CN108865505A - A kind of Tea Saponin dish washing liquid and preparation method thereof - Google Patents
A kind of Tea Saponin dish washing liquid and preparation method thereof Download PDFInfo
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- CN108865505A CN108865505A CN201810712670.4A CN201810712670A CN108865505A CN 108865505 A CN108865505 A CN 108865505A CN 201810712670 A CN201810712670 A CN 201810712670A CN 108865505 A CN108865505 A CN 108865505A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
The invention discloses a kind of Tea Saponin dish washing liquids and preparation method thereof, belong to dish washing liquid field.A kind of Tea Saponin dish washing liquid, by following parts by weight at being grouped as：13-20 parts of Tea Saponin, 20-30 parts of cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates receive 10-20 parts, 7-9 parts of sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two receive 11-13 parts, 5-7 parts of glucosides, 1-3 parts of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 5-8 parts, 1-3 parts of citric acid, 1-3 parts of sodium benzoate, 9-12 parts of deionized water, 1-3 parts of safflower essential oil, 10-12 parts of longan flower extract, 15-20 parts of seed residues of seabuckthorn enzymolysis product and 6-8 parts of fungicide.The purpose of the present invention is to provide a kind of Tea Saponin dish washing liquids and preparation method thereof, and dish washing liquid prepared by the present invention is not only environmentally protective, but also dirty removal capacities and sterilizing ability are high.
Description
Technical field
The invention belongs to dish washing liquid fields, and in particular to a kind of Tea Saponin dish washing liquid and preparation method thereof.
Background technique
Detergents and cosmetic abluent is a kind of people's widely applied daily chemical products in daily life, existing abluent product
Kind is more, mostly containing synthesis chemical washing ingredient, is not easy to reduce, and cause environment certain pollution, meanwhile, it is washing
In the process, residue problem can also be generated.In addition, the antibacterial effect of existing dish washing liquid also allows of no optimist.Current Europe, the U.S., day
This grade industrially developed country pays close attention to environmental safety, selected ingredient is to people in terms of the selection of dish washing liquid main component
It is main to become apparent from the dish washing liquid current better than China better than developing countries such as Southeast Asia for the safety of body health and ecological environment
Ingredient, in China, the development of Environmental Protection in China type dish washing detergent is slower.With the gradually enhancing of people's environmental consciousness, tableware
The developing direction in detergent future will be using environment-friendly and green type as mainstream.
Summary of the invention
The purpose of the present invention is to provide a kind of Tea Saponin dish washing liquids and preparation method thereof, and dish washing liquid prepared by the present invention is not
It is only environmentally protective, and dirty removal capacities and sterilizing ability are high.
Technical scheme is as follows：
A kind of Tea Saponin dish washing liquid, by following parts by weight at being grouped as：13-20 parts of Tea Saponin, coco-nut oil fatty acid
20-30 parts of diglycollic amide, ethoxylated alkyl sulfates receive 10-20 parts, 7-9 parts of sodium lauroyl sarcosine, cocoyl Portugal tetrem
Acid two receive 11-13 parts, 5-7 parts of glucosides, 1-3 parts of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 5-8 parts, citric acid 1-3
Part, 1-3 parts of sodium benzoate, 9-12 parts of deionized water, 1-3 parts of safflower essential oil, 10-12 parts of longan flower extract, seed residues of seabuckthorn
15-20 parts and fungicide 6-8 parts of enzymolysis product.
Further, by following parts by weight at being grouped as：15 parts of Tea Saponin, cocoanut fatty acid diethanolamide 25
Part, ethoxylated alkyl sulfates receive 15 parts, 8 parts of sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two receive 12 parts, 6 parts of glucosides, coconut palm
2 parts of oleoyl propyl betaine, ethylenediamine tetra-acetic acid two receive 6 parts, 2 parts of citric acid, 2 parts of sodium benzoate, 10 parts of deionized water, safranine
2 parts of flower essential oil, 11 parts of longan flower extract, 18 parts of seed residues of seabuckthorn enzymolysis product and 7 parts of fungicide.
