KR101564430B1 - Cosmetic preparation comprising rose of sharon extracts containing physiological active materials - Google Patents

Abstract

The present invention relates to a cosmetic which does not use an organic solvent harmful to human bodies, is produced by an extraction method capable of easily removing heavy metals and comprises a Hibiscus syriacus extract.

Description

[0001] The present invention relates to a cosmetic preparation comprising rosemary extract containing an effective physiologically active substance,

The present invention relates to cosmetics containing an active ingredient of Mugunghwa, a domestic native plant, and an oilseed rape extract which can utilize the pigment.

It has been reported that pigments contained in cosmetics, especially lipsticks, contain heavy metals such as lead, and much attention and research are focused on cosmetics that do not contain heavy metals.

Rose of sharon is a dicotyledonous plant belonging to the wolfberry family. It is cold tolerant, has a strong fertility, and is said to have efficacy such as cyanosis, fever, dehydration, detoxification and so on. Mugunghwa contains saponarin, malvalic acid, sterculic acid, tannic acid, dihydrosteroylic acid, and mucilage, which are known to be contained in large amounts in ginseng. , It has been reported that a large amount of saponin, which can help the human body's physiological activity, is contained. In addition, since Mugunghwa contains non-tar natural pigments, it can be usefully used as cosmetic raw material.

Various extraction methods have been proposed to utilize these active ingredients, but most of them use organic solvent as an extraction solvent. Therefore, there is a possibility of harmful to the human body. In addition, , Which may contain many heavy metals similar to herbal medicines.

[Patent Document 1] Registered Patent Publication No. 10-0985719 [Patent Document 2] Registered Patent Publication No. 10-0169012 [Patent Document 3] Registration Patent Publication No. 10-0169011 [Patent Document 4] Registration Patent Publication No. 10-0169006

Accordingly, the present invention provides a cosmetic composition containing a mugunghwa extract, which is prepared by a method of extracting Mugunghwa, which does not use a component such as an organic solvent harmful to human body and can easily remove heavy metals.

According to a first aspect of the present invention, there is provided a method for preparing a vegetable oil, comprising the steps of: adding lemon juice, citric acid, and purified water to a vegetable oil; Firstly heating and aging the leftover solution of the soymilk material; Heating and aging the primary heating and aged hibiscus raw material-containing solution; Allowing the secondary heating and the aged hibernation raw material-containing solution to pass through a tunnel in which a magnetic field is formed; And an oil-in-water extract (E1) prepared through a step of drying the solution containing the cigarette raw material which has passed through the tunnel.

According to a second aspect of the present invention, there is also provided a method for preparing a vegetable oil, comprising the steps of: adding pH of purified water, lemon juice or citric acid to a vegetable oil; Agitating the pH-regulated solution of the crude oil-containing material for the first time and then adding the microorganism to primary-aged the solution; Subjecting the primary aged microorganism-containing raw material solution to secondary stirring, and then extracting or extracting the active ingredient by extrusion or centrifugation; Heating the extracted active ingredient, adding microorganisms and secondary aging; Passing the second aged active ingredient through a tunnel in which a magnetic field is formed; And an oil-in-water extract (E2) prepared through a step of drying the active ingredient that has passed through the tunnel.

The present invention also provides a cosmetic comprising the extract of Hibiscus according to the first aspect and the extract of Hibiscus according to the second aspect, wherein the Hibiscus extract according to the first aspect and the Hibiscus rose extract according to the second aspect are mixed at a weight ratio of 1: 1 .

According to the present invention, the cosmetic material is at least one selected from the group consisting of lipsticks, eye shadow, ball lotion, foundation cream, cleansing foam, moisturizing gel, moisturizing cream, moisturizing milky lotion, shaving lotion, shaving cream, Gels, lip balms, shampoos, rinses, hair treatments and hair dyeing agents.

