CN103194339A - General non-phosphorus low-foam cleaning cream - Google Patents
General non-phosphorus low-foam cleaning cream Download PDFInfo
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- CN103194339A CN103194339A CN2013101423812A CN201310142381A CN103194339A CN 103194339 A CN103194339 A CN 103194339A CN 2013101423812 A CN2013101423812 A CN 2013101423812A CN 201310142381 A CN201310142381 A CN 201310142381A CN 103194339 A CN103194339 A CN 103194339A
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Abstract
The invention relates to cleaning cream suitable for clothes and hard surfaces. The cleaning cream comprises a soap base, fatty alcohol-polyoxyethylene ether, coconut oleic acid diethanolamine, a four-A molecular sieve, ethylene diamine tetraacetic acid (EDTA), sodium carbonate, sodium chloride, sodium carboxymethylcellulose, sodium metasilicate pentahydrate, an organic silicon defomaing agent, ethanol water with the concentration of 75-90 percent and essence. The cleaning cream product is mild, has no phosphorus, is high in infiltration capacity, can resist hard water and can be used for effectively removing various stubborn stains.
Description
Technical field
The present invention relates to a kind of cleansing cream, be specifically related to a kind of cleaning paste that is applicable to clothing and crust.
Background technology
Washing powder, washing cream are the clothes washing products of using always, cleansing cream is because own expansion of effective constituent is dispersed in the moisture auxiliary agent than the advantage of washing powder, it is faster to dissolve rate of dispersion than solid laundry powder in water, and dissolution rate is fast when therefore washing clothes, and washing effect is given full play to.
Washing composition is made up of main lotion and washing assistant and essence pigment etc.The main lotion of at present commercially available washing cream is generally tensio-active agent, and it normally is that the raw material chemosynthesis gets with the oil, and is not only expensive, and skin is had certain pungency.A kind of environment-friendly high-efficiency washing cream is namely disclosed as CN200410022472.3, its main lotion is that Sodium dodecylbenzene sulfonate and sodium lauryl sulphate are composite, washing assistant is that four A zeolites replace tripoly phosphate sodium STPP, but the content of four A zeolites is higher, be 10% ~ 20%, four A zeolites are synthetic, and its cost is higher.
Summary of the invention
The invention provides a kind of emulsification, strong, the anti-hard water of penetrating power, can effectively remove the without phosphorus low foaming cleaning paste that is applicable to clothing and crust of mild of multiple stain.
Technical scheme of the present invention is as follows:
Cleaning paste of the present invention comprises the raw material of following weight parts: aqueous ethanolic solution 2.5-3.5 part and essence 0.1-0.2 part of soap base 15-19.0 part, 2.0 parts of fatty alcohol-polyoxyethylene ether, 2.0 parts of coconut oil diethanolamine, four A molecular sieve 4.0-5.0 parts, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, silicone antifoam agent 0.3-0.5 part, 75-90%.
Soap base of the present invention comprises the raw material of following weight parts: 0.5 ~ 1.0 part in 20 ~ 25 parts of the aqueous sodium hydroxide solutions of 10 parts of Oleum Cocois, 10 parts of winterized stearins, 30 parts of oils extracted from rice husks, 25 ~ 30 parts of plam oils, 25-35% weight percent and sodium-chlor.
Soap base of the present invention comprises the raw material of following weight parts: 0.5 ~ 1.0 part of 10 parts of Oleum Cocois, 10 parts of winterized stearins, 30 parts of Oleum Gossypii semens, 25 ~ 30 parts of plam oils, the aqueous sodium hydroxide solution 20 ~ 25 of 25-35% weight percent, sodium-chlor.
