CN105088759B - The preparation method of a kind of silk facial film and facial film - Google Patents
The preparation method of a kind of silk facial film and facial film Download PDFInfo
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- CN105088759B CN105088759B CN201510489327.4A CN201510489327A CN105088759B CN 105088759 B CN105088759 B CN 105088759B CN 201510489327 A CN201510489327 A CN 201510489327A CN 105088759 B CN105088759 B CN 105088759B
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- greig
- silk
- ammonium chloride
- modifying agent
- facial film
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- 230000001815 facial effect Effects 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 46
- 238000005406 washing Methods 0.000 claims abstract description 45
- 239000004576 sand Substances 0.000 claims abstract description 31
- 238000012986 modification Methods 0.000 claims abstract description 27
- 230000004048 modification Effects 0.000 claims abstract description 27
- 241000255789 Bombyx mori Species 0.000 claims abstract description 11
- 108010022355 Fibroins Proteins 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 7
- 239000003607 modifier Substances 0.000 claims abstract description 6
- 238000012545 processing Methods 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 44
- 238000000034 method Methods 0.000 claims description 36
- -1 3-sulfopropyl dodecyl Chemical group 0.000 claims description 25
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims description 18
- ALNUPAIRBMNLLB-UHFFFAOYSA-M dodecyl-dimethyl-(oxiran-2-ylmethyl)azanium;chloride Chemical group [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1CO1 ALNUPAIRBMNLLB-UHFFFAOYSA-M 0.000 claims description 17
- 239000004744 fabric Substances 0.000 claims description 15
- GLPQBRRAPGABDN-UHFFFAOYSA-N Cl.C(CC)N.[O] Chemical compound Cl.C(CC)N.[O] GLPQBRRAPGABDN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000344 soap Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 238000007670 refining Methods 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 11
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 9
- 239000002585 base Substances 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 229960003237 betaine Drugs 0.000 claims description 3
- NDORGWUNFGHGKU-UHFFFAOYSA-N dodecanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(O)=O NDORGWUNFGHGKU-UHFFFAOYSA-N 0.000 claims description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229940045998 sodium isethionate Drugs 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 2
- 238000012805 post-processing Methods 0.000 claims description 2
- PYNUOAIJIQGACY-UHFFFAOYSA-N propylazanium;chloride Chemical compound Cl.CCCN PYNUOAIJIQGACY-UHFFFAOYSA-N 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 19
- 238000006386 neutralization reaction Methods 0.000 abstract description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 45
- 230000000694 effects Effects 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000003020 moisturizing effect Effects 0.000 description 5
- 108010013296 Sericins Proteins 0.000 description 4
- XRJJGXZTIJPXNZ-UHFFFAOYSA-N [Cl-].C(CC)[NH3+].CC(C)=C Chemical compound [Cl-].C(CC)[NH3+].CC(C)=C XRJJGXZTIJPXNZ-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 241000255791 Bombyx Species 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- SPJCDLBLJTXFRB-UHFFFAOYSA-N [Na].CCCCCCCCCCCC(=O)C(O)CS(O)(=O)=O Chemical compound [Na].CCCCCCCCCCCC(=O)C(O)CS(O)(=O)=O SPJCDLBLJTXFRB-UHFFFAOYSA-N 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- HWNBNVYZPNDRPK-UHFFFAOYSA-N CCCCCCCCCCCCCl(C)(C)CC1OC1 Chemical compound CCCCCCCCCCCCCl(C)(C)CC1OC1 HWNBNVYZPNDRPK-UHFFFAOYSA-N 0.000 description 1
- 235000005956 Cosmos caudatus Nutrition 0.000 description 1
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- 206010013786 Dry skin Diseases 0.000 description 1
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- 206010020751 Hypersensitivity Diseases 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010039792 Seborrhoea Diseases 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
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- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
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- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
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- 238000004153 renaturation Methods 0.000 description 1
- XPOMMEZJJLGASF-UHFFFAOYSA-N s-ethoxy dodecanethioate Chemical compound CCCCCCCCCCCC(=O)SOCC XPOMMEZJJLGASF-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of facial film, silk prepare.Its preparation method includes the step to greig refine, sand washing or the step of sanding and the step of graft modification, and the greig after graft modification blows be then punched into facial film through neutralization, drying, cold wind；Wherein the step of graft modification is: it is in 0.3% 2% modifier solutions that greig puts into mass concentration, is modified processing under conditions of temperature 20 50 DEG C, pH5 8, and described modifying agent is for can improve silkworm silk absorptive fibroin modifying agent.Substantially increase the water absorption of silk, more than the twice of common silk water absorption rate can be reached.
