CN101768524B - Mineral-element detergent and preparation method thereof - Google Patents
Mineral-element detergent and preparation method thereof Download PDFInfo
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- CN101768524B CN101768524B CN2010101081370A CN201010108137A CN101768524B CN 101768524 B CN101768524 B CN 101768524B CN 2010101081370 A CN2010101081370 A CN 2010101081370A CN 201010108137 A CN201010108137 A CN 201010108137A CN 101768524 B CN101768524 B CN 101768524B
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- cholla
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- 239000003599 detergent Substances 0.000 title claims abstract description 33
- 239000002366 mineral element Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000000284 extract Substances 0.000 claims abstract description 32
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 238000001914 filtration Methods 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 39
- 239000011780 sodium chloride Substances 0.000 claims description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 24
- 241000931143 Gleditsia sinensis Species 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- -1 polyoxy Polymers 0.000 claims description 16
- 235000001427 Cylindropuntia imbricata Nutrition 0.000 claims description 15
- 240000005729 Cylindropuntia imbricata Species 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 241001116389 Aloe Species 0.000 claims description 14
- 235000011399 aloe vera Nutrition 0.000 claims description 14
- 229960004756 ethanol Drugs 0.000 claims description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000002481 ethanol extraction Methods 0.000 claims description 12
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- 230000003292 diminished effect Effects 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 238000002137 ultrasound extraction Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 7
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 7
- 229940069521 aloe extract Drugs 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 5
- 241000628997 Flos Species 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 230000008719 thickening Effects 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims 2
- 125000000373 fatty alcohol group Chemical group 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 18
- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000012141 concentrate Substances 0.000 abstract description 2
- 238000005202 decontamination Methods 0.000 abstract description 2
- 230000003588 decontaminative effect Effects 0.000 abstract description 2
- 230000007062 hydrolysis Effects 0.000 abstract description 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 abstract description 2
- 230000002528 anti-freeze Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 239000003974 emollient agent Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 239000013618 particulate matter Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 241001131796 Botaurus stellaris Species 0.000 description 1
- 241000219357 Cactaceae Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000018569 Respiratory Tract disease Diseases 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
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Abstract
The invention discloses a mineral-element detergent and a preparation method thereof. The mineral-element detergent comprises the following components in part by weight: 20-35 parts of salt lake water concentrate, 5-10 parts of ionic surface active agent, 5-10 parts of non-ionic surface active agent, 10-15 parts of traditional Chinese medicine extract, 0.5-5 parts of emollient, 0.5-5 portions of cosolvent, 0.5-5 parts of antifreeze and balance of de-ionized water. The preparation method comprises the following steps: adding the components based on the proportion, thoroughly mixing, adding the de-ionized water based on the proportion, and uniformly mixing; and carrying out supersonic treatment for 30-50 minutes, stirring at 50-60 DEG C until the solution is uniform and transparent, cooling to room temperature, and filtering to obtain the mineral-element detergent. The product has the advantages of good sterilization and decontamination capability, and ensures no residue, no opaqueness, no precipitation and no secondary pollution after hydrolysis.
Description
Technical field
The present invention relates to a kind of liquid detergent and preparation method thereof, particularly a kind of is the liquid detergent and preparation method thereof of activeconstituents with the salt lake water mineral element.
Background technology
Existing various liquid detergent belongs to synthetic class washing composition, have higher soil removability and stronger sterilizing ability, wherein main decontamination active substance is the chemosynthesis material, these materials have non-degradable, and wherein contained white dyes, formaldehyde all are carcinogenss, and the sewage that uses the back discharging also can serious environment pollution.But along with the raising of people's living standard, these petrochemical industry synthetic detergents are used in a large number, are used in the kitchen of ordinary people, are used for catering trade, and people's health has been caused serious threat.
