KR102397833B1 - Manufacturing method of functional foaming detergent using jeju green tangerine and functional foaming detergent manufactured by the same - Google Patents

Abstract

The present invention relates to a functional foaming detergent using Jeju (a region in Korea) green tangerine and a manufacturing method of the same, the manufacturing method comprising the steps of: preparing a base mixture by mixing a carbonate, a water-soluble organic acid, an excipient, a dispersant and a disintegrant; drying after preparing a base detergent composition by adding a natural surfactant containing a rhododendron extract and a soap water extract to the base mixture and stirring; preparing and aging an eco-friendly complex functional composition including sun salt, and a green tangerine complex mixture containing green tangerine juice and green tangerine oil; preparing a functional foaming detergent composition by adding the eco-friendly complex functional composition subjected to the step of aging to the base detergent composition subjected to the step of drying and stirring; and molding the functional foaming detergent composition into a tablet form.

Description

Manufacturing method of functional foaming detergent using Jeju green tangerine and foaming detergent thereof

The present invention relates to a method for manufacturing a functional foaming detergent using Jeju green tangerine, and a functional foaming detergent therefor, and more particularly, to a method for manufacturing a functional foaming detergent using an eco-friendly complex functional composition containing sea salt, green tangerine juice and green tangerine oil, and its functionality It relates to foam cleaners.

In general, detergents or detergents are mixtures that help efficient cleaning against contamination, and are composed of surfactants and various auxiliary components, and most of them are synthetic detergents using synthetic surfactants. However, synthetic detergents cause environmental pollution by synthetic detergents, and are absorbed into the body and cause diseases, and also cause various skin problems including housewife eczema.

In particular, in dishes, dishcloths, scrubbers, cutting boards, etc. used in the kitchen, many kinds of bacteria grow due to food residues and moisture, and the food residues remaining after washing decay and generate an unpleasant odor. In addition, it irritates the skin of users who come into contact with detergents and food waste, causing inflammation, and odors such as fish, meat, watery (amine-based odor), kimchi (mercaptan-based odor), etc. Remaining food waste and odors such as ammonia and amines generated by bacteria propagating in the food waste are not easily removed.

Meanwhile, along with the recent economic growth, the social trend of well-being, which seeks to pursue a healthy life due to the improvement of people's living standards, has brought about a change in the consumption culture that favors eco-friendly products. Chemical products, including environmental hormones, which are harmful to the environment and the human body, accumulate in the body and cause endocrine disorders, and are known as factors that cause skin diseases such as atopy by lowering immune function. will be.

Accordingly, there is a demand for the development of a detergent or detergent (hereinafter referred to as a detergent) that is environmentally friendly using natural materials, has excellent cleaning properties, deodorization properties, sterilization and antibacterial properties, and is beneficial to human skin.

Furthermore, the need for development of a detergent in the form of an effervescent tablet is increasing recently. This is because the detergent in tablet form has advantages including ease of handling, metering, transport and storage, and rapid dissolution of the active ingredient. However, detergents in the form of effervescent tablets have failed to dominate the market in spite of the advantages mentioned above. Some of the reasons for this may be in complex manufacturing methods that require specific environmental conditions and must be taken into account that unwanted interactions between components may occur. In addition, a compromise has to be made between the mechanical strength of the tablet and the ease of disintegration, two characteristics that conflict with each other but must be satisfied at the same time.

Considering that these effervescent tablet-type cleaners are very sensitive to moisture during manufacture and storage, it is required to develop an effervescent detergent excellent in detergency, deodorization, sterilization and skin protection along with stability of manufacture and storage.

The technology that is the background of the present application is disclosed in Korean Patent Application Laid-Open No. 10-2017-0134476.

The technical problem to be solved by the present invention is a method for manufacturing a functional foaming detergent using Jeju green tangerine, which is environmentally friendly and harmless to the human body, and has improved cleaning power, deodorization, sterilization and skin protection effect, and excellent manufacturing stability, and its functional foam To provide a cleaning agent.

The problems to be solved by the present invention are not limited to the problems mentioned above, and other problems not mentioned will be clearly understood by those skilled in the art from the following description.

A method for manufacturing a functional foaming detergent using Jeju green tangerine according to an embodiment of the present invention for achieving the above object is carbonate, citric acid, tartaric acid comprising at least one of sodium hydrogen carbonate, potassium bicarbonate, calcium bicarbonate, sodium carbonate and potassium carbonate , a water-soluble organic acid comprising at least one of phosphoric acid, acetic acid, maleic acid and fumaric acid, an excipient comprising at least one of sugar, maltitol, sorbitol and starch sugar, a dispersant comprising at least one of sodium gluconate, sodium phosphate and sodium silicate and preparing a base mixture by mixing a disintegrant comprising at least one of starch, sodium starch glycolate and sodium carboxymethyl cellulose; performing a drying process after preparing a base detergent composition by adding and stirring a natural surfactant including an extract of non-patient tree and soapy water to the base mixture; performing an aging process after preparing an eco-friendly complex functional composition comprising a green tangerine complex mixture containing sea salt, green tangerine juice and green tangerine oil; preparing a functional foaming detergent composition by adding and stirring the eco-friendly complex functional composition on which the aging process is performed to the base detergent composition on which the drying process has been performed; and performing a molding process of molding the functional foaming detergent composition into a tablet form.

