CN106701355A - Natural plant composition detergent and preparation method thereof - Google Patents
Natural plant composition detergent and preparation method thereof Download PDFInfo
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- CN106701355A CN106701355A CN201610950349.0A CN201610950349A CN106701355A CN 106701355 A CN106701355 A CN 106701355A CN 201610950349 A CN201610950349 A CN 201610950349A CN 106701355 A CN106701355 A CN 106701355A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a natural plant composition detergent and a preparation method thereof. According to the prepared detergent, a natural plant composition is adopted as a main raw material, a composite prepared from a natural plant extract is adopted as an antibacterial agent, and the synergistic antibacterial and bactericidal effects of a chitosan amphoteric high molecular surfactant and the natural plant extract are utilized, so that the antibacterial activity is greatly improved, the detergent has the characteristics of broad antibacterial spectrum and high antibacterial efficiency, an antibacterial effect is effectively achieved, meanwhile, dirt and pesticide residues can be removed, and an odor elimination effect is also achieved.
Description
Technical field
The present invention relates to a kind of liquid detergent, particularly a kind of natural plant composition liquid detergent and preparation method thereof.
Background technology
With the enhancing of environmental consciousness, people propose three and substantially greatly today's society on to the pursuit of the clean product of novel washing
Ask：Green Product；Using safely, the neutral products that do not hurt hands；Detergency product high.Detergent for tableware class for many years
Health safety issues involved by product increasingly cause the concern of people.The chemical residual of liquid detergent be possible to it is direct or
Ground connection influence health.Therefore using not harmful to human, do not destroy living environment, non-toxic and non-pollution green safety and wash
Clean essence just turns into the task of top priority.Selecting party of the industrially developed country such as current Europe, the U.S., Japan in liquid detergent key component
Face, pays close attention to environmental safety, and its selected composition is to the security of health and ecological environment better than the development such as Southeast Asia
Middle country, becomes apparent from the liquid detergent main component current better than China, in the development ratio of China's Environmental Protection in China type dish washing detergent
It is slower.With the progressively enhancing of people's environmental consciousness, following developing direction of dish washing detergent will be with environment-friendly and green type
Main flow.
Through investigating pertinent literature, Chinese Patent Application No. 201210241913.3 discloses a kind of washing containing Tea Saponin
Clean essence, during sodium sulfate of polyethenoxy ether of fatty alcohol, production sodium sulfate of polyethenoxy ether of fatty alcohol are contained in this liquid detergent
Diox accessory substance , dioxs can be produced to belong to noxious material, can be irritant to skin, eye and respiratory system, and can
Liver, kidney and nervous system can be caused damage, long-term use is also possible to can be carcinogenic.
The content of the invention
In view of this, the present invention provides a kind of natural plant composition liquid detergent and preparation method thereof, and prepared by the present invention washes
With natural plant composition as primary raw material, the compound prepared by natural plant extracts is used as antiseptic to clean essence, based on shell
The antibiotic and sterilizing cooperative effect of glycan amphoteric polymeric surfactant and natural plant extracts, its antibacterial activity is significantly carried
Height, with has a broad antifungal spectrum, antimicrobial efficiency is high the characteristics of, while effective sterilized, dirt can be removed and agriculture is residual, and played and remove
The effect of taste.
The technical scheme is that：A kind of natural plant composition liquid detergent, by following parts by weight into being grouped into：Shell
34-52 parts of glycan amphoteric polymeric surfactant, Tea Saponin 12-23 parts, cocoanut fatty acid diethanolamide 22-34
Part, deionized water 8-14 parts, 2-5 parts of safflower essential oil, 13-17 parts of longan flower extract, seed residues of seabuckthorn enzymolysis product 14-
27 parts.
Further, described natural plant composition liquid detergent, by following parts by weight into being grouped into：Shitosan both sexes
High molecular surfactant 38-46 parts, Tea Saponin 15-19 parts, cocoanut fatty acid diethanolamide 26-31 parts, deionization
Water 9-12 parts, 3-5 parts of safflower essential oil, 14-16 parts of longan flower extract, 18-23 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=10-22.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 6.8-7.2, adds flos longan to extract
Thing, seed residues of seabuckthorn enzymolysis product, safranine extrait, is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, de- using vacuum
Gas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtain natural plant composition liquid detergent.
