CN106283392A - A kind of film cloth used for cosmetic and processing method thereof and purposes - Google Patents
A kind of film cloth used for cosmetic and processing method thereof and purposes Download PDFInfo
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- CN106283392A CN106283392A CN201510322948.3A CN201510322948A CN106283392A CN 106283392 A CN106283392 A CN 106283392A CN 201510322948 A CN201510322948 A CN 201510322948A CN 106283392 A CN106283392 A CN 106283392A
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Abstract
The present invention discloses a kind of film cloth used for cosmetic and processing method thereof and purposes, and this film cloth is the lamination cloth containing at least 1 layer of nanofiber layer, and the stiction of described lamination cloth is more than 100cN, and water-retaining property is more than 400%.The film cloth used for cosmetic of the present invention not only has that flexibility is good, the feature of good water-retaining property, but also has the feature good with skin applicating property, can be used for facial film, cervacoria, foot film etc..
Description
Technical field
The present invention relates to a kind of film cloth used for cosmetic and processing method thereof and purposes.
Background technology
Along with growth in the living standard and the quickening of rhythm of life, people are more and more higher for the requirement of various health skin-protection products, and particularly skin protection enjoys the concern of people with various film cloth.The film cloth formed based on various chemical fibres, native cellulose fibre and man-made cellulose fibers in the market.The biggest portion of diameter of these fibers is all at tens microns, and the amount of liquid medicine of the film cloth impregnation of formation is few, poor water retention property；Flexibility is poor simultaneously, bad with the applicating property of skin, thus have impact on the medicinal liquid effective nursing to skin.
But, few, the shortcoming of poor water retention property for the impregnation amount of liquid medicine of above-mentioned general fibre film cloth, market also develops the general fibre film cloth of some thicker, amount of liquid medicine is few, the problem of poor water retention property to some extent solve impregnation, but the increase due to thickness, make flexibility become worse, can not fully stick with skin.And the shortcoming that poor for flexibility and skin applicating property is bad, also some extra-thin general fibre film cloth are developed, to some extent solve the problem that poor and skin the applicating property of flexibility is poor, but the reduction due to thickness, amount of liquid medicine is less, water-retaining property is worse to make impregnation, degradation the most easy to use.
And on market, have also been developed the film cloth that can simultaneously solve above-mentioned 2 aspect problems, as Japanese Laid-Open Patent JP 2007-70347A discloses the film cloth that the non-woven fabrics containing nanofiber layer of more than a kind of at least two-layer is formed, although this facial mask cloth improves the shortcoming that impregnation amount of liquid medicine is few, poor water retention property, flexibility are poor and skin applicating property is bad of general fibre film cloth to a certain extent, but the applicating property of flexibility, water-retaining property and skin needs to be improved further；This invention simultaneously did not carry out plasma process and processed.
Summary of the invention
It is an object of the invention to provide a kind of good water-retaining property, the good used for cosmetic film cloth good with skin applicating property of flexibility and processing method thereof.
The technical solution of the present invention is as follows: the film cloth used for cosmetic of the present invention is the lamination cloth containing at least 1 layer of nanofiber layer, and the stiction of described lamination cloth is more than 100cN, and water-retaining property is more than 400%.
The film cloth used for cosmetic of the present invention had both solved the impregnation of Vehicles Collected from Market general fibre film cloth, and medicinal liquid is few, the problem of poor water retention property；Solve again the problem that flexibility is poor and skin applicating property is poor simultaneously.The film cloth used for cosmetic of the present invention not only has that flexibility is good, the feature of good water-retaining property, but also has the feature good with skin applicating property, can be used for facial film, cervacoria, foot film etc..