According to one embodiment, the base mixture comprises at least one of citric acid, tartaric acid, phosphoric acid, acetic acid, maleic acid and fumaric acid per 100 parts by weight of a carbonate containing at least one of sodium hydrogencarbonate, potassium bicarbonate, calcium bicarbonate, sodium carbonate and potassium carbonate. 80 to 90 parts by weight of a water-soluble organic acid, 10 to 15 parts by weight of an excipient containing at least one of sugar, maltitol, sorbitol and starch sugar, 10 to 15 parts by weight of a dispersant comprising at least one of sodium gluconate, sodium phosphate and sodium silicate It is prepared to contain 15 to 20 parts by weight of a disintegrant comprising at least one of parts and starch, sodium starch glycolate and sodium carboxymethyl cellulose, and the base detergent composition is a patient-free tree extract per 100 parts by weight of carbonate contained in the base mixture, and The soap grass extract may be prepared to contain 5 to 10 parts by weight of a natural surfactant mixed in a weight ratio of 1:0.4 to 0.5.

According to one embodiment, the eco-friendly complex functional composition is prepared to contain 35 to 50 parts by weight of a green tangerine complex mixture in which green tangerine juice and green tangerine oil are mixed in a weight ratio of 1:0.8 to 1 per 100 parts by weight of sea salt, The aging process is performed at a temperature of 18 to 25° C. for 48 to 72 hours, and the functional foaming detergent composition may be prepared to include 5 to 10 parts by weight of the eco-friendly complex functional composition per 100 parts by weight of the base detergent composition.

According to one embodiment, the eco-friendly complex functional composition is a functional mixture powder including sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agaric agar extract, green onion extract, mother-of-pearl extract, and a seaweed extract mixture including Ecklonia cava extract. It can be prepared to include

According to one embodiment, the step of preparing the eco-friendly complex functional composition includes: obtaining green tangerine juice and green tangerine oil from green tangerines from Jeju; preparing a first green tangerine complex mixture by mixing the green tangerine juice and the green tangerine oil; To the first green tangerine complex mixture, a functional mixture powder containing sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agar agar extract, green onion extract, mother-of-pearl extract, and a seaweed extract mixture containing Ecklonia cava extract were added and stirred to prepare 2 preparing a green tangerine complex mixture; and adding the second green tangerine complex mixture to the sea salt and stirring the mixture, and then performing an aging process.

According to one embodiment, the eco-friendly complex functional composition is prepared to contain 35 to 50 parts by weight of a green tangerine complex mixture in which green tangerine juice and green tangerine oil are mixed in a weight ratio of 1:0.8 to 1 per 100 parts by weight of sea salt, The aging process is performed at a temperature of 18 to 25° C. for 48 to 72 hours, and the functional foaming detergent composition may be prepared to include 5 to 10 parts by weight of the eco-friendly complex functional composition per 100 parts by weight of the base detergent composition.

A functional foaming detergent using Jeju green tangerine according to an embodiment of the present invention for achieving the above object is prepared by any one of the above methods.

The functional foaming detergent using Jeju green tangerine prepared according to the embodiments of the present invention contains sea salt, green tangerine juice and green tangerine oil, so it has an excellent sterilization effect, and effectively removes oil stains with deodorizing effects such as water fishy smell and odor removal The cleaning power can be increased, and a natural fragrance effect that maintains the fragrance for a long time can be expected.

In addition, as the functional foaming detergent further includes a seaweed extract mixture including sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, functional mixed powder including chitosan and agar agar extract, green onion extract, mother-of-pearl extract and Ecklonia cava extract, sterilization , detoxification and deodorization effects are further increased, and the skin protection effect can be further increased through skin irritation relief and skin soothing.

In addition, as the functional foaming detergent uses the plant-derived natural surfactant extracts of radish tree and soap grass instead of using chemical solvents as surfactants, it is possible to prevent skin irritation or skin troubles that may occur due to the addition of chemical components. there is.

Accordingly, it is possible to provide a method for manufacturing a functional foaming detergent using Jeju green tangerine, which is environmentally friendly and harmless to the human body, as well as improved cleaning power, deodorization, sterilization and skin protection effect, and excellent manufacturing stability, and a functional foaming detergent thereof. .

1 is a flowchart for explaining a method of manufacturing a functional foaming detergent using Jeju green tangerines according to embodiments of the present invention.
2 is a flowchart for explaining a method of manufacturing an eco-friendly composite functional composition according to another embodiment of the present invention, and is a view corresponding to step S30 of FIG. 1 .

Advantages and features of the present invention, and methods for achieving them, will become apparent with reference to the embodiments described below in detail in conjunction with the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but may be implemented in various different forms, and only this embodiment serves to complete the disclosure of the present invention, and to obtain common knowledge in the technical field to which the present invention pertains. It is provided to fully inform the possessor of the scope of the invention, and the present invention is only defined by the scope of the claims. Like reference numerals refer to like elements throughout.

Also, in the present specification, when a part "includes" a certain component, it means that other components may be further included, rather than excluding other components, unless otherwise stated. As used throughout this specification, the terms "about," "substantially," and the like are used in a sense at or close to the numerical value when the manufacturing and material tolerances inherent in the stated meaning are presented, and are used in the understanding of this application. It is used to prevent unfair use by unconscionable infringers of the disclosure in which exact or absolute figures are mentioned to help

Hereinafter, with reference to the drawings, a method for manufacturing a functional foaming detergent using Jeju green tangerine according to embodiments of the present invention and a functional foaming detergent using Jeju green tangerine manufactured using the same will be described in detail.

