CN108004054A - A kind of compliance function particle for washing powder and preparation method thereof - Google Patents
A kind of compliance function particle for washing powder and preparation method thereof Download PDFInfo
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- CN108004054A CN108004054A CN201711386849.7A CN201711386849A CN108004054A CN 108004054 A CN108004054 A CN 108004054A CN 201711386849 A CN201711386849 A CN 201711386849A CN 108004054 A CN108004054 A CN 108004054A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Abstract
The invention discloses a kind of compliance function particle for washing powder, it is characterised in that by weight, is made of following component：Modified alta-mud 74 ~ 94%；Sodium citrate 5 ~ 25%；Modified polyorganosiloxane 1 ~ 10%.The compliance function particle for washing powder of the present invention can not only strengthen the dirt-removing power of detergent, but also have excellent submissive effect so that clothes can be done softness processing by washing powder while laundry takes, and achieve significant effect.
Description
Technical field
The present invention relates to a kind of compliance function particle for washing powder and preparation method thereof, belong to daily article for washing skill
Art field.
Background technology
In the prior art, washing powder is for the purpose of decontamination, cleaning, and domestic huge portion washes agent is anion at present
Surfactant is as main active substances.And softener is so that the fabric after washing can feel soft, comfortable, softener is main
It is cationic surfactant.Therefore, existing washing powder（Or cleaning solution, detergent）It cannot make at the same time with softener
With otherwise yin, yang surfactant can react and cause washing powder to fail.And people use machine substantially at present（Wash
Clothing machine）To wash clothing, washing powder（Detergent）Washing process cannot be added at the same time with softener brings larger puzzlement.
On the other hand, bentonite resource species in China's is enriched, and reserves are huge, due to the distinctive nanoscale stratiform knot of bentonite
Structure, assigns its good thixotropy, suspension, the performance such as slow release and adsorptivity, can be significantly reduced in washing process
Friction factor between fabric fibre, fiber is freely stretched and be not easy to cohere it is agglomerating, play softening fabrics enhancing washing effect
Effect.However, existing bentonite is used to lift submissive effect unobvious in detergent.For above-mentioned technical problem, ability
The technical staff in domain is improved.For example, Chinese invention patent application CN101280126A discloses a kind of modified alta-mud,
It is made of the cationic surfactant of bentonite and macromolecular steric configuration, and the cation form of the macromolecular steric configuration
Face activating agent carries the quaternary ammonium salt of functional group to be connected with 2 or more than 2 Long carbon chain groups on N atoms, and on these Long carbon chains
Cationic surfactant；The modified alta-mud is 2 ~ 20% in the weight percent content of washing powder so that the washing powder of system
Submissive effect can be further protruded at the same time with good clean effect.However, it is demonstrated experimentally that above-mentioned pass through quaternary ammonium salt cationic
Surfactant-modified bentonite dissolves scattered poor, actually to play a role quaternary cationics in water
Less, submissive effect is limited.
Further, since bentonite contains substantial amounts of calcium/magnesium ion, the dirt-removing power of detergent can be influenced.Therefore, it is swollen at present
Profit soil is applied in industry is washed faces larger difficulty.
Therefore, a kind of compliance function particle for washing powder with excellent dissolution dispersiveness is developed so that washing powder
Clothes can be done into softness processing while laundry takes, it is clear that there is the positive effect of reality.
The content of the invention
The goal of the invention of the present invention is to provide a kind of compliance function particle for washing powder and preparation method thereof.