Description
Technical field
The present invention relates to a kind of silk facial film and preparation method thereof, belong to textile material manufacture field.
Background technology
Facial film is the indispensable skin care item of numerous women, and silk mask relies on effect of its mystery by extensively especially
Application.Silkworm silk is as the animal proteinum of pure natural, the most similar to the composition of human skin.In fibroin
Tyrosine, tryptophan and phenylalanine etc. can absorb ultraviolet, after these Amino Acid Absorption ultraviolet, resistance
Ultraviolet catalyzed of having broken forms melanic reaction, therefore has the uvioresistant effect of whitening.It addition, sericin
Serine in albumen has the strongest moisture retention, in fibroin albumen rich in glycine there is antioxidation, guarantor
Wet effect.Silkworm silk is a kind of fibrous material integrating whitening, moisturizing, antioxidation, has very
High using value.
It practice, commercially available silk mask is essentially silkworm silk technique facial film, because having soyeux feel and leading to
Thoroughly property and be called silk mask.Being divided into two kinds: a kind of is silk mask patch, one is silk mask frost.
Mostly silk mask patch is to use non-woven fabrics craft to make, and silkworm silk material used mostly is silk spinning raw material, at high temperature
Under conditions of high pressure is quick-drying, lapping forms spun-laced nonwoven fabric.Silk mask frost is to add a small amount of silk in face pack cream
Glue or fibroin peptide matters, these sericin and fibroin are most through high temperature high pressure process during being extracted.
The denaturation renaturation of fibroin is not unlimited, in high temperature high pressure process repeatedly, continuous degeneration, multiple
Property, the activity of albumen is substantially reduced, and use value is also had a greatly reduced quality.
Silk is the most really for facial film at present, because the moisture absorption of silkworm silk own does not absorbs water, it is impossible to inhale with skin
Affixed conjunction, cannot be used for facial film use if therefore processed without hydrophilizing agent.
The silk craft of China comparative maturity, (the silk woven with raw silk or organzine from Bombyx bombycis to greig
Fabric is referred to as greig, and greig is refined, become soft pongee after degumming and bleaching dyes, and greig contains nearly 30%
Sericin) production process in, temperature can be controlled within 90 degree, under the conditions of comparatively gentle
Carry out greig production, it is ensured that protein active.Owing in silkworm silk, protein content is higher than famous and precious Margarita powder,
Silk so how is made to absorb water, it is achieved albumen is combined closely with skin, really plays cosmetic result, becomes
Silk is applied to the difficult point of facial film.Have not yet to see the example that silk is used for facial film.
Summary of the invention
For existing problem, it is an object of the invention to provide a kind of facial film, another object of the present invention exists
In the preparation method providing this kind of silk facial film so that silk can truly be used for mask product.
To achieve these goals, the technical scheme is that such: a kind of facial film, it is characterised in that:
Prepared by silk.
Concrete silk is the most first modified:
A kind of preparation method of silk facial film, it is characterised in that: include the step to greig refine, sand washing or
The step of sanding and the step of graft modification, the greig after graft modification blows so through neutralization, drying, cold wind
After strike out facial film；
Wherein the step of graft modification is: it is in 0.3%-2% modifier solution that greig puts into mass concentration,
Being modified processing under conditions of temperature 20-50 DEG C, pH5-8, described modifying agent is for improving silkworm silk water suction
The fibroin modifying agent of property.
Use such scheme to use and can improve the absorptive modifying agent being grafted on silkworm silk of silkworm silk to greig
It is modified so that the water absorption rate of greig is greatly improved, combining closely, really of albumen and skin can be realized
Play the effect of beauty treatment.The facial film prepared is compared with the silk mask directly prepared with Bombyx bombycis, more smooth, flat
Whole.
In such scheme: described Sand Wash Process is, the greig through refine is packed, puts in sand washing liquid,
At 40-70 DEG C, soak 20-40min, then take out, wash, in acetum and standby；Described sand washing liquid
In containing soda 0.5g/L-15g/L, paregal O 0.5g/L-2g/L.Bath raio 1:30-1:50, after sand washing,
There are some fine fleece fabrics in silk surface so that water absorption rate is higher, more preferable to the absorption affinity of skin.