1 is a flowchart for explaining a method of manufacturing a functional foaming detergent using Jeju green tangerine according to embodiments of the present invention.

Referring to Figure 1, the method for producing a functional foaming detergent using Jeju green tangerine according to embodiments of the present invention is to prepare a base mixture by mixing carbonate, water-soluble organic acid, excipient, dispersant and disintegrant (S10), the base A step (S20) of performing a drying process after preparing a base detergent composition by adding and stirring a natural surfactant including an extract of non-patient tree and soap water extract to the mixture, a green tangerine complex containing sea salt, green tangerine juice and green tangerine oil A step of performing the aging process after preparing an eco-friendly complex functional composition containing the mixture (S30), adding the eco-friendly complex functional composition subjected to the aging process to the base detergent composition on which the drying process has been performed, and stirring to obtain a functional foaming detergent composition It may include the step of manufacturing (S40), and performing a molding process of molding the functional foaming detergent composition into a tablet form (S50).

Specifically, a base mixture may be prepared by mixing a carbonate, a water-soluble organic acid, an excipient, a dispersing agent, and a disintegrant (S10).

Carbonates and water-soluble organic acids can function as blowing agents to disintegrate the tablet upon contact with water. For example, the carbonate may include at least one of sodium hydrogen carbonate, potassium bicarbonate, calcium bicarbonate, sodium carbonate and potassium carbonate, and the water-soluble organic acid may include at least one of citric acid, tartaric acid, phosphoric acid, acetic acid, maleic acid, and fumaric acid. .

Preferably, sodium hydrogen carbonate may be used as the carbonate, and citric acid may be used as the water-soluble organic acid.

Sodium hydrogen carbonate is a colorless crystalline powder that has a deodorizing function, and when dissolved in water, bicarbonate ions (HCO3-) are generated, and then carbon dioxide (CO2) bubbles are generated. In particular, when sodium bicarbonate is dissolved in water with citric acid, hydrogen ions (H+) from citric acid increase and combine with bicarbonate ions (HCO3-) from sodium bicarbonate to produce more carbonic acid (H2CO3), and carbonic acid ( H2CO3) is separated into water and carbon dioxide, so a larger amount of carbon dioxide can be generated in the water.

Citric acid is a white or colorless transparent crystalline powder that is used as a food additive and as a disinfectant for tableware, cutting boards, and knives. In the present invention, citric acid helps the foaming of sodium bicarbonate, shortens the dissolution time, and lowers the pH of the washing solution to control the pH.

The excipient may include at least one of sugar, maltitol, sorbitol and starch sugar, preferably sugar. Sugar can function as an excipient and increase the foaming power of the detergent.

The dispersing agent may include at least one of sodium gluconate, sodium phosphate and sodium silicate, preferably sodium gluconate. Sodium gluconate functions as a dispersing agent for alleviating aggregation of each material and improving fluidity, and can also be used as a cleaning aid for cleaning action and removal of metallic particles.

The disintegrant may include at least one of starch, sodium starch glycolate and sodium carboxymethyl cellulose, preferably corn starch or potato starch.

According to one embodiment, the base mixture comprises at least one of citric acid, tartaric acid, phosphoric acid, acetic acid, maleic acid and fumaric acid per 100 parts by weight of a carbonate comprising at least one of sodium hydrogencarbonate, potassium bicarbonate, calcium bicarbonate, sodium carbonate and potassium carbonate. 80 to 90 parts by weight of a water-soluble organic acid, 10 to 15 parts by weight of an excipient containing at least one of sugar, maltitol, sorbitol and starch sugar, 10 to 15 parts by weight of a dispersant comprising at least one of sodium gluconate, sodium phosphate and sodium silicate It may be prepared to contain 15 to 20 parts by weight of a disintegrant comprising at least one of parts and starch, sodium starch glycolate and sodium carboxymethyl cellulose. As the base mixture is mixed in the same weight ratio as described above, cleaning power, disintegration property and/or moldability may be further increased due to a synergistic effect according to the interaction of each component.

A drying process may be performed after preparing a base detergent composition by adding and stirring a natural surfactant including an extract of non-patient tree and soapy water to the base mixture (S20).

The Soapberry Tree is called a sick tree because it is said that planting this tree will not cause anger to its children. The fruit is called Soapnut and is a round drupe and ripens around October. Due to the innumerable amount of saponin in the soapnut, it is used as a natural surfactant, and the fruit has effects on dry heat, digestion, and small swelling. It is also used as a shampoo, body wash, and treatment for skin diseases. As it is rich in saponin, it foams easily even when it comes in contact with water. This foam is harmless to the human body, is not slippery, and disappears quickly. However, the cleaning power is very good, and even if washed in cold water, the same outstanding effect as general detergents can be seen. The water that comes out after washing can be used as an insecticide such as flowers.

Soap grass (Saponaria officinalis L.) is a perennial herb of the genus Saponaria family, native to Europe. Its main ingredients include triterpene, resin, mucus, plant sterols, vitamin C, and small amounts of volatile oils , contains a large amount of saponin, a natural surfactant component. The scientific name of saponana, meaning 'soap', was given because the roots and stems of soap grass were cut into small pieces, put in water and shaken vigorously to form soap bubbles. In particular, the roots and leaves contain 10 to 20% saponin and saponarin, so when immersed in water, the juice flows out like soap. Soap grass is effective for bronchitis, clearing phlegm and stopping coughing. Also, because it has antiviral and antibacterial functions, it is effective for acne and eczema, and has anti-inflammatory properties, so it is used to treat rheumatoid arthritis. In addition, it is also used as a hair growth agent. It also has the ability to dissolve oil, so it can be used as a natural cleaner by boiling the leaves or roots in water.

