A kind of salt shuffles suppurative mastitis and preparation method thereof
Technical field
The present invention relates to a kind of hair washing product, be specifically related to a kind of salt take salt as the main body composition and shuffle suppurative mastitis and preparation method thereof, belong to the daily chemical products field.
Background technology
Daily chemical products mainly is divided into soap, synthetic detergent, cosmetics and oral cavity cleaning hygienic article etc., such as fancy soap, and liquid detergent, shampoo, facial milk cleanser, liquid detergent, floral water, hand cream, handwashing liquid, detergent, lip pomade etc.In cosmetics, the purpose that adds sterilization bacteriostat mainly is for effective kill bacteria and suppresses its Growth and reproduction, but also there is certain injury in such material to human body cell equally, 132 kinds of raw materials that the consumption restriction is arranged have been enumerated altogether in " components of cosmetics limits the use of material " and " limiting the use of antiseptic " of " the cosmetics health standard " of therefore publishing in 2007, wherein, the sterilization bacteriostat of long usefulness is all at these row in the hair washing product, as: ZPT, climbazole etc.Along with the progress of technology, various Chinese herbal medicine carry thing and neutral inorganic matter begins to replace gradually traditional chemical sterilization antibacterial, have brought more natural and green product for people's life.
Yet the dandruff problem of scalp does not obtain fine solution always, is a kind of long-standing phenomenon.According to statistics, there is the puzzlement of the dandruff in the adult more than 80%, and for this consumption demand, current anti-dandruff product on the market emerges in an endless stream.But use maximum anti-sterilization bacteriostats to remain chemical products ZPT and climbazole.Although also emerged in recent years more saliferous daily chemical products, be not to be (being that NaCl content is lower) take salt as primary raw material, only to use as additive, the effect of salt is less.Disclose a kind of hair washing emulsion inorganic salt and Chinese medicine, that have better removing scurf and relieving itching effect that contains such as Chinese patent CN200810058121.6, the additive of removing scurf and relieving itching is monovalence and bivalence inorganic salt and Chinese herbal medicine extract in this hair washing emulsion; The monovalence inorganic salt has sodium chloride, potassium chloride, lithium chloride, and the bivalence inorganic salt has magnesium chloride, magnesium sulfate, zinc chloride, zinc sulfate, copper chloride, copper sulfate, cobaltous chloride, cobaltous sulfate, manganese chloride, manganese sulfate.Inorganic salt mainly plays antibacterial, bactericidal action.Chinese herbal medicine is comprised of Radix Angelicae Sinensis, Radix Sophorae Flavescentis, Rhizoma Coptidis, Radix Scutellariae, Rhizoma Zingiberis Recens, Radix Polygoni Multiflori, Fructus Viticis, Cortex Mori, Rhizoma Chuanxiong, Cacumen Platycladi, and with water extract extractum or dry powder, it has antibacterial and hair care, hair care effect during use.Be not difficult to find out that still there is following problem in this shampoo:
1, raw material contains a large amount of Chinese medicine organic components in forming, oxidation stain is spoiled easily, durable depositing need to do not strengthened color and abnormal smells from the patient that pigment and essence consumption hide the herbal raw material of product when being applied to product, not only increases cost but also destroyed the natural characteristics that product is given prominence to originally.
2, NaCl content was lower during raw material formed, except monovalence inorganic salt sodium chloride, also be added with potassium chloride, lithium chloride, and bivalence inorganic salt magnesium chloride, magnesium sulfate, zinc chloride, zinc sulfate, copper chloride, copper sulfate, cobaltous chloride, cobaltous sulfate, manganese chloride, manganese sulfate, complicated component, cost is high, does not embody antibacterial, the bactericidal action of inorganic salt sodium chloride single component itself, and natural mineral products salt can not fully be used.
3, the inorganic salt that adds need to the composite competence exertion of Chinese medicine extract anti-dandruff, antipruritic effect preferably, and complicated process of preparation can to environment, be unfavorable for practicing.