Detailed description of the invention
The film cloth used for cosmetic of the present invention is the lamination cloth containing at least 1 layer of nanofiber layer, and the stiction of described lamination cloth is more than 100cN, and water-retaining property is more than 400%.Here at least one of which nanofiber layer can be only one layer, it is also possible to more than two-layer, but in view of production cost, nanofiber layer typically will not use more than 3 layers, and the film cloth used for cosmetic of the present invention is preferably the lamination cloth containing two-layer nanofiber layer.Because when nanofiber layer is as surface and contact skin, the feature of inventive film cloth can be played, so when only one layer of nanofiber layer, this film cloth can be made up of independent one layer of nanofiber layer, can also be made up of with other ordinary fiber layer one layer of nanofiber layer, being accomplished by differentiating which face when now using is this nanofiber layer；And during containing two-layer nanofiber layer, the structure of this film cloth is upper and lower surface nanofiber layer, middle ordinary fiber layer.Compared with general fibre, owing to nanofiber number of fiber in unit are is many, during as nanofiber layer and the skin contact on film cloth surface, contact area is bigger, thus improves the applicating property with skin；And when film cloth infiltration essence, it is possible to absorbing the essence of more times, during skin protection, essence is difficult to be dried, and Glycerin is more abundant, can better ensure that skin water moistens, and fine and smooth nanofiber layer is low to the zest of skin.The monofilament radical of film cloth surface fiber and the apparent condition of fibre single thread directly determine the stiction of film cloth.When stiction is less than 100cN, film cloth is poor with the applicating property of skin, and film cloth can not be fully contacted with skin, thus causes essence can not be fully absorbed by skin；Film cloth easily comes off from skin simultaneously.When water-retaining property less than 400% time, show film cloth infiltration essence after, the essence that film cloth is possessed is few, the weak effect moisten skin, maintained.
The nanofiber layer of the present invention is nonwoven layer or braid layer.In view of the stickiness of film cloth Yu skin, the preferred nonwoven layer of this nanofiber layer.
Containing one layer of ordinary fiber layer in the film cloth used for cosmetic of the present invention, this ordinary fiber layer is combined with nanofiber layer by the spun lacing processing method of non-woven fabrics, forms lamination cloth.When comprising only one layer of nanofiber layer in the film cloth used for cosmetic of the present invention, one of them surface is nanofiber layer, and another one surface is ordinary fiber layer；When comprising only the above nanofiber layer of two-layer in the film cloth used for cosmetic of the present invention, this ordinary fiber layer is in the intermediate layer of film cloth, and the upper and lower surface of film cloth is all nanofiber layer.
The nanofiber layer of the present invention be by diameter 100～1000nm polyamide or polyester fiber formed.If the diameter of nanofiber is too small, fiber process difficulty, it is difficult to prepare nanofiber layer；If the diameter of nanofiber is excessive, it is impossible to give full play to that nanofiber is very thin, soft, the effect of low stimulation, thus nanofiber layer can not be made to fit tightly with skin.In view of processability and soft low irritant, fibre diameter preferably 150～800nm, more preferably 200～500nm.The non-woven nanofiber layer of the present invention is formed through de-sea process by polylactic acid/polyamide or the polyester that overlaps altogether/polyester sea-island fiber.In view of high liquid-absorbing, nanofiber layer is preferably formed by Fypro.
This ordinary fiber layer is made up of hydrophilic fibre.This hydrophilic fibre can be the natural fibers such as cotton, fiber crops, real silk, it is also possible to for regenerated celulose fibres such as viscose glue, tencel, Modal, milk fibre, soybean fiber, bamboo fibres, it is also possible to for hydrophilic chemistries fibers such as polyamide, polyester, polyacrylonitrile.
The nanofiber layer of the present invention comprises at least one hydrophilic polymer, owing to hydrophilic polymer can increase the absorbtivity of essence, the most in use can preferably discharge, can preferably be absorbed infiltration by skin, not have the phenomenon that during facial mask cloth uses, essence significantly reduces, is dried.Cosmetics film cloth in view of the present invention needs the alkali carrying out NaOH solution to process in process of manufacture, the polyamide polymer that the preferred alkali resistance of above-mentioned hydrophilic polymer is good.