The patient-free tree extract and soapgrass extract may be obtained using an extraction method and an extraction solvent known in the art, and contain saponin, a natural surfactant, in the present invention, the patient-free tree extract and soapgrass extract It can be used as a natural surfactant.

In the present invention, as a surfactant, instead of using a chemical solvent, by using the botanical natural surfactants, such as the radish tree extract and soap grass extract, it is possible to prevent skin irritation or skin troubles that may occur due to the addition of chemical components.

According to one embodiment, the base cleaning composition may be prepared to contain 5 to 10 parts by weight of a natural surfactant in which the extract of oyster tree and soap grass extract are mixed in a weight ratio of 1:0.4 to 0.5 per 100 parts by weight of carbonate contained in the base mixture. there is. If the natural surfactant is less than the lower limit, the function as a surfactant may be insignificant, and if it exceeds the upper limit, moldability may be deteriorated. In addition, as the patient-free tree extract and soap grass extract are mixed in the same weight ratio as above, the efficacy as a natural surfactant can be maximized.

The drying process of the base cleaner composition is to prevent the carbonate and water-soluble organic acid in the base cleaner composition from contacting with moisture to generate carbon dioxide gas, and may be performed at a temperature of 50 to 70° C. for 60 to 90 minutes.

After preparing an eco-friendly complex functional composition including a green tangerine complex mixture containing sea salt, green tangerine juice and green tangerine oil, the aging process may be performed (S30).

The eco-friendly complex functional composition can be used to improve deodorization, sterilization and skin protection as well as to improve cleaning power.

Sea salt refers to salt made by naturally evaporating water from seawater with sunlight and wind. Sea salt contains a lot of minerals and inorganic components such as magnesium, calcium, and potassium, and has effects such as sterilization, detoxification and decay prevention, odor removal, and freezing prevention. In the present invention, sea salt is used for sterilization and anti-rot effect.

Citrus fruits are rich in juice compared to other fruits and have a unique flavor and color, as well as essential oil components d-limonene, linalool, linalylacetate, and flavonoids hesperidin. , naringin, porcirin, nobiletin and alkaloids synephrine, pectin, ascorbic acid, beta-cryptoxanthin ), is known to contain substances such as coumarin (courin).

Green tangerines are green unripe tangerines before the peel of the tangerine is colored, and are called green tangerines. Unripe tangerine means an extremely early hot tangerine with a sugar content of less than 8°Bx or an early and ordinary hot tangerine with a sugar content of less than 9°Bx. In particular, green tangerines (Citrus Unshiu) are picked and discarded from trees in July and September to improve quality, and are a factor contaminating the environment around the orchard.

In the present invention, green tangerine juice and green tangerine oil may be obtained from Jeju green tangerines. For example, by preparing green tangerines from Jeju, foreign substances remaining in the green tangerines may be washed and removed. Thereafter, the washed green tangerine flesh and peel (ie, the peel) can be separated. Green mandarin juice can be obtained by pressing the separated green mandarin fruit. Juicing of green mandarin orange juice is not limited to the compression method, and various known methods such as low-temperature pressurization extraction and low-temperature ultrasonic extraction method may be used.

The washed rind of green tangerine is dried to adjust the moisture content in the range of 5 to 20% by weight, and the dried rind is pulverized and powdered. Then, for the pulverized fruit skin powder, steam at a temperature of 100 to 120 ℃ is applied to humidify and heat the seed powder. In this case, the time for applying the steam may be about 15 to 30 minutes. Through this humidification and heating process, the oil in the rind is melted by the hot steam and the milking process can be made smoothly. Thereafter, the fruit peel powder is supercritical fluid extraction with carbon dioxide to obtain green tangerine oil.

A green tangerine complex mixture can be prepared by mixing the green tangerine juice and green tangerine oil obtained as described above.

The green tangerine complex containing green tangerine juice and green tangerine oil contains a large amount of vitamin C, citric acid (ie, citric acid), limonoid, limonene, flavonoid and carotenoid, and has anti-allergic, anti-inflammatory, anti-viral and antioxidant effects. is excellent In particular, green tangerine juice and green tangerine oil contain higher amounts of citric acid and limonene than general citrus juice or citrus oil, so the deodorizing effect such as water fishy smell and odor removal and the cleaning power to effectively remove oil stains can be increased, and for a long time It can also be expected to have a natural aroma effect that maintains the fragrance.

According to one embodiment, the eco-friendly complex functional composition may be prepared to contain 35 to 50 parts by weight of a green tangerine complex mixture in which green tangerine juice and green tangerine oil are mixed in a weight ratio of 1:0.8 to 1 per 100 parts by weight of sea salt. As the eco-friendly complex functional composition is mixed in the same weight ratio as above, the efficacy of the sea salt and green tangerine complex mixture can be maximized.

The aging process of the eco-friendly complex functional composition is for the generation of a synergistic effect according to the interaction of each component through sufficient mixing of useful components and may be performed at a temperature of 18 to 25° C. for 48 to 72 hours. If the aging time is less than 48 hours, the ingredients in the eco-friendly complex functional composition may not be sufficiently mixed so that the efficacy of each component may not be properly exhibited. there is.