To achieve the above object of the invention, the technical solution adopted by the present invention is：A kind of compliance function grain for washing powder
Son, by weight, is made of following component：
Modified alta-mud 74 ~ 94%
Sodium citrate 5 ~ 25%
Modified polyorganosiloxane 1 ~ 10%；
Wherein, the method for preparing modified bentonite is as follows：
The first step：Bentonite material is crushed to 200 ~ 325 mesh, wherein bentonite material is calcium-base bentonite or sodium bentonite
It is one or two kinds of；
Second step：Bentonite material after crushing is added into water slurrying, concentration is 10 ~ 20%, makes bentonite water suction disintegration, then
It is placed in sand mill, and adds the first inorganic modifier, is stirred, bentonite is fully peeled off into monocrystalline tablet, sand
When time consuming 1 ~ 6 is small；Obtain that slurry is sanded；
First inorganic modifier is the molar ratio of inorganic sodium and the mixture of inorganic lithium salt, inorganic sodium and inorganic lithium salt
For 20：1~1：10；One or more of the inorganic sodium in sodium carbonate, sodium fluoride, sodium chloride, the inorganic lithium salt choosing
From one or both of lithium carbonate, lithium fluoride；
By weight, the first inorganic modifier dosage is the 1 ~ 10% of bentonite material；
3rd step：The second inorganic modifier, high speed dispersion hybrid reaction, 10 ~ 30min of time are added in above-mentioned sand milling slurry；
The one kind of second inorganic modifier in sodium pyrophosphate, sodium trimetaphosphate, four sodium metaphosphates and calgon
It is or several；
By weight, the second inorganic modifier dosage is the 0.05 ~ 1% of bentonite material；
4th step：The slurry is centrifuged, takes upper slurry, it is dry, as obtain modified alta-mud.
Above, the bentonite material in the first step is preferably sodium bentonite.
The present invention is by bentonite modification for composite, removing the impurity in bentonite and at utmost reducing bentonite
The content of middle calcium/magnesium ion, strengthens its sequestering power to calcium ions and magnesium ions in hard water；Then modified polyorganosiloxane and lemon are added
Sour sodium, effectively improves particle rate of dispersion and softness in water.Modified siloxane is with modified alta-mud in washing process
In have well synergistic effect.Modified alta-mud can wrap up modified polyorganosiloxane, reduce modified polyorganosiloxane and washing
During loss, help it to be adsorbed onto on clothing, strengthen and wash submissive effect.Disintegration rate is fast in water for sodium citrate, can
To improve the dispersing and dissolving performance of particle in water, further promote the detergency ability of detergent.
In above-mentioned technical proposal, in the method for preparing modified bentonite, in its 4th step using centrifuge carry out from
The heart, the rotating speed of centrifuge is 1000 ~ 6000 turns/min.
In above-mentioned technical proposal, the modified polyorganosiloxane be selected from amino modified polysiloxane, hydroxyl modification polysiloxanes,
Carboxy-modified polysiloxanes, Siloxane-Oxyalkylene Copolymers, epoxy alkyl modified polyorganosiloxane and polyethers-amino-epoxy base-carboxyl
One or more in comodified polysiloxane.
Preferably, the modified polyorganosiloxane is selected from amino modified polysiloxane, hydroxyl modification polysiloxanes, carboxy-modified
Polysiloxanes, Siloxane-Oxyalkylene Copolymers, epoxy alkyl modified polyorganosiloxane and polyethers-amino-epoxy base-carboxyl are modified poly- altogether
One or more in siloxanes.More optimize, the modified polyorganosiloxane for amino modified polysiloxane or polyethers-amino-
Epoxy group-carboxyl comodified polysiloxane.
Preferably, by weight, it is made of following component：
Modified alta-mud 74 ~ 94%
Sodium citrate 5 ~ 25%
Modified polyorganosiloxane 1 ~ 10%.
Preferably, the compliance function particle is the particle of 10 ~ 60 mesh.
Preferably, the ratio of the modified polyorganosiloxane is 2 ~ 5%.
