CN106753891A - A kind of sterilization-deodordetergent detergent and preparation method thereof - Google Patents
A kind of sterilization-deodordetergent detergent and preparation method thereof Download PDFInfo
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- CN106753891A CN106753891A CN201610950359.4A CN201610950359A CN106753891A CN 106753891 A CN106753891 A CN 106753891A CN 201610950359 A CN201610950359 A CN 201610950359A CN 106753891 A CN106753891 A CN 106753891A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The present invention provides a kind of sterilization-deodordetergent detergent and preparation method thereof, the present invention prepare liquid detergent with natural component as primary raw material, safety non-toxic, non-excitant, with natural plant fragrance, deodorization and sterilization effect is good, also has functions that strong washing function and skin care.
Description
Technical field
The present invention relates to a kind of liquid detergent, particularly a kind of sterilization-deodordetergent detergent and preparation method thereof.
Background technology
Liquid detergent is a major class in synthetic detergent, and what yield was maximum in synthetic detergent is washing powder, hair
It is liquid detergent that exhibition is most fast.Because liquid detergent has very at aspects such as kind, performance, production technologies compared with solid detergent
Many advantages, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid detergent is that it has surfactant solution using water or other organic solvents as the articles for washing of base-material
Characteristic.The fluid product with cleaning function is typically referred to as liquid detergent.It is divided into liquid detergent according to purposes or function, knits
Thing liquid detergent, shampoo and skin cleaner and hard surface cleaner.
Liquid detergent is mainly used in washing tableware, tea set and kitchen tools etc.；Can be used for washings fruits and vegetables and greasy dirt weight
Clothing.It is the indispensable washing product of the catering trade and family.Dish washing detergent belongs to allotment type product, develops ten at home in recent years
Divide rapid.Tableware on the market is washed at present
Wash that agent is a feast for the eyes, have that detergency is superpower, have concentrated type and strong sterilizing power etc..With people's environmental consciousness
Progressively strengthen, following developing direction of dish washing detergent will be with environment-friendly and green type as main flow.Except there is strong detergency, to human body
Outside harmless, sterilizing, the function of gentle high bubble, should also easily degrade, it is free from environmental pollution.The active ingredient master of dish washing detergent
If surfactant, conventional cutlery detergent is main with synthetic surfactant (such as LAS, AS, AES, SAS)
It is raw material.But they are not mostly degradable or cannot degrade, and environment is polluted.Therefore, Environment-friendlytableware tableware detergent is developed
The trend in epoch is complied with, especially in Europe, the U.S. and Japan, the use of Environment-friendlytableware tableware detergent is fairly common.But
The country, the development of Environment-friendlytableware tableware detergent is slower, and particularly feature liquid detergent is just fewer.
The content of the invention
In view of this, the present invention provides a kind of sterilization-deodordetergent detergent and preparation method thereof, liquid detergent prepared by the present invention
With natural component as primary raw material, safety non-toxic, non-excitant, with natural plant fragrance, deodorization and sterilization effect is good, also has
Strong washing function and effect of skin care.
The technical scheme is that：A kind of sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shitosan
Amphoteric polymeric surfactant 34-52 parts, sodium 2-ethylhexyl sulfate 12-23 parts, lauroylamidopropyl betaine 22-
34 parts, deionized water 8-14 parts, 2-5 parts of shaddock peel essential oil, pomegranate rind extract 13-17 parts, Chinese gall enzymolysis product 14-
27 parts.
Further, described sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shitosan both sexes high score
Sub- surfactant 38-46 parts, sodium 2-ethylhexyl sulfate 15-19 parts, lauroylamidopropyl betaine 26-31 parts, go from
Sub- water 9-12 parts, 3-5 parts of shaddock peel essential oil, pomegranate rind extract 14-16 parts, 18-23 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=10-22.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 6.8-7.2, adds granatum to extract
Thing, Chinese gall enzymolysis product, pomelo peel essence, is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas,
Vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtain sterilization-deodordetergent detergent.