In addition, the moisture content in the eco-friendly complex functional composition may be reduced by drying naturally during the aging process, and accordingly, it is possible to minimize the generation of carbon dioxide gas by reacting the foaming agent component with moisture during the manufacturing process, thereby improving manufacturing stability. .

A functional foaming detergent composition can be prepared by adding and stirring the environment-friendly complex functional composition subjected to the aging process to the drying process-performed base detergent composition (S40).

According to one embodiment, the functional foaming detergent composition may be prepared to contain 5 to 10 parts by weight of the eco-friendly complex functional composition per 100 parts by weight of the base detergent composition. If the eco-friendly composite functional composition is less than 5 parts by weight, its efficacy may not be sufficiently exhibited, and if it exceeds 10 parts by weight, moldability may be deteriorated.

Subsequently, a molding process of molding the functional foaming detergent composition into a tablet form may be performed (S50).

The molding process of the functional foaming detergent composition can be performed using a tableting machine, and the functional foaming detergent molded in the form of a tablet through the molding process is tested for weight, strength and appearance after sampling, and then packaged in the packaging room to check the packaging condition After that, it can be shipped as a product.

When the functional functional foaming detergent in the form of a tablet prepared in this way is added with water, the sodium bicarbonate dissolves in water and bubbles are generated, and the generation of bubbles is amplified by citric acid and aeration is performed, thereby sterilizing and cleaning the user. can visually confirm the sterilization and cleaning action. At this time, the sugar creates bubbles during aeration, so that the disinfection process can be visually confirmed better. In addition, the eco-friendly complex functional composition containing green tangerine juice and green tangerine oil can effectively remove fishy smell, odor and oil stains, and can improve user preference by maintaining good flavor for a long time.

According to another embodiment, the eco-friendly complex functional composition is a functional mixed powder including sulfur powder, rice bran powder, persimmon leaf powder and acorn powder in addition to the above-mentioned sea salt and green tangerine complex mixture; It may be prepared to further include a seaweed extract mixture comprising a. This will be described in more detail with reference to FIG. 2 .

FIG. 2 is a flowchart for explaining a method of manufacturing an eco-friendly composite functional composition according to another embodiment of the present invention, and is a view corresponding to step S30 of FIG. 1 .

Referring to FIG. 2, the preparation of the eco-friendly complex functional composition includes the steps of obtaining green tangerine juice and green tangerine oil from Jeju green tangerines (S31), and preparing a first green tangerine complex mixture by mixing green tangerine juice and green tangerine oil ( S32), to the first green tangerine complex mixture, a functional mixture powder containing sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agaric agar extract, green onion extract, mother-of-pearl extract, and a seaweed extract mixture containing Ecklonia cava extract are added and stirred to prepare a second green tangerine complex mixture (S33) and adding the second green tangerine complex mixture to sea salt, stirring, and then performing the aging process (S34).

First, green tangerine juice and green tangerine oil are obtained from green tangerines from Jeju, and the first green tangerine complex can be prepared by mixing them. At this time, green tangerine juice and green tangerine oil may be mixed in a weight ratio of 1:0.8 to 1 as described above. The step of obtaining green tangerine juice and green tangerine oil from Jeju green tangerine (S31) and the step of preparing a first green tangerine complex mixture by mixing green tangerine juice and green tangerine oil (S32) were previously described with reference to step S30 of FIG. Since it is the same as or similar to the above, a detailed description thereof will be omitted.

Next, a seaweed extract mixture containing sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agar agar extract, green onion extract, mother-of-pearl extract, and Ecklonia cava extract was added to the first green tangerine complex mixture and stirred. A second green tangerine complex mixture may be prepared (S33).

In the functional mixed powder, useful ingredients (eg, citric acid, limonene, etc.) contained in the first green tangerine complex mixture are impregnated in the functional mixed powder, and a certain amount is continuously discharged outside with the improvement of sterilization, antibacterial and antioxidant effects It can be used for functions such that its potency remains consistently high.

For example, the sulfur powder may be a powder of dietary sulfur (MSM; Methyl Sulfonyl methane). Dietary sulfur is an oxidative metabolite of dimethyl-sulfoxide (DMSO) containing about 34% sulfur, and is a natural organic form of bioavailable sulfur. Sulfur has a mysterious detoxifying action that detoxifies heavy metals, toxic substances, and chemical poisons, which are the biggest enemies in modern people's health path, than any other element. )' is called. Sulfur is one of the basic substances constituting life, like water, and is the fourth most abundant mineral in the human body after calcium, phosphorus, and potassium. It is found in all cells in the body and is essential for the life of the cell itself as a component of the important amino acids cystine, cysteine, and methionine. It is also a component of vitamins Thiamine and Biotin, and is also present in saliva, bile, and the hormone insulin. It accounts for 0.15% of body weight and accounts for 10% of the mineral content in the body.

Dietary sulfur also exhibits antibacterial effects through oral administration, vascular injection, and topical application. In Korea, sulfur has been mainly used as a prescription for dermatitis, and in Chinese medical records, there is a prescription that a mixture of sulfur, alum, garlic, nogam stone, zinc oxide, and vinegar in an appropriate ratio and applied to the affected area can cure ringworm. Do. If we look at the sterilization action of sulfur biochemically, when sulfur is applied to the skin, it interacts with organic matter to form pentathionic acid (HO-SO2-S3-SO2-OH), and this substance dissolves the dead skin cells, thereby providing insecticidal and sterilizing effects. do. Therefore, it is reported that sulfur, as a non-toxic sulfur element supply agent, relieves inflammation and plays a good role in dermatitis due to its strong sterilization power.