Further, the fungicide is by following parts by weight at being grouped as：5-8 parts of Pericarpium Zanthoxyli extract, dandelion mention
Take 10-13 parts of liquid, 6-8 parts of asarum extracting solution, 2-5 parts of licorice extract, 4-7 parts of Rhizoma Atractylodis Macrocephalae extracting solution, 5-7 parts of orange peel extracting solution,
3-5 parts of chrysanthemum extract, 2-4 parts of Ginger P.E, 11-13 parts of pomelo peel extracting solution.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is through crushing, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 4 (m/V) plus water, soaked overnight, using the side of trypsase and papain mixed enzymolysis
Formula, enzymatic hydrolysis condition are：40-45 DEG C of temperature, pH6.8-7.5, hydrolysis time 2-2.5h, trypsase and papain it is enzyme
Amount is respectively 1400-1500U/g and 1200-1300U/g；Enzyme deactivation after enzymatic hydrolysis, by enzymolysis liquid at 2-4 DEG C 4500-
5000r/min is centrifuged 8-12min, takes supernatant, obtains seed residues of seabuckthorn enzymolysis product using micro-filtration.
Further, the preparation method of the flos longan extraction product is：It is ground by flos longan clean dry, then flos longan
It clays into power and crosses 50-53 mesh, the ethyl alcohol of 68-70%, the quality (g) of flos longan powder is added in the flos longan powder after sieving
Volume (mL) with ethyl alcohol is than m: V=1: 12；Flos longan ethanol flows back through water-bath extract again, and extraction temperature is 60-65 DEG C, leaching
It mentions 3 times, each 1-1.5h, filters centrifugation, rotary evaporation in vacuo recycles ethyl alcohol after filtering, obtains longan flower extract.
Further, the preparation method of the fungicide is：By Chinese prickly ash, dandelion, asarum, Radix Glycyrrhizae, Rhizoma Atractylodis Macrocephalae, orange peel, chrysanthemum
After the pretreatment such as flower, ginger and pomelo peel drying, crushing, sieving and impurity elimination, with the alcoholic extract 48-50h of 30%-40%,
It is concentrated under reduced pressure after extracting solution is centrifuged, obtains fungicide, the fungicide is placed in spare in 0-4 DEG C of refrigerator.
A kind of preparation method of Tea Saponin dish washing liquid, including step in detail below：Deionized water is added in reaction kettle, is added
Heat sequentially adds Tea Saponin, cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates to 65-80 DEG C in parts by weight
Receive, sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two are received, glucosides, cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two are received,
After mixing evenly, temperature is down to 20-40 DEG C for citric acid, sodium benzoate, and the pH value of solution is adjusted to 6.8-7.2, flos longan is added
Extract, seed residues of seabuckthorn enzymolysis product, safranine extrait and fungicide, are stirred until homogeneous, and the feed liquid being stirred is de-gassed,
Using vacuum outgas, vacuum cavitations dispense mixed liquor in 4.5-5Mpa, and Tea Saponin dish washing liquid can be obtained.
By adopting the above-described technical solution, the beneficial effects of the invention are as follows：
1. in composition of the invention, Tea Saponin is derived from natural nonionic surfactant as a kind of, and surface is faced
It is 0.5% that beam concentration (CMC) is handed on boundary, and HLB value 16, surface tension is minimum, has hydrophilic and oleophylic two parts, in dispersion, hair
Bubble, decontamination etc. have preferable performance；As a kind of natural surfactant, Tea Saponin not only has excellent washing
Property, also have many advantages, such as nontoxic, non-stimulated, biodegradable rapid, anti-oxidant, sterilization, pollution-free, nonhazardous, is that performance is comprehensive
Green surfactant.Safflower essential oil in the present invention, longan flower extract are rich in seed residues of seabuckthorn enzymolysis product
Bioactive ingredients are not chemical industry synthesis product, can substitute chemical solvent used in dish washing liquid, cleaning effect is good, while energy
Enough by the synergy of each component, the cell wall and cell film system of pathogenic bacteria are acted on, directly and rapidly destroys and depends on
The selective permeability to substance that the energetic supersession of membrane structure integrality and cell and organelle are depended on for existence, make nutriment with
And metabolite can not make microorganism lose nutrition and cause its growth retardation normally through cell membrane, reach the mesh of restraining and sterilizing bacteria
's；Either by inhibiting the respiration of pathogenic bacteria, so that metabolic activity is obstructed, normal dynamic membrane structure cannot be maintained, led
Cause the self-dissolving of cell.By groups such as the hydroxyls abundant that contains in the active constituent in invention, it is easy and active site in alcohol
Hydrogen bond is formed, and then leads to metabolic system disorder, and then achieve the effect that antibiotic and sterilizing.Cocoanut fatty acid diethanolamide,
Ethoxylated alkyl sulfates are received, sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two are received, glucosides, cocounut oil acyl propyl betaine are made
For nonionic surfactant, gain effect can be generated with Tea Saponin, further increase the dirt-removing power of this product, and laurel
Acylsarcosine sodium, cocoyl Portugal tetraacethyl two are received, glucosides can be improved safflower essential oil, longan flower extract, seed residues of seabuckthorn enzyme
The bioactivity of solution, to improve the sterilizing ability of the dish washing liquid.Green of the invention is harmless, has natural plant fragrance, can
It removes odors, does not stimulate skin.