The technique of described sanding is: rubbed on the cylinder of roughing-up machine by the greig through refine, on silk fabric face
Grind one layer of fine hair, described cylinder is enclosed with rubber.Sanding as the effect of sand washing, the water absorption rate being
Improve, more preferable to the absorption affinity of skin, more comfortable.
In such scheme: described modifying agent is by lauric acid sodium isethionate and 3-sulfopropyl dodecyl two
Glycidyl glycine betaine forms, and the mass ratio of two materials is 11-15:5-9.Process through this modifier modification
Silk facial film there is the effect that moisturizing is clean, be suitable for neutral skin and use.
In such scheme: described modifying agent is dodecyl dimethyl glycidyl ammonium chloride or myristyl
Isobutylene propyl ammonium chloride.The silk facial film obtained through this modification has antibacterial effect of deoiling, and is suitable for
Oily skin uses.
In such scheme: described modifying agent is dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulfopropyl
The mixture of dodecyl diepoxy CAB, or be dodecyl dimethyl glycidyl ammonium chloride and
The mixture of 3-sulfopropyl dodecyl diepoxy CAB, dodecyldimethylamine basic ring oxygen propyl ammonium chloride
Mass ratio and dodecyl dimethyl glycidyl with 3-sulfopropyl dodecyl diepoxy CAB
Ammonium chloride is 3-5:2-4 with the mass ratio of 3-sulfopropyl dodecyl diepoxy CAB.Change through this
Property the modified silk facial film of agent there is the effect of identical moisturizing, be suitable for dry skin and use.
In such scheme: described modifying agent is dodecyldimethylamine basic ring oxygen propyl ammonium chloride and paregal O
Mixture, or be dodecyl dimethyl glycidyl ammonium chloride and the mixture of paregal O, the tetradecane
The mass ratio of base isobutylene propyl ammonium chloride and paregal O and dodecyl dimethyl glycidyl chlorine
The mass ratio changing ammonium and paregal O is 4-6:0.5-2.The silk facial film obtained through this modification has moisturizing
The effect of oil so that mixed type skin uses.
In such scheme: described modifying agent is that 3-(N-dodecyl-N, N-diepoxy propyl group)-sulfo group is sweet
Dish alkali.Only this modified facial film prepared has the effect of gentle moisturizing, is suitable for sensitivity skin and uses.
In such scheme: refine comprises the following steps:
(1), pretreatment, greig is put in pretreatment fluid, under temperature 80-90 DEG C, pH10-10.5 soak
Bubble, containing sodium carbonate 0.5g/L-1g/L and penetrating agent JFC 0.1g/L-0.5g/L in described pretreatment fluid；
(2), the greig through pretreatment is taken out, be the hot water wash of 80-90 DEG C by temperature, then put into
In refining liquid, soak under conditions of temperature 80-90 DEG C, pH10-10.5, containing carbonic acid in described refining liquid
Sodium 0.5g/L-0.8g/L, industry soap 4g/L-8g/L, sodium silicate 0.5g/L-0.8g/L and sodium hydrosulfite 0.3g/L
-0.5g/L；
(3), post processing, the greig after refine is 50-70 by the hot water wash that temperature is 80-90 DEG C, temperature successively
DEG C warm water clean, place into concentration be in 0.4g/L-0.6g/L acetum after soaking at room temperature take out wash with water.
Refinery practice mild condition of the present invention (not higher than 90 DEG C), ensure that the activity of sericin greatly.Pass through
After refine, silk gum content can be maintained at 3%-6%.The bath raio of each step in refining process is
1:30-1:50, the bath raio during graft modification is 1:10-1:20.
In such scheme: 15-100g/m selected by described greig2Greig.The silk so obtained strikes out face
After film, its thickness is more moderate.