Rice bran refers to the pulverized product of pericarp, seed coat and aloe layer obtained when brown rice is polished to white rice. Rice bran contains high-quality protein, dietary fiber, and various vitamins and minerals as well as physiologically active substances such as phenolic compounds, ferulic acid, gamma-oryzanol, GABA, and ceramide. ), tocotrienols, and phytosterols are rich in natural antioxidants.

The persimmon tree (Diospyros kaki Thunb) is mainly distributed in the central and southern regions of Korea. In addition to the reproductive Shija, the leaves, Shihwa, and cadavers have been used as folk remedies since ancient times. Among them, persimmon leaves are mainly used as tea, and it is recorded in Donguibogam that it is effective in preventing and treating vascular diseases as well as in purpura (vascular inflammation). Persimmon leaves contain various substances such as vitamin C, amino acids, nucleic acids, phenolic compounds, and free sugar. The flavonoids of persimmon leaves exist in glycoside forms such as astragalin, a glycoside of kaempferol, and myricitrin, isoquercitrin, a glycoside of myricetin, a glycoside of myricetin. Persimmon leaves have a high total phenolic compound content of 0.1 to 5.8% compared to other plants, and have excellent antioxidant and antibacterial properties, and are known to be involved in superoxide dismutase (SOD) activity.

Acorn (Quercus acutissima CARR) is a generic term for the fruits of oak trees, oak trees, Japanese oak trees, and oak trees. In general, the chemical composition of acorns is about 70% starch, and about 6-9%. was reported to be composed of tannins. Tannins are originally astringent and bitter in taste, but these tannins are a kind of polyphenol component and are known as a major component for antioxidant effects. Acorns are used by peeling the skin, separating the inner nut, and grinding it finely. After mixing the acorn powder with a large amount of water and brewing it, the sediment is settled and filtered, so that the fiber and starch components in the acorn powder can be separated. In this process, not only the fiber and starch are separated, but also the tannin component in the starch escapes through diffusion.

Tannin is a type of polyphenol and is known to have detoxification, sterilization, hemostasis, and anti-inflammatory properties. Detoxification is the action of tannin to discharge alkaloids, which are toxic components, out of the body, and it means the ability to precipitate harmful heavy metals and discharge them out of the body. An example of this is nicotine excretion. In addition, the sterilization action means the action of killing pathogens because tannins penetrate into the cells and bind with proteins to coagulate. In addition, hemostasis refers to hemostasis by quickly healing wounds by astringent action of tannins, and can also serve to treat diarrhea or dysentery or to protect the intestinal and gastric mucosa. In addition, the anti-inflammatory action is to add tannin to the bite of a poisonous insect, which causes fever and redness, swelling, and the fever can be lowered and swelling can be relieved.

Each of the sulfur powder, rice bran powder, persimmon leaf powder and acorn powder is prepared by a known method, and it can be used that is pulverized to 100 to 500 mesh.

Chitosan and seaweed extract mixture can be used for skin irritation relief and skin soothing effect.

Chitosan is a component present in the shells of crustaceans such as crabs and shrimps, and insects such as grasshoppers. The molecular structure chemically bound to a polysaccharide called glucosamine is very similar to our human tissue, so it has good affinity and no immune response. It is a highly useful ingredient. Chitosan is absorbed into the skin, regulates the balance of moisture and fat in the cell membrane, protects the skin by creating a moisturizing film, and has a skin soothing effect that soothes sensitive skin. In addition, while chitosan has antibacterial activity, it is known that there are other effects such as immune effect, physiological activation effect, antioxidant action, cell activation action, and bleeding effect. Chitosan may be commercially available or prepared by a known method.

Agar agar is a seaweed belonging to the red algae Agaraceae, and contains proteins, lipids, carbohydrates, calcium, iron, polysaccharides (agarose, agaropectin), and the like. The agar agar extract is rich in complex polysaccharides called carrageenan and minerals, and contains a large amount of iodine and calcium. In addition, the iodine contained in the agar agar extract promotes the secretion of thyroid hormones, which stimulates the adrenal glands by secreting a hormone called tyrosine, and secretes the adrenal hormones epinephrine and cordysol.

Green leaf extract purifies the blood, gives a wool effect, helps you look younger, shows a good effect on skin inflammation such as trauma, eczema, burns, and shows an excellent effect on atopic dermatitis and hypersensitivity dermatitis.

Vitamin C contained in Mozambique extract helps the synthesis of collagen, a skin protein, and prevents fine lines by protecting elastin, a protein that gives skin elasticity. In addition, mother-of-pearl extract prevents oxidation in the human body due to its antioxidant action, preventing excessive production of melanin. And, it is good for allergic skin and easily reddened skin by strengthening skin resistance and preventing freckles, acne, age spots, etc. at the same time as whitening with UV blocking effect.

Ecklonia cava extract promotes fibroblast cell activity and collagen synthesis to relieve wrinkles and give skin elasticity.

