CN105039038B - A kind of sodium montmorillonite adsorption liquid and preparation method thereof - Google Patents
A kind of sodium montmorillonite adsorption liquid and preparation method thereof Download PDFInfo
- Publication number
- CN105039038B CN105039038B CN201510534660.2A CN201510534660A CN105039038B CN 105039038 B CN105039038 B CN 105039038B CN 201510534660 A CN201510534660 A CN 201510534660A CN 105039038 B CN105039038 B CN 105039038B
- Authority
- CN
- China
- Prior art keywords
- sodium
- sodium montmorillonite
- adsorption liquid
- natural
- micro emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses the preparation method of a kind of sodium montmorillonite adsorption liquid and the adsorption liquid, surfactant and natural thickener are dissolved in sodium montmorillonite micro emulsion and are made using sodium montmorillonite micro emulsion as carrier by the sodium montmorillonite adsorption liquid.The characteristics of each component is all made of pure natural raw material and is prepared in this sodium montmorillonite adsorption liquid of the invention, does not add any essence and flavoring agent, pigment and traditional chemical antiseptic etc., and there is low bubble, strong detergency easily to rinse, and is not necessarily to softener, environmentally friendly, skin care.
Description
Technical field
The present invention relates to a kind of articles for washing, the preparation side of specifically a kind of sodium montmorillonite adsorption liquid and the adsorption liquid
Method belongs to the manufacturing technology field of adsorbing separation product.
Background technology
Higher and higher, the requirement needs energy fast decontaminating to articles for washing is required along with modern living standards of the people,
Nontoxic, using water wisely, convenient for washing, environmental protection is not hurt hands, not damaging laundry, clothing is dry and comfortable after washing, submissive colour-fast.But mesh
Preceding all kinds of articless for washing in the market all contain various chemical classes preparations, and long-time service will appear coarse hand skin, decortication, do
It splits, the problems such as injury is faded is generated to clothing.Therefore, existing market lacks a kind of cleaning solution based on the absorption of natural mine plant.
Invention content
Purpose of the present invention is to：In view of the above-mentioned problems, present invention offer one kind is with natural minerals and natural plants additive
The sodium montmorillonite adsorption liquid of main component, while the preparation method of this adsorption liquid is also disclosed, which has quick
Decontamination, nontoxic, using water wisely, convenient for washing, environmental protection is not hurt hands, not damaging laundry, clothing is dry and comfortable after washing, submissive colour-fast
The characteristics of.
In order to achieve the above object, the technical solution adopted by the present invention is：A kind of sodium montmorillonite adsorption liquid, is covered with sodium
De- stone micro emulsion is carrier, and surfactant and natural thickener are dissolved in sodium montmorillonite micro emulsion and are made.
This sodium montmorillonite adsorption liquid of the present invention further includes following preferred embodiment based on the above technical solution：
The weight percent of the surfactant, natural thickener and sodium montmorillonite micro emulsion is respectively：
Surfactant 2.0~20.0%；
Natural thickener 0.5%~2.0%；
Surplus is sodium montmorillonite micro emulsion.
The surfactant is the mixture of natural surfactant and non-natural surfactant, wherein natural table
Face activating agent is selected from fatty acid methyl ester-α-sodium sulfonate, lecithin, sorbitan fatty acid ester, sorbitan fatty acid ester
Any one in derivative or two or more mixtures, non-natural surfactant are selected to aliphatic alcohol polyoxyethylene sulfuric acid
In sodium, sodium alkyl benzene sulfonate, alkyl phenol polyoxydivinyl ether, fatty acid methyl ester ethoxylate any one or it is two or more
Mixture.
The natural thickener is any one in alginic acid, sodium alginate, carragheen, Arabic gum, starch, pectin
Kind or two or more mixtures.
The preparation method of this sodium montmorillonite adsorption liquid of the present invention is：
It is stood after surfactant, natural thickener and sodium montmorillonite micro emulsion are mixed evenly, and the sodium is made
Change montmorillonite adsorption liquid finished product.