A kind of preparation method of the compliance function particle for washing powder, including following step is claimed in the present invention at the same time
Suddenly：
The first step：Bentonite material is crushed to 200 ~ 325 mesh, wherein bentonite material is calcium-base bentonite or sodium bentonite
It is one or two kinds of；
Second step：Bentonite material after crushing is added into water slurrying, concentration is 10 ~ 20%, makes bentonite water suction disintegration, then
It is placed in sand mill, and adds the first inorganic modifier, is stirred, bentonite is fully peeled off into monocrystalline tablet, sand
When time consuming 1 ~ 6 is small；Obtain that slurry is sanded；
First inorganic modifier is the molar ratio of inorganic sodium and the mixture of inorganic lithium salt, inorganic sodium and inorganic lithium salt
For 20：1~1：10；One or more of the inorganic sodium in sodium carbonate, sodium fluoride, sodium chloride, the inorganic lithium salt choosing
From one or both of lithium carbonate, lithium fluoride；
By weight, the first inorganic modifier dosage is the 1 ~ 10% of bentonite material；
3rd step：The second inorganic modifier, high speed dispersion hybrid reaction, 10 ~ 30min of time are added in above-mentioned sand milling slurry；
The one kind of second inorganic modifier in sodium pyrophosphate, sodium trimetaphosphate, four sodium metaphosphates and calgon
It is or several；
By weight, the second inorganic modifier dosage is the 0.05 ~ 1% of bentonite material；
4th step：The slurry is centrifuged, takes upper slurry, obtains modified alta-mud slurry；
5th step：Sodium citrate, modified polyorganosiloxane are proportionally added into above-mentioned modified alta-mud slurry, are sufficiently mixed；
To mixture；
6th step：It is 20 ~ 50% by said mixture drying to moisture, is then granulated, the particle made is sent to stream
Change and be dried in bed, sieved, you can obtain the compliance function particle.
Above, the bentonite material in the first step is preferably sodium bentonite.
Preferably, the compliance function particle is the particle of 10 ~ 60 mesh.
Preferably, in the 6th step, drying temperature is 100 ~ 200 degrees Celsius.
A kind of washing powder is claimed at the same time in the present invention, and containing the above-mentioned compliance function particle for washing powder, this is soft
Suitable functional particles are 10 ~ 20% in the weight percent content of washing powder.
Since above-mentioned technical proposal is used, the present invention has following advantages compared with prior art：
1st, the present invention develops a kind of new compliance function particle for washing powder, which can not only strengthen
The dirt-removing power of detergent, and there is excellent submissive effect so that washing powder can make clothes while laundry takes soft
Sofening treatment, achieves significant effect；Experiment proves：Relative to the prior art（CN101280126A）, the present invention with
More preferably submissive effect while, also improve the dirt-removing power of detergent, thus with more practicality；
2nd, compliance function particle of the invention has the advantages that fast dissolution velocity, softening of water and submissive performance are good, not only has
Stronger calcium ions and magnesium ions sequestering power, has preferable synergistic effect with the active material in detergent, improves the decontamination of detergent
Ability, while can significantly reduce the friction factor between fabric fibre in washing process, enables fiber freely to stretch
Open up and be not easy to cohere agglomerating, play the role of softening fabrics, make the clothing after washing that there is good compliance；
3rd, preparation method of the invention is simple and practicable, and cost is relatively low, suitable for promoting and applying.
Embodiment
The present invention is further described with reference to embodiment.
Embodiment one
A kind of compliance function particle for washing powder, by weight, is made of following component：Modified alta-mud 90%, citric acid
Sodium 5%, modified polyorganosiloxane 5%.
Wherein, the first inorganic modifier chooses sodium carbonate during prepared by modified alta-mud：Lithium carbonate=10：1, dosage is swelling
The 3% of native total amount；Second inorganic modifier chooses sodium pyrophosphate, and dosage is the 0.2% of bentonite total amount；Modified polyorganosiloxane selects
Amino modified polysiloxane and hydroxyl modification polysiloxane mixture.The preparation method of above-mentioned compliance function particle is as follows：
The first step：Bentonite mineral are crushed to 200 ~ 325 mesh, wherein bentonite material is sodium bentonite；
Second step：The bentonite material of crushing is added into water slurrying, concentration is 10 ~ 20%, makes bentonite water suction disintegration, is placed in sand milling
In machine, and the first inorganic modifier is added, carry out mechanical agitation so that bentonite fully peels off into monocrystalline tablet, and the time 1 is sanded
~ 6 it is small when；
3rd step：Slurry after sand milling is added into the second inorganic modifier, and high speed dispersion hybrid reaction, 10 ~ 30min of time；
4th step：Modified slurry is centrifuged, 1000 ~ 6000 turns/min of centrifuge speed；Upper slurry is taken to be modified
Bentonite slurry is spare；
5th step：Sodium citrate, modified polyorganosiloxane are sequentially added in modified alta-mud slurry in proportion, are sufficiently mixed anti-
Should, when the time 1 ~ 3 is small；
6th step：Mixture drying to moisture is sent to comminutor for 20 ~ 50% and is granulated, the particle made is sent to fluidisation
It is dried in bed, 100 ~ 200 degrees Celsius of drying temperature, is sieved by 10 ~ 60 mesh sieve nets, packs 10 ~ 60 mesh particles.Its
Particle product index test result is：
Then the functional particles of the present embodiment are added in national standard washing powder, part by weight is particle：National standard washing powder=5：
100；Obtain the washing powder of the present embodiment one.Then detergency ability test is carried out, and it is special with national standard washing powder, addition Chinese invention
The washing powder of modified alta-mud described in profit application CN101280126A（Part by weight is modified alta-mud：National standard washing powder=5：
100）（The washing powder is denoted as comparative example one）Contrasted, as a result for：
Then submissive performance test is carried out, method is as follows：Experiment takes 20 towels every time, uses automatic washing machine, washing one
It is secondary（10min）, rinse 2 times（5min）, naturally dry, as a result for：
Note：Difference is bigger, represents that sample bulkiness is better.