The preparation method of cleaning paste of the present invention comprises the steps: to take by weighing the soap base of 15-19.0 weight part, 2.0 the fatty alcohol-polyoxyethylene ether of weight part (AEO-9), 2.0 the coconut oil diethanolamine of weight part, 4.0-5.0 four A molecular sieves of weight part, 0.5 the EDTA of weight part, 5.0 weight parts of sodium carbonate, 1.5 the sodium-chlor of weight part, 0.5 the Xylo-Mucine of weight part, 1.5 the metasilicate pentahydrate sodium of weight part, 0.3-0.5 the water of the silicone antifoam agent of weight part and 58.5 ~ 65.5 weight parts adds in the reactor, being warming up to 70-80 ℃ stirred 10-15 minute, when the gained mixture is cooled to 30 ~ 45 ℃, the aqueous ethanolic solution 2.5-3.5 weight part and the essence 0.1-0.2 weight part that add 75-90% are keeping being cooled to the paste solid after the packing under the 35-40 ℃ of temperature constant state.
Beneficial effect of the present invention:
The main lotion of cleansing cream of the present invention is soap base, it is got through simple saponification by natural fats and oils, therefore have better submissive effect usually, reduce damage to clothing and article, gentle to skin, and soap base generates oil-soluble calcium soap and has the bubble ability that presses down in hard water, thereby few, the easy rinse of foam, water-saving during laundry, saves time and laborsaving.
Cleansing cream of the present invention contains four A molecular sieves and EDTA as washing assistant.Four A molecular sieves are a kind of synthetic, have the silico-aluminate of microporous type cubic(al)grating.The Ca of washing assistant in can exchanged water
2+, Mg
2+Produce softening water, remove dirt and prevent soil redeposition.Four A molecular sieve content of the present invention are lower, are 4 ~ 5% only, are conducive to reduce cost.
Cleansing cream of the present invention contains yellow soda ash and sodium-chlor as disintegrating agent, and its adding can make decontamination paste of the present invention dissolve fast, and yellow soda ash and sodium-chlor is cheap.
Cleansing cream of the present invention contains the coconut oil diethanolamine, its be a kind of be the synthetic nonionogenic tenside of raw material with the Oleum Cocois, have significant thickening, foam enhancing, foam stability energy, and have significant emulsification, soil removability.
Cleansing cream of the present invention is oyster white or painted paste solid, slightly fragrant, can remove the spot on textiles or hard objects surface efficiently, bloodstain, animal oil, vegetables oil, mineral oil, ballpoint pen road, carbon pen road, chewing gum are all had significant washing cleaning effect.
The present invention can adopt homemade soap base as raw material, and homemade soap base is compared with commercially available soap base, and homemade soap base has better compatibility and economy.
Cleansing cream good stability of the present invention, proterties is stable under the environment of high temperature or low temperature.In the time of 40 ℃, placed 24 hours the lotion no change; In the time of-15 ℃, placed 24 hours lotion no change after the recovery room temperature.
Cleansing cream good stability of the present invention, low bubble, water-saving, easily dissolving and be not subjected to the influence of water temperature.
Embodiment
The using method of the decontamination paste for preparing in the embodiments of the invention is:
Deoil in the part: only need this product is covered pollution place, pinch local the doing of emphasis with two hands after ten minutes and rub with the hands, after the dissolving, water washes down and gets final product.
Whole washing: this product is coated on the clothing, and slightly overbrushing is a little in heavy dirty district such as neck, sleeve, pocket mouth, and with brush brush or hand rubbing or laundry machine washing, wash down can be neat and tidy for water then.
The cleaning of hard product such as appliance shell, household office appliance, kitchen countertop, lathe, car decorations, plastics etc.: with damp cotton be stained with this product a little, directly wiping on crust.
Concrete consumption can be regulated according to size and the degree of clothing and article, generally cleans shortage of money down jackets and needs the 25-40 gram.