The preparation method of this sodium montmorillonite adsorption liquid of the present invention further includes following based on the above technical solution
Preferred embodiment：
The tool of described " being stood after surfactant, natural thickener and sodium montmorillonite micro emulsion are mixed evenly "
Body operating method is：Sodium montmorillonite micro emulsion is added in high speed dispersor and is slowly added to surface-active under stirring condition
Agent, adds the natural thickener being dissolved in the water after being completely dispersed, and adjusting viscosity is static to suitable, stopping dispersion
To the removal of foam.
It is also filling to sodium montmorillonite adsorption liquid finished product obtained progress, and obtain sodium montmorillonite adsorption liquid and be packaged into
Product.
The preparation method of the sodium montmorillonite micro emulsion includes the following steps：
Step 1: first the pure water of 15~25 times of weight of natural smectite mine soil is stirred, and fully impregnate 50 hours with
On, after it is fully expanded, solution is made to be sieved through the above vibrating screen of 200 mesh while stirring；
Step 2: the lotion that the step 1 obtains is ground 40 hours or more in grinder of delaminating, after grinding
Sodium agent water-soluble liquid is added in lotion, the quality of sodium agent solute accounts for solid in the lotion in the sodium agent water-soluble liquid
The 2.0~7.0% of material mass are sufficiently stirred 2 hours or more in dispersion machine.
Preferably, further including Step 3: the material that the step 2 obtains is isolated greatly through high speed tube centrifuge
Particle, to which sodium montmorillonite micro emulsion finished product be made.
Preferably, the sodium agent is arbitrary in sodium carbonate, sodium bicarbonate, sodium pyrophosphate, sodium phosphate, sodium sulphate
One or more kinds of mixtures.
This sodium montmorillonite adsorption liquid of the present invention, using sodium montmorillonite micro emulsion as carrier, by surfactant and naturally
Thickener is dissolved in sodium montmorillonite micro emulsion and is made, and has the following advantages：
1, for montmorillonite after sodium ion exchange, itself carries charge, has again while low bubble decontamination and is knitted to clothes
Fibres carry out antistatic surface processing, no longer need to carry out individually submissive processing after making clothes washing, you can keep clothing softness suitable
It is sliding.
2, montmorillonite itself has absorption property, can adsorb the foreign matter on clothing and enhance dirt-removing power.
3, montmorillonite molecule can generate mechanical friction to the dirt in clothing, increase decontamination under the action of water again
Ability.
4, there is the montmorillonite after sodium alkalescence can effectively enhance the ability of degreasing.
5, compared to the liquid detergent prepared by various artificial synthesized chemicals, this sodium montmorillonite adsorption liquid of the present invention
With natural bacteriostatic, the mild feature of performance.
6, each component is all made of pure natural raw material and is prepared in this sodium montmorillonite adsorption liquid of the present invention, does not add and appoints
There is what essence and flavoring agent, pigment and traditional chemical antiseptic etc. low bubble, strong detergency easily to rinse, and be not necessarily to softener, environmental protection, shield
The characteristics of skin.This sodium montmorillonite adsorption liquid cooperation small-scale ultrasonic cleaning machine uses cleaning performance more preferably.
Specific implementation mode
Said program is described further below in conjunction with specific embodiment.It should be understood that these embodiments are for illustrating
The present invention and be not limited to limit the scope of the invention.The implementation condition used in embodiment can be done according to the condition of specific producer
Further adjustment, the implementation condition being not specified is usually the condition in routine experiment.
Embodiment one：The preparation of sodium montmorillonite adsorption liquid
1) raw material preparation：
It is ready to first as the sodium montmorillonite micro emulsion 93.60Kg for making raw material, fatty acid methyl ester-α-sodium sulfonate and fat
Fat alcohol polyoxydivinyl ether sodium sulphate total 5.00kg, alginic acid 1.40kg.
