CN109971564A - Natural three-dimensional laundry block that can quantitatively launch and preparation method thereof - Google Patents
Natural three-dimensional laundry block that can quantitatively launch and preparation method thereof Download PDFInfo
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- CN109971564A CN109971564A CN201910279493.XA CN201910279493A CN109971564A CN 109971564 A CN109971564 A CN 109971564A CN 201910279493 A CN201910279493 A CN 201910279493A CN 109971564 A CN109971564 A CN 109971564A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of natural three-dimensional laundry blocks and preparation method thereof that can quantitatively launch, according to parts by weight, including following components: 20-35 parts of natural surfactant, natural 1-8 parts of softening agent, powder is bonded regulator 1-5 parts, 0-5 parts of natural promoter, the natural softening agent includes glycine betaine and vegetable oil softening agent.By the constituent and preparation process of optimization laundry block, the laundry block with good " formability " and " dispersibility " has been made.The ingredient origin of laundry block is pure natural, will not environment and people be caused damages and be polluted.
Description
Technical field
The present invention relates to articles for washing technical fields, and in particular to the natural three-dimensional laundry block that can quantitatively launch and its preparation
Method.
Background technique
Laundry detergents are one of detergent, in the market existing detergent either washing powder, liquid detergent or other shapes
The product of formula is chemical detergent mostly, and the dirt-removing power of chemical detergent is mainly from surfactant.Surfactant
Molecular structure has amphipathic: one end is hydrophilic radical, and the other end is hydrophobic grouping, can be aligned on the surface of solution, is risen
To the effect for reducing surface tension, can penetrate into Lian Shui can not all seep in the fiber gap of people, in plant fiber gap
Dirt is extruded.
Existing laundry detergents, majority are all to be made using petroleum as raw material through chemical synthesis, and clean effect is good, cheap.
However chemical laundry detergents can then remain among the gap of clothing, with shipwreck to wash them, will result in chemical reagent
Residual.Remaining chemical substance (such as phosphorus), which is accumulated over a long period, not only pollutes environment, also will affect health.Studies have shown that
Chemical laundry detergents can aggravate burden of liver, induce cancer, influence human fertility's ability and immunity.In addition, chemical laundry detergents
Biological degradability it is low, it is not degradable, can also cause secondary pollution to environment, destroy ecological environment.It is few at present to adopt completely
Use pure natural product as the laundry detergents of primary raw material.
Household laundry agent at present mainly has washing powder and two kinds of liquid detergent.Powdered laundry detergents product, it is artificial to launch not
It is easily quantitative, but if then having strict demand to bulk density, mobility and hygroscopicity by washing machine quantitative mechanism washing-powder feeding.
If block/sheet made of detergent powder body is launched convenient for quantitative, but it is difficult to take into account of both " formability " and " dispersibility "
It is required that.Disintegrating agent would generally be added in order to overcome the problems, such as that solution rate is slow in some detergent products into detergent, although molten
Solution speed and storage stability are improved, but disintegrating agent forms electrolyte and insoluble substance after dispersing, to washed
Journey can adversely affect.And the current laundry detergents using pure natural product as primary raw material can not even more overcome this to ask
Topic.
Therefore, it is necessary to one kind to launch convenient for quantitative, and can combine " formability " and " dispersibility " and pure natural next
The laundry detergents of the multiple requirements such as source.
Summary of the invention
In view of the problems of the existing technology, one of the objects of the present invention is to provide a kind of natural verticals that can quantitatively launch
Body laundry block.
Another object of the present invention is to provide a kind of preparation method of natural three-dimensional laundry block that can quantitatively launch.
The invention adopts the following technical scheme:
The natural three-dimensional laundry block that can quantitatively launch, according to parts by weight, including following components:
The natural softening agent includes that glycine betaine (extracting from the root of natural plants, stem, leaf and fruit) and vegetable oil are soft
Soft dose.Further, the mass ratio of the glycine betaine and vegetable oil softening agent is 1:0.5~2.
Optionally, the natural three-dimensional laundry block that can quantitatively launch, according to parts by weight, including following components:
Further, the natural surfactant includes Fructus Gleditsia extract, soapberry extract, in tealeaves seed extract
At least one.
Optionally, the natural surfactant can be Fructus Gleditsia extract, and the Fructus Gleditsia extract can be 20-35
Part, such as 20,21,22,23,24,25,26,27,28,30,32 or 35 parts.