Embodiment 1
Present embodiment adopts the configuration of following components by weight percent, 60.6 parts in 0.5 part of 18.2 parts of soap base, 2.0 parts of fatty alcohol-polyoxyethylene ether (AEO-9), 2.0 parts of coconut oil diethanolamine, 5.0 parts in four A molecular sieves, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, silicone antifoam agent, 75% 0.2 part in 2.5 parts of ethanol, essence and water.Wherein the soap base buying certainly: new east station of Guangzhou house oil fat chemical industry company limited.
The preparation method: with soap base, fatty alcohol-polyoxyethylene ether (AEO-9), coconut oil diethanolamine, four A molecular sieves, EDTA, yellow soda ash, sodium-chlor, Xylo-Mucine, metasilicate pentahydrate sodium, silicone antifoam agent and water according to said ratio, add reactor and be warming up to 70-80 ℃ of stirring 10-15 minute, when the gained mixture is cooled to 35 ℃ of left and right sides, add a certain amount of ethanol and essence according to above-mentioned weight proportion, after keeping being cooled to the paste solid after the can under 35 degrees centigrade of left and right sides temperature constant states, be packaged into finished product.
Result of use: large-area edible oil spot is arranged on the clothing, use the product of present embodiment to clean back spot noresidue, the clothing color and luster is as newly.
Embodiment 2
Adopt the synthetic soap base of following steps, take by weighing aqueous sodium hydroxide solution 20g, the sodium-chlor 0.5g of Oleum Cocois 10g, winterized stearin 10g, oil extracted from rice husks 30g, plam oil 30g, 25% weight percent.Above-mentioned raw materials is added in the reactor, is warming up to 80 ℃, reacted 1 hour, after the effluent discharge, both required soap base.
Get the soap base of above-mentioned steps gained, according to 59.5 parts in 0.3 part of 19 parts of soap base, 2.0 parts of fatty alcohol-polyoxyethylene ether (AEO-9), 2.0 parts of coconut oil diethanolamine, 5.0 parts in four A molecular sieves, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, silicone antifoam agent, 90% 0.2 part in 3 parts of ethanol, essence and water, take by weighing required compound.
With soap base, fatty alcohol-polyoxyethylene ether (AEO-9), coconut oil diethanolamine, four A molecular sieves, EDTA, yellow soda ash, sodium-chlor, Xylo-Mucine, metasilicate pentahydrate sodium, silicone antifoam agent and water according to said ratio, add in the reactor warm to 80 ℃ of stirrings 15 minutes, when the gained mixture is cooled to 30 ℃, add a certain amount of ethanol and essence according to above-mentioned weight proportion, be cooled to paste solids package finished product after the can under the temperature constant state of 30 ℃ of maintenances.
Result of use: large-area vegetables oil spot is arranged on the kitchen countertop, use the product of present embodiment to clean back spot noresidue, the clothing color and luster is as newly.
Embodiment 3
Adopt the synthetic soap base of following steps, take by weighing aqueous sodium hydroxide solution 25g, the sodium-chlor 1.0g of Oleum Cocois 10g, winterized stearin 10g, rapeseed oil 30g, plam oil 25g, 35% weight percent.Above-mentioned raw materials is added in the reactor, is warming up to 100 ℃, reacted 40 minutes, after the effluent discharge, both required soap base.
Get the soap base of above-mentioned steps gained, according to 60.2 parts in 18.2 parts of soap bases, 2.0 parts of fatty alcohol-polyoxyethylene ether (AEO-9), 2.0 parts of coconut oil diethanolamine, 5.0 parts in four A molecular sieves, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, 0.5 part of defoamer, 3.0 parts of ethanol, 0.1 part in essence and water, take by weighing required compound.
With soap base, fatty alcohol-polyoxyethylene ether (AEO-9), coconut oil diethanolamine, four A molecular sieves, EDTA, yellow soda ash, sodium-chlor, Xylo-Mucine, metasilicate pentahydrate sodium, silicone antifoam agent and water according to said ratio, add in the reactor warm to 75 ℃ of stirrings 10 minutes, when the gained mixture is cooled to 40 ℃, add a certain amount of ethanol and essence according to above-mentioned weight proportion, keeping being cooled to paste solids package finished product after the can under 40 ℃ of temperature constant states.