China western part is high and cold, the arid area accumulates and educating countless salt lake, endless precious precious deposits in the salt lake.The salt lake that has is exactly the sea in ancient times, and owing to crust rising, seawater withdrawed from afterwards, and a interior basin that can't see the limit has just occurred, and develops into the salt lake.The salt lake that has develops from the freshwater lake development and forms.The bump height of its lake rim shoal is all different at different times, and when shoal was lower than sea level, lake basin was the semi-closure stream mode, and seawater flows into; When shoal surpassed sea level, lake basin was and closes stream mode.Weather prolonged drought, sweltering heat, concentrate and also to become bittern the lake water violent evaporation, and salt deposits gradually.
Introduce the development and use and the Sustainable development of the western salt lake resources of China, environmental system in " reticent precious deposits one salt lake resources " book specially.System introduction the distribution of Chinese salt lake, Chinese salt lake type, salt lake be salt lake resources that how to form, Chinese, salt lake resources in the developing status of Chinese national economy, science and reasonably develop western salt lake resources, salt lake resources exploitation and Sustainable development or the like how.Mineral substance in the salt lake saline is 10 times of common seawater generally at 25%-35%, the natural mineral prime element of multiple needed by human in containing: mineral elements such as calcium, magnesium, potassium, chlorine.Once put down in writing the magical curative effect of the mineral substance of salt lake saline in the Compendium of Material Medica, and claimed it " to make moist, full of vitality, the difficult aging of people's skin " tetter, rheumatalgia and respiratory tract disease.Research proves that also salt lake saline has good sterilization, soil removability, is fit to be developed to natural, the product of keeping a public place clean efficiently, but does not find with the salt lake water to be the relevant report and the product of liquid detergent of main active ingredient at present.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, provide a kind of sterilization, the ability that degreases is strong, the salt lake water mineral-element detergent of clean environment firendly and preparation method thereof.
A kind of mineral-element detergent comprises following component: salt lake saline enriched material, anion surfactant, nonionogenic tenside, Chinese medical extract, softener, solubility promoter, antifreezing agent and deionized water;
The shared ratio of wherein above-mentioned each component can be by weight:
20～35 parts of salt lake saline enriched materials
5～10 parts of ionic surface active agents
5～10 parts of nonionogenic tensides
10～15 parts of Chinese medical extracts
0.5～5 part of softener
0.5～5 part of solubility promoter
0.5～5 part of antifreezing agent
All the other are deionized water;
Wherein said salt lake saline enriched material obtains by following preparation method:
Get salt lake water, filter, pass through the gac filter bed again, handle with ozone treatment apparatus at last, and adjusting salt lake saline pH value reaches 7-10 through sand filter; Treated lake water is injected the finished product pond, thickening, spraying drying makes salt lake saline enriched material pulvis with dry thing through micronizing again;
Wherein said Chinese medical extract is: Oleum Cocois, Flos Rosae Rugosae quintessence oil or Herba Lysimachiae foenumgraeci quintessence oil and Fructus Gleditsiae Abnormalis extract, Radix et Caulis Opuntiae Dillenii extract, Aloe extract etc. are according to mass ratio 1: the 5-10 mixed obtains mixture;
Wherein said Fructus Gleditsiae Abnormalis extract, Radix et Caulis Opuntiae Dillenii extract, Aloe extract make according to following method:
Chinese honey locust, Root and stem of Cholla or aloe are dried, pulverize, sieve, and with ethyl acetate ultrasonic assisted extraction 3 times, each 1 hour, the mince ratio of volume and weight of ethyl acetate and Chinese honey locust, Root and stem of Cholla or aloe powder was 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, and concentrating under reduced pressure is flung to solvent, obtains Chinese honey locust, Root and stem of Cholla or Aloe extract; Or Chinese honey locust, Root and stem of Cholla or aloe dried, pulverize, sieve, with the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and Chinese honey locust, Root and stem of Cholla or aloe powder mince and the ratio of weight are 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains Chinese honey locust, Root and stem of Cholla or aloe ethanol extraction.