Saponin containing bioactive triterpene in Chinese honey locust has the big polar groups of hydrophilies such as sugared body, aglucon, organic acid in structure,
And glucoside member molecular structure is big, polarity is low, has lipophilicity, has the design feature of surfactant-like on molecular structure, is
A kind of nonionic surface active agent has good dirt-removing power.
The preparation method of Fructus Gleditsia extract: using Chinese honey locust as raw material, cleaning up, and dries, and crushes, Chinese honey locust powder is obtained, by soap
Pod powder is mixed with ethanol solution 1:2~6 in mass ratio of 30%~80% (volume fraction), stirring and leaching 1-3h, collects filtrate,
Medicinal extract, as Fructus Gleditsia extract is concentrated under reduced pressure to obtain, as an example, Fructus Gleditsia extract can be purity greater than 70%, or is greater than
80%, or it is greater than the gleditsin solution of 90% (wt).
Optionally, the natural surfactant can be soapberry extract, and the soapberry extract can be 20-
35 parts, such as 20,21,22,23,24,25,26,27,28,30,32 or 35 parts.
Containing triterpenoid saponins such as sapindosides in the pericarp of soapberry, it can be used for manufacturing the detergent of natural nuisance-free,
Play the function of surfactant.
The preparation method of soapberry extract: using soapberry fruit as raw material, cleaning up, and dries, and crushes, obtains 100-
The spaonin powder of 200 mesh, ethanol solution 1:5~10 in mass ratio of spaonin powder and 60%~80% (volume fraction) are mixed
It closes, stirring and leaching 1-3h, collects filtrate, medicinal extract, as soapberry extract is concentrated under reduced pressure to obtain, as an example, soapberry extracts
Object can be purity greater than 40%, or be greater than 50%, or be greater than 60%, or be greater than the sapindoside solution of 70% (wt).
Optionally, the natural surfactant can be tealeaves seed extract, and the tealeaves seed extract can be 20-
35 parts, such as 20,21,22,23,24,25,26,27,28,30,32 or 35 parts.
Tea seeds are the fruits of plant of theaceae tea, i.e. the fruit of tea tree, are the byproducts of Tea Production, and tea seeds are
The part of whole tea tree most nutritive value.Tea seeds oil content 18%~30% separately contains about 10% Tea Saponin, abundant
Starch, protein and soluble sugar, simultaneously containing ingredients such as tea polyphenols, tocopherols.Tea seeds are natural detergent, be can be used to
Chemical detergent is replaced, can not only remove spot, but also skin friendly.
The preparation method of tealeaves seed extract: tea seeds are crushed, and obtain the tea seeds powder of 100-200 mesh, by tea seeds powder
It is mixed with ethanol solution 1:6~10 in mass ratio of 30%~80% (volume fraction), stirring and leaching 1-3h, collects filtrate, subtract
Pressure is concentrated to give medicinal extract, as tealeaves seed extract, as an example, tealeaves seed extract can be purity greater than 70%, or is greater than
80%, or it is greater than the Tea Saponin solution of 90% (wt).
Preferably, it is that the Fructus Gleditsia extract of 1:0.5~2:1~3, soapberry mention that the natural surfactant, which is mass ratio,
Take object, tealeaves seed extract.
Further, the natural surfactant include lecithin, alkyl polyglycoside, sorbitan fatty acid ester,
At least one of sucrose fatty ester, sodium lauryl sulfate.
Optionally, the natural surfactant includes Fructus Gleditsia extract, soapberry extract, in tealeaves seed extract
At least one, while further including lecithin, alkyl polyglycoside, sorbitan fatty acid ester, sucrose fatty ester, laurel sulfuric acid
At least one of ester sodium.For example, the natural surfactant is the Fructus Gleditsia extract and sucrose fatty ester of 1:0.5~2.
Further, the vegetable oil softening agent is 1~8 part, such as 1,2,3,4,5,6,7 or 8 part.The vegetable oil is soft
Soft dose including in coconut oil, grape seed oil, apricot kernel oil, shea butter, herb mixtures tea oil, Avocado Oil, castor oil, palm oil, olive oil
At least one.