According to the present invention, it is possible to provide a cosmetic comprising an extract of Mugunghwa, which contains an effective physiologically active substance prepared by a method of extracting Mugunghwa, which does not use a component such as an organic solvent harmful to human body and can easily remove heavy metals .

Therefore, it is possible to provide cosmetics of natural materials harmless to the human body.

In addition, the cosmetic according to the present invention contains a large amount of saponin, which is a useful ingredient contained in the Hibiscus tea extract, and thus can provide an anti-aging effect.

Hereinafter, the present invention will be described in detail with examples. In describing the present invention, a detailed description of related processes or configurations will be omitted so as not to obscure the gist of the present invention.

The present invention provides a cosmetic comprising an oil-in-water extract containing an effective physiologically active substance to utilize the cell regeneration improving effect and the cell aging inhibiting effect of hibiscus.

The hibiscus extract contained in the cosmetic of the present invention is produced according to the first or second aspect.

The method according to the first aspect of the present invention comprises the steps of adding lemon juice, citric acid, and purified water to a raw material of hibiscus after adjusting the pH and allowing it to stand; Firstly heating and aging the leftover solution of the soymilk material; Heating and aging the primary heating and aged hibiscus raw material-containing solution; Allowing the secondary heating and the aged hibernation raw material-containing solution to pass through a tunnel in which a magnetic field is formed; And drying the cigarette raw material-containing solution that has passed through the tunnel.

Mugunghwa raw materials include flowers, leaves, bark, and roots collected from rose of sharon, and they are prepared separately and separately. It is preferable that the raw material of the soap is dried and pulverized in order to facilitate extraction. Drying is for primary disinfection and may be dried in a natural state or dried using hot air. The temperature of the hot air is set at 30 to 40 ° C to minimize the heat damage to the active ingredients contained in the cow's milk raw material.

It is more preferable to sterilize and purify the cow's milk raw material by irradiation with ultraviolet rays after drying or with hot air drying. Ultraviolet irradiation can be conducted while passing through a tunnel equipped with a net conveyor. When the ultraviolet rays are irradiated, impurities contained in the raw materials for cigarette fall down to the net, and ultraviolet rays can sterilize the cigarette raw materials. The pulverization can be carried out by a known method.

It is preferable that the pH is adjusted by adding purified water, lemon juice or citric acid to the selected raw materials of mugunghwa, and the pH is adjusted to 6.0 ~ 7.0. Lemon juice or citric acid is added to soften the cow's raw material. It is preferable that purified water be mixed with 60 to 70% by weight: 30 to 40% by weight of the cow's milk raw material for sufficient elution of the active ingredient. Raw materials mixed with purified water are kept at 15 ~ 20 ℃ for 1 ~ 2 days, so that raw materials are wetted.

The solution containing the wetted hibiscus raw material is firstly heated at 70 to 80 ° C for 3 to 4 hours by vacuum low pressure method and first aged at room temperature for 1 to 2 days.

The primary heating and the aged raw material-containing solution are subjected to secondary heating and secondary aging under the same conditions for sufficient elution and aging of the active ingredient.

The secondary heated and aged feedstock containing solution is allowed to pass through the tunnel in which the magnetic field is formed. It is preferable that a magnetic field tunnel formed of a pipe tube made of a sanitary elastomer resin has a magnetic field of about 30,000 (3T) to 40,000 (4T) gauss per second, It is preferable to adjust the speed of the solution to 1.2 m / s to 1.5 m / s and let it pass for about 10 to 20 seconds.

When the magnetic tunnel passes under the above-mentioned conditions, the water, organic material, salts, etc. contained in the raw material-containing solution are diamagnetic substances, which are repulsive to the magnetic field and pass through the magnetic tunnel Heavy metals such as iron (Fe), nickel, cobalt and aluminum are magnetic substances that remain magnetized in the magnetic field of the magnetic field in the magnetic tunnel, Process.