2. the invention also includes the fungicide being made of traditional Chinese medicine ingredients, thus while increasing dish washing liquid sterilizing ability
Avoid its toxic side effect generated therewith.
3. of the invention novel in design, rationally, manufacture is easy, easy to industrialized production for combination；It is washed using what the present invention developed
The alternative common dish washing liquid currently on the market of clean essence is used for family, tableware, fruit and the vegetable in the places such as hotel and all kinds of dining rooms
The cleaning of dish, while having the functions such as deodorization and sterilization, removal pesticide residue, significant effect.
Specific embodiment
Technical solution of the present invention is further described in detail With reference to embodiment.
Embodiment 1：
A kind of Tea Saponin dish washing liquid, by following parts by weight at being grouped as：13 parts of Tea Saponin, coco-nut oil fatty acid diethyl
20 parts of alkylolamides, ethoxylated alkyl sulfates receive 10 parts, 7 parts of sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two receive 11 parts, sugar
5 parts of glycosides, 1 part of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 5 parts, 1 part of citric acid, 1 part of sodium benzoate, deionized water 9
Part, 1 part of safflower essential oil, 10 parts of longan flower extract, 15 parts of seed residues of seabuckthorn enzymolysis product and 6 parts of fungicide.
The fungicide is by following parts by weight at being grouped as：It is 5 parts of Pericarpium Zanthoxyli extract, 10 parts of dandelion extracting solution, thin
6 parts of pungent extracting solution, 2 parts of licorice extract, 4 parts of Rhizoma Atractylodis Macrocephalae extracting solution, 5 parts of orange peel extracting solution, 3 parts of chrysanthemum extract, ginger extract
2 parts of object, 11 parts of pomelo peel extracting solution.
The preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn through crushing, sieving and impurity elimination etc. pretreatment after,
With solid-liquid ratio 1: 4 (m/V) plus water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymatic hydrolysis condition
For：40 DEG C of temperature, pH6.8, hydrolysis time 2h, trypsase and papain enzyme concentration be respectively 1400U/g and
1200U/g；Enzyme deactivation after enzymatic hydrolysis, by enzymolysis liquid, 4500r/min is centrifuged 8min at 2 DEG C, takes supernatant, obtains using micro-filtration
Obtain seed residues of seabuckthorn enzymolysis product.
The preparation method that the flos longan extracts product is：By flos longan clean dry, then flos longan grind into powder
And 50 meshes are crossed, 68% ethyl alcohol, the quality (g) of flos longan powder and the volume of ethyl alcohol is added in the flos longan powder after sieving
(mL) than m: V=1: 12；Flos longan ethanol flows back through water-bath extract again, and extraction temperature is 60 DEG C, is extracted 3 times, each 1h, takes out
Filter centrifugation, rotary evaporation in vacuo recycles ethyl alcohol after filtering, obtains longan flower extract.
The preparation method of the fungicide is：By Chinese prickly ash, dandelion, asarum, Radix Glycyrrhizae, Rhizoma Atractylodis Macrocephalae, orange peel, chrysanthemum, ginger and
After the pretreatment such as pomelo peel drying, crushing, sieving and impurity elimination, with the alcoholic extract 48h of 30%-40%, extracting solution is centrifuged
After be concentrated under reduced pressure, obtain fungicide, the fungicide be placed in spare in 0 DEG C of refrigerator.