In addition, Chinese patent CN 201010524089.3 discloses a kind of facial milk cleanser that contains rock salt and preparation method thereof, this mineral salt cleanser by the raw material of following weight parts through stirring, heating for dissolving, formulated after stirring and emulsifying and the ageing: anion surfactant 200-400 part, non-ionic surface active agent 30-100 part, trimethyl glycine 10-50 part, alkanolamide 20-50 part, plant moisturizing agent 10-50 part, hydrophilicity lanolin 10-40 part, glycol distearate 10-30 part, thickening agent 1-10 part, disodiumedetate 1-5 part, polyhydric alcohol 10-100 part, sodium chloride 250-500 part, essence 1-6 part, antiseptic 0.1-1 part, water 200-400 part.Because lipophilicity substance was few during the raw material of this mineral salt cleanser formed, the raw material processing procedure mainly is the mixed process of heating for dissolving, product is not easy to occur the oil-water separation phenomenon, thereby need not to add lipophilicity substance, the hydrophile-lipophile balance value of Surfactant (HLB value) and consumption require lower.Shuffling suppurative mastitis with respect to salt needs then that balance is hydrophilic, the relation of oleophilic substance, thereby has higher requirement at selection and the consumption of the HLB of Surfactant value.
Summary of the invention
The present invention is intended to provide a kind of salt take salt as the high content of salt of main body composition to shuffle suppurative mastitis and preparation method thereof for being added with chemical bactericide and the low defective of NaCl content in the existing anti-dandruff shampoo product.This salt shuffles suppurative mastitis and takes full advantage of natural mineral products salt resource, can effectively control the growth of bacterium colony on the scalp by the NaCl of high concentration content, removing scurf and relieving itching is effective, cost is low, the use that the complete substituted chemistry of energy is anti-dandruff dose, the murder by poisoning of having avoided the chemical agent prolonged stay to cause at the human body scalp, safer.
The present invention is the goal of the invention that reaches by the technical scheme that is implemented as follows.
A kind of salt shuffles suppurative mastitis, it is characterized in that raw material composition by weight comprises:
Anion surfactant 200-400 part
Amphoteric surfactant 20-100 part
Conditioner 10-80 part
Thickening agent 0-10 part
Disodiumedetate 1-5 part
Sodium chloride 300-650 part
Glycol distearate 0-30 part
Organosilicon 10-100 part
Essence 0-6 part
Antiseptic 0-5 part
Water 100-400 part
Described anion surfactant is selected from polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether sulfosuccinic monoester disodium, ammonium lauryl sulfate, at least a in sodium lauryl sulphate or the dodecylbenzene sodium sulfonate, or they are with the compositions of any weight ratio.
Described amphoteric surfactant is selected from dodecyldimethylammonium hydroxide inner salt, cocamido propyl betaine, and at least a in the amine oxide, or they are with the compositions of any weight ratio.
Described conditioner is selected from least a in the polyquaternary ammonium salt, or they are by the mixture of any weight ratio.As: polyquaternary ammonium salt-1, polyquaternary ammonium salt-2, polyquaternary ammonium salt-7, polyquaternary ammonium salt-9, polyquaternary ammonium salt-15 etc.
Described thickening agent is selected from least a material in the cellulose ether or derivatives thereof, or they are by the compositions of any weight ratio.As: carboxymethyl cellulose, hydroxyethyl-cellulose, guar gum etc.
Described sodium chloride is selected from a kind of in mine salt, lake salt, the sea salt, or they are by the combination of any weight ratio.
Described organosilicon is selected from a kind of of cetyl polydimethylsiloxane, polydimethylsiloxane, polysiloxanes apoplexy due to endogenous wind, or they are by the combination of any weight ratio.
Described essence is fruits essence, plants herb class essence, and at least a material in the synthetic class essence, as: apple essence, lavandula angustifolia essence, India's fruit Pedicellus et Pericarpium Trapae essence etc.
Described antiseptic is 1,3 dihydroxymethyl-5,5 dimethyl hydantion (DMDMH), sodium benzoate, U.S.-BP(germall extremely) at least a, or they are by the combination of any weight ratio.