In terms of above-mentioned 3 forms can be seen that compliance, the compliance of embodiment one is far better than un-added national standard
Washing powder, is also slightly improved compared to comparative example one；With the increase of washing times, the compliance of embodiment gradually steps up, and not
Add the sample of particle washing（National standard washing powder）Compliance gradually reduces, and submissive sex differernce is more obvious after washing three times；And
It is more poor than embodiment must to improve degree for compliance after comparative example one is washed three times.Compared to comparative example one and national standard washing powder, implement
Example washing after bulkiness more preferably.
Embodiment two
A kind of compliance function particle for washing powder, by weight, is made of following component：Modified alta-mud 88%, citric acid
Sodium 10%, modified polyorganosiloxane 2%.
Wherein, the first inorganic modifier chooses sodium carbonate during prepared by modified alta-mud：Lithium carbonate=1：1, dosage is bentonite
The 3% of total amount；Second inorganic modifier chooses sodium pyrophosphate, and dosage is the 0.2% of bentonite total amount；Modified polyorganosiloxane selects ammonia
Base modified polyorganosiloxane and hydroxyl modification polysiloxane mixture.The preparation method of above-mentioned compliance function particle is as follows：
The first step：Bentonite mineral are crushed to 200 ~ 325 mesh, wherein bentonite material is sodium bentonite；
Second step：The bentonite material of crushing is added into water slurrying, concentration is 10 ~ 20%, makes bentonite water suction disintegration, is placed in sand milling
In machine, and the first inorganic modifier is added, carry out mechanical agitation so that bentonite fully peels off into monocrystalline tablet, and the time 1 is sanded
~ 6 it is small when；
3rd step：Slurry after sand milling is added into the second inorganic modifier, and high speed dispersion hybrid reaction, 10 ~ 30min of time；
4th step：Modified slurry is centrifuged, 1000 ~ 6000 turns/min of centrifuge speed；Upper slurry is taken to be modified
Bentonite slurry is spare；
5th step：Sodium citrate, modified polyorganosiloxane are sequentially added in modified alta-mud slurry in proportion, are sufficiently mixed anti-
Should, when the time 1 ~ 3 is small；
6th step：Mixture drying to moisture is sent to comminutor for 20 ~ 50% and is granulated, the particle made is sent to fluidisation
It is dried in bed, 100 ~ 200 degrees Celsius of drying temperature, is sieved by 10 ~ 60 mesh sieve nets, packs 10 ~ 60 mesh particles.Its
Particle product index test result is：
Then the functional particles of the present embodiment are added in national standard washing powder, part by weight is particle：National standard washing powder=5：
100；Obtain the washing powder of the present embodiment two.Then detergency ability test is carried out, and it is special with national standard washing powder, addition Chinese invention
The washing powder of modified alta-mud described in profit application CN101280126A（Part by weight is modified alta-mud：National standard washing powder=5：
100）（The washing powder is denoted as comparative example two）Contrasted, as a result for：
Then submissive performance test is carried out, method is as follows：Experiment takes 20 towels every time, uses automatic washing machine, washing one
It is secondary（10min）, rinse 2 times（5min）, naturally dry, as a result for：
Note：Difference is bigger, represents that sample bulkiness is better.