The beneficial effects of the present invention are：Modern design, combination is reasonable, and manufacture is easy, it is easy to industrialized production；Use
The alternative liquid detergent common in the market of liquid detergent that the present invention is developed is used for family, the place such as hotel and all kinds of dining rooms
The cleaning of tableware, fruit and vegetables, while having the functions, effect is significant such as deodorization and sterilization, removal residues of pesticides；In the composition
The surfactants such as shitosan amphoteric polymeric surfactant do not only have excellent washing performance, and possess nontoxic, non-stimulated, raw
The performances such as thing degraded is rapid, safety, are the comprehensive green surfactants of performance；Safflower essential oil in the present invention, flos longan carries
Thing is taken, is not chemical industry synthesis product containing abundant bioactive ingredients in seed residues of seabuckthorn enzymolysis product, in can substituting liquid detergent
The chemical solvent for using, cleaning performance is good, while the cell membrane of pathogenic bacteria can be acted on by the Synergistic of each component
With cell film system, the energetic supersession and cell that depend on membrane structure integrality is destroyed directly and rapidly and organelle is depended on for existence
The selective permeability to material, make nutriment and metabolite normally through cell membrane microorganism cannot be made to lose battalion
Support and cause its growth retardation, reach the purpose of restraining and sterilizing bacteria；Or by suppressing the respiration of pathogenic bacteria, make metabolic activity
It is obstructed, it is impossible to maintain normal dynamic membrane structure, cause the self-dissolving of cell.It is abundant by what is contained in the active component in invention
The group such as hydroxyl, hydrogen bond is easily formed with active site in alcohol, and then cause metabolic system disorderly, and then reach antibiotic and sterilizing
Effect.It is in use non-harmful, with natural plant fragrance, can goes to eliminate the unusual smell, skin care does not stimulate.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：43 parts of shitosan amphoteric polymeric surfactant, 17 parts of Tea Saponin, cocoanut fatty acid diethanolamide 28
Part, 11 parts of deionized water, 4 parts of safflower essential oil, 15 parts of longan flower extract, 21 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 6.8, adds longan flower extract,
Seed residues of seabuckthorn enzymolysis product, safranine extrait, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, and using vacuum outgas, bear
Voltage-controlled system is dispensed, you can obtain natural plant composition liquid detergent in 5Mpa to mixed liquor.
Embodiment 2
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：43 parts of shitosan amphoteric polymeric surfactant, 17 parts of Tea Saponin, cocoanut fatty acid diethanolamide 28
Part, 11 parts of deionized water, 3 parts of safflower essential oil, 16 parts of longan flower extract, 18 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=18.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.2, adds longan flower extract,
Seed residues of seabuckthorn enzymolysis product, safranine extrait, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, and using vacuum outgas, bear
Voltage-controlled system is dispensed, you can obtain natural plant composition liquid detergent in 5Mpa to mixed liquor.
Embodiment 3
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：41 parts of shitosan amphoteric polymeric surfactant, 17 parts of Tea Saponin, 29 parts of cocoanut fatty acid diethanolamide,
11 parts of deionized water, 5 parts of safflower essential oil, 14 parts of longan flower extract, 23 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=14.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds longan flower extract,
Seed residues of seabuckthorn enzymolysis product, safranine extrait, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, and using vacuum outgas, bear
Voltage-controlled system is dispensed, you can obtain natural plant composition liquid detergent in 5Mpa to mixed liquor.
Embodiment 4
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：38 parts of shitosan amphoteric polymeric surfactant, 15 parts of Tea Saponin, cocoanut fatty acid diethanolamide 26
Part, 9 parts of deionized water, 4 parts of safflower essential oil, 15 parts of longan flower extract, 21 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=20.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 6.9, adds longan flower extract,
Seed residues of seabuckthorn enzymolysis product, safranine extrait, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, and using vacuum outgas, bear
Voltage-controlled system is dispensed, you can obtain natural plant composition liquid detergent in 5Mpa to mixed liquor.