According to one embodiment, the second green tangerine complex mixture contains sulfur powder, rice bran powder, persimmon leaf powder and acorn powder per 100 parts by weight of the first green tangerine complex mixture in which green tangerine juice and green tangerine oil are mixed in a weight ratio of 1:0.8 to 1. It may be prepared to contain 30 to 40 parts by weight of the functional mixture powder, 5 to 10 parts by weight of chitosan, and 20 to 30 parts by weight of a seaweed extract mixture including agar agar extract, green onion extract, mother-of-pearl extract, and Ecklonia cava extract. At this time, it is preferable to use a mixture of sulfur powder, rice bran powder, persimmon leaf powder and acorn powder in a weight ratio of 1:1:0.5 to 1:0.5 to 1 as the functional mixed powder, and the seaweed extract mixture is agar agaric extract and green leek extract , it may be preferable to use a mixture of mother and child extract, Ecklonia cava extract in a weight ratio of 1:1:1:1.

Then, after adding and stirring the second green tangerine complex mixture to the sea salt, the aging process may be performed (S34), thereby completing the preparation of the eco-friendly complex functional composition.

For example, the eco-friendly complex functional composition may be prepared to contain 35 to 50 parts by weight of the second green tangerine complex mixture per 100 parts by weight of sea salt, and the aging process may be performed at a temperature of 18 to 25° C. for 48 to 72 hours. In this example, the eco-friendly complex functional composition further includes a seaweed extract mixture including a functional mixed powder including sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agaric extract, green onion extract, mother-of-pearl extract and Ecklonia cava extract. Accordingly, the sterilization, detoxification and deodorization effects are further increased, and the skin protection effect can be further increased by alleviating skin irritation and soothing the skin.

The eco-friendly composite functional composition prepared through the steps S31 to S34 of FIG. 2 may be used in the manufacture of the functional foaming detergent in the same manner as described with reference to FIG. 1 . In this embodiment, steps (S10), (S20), (S40), and (S50) described with reference to FIG. 1 are substantially the same, so the Detailed description will be omitted.

The functional foaming detergent using Jeju green tangerine prepared by the method as described above may be directly used as a kitchen cleaner for water bottles, tumblers, tableware, coffee pots, cooking utensils, etc., but the usage aspect is not limited thereto. In another use aspect, the functional foam cleaner of the present invention is used for washing dishes by a dishwasher, or for degreasing from hard surfaces (e.g. extractor hoods, kitchens, glass-ceramic range tops, induction range tops), hard surfaces ( For example, ceramic floors, tile floors, parquet floors, synthetic wood countertops, natural stone countertops, synthetic stone countertops, walls) cleaning, hard surfaces (eg floors, walls, toilets, bathtubs, sinks) disinfection, clothing washing and It can be used to prepare aqueous detergent solutions for softening or descaling.

Hereinafter, the present invention will be described in detail through examples.

[Examples and Comparative Examples]

After preparing the raw materials in the mixing ratio of Table 1 below, the base mixture and the natural surfactant were mixed to prepare a base detergent composition. Thereafter, a drying process was performed at a temperature of 55° C. for 60 minutes. An eco-friendly complex functional composition was added to the base detergent composition subjected to the drying process and stirred to prepare a functional foamed detergent composition, and then a tablet-type foamed detergent was prepared using a tablet press. At this time, the aging process of the eco-friendly complex functional composition was performed at a temperature of about 25 ℃ for 48 hours. Meanwhile, in Comparative Example 2, 5 parts by weight of sodium alkylbenzenesulfonate and 5 parts by weight of polyoxyethylene alkyl ether were used instead of the natural surfactant.

division ingredient Content (parts by weight, based on 100 parts by weight of sodium hydrogen carbonate) Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 base mixture sodium bicarbonate 100 100 100 100 100 citric acid 87.5 87.5 87.5 87.5 87.5 sugar 12.5 12.5 12.5 12.5 12.5 sodium gluconate 12.5 12.5 12.5 12.5 12.5 corn starch 15 15 15 15 15 natural surfactant patient-free tree extract 6.25 6.25 6.25 6.25 0 soap grass extract 2.5 2.5 2.5 2.5 0 Eco-friendly complex functional composition sea salt 10 15 15 0 0 green tangerine juice 2 4 2 0 0 green tangerine oil 1.75 3.5 1.75 0 0 sulfur powder 0 0 0.5 0 0 Rice bran powder 0 0 0.5 0 0 persimmon leaf powder 0 0 0.25 0 0 acorn powder 0 0 0.25 0 0 chitosan 0 0 0.2 0 0 agar agar extract 0 0 0.2 0 0 green seaweed extract 0 0 0.2 0 0 Mosquito extract 0 0 0.2 0 0 Ecklonia extract 0 0 0.2 0 0

[Experimental example]

Examples and comparative examples were compared by performing a sensory test for the foaming detergent. After 20 housewives were allowed to use the foaming detergent for 2 weeks, the 9-point rating method (1; very bad, 9; very good) was evaluated for detergency, skin irritation relief, fragrance, and preference. The results are shown in [Table 2] below.

division detergency skin irritation relief incense symbol Example 1 7.4 7.1 7.5 7.4 Example 2 7.6 7.5 7.8 7.7 Example 3 8.0 7.8 7.9 7.9 Comparative Example 1 6.6 6.5 6.0 6.7 Comparative Example 2 6.5 6.0 6.4 6.3

As can be seen in Table 2, it can be seen that Examples 1 to 3 of the present invention are generally superior in properties with respect to cleaning power, skin irritation relief, fragrance, and preference compared to Comparative Examples 1 and 2. In particular, in the case of Example 3 in which various components of the eco-friendly composite functional composition are contained, it can be seen that all properties are the best. In the present specification, preferred embodiments of the present invention have been disclosed, and although specific terms are used, these are only used in a general sense to easily explain the technical content of the present invention and help the understanding of the present invention, and to limit the scope of the present invention. It is not meant to be limiting. It is apparent to those of ordinary skill in the art to which the present invention pertains that other modifications based on the technical spirit of the present invention can be implemented in addition to the embodiments disclosed herein.