A kind of preparation method of Tea Saponin dish washing liquid, including step in detail below：Deionized water is added in reaction kettle, is added
Heat sequentially adds Tea Saponin to 65 DEG C in parts by weight, cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates receive,
Sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two are received, glucosides, cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two are received, lemon
After mixing evenly, temperature is down to 20 DEG C for acid, sodium benzoate, and the pH value of solution is adjusted to 6.8, longan flower extract, sea-buckthorn is added
Seed slag enzymolysis product, safranine extrait and fungicide, are stirred until homogeneous, and the feed liquid being stirred is de-gassed, de- using vacuum
Gas, vacuum cavitations dispense mixed liquor in 4.5Mpa, and Tea Saponin dish washing liquid can be obtained.
Embodiment 2：
A kind of Tea Saponin dish washing liquid, by following parts by weight at being grouped as：15 parts of Tea Saponin, coco-nut oil fatty acid diethyl
25 parts of alkylolamides, ethoxylated alkyl sulfates receive 15 parts, 8 parts of sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two receive 12 parts, sugar
6 parts of glycosides, 2 parts of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 6 parts, 2 parts of citric acid, 2 parts of sodium benzoate, deionized water
10 parts, 2 parts of safflower essential oil, 11 parts of longan flower extract, 18 parts of seed residues of seabuckthorn enzymolysis product and 7 parts of fungicide.
The fungicide is by following parts by weight at being grouped as：It is 6 parts of Pericarpium Zanthoxyli extract, 12 parts of dandelion extracting solution, thin
7 parts of pungent extracting solution, 4 parts of licorice extract, 6 parts of Rhizoma Atractylodis Macrocephalae extracting solution, 6 parts of orange peel extracting solution, 4 parts of chrysanthemum extract, ginger extract
3 parts of object, 12 parts of pomelo peel extracting solution.
The preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn through crushing, sieving and impurity elimination etc. pretreatment after,
With solid-liquid ratio 1: 4 (m/V) plus water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymatic hydrolysis condition
For：44 DEG C of temperature, pH7, hydrolysis time 2.3h, trypsase and papain enzyme concentration be respectively 1455U/g and
1255U/g；Enzyme deactivation after enzymatic hydrolysis, by enzymolysis liquid, 4600r/min is centrifuged 9min at 3 DEG C, takes supernatant, obtains using micro-filtration
Obtain seed residues of seabuckthorn enzymolysis product.
The preparation method that the flos longan extracts product is：By flos longan clean dry, then flos longan grind into powder
And 52 meshes are crossed, 69% ethyl alcohol, the quality (g) of flos longan powder and the volume of ethyl alcohol is added in the flos longan powder after sieving
(mL) than m: V=1: 12；Flos longan ethanol flows back through water-bath extract again, and extraction temperature is 63 DEG C, extracts 3 times, each 1.4h,
Centrifugation is filtered, rotary evaporation in vacuo recycles ethyl alcohol after filtering, obtains longan flower extract.
The preparation method of the fungicide is：By Chinese prickly ash, dandelion, asarum, Radix Glycyrrhizae, Rhizoma Atractylodis Macrocephalae, orange peel, chrysanthemum, ginger and
After the pretreatment such as pomelo peel drying, crushing, sieving and impurity elimination, with 35% alcoholic extract 49h, depressurized after extracting solution is centrifuged
Concentration, obtains fungicide, the fungicide is placed in spare in 0-4 DEG C of refrigerator.
A kind of preparation method of Tea Saponin dish washing liquid, including step in detail below：Deionized water is added in reaction kettle, is added
Heat sequentially adds Tea Saponin to 70 DEG C in parts by weight, cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates receive,
Sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two are received, glucosides, cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two are received, lemon
After mixing evenly, temperature is down to 30 DEG C for acid, sodium benzoate, and the pH value of solution is adjusted to 7, longan flower extract, seabuckthorn seeds is added
Slag enzymolysis product, safranine extrait and fungicide, are stirred until homogeneous, and the feed liquid being stirred is de-gassed, using vacuum outgas,
Vacuum cavitations dispense mixed liquor in 4.6Mpa, and Tea Saponin dish washing liquid can be obtained.