Embodiment 5
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：46 parts of shitosan amphoteric polymeric surfactant, 19 parts of Tea Saponin, 31 parts of cocoanut fatty acid diethanolamide,
12 parts of deionized water, 4 parts of safflower essential oil, 15 parts of longan flower extract, 21 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=12.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.1, adds longan flower extract,
Seed residues of seabuckthorn enzymolysis product, safranine extrait, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, and using vacuum outgas, bear
Voltage-controlled system is dispensed, you can obtain natural plant composition liquid detergent in 5Mpa to mixed liquor.
Comparative example 1
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：17 parts of Tea Saponin, 28 parts of cocoanut fatty acid diethanolamide, 11 parts of deionized water, 4 parts of safflower essential oil, dragon
15 parts of dim eyesight extract, 21 parts of seed residues of seabuckthorn enzymolysis product.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, after Tea Saponin stirs, temperature
Degree is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, addition longan flower extract, seed residues of seabuckthorn enzymolysis product, safranine extrait,
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain natural plant composition liquid detergent.
Comparative example 2
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：43 parts of shitosan amphoteric polymeric surfactant, 17 parts of Tea Saponin, 11 parts of deionized water, 4 parts of safflower essential oil,
15 parts of longan flower extract, 21 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, Tea Saponin is sequentially added by weight, shitosan amphoteric polymeric surfactant stirs
Afterwards, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds longan flower extract, seed residues of seabuckthorn enzymolysis product, safflower
Essence, is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, and using vacuum outgas, vacuum cavitations enter in 5Mpa to mixed liquor
Row packing, you can obtain natural plant composition liquid detergent.
Comparative example 3
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：43 parts of shitosan amphoteric polymeric surfactant, 17 parts of Tea Saponin, cocoanut fatty acid diethanolamide 28
Part, 11 parts of deionized water, 4 parts of safflower essential oil, 21 parts of seed residues of seabuckthorn enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn is size-reduced, sieving and impurity elimination etc.
After pretreatment, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using trypsase and the side of papain mixed enzymolysis
Formula, enzymatic hydrolysis condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain point
Wei not 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant
Liquid, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds seed residues of seabuckthorn enzymolysis to produce
Thing, safranine extrait, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations in 5Mpa,
Mixed liquor is dispensed, you can obtain natural plant composition liquid detergent.
Comparative example 4
The present embodiment provides a kind of natural plant composition liquid detergent, natural plant composition liquid detergent, by following parts by weight into
It is grouped into：43 parts of shitosan amphoteric polymeric surfactant, 17 parts of Tea Saponin, cocoanut fatty acid diethanolamide 28
Part, 11 parts of deionized water, 4 parts of safflower essential oil, 15 parts of longan flower extract.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Dragon
Dim eyesight ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of natural plant composition liquid detergent, including step in detail below：Deionized water is added and is reacted
In kettle, 70 DEG C are heated to, cocoanut fatty acid diethanolamide is sequentially added by weight, Tea Saponin, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, add longan flower extract,
Safranine extrait, is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations in 5Mpa, to mixed
Close liquid to be dispensed, you can obtain natural plant composition liquid detergent.
Comparative example 5
Receive the full effect enriching liquid detergent of good Mrs's brand of Li Xinxihua Co., Ltds production from Hebei, bucket limit makes the date be
20180523, as a comparison case 5.
Comparative example 6
From the lemon aloe liquid detergent of labourer's personal style and attitude board of Guangzhou Nanshun Cleaning Products Co., Ltd.'s production, bucket limit makes the date be
20180803A, as a comparison case 6.
Experimental test
1. bactericidal effect test
Using Suspension quantitative bactericidal test, Escherichia coli, Listeria, S. aureus Inoculate after activation are taken first extremely
In triangle shaking flask, 37 DEG C, the 160 r/h of min shaken cultivations 36.Then respectively inoculation 1ml above-mentioned bacteria suspensions respectively with
The 2% dilution mixing of the liquid detergent of 9 ml embodiments 1-5 and comparative example 1-6,37 DEG C, 160 r/min vibrations
30min, detergent is determined to Escherichia coli, Listeria, the killing logarithm value of staphylococcus aureus, weight with the dilution method of falling ware
Multiple three parallel tests, calculate bactericidal effect such as following table.