The hibiscus, which is exposed to nature, is exposed to heavy metals such as fine iron (Fe), nickel, cobalt, and aluminum in the air, and the heavy oil is contained in the cigars. For this reason, in the present invention, in order to remove a small amount of heavy metal contained in the raw material of the cow, the magnetic field is made to pass through the tunnel. This eliminates the possibility that the heavy metals contained in the raw materials of the first oil are primarily removed and the secondary metals remaining in the oil-extracted extracts cause the unnecessary chemical reactions and the like.

The solution containing the crude oil after passing through the tunnel can be made into powder or granular form after drying. The drying is preferably carried out by blowing heat at a temperature of 40 to 50 DEG C and spray drying.

On the other hand, after the step of passing through the tunnel in which the magnetic field is formed, the solution containing the crude oil is further subjected to filtration after distilling the raw material-containing solution in the far-infrared ray evaporator before drying for further purification. In the evaporator in which the far-infrared ray is radiated, the solution containing the cigarette raw material is steamed by heating and then cooled again to be filtered.

In addition, after the step of passing through the tunnel in which the magnetic field is formed, the solution containing the cigarette raw material may be passed through the ultrasonic extraction device before drying to soften the fibrous tissue contained in the solution. Ultrasonic waves irradiated from a device irradiated with ultrasonic waves can make the fibrous tissue in the solution of the cigarette raw material smoother. It is preferable that the ultrasonic irradiation treatment is carried out before the far-infrared ray evaporator treatment when it is performed like a far-infrared ray evaporator.

The method according to the second aspect of the present invention includes the step of adjusting the pH by adding purified water and lemon juice or citric acid to the raw material of hibiscus, Agitating the pH-regulated solution of the crude oil-containing material for the first time and then adding the microorganism to primary-aged the solution; Subjecting the primary aged microorganism-containing raw material solution to secondary stirring, and then extracting or extracting the active ingredient by extrusion or centrifugation; Heating the extracted active ingredient, adding microorganisms and secondary aging; Passing the second aged active ingredient through a tunnel in which a magnetic field is formed; And drying the active ingredient that has passed through the tunnel.

The preparation of the crude oil and the pH adjustment may be carried out in the same manner as in the first mode.

The pH-adjusted solution of the cow's milk raw material is first agitated and then added with the microorganism and allowed to mature first. Agitation of the pH-adjusted raw material-containing solution is preferably carried out in an aseptic stainless steel vessel with a stirrer at a rotation speed of 70 to 90 RPM for 1 to 2 hours.

Lactobacillus rhamnosus or Lactobacillus acidophilus is preferably used as the microorganism to be added to the stirred raw material-containing solution, and after addition of the microorganism, it is left to stand at 15 to 20 ° C for 24 hours to wet .

The secondary agitation of the wetted microorganism-containing raw material solution is preferably carried out with a stirrer at a rotation speed of 50 to 60 RPM per minute for 2 to 3 hours. After stirring, the active ingredient is extracted by extrusion or centrifugation.

The extracted active ingredient is preferably heated at 90 to 95 ° C for 3 to 4 hours in a vacuum low pressure manner.

It is preferable to add Streptococcus thermophilus, which is a microorganism, to the heated active ingredient, and then to perform secondary aging for 24 hours at a temperature of 40 to 45 캜 in a vacuum state.

The step of allowing the second aged active ingredient to pass through the tunnel in which the magnetic field is formed can be carried out in the same manner as in the first aspect.

The solution containing the cigarette raw material that has passed through the magnetic field forming tunnel can be made into powder or granular form after drying. The drying is preferably carried out by blowing heat at a temperature of 40 to 50 DEG C and spray drying.

The hibiscus flower extract (E1) prepared according to the first aspect and the hibiscus flower extract (E2) prepared according to the second aspect may be contained in cosmetics, respectively, or may be mixed in a weight ratio of 1: 1 when mixed.