Described ionogenic surfactant is that poly alkyl alcohol alkene ether salt, Fatty Alcohol(C12-C14 and C12-C18) polyoxy alkene ether salt are aliphatic alcohol polyethenoxy hydrocarbyl ether salt, poly alkyl alcohol butylene hydrocarbyl ether salt, calcium dodecylbenzene sulphonate, sodium dodecyl benzenylsulfonate, preferred fat alcohol polyoxyethylene hydrocarbyl ether vitriol and sodium dodecyl benzenylsulfonate are pressed 1: 1 composite mixture of mass ratio;
Described nonionic surface active agent is alkylol amide salt, fatty alkanol amide salt; Preferred fat acyl diethanolamine;
Used solubility promoter is a dehydrated alcohol;
Used softener is a glycerine;
Used antifreezing agent is ethylene glycol or glycerol.
The preparation method of above-mentioned mineral-element detergent, comprise following operation steps: salt lake saline enriched material, Chinese medical extract and tensio-active agent, solubility promoter, softener, antifreezing agent are added in proportion, thorough mixing adds distilled water in proportion or deionized water mixes; Apply supersound process, the supersound process condition is as follows: ultrasonic power 200-500W, circulation rotating speed 10-20r/s, work/intermittence than 1,2,3s/s, supersound process time 30-50min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent.
The advantage of product of the present invention is that salt lake saline contains abundant mineral element, is equipped with the Chinese medical extract with soil removability again, has sterilization preferably, soil removability; In use can not generate toxicant, noresidue after the hydrolysis, not muddy, do not precipitate, non-secondary pollution, the main active substances of product of the present invention all is that crude substance, environmental protection, raw material are easy to get, cost is low.
Embodiment
Further illustrate the present invention below by example, but do not place restrictions on the present invention.
Embodiment 1:
Material rate is as follows:
Salt lake saline enriched material 20 grams
Ionic surface active agent 5 grams
Nonionogenic tenside 5 grams
Chinese medical extract 10 grams
Softener 0.5 gram
Solubility promoter 0.5 gram
Antifreezing agent 0.5 gram
All the other are deionized water;
The preparation process of salt lake saline enriched material: get Yuncheng, Shanxi salt lake saline double centner, filter through sand filter earlier and remove particulate matter, pass through the gac filter bed again, handle with ozone treatment apparatus at last, wherein the concentration of ozone is 13.6mg/m
3≤ O
3Concentration≤40mg/m
3, and adjusting salt lake saline pH value reaches 8; Treated lake water is injected the finished product pond, dehydration by evaporation, spray-dried again to the finite concentration, drier thing is made 20 kilograms in salt lake saline enriched material pulvis through micronizing at last;
The preparation process of Chinese medical extract: Chinese honey locust is dried, pulverizes, sieved, use the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and spaonin powder mince and the ratio of weight are 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains the Chinese honey locust ethanol extraction; Oleum Cocois is the commercially available prod.
The preparation process of above-mentioned mineral-element detergent: salt lake saline enriched material, the Chinese medical extract (wherein the ratio of Oleum Cocois and Chinese honey locust ethanol extraction is 1: 5) of aforementioned proportion are added in proportion with ionogenic surfactant (aliphatic alcohol polyethenoxy hydrocarbyl ether vitriol), nonionic surface active agent (diethanolamine of fat acyl), solubility promoter (dehydrated alcohol), softener (glycerine), antifreezing agent (ethylene glycol), thorough mixing adds distilled water in proportion or deionized water mixes; Apply supersound process, the supersound process condition is as follows: ultrasonic power 200W, circulation rotating speed 10/s, work/intermittence is than 1s/s, supersound process time 30min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent of the present invention.
Embodiment 2:
Material rate is as follows:
Salt lake saline enriched material 35 grams
Ionic surface active agent 10 grams
Nonionogenic tenside 10 grams
Chinese medical extract 15 grams
Softener 5 grams
Solubility promoter 5 grams
Antifreezing agent 5 grams
All the other are deionized water;
The preparation process of salt lake saline enriched material: get Qaidam salt lake saline double centner, filter through sand filter earlier and remove particulate matter, pass through the gac filter bed again, handle with ozone treatment apparatus at last, wherein the concentration of ozone is 13.6mg/m
3≤ O
3Concentration≤40mg/m
3, and adjusting salt lake saline pH value reaches 9; Treated lake water is injected the finished product pond, dehydration by evaporation, spray-dried again to the finite concentration, drier thing is made 25 kilograms in salt lake saline enriched material pulvis through micronizing at last;
The preparation process of Chinese medical extract: aloe is dried, pulverizes, sieves, use the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and aloe powder mince and the ratio of weight are 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains the aloe ethanol extraction; Oleum Cocois is the commercially available prod.