2. detergency experiment
Press《Manual dishwashing detergent》The method of the standards of GB 9985-2000 purchase artificial dirt, 250 ppm hard water,
Instrument needed for dirt ceramics plate and foam level method test detergency.Using foam end point method, respectively Example 1-5 with
And comparative example 1-6 liquid detergent 5mL, by 1000mL concentration for the hard water of 250ppm is poured into enamel basin, separately by 1000mL concentration
For the hard water of 250ppm is put into tubualted bottle.In room temperature（25 ℃）Under, the delivery port of tubualted bottle is opened, hard water is rushed in flowing into basin
Spume.After hard water stops flowing out（The s of process about 45）, plate is scrubbed with 102 mm pigs palm fibre paintbrush, first brush clockwise
5 times, another mistake hour hands brush 5 times, after so repeating 1 time, the dirt major part being applied on plate is washed down, finally again will not
Wash lower part to scrub off, until foam is wholly absent, record the number that washes dishes, and be finally converted into deep bid subnumber, it is as a result as follows
Shown in table.
3. security toxicological test.
The main formula of Example 1 carries out toxicological test, foundation respectively《Foodsafety Toxicological Assessment program and side
Method》GB 15193-2003, using maximum tolerance metering experiment method, dosage is set to 10000 mg/kg BW, from 20
Kunming mice, male and female half and half.The h of animal fasting 16, drinking-water is not limited before experiment.The mg/mL of animal 500 is given using administration by gavage
The sample solution of concentration, gavage amount is 0.4 mL/20 g body weight.The poisoning manifestations and death condition of animal are observed after gavage,
Weigh weekly 1 time, observe 14 d, it is as a result as shown in the table.
| Sample ID | Shitosan amphoteric polymeric surfactant | Flos longan extracts product | Seed residues of seabuckthorn enzymolysis product |
| LD50（mg/kg·BW） | 20000 | 50000 | 45000 |
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask and limited rather than described above, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.The ins and outs not described in detail in the present invention, can be by any in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (7)
1. a kind of natural plant composition liquid detergent, it is characterised in that by following parts by weight into being grouped into：Shitosan both sexes are high
Molecular surface active agent 34-52 parts, Tea Saponin 12-23 parts, cocoanut fatty acid diethanolamide 22-34 parts, deionized water
8-14 parts, 2-5 parts of safflower essential oil, 13-17 parts of longan flower extract, 14-27 parts of seed residues of seabuckthorn enzymolysis product.
2. natural plant composition liquid detergent according to claim 1, it is characterised in that by following parts by weight into packet
Into：38-46 parts of shitosan amphoteric polymeric surfactant, Tea Saponin 15-19 parts, cocoanut fatty acid diethanolamide
26-31 parts, deionized water 9-12 parts, 13-15 parts of safflower essential oil, 4-6 parts of longan flower extract, seed residues of seabuckthorn enzymolysis product
18-23 parts.
3. natural plant composition liquid detergent according to claim 1, it is characterised in that the shitosan Amphiphatic high polymer table
The molecular formula of face activating agent is, wherein n=10-22.
4. natural plant composition liquid detergent according to claim 3, it is characterised in that the shitosan Amphiphatic high polymer table
Face activating agent is, with natural chitosan as raw material, to be closed as alkylating reagent using long-chain fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid
Into a kind of water soluble polymer surfactant based on shitosan for preparing.
5. natural plant composition liquid detergent according to claim 1, it is characterised in that the seed residues of seabuckthorn enzymolysis product
Preparation method is：After the pretreatments such as seed residues of seabuckthorn is size-reduced, sieving and impurity elimination, with solid-liquid ratio 1: 5（m/V）Add water, soaked
At night, by the way of trypsase and papain mixed enzymolysis, enzymatic hydrolysis condition is：45 DEG C of temperature, pH 7.5, hydrolysis
The enzyme concentration of the .5h of time 2, trypsase and papain is respectively 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested,
By enzymolysis liquid, 5000r/min is centrifuged 10min at 4 DEG C, takes supernatant, then obtain seed residues of seabuckthorn enzymolysis product by micro-filtration.