Further, powder bonding regulator is 1~5 part, such as 1,2,3,4 or 5 part.The powder bonding is adjusted
Agent includes at least one of carragheen, xanthan gum, cellulose gum, Arabic gum, guar gum, seaweed glue.
Further, the natural promoter is 0~5 part, such as 0,1,2,3,4 or 5 part.The natural promoter includes natural
At least one of pigment, natural perfume material, biological enzyme.
Further, the natural pigment include natural Beta-carotene, cuckoo florigen, grape skin color, red sorghum pigment,
Mulberry red pigment, ginkgo uranidin, purple sweet potato cyanidin, indigo fruit pigment, lycium ruthenicum anthocyanidin, in chrysanthemum uranidin at least
It is a kind of.
Further, the natural perfume material is the natural perfume material by flowers by air-drying, obtaining after milled processed, the flower
Grass include lily, chrysanthemum, orchid, Jasmine, cloves, cordate telosma, rose, sweet osmanthus, Chinese rose, lotus, in lavender extremely
Few one kind.
Further, the natural three-dimensional laundry block that the present invention described quantitatively launch spatially form, be not it is powdered,
It is not liquid, flowable state, shape is solid-state, it is important to note that laundry block of the invention is not limited only to box-shaped,
But three-dimensional form, such as can be triangle, rectangular, pentalpha, sheet, square block, such as cuboid, or irregular
Shape, convenient for being fabricated to the laundry detergents of different shapes, good appearance.The natural three-dimensional laundry block quantitatively launched of the invention
It can according to need and various shape is made, such as blocky, spherical, special-shaped shape etc..Drawing method are as follows: 15~20g of powder is taken,
(cavity cuboid 12*3*1.5cm) 0.5~0.8g/cm of apparent density is put into the stainless steel mould of hand-operated hydraulic press3, pressure maintaining
10~20s of time, the block size suppressed are 12*3* (0.4~0.6) cm, density about 1.2~1.5g/cm3.Pass through mould
The air inside powder is pressed or squeezed out, the particle aggregate of the closs packing state of compacting is formed, to guarantee the steady of its form
It is qualitative.
Laundry block product individual packaging of the invention, independent to store, the resting period is more longlasting.
Further, the laundry block does not add water soluble film, swelling agent and adhesive, to more environment-friendly.
Term " water soluble film " used herein is a kind of material by that can decompose rapidly after contacting with water, belongs to packet
Package material.That relatively conventional is PVA (polyvinyl alcohol) water soluble film, the outer packing using PVA water soluble film as laundry detergents, Ke Yida
It is quickly dissolved to water is met when washing, the effect of delivering laundry agent, but because of the physics of water soluble film, chemical property difference, it is easy to
Clothing, washing machine strainer, washing machine inner wall etc. form dirt, dirty spot, lead to blocking, bacteria breed.And it will form
Chemical residual, to environmental pollution.
The swelling agent can be poly- (the N- vinylpyrrolidone) and/or effervescent system of such as crosslinking.
Described adhesive can be for example synthetic starch, sodium carboxymethylcellulose, polyethylene glycol, acrylic resin or its
Its chemically synthesized adhesive etc..
Laundry block of the present invention does not add above-mentioned water soluble film, swelling agent and adhesive, and green non-pollution, day may be implemented
So strict standard of environmental protection.
Optionally, the usage amount of the laundry block is quantitatively added or is adjusted according to the weight of object to be cleaned, is realized and is precisely used
Amount is launched.Specifically.Such as 1 kilogram of clothing (about 3) of washing, the laundry block dosage are 8~10 grams, it can will be of the invention
The laundry block (every piece of weight is 8 grams) of sheet is made in the laundry block, launches 1 (block), may not need user in this way
Take a lot of trouble the additive amount of calculating laundry block, while in turn avoiding wasting.Optionally, such as 3 kilograms of clothing (about 10) of washing, institute
Stating laundry block dosage is 24~30 grams, and laundry block of the present invention can be made to the laundry block of 1 piece of (weight is 8 grams) sheet,
3 (block) is launched, rule is appropriate according to this launches.
The object to be cleaned includes but is not limited to following: clothes, trousers, cap, scarf, gloves, sweater, woollen sweater, plumage
Suede clothes, T-shirt, jeans, cotton, fiber crops, silk, nylon, natural fiber, chemical fibre, silk fabric and its mixture.
