201113063 六、發明說明： 【發明所屬之技術領域】 本發明係關於具有天然植物性果實之清潔劑，特別是 無患子果實。 【先前技術】 早期無患子普遍被應用於清潔去污之用途。但是，隨 著科技進步越來越多的石化清潔品問世後，無患子便逐漸 被取代。然而近年來爲符合環保與健康，由天然素材製成 〇 之清潔劑廣受消費者歡迎，因此坊間亦不乏含各種植物萃 取液或植物本體等天然素材製成之清潔用品。如含有無患 子果實之香皂M3 70602、洗滌顆粒CN 1 0 1 659909A、草本植 物洗滌粉 US5840669 、含無患子萃取物之洗髮乳 TW20094424。 【發明内容】 [發明欲解決之課題] 一般清潔劑如沐浴乳、洗髮精、潔手乳、洗面乳等等，201113063 VI. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to detergents having natural botanical fruits, particularly sapindus fruits. [Prior Art] Early sapindus is commonly used for cleaning decontamination purposes. However, with the advent of more and more petrochemical cleaning products, more and more children are gradually replaced. However, in recent years, in order to comply with environmental protection and health, the cleaning agent made of natural materials has been widely welcomed by consumers. Therefore, there are many cleaning products made of natural materials such as various plant extracts or plant bodies. For example, soap containing M3 70602, washing particles CN 1 0 1 659909A, herbal plant washing powder US5840669, shampoo containing schisandra extract TW20094424. SUMMARY OF THE INVENTION [Problems to be Solved by the Invention] General cleaning agents such as shower gel, shampoo, cleansing lotion, facial cleanser, etc.
Q 大多需添加增黏劑來調整清潔劑之黏稠度。再者，雖然坊 間含無患子萃取物之清潔劑眾多，然而，其中所含之植物 萃取液含量所佔比例往往過低，甚至不實。消費者亦難以 由外觀辨認含無患子萃取物之清潔劑，其是否確實含有無 患子萃取物。 另外含無患子果實或其果肉粉體之清潔用品，多爲固 體狀或粉狀（如 M370602、CN101659909A' US5840669 )。 其係因未經處理之天然無患子果實，保存期限往往不到3 201113063 個月，受潮或經泡水後保存期限更短。因此若直接添加無 患子至清潔用品中，會有穩定性差、容易產生腐敗等問題。 [解決課題之手段] 由此可知，上述含無患子萃取物之清潔劑仍有待加以 改良。本發明爲解決上述缺點，而提供一種含無患子萃取 物之清潔劑之製造方法。本發明係可利用分次添加無患子 萃取物來調整清潔劑之黏稠度，而非以添加增黏劑（增稠劑 來調整。 本發明亦提供一種含無患子果實或果肉之清潔劑之製 造方法，即將經精製後之無患子果實或果肉添加至分裝於 包裝容器之清潔劑中，放置一段時間，使其釋出無患子皂 苷。上述於包裝容器之清潔劑中釋出無患子皂苷，即所謂 的瓶中製皂方式。 [發明效果] 藉由本發明，所提供之方法即可製得含有天然無患子 果實或果肉之清潔劑，而且由於該無患子果實或果肉係經 過精製處理，故亦不易腐壞。 且，由於清潔劑中含有天然無患子果實或果肉，在使 用期間無患子皂苷亦會不斷釋出。其係有別於藉由於外部 萃取後再添加到清潔劑中之方式，藉由瓶中製皂方式可讓 使用者清楚的看到皂苷的釋出。 此外，本發明所製得之清潔劑除了可用於一般清潔用 途（例如：皮膚、毛髮、衣物、蔬果清潔或其他洗淨用途） 外，較低黏稠度的本發明製品亦可用來作爲卸妝用之清潔 -4 _ 201113063 劑。 【實施方式】 含無患子萃取物之清潔劑之製造： 在常溫中，將0.1~4重量份（較佳爲1〜2重量份，更佳 爲2重量份）氯化鈉加入55~7 5重量份（較佳爲60〜70重量 份，更佳爲65~67重量份）蒸餾水中，攪拌使其溶解後，添 加3〜23重量份（較佳爲8〜17重量份陰離子界面活性劑及 3〜1 0重量份兩性界面活性劑，更佳爲1 〇〜1 5重量份陰離子 〇 界面活性劑及5〜8重量份兩性界面活性劑）界面活性劑，並 攪拌均勻。接著依序添加3〜12重量份（較佳爲4〜11重量 份’更佳爲5~10重量份）甘油、0.1〜1.4重量份（較佳爲 0.15-1.15重量份）復脂劑、0.05〜0.35重量份抑菌劑（較佳爲 0.1〜0.25重量份）後形成混合液，再按所需要之黏稠度以多 次添加方式，將3.5~10重量份（較佳爲4.5〜7重量份，更 佳爲4 · 5重量份）之無患子萃取物加入上述混合液中，形成 & 含無患子萃取物之清潔劑。同時亦可依其所需要之目的選 擇性地適量添加各種添加物，例如：竹醋液、竹碳粉、蘆 薈或精油等等。其中竹碳粉之顆粒大小必須大於2000篩 目，較佳爲1 2000篩目。 其中該界面活性劑係包含一般清潔劑所使用之陰離子 界面活性劑、兩性界面活性劑之至少一種。其中較佳之陰 離子界面活性劑包含月桂醚硫酸鈉、烷基聚葡萄糖甘、醯 基肌胺酸鈉、胺基酸系的界面活性劑之至少一種。其中較 佳之兩性界面活性劑包括椰油醯胺丙基甜菜鹼、椰油基-甜 201113063 菜鹼、月桂基甜菜鹼之至少一種。 其中上述作爲泡沫安定劑使用之復脂劑較佳包括椰子 醯胺DEA、大豆油醯胺DEA、PEG-7椰酸甘油之至少一種。 其中上述抑菌劑較佳係包含苯甲酸甲脂、甲基氯異噻 唑啉酮、甲基異噻唑啉酮之至少一種。 其中無患子萃取物之取得可使用一般業界常用之萃取 法（CN1056 5 25A、CN 1 0 1 225349A、特開 2000- 1 92089、 1302101)，如：以水作爲萃取溶劑；或以冷萃取方式萃取， 即以低沸點有機溶劑（如：醇類或c2〜c5酯類）作爲萃 取溶劑，並將萃取液蒸餾取得萃取物。 無患子果實或果肉精製方法： 爲使無患子能長期保存，去除容易導致果實或果肉腐 敗的因子，本發明係將無患子果實進行乾燥處理、及清洗。 該乾燥處理係可使用一般常用之乾燥處理方式進行，例 如：以乾燥機在80〜12(TC下（較佳爲80〜loot：)，歷經8 〜12小時（較佳爲8〜10小時）’使其乾燥去除水分；抑或以 天然乾燥法日曬3〜7天，使其乾燥去除水分。再將無患子 果實或經去種仁之無患子果肉以乙醇溶液或異丙醇溶液清 洗、或浸入乙醇溶液或異丙醇溶液後取出進行1次或反覆 數次，並使其乾燥。 含無患子果肉之清潔劑之製造： 將含無患子萃取物之清潔劑分裝於包裝容器後，將精 製後之無患子果實或果肉直接加入分裝後的含無患子萃取 物之清潔劑中’使（無患子果實或果肉）：（清潔劑+無患子 201113063 果實或果肉）= 0.5〜3:30，放置一段時間（15天以上爲佳’ 30 天以上更佳，惟不超過5年以下），使其自然釋出無患子之 皂苷。 實施例1 在常溫中，將2重量份氯化鈉加入6 5重量份蒸餾水 中，攪拌使其溶解後，添加15重量份月桂醚硫酸鈉及8重 量份椰油醯胺丙基甜菜鹼，並攪拌均勻。