The preparation process of above-mentioned mineral-element detergent: salt lake saline enriched material, the Chinese medical extract (wherein the ratio of Oleum Cocois and aloe ethanol extraction is 1: 10) of aforementioned proportion are added in proportion with ionogenic surfactant (sodium dodecyl benzenylsulfonate), nonionic surface active agent (diethanolamine of fat acyl), solubility promoter (dehydrated alcohol), softener (glycerine), antifreezing agent (ethylene glycol), thorough mixing adds distilled water in proportion or deionized water mixes; Apply supersound process, the supersound process condition is as follows: ultrasonic power 300W, circulation rotating speed 15/s, work/intermittence is than 2s/s, supersound process time 40min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent of the present invention.
Embodiment 3:
Material rate is as follows:
Salt lake saline enriched material 25 grams
Ionic surface active agent 7 grams
Nonionogenic tenside 8 grams
Chinese medical extract 12 grams
Softener 4 grams
Solubility promoter 3 grams
Antifreezing agent 4 grams
All the other are deionized water;
The preparation process of salt lake saline enriched material: get Qaidam salt lake saline double centner, filter through sand filter earlier and remove particulate matter, pass through the gac filter bed again, handle with ozone treatment apparatus at last, wherein the concentration of ozone is 13.6mg/m
3≤ O
3Concentration≤40mg/m
3, and adjusting salt lake saline pH value reaches 9; Treated lake water is injected the finished product pond, dehydration by evaporation, spray-dried again to the finite concentration, drier thing is made 25 kilograms in salt lake saline enriched material pulvis through micronizing at last;
The preparation process of Chinese medical extract: Root and stem of Cholla is dried, pulverizes, sieves, use the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and cactus powder mince and the ratio of weight are 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains the Root and stem of Cholla ethanol extraction; Flos Rosae Rugosae quintessence oil is the commercially available prod.
The preparation process of above-mentioned mineral-element detergent: (aliphatic alcohol polyethenoxy hydrocarbyl ether vitriol and sodium dodecyl benzenylsulfonate are pressed 1: 1 composite mixture of mass ratio with ionogenic surfactant with salt lake saline enriched material, the Chinese medical extract (wherein the ratio of Flos Rosae Rugosae quintessence oil and Root and stem of Cholla ethanol extraction is 1: 10) of aforementioned proportion; ), nonionic surface active agent (diethanolamine of fat acyl), solubility promoter (dehydrated alcohol), softener (glycerine), antifreezing agent (glycerol) add in proportion, thorough mixing, add distilled water in proportion or deionized water mixes: apply supersound process, the supersound process condition is as follows: ultrasonic power 500W, circulation rotating speed 20/s, work/intermittence is than 3s/s, supersound process time 50min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent of the present invention.
Embodiment 4:
Material rate is as follows:
Salt lake saline enriched material 25 grams
Chinese medical extract 12 grams
Solubility promoter 3 grams
Antifreezing agent 4 grams
All the other are deionized water;
The preparation process of salt lake saline enriched material: get Qaidam salt lake saline double centner, filter through sand filter earlier and remove particulate matter, pass through the gac filter bed again, handle with ozone treatment apparatus at last, wherein the concentration of ozone is 13.6mg/m
3≤ O
3Concentration≤40mg/m
3, and adjusting salt lake saline pH value reaches 9; Treated lake water is injected the finished product pond, dehydration by evaporation, spray-dried again to the finite concentration, drier thing is made 25 kilograms in salt lake saline enriched material pulvis through micronizing at last;
The preparation process of Chinese medical extract: Chinese honey locust is dried, pulverizes, sieved, use the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and spaonin powder mince and the ratio of weight are 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains the Chinese honey locust ethanol extraction; Oleum Cocois is the commercially available prod.