The preparation method for the natural three-dimensional laundry block that can quantitatively launch, comprising the following steps:
(1) according to each group distribution ratio, add water and stir it is uniformly mixed, after spray drying or freeze-drying, ground, screening system
At partial size≤200 mesh powder；
(2) powder made from step (1) is molded or is squeezed, solid shape is made.
Further, pressure≤3MPa of the molding in step (2) or extruding.
As it is used herein, "and/or" includes any and one or more associations list all combined terms of item.
Term used herein is only used for description specific embodiment, without being intended to the limitation present invention.As it is used herein, singular
Form " one ", "one", "an" and "the" are also intended to include plural form, unless the context clearly indicates otherwise.Further
Understanding, " comprising " when using in the present specification, specifies stated feature, integer, step, operation, element and/or composition,
But one or more of the other feature is not precluded the presence or addition of, integer, step operates, element, composition and/or their combination.
Unless otherwise defined, all terms (including technical and scientific term) used herein have skill belonging to the present invention
The identical meaning that those of ordinary skill is commonly understood by art field.It further understands, term, it is fixed such as in common dictionary
Justice, explains consistent with their meanings in the environment of related fields, and not idealizes or meaning too formal, unless
Here it is clearly defined.
Exemplary invention described herein can suitably lack any one or more of element limitation, here without special
It is open.Therefore, "comprising", " comprising ", the term of " containing " etc. should be by wide in range and without limitation understand.In addition, being made herein
Term expression is used as describing, there is no limit, and do not include using these any equivalent characterizations term expression be
Unintentionally, their a part of characteristic is only described, but according to right, various modifications are possible within the scope of the invention.
Therefore, although the present invention has passed through preferred embodiment and optional feature is specifically disclosed, sheet of the modification disclosed herein to embody
The variation of invention may be recorded by those skilled in the art, and such modifications and variations can be considered of the invention
Within the scope of.
Compared with the prior art, beneficial effects of the present invention:
By improving the composition and proportion of laundry block, without using disintegrating agent in the prior art (such as crosslinking hydroxyl first
Ji Xianweisuna, crospovidone), and natural softening agent (including glycine betaine and vegetable oil softening agent) is added in laundry block,
Regulator Nian Jie with natural surfactant and powder is applied in combination simultaneously, make laundry block obtained have preferable formability with
Dispersibility；It is also known that powder is lower by pressure pressure, the rate of dispersion of laundry block in water is faster, using of the invention
It does washing block component formula, stable solid shape can be formed under the pressure of≤3MPa, briquetting pressure is greatly reduced, into one
Step optimizes the dispersibility of laundry block in water, so that laundry block obtained disperses no residue in water.It is washed from there through optimization
The constituent and preparation process of clothing block, being made has good " formability " and " dispersibility " solid shape laundry block, into
And the quantitative addition of the laundry block in laundry is greatly facilitated, optimize laundry processes.Also, the ingredient origin for block of doing washing is pure
Naturally, will not environment and people be caused damages and is polluted.
Specific embodiment
In order to preferably explain the present invention, it is described further now in conjunction with following specific embodiments, but the present invention is unlimited
In specific embodiment.
Embodiment 1
Weigh 10 parts of Fructus Gleditsia extract, 10 parts of tealeaves seed extract, 2 parts of lecithin, 2 parts of glycine betaine, 2 parts of coconut oil, sea
2 parts of phycocolloid, 0.5 part of osmanthus spice add water and stir uniformly mixed (composition total mass concentration 40~50%), after spray drying, warp
It grinds, be sieved into partial size≤200 mesh powder；Powder obtained is molded or is squeezed under the pressure of 2MPa, is made
Spherical laundry block.
Embodiment 2
Weigh 10 parts of Fructus Gleditsia extract, 5 parts of soapberry extract, 10 parts of tealeaves seed extract, 3 parts of lecithin, glycine betaine 2
Part, 2 parts of palm oil, 2 parts of cellulose gum, 0.5 part of ginkgo uranidin, 0.5 part of rose fragrance add water and stir it is uniformly mixed (combination
Object total mass concentration 30~40%), it is ground, be sieved into partial size≤200 mesh powder after spray drying；2.5MPa's
Powder obtained is molded or is squeezed under pressure, blocky laundry block is made.