Result of use: large-area mineral oil spot is arranged on the clothing, use the product of present embodiment to clean back spot noresidue, the clothing color and luster is as newly.
Embodiment 4
Present embodiment adopts the configuration of following components by weight percent, 65 parts in 0.3 part of 15 parts of soap base, 2.0 parts of fatty alcohol-polyoxyethylene ether (AEO-9), 2.0 parts of coconut oil diethanolamine, 4 parts in four A molecular sieves, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, silicone antifoam agent, 90% 0.2 part in 2.5 parts of aqueous ethanolic solutions, essence and water.Wherein the soap base buying is from Dongnan Chemical Industry Co., Ltd. Hangzhou.
The preparation method: with soap base, fatty alcohol-polyoxyethylene ether (AEO-9), coconut oil diethanolamine, four A molecular sieves, EDTA, yellow soda ash, sodium-chlor, Xylo-Mucine, metasilicate pentahydrate sodium, silicone antifoam agent and water according to said ratio, add reactor and be warming up to 75 ℃ of stirrings 15 minutes, when the gained mixture is cooled to 40 ℃ of left and right sides, add a certain amount of ethanol and essence according to above-mentioned weight proportion, after keeping being cooled to the paste solid after the can under 40 ℃ of left and right sides temperature constant states, be packaged into finished product.
Result of use: large-area edible oil spot is arranged on the clothing, use the product of present embodiment to clean back spot noresidue, the clothing color and luster is as newly.
Embodiment 5
Present embodiment adopts the configuration of following components by weight percent, 0.4 part of 17 parts of soap base, 2.0 parts of fatty alcohol-polyoxyethylene ether (AEO-9), 2.0 parts of coconut oil diethanolamine, 4.5 parts in four A molecular sieves, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, silicone antifoam agent, 0.1 part and 62 parts water of 3 parts of aqueous ethanolic solutions, essence of 80%.Wherein soap base buying from Shijiazhuang clean beautiful chemical industry company limited.
The preparation method: with soap base, fatty alcohol-polyoxyethylene ether (AEO-9), coconut oil diethanolamine, four A molecular sieves, EDTA, yellow soda ash, sodium-chlor, Xylo-Mucine, metasilicate pentahydrate sodium, silicone antifoam agent and water according to said ratio, add reactor and be warming up to 75 ℃ of stirrings 15 minutes, when the gained mixture is cooled to 40 ℃ of left and right sides, add a certain amount of ethanol and essence according to above-mentioned weight proportion, after keeping being cooled to the paste solid after the can under 35 ℃ of left and right sides temperature constant states, be packaged into finished product.
Result of use: large-area chicken blood stains stain is arranged on the clothing, use the product of present embodiment to clean back spot noresidue, the clothing color and luster is as newly.
Claims (4)
1. a universal without phosphorus low bubble cleaning paste is characterized in that it comprises the raw material of following weight parts: aqueous ethanolic solution 2.5-3.5 part and essence 0.1-0.2 part of soap base 15.0-19.0 part, 2.0 parts of fatty alcohol-polyoxyethylene ether, 2.0 parts of coconut oil diethanolamine, four A molecular sieve 4.0-5.0 parts, 0.5 part of EDTA, 5.0 parts in yellow soda ash, 1.5 parts in sodium-chlor, 0.5 part of Xylo-Mucine, 1.5 parts of metasilicate pentahydrate sodiums, silicone antifoam agent 0.3-0.5 part, 75-90%.
2. a kind of universal without phosphorus low bubble cleaning paste according to claim 1 is characterized in that described soap base comprises the raw material of following weight parts: 0.5 ~ 1.0 part in 20 ~ 25 parts of the aqueous sodium hydroxide solutions of 10 parts of Oleum Cocois, 10 parts of winterized stearins, 30 parts of oils extracted from rice husks, 25 ~ 30 parts of plam oils, 25-35% weight percent and sodium-chlor.