Wherein fatty acid methyl ester-α-sodium sulfonate is common natural surfactant, and alginic acid is common natural thickening
Agent, aliphatic alcohol polyoxyethylene sodium sulphate are common non-natural surfactant.Certainly we can also use other days
Right surfactant substitutes fatty acid methyl ester-α-sodium sulfonate in this example, for example, lecithin, sorbitan fatty acid ester or
Person's sorbitan fatty acid ester derivative, we can also use fatty acid methyl ester-α-sodium sulfonate, lecithin, D-sorbite
Arbitrary two or more mixture substitutes individual fat in this example in acid anhydride aliphatic ester, sorbitan fatty acid ester derivative
Fatty acid methyl esters-α-sodium sulfonate.We can also use other non-natural surfactants to substitute the fatty alcohol polyoxy in this example
The dilute ether sodium sulfate of second, such as sodium alkyl benzene sulfonate, alkyl phenol polyoxydivinyl ether or fatty acid methyl ester ethoxylate, we
Aliphatic alcohol polyoxyethylene sodium sulphate, sodium alkyl benzene sulfonate, alkyl phenol polyoxydivinyl ether, fatty acid methyl ester ethoxy can also be used
The arbitrary two or more mixture in any one or two or more mixtures in glycolylate substitutes in this example individually
Aliphatic alcohol polyoxyethylene sodium sulphate.
Equally, we can also use other natural thickeners to substitute the alginic acid in this example, such as sodium alginate, card
Glue, Arabic gum, starch or pectin are drawn, we can also use alginic acid, sodium alginate, carragheen, Arabic gum, shallow lake
Arbitrary two or more mixture in powder, pectin substitutes the alginic acid being used alone in this example.
2) it mixes
In the high speed dispersor with 200L containers, ready sodium montmorillonite micro emulsion is added, under stirring condition,
It is slowly added to ready surfactant, adds to be dissolved in the water after being completely dispersed and is configured to 5% mass concentration
Natural thickener, adjust viscosity to suitable (the suitable viscosity number is generally 2000~3000mpa.s), stop dispersion, it is quiet
Only after the removal of foam can filling (be detected, weigh and pack according to a conventional method), to obtain sodium of the present invention cover it is de-
The packed products of stone adsorption liquid.
Embodiment two：The preparation of sodium montmorillonite adsorption liquid
1) raw material preparation：
It is ready to first as the sodium montmorillonite micro emulsion 91.42Kg for making raw material, (it is Natural surfactant to lecithin
Agent) and sodium alkyl benzene sulfonate (it is non-natural surfactant) total 6.80kg, sodium alginate (it is natural thickener)
1.78kg。
2) it mixes
In the high speed dispersor with 200L containers, ready sodium montmorillonite micro emulsion is added, under stirring condition,
It is slowly added to ready surfactant, is added after being completely dispersed and has been dissolved in the water that be configured to 6.5% mass dense
The natural thickener of degree adjusts viscosity to suitable, stops dispersion, it is static can be filling after the removal of foam, to obtain this hair
The packed products of natulanar montmorillonite adsorption liquid.
Embodiment three：The preparation of sodium montmorillonite adsorption liquid
1) raw material preparation：
It is ready to first as the sodium montmorillonite micro emulsion 90.35Kg for making raw material, (it is sorbitan fatty acid ester
Natural surfactant) and sodium alkyl benzene sulfonate (it is non-natural surfactant) total 9.00kg, (it is natural thickening to pectin
Agent) 0.65kg.
2) it mixes
In the high speed dispersor with 200L containers, ready sodium montmorillonite micro emulsion is added, under stirring condition,
It is slowly added to ready surfactant, adds to be dissolved in the water after being completely dispersed and is configured to 10% mass concentration
Natural thickener, adjust viscosity to suitable (appropriate viscosity mentioned here is usually 2000~3000mpa.s), stop point
Dissipate, it is static can be filling after the removal of foam, to obtain the packed products of sodium montmorillonite adsorption liquid of the present invention.
Example IV：The preparation of sodium montmorillonite adsorption liquid
1) raw material preparation：
It is ready to first as sodium montmorillonite micro emulsion 95.15Kg, fatty acid methyl ester-α-sodium sulfonate (its for making raw material
For natural surfactant) and fatty acid methyl ester ethoxylate (it is non-natural surfactant) total 2.90kg, pectin (its
For natural thickener) 1.95kg.