Embodiment 3
Weigh 10 parts of Fructus Gleditsia extract, 5 parts of soapberry extract, 10 parts of tealeaves seed extract, 5 parts of sucrose fatty ester,
2 parts of glycine betaine, 2 parts of palm oil, 2 parts of cellulose gum, 0.5 part of chrysanthemum uranidin, 0.5 part of chrysanthemum fragrance add water and stir it is uniformly mixed
(composition total mass concentration 50~60%), it is ground, be sieved into partial size≤200 mesh powder after spray drying；?
Powder obtained is molded or is squeezed under the pressure of 2.5MPa, square block laundry block is made.
Embodiment 4
Weigh 5 parts of Fructus Gleditsia extract, 5 parts of soapberry extract, 15 parts of tealeaves seed extract, sorbitan fatty acid ester
3 parts, 1 part of glycine betaine, 3 parts of herb mixtures tea oil, 2 parts of xanthan gum, 1 part of seaweed glue, 0.5 part of red sorghum pigment, 0.5 part of chrysanthemum fragrance plus water
It is uniformly mixed (composition total mass concentration 20~30%), it is ground, be sieved into partial size≤200 mesh after spray drying
Powder；Powder obtained is molded or is squeezed under the pressure of 2.5MPa, square block laundry block is made.
Embodiment 5
Weigh 10 parts of Fructus Gleditsia extract, 10 parts of soapberry extract, 10 parts of tealeaves seed extract, 3 parts of lecithin, sorbose
2 parts of alcohol acid anhydride aliphatic ester, 1 part of glycine betaine, 2 parts of shea butter, 1 part of grape seed oil, 2 parts of carragheen, natural Beta-carotene 0.5
Part, 0.5 part of chrysanthemum fragrance add water and stir uniformly mixed (composition total mass concentration 20~30%), after spray drying, it is ground,
It is sieved into partial size≤200 mesh powder；Powder obtained is molded or is squeezed under the pressure of 2MPa, spherical wash is made
Clothing block.
Comparative example 1
Weigh 10 parts of Fructus Gleditsia extract, 5 parts of soapberry extract, 10 parts of tealeaves seed extract, 2 parts of cellulose gum, ginkgo
0.5 part of uranidin, 0.5 part of rose fragrance add water and stir uniformly mixed (composition total mass concentration 30~40%), it is spraying dry
It is ground, be sieved into partial size≤200 mesh powder after dry；Powder obtained is molded or is squeezed under the pressure of 4MPa
Square block laundry block is made in pressure.
Comparative example 2
Weigh 10 parts of Fructus Gleditsia extract, 5 parts of soapberry extract, 10 parts of tealeaves seed extract, 5 parts of sucrose fatty ester,
2 parts of glycine betaine, 2 parts of cellulose gum, 0.5 part of chrysanthemum uranidin, 0.5 part of chrysanthemum fragrance add water and stir that uniformly mixed (composition is total
Mass concentration 50~60%), it is ground, be sieved into partial size≤200 mesh powder after spray drying；Under the pressure of 5MPa
Powder obtained is molded or is squeezed, square block laundry block is made.
Comparative example 3
Weigh 10 parts of Fructus Gleditsia extract, 10 parts of soapberry extract, 10 parts of tealeaves seed extract, 3 parts of lecithin, sorbose
2 parts of alcohol acid anhydride aliphatic ester, 1 part of glycine betaine, 2 parts of carragheen, 0.5 part of natural Beta-carotene, 0.5 part of chrysanthemum fragrance add water and stir it is mixed
It closes uniformly (composition total mass concentration 20~30%), it is ground, be sieved into partial size≤200 mesh powder after spray drying；
Powder obtained is molded or is squeezed under the pressure of 4MPa, square block laundry block is made.
Product test
1, molding evaluation
Form criterion of acceptability: sample seals at room temperature, stands 72h, indeformable, tack-free, freely falling body
(150cm to ceramic tile surface) scatters without fragmentation and particle.
2, dispersion test
1000 ml deionized waters being slowly stirred are plunged the sample into, container bottom particulate matter is recorded or floccule thoroughly disappears
The time of mistake.Test result is listed in table 1.