Salt of the present invention shuffles the preferred raw material of suppurative mastitis and consists of:
Polyoxyethylenated alcohol sodium sulfate 200-400 part
Cocamido propyl betaine 20-100 part
Polyquaternary ammonium salt-7 10-80 part
Carboxymethyl cellulose 0-10 part
Disodiumedetate 1-5 part
Sodium chloride 300-650 part
Glycol distearate 0-30 part
Polydimethylsiloxane 10-100 part
Essence 0-6 part
DMDMH 0-5 part
Water 100-400 part
Described salt shuffles the preparation method of suppurative mastitis to be undertaken by following processing step:
A, disodiumedetate is added to the water, after the disodiumedetate dissolving that accounts for 50%-80%, adds thickening agent again, it is stand-by to stir;
After B, the mixed material that steps A is obtained are heated to 40 ℃-60 ℃, add the sodium chloride of anion surfactant, glycol distearate and 8%-20%, rapid stirring also is warmed up to 75 ℃-85 ℃ and dissolves fully to material;
C, conditioner is joined in the material that step B obtains, after 75 ℃ of-85 ℃ of constant temperature stir 20 minutes, begin cooling, when temperature is down to 50 ℃, add amphoteric surfactant, organosilicon, antiseptic, and to adjust pH value be 5.0-8.0; When waiting to be cooled to 40 ℃, add first essence, add at last remaining sodium chloride, continue to stir, make material dispersion evenly obtain semi-finished product;
D, the semi-finished product that obtain are positioned between semi-finished vehicles namely get the leaves shampoo product after ageing 1-2 days.
Compared with prior art, useful technique effect of the present invention shows:
1, the present invention is take salt as the main body composition, the content of sodium chloride reaches 30%-65% in the hair washing emulsion, in product system, be built into the environment of a dense ionization, can have played the fungus of parasitism during hair washing and kill preferably and inhibitory action, can not cause again product to solidify fully simultaneously.
2, the present invention is at 40 ℃-60 ℃ lower anion surfactants that add adaptive amount, not only be conducive to the dispersion of anion surfactant, and this temperature range add raw material can anion surfactant not formed because of excess Temperature can't dissolved gum group.
3, the present invention is reduced to the amphoteric surfactant that adds adaptive amount under 50 ℃ of conditions in temperature, has both reduced the zest of product to human body skin, again the foam that produces has been played good Stabilization, and head retention is good.
4, the present invention is by adding this strong oil-wet material of organosilicon of adaptive amount; can effectively change the rear hair sense of touch of product; can make after the hair washing to do and be easier to combing when sending out; simultaneously; add the conditioner of adaptive amount; pullling of hair avoided in easier combing when then making wet sending out, and the enemy is initiated to good protective effect.
5, the present invention utilizes the soft water performance of disodiumedetate, makes product also can keep better frothing capacity when hard water uses.
6, the present invention is by adding the anion surfactant of adaptive amount, better effective clean result and emulsifying effect of having brought into play raw material.
7, the present invention is by adding the water of corresponding proportion, effectively changing on the basis of product flowability, difference according to packing of product form, also can play Accommodation to the product flowability by adding thickening agent, simultaneously by adding the glycol distearate of corresponding proportion, both can change the transparency of product, but also can significantly not change the flowability of product.
8, each material composition of the present invention consists of the complete formula that salt shuffles suppurative mastitis by corresponding proportion, and they hold mutually mutually, can effectively reduce the use of additive, and the leaves shampoo product of formation is easy to store, and cost is lower, more environmental protection; The use that the complete substituted chemistry of energy is anti-dandruff dose, the murder by poisoning of having avoided the chemical agent prolonged stay to cause at the human body scalp, safer.
9, on preparation method, the present invention is by adding first the sodium chloride of 8%-20%, effectively strengthened the polarity of water preparation, accelerated the dissolution velocity of anion surfactant in water preparation, thereby avoided anion surfactant micelle to occur, the problem that outward appearance seems inhomogeneous because dissolving easily the incomplete final products that cause.
10, in the whole processing step of the present invention, each step becomes an integral body, the restriction that checks and balance, and the product appearance that final emulsifying is obtained is even, foam abundant, has good anti-dandruff and antipruritic effect.
The specific embodiment
Embodiment 1
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
Anion surfactant 250-350 part
Amphoteric surfactant 50-80 part
Conditioner 30-60 part
Thickening agent 2-8 part
Disodiumedetate 2-5 part
Sodium chloride 300-600 part
Glycol distearate 5-20 part
Organosilicon 30-80 part
Essence 1-3 part
Antiseptic 1-3 part
Water 200-300 part
Described anion surfactant is selected from fatty alcohol-polyoxyethylene ether sulfosuccinic monoester disodium.
Described amphoteric surfactant is selected from dodecyldimethylammonium hydroxide inner salt.
Described conditioner is selected from polyquaternary ammonium salt-3.
Described thickening agent is selected from carboxymethyl cellulose.