2) it mixes
In the high speed dispersor with 200L containers, ready sodium montmorillonite micro emulsion is added, under stirring condition,
It is slowly added to ready surfactant, is added after being completely dispersed and has been dissolved in the water that be configured to 4.5% mass dense
The natural thickener of degree adjusts viscosity to suitable, stops dispersion, it is static can be filling after the removal of foam, to obtain this hair
The packed products of natulanar montmorillonite adsorption liquid.
Embodiment five：The preparation of sodium montmorillonite adsorption liquid
1) raw material preparation：
It is ready to first as the sodium montmorillonite micro emulsion 89.50Kg for making raw material, sorbitan fatty acid ester, lecithin
Fat, sorbitan fatty acid ester and the total 10.00kg of alkyl phenol polyoxydivinyl ether, Arabic gum (it is natural thickener)
0.50kg。
2) it mixes
In the high speed dispersor with 200L containers, ready sodium montmorillonite micro emulsion is added, under stirring condition,
It is slowly added to ready surfactant, adds to be dissolved in the water after being completely dispersed and is configured to 4% mass concentration
Natural thickener, adjust viscosity to suitable, stop dispersion, it is static can be filling after the removal of foam, to obtain the present invention
The packed products of sodium montmorillonite adsorption liquid.
Embodiment six：The preparation of sodium montmorillonite adsorption liquid
1) raw material preparation：
It is ready to first as the sodium montmorillonite micro emulsion 96.00Kg for making raw material, sorbitan fatty acid ester and alkane
The total 2.00kg of base phenol polyoxydivinyl ether, carragheen and starch (the two is natural thickener) total 2.00kg.
2) it mixes
In the high speed dispersor with 200L containers, ready sodium montmorillonite micro emulsion is added, under stirring condition,
It is slowly added to ready surfactant, adds to be dissolved in the water after being completely dispersed and is configured to 8% mass concentration
Natural thickener, adjust viscosity to suitable, stop dispersion, it is static can be filling after the removal of foam, to obtain the present invention
The packed products of sodium montmorillonite adsorption liquid.
It is not difficult to find out, above-mentioned six embodiments are using sodium montmorillonite micro emulsion as carrier, (are natural by surfactant
The mixture of surfactant and non-natural surfactant) and natural thickener be dissolved in sodium montmorillonite micro emulsion and be made
Sodium montmorillonite adsorption liquid finished product.The weight percent of each component is in obtained sodium montmorillonite adsorption liquid finished product：
Surfactant 2.0~20.0%；
Natural thickener 0.5%~2.0%；
Surplus is sodium montmorillonite micro emulsion.
Sodium montmorillonite adsorption liquid its dirt-removing power that above example obtains is by QB/T1224《Dress material washes agent by liquid》
JB-01, JB-02, JB-03 are detected, is：≈ standard liquid detergents detergency/1.0
It is compared using sodium montmorillonite adsorption liquid and traditional liquid detergent slurry amount as follows
Recorded " 4~8% ", " 8~12% ", " ＞ 12% ", refer to the weight percent of surfactant in upper table
(weight percent for accounting for surfactant, natural thickener and sodium montmorillonite micro emulsion total weight).
In above-mentioned each embodiment, used various surfactants and various natural thickeners are can be with outsourcing
Commodity.And sodium montmorillonite micro emulsion can be prepared via a method which, which includes following steps：
Step 1: first the pure water of 15~25 times of weight of natural smectite mine soil is stirred, and fully impregnate 50 hours with
On, after it is fully expanded, solution is made to be sieved through the above vibrating screen of 200 mesh while stirring；
Step 2: the lotion that the step 1 obtains is ground 40 hours or more in grinder of delaminating, after grinding
Sodium agent water-soluble liquid is added in lotion, the quality of sodium agent solute accounts for solid in the lotion in the sodium agent water-soluble liquid
The 2.0~7.0% of material mass, the mass concentration preferably 15~20% of the sodium agent water-soluble liquid, will add sodium agent water
The lotion of lysate is sufficiently stirred 2 hours or more in dispersion machine, obtains that sodium montmorillonite micro emulsion is made；
If having undissolved big object in the obtained sodium montmorillonite micro emulsion that step 2 obtains, we also need to carry out again
The operation of next step, i.e. step 3：The material that the step 2 obtains is isolated into bulky grain (body through high speed tube centrifuge
The larger particulate matter of type).