The hibiscus flower extract (E1) prepared according to the first aspect or the hibiscus flower extract (E2) prepared according to the second aspect may exhibit various colors depending on the content of the raw material contained in the extract. Specifically, it is dark blue in the case of blue-green algae as a raw material for Mugunghwa, pink in the case of red tenderness, and dark green in the case of Mugungwha. In addition, if the Mugunghwa flower is single-stranded flower, it is possible to obtain a beautiful pigment of light purple color and light brown color in flesh color. In addition, it is possible to create a variety of colors such as light brown, reddish, and beige by mixing different colors of Mugunghwa extract, so that natural colors can be obtained when used in color cosmetics.

Examples of the cosmetics include color cosmetics such as lipstick, eye shadow, ball lotion, and foundation; Cleansing cosmetics such as cleansing creams and cleansing foams; Moisturizing cosmetics such as moisturizing gel, moisturizing cream, moisturizing milky lotion, shaving lotion or cream, ultraviolet ray lotion or cream, massage gel and moisturizing lip balm; Hair cosmetics such as shampoo, conditioner, hair treatment, hair dye and the like.

In addition to the extract of Mugunghwa, the cosmetic composition may include functional adjuvants such as tocopherol acetate, nicotinamide, and aminoacid. In addition, appropriate additives according to each formulation may be added to make cosmetics using Mugunghwa .

Hereinafter, the present invention will be described in more detail by way of examples, but it should be understood that the present invention is not limited thereto and various modifications and changes may be made by those skilled in the art.

Example

Example 1: Preparation of lipstick containing hibiscus extract

After dissolving in 100 ml of Hibiscus granulosa extract obtained according to the first aspect, 180 ml of ethanol was added and 600 ml of purified water was added. The mixture was stirred for 1 to 2 hours at a rotation speed of 70 to 80 rpm in a stainless steel stirrer. 45 to 50 g of resin powder particles having a particle size of 5.5 to 6.0 탆 are added thereto, and the mixture is allowed to stand at 55 to 60 캜 for 70 to 80 minutes so that the resin powder particles are impregnated with the hibiscus flower extract. Then, it was concentrated and dried to obtain a solid component. Through this, a variety of Mugunghwa pigment suitable for lipstick was obtained according to the blend of flower color which is the raw material of Mugunghwa.

6.0% by weight of the obtained antimony pigment, 20.0% by weight of mica, 61.0% by weight of talc and 3.0% by weight of zinc stearate were mixed and stirred. 2.0% by weight of lanolin, 7.7% by weight of liquid paraffin and 0.3% by weight of fragrance were mixed and stirred, and then the mixture containing the above-mentioned hibiscus pigment was dissolved therein. This was again concentrated and dried, powdered, and then compression molded into a mold to make a lipstick.

Lipstick was also prepared in the same manner as described above for the hibiscus extract granules obtained according to the second aspect.

For commercial products containing the manufactured lipstick and tar-based artificial coloring, sensory tests were conducted on 50 adult women, and the results are shown in Table 1 below. The evaluation of the lipstick according to the first aspect and the lipstick according to the second aspect are similar, and the values shown in the following table are averaged.

According to the sensory test, the lipstick of Example 1 was found to have a very good evaluation.

Example 2: Preparation of shampoo containing hibiscus extract

1 kg of hibiscus extract granules obtained in accordance with the first embodiment, 3 kg of ALES, 2.5 kg of ALS, purified water of 3.4 kg and a thickening agent of 100 g were mixed and uniformly stirred in vacuum to prepare a shampoo containing 10 kg of Mugunghwa extract.

The hibiscus extract granules obtained according to the second aspect were also carried out in the same manner as above to prepare shampoos.

The manufactured shampoo may be filled in a plastic pumping vessel, which is a conventional shampoo vessel, or may be charged by adding carbonic acid to a vessel made of aluminum can with a gas-filled injection system such as ordinary hair mousse . When carbonic acid is added, the carbonic acid component having a property of decomposing lipid peroxidase and the saponin component having a natural surfactant effect contained in the hibiscus extract are synergized, The dandruff removal performance can be doubled.