The beneficial effects of the present invention are：Modern design, combination is reasonable, and manufacture is easy, it is easy to industrialized production；Use
The alternative liquid detergent common in the market of liquid detergent that the present invention is developed is used for family, the place such as hotel and all kinds of dining rooms
The cleaning of tableware, fruit and vegetables, while having the functions, effect is significant such as deodorization and sterilization, removal residues of pesticides；In the composition
The surfactants such as shitosan amphoteric polymeric surfactant do not only have excellent washing performance, and possess nontoxic, non-stimulated, raw
The performances such as thing degraded is rapid, safety, are the comprehensive green surfactants of performance；Shaddock peel essential oil in the present invention, granatum is carried
Thing is taken, is not chemical industry synthesis product containing abundant bioactive ingredients in Chinese gall enzymolysis product, can substitute make in liquid detergent
Chemical solvent, cleaning performance is good, while efficient bactericidal action can be played by the Synergistic of each component, is using
In be non-harmful, with natural plant fragrance, can go to eliminate the unusual smell, skin care does not stimulate.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
43 parts of glycan amphoteric polymeric surfactant, 17 parts of sodium 2-ethylhexyl sulfate, 28 parts of lauroylamidopropyl betaine goes
11 parts of ionized water, 4 parts of shaddock peel essential oil, 15 parts of pomegranate rind extract, 21 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 6.8, adds pomegranate rind extract,
Chinese gall enzymolysis product, pomelo peel essence, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, negative pressure
Control is dispensed, you can obtain sterilization-deodordetergent detergent in 5Mpa to mixed liquor.
Embodiment 2
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
43 parts of glycan amphoteric polymeric surfactant, 17 parts of sodium 2-ethylhexyl sulfate, 28 parts of lauroylamidopropyl betaine goes
11 parts of ionized water, 3 parts of shaddock peel essential oil, 16 parts of pomegranate rind extract, 18 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=18.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.2, adds pomegranate rind extract,
Chinese gall enzymolysis product, pomelo peel essence, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, negative pressure
Control is dispensed, you can obtain sterilization-deodordetergent detergent in 5Mpa to mixed liquor.
Embodiment 3
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
41 parts of glycan amphoteric polymeric surfactant, 17 parts of sodium 2-ethylhexyl sulfate, 29 parts of lauroylamidopropyl betaine, go from
11 parts of sub- water, 5 parts of shaddock peel essential oil, 14 parts of pomegranate rind extract, 23 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=14.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds pomegranate rind extract,
Chinese gall enzymolysis product, pomelo peel essence, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, negative pressure
Control is dispensed, you can obtain sterilization-deodordetergent detergent in 5Mpa to mixed liquor.
Embodiment 4
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
38 parts of glycan amphoteric polymeric surfactant, 15 parts of sodium 2-ethylhexyl sulfate, 26 parts of lauroylamidopropyl betaine goes
9 parts of ionized water, 4 parts of shaddock peel essential oil, 15 parts of pomegranate rind extract, 21 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=20.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 6.9, adds pomegranate rind extract,
Chinese gall enzymolysis product, pomelo peel essence, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, negative pressure
Control is dispensed, you can obtain sterilization-deodordetergent detergent in 5Mpa to mixed liquor.
Embodiment 5
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
46 parts of glycan amphoteric polymeric surfactant, 19 parts of sodium 2-ethylhexyl sulfate, 31 parts of lauroylamidopropyl betaine, go from
12 parts of sub- water, 4 parts of shaddock peel essential oil, 15 parts of pomegranate rind extract, 21 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=12.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.1, adds pomegranate rind extract,
Chinese gall enzymolysis product, pomelo peel essence, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, negative pressure
Control is dispensed, you can obtain sterilization-deodordetergent detergent in 5Mpa to mixed liquor.
Comparative example 1
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：
17 parts of sodium 2-ethylhexyl sulfate, 28 parts of lauroylamidopropyl betaine, 11 parts of deionized water, 4 parts of shaddock peel essential oil, pomegranate
15 parts of bark extract, 21 parts of Chinese gall enzymolysis product.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, after sodium 2-ethylhexyl sulfate stirs, temperature
Degree is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds pomegranate rind extract, and Chinese gall enzymolysis product, pomelo peel essence are stirred
Mix to uniform, the feed liquid that will be stirred is de-gassed, and using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor,
Can obtain sterilization-deodordetergent detergent.
Comparative example 2
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
43 parts of glycan amphoteric polymeric surfactant, 17 parts of sodium 2-ethylhexyl sulfate, 11 parts of deionized water, shaddock peel essential oil 4
Part, 15 parts of pomegranate rind extract, 21 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, sodium 2-ethylhexyl sulfate, the stirring of shitosan amphoteric polymeric surfactant are sequentially added by weight
After uniform, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds pomegranate rind extract, Chinese gall enzymolysis product, shaddock
Skin essence, is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations in 5Mpa, to mixed liquor
Dispensed, you can obtain sterilization-deodordetergent detergent.
Comparative example 3
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
43 parts of glycan amphoteric polymeric surfactant, 17 parts of sodium 2-ethylhexyl sulfate, 28 parts of lauroylamidopropyl betaine goes
11 parts of ionized water, 4 parts of shaddock peel essential oil, 21 parts of Chinese gall enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the Chinese gall enzymolysis product is：The pre- places such as Chinese gall is size-reduced, sieving and impurity elimination
After reason, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzyme
Solution condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Again Chinese gall enzymolysis product is obtained by micro-filtration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, adds Chinese gall enzymolysis to produce
Thing, pomelo peel essence, are stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations in 5Mpa,
Mixed liquor is dispensed, you can obtain sterilization-deodordetergent detergent.