The production method of the film cloth used for cosmetic of the present invention, comprises the following steps:
(1) preparation of island-in-sea type composite fiber stratum reticulare (fabric): by ready polylactic acid/polyamide island composite short fiber or the polyester that overlaps altogether/polyester island composite short fiber through opener-combing-lapping-acupuncture or spun lacing-hot-working, make the island-in-sea type composite fiber stratum reticulare of certain thickness and grammes per square metre；Or polyamide/polylactic acid island composite short fiber or the polyester that overlaps altogether/polyester island bicomponent filament yarn utilize tricot machine carry out braiding processing, prepares the composite braided thing in island；
(2) preparation of lamination cloth: after the composite braided thing of at least one of which island-in-sea type composite fiber stratum reticulare or island is placed in the NaOH solution of 6～10g/L, 90～98 DEG C process 0.5～2h, and be dried, thermal finalization, slough sea component polylactic acid or the polyester that overlaps altogether, form the lamination cloth containing at least one of which nanofiber layer；
(3) preparation of finished product: above-mentioned prepared lamination cloth is carried out Cement Composite Treated by Plasma, finally prepares finished product, and wherein, the electric discharge general power of plasma is 36～80kw, and the process time is 4～24s.
In the processing method of the film cloth used for cosmetic of the present invention, above-mentioned lamination cloth is through Cement Composite Treated by Plasma, owing to air produces substantial amounts of anion, cation, electronics and a part of molecule through plasma ionization, the fiber surface of lamination cloth is clashed into, the strand now making the fiber surface of lamination cloth will rupture, the fiber surface ultimately resulting in lamination cloth forms substantial amounts of pit, and the specific surface area of the fiber surface of such lamination cloth will significantly increase.If lamination cloth is immersed in emulsion, absorbent can not only increase at double, and it is more preferable to protect fluidity.Simultaneously as lamination cloth surface defines substantial amounts of pit, stiction is also largely increased, and during use, film cloth is more preferable with the sticking performance of skin.
When plasma discharge general power is less than 4s less than 36kw, the time that processes, air can not ionize the substantial amounts of anion of generation, cation, electronics and molecule, also the fiber surface of lamination cloth effectively cannot be clashed into, substantial amounts of pit can not be formed, finally do not reach the effect that absorbent increases and stiction is greatly improved；And when plasma discharge general power is more than 24s more than 80kw, the time that processes, the amount of anion, cation, electronics and molecule owing to producing is the biggest, too fierce to the shock of the fiber surface of lamination cloth, thus affect the outward appearance on lamination cloth surface, energy consumption also becomes big simultaneously.
Impregnated in facial treatment essence liquid by above-mentioned prepared finished product lamination cloth, the film cloth of the skin protection needed for formation, this facial treatment essence liquid composition brand does not limits, and the above-mentioned skin protection film cloth soaking essence is carried out FOLD AND PACK.
By following example, the invention will be further described, but protection scope of the present invention is not limited to embodiment, and each physical parameter in embodiment is measured by following method.
[grammes per square metre]
Measure according to JIS L1096, size of materialsing: 200mm × 200mm, 3 pieces, after the laboratory damping 24h of 20 ± 2 DEG C × 65 ± 4%, be measured with electronic balance, calculate the meansigma methods of sample grammes per square metre.
[stiction]
Take the circle that 3 pieces of specimen sizes are 5cm diameter respectively, after the laboratory damping 24h of 20 ± 2 DEG C × 65 ± 4%, sample is allowed to absorb astringent (Shiseido UARA) series of 5 times of own wts, sample is attached on the sample stage with 150g weight, and nanofiber aspect is contacted with friction material, friction material is the artificial skin of 40 years old women, is stretched with the speed of 100mm/min by sample stage, record the stiction of sample nanofiber aspect and artificial skin, calculate the meansigma methods of 3 times tests.