The preparation process of above-mentioned mineral-element detergent: salt lake saline enriched material, Chinese medical extract (wherein the ratio of Oleum Cocois and Chinese honey locust ethanol extraction is 1: 10), solubility promoter (dehydrated alcohol), the antifreezing agent (glycerol) of aforementioned proportion are added in proportion, thorough mixing adds distilled water in proportion or deionized water mixes; Apply supersound process, the supersound process condition is as follows: ultrasonic power 500W, circulation rotating speed 20/s, work/intermittence is than 3s/s, supersound process time 50min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent of the present invention.
Embodiment 5:
Material rate is as follows:
Ionic surface active agent 10 grams
Nonionogenic tenside 10 grams
Chinese medical extract 15 grams
Softener 5 grams
Solubility promoter 5 grams
Antifreezing agent 5 grams
All the other are deionized water;
The preparation process of Chinese medical extract: Chinese honey locust is dried, pulverizes, sieved, use the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and spaonin powder mince and the ratio of weight are 5: 1 (ml/g); Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains the Chinese honey locust ethanol extraction; Oleum Cocois is the commercially available prod.
The preparation process of above-mentioned mineral-element detergent: Chinese medical extract (wherein the ratio of Oleum Cocois and Chinese honey locust ethanol extraction is 1: 10) and ionogenic surfactant (sodium dodecyl benzenylsulfonate), nonionic surface active agent (diethanolamine of fat acyl), solubility promoter (dehydrated alcohol), softener (glycerine), the antifreezing agent (ethylene glycol) of aforementioned proportion are added in proportion, thorough mixing adds distilled water in proportion or deionized water mixes; Apply supersound process, the supersound process condition is as follows: ultrasonic power 300W, circulation rotating speed 15/s, work/intermittence is than 2s/s, supersound process time 40min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent of the present invention.
Liquid detergent benchmark test: (State Standard of the People's Republic of China's manual dishwashing washing composition GB9985-2000)
One stability test:
Product of the present invention is placed 24h in one 3 ℃～one 10 ℃ refrigerator, take out and observe no crystallization when returning to room temperature, does not have precipitation; (place 24h in 40 ± I) ℃ the insulation can, taking-up is observed not stratified, haze-free immediately, and does not change smell.
Two sterilization experiments:
Test group: with the liquid detergent after the dilution is the experiment bacteria suspension that sterilizing agent acts on intestinal bacteria, streptococcus aureus, and sampling is also poured into inoculation with agar, cultivates 48h, the observation net result in 37 ℃.
Control group: replace disinfectant solution with standard hard water, test by above-mentioned same step.The gained result represents the original concentration of bacterium liquid, kills logarithmic starting point concentration with it as calculating.
Calculate viable bacteria concentration (cfu/mL) of each group, and be scaled logarithmic value (N), and be calculated as follows and kill logarithmic value:
Kill in logarithmic value (No)-test group viable bacteria concentration logarithmic value (Nx) the suspension quantitative disinfecting test of logarithmic value (KL)=average viable bacteria concentration of control group, kill logarithmic value 〉=5, promptly this effect product sterilization of decidable is qualified.
The mensuration of three detersive poweies:
With reference to GB9985-2000 appendix B, method one, the rate of deoiling method (arbitration law).
The mensuration of four other every indexs of liquid detergent
According to the washing composition requirement of GB 9985-2000 manual dishwashing, measure product appearance, smell, stability, foaming properties and pH value.