接著依序添加5 重量份甘油、0.15重量份椰子醯胺DEA、0.15重量份苯甲 酸甲脂、0.05重量份甲基氯異噻唑啉酮及0.05重量份甲基 異噻唑啉酮後形成混合液，再將約4.5重量份無患子萃取 物以多次添加方式加入上述混合液中，並加入0 . 1重量份 竹醋形成含無患子萃取物之清潔劑。 實施例2 在常溫中，將2重量份氯化鈉加入67重量份蒸餾水 中，攪拌使其溶解後，添加10重量份月桂醚硫酸鈉及5重 量份椰油醯胺丙基甜菜鹼，並攪拌均勻。接著依序添加10 重量份甘油、0.15重量份椰子醯胺DEA、1重量份PEG-7 椰酸甘油、0.15重量份苯甲酸甲脂、〇.〇5重量份甲基氯異 噻唑啉酮及0.05重量份甲基異噻唑啉酮後形成混合液，再 將約4.5重量份無患子萃取物以多次添加方式，加入上述 混合液中，並加入〇. 1重量份竹醋形成含無患子萃取物之 清潔劑。 實施例3Q Most of the tackifiers need to be added to adjust the consistency of the cleaner. Furthermore, although there are many detergents containing Sapindus extracts, the proportion of plant extracts contained therein is often too low or even false. It is also difficult for consumers to identify the detergent containing the Sapindus extract from the appearance, and whether it does contain the Sapindus extract. In addition, cleaning products containing sapindus fruit or its flesh powder are mostly solid or powdery (eg, M370602, CN101659909A' US5840669). It is due to the untreated natural sarcoid fruit, and the shelf life is often less than 3 201113063 months, and the shelf life is shorter after damp or water. Therefore, if the harmless child is directly added to the cleaning article, there are problems such as poor stability and prone to spoilage. [Means for Solving the Problem] From the above, it has been found that the above-mentioned detergent containing Sapindus extract has yet to be improved. SUMMARY OF THE INVENTION The present invention has been made to solve the above disadvantages and to provide a method for producing a detergent containing a sarcoid extract. The present invention can adjust the viscosity of the detergent by using the additive addition of sapindus in a fractional manner, instead of adding a tackifier (thickener). The present invention also provides a method for producing a detergent containing sapindus fruit or pulp. The refined fruit or pulp of the sapindus is added to the detergent packaged in the packaging container and allowed to stand for a period of time to release the saxifronicin. The above-mentioned detergent in the packaging container releases the sapindus saponin, the so-called bottle. [Inventive Effect] According to the present invention, a cleansing agent containing natural sapindus fruit or pulp can be obtained by the method provided, and since the sapindus fruit or pulp is subjected to refining treatment, it is not easily spoiled. Since the detergent contains natural sapindus fruit or pulp, the sapindus saponin is continuously released during use. It is different from the method of adding soap to the detergent by external extraction, and the soap can be made in the bottle. The user clearly sees the release of the saponin. In addition, the cleaning agent prepared by the present invention can be used for general cleaning purposes ( For example, skin, hair, clothing, fruit and vegetable cleaning or other cleaning purposes, the lower viscosity of the present invention can also be used as a cleansing agent for cleaning - _ 201113063. [Embodiment] Cleansing with Sapindus extract Manufacture of the agent: 0.1 to 4 parts by weight (preferably 1 to 2 parts by weight, more preferably 2 parts by weight) of sodium chloride is added in an amount of 55 to 75 parts by weight (preferably 60 to 70 parts by weight) at normal temperature. More preferably, it is 65 to 67 parts by weight) in distilled water, and after stirring to dissolve it, 3 to 23 parts by weight (preferably 8 to 17 parts by weight of an anionic surfactant and 3 to 10 parts by weight of