Embodiment 3：
A kind of Tea Saponin dish washing liquid, by following parts by weight at being grouped as：20 parts of Tea Saponin, coco-nut oil fatty acid diethyl
30 parts of alkylolamides, ethoxylated alkyl sulfates receive 20 parts, 9 parts of sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two receive 3 parts, sugar
7 parts of glycosides, 3 parts of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 8 parts, 3 parts of citric acid, 3 parts of sodium benzoate, deionized water
12 parts, 3 parts of safflower essential oil, 12 parts of longan flower extract, 20 parts of seed residues of seabuckthorn enzymolysis product and 8 parts of fungicide.
The fungicide is by following parts by weight at being grouped as：It is 8 parts of Pericarpium Zanthoxyli extract, 13 parts of dandelion extracting solution, thin
8 parts of pungent extracting solution, 5 parts of licorice extract, 7 parts of Rhizoma Atractylodis Macrocephalae extracting solution, 7 parts of orange peel extracting solution, 5 parts of chrysanthemum extract, ginger extract
4 parts of object, 13 parts of pomelo peel extracting solution.
The preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn through crushing, sieving and impurity elimination etc. pretreatment after,
With solid-liquid ratio 1: 4 (m/V) plus water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymatic hydrolysis condition
For：450 DEG C of temperature, pH7.5, hydrolysis time 2.5h, trypsase and papain enzyme concentration be respectively 1500U/g and
1300U/g；Enzyme deactivation after enzymatic hydrolysis, by enzymolysis liquid, 5000r/min is centrifuged 12min at 4 DEG C, supernatant is taken, using micro-filtration
Obtain seed residues of seabuckthorn enzymolysis product.
The preparation method that the flos longan extracts product is：By flos longan clean dry, then flos longan grind into powder
And 53 meshes are crossed, 70% ethyl alcohol, the quality (g) of flos longan powder and the volume of ethyl alcohol is added in the flos longan powder after sieving
(mL) than m: V=1: 12；Flos longan ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extracts 3 times, each 1.5h,
Centrifugation is filtered, rotary evaporation in vacuo recycles ethyl alcohol after filtering, obtains longan flower extract.
The preparation method of the fungicide is：By Chinese prickly ash, dandelion, asarum, Radix Glycyrrhizae, Rhizoma Atractylodis Macrocephalae, orange peel, chrysanthemum, ginger and
After the pretreatment such as pomelo peel drying, crushing, sieving and impurity elimination, with 40% alcoholic extract 50h, depressurized after extracting solution is centrifuged
Concentration, obtains fungicide, the fungicide is placed in spare in 4 DEG C of refrigerator.
A kind of preparation method of Tea Saponin dish washing liquid, including step in detail below：Deionized water is added in reaction kettle, is added
Heat sequentially adds Tea Saponin to 80 DEG C in parts by weight, cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates receive,
Sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two are received, glucosides, cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two are received, lemon
After mixing evenly, temperature is down to 40 DEG C for acid, sodium benzoate, and the pH value of solution is adjusted to 7.2, longan flower extract, sea-buckthorn is added
Seed slag enzymolysis product, safranine extrait and fungicide, are stirred until homogeneous, and the feed liquid being stirred is de-gassed, de- using vacuum
Gas, vacuum cavitations dispense mixed liquor in 5Mpa, and Tea Saponin dish washing liquid can be obtained.
Comparative example 1：The dish washing liquid of selection be on the market found white dish washing liquid.
Comparative example 2：Essentially identical with the formula and preparation method of embodiment 2, difference is：The dish washing liquid of comparative example 2 is not
Essential oil containing safflower, longan flower extract, seed residues of seabuckthorn enzymolysis product.
Comparative example 3：Essentially identical with the formula and preparation method of embodiment 2, difference is：The dish washing liquid of comparative example 2 is not
It is received containing cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates, sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two
It receives, glucosides, cocounut oil acyl propyl betaine.
Comparative example 4：What is selected is olive chrysanthemum dish washing liquid on the market.