Every test index of table 1. embodiment of the invention product
Claims (6)
1. a mineral-element detergent is characterized in that composed of the following components: salt lake saline enriched material, anion surfactant, nonionogenic tenside, Chinese medical extract, softener, solubility promoter, antifreezing agent and deionized water;
The shared ratio of wherein above-mentioned each component is by weight:
All the other are deionized water;
Wherein said Chinese medical extract is: Oleum Cocois, Flos Rosae Rugosae quintessence oil or Herba Lysimachiae foenumgraeci quintessence oil and Fructus Gleditsiae Abnormalis extract, Radix et Caulis Opuntiae Dillenii extract or Aloe extract are according to mass ratio 1: the 5-10 mixed obtains mixture; Wherein said Fructus Gleditsiae Abnormalis extract, Radix et Caulis Opuntiae Dillenii extract or Aloe extract are according to following method system: Chinese honey locust, Root and stem of Cholla or aloe are dried, pulverize, sieve, with the ultrasonic assisted extraction of ethyl acetate 3 times, each 1 hour, the volume that ethyl acetate and Chinese honey locust, Root and stem of Cholla or aloe powder mince and the ratio of weight were 5: 1ml/g; Filtration under diminished pressure merges No. 3 times extracting solution, and concentrating under reduced pressure is flung to solvent, obtains Chinese honey locust, Root and stem of Cholla or Aloe extract; Or Chinese honey locust, Root and stem of Cholla or aloe dried, pulverize, sieve, with the ultrasonic assisted extraction of ethanol 3 times, the volume that ethanol and Chinese honey locust, Root and stem of Cholla or aloe powder mince and the ratio of weight are 5: 1ml/g; Filtration under diminished pressure merges No. 3 times extracting solution, filters, and concentrating under reduced pressure is flung to solvent, obtains Chinese honey locust, Root and stem of Cholla or aloe ethanol extraction.
2. a kind of mineral-element detergent according to claim 1, it is characterized in that wherein said salt lake saline enriched material obtains by following preparation method: get salt lake water, filter through sand filter, pass through the gac filter bed again, handle with ozone treatment apparatus at last, and adjusting salt lake saline pH value reaches 7-10; Treated lake water is injected the finished product pond, thickening, spraying drying makes salt lake saline enriched material pulvis with dry thing through micronizing again.
3. a kind of mineral-element detergent according to claim 1 is characterized in that wherein said anion surfactant is Fatty Alcohol(C12-C14 and C12-C18) polyoxy alkene ether salt, calcium dodecylbenzene sulphonate, Sodium dodecylbenzene sulfonate; Described nonionogenic tenside is a diethanolamine of fat acyl; Used solubility promoter is a dehydrated alcohol; Used softener is a glycerine; Used antifreezing agent is ethylene glycol or glycerol.
4. a kind of mineral-element detergent according to claim 3 is characterized in that wherein said anion surfactant is an aliphatic alcohol polyethenoxy hydrocarbyl ether salt.
5. a kind of mineral-element detergent according to claim 3 is characterized in that wherein said anion surfactant is that aliphatic alcohol polyethenoxy hydrocarbyl ether vitriol and Sodium dodecylbenzene sulfonate are by 1: 1 composite mixture of mass ratio.
6. based on the preparation method of the described a kind of mineral-element detergent of claim 1-5, comprise following operation steps: salt lake saline enriched material, Chinese medical extract and tensio-active agent, solubility promoter, softener, antifreezing agent are added in proportion, thorough mixing adds deionized water in proportion and mixes; Apply supersound process, the supersound process condition is as follows: ultrasonic power 200-500W, circulation rotating speed 10-20r/s, work/intermittence than 1,2,3s/s, supersound process time 30-50min, 50 ℃～60 ℃ stirrings down to homogeneous transparent, be cooled to room temperature, filtration, make mineral-element detergent.
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| CN1948449A (en) * | 2006-03-29 | 2007-04-18 | 成都死海盐疗健康馆服务有限公司 | Mineral salt perfumed soap |
| CN101492636A (en) * | 2009-03-03 | 2009-07-29 | 周慧堂 | Mineral surroundings cleanser and method for preparing the same |
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Effective date of registration: 20170313 Address after: 212000 Zhenjiang City, Jiangsu province Runzhou District Nan Xu Road No. 101 Zhenjiang high tech Zone Innovation Building University Science Park building C Room 301 Patentee after: Jiangsu Dragon Boat Mineral Technology Co.,Ltd. Address before: 212002 Zhenjiang City, Jiangsu province Runzhou district was built 16 room 2-303 Patentee before: Ge Xin Patentee before: Chen Junxi |
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