Table 1
It can be seen that product of the invention has good mouldability and dispersibility by above-mentioned test, by laundry block
Middle addition glycine betaine and vegetable oil softening agent, while regulator Nian Jie with natural surfactant and powder is applied in combination, and makes to make
The laundry block obtained has preferable formability and dispersibility, even if molding result is excellent under the pressure condition lower than comparative example
In the comparative example product for being added to disintegrating agent, and product of the invention belongs to pure natural source, does not generate danger to environment and people
Evil.
Above is only a specific embodiment of the present invention, it is not intended to limit the scope of the invention, all utilizations
The equivalent transformation that the present invention makees, is applied directly or indirectly in other relevant technical fields, similarly includes of the invention
Among scope of patent protection.
Claims (11)
1. the natural three-dimensional laundry block that can quantitatively launch, which is characterized in that according to parts by weight, including following components:
The natural softening agent includes glycine betaine and vegetable oil softening agent.
2. the natural three-dimensional laundry block according to claim 1 quantitatively launched, which is characterized in that the self-faced is living
Property agent includes at least one of Fructus Gleditsia extract, soapberry extract, tealeaves seed extract.
3. the natural three-dimensional laundry block according to claim 1 quantitatively launched, which is characterized in that the self-faced is living
Property agent include lecithin, alkyl polyglycoside, sorbitan fatty acid ester, sucrose fatty ester, in sodium lauryl sulfate extremely
Few one kind.
4. the natural three-dimensional laundry block according to claim 1 quantitatively launched, which is characterized in that the vegetable oil is soft
Agent include coconut oil, grape seed oil, apricot kernel oil, shea butter, herb mixtures tea oil, Avocado Oil, castor oil, palm oil, in olive oil
It is at least one.
5. the natural three-dimensional laundry block according to claim 1 quantitatively launched, which is characterized in that the powder bonding is adjusted
Saving agent includes at least one of carragheen, xanthan gum, cellulose gum, Arabic gum, guar gum, seaweed glue.
6. the natural three-dimensional laundry block according to claim 1 quantitatively launched, which is characterized in that the natural promoter packet
Include at least one of natural pigment, natural perfume material, biological enzyme.
7. the natural three-dimensional laundry block according to claim 6 quantitatively launched, which is characterized in that the natural pigment packet
Include natural Beta-carotene, cuckoo florigen, grape skin color, red sorghum pigment, mulberry red pigment, ginkgo uranidin, purple sweetpotato flower
One kind in green element, indigo fruit pigment, lycium ruthenicum anthocyanidin, chrysanthemum uranidin at least.
8. the natural three-dimensional laundry block according to claim 6 quantitatively launched, which is characterized in that the natural perfume material is
By flowers by the natural perfume material that air-dries, obtain after milled processed, the flowers include lily, chrysanthemum, orchid, Jasmine,
At least one of cloves, cordate telosma, rose, sweet osmanthus, Chinese rose, lotus, lavender.
9. the natural three-dimensional laundry block according to claim 1 to 8 quantitatively launched, which is characterized in that described
Laundry block does not add water soluble film, swelling agent and adhesive.
10. the natural three-dimensional laundry block according to claim 1 to 8 quantitatively launched, which is characterized in that institute
The usage amount for stating laundry block is quantitatively added according to the weight of object to be cleaned.
11. the preparation method of the natural three-dimensional laundry block of any of claims 1-10 quantitatively launched, feature
It is, comprising the following steps:
(1) according to each group distribution ratio, add water and stir it is uniformly mixed, it is ground, be sieved into grain after spray drying or freeze-drying
Diameter≤200 mesh powder；
(2) powder made from step (1) is molded or is squeezed, solid shape is made, wherein the pressure of molding or extruding≤
3MPa。
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| CN201910279493.XA CN109971564A (en) | 2019-04-09 | 2019-04-09 | Natural three-dimensional laundry block that can quantitatively launch and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910279493.XA CN109971564A (en) | 2019-04-09 | 2019-04-09 | Natural three-dimensional laundry block that can quantitatively launch and preparation method thereof |
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| CN109971564A true CN109971564A (en) | 2019-07-05 |
Family
ID=67083621
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234954A (en) * | 2020-03-06 | 2020-06-05 | 广州市百爱神生物科技有限公司 | Plant extract-containing microcapsule fragrance-retaining mother-infant detergent and preparation method thereof |
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| CN106190641A (en) * | 2016-07-27 | 2016-12-07 | 李红霞 | Laundry sheet and cleaning method |
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