The invention has the beneficial effects as follows: compared with prior art, greig is carried out at sand washing and modification by the present invention
Reason so that its water absorption is greatly improved, and can reach more than the twice of common silk water absorption rate so that silk energy
Truly it is used for making facial film, gives full play to the beauty functions of fibroin in silk.The present invention processes
Process conditions are gentle, keep the activity of fibroin to greatest extent.It addition, the present invention develops the most of the same race
The silk modifying agent of class, prepares different types of silk facial film, is suitable for different types of skin and uses, makes
Not havinging the phenomenon of allergy after with, prepared facial film is smooth, smooth, soft.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described:
The modifying agent that the present invention uses is:
HF-A, modifying agent is by lauric acid sodium isethionate and 3-sulfopropyl dodecyl diepoxy propyl group Radix Betae
Alkali forms, and the mass ratio of two materials is 11-15:5-9.
HF-J modifying agent is dodecyl dimethyl glycidyl ammonium chloride or dodecyldimethylamine basic ring oxygen third
Ammonium chloride.
HF-M, modifying agent is dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulfopropyl dodecyl bicyclo-
The mixture of oxygen CAB, or be dodecyl dimethyl glycidyl ammonium chloride and 3-sulfopropyl 12
The mixture of alkyl diepoxy CAB, dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulfopropyl
The mass ratio of dodecyl diepoxy CAB and dodecyl dimethyl glycidyl ammonium chloride and 3-
The mass ratio of sulfopropyl dodecyl diepoxy CAB is 3-5:2-4.
HF-P, modifying agent is dodecyldimethylamine basic ring oxygen propyl ammonium chloride and the mixture of paregal O, or
For dodecyl dimethyl glycidyl ammonium chloride and the mixture of paregal O, dodecyldimethylamine basic ring oxygen
The mass ratio of propyl ammonium chloride and paregal O and dodecyl dimethyl glycidyl ammonium chloride and peregal
The mass ratio of O is 3-5:2-4.
HF-D modifying agent is 3-(N-dodecyl-N, N-diepoxy propyl group)-sulfobetaines.
The pretreatment fluid of the present invention, refining liquid, acetum and modifier solution are water preparation solution.
Embodiment 1
1. it is 15g/m by square grammes per square metre2Habotai greig to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Note above-mentioned solution formulated by water.
Technological process:
Greig is put in pretreatment fluid, bath raio 1:40, soaks 30min 90 DEG C, pH=10～10.5 times,
Pull out, put in the hot water that temperature is 90 DEG C and clean 5min, then take out, put in refining liquid, bath raio 1:40,
Under the conditions of temperature 90 DEG C, pH=10～10.5, soak 40min.
Greig in refining liquid is taken out, puts in the hot water that temperature is 90 DEG C and soak 5min, then put into temperature
It is immersion 5min in the warm water of 60 DEG C, finally puts in soaking at room temperature 5min in aftertreatment fluid, take out, cold water
Wash stand-by.
2. sand washing
Silk loading cloth bag, puts in sand washing liquid, bath raio 1:50, containing 8g/L soda, 0.5g/L in sand washing liquid
Paregal O, soaks 40min under conditions of temperature is 40 DEG C, and taking-up washes with water, rear input 0.5g/L's
In acetum in room temperature and 5min, take out stand-by.
3. graft modification
Silk after sand washing is taken out, puts in the modifying agent HF-A that mass concentration is 0.3%, wherein lauroyl hydroxyl
Ethylsulfonic acid sodium is 11:5 with the mass ratio of 3-sulfopropyl dodecyl diepoxy CAB, bath raio 1:12
It is 40 DEG C in temperature, soaks 1h under conditions of pH7, take out washing.
4 neutralize
0.5g/L acetic acid, room temperature, 15min, pH=6
5. dry
6. cold wind blows so that have the fluffy sense of lint.
7. strike out facial film
Embodiment 2.
1. it is 30g/m by square grammes per square metre2Qiao its to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 50min, pH=10～10.5) → hot water wash (90 DEG C, 5min) → concise (90
DEG C, 40min, pH=10) → hot water wash (90 DEG C, 5min) → warm water washes (60 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 5min) → cold water is washed.
2. sand washing
Silk is loaded cloth bag → sand washing (bath raio 1:40, sand washing liquid contain 10g/L soda, 0.8g/L paregal O,
60 DEG C, 30min) → washing → neutralize (0.5g/L acetic acid, room temperature, 5min)
3. graft modification
Grafting (1:12,1% modifying agent HF-M, 1h, 40 DEG C, pH=8) → washing
Modifying agent HF-M is by dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulfopropyl dodecyl diepoxy third
Base glycine betaine is mixed to get according to mass ratio 3:2.