Comparative example 4
The present embodiment provides a kind of sterilization-deodordetergent detergent, sterilization-deodordetergent detergent, by following parts by weight into being grouped into：Shell
43 parts of glycan amphoteric polymeric surfactant, 17 parts of sodium 2-ethylhexyl sulfate, 28 parts of lauroylamidopropyl betaine goes
11 parts of ionized water, 4 parts of shaddock peel essential oil, 15 parts of pomegranate rind extract.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the shitosan amphoteric polymeric surfactant is with natural chitosan as raw material, with long-chain fat
Fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid are used as a kind of synthetically prepared water-soluble high score based on shitosan for obtaining of alkylating reagent
Sub- surfactant.
Further, the preparation method of the granatum extraction product is：Granatum is cleaned into stripping and slicing to dry, then pomegranate
Skin grind into powder simultaneously crosses 50 mesh sieves, and the Pomegranate Rind after sieving adds 70% ethanol, the quality of Pomegranate Rind
G the volume (mL) of () and ethanol is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) assisted extraction 20
min；Granatum ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration
Centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains granatum crude extract；By HPD-300
Macroreticular resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropores
The special chromatographic column of resin；Granatum crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains granatum and extracts product after wash-out liquid condensing concentration.
A kind of preparation method of sterilization-deodordetergent detergent, including step in detail below：By deionized water add reactor in,
70 DEG C are heated to, lauroylamidopropyl betaine is sequentially added by weight, sodium 2-ethylhexyl sulfate, shitosan both sexes are high
After molecular surface active agent stirs, temperature is down to 40 DEG C, and the PH values of solution are adjusted into 7.0, add pomegranate rind extract,
Pomelo peel essence, is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations in 5Mpa, to mixed
Close liquid to be dispensed, you can obtain sterilization-deodordetergent detergent.
Comparative example 5
Receive the full effect enriching liquid detergent of good Mrs's brand of Li Xinxihua Co., Ltds production from Hebei, bucket limit makes the date be
20180523, as a comparison case 5.
Comparative example 6
From the lemon aloe liquid detergent of labourer's personal style and attitude board of Guangzhou Nanshun Cleaning Products Co., Ltd.'s production, bucket limit makes the date be
20180803A, as a comparison case 6.
Experimental test
1. bactericidal effect test
Using Suspension quantitative bactericidal test, Escherichia coli, Candida albicans, the S. aureus Inoculate after activation are taken first
Into triangle shaking flask, 37 DEG C, the 160 r/h of min shaken cultivations 36.Then the above-mentioned bacteria suspensions of inoculation 1ml are distinguished respectively
2% dilution with the liquid detergent of 9 ml embodiments 1-5 and comparative example 1-6 mixes, 37 DEG C, 160 r/min vibrations
30min, with dilution the method for falling ware measure detergent to Escherichia coli, Candida albicans, staphylococcus aureus killing logarithm value,
Parallel test in triplicate, calculates bactericidal effect such as following table.
2. detergency experiment
Press《Manual dishwashing detergent》The method of the standards of GB 9985-2000 purchase artificial dirt, 250 ppm hard water,
Instrument needed for dirt ceramics plate and foam level method test detergency.Using foam end point method, respectively Example 1-5 with
And comparative example 1-6 liquid detergent 5mL, by 1000mL concentration for the hard water of 250ppm is poured into enamel basin, separately by 1000mL concentration
For the hard water of 250ppm is put into tubualted bottle.In room temperature（25 ℃）Under, the delivery port of tubualted bottle is opened, hard water is rushed in flowing into basin
Spume.After hard water stops flowing out（The s of process about 45）, plate is scrubbed with 102 mm pigs palm fibre paintbrush, first brush clockwise
5 times, another mistake hour hands brush 5 times, after so repeating 1 time, the dirt major part being applied on plate is washed down, finally again will not
Wash lower part to scrub off, until foam is wholly absent, record the number that washes dishes, and be finally converted into deep bid subnumber, it is as a result as follows
Shown in table.
3. security toxicological test.