It is general to select inorganic sodium as the sodium agent, preferably sodium carbonate, sodium bicarbonate, sodium pyrophosphate, sodium phosphate,
Any one in sodium sulphate or two or more mixtures.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow people that can understand this hair
Bright content is simultaneously implemented according to this, and it is not intended to limit the scope of the present invention.It is all according to main technical schemes of the present invention
The equivalent transformation or modification that Spirit Essence is done, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of sodium montmorillonite adsorption liquid, which is characterized in that the adsorption liquid lives surface using sodium montmorillonite micro emulsion as carrier
Property agent and natural thickener are dissolved in sodium montmorillonite micro emulsion and are made；
The weight percent of the surfactant, natural thickener and sodium montmorillonite micro emulsion is respectively：
Surfactant 2.0~20.0%；
Natural thickener 0.5%~2.0%；
Surplus is sodium montmorillonite micro emulsion；
The surfactant is the mixture of natural surfactant and non-natural surfactant, wherein self-faced is lived
Property agent be selected from fatty acid methyl ester-α-sodium sulfonate, lecithin, sorbitan fatty acid ester, sorbitan fatty acid ester derive
Any one in object or two or more mixtures, non-natural surfactant select to aliphatic alcohol polyoxyethylene sodium sulphate,
In sodium alkyl benzene sulfonate, alkyl phenol polyoxydivinyl ether, fatty acid methyl ester ethoxylate any one or it is two or more mixed
Close object；
The preparation method of the sodium montmorillonite micro emulsion includes the following steps：
Step 1: first the pure water of 15~25 times of weight of natural smectite mine soil is stirred, and fully impregnated 50 hours or more, it waits for
After it is fully expanded, solution is made to be sieved through the above vibrating screen of 200 mesh while stirring；
Step 2: the lotion that the step 1 obtains is ground 40 hours or more in grinder of delaminating, lotion after grinding
Middle addition sodium agent water-soluble liquid, the quality of sodium agent solute accounts for solid matter in the lotion in the sodium agent water-soluble liquid
The 2.0~7.0% of quality are sufficiently stirred 2 hours or more in dispersion machine.
2. sodium montmorillonite adsorption liquid according to claim 1, which is characterized in that the natural thickener is selected from seaweed
Any one in acid, sodium alginate, carragheen, Arabic gum, starch, pectin or two or more mixtures.
3. a kind of preparation method of sodium montmorillonite adsorption liquid as claimed in claim 1 or 2, it is characterised in that this method is：
It is stood after surfactant, natural thickener and sodium montmorillonite micro emulsion are mixed evenly, and the sodium montmorillonite is made
Adsorption liquid finished product.
4. the preparation method of sodium montmorillonite adsorption liquid according to claim 3, which is characterized in that described " by surface
Activating agent, natural thickener and sodium montmorillonite micro emulsion are stood after being mixed evenly " concrete operation method be：In high speed point
It dissipates addition sodium montmorillonite micro emulsion in machine and is slowly added to surfactant under stirring condition, added after being completely dispersed
Natural thickener through being dissolved in the water, adjusting viscosity are static to the removal of foam to suitable, stopping dispersion.
5. the preparation method of sodium montmorillonite adsorption liquid according to claim 3, which is characterized in that also to sodium obtained
The progress of montmorillonite adsorption liquid finished product is filling, and obtains sodium montmorillonite adsorption liquid packed products.
6. the preparation method of sodium montmorillonite adsorption liquid according to claim 3, which is characterized in that the sodium montmorillonite
The preparation method of micro emulsion further includes step 3：The material that the step 2 obtains is isolated big through high speed tube centrifuge
Grain.