[water-retaining property]
Taking 3 pieces of specimen sizes respectively is 100mm × 100mm, after the laboratory damping 24h of 20 ± 2 DEG C × 65 ± 4%, weigh weight G1 of coupons, coupons is impregnated 60 seconds in water, takes out after standing 120 seconds, again weigh coupons weight G2, repetitive operation 3 times, formula calculates water retention calculated as described below, calculates the meansigma methods of 3 times
Water retention (%)=(G2-G1)/G1 × 100%.
[fibre diameter of nanofiber layer]
Measure (meansigma methods of N=30) by TEM ultramicroscope to test.
[adherence of film cloth, moisturizing persistence and take convenience]
Sample being cut into facial film shape, selects 10 women of 40 years old to be evaluated experiment after infiltrating with the astringent (Shiseido) of 30mL, total score 5 points is evaluated, and takes the meansigma methods (rounding up after arithmetic point) of 10, and the concrete meaning of each mark is described as follows.
Embodiment 1
(1) preparation of the composite braided thing in island: by island ratio be 60/40, fiber number be the polylactic acid/polyamide 6 sea island filament of 43.9dtex, utilize tricot machine to carry out braiding processing, obtaining grammes per square metre is 95g/m2Polylactic acid/polyamide 6 WARP-KNITTING；
(2) preparation of lamination cloth: above-mentioned prepared polylactic acid/polyamide 6 WARP-KNITTING is placed in 8g/L, the NaOH solution of 95 DEG C and processes 30min, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component acid fiber by polylactic is dissolved, and forms the lamination cloth of nanofiber layer a of the daiamid-6 fiber of one layer of a diameter of 120nm；
(3) preparation of film cloth: by above-mentioned prepared nanofiber layer a electric discharge general power be 38kw, the process time be under 22s, to carry out Cement Composite Treated by Plasma, the final film cloth used for cosmetic preparing the present invention.Evaluating the physical property of this film cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Embodiment 2
(1) preparation of island-in-sea type composite fiber stratum reticulare a: by island ratio be 60/40, fiber number be 3.6dtex, the polylactic acid of a length of 51mm/polyamide 6 sea-island staple fiber put into blending box and carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 40g/m2Polylactic acid/polyamide 6 island-in-sea type composite fiber stratum reticulare a；
(2) preparation of ordinary fiber layer b: by fiber number be 2.2 dtex, the polyamide 6 chopped fiber of a length of 51mm put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 35g/m2Polyamide 6 nonwoven layer b；
(3) preparation of lamination cloth: carry out composite spunlaced after above-mentioned prepared island-in-sea type composite fiber stratum reticulare a, polyamide 6 nonwoven layer b are stacked again, again will after processing two be placed on 8g/L, the NaOH solution of 90 DEG C process 1h after, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component acid fiber by polylactic is dissolved, and forms the lamination cloth of the polyamide 6 nanofiber layer containing one layer of a diameter of 150nm；
(4) preparation of film cloth: by above-mentioned prepared lamination cloth electric discharge general power be 46kw, the process time be under 18s, to carry out Cement Composite Treated by Plasma, the final film cloth used for cosmetic preparing the present invention.Evaluating the physical property of this film cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Embodiment 3
(1) preparation of island-in-sea type composite fiber stratum reticulare a: by island ratio be 60/40, fiber number be 3.6dtex, the polylactic acid of a length of 51mm/polyamide 6 sea-island staple fiber put into blending box and carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 40g/m2Polylactic acid/polyamide 6 island-in-sea type composite fiber stratum reticulare a；
(2) preparation of ordinary fiber layer b: by fiber number be 2.2 dtex, the polyamide 6 chopped fiber of a length of 51mm put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 45g/m2Polyamide 6 nonwoven layer b；
(3) preparation of lamination cloth: carry out composite spunlaced after above-mentioned prepared island-in-sea type composite fiber stratum reticulare a, polyamide 6 nonwoven layer b, island-in-sea type composite fiber stratum reticulare a are stacked successively again, again will after processing two be placed on 10g/L, the NaOH solution of 90 DEG C process 40min after, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component acid fiber by polylactic is dissolved, and forms the lamination cloth of the polyamide 6 nanofiber layer of a diameter of 220nm containing a layer；