Described sodium chloride is selected from mine salt.
Described organosilicon is selected from the cetyl polydimethylsiloxane.
Described essence is apple essence essence.
Described antiseptic is sodium benzoate.
Embodiment 2
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
Anion surfactant 250 grams
Amphoteric surfactant 30 grams
Conditioner 30 grams
Thickening agent 6 grams
Disodiumedetate 2 grams
Sodium chloride 350 grams
Glycol distearate 20 grams
Organosilicon 40 grams
Essence 2 grams
Antiseptic 2 grams
Water 270 grams
Described anion surfactant is selected from ammonium lauryl sulfate.
Described amphoteric surfactant is selected from cocamido propyl betaine.
Described conditioner is selected from polyquaternary ammonium salt-7.
Described thickening agent is selected from hydroxyethyl-cellulose.
Described sodium chloride is selected from lake salt.
Described organosilicon is selected from polydimethylsiloxane.
Described essence is lavandula angustifolia essence.
Described antiseptic is 1,3 dihydroxymethyl-5,5 dimethyl hydantion (DMDMH).
Embodiment 3
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
Anion surfactant 200 grams
Amphoteric surfactant 100 grams
Conditioner 10 grams
Thickening agent 6 grams
Disodiumedetate 2 grams
Sodium chloride 450 grams
Glycol distearate 20 grams
Organosilicon 10 grams
Essence 2 grams
Antiseptic 1 gram
Water 205 grams
Described anion surfactant is selected from sodium lauryl sulphate.
Described amphoteric surfactant is selected from amine oxide.
Described conditioner is selected from polyquaternary ammonium salt-15.
Described thickening agent is selected from guar gum.
Described sodium chloride is selected from sea salt.
Described organosilicon is selected from polysiloxanes.
Described essence is India's fruit Pedicellus et Pericarpium Trapae essence.
Described antiseptic is U.S.-BP(germall extremely).
Embodiment 4
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
Anion surfactant 350 grams
Amphoteric surfactant 100 grams
Conditioner 10 grams
Thickening agent 3 grams
Disodiumedetate 2 grams
Sodium chloride 580 grams
Glycol distearate 20 grams
Organosilicon 20 grams
Water 115 grams
Described anion surfactant is selected from fatty alcohol-polyoxyethylene ether sulfosuccinic monoester disodium.
Described amphoteric surfactant is selected from cocamido propyl betaine.
Described conditioner is selected from polyquaternary ammonium salt-7 and the combination of quaternary ammonium salt-15 by weight 1:2
Described thickening agent is selected from hydroxyethyl-cellulose and the by weight combination of 1:2 of carboxymethyl cellulose.
Described sodium chloride is selected from mine salt and the by weight combination of 1:1 of sea salt.
Described organosilicon is selected from the cetyl polydimethylsiloxane.
Embodiment 5
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
Anion surfactant 280 grams
Amphoteric surfactant 60 grams
Conditioner 20 grams
Thickening agent 5 grams
Disodiumedetate 2 grams
Sodium chloride 520 grams
Glycol distearate 30 grams
Organosilicon 80 grams
Water 115 grams
Described anion surfactant is selected from the by weight combination of 2:3:1 of polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether sulfosuccinic monoester disodium, ammonium lauryl sulfate.
Described amphoteric surfactant is selected from cocamido propyl betaine.
Described conditioner is selected from polyquaternary ammonium salt-3 and the combination of polyquaternary ammonium salt-15 by weight 3:2.
Described thickening agent is selected from hydroxyethyl-cellulose and the by weight combination of 3:2 of guar gum.
Described sodium chloride is selected from lake salt and the by weight combination of 2:1 of sea salt.
Described organosilicon is selected from dimethyl siloxane and the by weight combination of 1:1 of siloxanes.
Embodiment 6
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
400 parts of anion surfactants
100 parts of amphoteric surfactantes
80 parts of conditioners
10 parts of thickening agents
3 parts of disodiumedetates
650 parts in sodium chloride
30 parts of glycol distearates
80 parts of organosilicons
5 parts of antiseptic
400 parts in water
Described anion surfactant is selected from the by weight combination of 1:1:1 of fatty alcohol-polyoxyethylene ether sulfosuccinic monoester disodium, sodium lauryl sulphate, dodecylbenzene sodium sulfonate.