3. a kind of universal without phosphorus low bubble cleaning paste according to claim 1 is characterized in that described soap base comprises the raw material of following weight parts: 0.5 ~ 1.0 part in the aqueous sodium hydroxide solution 20 ~ 25 of 10 parts of Oleum Cocois, 10 parts of winterized stearins, 30 parts of Oleum Gossypii semens, 25 ~ 30 parts of plam oils, 25-35% weight percent and sodium-chlor.
4. one kind prepares the preparation method who cleans paste as any described universal without phosphorus low bubble in the claim 1 ~ 3, it is characterized in that it comprises the steps: to take by weighing the soap base of 15.0-19.0 weight part, 2.0 the fatty alcohol-polyoxyethylene ether of weight part, 2.0 the coconut oil diethanolamine of weight part, 4.0-5.0 four A molecular sieves of weight part, 0.5 the EDTA of weight part, 5.0 weight parts of sodium carbonate, 1.5 the sodium-chlor of weight part, 0.5 the Xylo-Mucine of weight part, 1.5 the metasilicate pentahydrate sodium of weight part, 0.3-0.5 the water of the silicone antifoam agent of weight part and 58.5 ~ 65.5 weight parts adds in the reactor, being warming up to 70-80 ℃ stirred 10-15 minute, when the gained mixture is cooled to 30 ~ 45 ℃, the aqueous ethanolic solution 2.5-3.5 weight part and the essence 0.1-0.2 weight part that add 75-90% are keeping being cooled to the paste solid after the packing under the 35-40 ℃ of temperature constant state.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013101423812A CN103194339A (en) | 2013-04-23 | 2013-04-23 | General non-phosphorus low-foam cleaning cream |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013101423812A CN103194339A (en) | 2013-04-23 | 2013-04-23 | General non-phosphorus low-foam cleaning cream |
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| CN103194339A true CN103194339A (en) | 2013-07-10 |
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| CN2013101423812A Pending CN103194339A (en) | 2013-04-23 | 2013-04-23 | General non-phosphorus low-foam cleaning cream |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104450252A (en) * | 2014-11-19 | 2015-03-25 | 苏州佑君环境科技有限公司 | Environment-friendly purification washing paste and preparation method thereof |
| CN107400574A (en) * | 2017-07-17 | 2017-11-28 | 安徽华翎羽毛制品有限公司 | A kind of badminton head detergent |
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| CN101012416A (en) * | 2007-02-13 | 2007-08-08 | 买德颐 | Decontamination contaminant releasing washing plaster |
| CN102115695A (en) * | 2010-01-05 | 2011-07-06 | 哈尔滨理工大学 | Environmentally-friendly phosphorous-free washing cream and preparation method thereof |
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2013
- 2013-04-23 CN CN2013101423812A patent/CN103194339A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101012416A (en) * | 2007-02-13 | 2007-08-08 | 买德颐 | Decontamination contaminant releasing washing plaster |
| CN102115695A (en) * | 2010-01-05 | 2011-07-06 | 哈尔滨理工大学 | Environmentally-friendly phosphorous-free washing cream and preparation method thereof |
| CN102676326A (en) * | 2012-05-16 | 2012-09-19 | 济南大学 | Method for producing phosphorus-free pulpy detergent by comprehensively utilizing 4A zeolite and production liquid waste thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104450252A (en) * | 2014-11-19 | 2015-03-25 | 苏州佑君环境科技有限公司 | Environment-friendly purification washing paste and preparation method thereof |
| CN107400574A (en) * | 2017-07-17 | 2017-11-28 | 安徽华翎羽毛制品有限公司 | A kind of badminton head detergent |
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Application publication date: 20130710 |
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