an amphoteric surfactant are added, More preferably, it is 1 〇~1 5 parts by weight of an anionic quinone surfactant and 5 to 8 parts by weight of an amphoteric surfactant) surfactant, and is uniformly stirred. Then, 3 to 12 parts by weight (preferably 4 to 11) are sequentially added. More preferably, it is more preferably 5 to 10 parts by weight of glycerin, 0.1 to 1.4 parts by weight (preferably 0.15-1.15 parts by weight) of a reconstituting agent, and 0.05 to 0.35 parts by weight of a bacteriostatic agent (preferably 0.1 to 0.25 parts by weight). After the formation of the mixture, and then according to the desired consistency, multiple additions, 3.5 to 10 parts by weight (preferably 4.5 to 7 parts by weight, more preferably 4 to 5 parts by weight) of the Sapindus extract is added to the above mixture to form a & detergent containing the extract of Sapindus. The desired purpose is to selectively add various additives such as bamboo vinegar, bamboo carbon powder, aloe vera or essential oil, etc. The particle size of the bamboo carbon powder must be greater than 2000 mesh, preferably 1 2000 mesh. Wherein the surfactant comprises at least one of an anionic surfactant and an amphoteric surfactant used in a general cleaning agent. Among the preferred anionic surfactants, sodium lauryl ether sulfate, alkyl polyglucose, thioglycine At least one of a sodium or amino acid surfactant. Among the preferred amphoteric surfactants are at least one of cocoamidopropyl betaine, cocoyl-sweet 201113063 alkaloids, and lauryl betaine. The re-fatting agent used as the foam stabilizer is preferably at least one of coconut decyl DEA, soybean oil decyl DEA, and PEG-7 cocoglycerol. Preferably, the bacteriostatic agent comprises at least one of methyl benzoate, methyl chloroisothiazolinone, and methyl isothiazolinone. Among them, the extract of Sapindus can be obtained by the extraction method commonly used in the industry (CN1056 5 25A, CN 1 0 1 225349A, JP-A 2000-1292089, 1302101), such as: using water as an extraction solvent; or extracting by cold extraction. That is, a low-boiling organic solvent (such as an alcohol or a c2~c5 ester) is used as an extraction solvent, and the extract is distilled to obtain an extract. Sapindus fruit or pulp refining method: In order to preserve the sarcoids for a long period of time and remove factors which easily cause fruit or pulp to be degraded, the present invention is to dry and wash the sapindus fruit. The drying treatment can be carried out by a commonly used drying treatment method, for example, in a dryer at 80 to 12 (TC (preferably 80 to loot:), for 8 to 12 hours (preferably 8 to 10 hours). 'Make it dry to remove moisture; or dry it in the natural drying method for 3 to 7 days, dry it to remove water. Then wash the fruit of the sapindus or the seed of the seedless kernel with ethanol or isopropanol solution, or immerse in ethanol solution Or the isopropyl alcohol solution is taken out once or several times and dried. The manufacture of the detergent containing the succulent pulp: After the detergent containing the schisandra extract is dispensed into the packaging container, the refined sachetberry fruit is Or the flesh is directly added to the sub-packaged detergent containing Sapindus extract (the fruit or the flesh of the fruit): (detergent + sapless 201113063 fruit or pulp) = 0.5~3:30, placed for a period of time (more than 15 days) Preferably, it is more than 30 