(4) preparation of film cloth: by above-mentioned prepared lamination cloth electric discharge general power be 60kw, the process time be under 12s, to carry out Cement Composite Treated by Plasma, the final film cloth used for cosmetic preparing the present invention.Evaluating the physical property of this film cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Embodiment 4
(1) preparation of island-in-sea type composite fiber stratum reticulare a: by island ratio be 60/40, fiber number be 3.6dtex, the polylactic acid of a length of 51mm/polyamide 6 sea-island staple fiber put into blending box and carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 55g/m2Polylactic acid/polyamide 6 island-in-sea type composite fiber stratum reticulare a；
(2) preparation of ordinary fiber layer b: by fiber number be 2.2 dtex, the wood pulp fluff of a length of 51mm dimension put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 60g/m2Wood pulp nonwoven layer of cloth b；
(3) preparation of lamination cloth: carry out composite spunlaced after above-mentioned prepared island-in-sea type composite fiber stratum reticulare a, wood pulp nonwoven layer of cloth b are stacked again, again will after processing two be placed on 7g/L, the NaOH solution of 96 DEG C process 1.5h after, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component acid fiber by polylactic is dissolved, and forms the lamination cloth of the polyamide 6 nanofiber layer of a diameter of 180nm containing a layer；
(4) preparation of film cloth: by above-mentioned prepared lamination cloth electric discharge general power be 72kw, the process time be under 5s, to carry out Cement Composite Treated by Plasma, the final film cloth used for cosmetic preparing the present invention.Evaluating the physical property of this film cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Embodiment 5
(1) preparation of the composite braided thing in island: by island ratio be 30/70, fiber number be the common coincidence PET/PET sea island filament of 61.4dtex, utilize tricot machine to carry out braiding processing, obtaining grammes per square metre is 60g/m2Coincidence PET/PET WARP-KNITTING altogether；
(2) preparation of lamination cloth: above-mentioned prepared common coincidence PET/PET WARP-KNITTING is placed in 6g/L, the NaOH solution of 90 DEG C and processes 30min, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component coincidence PET altogether is dissolved, and forms the lamination cloth of nanofiber layer a of the PET of one layer of a diameter of 360nm；
(3) preparation of film cloth: by above-mentioned prepared nanofiber layer a electric discharge general power be 38kw, the process time be under 22s, to carry out Cement Composite Treated by Plasma, the final film cloth used for cosmetic preparing the present invention.Evaluating the physical property of this film cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Embodiment 6
(1) preparation of island-in-sea type composite fiber stratum reticulare a: by island ratio be 30/70, fiber number be 3.6dtex, the common coincidence PET/PET sea-island staple fiber of a length of 51mm put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 40g/m2Common coincidence PET/PET island-in-sea type composite fiber stratum reticulare a；
(2) preparation of ordinary fiber layer b: by fiber number be 2.2 dtex, the PET chopped fiber of a length of 51mm put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 35g/m2The nonwoven layer b of PET；
(3) preparation of lamination cloth: carry out composite spunlaced after above-mentioned prepared island-in-sea type composite fiber stratum reticulare a, nonwoven layer b are stacked again, again will after processing two be placed on 6g/L, the NaOH solution of 90 DEG C process 30min after, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component coincidence PET altogether is dissolved, and forms the lamination cloth of the PET nanofiber layer containing one layer of a diameter of 320nm；
(4) preparation of film cloth: by above-mentioned prepared lamination cloth electric discharge general power be 46kw, the process time be under 18s, to carry out Cement Composite Treated by Plasma, the final film cloth used for cosmetic preparing the present invention.Evaluating the physical property of this film cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
The film cloth used for cosmetic prepared in embodiment 1～6 can be applicable in facial film, cervacoria, foot film.