The manufactured shampoo was thoroughly cleaned once a day for two months in a usual manner for 10 men and women, and hair condition such as hair loss, dandruff prevention and itching was evaluated. The results are shown in Table 2 below.

According to Table 2, shampoo containing Mugunghwa extract showed very good effect on hair and scalp irrespective of the extraction sun of Mugunghwa extract.

Example 3: Preparation of hair tonic containing hibiscus extract

The hibiscus oil extract granules obtained according to the first aspect and ethanol were mixed at a weight ratio of 3: 7, stirred with a stirrer, and then sodium benzoate, tocopherol acetate, Hair tonic was prepared by adding salicylic acid, menthol, biotin, coconut oil, dexpanthenol, nicotinic acid amide, amino acid and the like according to a known hair tonic manufacturing method.

The hyaluronic acid extract granules obtained according to the second aspect were also carried out in the same manner as described above to make hair tonic.

The hair tonic was applied to the scalp for 3 months with 10 ml of male and female alopecia, which was accompanied by itching and severe dandruff.

The results are shown in Table 3 below.

According to Table 3, the hair tonic containing the extract of Mugunghwa extract showed a very good effect on the hair and scalp regardless of the extraction time of the Mugunghwa extract.

In Table 2 and Table 3 -: no symptoms, +: slight increase in hair, ++: when birth moth appeared, +++: when moth appeared, ++++: increased growth of moth Respectively.

Example 4: Preparation of a hair dye containing Hibiscus extract

A hair dye containing the extract of mugwort cosmetic extract according to the first aspect of the present invention was produced according to a known production method.

First, a hair dyeing agent agent serving as a dye is prepared. The horseradish extract granules obtained according to the first aspect were prepared by mixing 0.500 wt% of 90.430 wt% monoethanolamine, 2.505 wt% of hydroxyethylcellulose, 0.040 wt% of phenoxyethanol, 0.100 wt% of thioglycolic acid, 1.000 wt% of sodium lauryl sulfate, polyimide propyl betaine (Cocamidopropyl betaine) 1.000% by weight, 0.100% by weight EDTA, resorcinol 0.900% by weight, 1.052% by weight of m- amino-phenol, m- phenylenediamine 0.113 wt%, 2.260 wt% of p- phenylenediamine The mixture was stirred at 80 to 85 ° C for 3 to 4 minutes at a speed of 1,800 rpm to 2,000 rpm and then stirred at a speed of 150 rpm for 3 to 4 minutes with a paddle mixer. , And then 0.80 wt% of monoethanolamine is further added. Then, the mixture is cooled to 24 to 25 ° C, the mixture is filtered in a nitrogen atmosphere, and aged for 24 to 30 hours.

Next, a hair dye forming agent serving as an oxidizing agent is prepared. A mixture of 85.400% by weight of the extract of Mugunghwa cosmetic extract obtained according to the first aspect, 1.900% by weight of liquid paraffin, 3.000% by weight of cetyl alcohol, 1.000% by weight of lanolin, 0.030% by weight of phosphoric acid, 0.070% by weight of sodium pyrophosphate, And 0.300 wt% of Steartrimonium Chloride were put into a manufacturing tank and rotated at a temperature of 80 to 85 ° C at a speed of 1,800 rpm to 2,000 rpm for 3 to 4 minutes, After cooling to 45 ° C with stirring for 4 minutes in a paddle mix, the mixture is filtered in a nitrogen atmosphere and aged for 24-30 hours.

The prepared hair dyes were uniformly mixed with the first agent and the second agent, and the ratio was adjusted to a gel phase liquid, which was used by 25 adult men and women. The results are shown in Table 4.

According to Table 4, it is estimated that the hair dyeing agent according to Example 4 is slightly superior in terms of mixing property, flowability, spreadability, and hair feel, which is a performance required as a hair dyeing agent even in comparison with a commercially available hair dyeing agent. In addition, the hair dyes according to Example 4 have a merit that they are harmless to the human body as compared with commercial dyes using chemical dyes in that they use natural materials, such as Hibiscus extract, as dyes.