4 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
5. dry
6. cold wind blows
7. strike out facial film
Embodiment 3:
1. by square grammes per square metre it is: 50g/m2Twill silk to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 30min, pH=10～10.5) → hot water wash (80 DEG C, 5min) → concise (90
DEG C, 60min, pH=10) → hot water wash (80 DEG C, 5min) → warm water washes (40 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 3min) → cold water is washed
2. sand washing
Silk is loaded cloth bag → sand washing (bath raio 1:40, sand washing liquid contain 12g/L soda, 1g/L paregal O, 60
DEG C, 20min) → washing → neutralize (0.5g/L acetic acid, room temperature, 5min)
3. graft modification
Grafting (1:20,0.8% modifying agent HF-J, 2h, room temperature, pH=8) → washing, herein, uses dodecane
Base isobutylene propyl ammonium chloride or dodecyldimethylamine basic ring oxygen propyl ammonium chloride.
4 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
5. dry
6. cold wind blows
7. strike out facial film
Embodiment 4:
1. by square grammes per square metre it is: 80g/m2Crepe de Chine to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 10min, pH=10～10.5) → hot water wash (90 DEG C, 5min) → concise (90
DEG C, 20min, pH=10) → hot water wash (90 DEG C, 5min) → warm water washes (60 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 10min) → cold water is washed
2. sand washing
Silk is loaded cloth bag → sand washing (bath raio 1:40, sand washing liquid contain 15g/L soda, 1.5g/L paregal O,
70 DEG C, 20min) → washing → neutralize (0.5g/L acetic acid, room temperature, 5min)
3. graft modification
Grafting (bath raio 1:10,1% modifying agent HF-P, 1.5h, 40 DEG C, pH=8) → washing
Modifying agent mixed according to mass ratio 4:0.5 by dodecyl dimethyl glycidyl ammonium chloride and paregal O and
Become.
4 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
5. dry
6. cold wind blows
7. strike out facial film
Embodiment 5:
1. by square grammes per square metre it is: 100g/m2Crepe de Chine to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (80 DEG C, 30min, pH=10～10.5) → hot water wash (80 DEG C, 5min) → concise (80
DEG C, 40min, pH=10) → hot water wash (80 DEG C, 5min) → warm water washes (40 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 5min) → cold water is washed
2. sand washing
Silk is loaded cloth bag → sand washing (bath raio 1:40, sand washing liquid contain 15g/L soda, 2g/L paregal O, 50
DEG C, 20min) → washing → neutralize (0.5g/L acetic acid, room temperature, 5min)
3. graft modification
Grafting (bath raio 1:12,2% modifying agent HF-D, 1h, room temperature, pH=7) → washing
4 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
5. dry
6. cold wind blows
7. strike out facial film
Embodiment 6
It is 15g/m by square grammes per square metre2Habotai greig to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Note above-mentioned solution formulated by water.
Technological process:
Greig is put in pretreatment fluid, bath raio 1:40, soaks 30min 90 DEG C, pH=10～10.5 times,
Pull out, put in the hot water that temperature is 90 DEG C and clean 5min, then take out, put in refining liquid, bath raio 1:40,
Under the conditions of temperature 90 DEG C, pH=10～10.5, soak 40min.
Greig in refining liquid is taken out, puts in the hot water that temperature is 90 DEG C and soak 5min, then put into temperature
It is immersion 5min in the warm water of 60 DEG C, finally puts in soaking at room temperature 5min in aftertreatment fluid, take out, cold water
Wash stand-by.
Graft modification
Silk after refine is taken out, puts in the modifying agent HF-A that mass concentration is 0.3%, wherein lauroyl hydroxyl
Ethylsulfonic acid sodium is 11:5 with the mass ratio of 3-sulfopropyl dodecyl diepoxy CAB, bath raio 1:12
It is 40 DEG C in temperature, soaks 1h under conditions of pH7, take out washing.
Neutralize
0.5g/L acetic acid, room temperature, 15min, pH=6
Dry
Cold wind blows
Strike out facial film
Embodiment 7.
1. it is 30g/m by square grammes per square metre2Qiao its to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 50min, pH=10～10.5) → hot water wash (90 DEG C, 5min) → concise (90
DEG C, 40min, pH=10) → hot water wash (90 DEG C, 5min) → warm water washes (60 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 5min) → cold water is washed.