Comparative example 1
(1) preparation of island-in-sea type composite fiber stratum reticulare a: by island ratio be 60/40, fiber number be 3.6dtex, the polylactic acid of a length of 51mm/polyamide 6 sea-island staple fiber put into blending box and carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 40g/m2Polylactic acid/polyamide 6 island-in-sea type composite fiber stratum reticulare a；
(2) preparation of ordinary fiber layer b: by fiber number be 2.2 dtex, the polyamide 6 chopped fiber of a length of 51mm put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 35g/m2The nonwoven layer b of polyamide 6；
(3) preparation of lamination cloth: carry out composite spunlaced after above-mentioned prepared island-in-sea type composite fiber stratum reticulare a, nonwoven layer b are stacked again, again will after processing two be placed on 8g/L, the NaOH solution of 95 DEG C process 30min after, then temperature be 150 DEG C, speed be 26m/min under conditions of be dried thermal finalization, now sea component acid fiber by polylactic is dissolved, and forms the lamination cloth of the polyamide 6 nanofiber layer of a diameter of 150nm containing a layer.Evaluating the physical property of this lamination cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Comparative example 2
By fiber number be 2.2 dtex, the polyamide 6 chopped fiber of a length of 51mm put into blending box carry out fibrillation mixed cotton combing lapping spun lacing, obtaining grammes per square metre is 51g/m2The non-weaving cloth of polyamide 6.Evaluating the physical property of this non-weaving cloth, this film cloth is cut into facial film shape, is impregnated in Shiseido UARA essence, evaluate the physical property of this film cloth, each physical property of film cloth sees table 1 below.
Table 1
Claims (9)
1. a film cloth used for cosmetic, it is characterised in that: this film cloth is the lamination cloth containing at least 1 layer of nanofiber layer, and the stiction of described lamination cloth is more than 100cN, and water-retaining property is more than 400%.
Film cloth used for cosmetic the most according to claim 1, it is characterised in that: described nanofiber layer is nonwoven layer or braid layer.
Film cloth used for cosmetic the most according to claim 1, it is characterised in that: containing one layer of ordinary fiber layer in described lamination cloth.
Film cloth used for cosmetic the most according to claim 1, it is characterised in that: described nanofiber layer is to be formed at the Fypro of 100～1000nm by diameter.
Film cloth used for cosmetic the most according to claim 1, it is characterised in that: described nanofiber layer is to be formed at the polyester fiber of 100～1000nm by diameter.
Film cloth used for cosmetic the most according to claim 1, it is characterised in that: described nanofiber layer comprises at least one hydrophilic polymer.
7. the processing method of the film cloth used for cosmetic described in a claim 1, it is characterised in that: the lamination cloth containing at least 1 layer of nanofiber layer is carried out Cement Composite Treated by Plasma, finally prepares finished product.
The processing method of film cloth used for cosmetic the most according to claim 7, it is characterised in that: described plasma discharge general power is 36～80kw, and the process time is 4～24s.
9. the application in facial film, cervacoria, foot film of the film cloth used for cosmetic described in a claim 1.
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| CN108030702A (en) * | 2017-12-20 | 2018-05-15 | 天津工业大学 | A kind of water lock moisture saver mask cloth and its preparation method and application |
| CN108505211A (en) * | 2017-02-27 | 2018-09-07 | 东丽纤维研究所（中国）有限公司 | A kind of film cloth used for cosmetic |
| CN109955573A (en) * | 2017-12-14 | 2019-07-02 | 东丽纤维研究所（中国）有限公司 | A kind of non-woven lamination cloth |
| US11937684B1 (en) | 2018-06-19 | 2024-03-26 | Summer Proctor | Beauty applicator systems and related methods |
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| CN109955573B (en) * | 2017-12-14 | 2023-01-06 | 东丽纤维研究所（中国）有限公司 | Non-woven laminated fabric |
| CN108030702A (en) * | 2017-12-20 | 2018-05-15 | 天津工业大学 | A kind of water lock moisture saver mask cloth and its preparation method and application |
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Application publication date: 20170104 |