6. natural plant composition liquid detergent according to claim 1, it is characterised in that the flos longan extracts the system of product
Preparation Method is：By flos longan clean dry, then flos longan grind into powder and cross 50 mesh sieves, the longan pollen after sieving
End adds 70% ethanol, and the quality (g) of flos longan powder is with the volume (mL) of ethanol than m: V=1: 13；Ultrasonic wave
Shaker (40 DEG C, 450 W) min of assisted extraction 20；Flos longan ethanol flows back through water-bath extract again, and extraction temperature is
65 DEG C, extract 3 times, 1.5 h every time, suction filtration centrifugation (5000r/min, 15min), rotary evaporation in vacuo after filtering
Ethanol is reclaimed, flos longan crude extract is obtained；By HPD-300 macroreticular resins with 95% ethanol soak 24 h, distilled water clean to
Without being put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins after ethanol flavor；Flos longan crude extract with 400 BV/h (
BV:The volume of macroreticular resin) the rate of adsorption be adsorbed on HPD-300 macroreticular resins, upper column quantity be 600 BV；Absorption
The complete resin distilled water of 800 BV is with the impurity on the flow velocity eluted resin of 1000 BV/h, then uses 1200 BV
60% ethanol the crude extract being attached on resin is eluted, wash-out liquid condensing concentration after obtain flos longan extract produce
Thing.
7. the preparation method of a kind of natural plant composition liquid detergent as described in any one of claim 1- 6, it is characterised in that
Including step in detail below：By in deionized water addition reactor, 70 DEG C are heated to, coconut grease is sequentially added by weight
Fat acid diglycollic amide, Tea Saponin, after shitosan amphoteric polymeric surfactant stirs, temperature is down to 40 DEG C, will be molten
The PH values of liquid are adjusted to 6.8-7.2, add longan flower extract, seed residues of seabuckthorn enzymolysis product, safranine extrait to be stirred until homogeneous,
The feed liquid that will be stirred is de-gassed, and using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtained
Natural plant composition liquid detergent.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107345177A (en) * | 2017-08-18 | 2017-11-14 | 广西钱隆投资管理有限公司 | A kind of long-acting cleaning liquid detergent and preparation method thereof |
| CN107384610A (en) * | 2017-08-18 | 2017-11-24 | 广西钱隆投资管理有限公司 | A kind of plant skin-care detergent and preparation method thereof |
| CN107815364A (en) * | 2017-11-14 | 2018-03-20 | 蒙城县存胜家居清洁用品有限公司 | A kind of Chinese herbal medicine detergent |
| CN108721128A (en) * | 2018-06-29 | 2018-11-02 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin hand cleanser and preparation method thereof |
| CN108865505A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin dish washing liquid and preparation method thereof |
| CN111575119A (en) * | 2020-05-27 | 2020-08-25 | 山东中特新能源有限公司 | Photocatalytic disinfection and sterilization self-cleaning agent |
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2016
- 2016-11-03 CN CN201610950349.0A patent/CN106701355A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107345177A (en) * | 2017-08-18 | 2017-11-14 | 广西钱隆投资管理有限公司 | A kind of long-acting cleaning liquid detergent and preparation method thereof |
| CN107384610A (en) * | 2017-08-18 | 2017-11-24 | 广西钱隆投资管理有限公司 | A kind of plant skin-care detergent and preparation method thereof |
| CN107815364A (en) * | 2017-11-14 | 2018-03-20 | 蒙城县存胜家居清洁用品有限公司 | A kind of Chinese herbal medicine detergent |
| CN108721128A (en) * | 2018-06-29 | 2018-11-02 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin hand cleanser and preparation method thereof |
| CN108865505A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin dish washing liquid and preparation method thereof |
| CN111575119A (en) * | 2020-05-27 | 2020-08-25 | 山东中特新能源有限公司 | Photocatalytic disinfection and sterilization self-cleaning agent |
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