2. graft modification
Grafting (1:12,1% modifying agent HF-M, 1h, 40 DEG C, pH=8) → washing
Modifying agent HF-M is by dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulfopropyl dodecyl diepoxy third
Base glycine betaine is mixed to get according to mass ratio 3:2.
3 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
4. dry
5. cold wind blows
6 strike out facial film
Embodiment 8:
1. by square grammes per square metre it is: 50g/m2Twill silk to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 30min, pH=10～10.5) → hot water wash (80 DEG C, 5min) → concise (90
DEG C, 60min, pH=10) → hot water wash (80 DEG C, 5min) → warm water washes (40 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 3min) → cold water is washed
2. graft modification
Grafting (1:20,0.8% modifying agent HF-J, 2h, room temperature, pH=8) → washing, herein, uses dodecane
Base isobutylene propyl ammonium chloride or dodecyldimethylamine basic ring oxygen propyl ammonium chloride.
3 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
4. dry
5. cold wind blows
6 strike out facial film
Embodiment 9:
1. by square grammes per square metre it is: 80g/m2Crepe de Chine to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 10min, pH=10～10.5) → hot water wash (90 DEG C, 5min) → concise (90
DEG C, 20min, pH=10) → hot water wash (90 DEG C, 5min) → warm water washes (60 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 10min) → cold water is washed
2. graft modification
Grafting (bath raio 1:10,1% modifying agent HF-P, 1.5h, 40 DEG C, pH=8) → washing
Modifying agent mixed according to mass ratio 4:0.5 by dodecyl dimethyl glycidyl ammonium chloride and paregal O and
Become.
3 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
4. dry
5. cold wind blows
6. strike out facial film
Embodiment 10:
1. by square grammes per square metre it is: 100g/m2Crepe de Chine to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (80 DEG C, 30min, pH=10～10.5) → hot water wash (80 DEG C, 5min) → concise (80
DEG C, 40min, pH=10) → hot water wash (80 DEG C, 5min) → warm water washes (40 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 5min) → cold water is washed
2. graft modification
Grafting (bath raio 1:12,2% modifying agent HF-D, 1h, room temperature, pH=7) → washing
3 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
4. dry
5. cold wind blows
6. strike out facial film
Embodiment 11
It is 15g/m by square grammes per square metre2Habotai greig to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Note above-mentioned solution formulated by water.
Technological process:
Greig is put in pretreatment fluid, bath raio 1:40, soaks 30min 90 DEG C, pH=10～10.5 times,
Pull out, put in the hot water that temperature is 90 DEG C and clean 5min, then take out, put in refining liquid, bath raio 1:40,
Under the conditions of temperature 90 DEG C, pH=10～10.5, soak 40min.
Greig in refining liquid is taken out, puts in the hot water that temperature is 90 DEG C and soak 5min, then put into temperature
It is immersion 5min in the warm water of 60 DEG C, finally puts in soaking at room temperature 5min in aftertreatment fluid, take out, cold water
Wash stand-by.
Sand washing
Silk loading cloth bag, puts in sand washing liquid, bath raio 1:50, containing 8g/L soda, 0.5g/L in sand washing liquid
Paregal O, soaks 40min under conditions of temperature is 40 DEG C, and taking-up washes with water, rear input 0.5g/L's
In acetum in room temperature and 5min, take out standby.
Silk embodiment of the present invention 1-11 prepared and Traditional Silk carry out water absorption rate test
Method of testing:
Silk after congener common silk and modifier treatment is placed eight basket oven for drying, dries
After take out in exsiccator balance 10min, claim its weight, front and back twice of poor quality at 0.3% model
Being considered as in enclosing drying is constant weight, is designated as last quality drying to the dry weight of sample during constant weight, and
Record its exact mass m1(being accurate to 0.01g), loads in polypropylene non-fabrication cloth cloth bag.
The beaker filling 1000ml distilled water (water temperature (20 ± 2) DEG C) is placed on stable testing stand,
After the water surface is totally stationary, by non-fabrication for ready polypropylene cloth cloth bag directly over distance beaker mouth
Timing at once in beaker is vertically put in the position of 10cm, takes out after 10min, and being transferred to Circularhole diameter is
On the wire netting of 3mm (wire netting both sides need to be suspended in the air, it is ensured that below without any obstruction),
Placing 10min respectively, precise also records now quality m2(being accurate to 0.01g).