Experiment test：
1. sterilization test
Test uses Suspension quantitative bactericidal test, Escherichia coli, Listeria, Staphylococcus aureus after taking activation first
Bacterium is seeded in triangle shake bottle, 37 DEG C, 160r/min shaken cultivation 36h.Then 7 groups of above-mentioned bacteria suspensions of 1ml are real with 9ml respectively
Apply the dish washing liquid of a 1-3 and comparative example 1-4 2% dilution mixing, 37 DEG C, 160r/min vibrate 30min, with dilution fall ware
Method measures detergent to Escherichia coli, Listeria, the killing logarithm of staphylococcus aureus, parallel test in triplicate,
Calculate bactericidal effect such as following table：
2. detergency is tested
It presses《Manual dishwashing detergent》The method of 9985-2000 standard of GB purchases artificial dirt, 250ppm hard water, dirt
Instrument needed for dirty ceramics plate and foam level method test detergency.Using foam end point method, Example 1-3 and right respectively
The hard water that 1000mL concentration is 250ppm is poured into enamel basin, is separately by 1000mL concentration by ratio 1-4 dish washing liquid 5mL
The hard water of 250ppm is put into tubualted bottle.Under room temperature (25 DEG C), the water outlet of tubualted bottle is opened, hard water, which flows into, rushes blistering in basin
Foam.After hard water stops flowing out (process about 45s), plate is scrubbed with 102mm pig palm fibre paintbrush, first brush 5 times clockwise, when another mistake
Needle brush 5 times, after being so repeated 1 times, the dirt being applied on plate is largely washed down, will finally not washed lower part again and be scrubbed off,
Until foam completely disappears, record washes dishes number, and is finally converted into deep bid subnumber, as a result as shown in the table.
3. safety toxicological test.
The dish washing liquid of Example 1 carries out toxicological test, foundation respectively《Foodsafety Toxicological Assessment program and method》
GB15193-2003 is resistant to metering experiment method using maximum, and dosage is set as 10000mg/kg BW, selects 20 Baise mouse,
Half male and half female.Animal fasting 16h, unlimited drinking-water before testing.The sample solution of animal 500mg/mL concentration is given using administration by gavage,
Stomach-filling amount is 0.4mL/20g weight.The poisoning manifestations and death condition that animal is observed after stomach-filling, weigh weekly 1 time, observe
14d, as a result mouse is there is no the phenomena of mortality, and also there is no significant changes for weight.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the patents of the present invention.
Claims (7)
1. a kind of Tea Saponin dish washing liquid, which is characterized in that by following parts by weight at being grouped as：13-20 parts of Tea Saponin, coconut
20-30 parts of fatty acid oil diglycollic amide, ethoxylated alkyl sulfates receive 10-20 parts, 7-9 parts of sodium lauroyl sarcosine, cocounut oil
Base Portugal tetraacethyl two receive 11-13 parts, 5-7 parts of glucosides, 1-3 parts of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 5-8 parts,
1-3 parts of citric acid, 1-3 parts of sodium benzoate, 9-12 parts of deionized water, 1-3 parts of safflower essential oil, 10-12 parts of longan flower extract,
15-20 parts and fungicide 6-8 parts of seed residues of seabuckthorn enzymolysis product.
2. Tea Saponin dish washing liquid according to claim 1, which is characterized in that by following parts by weight at being grouped as：Tea
15 parts of saponin, 25 parts of cocoanut fatty acid diethanolamide, ethoxylated alkyl sulfates receive 15 parts, 8 parts of sodium lauroyl sarcosine,
Cocoyl Portugal tetraacethyl two receive 12 parts, 6 parts of glucosides, 2 parts of cocounut oil acyl propyl betaine, ethylenediamine tetra-acetic acid two receive 6 parts, citric acid
2 parts, 2 parts of sodium benzoate, 10 parts of deionized water, 2 parts of safflower essential oil, 11 parts of longan flower extract, seed residues of seabuckthorn enzymolysis product
18 parts and 7 parts of fungicide.
3. Tea Saponin dish washing liquid according to claim 1, which is characterized in that the fungicide by following parts by weight at
It is grouped as：It is 5-8 parts of Pericarpium Zanthoxyli extract, 10-13 parts of dandelion extracting solution, 6-8 parts of asarum extracting solution, 2-5 parts of licorice extract, white
4-7 parts of art extracting solution, 5-7 parts of orange peel extracting solution, 3-5 parts of chrysanthemum extract, 2-4 parts of Ginger P.E, pomelo peel extracting solution 11-
13 parts.