In terms of above-mentioned 3 forms can be seen that compliance, the compliance of embodiment is washed far better than un-added national standard
Clothing powder, is also slightly improved compared to comparative example；With the increase of washing times, the compliance of embodiment gradually steps up, and is not added with
The sample of particle washing（National standard washing powder）Compliance gradually reduces, and submissive sex differernce is more obvious after washing three times；And contrast
It is more poor than embodiment must to improve degree for compliance after example washing three times.Compared to comparative example and national standard washing powder, after embodiment washing
Bulkiness is more preferably.
The specific embodiment is invented above, for those skilled in the art it is readily apparent that not
Can be as many other change and deformation, therefore, the appended claims purport in the case of the spirit and scope of the present invention
Covering all such changes and modification in the scope of the invention.
Claims (10)
1. a kind of compliance function particle for washing powder, it is characterised in that by weight, be made of following component：
Modified alta-mud 74 ~ 94%
Sodium citrate 5 ~ 25%
Modified polyorganosiloxane 1 ~ 10%；
Wherein, the method for preparing modified bentonite is as follows：
The first step：Bentonite material is crushed to 200 ~ 325 mesh, wherein bentonite material is calcium-base bentonite or sodium bentonite
It is one or two kinds of；
Second step：Bentonite material after crushing is added into water slurrying, concentration is 10 ~ 20%, makes bentonite water suction disintegration, then
It is placed in sand mill, and adds the first inorganic modifier, is stirred, bentonite is fully peeled off into monocrystalline tablet, sand
When time consuming 1 ~ 6 is small；Obtain that slurry is sanded；
First inorganic modifier is the molar ratio of inorganic sodium and the mixture of inorganic lithium salt, inorganic sodium and inorganic lithium salt
For 20：1~1：10；One or more of the inorganic sodium in sodium carbonate, sodium fluoride, sodium chloride, the inorganic lithium salt choosing
From one or both of lithium carbonate, lithium fluoride；
By weight, the first inorganic modifier dosage is the 1 ~ 10% of bentonite material；
3rd step：The second inorganic modifier, high speed dispersion hybrid reaction, 10 ~ 30min of time are added in above-mentioned sand milling slurry；
The one kind of second inorganic modifier in sodium pyrophosphate, sodium trimetaphosphate, four sodium metaphosphates and calgon
It is or several；
By weight, the second inorganic modifier dosage is the 0.05 ~ 1% of bentonite material；
4th step：The slurry is centrifuged, takes upper slurry, it is dry, as obtain modified alta-mud.
2. the compliance function particle according to claim 1 for washing powder, it is characterised in that：The modified alta-mud
In preparation method, centrifuged in its 4th step using centrifuge, the rotating speed of centrifuge is 1000 ~ 6000 turns/min.
3. the compliance function particle according to claim 1 for washing powder, it is characterised in that：The modified polyorganosiloxane
Selected from amino modified polysiloxane, hydroxyl modification polysiloxanes, carboxy-modified polysiloxanes, Siloxane-Oxyalkylene Copolymers, epoxy
One or more in alkyl-modified polysiloxanes and polyethers-amino-epoxy base-carboxyl comodified polysiloxane.
4. the compliance function particle according to claim 3 for washing powder, it is characterised in that：The modified polyorganosiloxane
Selected from amino modified polysiloxane, hydroxyl modification polysiloxanes, carboxy-modified polysiloxanes, Siloxane-Oxyalkylene Copolymers, epoxy
One or more in alkyl-modified polysiloxanes and polyethers-amino-epoxy base-carboxyl comodified polysiloxane.
5. the compliance function particle according to claim 1 for washing powder, it is characterised in that：By weight, by as follows
Component forms：
Modified alta-mud 74 ~ 94%
Sodium citrate 5 ~ 25%
Modified polyorganosiloxane 1 ~ 10%.
6. the compliance function particle according to claim 1 for washing powder, it is characterised in that：The compliance function particle
For the particle of 10 ~ 60 mesh.