Water absorption rate W is calculated as follows, and result takes the arithmetic mean of instantaneous value of 3 measurement results.
W=(m2-m1)/m1× 100%
In formula:
W water absorption rate, unit is percentage rate (%).
m2Quality after sample water suction, unit is gram (g).
m1Quality after sample constant weight, unit is gram (g).
Experimental result:
From experimental result it can be seen that after graft modification of the present invention processes, water absorption rate is greatly improved.Add
After sand washing, water absorption rate can reach more than the twice of common silk.
Embodiment 12, other are same as in Example 1, and different is only that modifying agent HF-A is by lauroyl ethoxy sulphur
Acid sodium is that 15:9 is obtained by mixing with the mass ratio of 3-sulfopropyl dodecyl diepoxy CAB.According to upper
Stating water absorption rate test, the result obtained is 345.1W/%.
Embodiment 13, other are same as in Example 2, and except for the difference that, modifying agent HF-M is by dodecyl dimethyl
Glycidyl ammonium chloride mixes according to mass ratio 5:4 with 3-sulfopropyl dodecyl diepoxy CAB
Arrive.Testting according to above-mentioned water absorption rate, the result obtained is 358.9W/%.
Embodiment 14, other are the same as in Example 4, and except for the difference that modifying agent is by dodecyl dimethyl glycidyl
Ammonium chloride mixes according to mass ratio 6:2 with paregal O.Test according to above-mentioned water absorption rate, the knot obtained
Fruit is 325.6W/%.
Embodiment 15:
1. by square grammes per square metre it is: 50g/m2Twill silk to carry out soap alkaline process concise
Prescription for the treatment of liquid:
Technological process:
Pretreatment (90 DEG C, 30min, pH=10～10.5) → hot water wash (80 DEG C, 5min) → concise (90
DEG C, 60min, pH=10) → hot water wash (80 DEG C, 5min) → warm water washes (40 DEG C, 5min) → locate afterwards
Reason liquid (room temperature, 3min) → cold water is washed
2. sanding: rubbed on the cylinder of roughing-up machine by the greig through refine, grinds one layer of fine hair on silk fabric face,
It is enclosed with rubber on described cylinder.
3. graft modification
Grafting (1:20,0.8% modifying agent HF-J, 2h, room temperature, pH=8) → washing, herein, uses dodecane
Base isobutylene propyl ammonium chloride or dodecyldimethylamine basic ring oxygen propyl ammonium chloride.
4 neutralize
0.5g/L acetic acid, room temperature, 30min, pH=6
5. dry
6. cold wind blows
7. strike out facial film
The present invention is not limited to above-mentioned specific embodiment, it will be appreciated that those of ordinary skill in the art without
Creative work just can make many modifications and variations according to the design of the present invention.In a word, all technology neck
In territory, technical staff passes through logical analysis, reasoning the most on the basis of existing technology or has
The available technical scheme of experiment of limit, all should be in the protection domain being defined in the patent claims.
Claims (4)
1. the preparation method of a silk facial film, it is characterised in that: include the step to greig refine, sand
Wash or the step of sanding and the step of graft modification, the greig after graft modification through neutralizing, drying, cold wind
Blow and be then punched into facial film；
Wherein the step of graft modification is: it is in 0.3%-2% modifier solution that greig puts into mass concentration,
Being modified processing under conditions of temperature 20-50 DEG C, pH5-8, described modifying agent is for improving silkworm silk water suction
The fibroin modifying agent of property；
Described modifying agent is dodecyl dimethyl glycidyl ammonium chloride or dodecyldimethylamine basic ring oxygen third
Ammonium chloride；
Or described modifying agent is dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulfopropyl dodecyl two
The mixture of glycidyl glycine betaine, or be dodecyl dimethyl glycidyl ammonium chloride and 3-sulfopropyl ten
The mixture of dialkyl group diepoxy CAB, dodecyldimethylamine basic ring oxygen propyl ammonium chloride and 3-sulphur third
The mass ratio of base dodecyl diepoxy CAB and dodecyl dimethyl glycidyl ammonium chloride with
The mass ratio of 3-sulfopropyl dodecyl diepoxy CAB is 3-5:2-4；
Or described modifying agent is dodecyldimethylamine basic ring oxygen propyl ammonium chloride and the mixture of paregal O, or
For dodecyl dimethyl glycidyl ammonium chloride and the mixture of paregal O, dodecyldimethylamine basic ring oxygen
The mass ratio of propyl ammonium chloride and paregal O and dodecyl dimethyl glycidyl ammonium chloride and peregal
The mass ratio of O is 4-6:0.5-2；
Or described modifying agent is 3-(N-dodecyl-N, N-diepoxy propyl group)-sulfobetaines；
Or described modifying agent is sweet by lauric acid sodium isethionate and 3-sulfopropyl dodecyl diepoxy propyl group
Dish alkali forms, and the mass ratio of two materials is 11-15:5-9.