4. Tea Saponin dish washing liquid according to claim 1, which is characterized in that the preparation side of the seed residues of seabuckthorn enzymolysis product
Method is：Seed residues of seabuckthorn is after the pretreatment such as crushing, sieving and impurity elimination, with solid-liquid ratio 1: 4 (m/V) plus water, soaked overnight, using pancreas
The mode of protease and papain mixed enzymolysis, enzymatic hydrolysis condition are：40-45 DEG C of temperature, pH6.8-7.5, hydrolysis time 2-
The enzyme concentration of 2.5h, trypsase and papain are respectively 1400-1500U/g and 1200-1300U/g；After enzymatic hydrolysis
Enzyme deactivation, by enzymolysis liquid, 4500-5000r/min is centrifuged 8-12min at 2-4 DEG C, takes supernatant, obtains seabuckthorn seeds using micro-filtration
Slag enzymolysis product.
5. Tea Saponin dish washing liquid according to claim 1, which is characterized in that the flos longan extracts the preparation method of product
For：By flos longan clean dry, then flos longan grind into powder and 50-53 mesh is crossed, the flos longan powder after sieving is added
The ethyl alcohol of 68-70%, the quality (g) of flos longan powder and the volume (mL) of ethyl alcohol are than m: V=1: 12；Flos longan ethanol passes through again
Water-bath reflux extraction, extraction temperature are 60-65 DEG C, extract 3 times, each 1-1.5h, filter centrifugation, rotary evaporation in vacuo after filtering
Ethyl alcohol is recycled, longan flower extract is obtained.
6. Tea Saponin dish washing liquid according to claim 3, which is characterized in that the preparation method of the fungicide is：It will spend
The pretreatment such as green pepper, dandelion, asarum, Radix Glycyrrhizae, Rhizoma Atractylodis Macrocephalae, orange peel, chrysanthemum, ginger and pomelo peel drying, crushing, sieving and impurity elimination
Afterwards, it with the alcoholic extract 48-50h of 30%-40%, is concentrated under reduced pressure after extracting solution is centrifuged, obtains fungicide, by the fungicide
It is placed in spare in 0-4 DEG C of refrigerator.
7. a kind of preparation method of Tea Saponin dish washing liquid as claimed in any one of claims 1 to 6, which is characterized in that including following
Specific steps：Deionized water is added in reaction kettle, 65-80 DEG C is heated to, sequentially adds Tea Saponin, coconut oil in parts by weight
Fatty diglycollic amide, ethoxylated alkyl sulfates are received, sodium lauroyl sarcosine, cocoyl Portugal tetraacethyl two are received, glucosides, coconut palm
Oleoyl propyl betaine, ethylenediamine tetra-acetic acid two receive, citric acid, sodium benzoate after mixing evenly, temperature is down to 20-40 DEG C, will
The pH value of solution is adjusted to 6.8-7.2, and longan flower extract, seed residues of seabuckthorn enzymolysis product, safranine extrait and fungicide is added, stirs
It mixes to uniform, the feed liquid being stirred is de-gassed, using vacuum outgas, vacuum cavitations carry out mixed liquor in 4.5-5Mpa
Packing, can be obtained Tea Saponin dish washing liquid.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666547A (en) * | 2018-12-17 | 2019-04-23 | 福州立洁生物科技有限公司 | A kind of Antibiotic liquid detergent and preparation method thereof |
| CN111690474A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Low-foaming tea saponin detergent and preparation method thereof |
| CN113881514A (en) * | 2021-11-05 | 2022-01-04 | 佛山市橙洁士洗涤剂有限公司 | Two-in-one liquid detergent for cleaning and protecting hands |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106701355A (en) * | 2016-11-03 | 2017-05-24 | 广东康绿宝科技实业有限公司 | Natural plant composition detergent and preparation method thereof |
| CN108865503A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin washing powder and preparation method thereof |
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2018
- 2018-06-29 CN CN201810712670.4A patent/CN108865505A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106701355A (en) * | 2016-11-03 | 2017-05-24 | 广东康绿宝科技实业有限公司 | Natural plant composition detergent and preparation method thereof |
| CN108865503A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin washing powder and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666547A (en) * | 2018-12-17 | 2019-04-23 | 福州立洁生物科技有限公司 | A kind of Antibiotic liquid detergent and preparation method thereof |
| CN111690474A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Low-foaming tea saponin detergent and preparation method thereof |
| CN113881514A (en) * | 2021-11-05 | 2022-01-04 | 佛山市橙洁士洗涤剂有限公司 | Two-in-one liquid detergent for cleaning and protecting hands |
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Application publication date: 20181123 |