The main formula of Example 1 carries out toxicological test, foundation respectively《Foodsafety Toxicological Assessment program and side
Method》GB 15193-2003, using maximum tolerance metering experiment method, dosage is set to 10000 mg/kg BW, from 20
Kunming mice, male and female half and half.The h of animal fasting 16, drinking-water is not limited before experiment.The mg/mL of animal 500 is given using administration by gavage
The sample solution of concentration, gavage amount is 0.4 mL/20 g body weight.The poisoning manifestations and death condition of animal are observed after gavage,
Weigh weekly 1 time, observe 14 d, it is as a result as shown in the table.
| Sample ID | Shitosan amphoteric polymeric surfactant | Granatum extracts product | Chinese gall enzymolysis product |
| LD50（mg/kg·BW） | 20000 | 35000 | 30000 |
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask and limited rather than described above, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.The ins and outs not described in detail in the present invention, can be by any in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (7)
1. a kind of sterilization-deodordetergent detergent, it is characterised in that by following parts by weight into being grouped into：Shitosan Amphiphatic high polymer
Surfactant 34-52 parts, sodium 2-ethylhexyl sulfate 12-23 parts, lauroylamidopropyl betaine 22-34 parts, deionization
Water 8-14 parts, 2-5 parts of shaddock peel essential oil, pomegranate rind extract 13-17 parts, 14-27 parts of Chinese gall enzymolysis product.
2. sterilization-deodordetergent detergent according to claim 1, it is characterised in that by following parts by weight into being grouped into：
38-46 parts of shitosan amphoteric polymeric surfactant, sodium 2-ethylhexyl sulfate 15-19 parts, lauroylamidopropyl betaine
26-31 parts, deionized water 9-12 parts, 13-15 parts of shaddock peel essential oil, pomegranate rind extract 4-6 parts, Chinese gall enzymolysis product 18-
23 parts.
3. sterilization-deodordetergent detergent according to claim 1, it is characterised in that live on the shitosan Amphiphatic high polymer surface
The molecular formula of property agent is, wherein n=10-22.
4. sterilization-deodordetergent detergent according to claim 3, it is characterised in that live on the shitosan Amphiphatic high polymer surface
Property agent be with natural chitosan as raw material, using long-chain fat aldehyde, 3- chlorine-2-hydroxyls propane sulfonic acid as alkylating reagent synthesize make
A kind of standby water soluble polymer surfactant based on shitosan for obtaining.
5. sterilization-deodordetergent detergent according to claim 1, it is characterised in that the preparation side of the Chinese gall enzymolysis product
Method is：After the pretreatments such as Chinese gall is size-reduced, sieving and impurity elimination, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, using pancreas
The mode of protease and papain mixed enzymolysis, enzymatic hydrolysis condition is：45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2,
The enzyme concentration of trypsase and papain is respectively 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, enzymolysis liquid is existed
5000r/min centrifugations 10min at 4 DEG C, takes supernatant, then obtain Chinese gall enzymolysis product by micro-filtration.
6. sterilization-deodordetergent detergent according to claim 1, it is characterised in that the granatum extracts the preparation side of product
Method is：Granatum is cleaned into stripping and slicing to dry, then granatum grind into powder and crosses 50 mesh sieves, the granatum powder after sieving
End adds 70% ethanol, and the quality (g) of Pomegranate Rind is with the volume (mL) of ethanol than m: V=1: 13；Ultrasonic wave
Shaker (40 DEG C, 450 W) min of assisted extraction 20；Granatum ethanol flows back through water-bath extract again, and extraction temperature is
65 DEG C, extract 3 times, 1.5 h every time, suction filtration centrifugation (5000r/min, 15min), rotary evaporation in vacuo after filtering
Ethanol is reclaimed, granatum crude extract is obtained；By HPD-300 macroreticular resins with 95% ethanol soak 24 h, distilled water clean to
Without being put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins after ethanol flavor；Granatum crude extract with 400 BV/h (
BV:The volume of macroreticular resin) the rate of adsorption be adsorbed on HPD-300 macroreticular resins, upper column quantity be 600 BV；Absorption
The complete resin distilled water of 800 BV is with the impurity on the flow velocity eluted resin of 1000 BV/h, then uses 1200 BV
60% ethanol the crude extract being attached on resin is eluted, wash-out liquid condensing concentration after obtain granatum extract produce
Thing.
7. the preparation method of a kind of sterilization-deodordetergent detergent as described in any one of claim 1- 6, it is characterised in that including
Step in detail below：By in deionized water addition reactor, 70 DEG C are heated to, dodecanamide propyl is sequentially added by weight
Glycine betaine, sodium 2-ethylhexyl sulfate, after shitosan amphoteric polymeric surfactant stirs, temperature is down to 40 DEG C, will
The PH values of solution are adjusted to 6.8-7.2, add pomegranate rind extract, Chinese gall enzymolysis product, pomelo peel essence to be stirred until homogeneous,
The feed liquid that will be stirred is de-gassed, and using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtained
Sterilization-deodordetergent detergent.
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