days, but not more than 5 years, so that it naturally releases the saponin of Sapindus. Example 1 2 parts by weight of sodium chloride is added to 65 parts by weight of distilled water at normal temperature. After stirring and dissolving, 15 parts by weight of sodium lauryl ether sulfate and 8 parts by weight of cocoamidopropyl betaine were added and stirred uniformly. Then, 5 parts by weight of glycerin, 0.15 parts by weight of cocoamine DEA, and 0.15 by weight were sequentially added. a mixture of methyl benzoate, 0.05 parts by weight of methylchloroisothiazolinone and 0.05 parts by weight of methylisothiazolinone to form a mixed solution, and then about 4.5 parts by weight of the extract of Sapindus is added to the above mixture in multiple additions. And adding 0.1 part by weight of bamboo vinegar to form a detergent containing saxidu extract. Example 2 2 parts by weight of sodium chloride was added to 67 parts by weight of distilled water at room temperature, stirred to dissolve, and 10 parts by weight was added. Sodium lauryl ether sulfate and 5 parts by weight of cocoamidopropyl betaine, and stirred uniformly. Then, 10 parts by weight of glycerin, 0.15 parts by weight of cocoamine DEA, 1 part by weight of PEG-7 cocoglycerol, 0.15 by weight are sequentially added. a mixture of methyl benzoate, hydrazine, 5 parts by weight of methyl chloroisothiazolinone and 0.05 parts by weight of methyl isothiazolinone to form a mixed solution, and then about 4.5 parts by weight of the extract of Sapindus is added in multiple additions. The above mixture , And the square is added 1 part by weight Vinegar formed containing detergent extracts of Sapindus son Example 3
將無患子果實以三久牌通風乾燥機SKS-48CA在90°C 201113063 乾燥1 〇小時’再將無患子之果肉與種仁分離。將無患子果 肉浸入乙醇溶液後立即取出，並使其乾燥。 將含無患子萃取物之清潔劑分裝至包裝容器後，取精 製後之無患子果肉直接加入分裝後含無患子萃取物之清潔 劑中，使（無患子果肉）：（清潔劑+無患子果肉）=1 :30，放置 3 〇天以上，以製得含無患子果肉之清潔劑。 實施例4 除了使（無患子果肉）：（清潔劑+無患子果肉）= 2:30外， 其餘實施方式同實施例3進行。 實施例5 將由實施例3、4所製得之含無患子果肉之清潔劑搖 晃，使含較高皂苷成分的底部部分與上部之清潔劑均勻混 合，可得到低黏稠度之清潔劑。 雖然本發明參照較佳實施例而進行說明示範’惟應了 解的是在不脫離本發明之精神及範疇內，對於本發明所屬 技術領域中具有通常知識者而言，仍得有許多變化及修改。 【圖式簡單說明】 挑。 【主要元件符號說明】The fruit of the Sapindus was dried by the Sanji brand ventilation dryer SKS-48CA at 90 ° C 201113063 for 1 hour, and then the pulp of the Sapindus was separated from the seed. The succulent pulp was taken out immediately after immersing it in the ethanol solution and allowed to dry. After the detergent containing the Sapindus extract is dispensed into the packaging container, the refined Pulp fruit is directly added to the detergent containing the Sapindus extract after the package, so that (Pantilla pulp): (cleanser + sapindus pulp)=1 : 30, placed for more than 3 days to prepare a cleansing agent containing the fruit. Example 4 The other embodiment was carried out in the same manner as in Example 3 except that (Pantilla flave): (detergent + sarcoid pulp) = 2:30. Example 5 The detergent containing the succulent pulp prepared in Examples 3 and 4 was shaken to uniformly mix the bottom portion containing the higher saponin component with the upper detergent to obtain a low-viscosity detergent. While the invention has been described with respect to the preferred embodiments, it is understood that many changes and modifications may be made to those of ordinary skill in the art to which the invention pertains without departing from the spirit and scope of the invention. . [Simple description of the picture] Pick. [Main component symbol description]