7. the preparation method of a kind of compliance function particle for washing powder, it is characterised in that include the following steps：
The first step：Bentonite material is crushed to 200 ~ 325 mesh, wherein bentonite material is calcium-base bentonite or sodium bentonite
It is one or two kinds of；
Second step：Bentonite material after crushing is added into water slurrying, concentration is 10 ~ 20%, makes bentonite water suction disintegration, then
It is placed in sand mill, and adds the first inorganic modifier, is stirred, bentonite is fully peeled off into monocrystalline tablet, sand
When time consuming 1 ~ 6 is small；Obtain that slurry is sanded；
First inorganic modifier is the molar ratio of inorganic sodium and the mixture of inorganic lithium salt, inorganic sodium and inorganic lithium salt
For 20：1~1：10；One or more of the inorganic sodium in sodium carbonate, sodium fluoride, sodium chloride, the inorganic lithium salt choosing
From one or both of lithium carbonate, lithium fluoride；
By weight, the first inorganic modifier dosage is the 1 ~ 10% of bentonite material；
3rd step：The second inorganic modifier, high speed dispersion hybrid reaction, 10 ~ 30min of time are added in above-mentioned sand milling slurry；
The one kind of second inorganic modifier in sodium pyrophosphate, sodium trimetaphosphate, four sodium metaphosphates and calgon
It is or several；
By weight, the second inorganic modifier dosage is the 0.05 ~ 1% of bentonite material；
4th step：The slurry is centrifuged, takes upper slurry, obtains modified alta-mud slurry；
5th step：Sodium citrate, modified polyorganosiloxane are proportionally added into above-mentioned modified alta-mud slurry, are sufficiently mixed；
To mixture；
6th step：It is 20 ~ 50% by said mixture drying to moisture, is then granulated, the particle made is sent to stream
Change and be dried in bed, sieved, you can obtain the compliance function particle.
8. the preparation method of the compliance function particle according to claim 7 for washing powder, it is characterised in that：It is described soft
Along the particle that functional particles are 10 ~ 60 mesh.
9. the preparation method of the compliance function particle according to claim 7 for washing powder, it is characterised in that：Described
In six steps, drying temperature is 100 ~ 200 degrees Celsius.
10. a kind of washing powder, it is characterised in that, should containing the compliance function particle as claimed in claim 1 for being used for washing powder
Compliance function particle is 10 ~ 20% in the weight percent content of washing powder.
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| CN201711386849.7A CN108004054B (en) | 2017-12-20 | 2017-12-20 | Softening functional particle for washing powder and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111607467A (en) * | 2020-06-12 | 2020-09-01 | 廊坊佰美生物科技有限公司 | Bleaching powder and preparation method thereof |
| CN113462201A (en) * | 2020-04-03 | 2021-10-01 | 苏州中材非金属矿工业设计研究院有限公司 | Bentonite inorganic gel for washing powder and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1914308A (en) * | 2004-02-03 | 2007-02-14 | 宝洁公司 | A composition for use in the laundering or treatment of fabrics, and a process for making the composition |
| CN101175844A (en) * | 2005-05-12 | 2008-05-07 | 苏德-化学股份公司 | Fast-dissolving bentonite granulate |
-
2017
- 2017-12-20 CN CN201711386849.7A patent/CN108004054B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1914308A (en) * | 2004-02-03 | 2007-02-14 | 宝洁公司 | A composition for use in the laundering or treatment of fabrics, and a process for making the composition |
| CN101175844A (en) * | 2005-05-12 | 2008-05-07 | 苏德-化学股份公司 | Fast-dissolving bentonite granulate |
Non-Patent Citations (1)
| Title |
|---|
| 回清杰等: "织物柔软剂-HPN的研制与应用", 《日用化学工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113462201A (en) * | 2020-04-03 | 2021-10-01 | 苏州中材非金属矿工业设计研究院有限公司 | Bentonite inorganic gel for washing powder and preparation method thereof |
| CN113462201B (en) * | 2020-04-03 | 2022-06-03 | 苏州中材非金属矿工业设计研究院有限公司 | Bentonite inorganic gel for washing powder and preparation method thereof |
| CN111607467A (en) * | 2020-06-12 | 2020-09-01 | 廊坊佰美生物科技有限公司 | Bleaching powder and preparation method thereof |
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