7. the preparation method of sodium montmorillonite adsorption liquid according to claim 3, which is characterized in that the sodium agent is selected from
Any one in sodium carbonate, sodium bicarbonate, sodium pyrophosphate, sodium phosphate, sodium sulphate or two or more mixtures.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510534660.2A CN105039038B (en) | 2015-08-27 | 2015-08-27 | A kind of sodium montmorillonite adsorption liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510534660.2A CN105039038B (en) | 2015-08-27 | 2015-08-27 | A kind of sodium montmorillonite adsorption liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105039038A CN105039038A (en) | 2015-11-11 |
| CN105039038B true CN105039038B (en) | 2018-07-24 |
Family
ID=54446014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510534660.2A Active CN105039038B (en) | 2015-08-27 | 2015-08-27 | A kind of sodium montmorillonite adsorption liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105039038B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110003995A (en) * | 2019-04-26 | 2019-07-12 | 建平碧康家居用品有限公司 | A kind of montmorillonite natural mineral matter concentration liquid laundry detergent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060086291A1 (en) * | 2002-10-09 | 2006-04-27 | Jardine Leslie A | Amine-containing cement processing additives |
| CN101228258A (en) * | 2005-08-01 | 2008-07-23 | 花王株式会社 | Softening detergent composition |
| CN103725454A (en) * | 2012-10-11 | 2014-04-16 | 3M创新有限公司 | Cleaning agent and application thereof to clean hard products |
-
2015
- 2015-08-27 CN CN201510534660.2A patent/CN105039038B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060086291A1 (en) * | 2002-10-09 | 2006-04-27 | Jardine Leslie A | Amine-containing cement processing additives |
| CN101228258A (en) * | 2005-08-01 | 2008-07-23 | 花王株式会社 | Softening detergent composition |
| CN103725454A (en) * | 2012-10-11 | 2014-04-16 | 3M创新有限公司 | Cleaning agent and application thereof to clean hard products |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105039038A (en) | 2015-11-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102517177B (en) | Biological eco-friendly multifunctional specific laundry detergent and preparation method thereof | |
| CN102392374B (en) | Anti-back-staining agent used in jeans enzyme washing | |
| CN102078268B (en) | Explosive salt and preparation method thereof | |
| CN105176719A (en) | Natural handmade soap containing camellia seeds and preparation method of soap | |
| CN105695148B (en) | A kind of environment protection solid cleansing composition | |
| CN103784339B (en) | A kind of not containing the frosted cleaning products of emulsifying agent | |
| CN109831917A (en) | Alkoxy silane or other water-insoluble hydrophobing agents are emulsified by using amino-functional silicone to manufacture the method and its application of the lotion of not fluorine-containing carbon in the case where not using conventional surfactant/emulsifier | |
| CN105039038B (en) | A kind of sodium montmorillonite adsorption liquid and preparation method thereof | |
| CN103242976A (en) | Soapberry vegetable-fruit washing-up liquid | |
| CN105482915A (en) | Skin-protecting bactericidal cleanser essence | |
| CN107557189A (en) | A kind of cleaning powder and preparation method thereof | |
| CN112205431A (en) | Antibacterial composition, antibacterial infant clothes washing liquor and preparation method thereof | |
| CN103710167A (en) | Liquid laundry detergent for infants and preparation method thereof | |
| CN103320237A (en) | Laundry detergent and its preparation method | |
| CN102961272A (en) | Salt mixed hair shampoo and preparation method thereof | |
| CN101175793B (en) | Process for grinding cellulose ether | |
| CN110003994A (en) | A kind of efficient cleaning paste and preparation method thereof | |
| CN109700061A (en) | Pickering emulsifier and preparation method thereof and Pickering lotion containing the emulsifier | |
| CN104586724A (en) | Coix seed powder facial mask cream and composition preparation method thereof | |
| CN108004054A (en) | A kind of compliance function particle for washing powder and preparation method thereof | |
| TW201113063A (en) | Sapindus detergent and method for manufacturing the same | |
| CN105924929A (en) | Cell regulator used for wet synthetic leather and preparation method thereof | |
| CN105542999A (en) | Sterilization type clothes cleaning agent | |
| CN109439457A (en) | It is a kind of using cake of camellia oleifera seeds as emulsification disinfecting detergent of raw material and preparation method thereof | |
| CN108504795A (en) | A kind of leather care products and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |