteristic, reached purpose and effect for making present invention realization are easy to understand, with reference to
Specific embodiment, is expanded on further the present invention.
The present invention provides a kind of technical scheme：A kind of phosphate-free synthesized detergent Builder, is made up of the raw material of following weight portion：Dodecane
Base benzene sulfonic acid sodium salt 2-4 weight portions, disodium ethylene diamine tetraacetate 1-3 weight portions, sodium succinate 5-7 weight portions, acrylic acid-maleic acid
Copolymer sodium salt 10-12 weight portions, sodium metasilicate 10-12 weight portions, zeolite 10-12 weight portions, aloe extract 2-4 weight portions,
Sodium perborate 8-10 weight portions, sodium tripolyphosphate 6-8 weight portions, sodium carbonate 2-3 weight portions, anhydrous sodium metasilicate 7-9 weight portions,
Sodium carboxymethylcellulose 1-2 weight portions, bentonite 14-36 weight portions.
Aloe in aloe extract is a kind of aloe, is extracted using McAnalley and Coats cold-treating processes, i.e.,
Chinese aloe leaf is cleaned into peeling, slurry is milled to, cellulosic is removed, alcohol precipitation, centrifugal filtration, freeze-drying is finally made in raw material
Aloe extract.
Bentonite is one kind with bentonite as raw material, using montmorillonite in bentonite lamellar structure and its can in water or
It is swelling in organic solvent to be dispersed into colloid clay characteristic, organic coverture is inserted by ion exchange technique, what is be made is organic
Bentonite.
Ammonia generates the ammonium hydrogen carbonate of a molecule with water and carbon dioxide reaction, then reacts ammonium hydrogen carbonate and sodium chloride
Generation sodium acid carbonate precipitation and ammonium chloride, through being filtrated to get sodium bicarbonate solid, the sodium acid carbonate heat resolve that will be generated, generation
Sodium carbonate in raw material.
With quartzy rock dust and caustic soda as raw material, in autoclave, reacted under 0.6~1.0 MPa steam, in generation raw material
Sodium metasilicate.
As one embodiment of the present of invention：Contain the weight of neopelex 4 in the raw material of every 100 weight portion
Part, the weight portion of disodium ethylene diamine tetraacetate 1 is contained in the raw material of every 100 weight portion, fourth two is contained in the raw material of every 100 weight portion
The weight portion of sour sodium 7, contains the weight portion of acid-co-maleic acid sodium salt 10, every 100 weight in the raw material of every 100 weight portion
Contain the weight portion of sodium metasilicate 12 in the raw material of part, the weight portion of zeolite 10, every 100 weight portion are contained in the raw material of every 100 weight portion
Raw material in contain the weight portion of aloe extract 4, in the raw material of every 100 weight portion contain the weight portion of sodium perborate 8, every 100 weight
Contain the weight portion of sodium tripolyphosphate 8 in the raw material of amount part, the weight portion of sodium carbonate 2, every 100 are contained in the raw material of every 100 weight portion
Contain the weight portion of anhydrous sodium metasilicate 9 in the raw material of weight portion, sodium carboxymethylcellulose 1 is contained in the raw material of every 100 weight portion
Weight portion, contains the weight portion of bentonite 24 in the raw material of every 100 weight portion.
As one embodiment of the present of invention：Most calcium, magnesium, iron ion in water can be chelated, effect is much better than mesh
Preceding 4A system of zeolites, with hard water resistance property is good, dissolving fast, strong detergency, it is gentle non-stimulated the features such as, and this formulation product
In builder as substitute for phosphate price it is lower than 4A system of zeolites, be easy to large-scale popularization to use, be the new side of washing powder phosphorus-free adjuvant from now on
To.
General principle of the invention and principal character and advantages of the present invention has been shown and described above, for this area skill
For art personnel, it is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing substantially from it is of the invention spirit or
In the case of essential characteristic, the present invention can be in other specific forms realized.Therefore, no matter from the point of view of which point, all should be by
Embodiment regards exemplary as, and is nonrestrictive, and the scope of the present invention is by appended claims rather than above stating
Bright restriction, it is intended that all changes fallen in the implication and scope of the equivalency of claim are included in the present invention
It is interior.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (6)
1. a kind of phosphate-free synthesized detergent Builder, it is characterised in that：It is made up of the raw material of following weight portion：Neopelex 2-4
Weight portion, disodium ethylene diamine tetraacetate 1-3 weight portions, sodium succinate 5-7 weight portions, acid-co-maleic acid sodium salt 10-
12 weight portions, sodium metasilicate 10-12 weight portions, zeolite 10-12 weight portions, aloe extract 2-4 weight portions, sodium perborate 8-10 weights
Amount part, sodium tripolyphosphate 6-8 weight portions, sodium carbonate 2-3 weight portions, anhydrous sodium metasilicate 7-9 weight portions, sodium carboxymethylcellulose
1-2 weight portions, bentonite 14-36 weight portions.
2. a kind of phosphate-free synthesized detergent Builder according to claim 1, it is characterised in that：Aloe in aloe extract is one kind
Aloe, is extracted using McAnalley and Coats cold-treating processes, will Chinese aloe leaf clean peeling, be milled to slurry, remove fine
Dimension matter, alcohol precipitation, centrifugal filtration, freeze-drying is finally made the aloe extract in raw material.
3. a kind of phosphate-free synthesized detergent Builder according to claim 1, it is characterised in that：The bentonite is one kind with bentonite
Be raw material, using montmorillonite in bentonite lamellar structure and its can in water or organic solvent it is swelling be dispersed into colloid glue
Grain characteristic, inserts organic coverture, the organobentonite being made by ion exchange technique.
4. a kind of phosphate-free synthesized detergent Builder according to claim 1, it is characterised in that：Ammonia is given birth to water and carbon dioxide reaction
Into the ammonium hydrogen carbonate of a molecule, then by ammonium hydrogen carbonate and sodium chloride reaction generation sodium acid carbonate precipitation and ammonium chloride, through filtering
Sodium bicarbonate solid is obtained, the sodium acid carbonate heat resolve that will be generated, the sodium carbonate in generation raw material.
5. a kind of phosphate-free synthesized detergent Builder according to claim 1, it is characterised in that：With quartzy rock dust and caustic soda as raw material,
In autoclave, reacted under 0.6~1.0 MPa steam, the sodium metasilicate in generation raw material.
6. a kind of phosphate-free synthesized detergent Builder according to claim 1, it is characterised in that：Contain in the raw material of every 100 weight portion
The weight portion of neopelex 4, contains the weight portion of disodium ethylene diamine tetraacetate 1, every 100 in the raw material of every 100 weight portion
Contain the weight portion of sodium succinate 7 in the raw material of weight portion, acid-co-maleic acid is contained in the raw material of every 100 weight portion
The weight portion of sodium salt 10, contains the weight portion of sodium metasilicate 12 in the raw material of every 100 weight portion, boiling is contained in the raw material of every 100 weight portion
The weight portion of stone 10, contains the weight portion of aloe extract 4 in the raw material of every 100 weight portion, contained in the raw material of every 100 weight portion
The weight portion of Boratex 8, contains the weight portion of sodium tripolyphosphate 8 in the raw material of every 100 weight portion, contain in the raw material of every 100 weight portion
There is the weight portion of sodium carbonate 2, the weight portion of anhydrous sodium metasilicate 9, the raw material of every 100 weight portion are contained in the raw material of every 100 weight portion
In contain the weight portion of sodium carboxymethylcellulose 1, in the raw material of every 100 weight portion contain the weight portion of bentonite 24.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710145509.9A CN106867688A (en) | 2017-03-13 | 2017-03-13 | A kind of phosphate-free synthesized detergent Builder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710145509.9A CN106867688A (en) | 2017-03-13 | 2017-03-13 | A kind of phosphate-free synthesized detergent Builder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106867688A true CN106867688A (en) | 2017-06-20 |
Family
ID=59170369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710145509.9A Pending CN106867688A (en) | 2017-03-13 | 2017-03-13 | A kind of phosphate-free synthesized detergent Builder |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280126A (en) * | 2008-05-26 | 2008-10-08 | 广州立白企业集团有限公司 | Modified bentonite and laundry powder |
| CN104371850A (en) * | 2014-11-19 | 2015-02-25 | 苏州佑君环境科技有限公司 | Non-phosphorus environmental-friendly washing powder and preparation method thereof |
| CN105602746A (en) * | 2016-01-26 | 2016-05-25 | 池州汉诺威机电设备科技有限公司 | Phosphate-free detergent and production method thereof |
| CN105802743A (en) * | 2014-12-30 | 2016-07-27 | 王宝燕 | Phosphorus-free hand-protecting washing powder |
-
2017
- 2017-03-13 CN CN201710145509.9A patent/CN106867688A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280126A (en) * | 2008-05-26 | 2008-10-08 | 广州立白企业集团有限公司 | Modified bentonite and laundry powder |
| CN104371850A (en) * | 2014-11-19 | 2015-02-25 | 苏州佑君环境科技有限公司 | Non-phosphorus environmental-friendly washing powder and preparation method thereof |
| CN105802743A (en) * | 2014-12-30 | 2016-07-27 | 王宝燕 | Phosphorus-free hand-protecting washing powder |
| CN105602746A (en) * | 2016-01-26 | 2016-05-25 | 池州汉诺威机电设备科技有限公司 | Phosphate-free detergent and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 侯冬岩等: ""芦荟的研究进展"", 《鞍山师范学院学报》 * |
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