Claims (7)

Sodium bicarbonate, potassium bicarbonate, calcium bicarbonate, carbonate containing at least one of sodium carbonate and potassium carbonate, water-soluble organic acid containing at least one of citric acid, tartaric acid, phosphoric acid, acetic acid, maleic acid and fumaric acid, sugar, maltitol, sorbitol and whole A base by mixing an excipient comprising at least one of powdered sugar, a dispersing agent comprising at least one of sodium gluconate, sodium phosphate and sodium silicate, and a disintegrant comprising at least one of starch, sodium starch glycolate and sodium carboxymethyl cellulose preparing a mixture;
performing a drying process after preparing a base detergent composition by adding and stirring a natural surfactant including an extract of a patient-free tree and a soap grass extract to the base mixture;
performing an aging process after preparing an eco-friendly complex functional composition comprising a green tangerine complex mixture containing sea salt, green tangerine juice and green tangerine oil;
preparing a functional foaming detergent composition by adding and stirring the eco-friendly complex functional composition on which the aging process is performed to the base detergent composition on which the drying process has been performed; and
Comprising the step of performing a molding process of molding the functional foaming detergent composition into a tablet form,
The eco-friendly complex functional composition is prepared to further include a seaweed extract mixture including a functional mixed powder including sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agar agar extract, green onion extract, mother-of-pearl extract and Ecklonia cava extract. A method for manufacturing a functional foaming detergent using green tangerines. According to claim 1,
The base mixture is a water-soluble organic acid containing at least one of citric acid, tartaric acid, phosphoric acid, acetic acid, maleic acid and fumaric acid per 100 parts by weight of carbonate containing at least one of sodium hydrogencarbonate, potassium bicarbonate, calcium bicarbonate, sodium carbonate and potassium carbonate. 90 parts by weight, 10 to 15 parts by weight of an excipient comprising at least one of sugar, maltitol, sorbitol and starch sugar, 10 to 15 parts by weight of a dispersant comprising at least one of sodium gluconate, sodium phosphate and sodium silicate, and starch, starch It is prepared to contain 15 to 20 parts by weight of a disintegrant comprising at least one of sodium glycolate and sodium carboxymethyl cellulose,
The base detergent composition is functional using Jeju green tangerine prepared to contain 5 to 10 parts by weight of a natural surfactant in which the extract of oyster tree and soap grass extract is mixed in a weight ratio of 1:0.4 to 0.5 per 100 parts by weight of carbonate contained in the base mixture. A method for manufacturing a foaming detergent. 3. The method of claim 2,
The eco-friendly complex functional composition is prepared to contain 35 to 50 parts by weight of a green tangerine complex mixture in which green tangerine juice and green tangerine oil are mixed in a weight ratio of 1:0.8 to 1 per 100 parts by weight of sea salt,
The aging process of the eco-friendly complex functional composition is carried out at a temperature of 18 to 25° C. for 48 to 72 hours,
The functional foaming detergent composition is a method of manufacturing a functional foaming detergent using Jeju green tangerine prepared to include 5 to 10 parts by weight of the eco-friendly complex functional composition per 100 parts by weight of the base detergent composition. delete According to claim 1,
The step of preparing the eco-friendly complex functional composition,
obtaining green tangerine juice and green tangerine oil from Jeju green tangerines;
preparing a first green tangerine complex mixture by mixing the green tangerine juice and the green tangerine oil;
To the first green tangerine complex mixture, a functional mixture powder containing sulfur powder, rice bran powder, persimmon leaf powder and acorn powder, chitosan and agar agar extract, green onion extract, mother-of-pearl extract, and a seaweed extract mixture containing Ecklonia cava extract were added and stirred to prepare 2 preparing a green tangerine complex mixture; and
A method for producing a functional foaming detergent using Jeju green tangerines, comprising the step of adding the second green tangerine complex mixture to sea salt, stirring, and performing a ripening process. 6. The method of claim 5,
The second green tangerine complex mixture contains sulfur powder, rice bran powder, persimmon leaf powder and acorn powder per 100 parts by weight of the first green tangerine complex mixture in which green tangerine juice and green tangerine oil are mixed in a weight ratio of 1:0.8-1: 1:0.5-1 : Seaweed in which 30 to 40 parts by weight of functional mixed powder mixed in a weight ratio of 0.5 to 1, 5 to 10 parts by weight of chitosan and agar agar extract, green onion extract, mother-of-pearl extract, and Ecklonia cava extract are mixed in a weight ratio of 1:1:1:1 It is prepared to include 20 to 30 parts by weight of the extract mixture,
The eco-friendly complex functional composition is prepared to contain 35 to 50 parts by weight of the second green tangerine complex mixture per 100 parts by weight of sea salt,
The aging process of the eco-friendly complex functional composition is a method of manufacturing a functional foaming detergent using Jeju green tangerines, which is performed for 48 to 72 hours at a temperature of 18 to 25°C. A functional foaming detergent using Jeju green tangerine prepared by the method of any one of claims 1 to 3 and 5 to 6.

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