Described amphoteric surfactant is selected from dodecyldimethylammonium hydroxide inner salt and cocamido propyl betaine by the combination of 2:3.
Described conditioner is selected from polyquaternary ammonium salt-15
Described thickening agent is selected from carboxymethyl cellulose and the by weight combination of 1:2 of hydroxyethyl-cellulose.
Described sodium chloride is selected from mine salt.
Described organosilicon is selected from cetyl polydimethylsiloxane and the by weight combination of 2:1 of dimethyl siloxane.
Described antiseptic is sodium benzoate and U.S.-BP(germall extremely) by weight the combination of 1:1.
Embodiment 7
A kind of salt shuffles suppurative mastitis, and raw material by weight forms and comprises:
200 parts of anion surfactants
20 parts of amphoteric surfactantes
10 parts of conditioners
1 part of disodiumedetate
300 parts in sodium chloride
10 parts of glycol distearates
10 parts of organosilicons
100 parts in water
Described anion surfactant is selected from fatty alcohol-polyoxyethylene ether sulfosuccinic monoester disodium.
Described amphoteric surfactant is selected from dodecyldimethylammonium hydroxide inner salt and the by weight combination of 1:3 of amine oxide.
Described conditioner is selected from polyquaternary ammonium salt-7.
Described sodium chloride is selected from mine salt.
Described organosilicon is selected from dimethyl siloxane.
Embodiment 8
Embodiment 1-7 is described, and to shuffle the step of preparation process of suppurative mastitis product as follows:
A, disodiumedetate is added to the water, after accounting for 50% disodiumedetate dissolving, adds thickening agent again, it is stand-by to stir;
After B, the mixed material that steps A is obtained are heated to 40 ℃, add the sodium chloride of anion surfactant, glycol distearate and 15%, rapid stirring also is warmed up to 75 ℃ and dissolves fully to material;
C, conditioner is joined in the material that step B obtains, after 85 ℃ of constant temperature stir 20 minutes, begin cooling, when temperature is down to 50 ℃, add amphoteric surfactant, organosilicon, antiseptic, and to adjust pH value be 5.0; When waiting to be cooled to 40 ℃, add first essence, add at last remaining sodium chloride, continue to stir, make material dispersion evenly obtain semi-finished product;
D, the semi-finished product that obtain are positioned between semi-finished vehicles namely get the leaves shampoo product after ageing 1-2 days.
Embodiment 9
Embodiment 1-7 is described, and to shuffle the step of preparation process of suppurative mastitis product as follows:
A, disodiumedetate is added to the water, after accounting for 80% disodiumedetate dissolving, adds thickening agent again, it is stand-by to stir;
After B, the mixed material that steps A is obtained are heated to 60 ℃, add the sodium chloride of anion surfactant, glycol distearate and 20%, rapid stirring also is warmed up to 85 ℃ and dissolves fully to material;
C, conditioner is joined in the material that step B obtains, after 80 ℃ of constant temperature stir 20 minutes, begin cooling, when temperature is down to 50 ℃, add amphoteric surfactant, organosilicon, antiseptic, and to adjust pH value be 7.0; When waiting to be cooled to 40 ℃, add first essence, add at last remaining sodium chloride, continue to stir, make the even semi-finished product that get of material dispersion;
D, the semi-finished product that obtain are positioned between semi-finished vehicles namely get the leaves shampoo product after ageing 1-2 days.
Embodiment 10
Embodiment 1-7 is described, and to shuffle the step of preparation process of suppurative mastitis product as follows:
A, disodiumedetate is added to the water, after accounting for 65% disodiumedetate dissolving, adds thickening agent again, it is stand-by to stir;
After B, the mixed material that steps A is obtained are heated to 50 ℃, add the sodium chloride of anion surfactant, glycol distearate and 8%-20%, rapid stirring also is warmed up to 80 ℃ and dissolves fully to material;
C, conditioner is joined in the material that step B obtains, after 75 ℃ of constant temperature stir 20 minutes, begin cooling, when temperature is down to 50 ℃, add amphoteric surfactant, organosilicon, antiseptic, and to adjust pH value be 8.0; When waiting to be cooled to 40 ℃, add first essence, add at last remaining sodium chloride, continue to stir, make the even semi-finished product that get of material dispersion;
D, the semi-finished product that obtain are positioned between semi-finished vehicles namely get the leaves shampoo product after ageing 1-2 days.