Claims (12)

delete Adding purified water and lemon juice or citric acid to the raw material of mugunghwa to adjust the pH to 6.0 ~ 7.0;
Agitating the pH-adjusted solution of the crude oil-containing raw material first, aging the mixture by adding Lactobacillus rhamnosus or Lactobacillus acidophilus;
Subjecting the primary aged microorganism-containing raw material solution to secondary stirring, and then extracting or extracting the active ingredient by extrusion or centrifugation;
The extracted active ingredient was heated at 90 to 95 ° C for 3 to 4 hours in a vacuum low pressure method. Then, Streptococcus thermophilus was added and the mixture was incubated at 40 to 45 ° C in vacuum for 24 hours for 2 hours. Aging;
Passing the second aged active ingredient through a tunnel having a magnetic field of 30,000 (3T) to 40,000 (4T) gauss per second; And
(E2) prepared by drying the active ingredient that has passed through the tunnel.
Adding lemon juice, citric acid, and purified water to the raw materials for cucumber seeds, adjusting the pH to 6.0 to 7.0, and allowing the leaves to stand at 15 to 20 ° C for 1 to 2 days; Firstly heating the leftover solution of the soymilk stock material at 70 to 80 ° C for 3 to 4 hours in a vacuum low pressure method and aging at room temperature for 1 to 2 days; Heating the primary heated and aged hibiscus raw material-containing solution at 70 to 80 ° C for 3 to 4 hours in a vacuum low pressure system and aging at room temperature for 1 to 2 days; Passing the secondary heating and the aged hibernation raw material-containing solution through a tunnel having a magnetic field of 30,000 (3T) to 40,000 (4T) gauss per second; And an oil-in-water extract (E1) prepared through distillation and filtration in a far-infrared ray evaporator through a tunnel and drying the solution; And
Adding purified water and lemon juice or citric acid to the raw material of mugunghwa to adjust the pH to 6.0 ~ 7.0; Agitating the pH-regulated solution of the soymilk starting material first, aging the mixture by adding Lactobacillus rhamnosus or Lactobacillus acidophilus; Subjecting the primary aged microorganism-containing raw material solution to secondary stirring, and then extracting or extracting the active ingredient by extrusion or centrifugation; The extracted active ingredient was heated at 90 to 95 ° C for 3 to 4 hours in a vacuum low pressure method. Then, Streptococcus thermophilus was added and the mixture was incubated at 40 to 45 ° C in vacuum for 24 hours for 2 hours. Aging; Passing the second aged active ingredient through a tunnel having a magnetic field of 30,000 (3T) to 40,000 (4T) gauss per second; And an oil-in-water extract (E2) prepared by drying an effective ingredient that has passed through the tunnel.
The method according to claim 2 or 3,
The above-mentioned cosmetics include lipsticks, eyelids, ball lotions, foundation creams, cleansing foams, moisturizing gels, moisturizing creams, moisturizing milks, shaving lotions, shaving creams, ultraviolet screening lotions, ultraviolet screening creams, massage gels, Shampoo, rinse, hair treatment, and hair dye.
The method of claim 3,
The cosmetic according to any one of claims 1 to 3, wherein the hibiscus flower extract (E1) and the hibiscus flower extract (E2) are contained in a weight ratio of 1: 1.
The method according to claim 2 or 3,
Wherein the purified water is mixed with 60 to 70 wt%: 30 to 40 wt% of the pulverized asparagus raw material.
The method of claim 3,
Wherein the solution containing the cigarette raw material that has passed through the tunnel is further subjected to an ultrasonic irradiation treatment before distillation and filtration in a far-infrared ray evaporator.
A shampoo of the gas-filled injection type filled with the cosmetic and carbonic acid according to claim 2 or 3. delete delete delete delete