The preparation method of silk facial film the most according to claim 1, it is characterised in that: described sand washing
Technique is, is packed by the greig through refine, puts in sand washing liquid, soaks 20-40min at 40-70 DEG C,
Then take out, wash, in acetum and standby；In described sand washing liquid containing soda 0.5g/L-15g/L,
Paregal O 0.5g/L-2g/L；
The technique of described sanding is: rubbed on the cylinder of roughing-up machine by the greig through refine, on silk fabric face
Grind one layer of fine hair, described cylinder is enclosed with rubber.
The preparation method of silk facial film the most according to claim 1, it is characterised in that:
Refine comprises the following steps:
(1), pretreatment, greig is put in pretreatment fluid, under temperature 80-90 DEG C, pH10-10.5 soak
Bubble, containing sodium carbonate 0.5g/L-1g/L and penetrating agent JFC 0.1g/L-0.5g/L in described pretreatment fluid；
(2), the greig through pretreatment is taken out, be the hot water wash of 80-90 DEG C by temperature, then put into
In refining liquid, soak under conditions of temperature 80-90 DEG C, pH10-10.5, containing carbonic acid in described refining liquid
Sodium 0.5g/L-0.8g/L, industry soap 4g/L-8g/L, sodium silicate 0.5g/L-0.8g/L and sodium hydrosulfite 0.3g/L
-0.5g/L；
(3), post processing, the greig after refine is 50-70 by the hot water wash that temperature is 80-90 DEG C, temperature successively
DEG C warm water clean, place into concentration be in 0.4g/L-0.6g/L acetum after soaking at room temperature take out wash with water.
4. according to the preparation method of silk facial film described in claim 2 or 1, it is characterised in that: described greig
Select 15-100g/m2Greig.
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| CN107190406A (en) * | 2017-05-09 | 2017-09-22 | 浙江梅盛实业股份有限公司 | Superfine fibre face mask substrate material and its manufacturing process with water suction and resilience function |
| CN111374933B (en) * | 2020-04-06 | 2022-03-25 | 广州玥颜化妆品有限公司 | Silk mask |
| CN112535654A (en) * | 2020-12-02 | 2021-03-23 | 罗亚文 | Preparation method of mask with water locking effect |
| CN117924219B (en) * | 2024-01-17 | 2024-08-09 | 山东滨州昱诚化工科技有限公司 | Vegetable gum stabilizer for oil field and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101570935A (en) * | 2009-04-30 | 2009-11-04 | 东华大学 | Modification method for preparing highly-hydrophilic real silk fiber spunlace non-woven material |
| CN104674355A (en) * | 2015-01-19 | 2015-06-03 | 丹东中天柞蚕生物科技有限公司 | Preparation method of tussore non-woven fabric mask |
| CN104762756A (en) * | 2015-04-24 | 2015-07-08 | 钱程 | Natural silk facial mask base cloth and preparation method thereof |
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| US20060048278A1 (en) * | 2004-09-02 | 2006-03-09 | George Pitsolis | Facial mask |
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2015
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570935A (en) * | 2009-04-30 | 2009-11-04 | 东华大学 | Modification method for preparing highly-hydrophilic real silk fiber spunlace non-woven material |
| CN104674355A (en) * | 2015-01-19 | 2015-06-03 | 丹东中天柞蚕生物科技有限公司 | Preparation method of tussore non-woven fabric mask |
| CN104762756A (en) * | 2015-04-24 | 2015-07-08 | 钱程 | Natural silk facial mask base cloth and preparation method thereof |
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